TWI825902B - Imitation wood recycling method and system thereof - Google Patents

Imitation wood recycling method and system thereof Download PDF

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TWI825902B
TWI825902B TW111129585A TW111129585A TWI825902B TW I825902 B TWI825902 B TW I825902B TW 111129585 A TW111129585 A TW 111129585A TW 111129585 A TW111129585 A TW 111129585A TW I825902 B TWI825902 B TW I825902B
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imitation wood
recycled
synthetic rubber
recycling
molding
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TW202407010A (en
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莊承翰
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莊承翰
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Abstract

The present invention relates to a method and system for recycling and reproducing imitation wood. The method for recovering and reproducing imitation wood is applied to the recovered wood imitation plastic scraps and recovered materials, and includes a crushing step, a mixing step, an adding step, a granulating step and a molding step. Among them, the pulverizing step is to powder the recovered wood imitation plastic scraps and recovered materials; the mixing step is to fully mix the recovered wood imitation plastic scraps and recovered materials to form recycled raw materials ; the adding step is to add functional additives to the recycled raw materials in powder form after the mixing step; the granulating step is to make the recycled raw materials into granular polymer raw materials after adding the functional additives ; the molding step is to melt these polymer raw materials into a flowing state to make a recycled imitation wood product. The imitation wood recycling system applies the imitation wood recycling method.

Description

仿木的回收再製方法及其系統Imitation wood recycling method and system

本發明係有關於一種仿木的回收再製方法及其系統,特別是關於一種實現環保及回收再利用仿木塑膠下腳料(scraps)及回收料的回收再製方法及其系統。The present invention relates to a method and system for recycling imitation wood, and in particular to a method and system for recycling imitation wood plastic scraps and recycled materials to achieve environmental protection and recycling.

按,在眾多自然資源中,森林資源實乃地球資源中極為重要之一資產,森林資源除孕育了豐富多樣的動植物生態外,亦提供人類所需之各種資材,且與人類生活息息相關,因此,如何增進木材利用率、回收率及再利用率等,即成為世界各國亟欲突破之一重要議題,以期能減少天然資源的無謂浪費,並有效減少殘料處理時所需之人力與物力。According to reports, among many natural resources, forest resources are actually one of the most important assets in the earth's resources. In addition to nurturing a rich and diverse ecosystem of animals and plants, forest resources also provide various materials needed by humans and are closely related to human life. Therefore, How to improve the utilization rate, recycling rate and reuse rate of wood has become an important issue that countries around the world are eager to break through, in order to reduce the unnecessary waste of natural resources and effectively reduce the manpower and material resources required for residual material processing.

有鑒於此,近年來,對於以木材殘削或碎片製備高分子塑膠生物複合材料(woodplastic composite, WPC)之研究,越來越受到世界各國重視,其原因係WPC除能有效利用木質纖維殘料製備複合材外,WPC較真實木材具備更良好的尺寸安定性及抵抗病蟲之能力,因此,無須特別維護,其使用年限即能高達25~30年之久。目前,WPC的應用範疇主要以交通運輸工具與非結構及半結構建築等用材為主。In view of this, in recent years, research on the preparation of polymer plastic biocomposites (woodplastic composite, WPC) from wood residues or fragments has attracted more and more attention around the world. The reason is that WPC can effectively utilize wood fiber residues. In addition to the preparation of composite materials, WPC has better dimensional stability and resistance to diseases and pests than real wood. Therefore, it does not require special maintenance and its service life can be as long as 25 to 30 years. At present, the application areas of WPC are mainly materials used in transportation vehicles and non-structural and semi-structural buildings.

一般而言,複合材料係利用兩種或兩種以上不同性質的原材料,以不同的加工法,結合在一起,以擷取各該原材料之特性與優點,發揮協同作用(synergistic effect),製成性能優異並能滿足需求的一種新材料。在眾多複合材料中,尤以纖維強化(fiber reinforced)之複合材料的性能較佳,應用也較廣。近年來,WPC在使用上已大量取代傳統的金屬、塑膠與實木材料,並常被應用至舖板、柵欄、外壁板、窗框及屋頂材料等製品上。然而,以利用兩種或兩種以上不同性質的原材料以不同的加工法結合在一起,仍存在許多問題,其中,最大的問題係在膠體之間常因表面極性的不同,阻礙二者間之化學鍵結。Generally speaking, composite materials are made by using two or more raw materials with different properties and combining them with different processing methods to capture the characteristics and advantages of each raw material and exert a synergistic effect. A new material that has excellent performance and meets the needs. Among many composite materials, fiber reinforced composite materials have better performance and are widely used. In recent years, WPC has largely replaced traditional metal, plastic and solid wood materials in use, and is often used in products such as decking, fences, exterior sidings, window frames and roofing materials. However, there are still many problems in combining two or more raw materials with different properties through different processing methods. Among them, the biggest problem is that the difference in surface polarity between colloids often hinders the connection between the two. Chemical bonding.

此外,在環保意識日益高漲之氛圍下,前述WPC複合材或其它塑膠複合材仍因存在前述諸多結構性缺點及毒性問題,而始終無法被普及使用或應用至人們之日常生活需求中。因此,如何提供一種有效處理WPC複合材的下腳料及回收料,並回收再製為各種用途的仿木成品,係為一研究人員待研究之重點項目。In addition, in an atmosphere of increasing environmental awareness, the aforementioned WPC composite materials or other plastic composite materials still cannot be widely used or applied to people's daily life needs due to the many structural shortcomings and toxicity problems mentioned above. Therefore, how to provide an effective way to process the scraps and recycled materials of WPC composites and recycle them into imitation wood products for various purposes is a key project to be studied by researchers.

有鑑於上述缺點,發明人乃針對該等缺點研究改進之道,終於有本發明產生。In view of the above shortcomings, the inventor researched ways to improve the shortcomings, and finally came up with the present invention.

本發明的目的係提供一種仿木的回收再製方法,其係應用於回收後的仿木塑膠下腳料及回收料,該回收再製方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。The object of the present invention is to provide a method for recycling imitation wood, which is applied to the recycled wood-imitation plastic scraps and recycled materials. The recycling and reproduction method powderizes the imitation wood plastic scraps and recycled materials, and adds plural Functional additives are added to the recycled raw materials in powder form to produce recycled imitation wood products. In this way, imitation wood plastic scraps and recycled materials can be effectively remade into various finished products according to user needs, greatly reducing the harm caused to the environment by burning waste, and at the same time recycling the waste.

本發明之另一目的在於提供一種仿木的回收再製系統,在使用特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。Another object of the present invention is to provide an imitation wood recycling system. After using specific equipment to pulverize imitation wood plastic scraps and recycled materials, an appropriate proportion of functional additives is added to make polystyrene, synthetic rubber, emulsified The flow rate of synthetic rubber and elastomers copolymerized with styrene and butadiene is increased, so that they can be used in molding machines to re-make various finished products. At the same time, by adding appropriate proportions of functional additives, the above mixtures can be effectively prevented from being used in subsequent injection molding. Or die expansion occurs during extrusion molding, and can reduce the interfacial tension between polystyrene, synthetic rubber, the emulsified synthetic rubber, and the elastomer copolymerized with styrene and butadiene, and improve the adhesion of the interface By stabilizing the mixture and molding it into a wood-like form, the mechanical properties such as tensile strength, flexural modulus and impact strength of the wood-like finished product of the present invention can be significantly improved, thereby producing low-cost and stable-quality wood-like imitations. finished products and create new economic value and benefits.

