TW202421404A - Imitation wood texture forming method - Google Patents
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Abstract
Description
本發明係有關於一種仿木紋理的形成方法,特別是關於一種實現環保及回收再利用仿木塑膠下腳料(scraps)及回收料之仿木紋理的形成方法The present invention relates to a method for forming a wood-like texture, and more particularly to a method for forming a wood-like texture by recycling and reusing wood-like plastic scraps and recycled materials.
按,在眾多自然資源中,森林資源實乃地球資源中極為重要之一資產,森林資源除孕育了豐富多樣的動植物生態外,亦提供人類所需之各種資材,且與人類生活息息相關,因此,如何增進木材利用率、回收率及再利用率等,即成為世界各國亟欲突破之一重要議題,以期能減少天然資源的無謂浪費,並有效減少殘料處理時所需之人力與物力。Among many natural resources, forest resources are one of the most important assets on earth. In addition to nurturing a rich and diverse ecosystem of plants and animals, forest resources also provide a variety of materials needed by humans and are closely related to human life. Therefore, how to increase the utilization rate, recycling rate and reuse rate of wood has become an important issue that countries around the world are eager to break through, in order to reduce the unnecessary waste of natural resources and effectively reduce the manpower and material resources required for waste disposal.
有鑒於此,近年來,對於以木材殘削或碎片製備高分子塑膠生物複合材料(woodplastic composite, WPC)之研究,越來越受到世界各國重視,其原因係WPC除能有效利用木質纖維殘料製備複合材外,WPC較真實木材具備更良好的尺寸安定性及抵抗病蟲之能力,因此,無須特別維護,其使用年限即能高達25~30年之久。目前,WPC的應用範疇主要以交通運輸工具與非結構及半結構建築等用材為主。In view of this, in recent years, the research on the preparation of polymer plastic biocomposites (woodplastic composite, WPC) from wood residues or fragments has been increasingly valued by countries around the world. The reason is that WPC can not only effectively utilize wood fiber residues to prepare composite materials, but also has better dimensional stability and resistance to pests and diseases than real wood. Therefore, without special maintenance, its service life can be as long as 25 to 30 years. At present, the application scope of WPC is mainly in transportation vehicles and non-structural and semi-structural buildings.
一般而言,複合材料係利用兩種或兩種以上不同性質的原材料,以不同的加工法,結合在一起,以擷取各該原材料之特性與優點,發揮協同作用(synergistic effect),製成性能優異並能滿足需求的一種新材料。在眾多複合材料中,尤以纖維強化(fiber reinforced)之複合材料的性能較佳,應用也較廣。近年來,WPC在使用上已大量取代傳統的金屬、塑膠與實木材料,並常被應用至舖板、柵欄、外壁板、窗框及屋頂材料等製品上。然而,以利用兩種或兩種以上不同性質的原材料以不同的加工法結合在一起,仍存在許多問題,其中,最大的問題係在膠體之間常因表面極性的不同,阻礙二者間之化學鍵結。Generally speaking, composite materials are made by combining two or more raw materials of different properties with different processing methods to capture the characteristics and advantages of each raw material, exert synergistic effects, and produce a new material with excellent performance and can meet the needs. Among many composite materials, fiber reinforced composite materials have better performance and wider applications. In recent years, WPC has largely replaced traditional metal, plastic and solid wood materials in use, and is often used in products such as pavement, fences, exterior wall panels, window frames and roof materials. However, there are still many problems in combining two or more raw materials with different properties through different processing methods. Among them, the biggest problem is that the chemical bonding between the colloids is often hindered due to the different surface polarities.
此外,在環保意識日益高漲之氛圍下,前述WPC複合材或其它塑膠複合材仍因存在前述諸多結構性缺點及毒性問題,而始終無法被普及使用或應用至人們之日常生活需求中。又,WPC複合材或其它塑膠複合材難以具有如真實木材的紋理,始終無法符合對於美感有追求之消費者的需求。因此,如何提供一種有效處理WPC複合材的下腳料及回收料,並回收再製為各種用途的仿木成品,係為一研究人員待研究之重點項目。In addition, in an environment where environmental awareness is growing, the aforementioned WPC composites or other plastic composites still cannot be widely used or applied to people's daily life needs due to the aforementioned structural defects and toxicity problems. In addition, WPC composites or other plastic composites are difficult to have the texture of real wood, and they cannot meet the needs of consumers who pursue aesthetics. Therefore, how to provide an effective way to process the scraps and recycled materials of WPC composites and recycle them into imitation wood products for various purposes is a key project to be studied by researchers.
有鑑於上述缺點,發明人乃針對該等缺點研究改進之道,終於有本發明產生。In view of the above shortcomings, the inventor has studied ways to improve these shortcomings and finally came up with the present invention.
本發明的目的係提供一種仿木紋理的形成方法,其係應用於回收後的仿木塑膠下腳料及回收料,該形成方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。The purpose of the present invention is to provide a method for forming imitation wood textures, which is applied to recycled imitation wood plastic scraps and reclaimed materials. The method powderizes the imitation wood plastic scraps and reclaimed materials, and adds a plurality of functional additives to the recycled raw materials in powder form to produce recycled imitation wood finished products. In this way, imitation wood plastic scraps and reclaimed materials can be effectively remade into various finished products according to user needs, greatly reducing the harm to the environment caused by incineration of waste, and at the same time recycling the waste for reuse.