為達成上述目的及功效,本發明所提供之仿木的回收再製方法,其係應用於回收後的一仿木塑膠下腳料及回收料,該仿木的回收再製方法包括:一粉碎步驟,其係將該仿木塑膠下腳料及回收料予以粉體化,該仿木塑膠下腳料及回收料係為一聚苯乙烯、一合成橡膠、一乳化合成橡膠以及一苯乙烯與丁二烯共聚之彈性體的混合物;一添加步驟,其係添加複數功能性助劑至該混合步驟後呈粉末狀之該仿木塑膠下腳料及回收料中,其中,該等功能性助劑包含一有機安定劑、一偶合劑、一熱安定劑、一膠化促進劑、一發泡劑以及一光吸收劑;一混合步驟,其係將添加步驟後之該聚苯乙烯、該合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑經攪拌後充分混合形成一回收原料;一造粒步驟,其係將充分混合該等功能性助劑後之該回收原料輸入至一造粒機構中,以產生顆粒狀的複數高分子原料;以及一成型步驟,其係將該等高分子原料輸入至一成型機構中,該成型機構直接透過熔化成流動狀後的該等高分子原料製成一回收再製的仿木成品。In order to achieve the above objectives and effects, the invention provides a method for recycling imitation wood, which is applied to the recycled imitation wood plastic scraps and recycled materials. The method for recycling imitation wood includes: a crushing step, which is The imitation wood plastic scraps and recycled materials are powdered. The imitation wood plastic scraps and recycled materials are a polystyrene, a synthetic rubber, an emulsified synthetic rubber and an elastomer copolymerized with styrene and butadiene. Mixture; an adding step, which is to add a plurality of functional additives to the imitation wood plastic scraps and recycled materials that are in powder form after the mixing step, wherein the functional additives include an organic stabilizer and a coupling agent , a heat stabilizer, a gelling accelerator, a foaming agent and a light absorber; a mixing step, which is to add the polystyrene, the synthetic rubber, the emulsified synthetic rubber and the styrene after the adding step The elastomer copolymerized with butadiene and the functional additives are stirred and then fully mixed to form a recycled raw material; a granulation step is to input the recycled raw material after fully mixing the functional additives into a granulator In a granulating mechanism, a plurality of granular polymer raw materials are produced; and a molding step is to input the polymer raw materials into a molding mechanism, and the molding mechanism directly passes the polymer raw materials melted into a flowing state. Made into a recycled imitation wood product.

較佳地,根據本發明之仿木的回收再製方法,其中,該聚苯乙烯的重量百分比介於30%-85%,該合成橡膠的重量百分比介於5%-50%,該乳化合成橡膠的重量百分比介於3%-45%,該苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。Preferably, according to the imitation wood recycling method of the present invention, the weight percentage of the polystyrene is between 30% and 85%, the weight percentage of the synthetic rubber is between 5% and 50%, and the emulsified synthetic rubber The weight percentage of the elastomer is between 3% and 45%, and the weight percentage of the elastomer copolymerized with styrene and butadiene is between 2% and 35%.

較佳地,根據本發明之仿木的回收再製方法,其中,該有機安定劑的百分含量(Parts per hundred parts of resin, PHR)介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。Preferably, according to the imitation wood recycling method of the present invention, the percentage content of the organic stabilizer (Parts per hundred parts of resin, PHR) is between 0.1% and 10%, and the percentage content of the coupling agent Between 0.1%-5%, the percentage content of the thermal stabilizer is between 0.1%-3%, the percentage content of the gelling accelerator is between 0.1%-10%, and the percentage content of the foaming agent is between The percentage content of the light absorber is between 0.1% and 3%.

較佳地,根據本發明之仿木的回收再製方法,其中,有機安定劑係選自抗氧化劑以及光穩定劑其中之一。Preferably, according to the imitation wood recycling method of the present invention, the organic stabilizer is selected from one of antioxidants and light stabilizers.

較佳地,根據本發明之仿木的回收再製方法,其中,該成型步驟在溫度介於150°C〜260°C的條件下,以押出成型與射出成型的其中一種方式成型出該回收再製的仿木成品。Preferably, according to the imitation wood recycling method of the present invention, the molding step is performed at a temperature between 150°C and 260°C, using one of extrusion molding and injection molding to shape the recycled wood. Imitation wood finished products.

又,本發明以上述之仿木的回收再製方法為基礎,進一步提供一種仿木的回收再製系統,其係應用於回收後的一仿木塑膠下腳料及回收料,該仿木的回收再製系統包括:一粉碎機構,其係將該仿木塑膠下腳料及回收料予以粉體化,該仿木塑膠下腳料及回收料係為一聚苯乙烯、一合成橡膠、一乳化合成橡膠以及一苯乙烯與丁二烯共聚之彈性體的混合物;一添加機構,其係耦接於該粉碎機構,該添加機構添加複數功能性助劑至呈粉末狀之該仿木塑膠下腳料及回收料中,其中,該等功能性助劑包含一有機安定劑、一偶合劑、一熱安定劑、一膠化促進劑、一發泡劑以及一光吸收劑;一混合機構,其係耦接於該添加機構,該混合機構係用於將該聚苯乙烯、該合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑攪拌後充分混合形成一回收原料;一造粒機構,其係耦接於該添加機構,該造粒機構係將充分混合該等功能性助劑後之該回收原料製成呈顆粒狀的複數高分子原料;以及一成型機構,其係耦接於該造粒機構,該成型機構直接透過熔化成流動狀後的該等高分子原料製成一回收再製的仿木成品。In addition, the present invention is based on the above-mentioned recycling method of imitation wood, and further provides a recycling and recycling system of imitation wood, which is applied to the recycled imitation wood plastic scraps and recycled materials. The recycling and recycling system of imitation wood includes : A crushing mechanism that pulverizes the imitation wood plastic scraps and recycled materials. The imitation wood plastic scraps and recycled materials are polystyrene, synthetic rubber, emulsified synthetic rubber and styrene and butadiene. A mixture of diene copolymerized elastomers; an adding mechanism coupled to the crushing mechanism, the adding mechanism adds a plurality of functional additives to the imitation wood plastic scraps and recycled materials in powder form, wherein, the Functional additives include an organic stabilizer, a coupling agent, a thermal stabilizer, a gelling accelerator, a foaming agent and a light absorber; a mixing mechanism coupled to the adding mechanism, the mixing mechanism The mechanism is used to stir the polystyrene, the synthetic rubber, the emulsified synthetic rubber and the elastomer copolymerized with styrene and butadiene with the functional additives and then thoroughly mix them to form a recycled raw material; a granulating mechanism , which is coupled to the adding mechanism, the granulating mechanism is used to make the recycled raw materials after fully mixing the functional additives into granular plurality of polymer raw materials; and a molding mechanism, which is coupled to The granulating mechanism and the molding mechanism directly produce a recycled imitation wood finished product by melting the polymer raw materials into a fluid state.

較佳地,根據本發明之仿木的回收再製系統,其中,該聚苯乙烯的重量百分比介於30%-85%,該合成橡膠的重量百分比介於5%-50%,該乳化合成橡膠的重量百分比介於3%-45%,該苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。Preferably, according to the imitation wood recycling system of the present invention, the weight percentage of the polystyrene is between 30% and 85%, the weight percentage of the synthetic rubber is between 5% and 50%, and the emulsified synthetic rubber The weight percentage of the elastomer is between 3% and 45%, and the weight percentage of the elastomer copolymerized with styrene and butadiene is between 2% and 35%.

較佳地,根據本發明之回收再製系統,其中,該有機安定劑的百分含量介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。Preferably, according to the recycling system of the present invention, the percentage content of the organic stabilizer is between 0.1% and 10%, the percentage content of the coupling agent is between 0.1% and 5%, and the percentage content of the thermal stabilizer is between 0.1% and 5%. The percentage content of the gelling accelerator is between 0.1% and 3%, the percentage content of the foaming agent is between 0.1% and 3%, and the percentage content of the light absorbing agent is between 0.1% and 3%. The content is between 0.1%-3%.

較佳地,根據本發明之回收再製系統,其中,該有機安定劑係選自抗氧化劑以及光穩定劑其中之一。Preferably, according to the recycling system of the present invention, the organic stabilizer is selected from one of antioxidants and light stabilizers.

較佳地,根據本發明之回收再製系統,其中,該成型機構在溫度介於150°C〜260°C的條件下,以押出成型與射出成型的其中一種方式成型出該回收再製的仿木成品。Preferably, according to the recycling system of the present invention, the molding mechanism molds the recycled imitation wood by one of extrusion molding and injection molding at a temperature between 150°C and 260°C. Finished product.