本發明另一目的在於提供一種仿木紋理的形成方法,在使用特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠與該乳化合成橡膠之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。Another object of the present invention is to provide a method for forming a wood-like texture. After using a specific device to powderize wood-like plastic scraps and recycled materials, a functional additive in an appropriate proportion is added to improve the fluidity of polystyrene, synthetic rubber, emulsified synthetic rubber, and styrene-butadiene copolymer elastomer, so that they can be used in a molding machine to re-make various finished products. At the same time, by adding a functional additive in an appropriate proportion, the above mixture is effectively prevented from The die head expands during subsequent injection molding or extrusion molding, and the interfacial tension between polystyrene, synthetic rubber and the emulsified synthetic rubber is reduced and the adhesion of the interface is improved to stabilize the mixture in the form of imitation wood. As a result, the mechanical properties such as tensile strength, flexural modulus and impact strength of the imitation wood product of the present invention can be significantly improved, thereby producing a low-cost and stable-quality imitation wood product and creating new economic value and benefits.
本發明又一目的在於提供一種仿木紋理的形成方法,由於其原料為仿木塑膠下腳料及回收料,因此製成的仿木成品係由具有不同玻璃轉換溫度的聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體組成。由於不同組合物之間具有不同的玻璃轉換溫度,因此透過放置步驟使得仿木塑膠下腳料及回收料與功能性助劑未完全混合,並於成型步驟在溫度介於150°C〜260°C的條件下,使得部分組合物處於完全融化但部分組合物處於未完全融化的狀態下,實現回收再製的仿木成品可以具有如真實木頭具有的天然紋理。Another object of the present invention is to provide a method for forming a wood-like texture. Since the raw materials are wood-like plastic scraps and recycled materials, the finished wood-like products are composed of polystyrene, synthetic rubber, emulsified synthetic rubber, and elastomers of styrene and butadiene copolymers with different glass transition temperatures. Since different compositions have different glass transition temperatures, the wood-like plastic scraps and recycled materials are not completely mixed with the functional additives through the placement step, and the temperature is between 150°C and 260°C in the molding step, so that part of the composition is completely melted but part of the composition is not completely melted, so that the recycled and remade wood-like finished products can have natural textures like real wood.
為達成上述目的及功效,本發明所提供之仿木紋理的形成方法,其係應用於回收後的一仿木塑膠下腳料及回收料,該仿木紋理的形成方法包括:一粉碎步驟,其係將該仿木塑膠下腳料及回收料予以粉體化;一添加步驟,其係添加複數功能性助劑至該粉碎步驟後呈粉末狀之該仿木塑膠下腳料及回收料中;一放置步驟,其係將添加步驟後之該仿木塑膠下腳料及回收料與該等功能性助劑放置一預設時間以混合形成一回收原料;一造粒步驟,其係將混合該等功能性助劑後之該回收原料輸入至一造粒機構中,以產生顆粒狀的複數高分子原料;以及一成型步驟,其係將該等高分子原料輸入至一成型機構中,該成型機構直接透過熔化成流動狀後的該等高分子原料製成一回收再製的仿木成品。In order to achieve the above-mentioned purpose and effect, the method for forming the imitation wood texture provided by the present invention is applied to recycled imitation wood plastic scraps and recycled materials. The method for forming the imitation wood texture comprises: a crushing step, which is to powderize the imitation wood plastic scraps and recycled materials; an adding step, which is to add a plurality of functional additives to the imitation wood plastic scraps and recycled materials in powder form after the crushing step; a placing step, which is to place the imitation wood plastic scraps and recycled materials after the adding step. The waste materials of wood plastic and recycled materials are placed for a preset time with the functional additives to mix and form a recycled raw material; a granulation step is to input the recycled raw material mixed with the functional additives into a granulation mechanism to produce a plurality of polymer raw materials in a granular form; and a molding step is to input the polymer raw materials into a molding mechanism, and the molding mechanism directly manufactures a recycled imitation wood product through the polymer raw materials melted into a flowing state.
較佳地,根據本發明之仿木紋理的形成方法,其中,該仿木塑膠下腳料及回收料係為一聚苯乙烯、一合成橡膠、一乳化合成橡膠以及一苯乙烯與丁二烯共聚之彈性體的混合物。Preferably, according to the method for forming the imitation wood texture of the present invention, the imitation wood plastic scraps and recycled materials are a mixture of polystyrene, a synthetic rubber, an emulsified synthetic rubber and an elastomer of styrene and butadiene copolymer.
較佳地,根據本發明之仿木紋理的形成方法,其中,該聚苯乙烯的重量百分比介於30%-85%,該合成橡膠的重量百分比介於5%-50%,該乳化合成橡膠的重量百分比介於3%-45%,該苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。Preferably, according to the method for forming the simulated wood texture of the present invention, the weight percentage of the polystyrene is between 30% and 85%, the weight percentage of the synthetic rubber is between 5% and 50%, the weight percentage of the emulsified synthetic rubber is between 3% and 45%, and the weight percentage of the elastomer of the copolymer of styrene and butadiene is between 2% and 35%.
較佳地,根據本發明之仿木紋理的形成方法,其中,該等功能性助劑包含一有機安定劑、一偶合劑、一熱安定劑、一膠化促進劑、一發泡劑以及一光吸收劑。Preferably, according to the method for forming the imitation wood texture of the present invention, the functional additives include an organic stabilizer, a coupling agent, a thermal stabilizer, a gelling accelerator, a foaming agent and a light absorber.
較佳地,根據本發明之仿木紋理的形成方法,其中,該有機安定劑的百分含量(Parts per hundred parts of resin, PHR)介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。Preferably, according to the method for forming the imitation wood texture of the present invention, the percentage of the organic stabilizer (Parts per hundred parts of resin, PHR) is between 0.1%-10%, the percentage of the coupling agent is between 0.1%-5%, the percentage of the thermal stabilizer is between 0.1%-3%, the percentage of the gelling accelerator is between 0.1%-10%, the percentage of the foaming agent is between 0.1%-3%, and the percentage of the light absorber is between 0.1%-3%.