綜上,本發明所提供之仿木的回收再製方法,其係應用於回收後的仿木塑膠下腳料及回收料,該回收再製方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。此外,本發明透過特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。In summary, the method for recycling imitation wood provided by the present invention is applied to the recycled imitation wood plastic scraps and recycled materials. The recycling and reproducing method pulverizes the imitation wood plastic scraps and recycled materials, and adds A plurality of functional additives are added to the recycled raw materials in powder form to produce recycled imitation wood products. In this way, imitation wood plastic scraps and recycled materials can be effectively remade into various finished products according to user needs, greatly reducing the harm caused to the environment by burning waste, and at the same time recycling the waste. In addition, the present invention uses specific equipment to powder the imitation wood plastic scraps and recycled materials, and then adds an appropriate proportion of functional additives to make polystyrene, synthetic rubber, emulsified synthetic rubber and the copolymer of styrene and butadiene more elastic. The flow rate of the mixture is increased so that it can be used in molding machines to make various finished products. At the same time, by adding appropriate proportions of functional additives, the above mixture can effectively prevent die expansion during subsequent injection molding or extrusion molding. It can also reduce the interfacial tension between polystyrene, synthetic rubber, emulsified synthetic rubber, and elastomers copolymerized with styrene and butadiene, and improve the adhesion of the interface to stabilize the mixture into a wood-like shape, thereby, It can significantly improve the mechanical properties such as tensile strength, flexural modulus and impact strength of the imitation wood products of the present invention, thereby producing low-cost and stable quality imitation wood products, and creating new economic value and benefits.

爲使熟悉該項技藝人士瞭解本發明之目的、特徵及功效,茲藉由下述具體實施例,並配合所附之圖式,對本發明詳加說明如下。In order to enable those familiar with the art to understand the purpose, features and effects of the present invention, the present invention is described in detail below with reference to the following specific embodiments and the accompanying drawings.

現在將參照其中示出本發明概念的示例性實施例的附圖 在下文中更充分地闡述本發明概念。以下藉由參照附圖更詳細地闡述的示例性實施例,本發明概念的優點及特徵以及其達成方法將顯而易見。然而,應注意,本發明概念並非僅限於以下示例性實施例,而是可實施為各種形式。因此,提供示例性實施例僅是為了揭露本發明概念並使熟習此項技術者瞭解本發明概念的類別。在圖式中,本發明概念的示例性實施例並非僅限於本文所提供的特定實例且為清晰起見而進行放大。Inventive concepts will now be elucidated more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the inventive concepts are shown. The advantages and features of the inventive concept, as well as the methods for achieving them, will be apparent from the following exemplary embodiments, which are explained in more detail with reference to the accompanying drawings. However, it should be noted that the inventive concept is not limited to the following exemplary embodiments, but can be implemented in various forms. Accordingly, the exemplary embodiments are provided solely to disclose the inventive concepts and to enable those skilled in the art to understand the nature of the inventive concepts. In the drawings, exemplary embodiments of the inventive concepts are not limited to the specific examples provided herein and are exaggerated for clarity.

本文所用術語僅用於闡述特定實施例,而並非旨在限制本發明。除非上下文中清楚地另外指明,否則本文所用的單數形式的用語「一」及「該」旨在亦包括複數形式。本文所用的用語「及/或」包括相關所列項其中一或多者的任意及所有組合。應理解,當稱元件「連接」或「耦合」至另一元件時,所述元件可直接連接或耦合至所述另一元件或可存在中間元件。The terminology used herein is for describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items. It will be understood that when an element is referred to as being "connected" or "coupled" to another element, it can be directly connected or coupled to the other element or intervening elements may be present.

相似地,應理解,當稱一個元件(例如層、區或基板)位於另一元件「上」時,所述元件可直接位於所述另一元件上,或可存在中間元件。相比之下,用語「直接」意指不存在中間元件。更應理解,當在本文中使用用語「包括」、「包含」時,是表明所陳述的特徵、整數、步驟、操作、元件、及/或組件的存在,但不排除一或多個其他特徵、整數、步驟、操作、元件、組件、及/或其群組的存在或添加。Similarly, it will be understood that when an element (such as a layer, region or substrate) is referred to as being "on" another element, it can be directly on the other element or intervening elements may be present. In contrast, the term "directly" means that there are no intermediate elements. Furthermore, it should be understood that when the words "include" and "include" are used herein, they indicate the presence of stated features, integers, steps, operations, elements, and/or components, but do not exclude one or more other features. , the existence or addition of integers, steps, operations, elements, components, and/or groups thereof.

此外,將藉由作為本發明概念的理想化示例性圖的剖視圖來闡述詳細說明中的示例性實施例。相應地,可根據製造技術及/或可容許的誤差來修改示例性圖的形狀。因此,本發明概念的示例性實施例並非僅限於示例性圖中所示出的特定形狀,而是可包括可根據製造製程而產生的其他形狀。圖式中所例示的區域具有一般特性,且用於說明元件的特定形狀。因此,此不應被視為僅限於本發明概念的範圍。Furthermore, exemplary embodiments in the detailed description will be illustrated by cross-sectional illustrations that are idealized illustrations of the concepts of the invention. Accordingly, the shape of the example diagrams may be modified based on manufacturing techniques and/or tolerable errors. Accordingly, exemplary embodiments of the inventive concepts are not limited to the specific shapes shown in the exemplary figures, but may include other shapes that may be produced depending on the manufacturing process. The regions illustrated in the drawings are of general nature and are intended to illustrate the specific shapes of components. Therefore, this should not be considered as limiting the scope of the inventive concept.

亦應理解,儘管本文中可能使用用語「第一」、「第二」、「第三」等來闡述各種元件,然而該些元件不應受限於該些用語。該些用語僅用於區分各個元件。因此,某些實施例中的第一元件可在其他實施例中被稱為第二元件,而此並不背離本發明的教示內容。本文中所闡釋及說明的本發明概念的態樣的示例性實施例包括其互補對應物。本說明書通篇中,相同的參考編號或相同的指示物表示相同的元件。It should also be understood that although the terms "first", "second", "third", etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish between various components. Thus, a first element in some embodiments could be termed a second element in other embodiments without departing from the teachings of the present invention. Exemplary embodiments of aspects of the inventive concepts illustrated and described herein include their complementary counterparts. Throughout this specification, the same reference number or designator indicates the same element.

此外,本文中參照剖視圖及/或平面圖來闡述示例性實施例,其中所述剖視圖及/或平面圖是理想化示例性說明圖。因此,預期存在由例如製造技術及/或容差所造成的相對於圖示形狀的偏離。因此,示例性實施例不應被視作僅限於本文中所示區的形狀,而是欲包括由例如製造所導致的形狀偏差。因此,圖中所示的區為示意性的,且其形狀並非旨在說明裝置的區的實際形狀、亦並非旨在限制示例性實施例的範圍。Furthermore, exemplary embodiments are described herein with reference to cross-sectional and/or plan views, which are idealized illustrations of the exemplary embodiments. Therefore, deviations from the shapes illustrated are expected to occur due, for example, to manufacturing techniques and/or tolerances. Thus, example embodiments should not be construed as limited to the shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. Accordingly, the regions shown in the figures are schematic and their shapes are not intended to illustrate the actual shapes of the regions of the device nor to limit the scope of the exemplary embodiments.

請參閱圖1-3所示,圖1為本發明之仿木的回收再製方法的方塊圖;圖2為根據本發明之仿木的回收再製系統的示意圖;圖3為說明實際執行根據本發明之仿木的回收再製方法的示意圖。如圖1-3所示,本發明所提供之仿木的回收再製方法,其係應用於回收後的仿木塑膠下腳料(scraps)及回收料11,該回收再製方法包括下列步驟:Please refer to Figures 1-3. Figure 1 is a block diagram of the imitation wood recycling method of the present invention; Figure 2 is a schematic diagram of the imitation wood recycling system according to the present invention; Figure 3 is an illustration of the actual implementation of the imitation wood recycling system according to the present invention. Schematic diagram of the recycling method of imitation wood. As shown in Figures 1-3, the imitation wood recycling method provided by the present invention is applied to the recycled imitation wood plastic scraps and recycled materials 11. The recycling method includes the following steps:

粉碎步驟S1,將仿木塑膠下腳料及回收料11予以粉體化,其中,該仿木塑膠下腳料及回收料11係為聚苯乙烯(Polystyrene)、合成橡膠(Styrene-Butadiene Rubber, SBR)、乳化合成橡膠(emulsion polymerized butadiene styrene rubber, ESBR)以及苯乙烯與丁二烯共聚之彈性體的混合物,接著執行添加步驟S2。In the crushing step S1, the imitation wood plastic scraps and recycled materials 11 are powdered, wherein the imitation wood plastic scraps and recycled materials 11 are polystyrene (Polystyrene), synthetic rubber (Styrene-Butadiene Rubber, SBR), emulsified A mixture of synthetic rubber (emulsion polymerized butadiene styrene rubber, ESBR) and elastomer copolymerized with styrene and butadiene is then added to step S2.