較佳地,根據本發明之仿木紋理的形成方法,其中,有機安定劑係選自抗氧化劑以及光穩定劑其中之一。Preferably, according to the method for forming the simulated wood texture of the present invention, the organic stabilizer is selected from one of an antioxidant and a light stabilizer.
較佳地,根據本發明之仿木紋理的形成方法,其中,該等功能性助劑進一步包含一填充劑以及一色料,該填充劑係選自碳酸鈣以及滑石粉其中之一或其組合。Preferably, according to the method for forming the simulated wood texture of the present invention, the functional additives further include a filler and a colorant, and the filler is selected from one or a combination of calcium carbonate and talc.
較佳地,根據本發明之仿木紋理的形成方法,其中,該輕質碳酸鈣的百分含量介於3%-25%,該色料的百分含量介於0.01%-2.5%。Preferably, according to the method for forming the imitation wood texture of the present invention, the percentage of the light calcium carbonate is between 3% and 25%, and the percentage of the colorant is between 0.01% and 2.5%.
較佳地,根據本發明之仿木紋理的形成方法,其中,該成型步驟在溫度介於150°C〜260°C的條件下,以押出成型與射出成型的其中一種方式成型出該回收再製的仿木成品。Preferably, according to the method for forming the imitation wood texture of the present invention, the molding step is performed at a temperature between 150°C and 260°C to mold the recycled imitation wood product by one of extrusion molding and injection molding.
綜上,本發明所提供之仿木紋理的形成方法,其係應用於回收後的仿木塑膠下腳料及回收料,該紋理的形成方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。此外,本發明透過特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、該乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。In summary, the method for forming the imitation wood texture provided by the present invention is applied to recycled imitation wood plastic scraps and reclaimed materials. The method for forming the texture powderizes the imitation wood plastic scraps and reclaimed materials, and adds a plurality of functional additives to the recycled raw materials in powder form to produce recycled imitation wood finished products. In this way, the imitation wood plastic scraps and reclaimed materials can be effectively remade into various finished products according to user needs, greatly reducing the harm to the environment caused by the incineration of waste, and at the same time recycling the waste for reuse. In addition, the present invention uses a specific device to powderize the wood-like plastic scraps and recycled materials, and then adds a proper proportion of functional additives to improve the fluidity of polystyrene, synthetic rubber, emulsified synthetic rubber styrene and butadiene copolymer elastomers, so that they can be used in molding machines to re-make various finished products. At the same time, by adding a proper proportion of functional additives, the above mixture can be effectively prevented from bulging in the die head during subsequent injection molding or extrusion molding. The invention can prevent the swelling of the imitation wood and reduce the interfacial tension between polystyrene, synthetic rubber, the emulsified synthetic rubber and the elastomer of styrene and butadiene copolymer and improve the adhesion of the interface to stabilize the mixture to be molded into the imitation wood form. Thus, the mechanical properties such as tensile strength, flexural modulus and impact strength of the imitation wood product of the invention can be significantly improved, thereby producing a low-cost and stable-quality imitation wood product and creating new economic value and benefits.
爲使熟悉該項技藝人士瞭解本發明之目的、特徵及功效,茲藉由下述具體實施例,並配合所附之圖式,對本發明詳加說明如下。In order to enable persons familiar with the art to understand the purpose, features and effects of the present invention, the present invention is described in detail as follows through the following specific embodiments and in conjunction with the attached drawings.
現在將參照其中示出本發明概念的示例性實施例的附圖 在下文中更充分地闡述本發明概念。以下藉由參照附圖更詳細地闡述的示例性實施例,本發明概念的優點及特徵以及其達成方法將顯而易見。然而,應注意,本發明概念並非僅限於以下示例性實施例,而是可實施為各種形式。因此,提供示例性實施例僅是為了揭露本發明概念並使熟習此項技術者瞭解本發明概念的類別。在圖式中,本發明概念的示例性實施例並非僅限於本文所提供的特定實例且為清晰起見而進行放大。The inventive concept will now be more fully described below with reference to the accompanying drawings in which exemplary embodiments of the inventive concept are shown. Advantages and features of the inventive concept and methods of achieving the same will become apparent from the exemplary embodiments described in more detail below with reference to the accompanying drawings. However, it should be noted that the inventive concept is not limited to the following exemplary embodiments, but may be implemented in various forms. Therefore, the exemplary embodiments are provided only to disclose the inventive concept and to enable those skilled in the art to understand the categories of the inventive concept. In the drawings, the exemplary embodiments of the inventive concept are not limited to the specific examples provided herein and are enlarged for clarity.
本文所用術語僅用於闡述特定實施例,而並非旨在限制本發明。除非上下文中清楚地另外指明,否則本文所用的單數形式的用語「一」及「該」旨在亦包括複數形式。本文所用的用語「及/或」包括相關所列項其中一或多者的任意及所有組合。應理解,當稱元件「連接」或「耦合」至另一元件時,所述元件可直接連接或耦合至所述另一元件或可存在中間元件。The terms used herein are used only to describe specific embodiments and are not intended to limit the present invention. Unless the context clearly indicates otherwise, the singular forms of the terms "a", "an" and "the" used herein are intended to include the plural forms as well. The term "and/or" used herein includes any and all combinations of one or more of the relevant listed items. It should be understood that when an element is said to be "connected" or "coupled" to another element, the element may be directly connected or coupled to the other element or there may be intermediate elements.