添加步驟S2,添加複數功能性助劑12至粉碎步驟S1後呈粉末狀之仿木塑膠下腳料及回收料11中,其中,該等功能性助劑12包含有機安定劑、偶合劑、熱安定劑、膠化促進劑、發泡劑以及光吸收劑,接著執行混合步驟S3。Adding step S2, adding a plurality of functional additives 12 to the powdery imitation wood plastic scraps and recycled materials 11 after the crushing step S1, wherein the functional additives 12 include organic stabilizers, coupling agents, and thermal stabilizers. , gelling accelerator, foaming agent and light absorber, and then perform mixing step S3.

混合步驟S3,將添加步驟S2後之該聚苯乙烯、該合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑12經攪拌後充分混合形成回收原料13,接著執行造粒步驟S4。In the mixing step S3, the polystyrene, the synthetic rubber, the emulsified synthetic rubber and the elastomer copolymerized with styrene and butadiene and the functional additives 12 added in step S2 are stirred and then thoroughly mixed to form a recycling process. Raw material 13, then perform granulation step S4.

造粒步驟S4,將充分混合功能性助劑12後之回收原料13輸入至造粒機構24(如圖2所示)中,以產生顆粒狀的複數高分子原料14,接著執行成型步驟S5。In the granulation step S4, the recovered raw material 13 after fully mixing the functional additives 12 is input into the granulation mechanism 24 (as shown in FIG. 2) to produce granular plurality of polymer raw materials 14, and then the molding step S5 is performed.

成型步驟S5,將高分子原料14輸入至成型機構25(如圖2所示)中,成型機構25直接透過熔化成流動狀後的高分子原料14製成回收再製的仿木成品15。In the molding step S5, the polymer raw material 14 is input into the molding mechanism 25 (as shown in FIG. 2). The molding mechanism 25 directly melts the polymer raw material 14 into a fluid state to form the recycled imitation wood finished product 15.

具體地,根據本發明之有機安定劑可以用於防止回收原料13變質。在一些實施例中,有機安定劑可以為抗氧化劑(antioxidants),抗臭氧劑(antiozonants),光保護裝置(light-protection means),UV穩定劑(UV stabilisers),UV吸收劑(UV absorbers)或UV阻斷劑(UV blockers),潤滑劑(lubricants),脫模劑(mould-release agents),分離裝置(separating means),鏈延長添加劑(chain-lengthening additives),染色劑(colourants),標記裝置(marking means),有機顏料(organic pigments),IR吸收劑(IR absorbers),NIR吸收劑(NIR absorbers),感光變色劑(photochromic agents),脫模劑(mould-release agents),增亮劑(optical brighteners),聚四氟乙烯(polytetrafluoroethylene),無鹵素阻燃劑(halogen-free flame retardants),天然層矽酸鹽(natural layer silicates),合成層矽酸鹽(synthetic layer silicates)等。更具體而言,在一些實施例中,根據本發明之有機安定劑可以選自氧化穩定劑以及光穩定劑其中之一,其中,抗氧化劑可以為苯丙酸,3,5-雙(1,1-二甲基-乙基)-4-羥基-C7-C9支鏈烷基酯(Benzenepropanoic acid,3,5-bis(1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkyl esters),光穩定劑可以為N-(1-乙醯基-2,2,6,6-四甲基-4-哌啶基)-2-十二基琥珀醯亞胺(N-(1-Acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecylsuccinimide),然而本發明不限於此。Specifically, the organic stabilizer according to the present invention can be used to prevent the recycled raw material 13 from deteriorating. In some embodiments, organic stabilizers may be antioxidants, antiozonants, light-protection means, UV stabilizers, UV absorbers, or UV blockers, lubricants, mold-release agents, separating means, chain-lengthening additives, colourants, marking devices (marking means), organic pigments, IR absorbers, NIR absorbers, photochromic agents, mold-release agents, brighteners ( optical brighteners), polytetrafluoroethylene, halogen-free flame retardants, natural layer silicate, synthetic layer silicate, etc. More specifically, in some embodiments, the organic stabilizer according to the present invention can be selected from one of oxidation stabilizers and light stabilizers, wherein the antioxidant can be phenylpropionic acid, 3,5-bis(1, Benzenepropanoic acid,3,5-bis(1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkyl esters), the light stabilizer can be N-(1-ethyl-2,2,6,6-tetramethyl-4-piperidyl)-2-dodecylsuccinimide (N-(1 -Acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecylsuccinimide), however the present invention is not limited thereto.

具體地,根據本發明之偶合劑可以用於改善黏合劑組成物與封裝材料之間的黏附性及黏附可靠性。需要進一步說明的是,根據本發明之偶合劑主要功用在於當將聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物在高溫和/或高濕度條件下維持達長的時間段的情況下,可提高其黏附可靠性。在一些實施例中,偶合劑可以包括矽烷化合物,例如γ-縮水甘油氧基丙基三乙氧基矽 烷、γ-縮水甘油氧基丙基三甲氧基矽烷、γ-縮水甘油氧基丙基甲基二乙氧基矽烷、γ-縮水甘油氧基丙基三乙氧基矽烷、3-巰基丙基三甲氧基矽烷、乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、γ-甲基丙烯醯氧基丙基三甲氧基矽烷、γ-甲基丙烯醯氧基丙基三乙氧基矽烷、γ-氨基丙基三甲氧基矽烷、γ-氨基丙基三乙氧基矽烷、3-異氰酸丙基三乙氧基矽烷、γ-乙醯乙酸丙基三甲氧基矽烷、γ-乙醯乙酸丙基三乙氧基矽烷、β-氰基乙醯基三甲氧基矽烷、β-氰基乙醯基三乙氧基矽烷及乙醯氧基乙醯三甲氧基矽烷等,然而本發明不限於此。Specifically, the coupling agent according to the present invention can be used to improve the adhesion and adhesion reliability between the adhesive composition and the packaging material. It should be further explained that the main function of the coupling agent according to the present invention is to maintain the mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomer copolymerized with styrene and butadiene under high temperature and/or high humidity conditions. The adhesion reliability can be improved over a long period of time. In some embodiments, the coupling agent may include a silane compound, such as γ-glycidoxypropyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropylmethyl Diethoxysilane, γ-glycidoxypropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, γ-methyl Acryloxypropyltrimethoxysilane, γ-methacryloxypropyltriethoxysilane, γ-aminopropyltrimethoxysilane, γ-aminopropyltriethoxysilane, 3- Propyltriethoxysilane isocyanate, γ-propyltrimethoxysilane acetylacetate, propyltriethoxysilane γ-acetylacetate, β-cyanoacetyltrimethoxysilane, β- Cyanoacetyltriethoxysilane, acetyloxyacetyltrimethoxysilane, etc., but the present invention is not limited thereto.

具體地,根據本發明之發泡劑主要係用於使得回收再製的仿木成品15可以具有與木材相類似的微泡組織結構。在一些實施例中,根據本發明之發泡劑可以採用偶氮甲醯胺、4,4'-氧代雙苯磺醯肼、對甲苯磺醯肼以及無機發泡劑(碳酸氫鈉)其中之一或其組合。較佳的是,發泡劑可選用粒徑為2μm至25μm的發泡劑,以避免加工成品發泡不均勻及避免提前發泡的情況,然而本發明不限於此。Specifically, the foaming agent according to the present invention is mainly used to enable the recycled imitation wood finished product 15 to have a microbubble structure similar to wood. In some embodiments, the blowing agent according to the present invention can use azomethamide, 4,4'-oxobishenylsulfonyl hydrazine, p-toluenesulfonyl hydrazine and an inorganic blowing agent (sodium bicarbonate), wherein one or a combination thereof. Preferably, the foaming agent can use a foaming agent with a particle size of 2 μm to 25 μm to avoid uneven foaming of the processed product and avoid premature foaming. However, the present invention is not limited thereto.