相似地,應理解,當稱一個元件(例如層、區或基板)位於另一元件「上」時,所述元件可直接位於所述另一元件上,或可存在中間元件。相比之下,用語「直接」意指不存在中間元件。更應理解,當在本文中使用用語「包括」、「包含」時,是表明所陳述的特徵、整數、步驟、操作、元件、及/或組件的存在,但不排除一或多個其他特徵、整數、步驟、操作、元件、組件、及/或其群組的存在或添加。Similarly, it should be understood that when an element (such as a layer, region, or substrate) is said to be "on" another element, the element may be directly on the other element, or there may be intervening elements. In contrast, the term "directly" means that there are no intervening elements. It should be further understood that when the terms "include" and "comprising" are used herein, they indicate the presence of the stated features, integers, steps, operations, elements, and/or components, but do not exclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
此外,將藉由作為本發明概念的理想化示例性圖的剖視圖來闡述詳細說明中的示例性實施例。相應地,可根據製造技術及/或可容許的誤差來修改示例性圖的形狀。因此,本發明概念的示例性實施例並非僅限於示例性圖中所示出的特定形狀,而是可包括可根據製造製程而產生的其他形狀。圖式中所例示的區域具有一般特性,且用於說明元件的特定形狀。因此,此不應被視為僅限於本發明概念的範圍。Furthermore, exemplary embodiments in the detailed description will be illustrated by cross-sectional views that are idealized exemplary views of the inventive concept. Accordingly, the shapes of the exemplary views may be modified according to manufacturing techniques and/or tolerable errors. Therefore, exemplary embodiments of the inventive concept are not limited to the specific shapes shown in the exemplary views, but may include other shapes that may be produced according to the manufacturing process. The areas illustrated in the drawings are of general nature and are used to illustrate specific shapes of the elements. Therefore, this should not be considered as limiting the scope of the inventive concept.
亦應理解,儘管本文中可能使用用語「第一」、「第二」、「第三」等來闡述各種元件,然而該些元件不應受限於該些用語。該些用語僅用於區分各個元件。因此,某些實施例中的第一元件可在其他實施例中被稱為第二元件,而此並不背離本發明的教示內容。本文中所闡釋及說明的本發明概念的態樣的示例性實施例包括其互補對應物。本說明書通篇中,相同的參考編號或相同的指示物表示相同的元件。It should also be understood that although the terms "first", "second", "third", etc. may be used herein to describe various elements, these elements should not be limited to these terms. These terms are only used to distinguish between various elements. Therefore, the first element in some embodiments may be referred to as the second element in other embodiments without departing from the teachings of the present invention. The exemplary embodiments of the aspects of the inventive concept explained and illustrated herein include their complementary counterparts. Throughout this specification, the same reference numerals or the same indicators represent the same elements.
此外,本文中參照剖視圖及/或平面圖來闡述示例性實施例,其中所述剖視圖及/或平面圖是理想化示例性說明圖。因此,預期存在由例如製造技術及/或容差所造成的相對於圖示形狀的偏離。因此,示例性實施例不應被視作僅限於本文中所示區的形狀,而是欲包括由例如製造所導致的形狀偏差。因此,圖中所示的區為示意性的,且其形狀並非旨在說明裝置的區的實際形狀、亦並非旨在限制示例性實施例的範圍。Furthermore, exemplary embodiments are described herein with reference to cross-sectional views and/or plan views, wherein the cross-sectional views and/or plan views are idealized exemplary illustrations. Therefore, deviations from the illustrated shapes due to, for example, manufacturing techniques and/or tolerances are expected. Therefore, the exemplary embodiments should not be considered limited to the shapes of the regions shown herein, but are intended to include shape deviations due to, for example, manufacturing. Therefore, the regions shown in the figures are schematic, and their shapes are not intended to illustrate the actual shapes of the regions of the device, nor are they intended to limit the scope of the exemplary embodiments.
請參閱圖1-3所示,圖1為本發明之仿木紋理的形成方法的方塊圖;圖2為根據本發明之仿木紋理的形成系統的示意圖;圖3為說明實際執行根據本發明之仿木紋理的形成方法的示意圖。如圖1-3所示,本發明所提供之仿木紋理的形成方法,其係應用於回收後的仿木塑膠下腳料(scraps)及回收料11,該紋理的形成方法包括下列步驟:Please refer to Figures 1-3, Figure 1 is a block diagram of the method for forming the imitation wood texture of the present invention; Figure 2 is a schematic diagram of the system for forming the imitation wood texture according to the present invention; Figure 3 is a schematic diagram for illustrating the actual implementation of the method for forming the imitation wood texture according to the present invention. As shown in Figures 1-3, the method for forming the imitation wood texture provided by the present invention is applied to recycled imitation wood plastic scraps and
粉碎步驟S1,將仿木塑膠下腳料及回收料11予以粉體化,接著執行添加步驟S2。In the crushing step S1, the wood-like plastic scraps and the
添加步驟S2,添加複數功能性助劑12至粉碎步驟S1後呈粉末狀之仿木塑膠下腳料及回收料11中,接著執行放置步驟S3。In the adding step S2, a plurality of