具體地,在一些實施例中,膠化促進劑選自但不限於丙烯酸脂。光吸收劑可包含一種或多種成分係選自由苯丙三唑類(Benzotriazole)化合物、二苯甲酮類(Benzophenone)化合物、水楊酸類(Salicylate)化合物、氰基丙烯酸酯類(Cyanoacrylate)化合物、草醯二苯胺類(Oxanilide)化合物及受阻胺類光穩定劑(Hindered amine light stabilizer;HALS)所組成之群組,然而本發明不限於此。Specifically, in some embodiments, the gelling accelerator is selected from, but is not limited to, acrylates. The light absorber may include one or more components selected from the group consisting of benzotriazole compounds, benzophenone compounds, salicylate compounds, cyanoacrylate compounds, A group consisting of oxanilide compounds and hindered amine light stabilizers (HALS), but the present invention is not limited thereto.

藉此,根據本發明之仿木的回收再製方法,其係透過添加步驟(S3)添加複數功能性助劑12至混合步驟S3後呈粉末狀之回收原料13中,使得聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物可以具備足夠的延展性,並透過造粒步驟(S4)將呈粉末狀之回收原料13製成顆粒狀的高分子原料14,最後透過成型步驟(S5)將高分子原料14製成回收再製的仿木成品15,達成大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。Thus, according to the imitation wood recycling method of the present invention, a plurality of functional additives 12 are added to the powdered recycled raw material 13 after the mixing step S3 through the adding step (S3), so that polystyrene, synthetic rubber , the mixture of emulsified synthetic rubber and styrene and butadiene copolymer elastomer can have sufficient ductility, and the powdered recycled raw material 13 is made into granular polymer raw material 14 through the granulation step (S4), Finally, through the molding step (S5), the polymer raw material 14 is made into a recycled imitation wood finished product 15, thereby significantly reducing the harm to the environment caused by burning waste and recycling the waste at the same time.

請參閱圖2所示,本發明再以上述之仿木的回收再製方法為基礎,進一步提供一種仿木的回收再製系統200,其係應用於回收後的仿木塑膠下腳料及回收料11,回收再製系統200包括:粉碎機構21、添加機構22、混合機構23、造粒機構24以及成型機構25。Please refer to Figure 2. Based on the above-mentioned imitation wood recycling method, the present invention further provides an imitation wood recycling system 200, which is applied to the recycled imitation wood plastic scraps and recycled materials 11. The reprocessing system 200 includes a crushing mechanism 21 , an adding mechanism 22 , a mixing mechanism 23 , a granulating mechanism 24 and a molding mechanism 25 .

具體地,如圖2-3所示,根據本發明之粉碎機構21,其係將該仿木塑膠下腳料及回收料11予以粉體化,以方便後續操作,該仿木塑膠下腳料及回收料11係為聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物。在一些實施例中,聚苯乙烯的重量百分比介於30%-85%,合成橡膠的重量百分比介於5%-50%,乳化合成橡膠的重量百分比介於3%-45%,苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。然而本發明不限於此。需要進一步說明的是,由於本發明之仿木塑膠下腳料及回收料11中聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體所佔的比例不同,因此製成回收再製的仿木成品15時,仿木成品15在同橫斷面上會具有不均勻的花紋,達成宛如年輪般之紋理,實現接近真實木料的花紋之功效,大幅增加本發明的適用性。Specifically, as shown in Figures 2-3, according to the crushing mechanism 21 of the present invention, the imitation wood plastic scraps and recycled materials 11 are powdered to facilitate subsequent operations. The imitation wood plastic scraps and recycled materials 11 It is a mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomers copolymerized with styrene and butadiene. In some embodiments, the weight percentage of polystyrene is between 30% and 85%, the weight percentage of synthetic rubber is between 5% and 50%, the weight percentage of emulsified synthetic rubber is between 3% and 45%, and the styrene and The weight percentage of butadiene copolymerized elastomer ranges from 2% to 35%. However, the present invention is not limited to this. It should be further explained that due to the different proportions of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomer copolymerized with styrene and butadiene in the imitation wood plastic scraps and recycled materials 11 of the present invention, they are made into recycled materials. When the imitation wood product 15 is remanufactured, the imitation wood product 15 will have uneven patterns on the same cross-section, achieving a texture like growth rings, achieving an effect close to the pattern of real wood, and greatly increasing the applicability of the present invention.

值得一提的是,由於仿木塑膠下腳料及回收料11呈不規則狀,例如:塊狀或片狀等,使用者將難以對仿木塑膠下腳料及回收料11進行各種操作,從而透過粉碎機構21可以有效將仿木塑膠下腳料及回收料11予以粉體化,大幅提升根據本發明之仿木的回收再製系統200的效率,然而本發明不限於此。It is worth mentioning that since the imitation wood plastic scraps and recycled materials 11 are in irregular shapes, such as blocks or flakes, it will be difficult for users to perform various operations on the imitation wood plastic scraps and recycled materials 11, thereby crushing them through the crushing mechanism. 21 can effectively powder the imitation wood plastic scraps and recycled materials 11, greatly improving the efficiency of the imitation wood recycling system 200 according to the present invention, but the present invention is not limited thereto.

具體地,如圖2-3所示,根據本發明之添加機構22,其係耦接於粉碎機構21,添加機構22添加複數功能性助劑12至混合後呈粉末狀之該仿木塑膠下腳料及回收料11中,其中,該等功能性助劑12包含有機安定劑、偶合劑、熱安定劑、膠化促進劑、發泡劑以及光吸收劑。需要進一步說明的是,在一些實施例中,該有機安定劑的百分含量介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。藉此,本發明之功能性助劑12配合所用的仿木塑膠下腳料及回收料11,有效將聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之流動率提高,使聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體的混合物可以應用於後續之成型機中。此外,藉由添加適當比例的功能性助劑12,可以有效防止該混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,借此,能顯著提升仿木成品15的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品15。 Specifically, as shown in Figures 2-3, according to the adding mechanism 22 of the present invention, it is coupled to the crushing mechanism 21. The adding mechanism 22 adds a plurality of functional additives 12 to the imitation wood plastic feet that are in powder form after mixing. In the raw materials and recycled materials 11, the functional additives 12 include organic stabilizers, coupling agents, thermal stabilizers, gelling accelerators, foaming agents and light absorbers. It should be further explained that in some embodiments, the percentage of the organic stabilizer ranges from 0.1% to 10%, the percentage of the coupling agent ranges from 0.1% to 5%, and the percentage of the thermal stabilizer ranges from 0.1% to 10%. The content is between 0.1% and 3%, the gelling accelerator is between 0.1% and 10%, the foaming agent is between 0.1% and 3%, and the light absorbing agent is between 0.1% and 3%. Between 0.1%-3%. In this way, the functional additive 12 of the present invention, combined with the used imitation wood plastic scraps and recycled materials 11, can effectively improve the flow rate of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomers copolymerized with styrene and butadiene. , so that the mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomer copolymerized with styrene and butadiene can be used in subsequent molding machines. In addition, by adding an appropriate proportion of functional additive 12, the mixture can be effectively prevented from die expansion during subsequent injection molding or extrusion molding, and can reduce polystyrene, synthetic rubber, emulsified synthetic rubber and benzene. The interfacial tension between the ethylene and butadiene copolymer elastomers and the improved adhesion of the interface stabilize the mixture into a wood-like shape. This can significantly improve the tensile strength and bending resistance of the wood-like finished product 15 Mechanical properties such as number and impact strength, thereby producing low-cost and stable-quality imitation wood products15.