放置步驟S3,將添加步驟S2後之木塑膠下腳料及回收料與該等功能性助劑12放置預設時間以混合形成回收原料13,接著執行造粒步驟S4。In a placing step S3, the waste wood plastic materials and recycled materials after adding the
造粒步驟S4,將混合功能性助劑12後之回收原料13輸入至造粒機構24(如圖2所示)中,以產生顆粒狀的複數高分子原料14,接著執行成型步驟S5。In the granulation step S4, the recycled
成型步驟S5,將高分子原料14輸入至成型機構25(如圖2所示)中,成型機構25直接透過熔化成流動狀後的高分子原料14製成回收再製的仿木成品15。In the forming step S5, the polymer
具體地,根據本發明之仿木塑膠下腳料及回收料11係為聚苯乙烯(Polystyrene)、合成橡膠(Styrene-Butadiene Rubber, SBR)、乳化合成橡膠(emulsion polymerized butadiene styrene rubber, ESBR)以及苯乙烯與丁二烯共聚之彈性體的混合物,然而本發明不限於此。Specifically, the wood-like plastic scraps and
具體地,根據本發明之功能性助劑12包含有機安定劑、偶合劑、熱安定劑、膠化促進劑、發泡劑以及光吸收劑,然而本發明不限於此。Specifically, the
更具體而言,根據本發明之有機安定劑可以用於防止回收原料13變質。在一些實施例中,有機安定劑可以為抗氧化劑(antioxidants),抗臭氧劑(antiozonants),光保護裝置(light-protection means),UV穩定劑(UV stabilisers),UV吸收劑(UV absorbers)或UV阻斷劑(UV blockers),潤滑劑(lubricants),脫模劑(mould-release agents),分離裝置(separating means),鏈延長添加劑(chain-lengthening additives),染色劑(colourants),標記裝置(marking means),有機顏料(organic pigments),IR吸收劑(IR absorbers),NIR吸收劑(NIR absorbers),感光變色劑(photochromic agents),脫模劑(mould-release agents),增亮劑(optical brighteners),聚四氟乙烯(polytetrafluoroethylene),無鹵素阻燃劑(halogen-free flame retardants),天然層矽酸鹽(natural layer silicates),合成層矽酸鹽(synthetic layer silicates)等。更具體而言,在一些實施例中,根據本發明之有機安定劑可以選自氧化穩定劑以及光穩定劑其中之一,其中,抗氧化劑可以為苯丙酸,3,5-雙(1,1-二甲基-乙基)-4-羥基-C7-C9支鏈烷基酯(Benzenepropanoic acid,3,5-bis(1,1-dimethyl-ethyl)-4-hydroxy-C7-C9 branched alkyl esters),光穩定劑可以為N-(1-乙醯基-2,2,6,6-四甲基-4-哌啶基)-2-十二基琥珀醯亞胺(N-(1-Acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecylsuccinimide),然而本發明不限於此。More specifically, the organic stabilizer according to the present invention can be used to prevent the recycled
更具體而言,根據本發明之偶合劑可以用於改善黏合劑組成物與封裝材料之間的黏附性及黏附可靠性。需要進一步說明的是,根據本發明之偶合劑主要功用在於當將聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物在高溫和/或高濕度條件下維持達長的時間段的情況下,可提高其黏附可靠性。在一些實施例中,偶合劑可以包括矽烷化合物,例如γ-縮水甘油氧基丙基三乙氧基矽 烷、γ-縮水甘油氧基丙基三甲氧基矽烷、γ-縮水甘油氧基丙基甲基二乙氧基矽烷、γ-縮水甘油氧基丙基三乙氧基矽烷、3-巰基丙基三甲氧基矽烷、乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、γ-甲基丙烯醯氧基丙基三甲氧基矽烷、γ-甲基丙烯醯氧基丙基三乙氧基矽烷、γ-氨基丙基三甲氧基矽烷、γ-氨基丙基三乙氧基矽烷、3-異氰酸丙基三乙氧基矽烷、γ-乙醯乙酸丙基三甲氧基矽烷、γ-乙醯乙酸丙基三乙氧基矽烷、β-氰基乙醯基三甲氧基矽烷、β-氰基乙醯基三乙氧基矽烷及乙醯氧基乙醯三甲氧基矽烷等,然而本發明不限於此。More specifically, the coupling agent according to the present invention can be used to improve the adhesion and adhesion reliability between the adhesive composition and the packaging material. It should be further explained that the main function of the coupling agent according to the present invention is to improve the adhesion reliability of the mixture of polystyrene, synthetic rubber, emulsified synthetic rubber and styrene-butadiene copolymer elastomer when it is maintained under high temperature and/or high humidity conditions for a long period of time. In some embodiments, the coupling agent may include a silane compound, such as γ-glycidyloxypropyltriethoxysilane. Silane, γ-glycidyloxypropyl trimethoxysilane, γ-glycidyloxypropyl methyldiethoxysilane, γ-glycidyloxypropyl triethoxysilane, 3-butylpropyl trimethoxysilane, vinyl trimethoxysilane, vinyl triethoxysilane, γ-methacryloxypropyl trimethoxysilane, γ-methacryloxypropyl triethoxysilane , γ-aminopropyltrimethoxysilane, γ-aminopropyltriethoxysilane, 3-isocyanatepropyltriethoxysilane, γ-acetylacetatepropyltrimethoxysilane, γ-acetylacetatepropyltriethoxysilane, β-cyanoacetyltrimethoxysilane, β-cyanoacetyltriethoxysilane and acetoxyacetyltrimethoxysilane, but the present invention is not limited thereto.
更具體而言,根據本發明之發泡劑主要係用於使得回收再製的仿木成品15可以具有與木材相類似的微泡組織結構。在一些實施例中,根據本發明之發泡劑可以採用偶氮甲醯胺、4,4'-氧代雙苯磺醯肼、對甲苯磺醯肼以及無機發泡劑(碳酸氫鈉)其中之一或其組合。較佳的是,發泡劑可選用粒徑為2μm至25μm的發泡劑,以避免加工成品發泡不均勻及避免提前發泡的情況,然而本發明不限於此。More specifically, the foaming agent according to the present invention is mainly used to make the recycled
更具體而言,在一些實施例中,膠化促進劑選自但不限於丙烯酸脂。光吸收劑可包含一種或多種成分係選自由苯丙三唑類(Benzotriazole)化合物、二苯甲酮類(Benzophenone)化合物、水楊酸類(Salicylate)化合物、氰基丙烯酸酯類(Cyanoacrylate)化合物、草醯二苯胺類(Oxanilide)化合物及受阻胺類光穩定劑(Hindered amine light stabilizer;HALS)所組成之群組,然而本發明不限於此。More specifically, in some embodiments, the gelling agent is selected from, but not limited to, acrylates. The light absorber may include one or more components selected from the group consisting of benzotriazole compounds, benzophenone compounds, salicylate compounds, cyanoacrylate compounds, oxanilide compounds, and hindered amine light stabilizers (HALS), but the present invention is not limited thereto.