具體地,如圖2-3所示,根據本發明之混合機構23,其係耦接於添加機構22,混合機構23係用於將聚苯乙烯、合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑12攪拌後充分混合形成回收原料13。混合機構23可以是但不限於高速混合機、太陽式攪拌機、臥式攪拌機以及立式攪拌機其中之一。較佳地,混合機構23可以是採用高速混合機。更具體而言,混合底料的方式可以是一次將所有原料同時一起混合,也可以分階段進行混合,並沒有一定的限制。較佳地,在本發明一些實施例中,是先將有機安定劑、偶合劑、熱安定劑、膠化促進劑、光吸收劑以及仿木塑膠下腳料及回收料11一併混合後,經高速攪拌一預定時間,再投入發泡劑繼續攪拌混合,然而本發明不限於此。 Specifically, as shown in Figures 2-3, according to the mixing mechanism 23 of the present invention, it is coupled to the adding mechanism 22. The mixing mechanism 23 is used to mix polystyrene, synthetic rubber, the emulsified synthetic rubber and the styrene. The elastomer copolymerized with butadiene and the functional additives 12 are stirred and then thoroughly mixed to form the recycled raw material 13 . The mixing mechanism 23 may be, but is not limited to, one of a high-speed mixer, a solar mixer, a horizontal mixer, and a vertical mixer. Preferably, the mixing mechanism 23 may be a high-speed mixer. More specifically, the method of mixing the base material can be to mix all the raw materials together at one time, or to mix them in stages, and there is no certain limit. Preferably, in some embodiments of the present invention, the organic stabilizer, coupling agent, thermal stabilizer, gelling accelerator, light absorber, imitation wood plastic scraps and recycled materials 11 are mixed together at high speed. Stir for a predetermined time, and then add the foaming agent to continue stirring and mixing. However, the present invention is not limited to this.

具體地,根據本發明之造粒機構24,其係耦接於該混合機構23,造粒機構24係將添加該等功能性助劑12後之回收原料13製成呈顆粒狀的複數高分子原料14。在一些實施例中,不同的造粒機構24可以針對不同的回收原料13產生不同的高分子原料14,舉例而言,造粒機構24可以為水拉條造粒機或模頭切製粒機等,然而本發明並非僅限於此。 Specifically, according to the granulation mechanism 24 of the present invention, it is coupled to the mixing mechanism 23. The granulation mechanism 24 makes the recycled raw material 13 after adding the functional additives 12 into granular plural polymers. Raw materials 14. In some embodiments, different granulation mechanisms 24 can produce different polymer raw materials 14 for different recycled raw materials 13 . For example, the granulation mechanism 24 can be a water strand granulator or a die-cut granulator. etc., however, the present invention is not limited thereto.

具體地,如圖2-3所示,根據本發明之成型機構25,其係耦接於該造粒機構24,成型機構25直接透過熔化成流動狀後的該等高分子原料14製成回收再製的仿木成品15。在一些實施例中,成型機構25係可以根據使用者需求選擇不同的成型機構25,舉例而言,成型機構25可以為射出成型機及熱壓成型機其中之一,當使用射出成型機時可以實現較小且精細的仿木成品15,但由於高分子原料14本身之流動性的限制,使用射出成型的方式難以製成較大型的仿木成品15,此時可以使用熱壓成型機以製成較大型的仿木成品15,使用者可以視其需求選擇何種方式較為適切,本發明並非僅限於特定之成型機構25。Specifically, as shown in Figures 2-3, according to the molding mechanism 25 of the present invention, it is coupled to the granulation mechanism 24. The molding mechanism 25 directly melts the polymer raw materials 14 into a fluid state to produce recycled materials. Remade imitation wood finished products15. In some embodiments, the molding mechanism 25 can select different molding mechanisms 25 according to user needs. For example, the molding mechanism 25 can be one of an injection molding machine and a hot press molding machine. When an injection molding machine is used, it can be Achieve smaller and fine imitation wood finished products 15. However, due to the limitation of fluidity of the polymer raw material 14 itself, it is difficult to make larger imitation wood finished products 15 by injection molding. In this case, a hot press molding machine can be used. To form a larger imitation wood finished product 15, the user can choose which method is more appropriate according to their needs. The present invention is not limited to a specific molding mechanism 25.

為供進一步瞭解本發明構造特徵、運用技術手段及所預期達成之功效,茲將本發明實際執行過程加以敘述,相信當可由此而對本發明有更深入且具體瞭解,如下所述:In order to further understand the structural features, technical means and expected effects of the present invention, the actual implementation process of the present invention is described. I believe that this will provide a deeper and more specific understanding of the present invention, as follows:

請參閱圖3,並搭配圖1以及圖2所示,根據本發明之仿木的回收再製方法具體說明如下:首先執行粉碎步驟S1,粉碎機構21將仿木塑膠下腳料及回收料11予以粉體化,仿木塑膠下腳料及回收料11為聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體的混合物;接著執行添加步驟S2,添加機構22添加複數功能性助劑12至粉碎步驟S1後呈粉末狀之仿木塑膠下腳料及回收料11中,其中,該等功能性助劑12包含有機安定劑、偶合劑、熱安定劑、膠化促進劑、發泡劑以及光吸收劑;之後執行混合步驟S3,混合機構23將添加步驟S2後之該聚苯乙烯、該合成橡膠、該乳化合成橡膠和該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑12經攪拌後充分混合形成回收原料13;隨後執行造粒步驟S4,透過造粒機構24將充分混合功能性助劑12後之回收原料13產生顆粒狀的高分子原料14;最後執行成型步驟S5,透過成型機構25將熔化成流動狀後的高分子原料14製成回收再製的仿木成品15。Please refer to Figure 3, and as shown in Figures 1 and 2, the method for recycling imitation wood according to the present invention is described in detail as follows: First, the crushing step S1 is performed, and the crushing mechanism 21 powders the imitation wood plastic scraps and recycled materials 11. The imitation wood plastic scraps and recycled materials 11 are a mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and elastomer copolymerized with styrene and butadiene; then the adding step S2 is performed, and the adding mechanism 22 adds a plurality of functional additives 12. Into the powdery wood-like plastic scraps and recycled materials 11 after the crushing step S1, wherein the functional additives 12 include organic stabilizers, coupling agents, thermal stabilizers, gelling accelerators, foaming agents, and Light absorber; then the mixing step S3 is performed, and the mixing mechanism 23 will add the polystyrene, the synthetic rubber, the emulsified synthetic rubber and the styrene-butadiene copolymer elastomer and the functional auxiliaries after step S2. The agent 12 is stirred and fully mixed to form the recycled raw material 13; then the granulation step S4 is performed, and the recycled raw material 13 after the functional additive 12 is fully mixed through the granulating mechanism 24 to produce granular polymer raw material 14; finally, the molding step is performed S5, the polymer raw material 14 melted into a fluid state is made into a recycled imitation wood finished product 15 through the molding mechanism 25.

綜合上述,利用本實施例所提供之仿木的回收再製系統200,並搭配上述之仿木的回收再製方法,本發明可以將原本需要由專用的焚化爐焚化處理之仿木塑膠下腳料及回收料予以回收,並根據使用者需求製成特性不同之回收再製的仿木成品15,具備高度環保性及廣泛適用性等功效。Based on the above, by using the imitation wood recycling system 200 provided in this embodiment and combining it with the above-mentioned imitation wood recycling method, the present invention can incinerate imitation wood plastic scraps and recycled materials that originally need to be incinerated in a dedicated incinerator. They are recycled and made into recycled imitation wood products 15 with different characteristics according to user needs, which are highly environmentally friendly and widely applicable.

以下,參照圖式,說明本發明的仿木的回收再製方法的第一實施之實施形態,以使本發明所屬技術領域中具有通常知識者更清楚的理解可能的變化。以與上述相同的元件符號指示的元件實質上相同於上述參照圖2所敘述者。仿木的回收再製方法中相同的元件、特徵、和優點將不再贅述。Hereinafter, the first embodiment of the imitation wood recycling method of the present invention will be described with reference to the drawings, so that those with ordinary knowledge in the technical field to which the present invention belongs can more clearly understand the possible changes. Components designated by the same component numbers as above are substantially the same as those described above with reference to FIG. 2 . The same components, features, and advantages of the imitation wood recycling method will not be described again.

請參閱圖4,圖4為本發明第一實施例之成型機構的透視圖。如圖4所示,本發明第一實施例之成型機構25可以包含有:本體251以及模具252。具體地,本發明第一實施例之成型機構25可以使用急冷急熱的成型加工技術,以動態模溫控制應用在射出成型製程上,於充填前先將模具表面溫度加熱至玻璃轉換溫度(Tg),於保壓與冷卻階段冷卻模具252的溫度回到產品頂出溫度(Te),此技術控制模具252的表面溫度在頂出溫度與轉換溫度之間進行動態變化,得到最短升溫時間(Th)與最短冷 卻時間(Tc),達到充填前快速加熱與充填後快速降低至模具溫度目的。更具體而言,本實施例之成型機構25在溫度介於180°C〜260°C的條件下,以射出成型的方式成型出回收再製的仿木成品15。藉此,本發明成功應用快速動態模溫控制技術,並控制溫度介於較加飯為實現消除熔接痕、提升結合強度、消除殘餘應力、改善微結構的複寫性、改善浮纖表面光澤、改善成型表面品質及成型高亮面產品,縮短冷卻時間,達成產品品質及效益提升等技術功效,然而本發明不限於此。Please refer to FIG. 4 , which is a perspective view of the forming mechanism according to the first embodiment of the present invention. As shown in FIG. 4 , the molding mechanism 25 of the first embodiment of the present invention may include: a body 251 and a mold 252 . Specifically, the molding mechanism 25 of the first embodiment of the present invention can use rapid cooling and rapid heating molding processing technology to apply dynamic mold temperature control to the injection molding process. Before filling, the mold surface temperature is heated to the glass transition temperature (Tg ), during the pressure holding and cooling stages, the temperature of the cooling mold 252 returns to the product ejection temperature (Te). This technology controls the surface temperature of the mold 252 to dynamically change between the ejection temperature and the conversion temperature to obtain the shortest heating time (Th) and the minimum cooling time (Tc) to achieve the purpose of rapid heating before filling and rapid cooling to the mold temperature after filling. More specifically, the molding mechanism 25 of this embodiment molds the recycled imitation wood finished product 15 by injection molding at a temperature between 180°C and 260°C. Through this, the present invention successfully applies rapid dynamic mold temperature control technology and controls the temperature to be within a relatively high range to eliminate weld lines, enhance bonding strength, eliminate residual stress, improve the reproducibility of microstructure, improve the surface gloss of floating fibers, and improve The molding surface quality and molding high-gloss surface products can shorten the cooling time and achieve technical effects such as product quality and efficiency improvement. However, the invention is not limited to this.

可以理解的是,本發明所屬技術領域中具有通常知識者能夠基於上述示例再作出各種變化和調整,在此不再一一列舉。It can be understood that those with ordinary knowledge in the technical field to which the present invention belongs can make various changes and adjustments based on the above examples, and they are not listed here one by one.

藉此,本發明具有以下之實施功效及技術功效:Thus, the present invention has the following implementation effects and technical effects:

其一,本發明提供一種仿木的回收再製方法,其係應用於回收後的仿木塑膠下腳料及回收料,該回收再製方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。First, the present invention provides a method for recycling imitation wood, which is applied to recycled imitation wood plastic scraps and recycled materials. The recycling and reproducing method pulverizes the imitation wood plastic scraps and recycled materials, and adds plural Functional additives are added to the recycled raw materials in powder form to produce recycled imitation wood products. In this way, imitation wood plastic scraps and recycled materials can be effectively remade into various finished products according to user needs, greatly reducing the harm caused to the environment by burning waste, and at the same time recycling the waste.

其二,本發明提供一種仿木的回收再製系統,在使用特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。Secondly, the present invention provides an imitation wood recycling system. After using specific equipment to pulverize imitation wood plastic scraps and recycled materials, an appropriate proportion of functional additives is added to make polystyrene, synthetic rubber, and emulsified synthetic rubber. The flow rate of the elastomer copolymerized with styrene and butadiene is increased, so that it can be used in molding machines to re-make various finished products. At the same time, by adding appropriate proportions of functional additives, it can effectively prevent the above mixture from being used in subsequent injection molding or pressing. Expansion of the die occurs during molding, and can reduce the interfacial tension between polystyrene, synthetic rubber, emulsified synthetic rubber and elastomers copolymerized with styrene and butadiene, and improve the adhesion of the interface to stabilize the mixture. By forming into a wood-like form, the mechanical properties such as tensile strength, flexural modulus and impact strength of the wood-like finished product of the present invention can be significantly improved, thereby producing a low-cost and stable-quality wood-like finished product, and creating New economic value and benefits.

以上係藉由特定的具體實施例說明本發明之實施方式,所屬技術領域具有通常知識者可由本說明書所揭示之內容輕易地瞭解本發明之其他優點及功效。The above is a description of the implementation of the present invention through specific embodiments. Those with ordinary skill in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification.

綜上所述,本發明在同類產品中實有其極佳之進步實用性,同時遍查國內外關於此類結構之技術資料,文獻中亦未發現有相同的構造存在在先,是以,本發明實已具備發明專利要件,爰依法提出申請。To sum up, the present invention has excellent practicality among similar products. At the same time, after reviewing the technical information on this type of structure at home and abroad, no similar structure has been found to exist in the literature. Therefore, This invention actually meets the requirements for an invention patent, and you need to file an application in accordance with the law.

惟,以上所述僅為本發明之較佳實施例,並非用以限定本發明之範圍;凡其它未脫離本發明所揭示之精神下所完成之等效改變或修飾,均應包含在下述之專利範圍內。However, the above descriptions are only preferred embodiments of the present invention and are not intended to limit the scope of the present invention; all other equivalent changes or modifications made without departing from the spirit of the present invention shall be included in the following. within the scope of the patent.

11:仿木塑膠下腳料及回收料11: Imitation wood plastic scraps and recycled materials

12:功能性助劑12: Functional additives

13:回收原料13: Recycling raw materials

14:高分子原料14:Polymer raw materials

15:仿木成品15: Imitation wood finished products

200:仿木的回收再製系統200: Imitation wood recycling system

21:粉碎機構21: Crushing mechanism

22:添加機構22:Add institution

23:混合機構23:Hybrid Mechanism

24:造粒機構24: Granulation mechanism

25:成型機構25: Forming mechanism

251:本體251:Ontology

252:模具252:Mold

S1:粉碎步驟S1: crushing step

S2:添加步驟S2: Add steps

S3:混合步驟S3: Mixing step

S4:造粒步驟S4: Granulation step

S5:成型步驟S5: Forming steps

圖1為本發明之仿木的回收再製方法的方塊圖; 圖2為根據本發明之仿木的回收再製系統的示意圖; 圖3為說明實際執行根據本發明之仿木的回收再製方法的示意圖;以及 圖4為根據本發明第一實施例之成型機構的透視圖。 Figure 1 is a block diagram of the imitation wood recycling method of the present invention; Figure 2 is a schematic diagram of the imitation wood recycling system according to the present invention; Figure 3 is a schematic diagram illustrating the actual implementation of the imitation wood recycling method according to the present invention; and Figure 4 is a perspective view of the forming mechanism according to the first embodiment of the present invention.

S1:粉碎步驟 S1: crushing step

S2:添加步驟 S2: Add steps

S3:混合步驟 S3: Mixing step

S4:造粒步驟 S4: Granulation step

S5:成型步驟 S5: Forming step

Claims (10)