藉此,根據本發明之仿木紋理的形成方法,其係透過添加步驟(S3)添加複數功能性助劑12至粉碎步驟S1後呈粉末狀之回收原料13中,使得聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物可以具備足夠的延展性,並透過造粒步驟(S4)將呈粉末狀之回收原料13製成顆粒狀的高分子原料14,最後透過成型步驟(S5)將高分子原料14製成回收再製的仿木成品15,達成大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。Thus, according to the method for forming the imitation wood texture of the present invention, a plurality of
請參閱圖2所示,本發明再以上述之仿木紋理的形成方法為基礎,進一步提供一種仿木紋理的形成系統200,其係應用於回收後的仿木塑膠下腳料及回收料11,回收再製系統200包括:粉碎機構21、添加機構22、放置機構23、造粒機構24以及成型機構25。Please refer to FIG. 2 . The present invention is based on the above-mentioned method for forming imitation wood texture and further provides a
具體地,如圖2-3所示,根據本發明之粉碎機構21,其係將該仿木塑膠下腳料及回收料11予以粉體化,以方便後續操作,該仿木塑膠下腳料及回收料11係為聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體的混合物。在一些實施例中,聚苯乙烯的重量百分比介於30%-85%,合成橡膠的重量百分比介於5%-50%,乳化合成橡膠的重量百分比介於3%-45%,苯乙烯與丁二烯共聚之彈性體的重量百分比介於2%-35%。然而本發明不限於此。需要進一步說明的是,由於本發明之仿木塑膠下腳料及回收料11中聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體所佔的比例不同,因此製成回收再製的仿木成品15時,仿木成品15在同橫斷面上會具有不均勻的花紋,達成宛如年輪般之紋理,實現接近真實木料的花紋之功效,同時仿木成品15的外表面也會產生不均勻的花紋,使得仿木成品15的外表面具有粗糙感而形成為仿木粗糙面,實現接近真實木料的花紋和粗糙面之功效,大幅增加本發明的適用性。Specifically, as shown in FIG. 2-3, according to the
值得一提的是,由於仿木塑膠下腳料及回收料11呈不規則狀,例如:塊狀或片狀等,使用者將難以對仿木塑膠下腳料及回收料11進行各種操作,從而透過粉碎機構21可以有效將仿木塑膠下腳料及回收料11予以粉體化,大幅提升根據本發明之仿木紋理的形成系統200的效率,然而本發明不限於此。It is worth mentioning that since the imitation wood plastic scraps and
具體地,如圖2-3所示,根據本發明之添加機構22,其係耦接於粉碎機構21,添加機構22添加複數功能性助劑12至混合後呈粉末狀之該仿木塑膠下腳料及回收料11中,其中,該等功能性助劑12包含有機安定劑、偶合劑、熱安定劑、膠化促進劑、發泡劑以及光吸收劑。需要進一步說明的是,在一些實施例中,該有機安定劑的百分含量介於0.1%-10%,該偶合劑的百分含量介於0.1%-5%,該熱安定劑的百分含量介於0.1%-3%,該膠化促進劑的百分含量介於0.1%-10%,該發泡劑的百分含量介於0.1%-3%,該光吸收劑的百分含量介於0.1%-3%。藉此,本發明之功能性助劑12配合所用的仿木塑膠下腳料及回收料11,有效將聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之流動率提高,使聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體的混合物可以應用於後續之成型機中。此外,藉由添加適當比例的功能性助劑12,可以有效防止該混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠與該乳化合成橡膠之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,借此,能顯著提升仿木成品15的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品15。Specifically, as shown in FIG. 2-3 , the adding
值得一提的是,在一些實施例中,該等功能性助劑12可以進一步包含有填充劑以及色料,該填充劑的百分含量介於3%-25%,該色料的百分含量介於0.01%-2.5%。更具體而言,填充劑可以是選自碳酸鈣以及滑石粉其中之一或其組合,然而本發明不限於此。藉此,透過填充劑能夠讓仿木成品15具有與真實木材相仿的耐衝擊性。並且,透過色料能夠讓仿木成品15的外表面產生與真實木材相仿的色彩。It is worth mentioning that in some embodiments, the
具體地,如圖2-3所示,根據本發明之放置機構23,其係耦接於添加機構22,放置機構23係用於將聚苯乙烯、合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體與該等功能性助劑12放置一預測時間以混合形成回收原料13。更具體而言,在一些實施例中,預設時間可是1小時、6小時、12小時或24小時等,以透過聚苯乙烯、合成橡膠、該乳化合成橡膠以及該苯乙烯與丁二烯共聚之彈性體的流動使得上述組合物相互混合,由於上述組合物僅透過放置的方式混合,而非透過其他物理方式(例如:攪拌)進行混合,因此本發明產生之仿木成品在未完全混合的狀態下,可以具有如真實木頭具有的天然紋理,然而本發明不限於此。Specifically, as shown in FIG. 2-3 , the
具體地,根據本發明之造粒機構24,其係耦接於該放置機構23,造粒機構24係將添加該等功能性助劑12後之回收原料13製成呈顆粒狀的複數高分子原料14。在一些實施例中,不同的造粒機構24可以針對不同的回收原料13產生不同的高分子原料14,舉例而言,造粒機構24可以為水拉條造粒機或模頭切製粒機等,然而本發明並非僅限於此。Specifically, the
具體地,如圖2-3所示,根據本發明之成型機構25,其係耦接於該造粒機構24,成型機構25直接透過熔化成流動狀後的該等高分子原料14製成回收再製的仿木成品15。在一些實施例中,成型機構25係可以根據使用者需求選擇不同的成型機構25,舉例而言,成型機構25可以為射出成型機及熱壓成型機其中之一,當使用射出成型機時可以實現較小且精細的仿木成品15,但由於高分子原料14本身之流動性的限制,使用射出成型的方式難以製成較大型的仿木成品15,此時可以使用熱壓成型機以製成較大型的仿木成品15,使用者可以視其需求選擇何種方式較為適切,本發明並非僅限於特定之成型機構25。Specifically, as shown in FIG. 2-3 , the
為供進一步瞭解本發明構造特徵、運用技術手段及所預期達成之功效,茲將本發明實際執行過程加以敘述,相信當可由此而對本發明有更深入且具體瞭解,如下所述:In order to further understand the structural features, applied technical means and expected effects of the present invention, the actual implementation process of the present invention is described. It is believed that this will provide a deeper and more specific understanding of the present invention, as described below:
請參閱圖3,並搭配圖1以及圖2所示,根據本發明之仿木紋理的形成方法具體說明如下:首先執行粉碎步驟S1,粉碎機構21將仿木塑膠下腳料及回收料11予以粉體化;接著執行添加步驟S2,添加機構22添加複數功能性助劑12至粉碎步驟S1後呈粉末狀之仿木塑膠下腳料及回收料11中;之後執行放置步驟S3,放置機構23將添加步驟S2後之該聚苯乙烯、該合成橡膠、該乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體與該等功能性助劑12放置預設時間以混合形成回收原料13;隨後執行造粒步驟S4,透過造粒機構24將混合功能性助劑12後之回收原料13產生顆粒狀的高分子原料14;最後執行成型步驟S5,透過成型機構25將熔化成流動狀後的高分子原料14製成回收再製的仿木成品15。Please refer to FIG. 3, and in conjunction with FIG. 1 and FIG. 2, the method for forming the imitation wood texture according to the present invention is specifically described as follows: first, a crushing step S1 is performed, and the crushing
綜合上述,利用本實施例所提供之仿木紋理的形成系統200,並搭配上述之仿木紋理的形成方法,本發明可以將原本需要由專用的焚化爐焚化處理之仿木塑膠下腳料及回收料予以回收,並根據使用者需求製成特性不同之回收再製的仿木成品15,具備高度環保性及廣泛適用性等功效。In summary, by utilizing the imitation wood
以下,參照圖式,說明本發明的仿木紋理的形成方法的第一實施之實施形態,以使本發明所屬技術領域中具有通常知識者更清楚的理解可能的變化。以與上述相同的元件符號指示的元件實質上相同於上述參照圖圖2所敘述者。仿木紋理的形成方法中相同的元件、特徵、和優點將不再贅述。Hereinafter, with reference to the drawings, the first embodiment of the method for forming the imitation wood texture of the present invention is described, so that those skilled in the art can more clearly understand the possible variations. The elements indicated by the same element symbols as above are substantially the same as those described in the above reference figure 2. The same elements, features, and advantages in the method for forming the imitation wood texture will not be described again.
請參閱圖4,圖4為本發明第一實施例之成型機構的透視圖。如圖4所示,本發明第一實施例之成型機構25可以包含有:本體251以及模具252。具體地,本發明第一實施例之成型機構25可以使用急冷急熱的成型加工技術,以動態模溫控制應用在射出成型製程上,於充填前先將模具表面溫度加熱至玻璃轉換溫度(Tg),於保壓與冷卻階段冷卻模具252的溫度回到產品頂出溫度(Te),此技術控制模具252的表面溫度在頂出溫度與轉換溫度之間進行動態變化,得到最短升溫時間(Th)與最短冷 卻時間(Tc),達到充填前快速加熱與充填後快速降低至模具溫度目的。更具體而言,本實施例之成型機構25在溫度介於180°C〜260°C的條件下,以射出成型的方式成型出回收再製的仿木成品15。藉此,本發明成功應用快速動態模溫控制技術,並控制溫度介於較加飯為實現消除熔接痕、提升結合強度、消除殘餘應力、改善微結構的複寫性、改善浮纖表面光澤、改善成型表面品質及成型高亮面產品,縮短冷卻時間,達成產品品質及效益提升等技術功效,然而本發明不限於此。Please refer to FIG4, which is a perspective view of the molding mechanism of the first embodiment of the present invention. As shown in FIG4, the
可以理解的是,本發明所屬技術領域中具有通常知識者能夠基於上述示例再作出各種變化和調整,在此不再一一列舉。It is understandable that a person having ordinary knowledge in the technical field to which the present invention belongs can make various changes and adjustments based on the above examples, which will not be listed one by one here.
藉此,本發明具有以下之實施功效及技術功效:Thus, the present invention has the following practical effects and technical effects:
其一,本發明提供一種仿木紋理的形成方法,其係應用於回收後的仿木塑膠下腳料及回收料,該紋理的形成方法將該仿木塑膠下腳料及回收料予以粉體化,並添加複數功能性助劑至呈粉末狀之該回收原料中,以製成回收再製的仿木成品。如此一來,有效根據使用者需求將仿木塑膠下腳料及回收料重新製成各種成品,大幅減少因焚燒廢棄物對環境所造成的危害,同時將廢棄物回收再利用。First, the present invention provides a method for forming a wood-like texture, which is applied to recycled wood-like plastic scraps and reclaimed materials. The texture forming method powderizes the wood-like plastic scraps and reclaimed materials, and adds a plurality of functional additives to the recycled raw materials in powder form to produce recycled wood-like finished products. In this way, the wood-like plastic scraps and reclaimed materials can be effectively remade into various finished products according to user needs, greatly reducing the harm to the environment caused by incineration of waste, and at the same time recycling the waste for reuse.