一種仿木的回收再製方法,其係應用於回收後的一仿木塑膠下腳料(scraps)及回收料,該仿木的回收再製方法包括:一粉碎步驟,其係將該仿木塑膠下腳料及回收料予以粉體化,該仿木塑膠下腳料及回收料係為一聚苯乙烯、一合成橡膠、一乳化合成橡膠以及一苯乙烯與丁二烯共聚之彈性體的混合物;一添加步驟,其係添加複數功能性助劑至該混合步驟後呈粉末狀之該仿木塑膠下腳料及回收料中,其中,該等功能性助劑包含一有機安定劑、一偶合劑、一熱安定劑、一膠化促進劑、一發泡劑以及一光吸收劑;一混合步驟,其係將添加步驟後之該聚苯乙烯、該合成橡膠及該乳化合成橡膠與該等功能性助劑經攪拌後充分混合形成一回收原料;一造粒步驟,其係將充分混合該等功能性助劑後之該回收原料輸入至一造粒機構中,以產生顆粒狀的複數高分子原料;以及一成型步驟,其係將該等高分子原料輸入至一成型機構中,該成型機構直接透過熔化成流動狀後的該等高分子原料製成一回收再製的仿木成品。 A method for recycling imitation wood, which is applied to recycled imitation wood plastic scraps and recycled materials. The method for recycling imitation wood includes: a crushing step, which is to crush the imitation wood plastic scraps and recycled materials. The recycled material is powdered. The imitation wood plastic scraps and recycled material are a mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and an elastomer copolymerized by styrene and butadiene; an adding step, in which A plurality of functional additives are added to the imitation wood plastic scraps and recycled materials that are in powder form after the mixing step. Among them, the functional additives include an organic stabilizer, a coupling agent, a thermal stabilizer, and a thermal stabilizer. A gelling accelerator, a foaming agent and a light absorber; a mixing step in which the polystyrene, the synthetic rubber and the emulsified synthetic rubber and the functional additives after the adding step are fully stirred. Mixing to form a recycled raw material; a granulation step, which is to input the recycled raw material after fully mixing the functional additives into a granulation mechanism to produce granular plurality of polymer raw materials; and a molding step, The method is to input the polymer raw materials into a molding mechanism, and the molding mechanism directly produces a recycled imitation wood finished product by melting the polymer raw materials into a fluid state. 如請求項1所述之仿木的回收再製方法,其中,該聚苯乙烯的重量百分比介於30%-85%,該合成橡膠的重量百分比介於5%-50%,該乳化合成橡膠的重量百分比介於3%-45%,該苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。 The method for recycling imitation wood as described in claim 1, wherein the weight percentage of the polystyrene is between 30% and 85%, the weight percentage of the synthetic rubber is between 5% and 50%, and the emulsified synthetic rubber is The weight percentage is between 3% and 45%, and the weight percentage of the styrene and butadiene copolymer elastomer is between 2% and 35%. 如請求項1所述之仿木的回收再製方法,其中,該有機安定劑的百分含量(Parts per hundred parts of resin,PHR)介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。 The method for recycling imitation wood as described in claim 1, wherein the percentage content of the organic stabilizer (Parts per hundred parts of resin, PHR) is between 0.1% and 10%, and the percentage content of the coupling agent is between 0.1% and 10%. At 0.1%-5%, the percentage content of the thermal stabilizer is between 0.1%-3%, the percentage content of the gelling accelerator is between 0.1%-10%, and the percentage content of the foaming agent is between 0.1%-3%, the percentage content of the light absorber is between 0.1%-3%. 如請求項1所述之仿木的回收再製方法,其中,有機安定劑係選自抗氧化劑以及光穩定劑其中之一。 The method for recycling imitation wood as described in claim 1, wherein the organic stabilizer is selected from the group consisting of antioxidants and light stabilizers. 如請求項1所述之仿木的回收再製方法,其中,該成型步驟在溫度介於150℃~260℃的條件下,以押出成型與射出成型的其中一種方式成型出該回收再製的仿木成品。 The method for recycling imitation wood as described in claim 1, wherein the molding step uses one of extrusion molding and injection molding to shape the recycled imitation wood at a temperature between 150°C and 260°C. Finished product. 一種仿木的回收再製系統,其係應用於回收後的一仿木塑膠下腳料及回收料,該仿木的回收再製系統包括:一粉碎機構,其係將該仿木塑膠下腳料及回收料予以粉體化,該仿木塑膠下腳料及回收料係為一聚苯乙烯、一合成橡膠、一乳化合成橡膠以及一苯乙烯與丁二烯共聚之彈性體的混合物;一添加機構,其係耦接於該粉碎機構,該添加機構添加複數功能性助劑至呈粉末狀之該仿木塑膠下腳料及回收料中,其中,該等功能性助劑包含一有機安定劑、一偶合劑、一熱安定劑、一膠化促進劑、一發泡劑以及一光吸收劑;一混合機構,其係耦接於該添加機構,該混合機構係用於將該聚苯乙烯、該合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑攪拌後充分混合形成一回收原料;一造粒機構,其係耦接於該混合機構,該造粒機構係將充分混合該等功能性助劑後之該回收原料製成呈顆粒狀的複數高分子原料;以及一成型機構,其係耦接於該造粒機構,該成型機構直接透過熔化成流動狀後的該等高分子原料製成一回收再製的仿木成品。 An imitation wood recycling system is used for recycling imitation wood plastic scraps and recycled materials. The imitation wood recycling system includes: a crushing mechanism that pulverizes the imitation wood plastic scraps and recycled materials. Integrated, the wood-like plastic scraps and recycled materials are a mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and an elastomer copolymerized by styrene and butadiene; an adding mechanism is coupled to The crushing mechanism and the adding mechanism add a plurality of functional additives to the powdered imitation wood plastic scraps and recycled materials, wherein the functional additives include an organic stabilizer, a coupling agent, and a thermal stabilizer. , a gelling accelerator, a foaming agent and a light absorber; a mixing mechanism coupled to the adding mechanism, the mixing mechanism is used to mix the polystyrene, the synthetic rubber, the emulsified synthetic rubber And the elastomer copolymerized with styrene and butadiene is stirred and fully mixed with the functional additives to form a recycled raw material; a granulating mechanism is coupled to the mixing mechanism, and the granulating mechanism is fully mixed The recycled raw materials after the functional additives are made into granular polymer raw materials; and a molding mechanism is coupled to the granulating mechanism, and the molding mechanism directly melts the polymer into a flowing state. A recycled imitation wood product is made from polymer raw materials. 如請求項6所述之回收再製系統,其中,該聚苯乙烯的重量百分比介於30%-85%,該合成橡膠的重量百分比介於5%-50%,該乳化合成橡膠的重量百分比介於3%-45%,該苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。 The recycling system as described in claim 6, wherein the weight percentage of the polystyrene is between 30% and 85%, the weight percentage of the synthetic rubber is between 5% and 50%, and the weight percentage of the emulsified synthetic rubber is between The weight percentage of the elastomer copolymerized with styrene and butadiene is between 2% and 35%. 如請求項6所述之回收再製系統,其中,該有機安定劑的百分含量介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。 The recycling system as described in claim 6, wherein the percentage content of the organic stabilizer is between 0.1% and 10%, the percentage content of the coupling agent is between 0.1% and 5%, and the percentage content of the thermal stabilizer is between 0.1% and 5%. The content of the gelling accelerator is between 0.1% and 3%, the gelling accelerator is between 0.1% and 10%, the foaming agent is between 0.1% and 3%, and the light absorbing agent is between 0.1% and 3%. The content is between 0.1%-3%. 如請求項6所述之回收再製系統,其中,該有機安定劑係選自抗氧化劑以及光穩定劑其中之一。 The recycling system as claimed in claim 6, wherein the organic stabilizer is selected from one of antioxidants and light stabilizers. 如請求項6所述之回收再製系統,其中,該成型機構在溫度介於150℃~260℃的條件下,以押出成型與射出成型的其中一種方式成型出該回收再製的仿木成品。The recycling system as described in claim 6, wherein the molding mechanism molds the recycled imitation wood finished product by one of extrusion molding and injection molding at a temperature between 150°C and 260°C.
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Publication number Priority date Publication date Assignee Title
CN105670076A (en) * 2016-01-26 2016-06-15 黄山华塑新材料科技有限公司 Wood-plastic material produced from discarded packages as well as production equipment and production method of wood plastic material
US20170320287A1 (en) * 2014-12-03 2017-11-09 Bernard Lootens A Composite Board Made from Recycled and Recyclable Materials
TWI656157B (en) * 2017-12-22 2019-04-11 遠東科技大學 Plastic wood substrate andmanufacturing method thereof
CN112976619A (en) * 2021-02-25 2021-06-18 云南峰海楹联文化有限公司 Method for manufacturing imitated wood couplet horizontal inscribed board by recycling waste plastics

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170320287A1 (en) * 2014-12-03 2017-11-09 Bernard Lootens A Composite Board Made from Recycled and Recyclable Materials
CN105670076A (en) * 2016-01-26 2016-06-15 黄山华塑新材料科技有限公司 Wood-plastic material produced from discarded packages as well as production equipment and production method of wood plastic material
TWI656157B (en) * 2017-12-22 2019-04-11 遠東科技大學 Plastic wood substrate andmanufacturing method thereof
CN112976619A (en) * 2021-02-25 2021-06-18 云南峰海楹联文化有限公司 Method for manufacturing imitated wood couplet horizontal inscribed board by recycling waste plastics

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