其二,本發明提供一種仿木紋理的形成方法,在使用特定設備粉體化仿木塑膠下腳料及回收料後,添加適當比例的功能性助劑,使得聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之流動率提高,以應用於成型機中重新製成各種成品,同時藉由添加適當比例的功能性助劑,有效防止上述混合物在後續射出成型或壓出成型時發生模頭膨脹的情形,並能降低聚苯乙烯、合成橡膠、乳化合成橡膠和苯乙烯與丁二烯共聚之彈性體之間的界面張力及提升介面的粘著性以安定該混合物成型為仿木的形態,藉此,能顯著提升本發明之仿木成品的抗張強度、抗折模數及衝擊強度等機械性質,進而制出低成本且品質穩定的仿木成品,並創造新的經濟價值與利益。Secondly, the present invention provides a method for forming a wood-like texture. After using a specific device to powderize wood-like plastic scraps and recycled materials, a functional additive in an appropriate proportion is added to improve the fluidity of polystyrene, synthetic rubber, emulsified synthetic rubber and styrene-butadiene copolymer elastomer, so that they can be used in a molding machine to re-make various finished products. At the same time, by adding a functional additive in an appropriate proportion, the above mixture can be effectively prevented from being molded or pressed in the subsequent injection molding. The invention can reduce the expansion of the die head during molding, reduce the interfacial tension between polystyrene, synthetic rubber, emulsified synthetic rubber and styrene-butadiene copolymer elastomer, and enhance the adhesion of the interface to stabilize the mixture when molded into a wood-like shape. Thus, the mechanical properties such as tensile strength, flexural modulus and impact strength of the wood-like finished product of the invention can be significantly improved, thereby producing a low-cost and high-quality wood-like finished product and creating new economic value and benefits.
其三,本發明提供一種仿木紋理的形成方法,於其原料為仿木塑膠下腳料及回收料,因此製成的仿木成品係由具有不同玻璃轉換溫度的聚苯乙烯、合成橡膠、乳化合成橡膠以及苯乙烯與丁二烯共聚之彈性體組成。由於不同組合物之間具有不同的玻璃轉換溫度,因此透過放置步驟使得仿木塑膠下腳料及回收料與功能性助劑未完全混合,並於成型步驟在溫度介於150°C〜260°C的條件下,使得部分組合物處於完全融化但部分組合物處於未完全融化的狀態下,實現回收再製的仿木成品可以具有如真實木頭具有的天然紋理,同時仿木成品15的外表面也會產生不均勻的花紋,使得仿木成品15的外表面具有粗糙感而形成為仿木粗糙面,實現接近真實木料的花紋和粗糙面之功效,大幅增加本發明的適用性。Thirdly, the present invention provides a method for forming a wood-like texture, wherein the raw materials are wood-like plastic scraps and recycled materials, and the finished wood-like product is composed of polystyrene with different glass transition temperatures, synthetic rubber, emulsified synthetic rubber, and an elastomer of styrene and butadiene copolymer. Since different compositions have different glass transition temperatures, the imitation wood plastic scraps and recycled materials are not completely mixed with the functional additives through the placement step, and in the molding step, under the condition of a temperature between 150°C and 260°C, part of the composition is completely melted but part of the composition is not completely melted, so that the recycled imitation wood product can have a natural texture like real wood. At the same time, the outer surface of the
以上係藉由特定的具體實施例說明本發明之實施方式,所屬技術領域具有通常知識者可由本說明書所揭示之內容輕易地瞭解本發明之其他優點及功效。The above is an explanation of the implementation of the present invention by means of specific embodiments. A person having ordinary knowledge in the relevant technical field can easily understand other advantages and effects of the present invention from the contents disclosed in this specification.
綜上所述,本發明在同類產品中實有其極佳之進步實用性,同時遍查國內外關於此類結構之技術資料,文獻中亦未發現有相同的構造存在在先,是以,本發明實已具備發明專利要件,爰依法提出申請。In summary, the present invention is extremely advanced and practical in the same category of products. At the same time, after searching the technical data on this type of structure at home and abroad, no similar structure has been found in the literature. Therefore, the present invention has the patent requirements and is filed in accordance with the law.
惟,以上所述僅為本發明之較佳實施例,並非用以限定本發明之範圍;凡其它未脫離本發明所揭示之精神下所完成之等效改變或修飾,均應包含在下述之專利範圍內。However, the above description is only a preferred embodiment of the present invention and is not intended to limit the scope of the present invention; any other equivalent changes or modifications that do not deviate from the spirit disclosed by the present invention should be included in the following patent scope.
11:仿木塑膠下腳料及回收料 12:功能性助劑 13:回收原料 14:高分子原料 15:仿木成品 200:仿木紋理的形成系統 21:粉碎機構 22:添加機構 23:放置機構 24:造粒機構 25:成型機構 251:本體 252:模具 S1:粉碎步驟 S2:添加步驟 S3:放置步驟 S4:造粒步驟 S5:成型步驟 11: Wood-like plastic scraps and recycled materials 12: Functional additives 13: Recycled raw materials 14: Polymer raw materials 15: Wood-like finished products 200: Wood-like texture formation system 21: Crushing mechanism 22: Adding mechanism 23: Placing mechanism 24: Granulating mechanism 25: Molding mechanism 251: Main body 252: Mold S1: Crushing step S2: Adding step S3: Placing step S4: Granulating step S5: Molding step
圖1為本發明之仿木紋理的形成方法的方塊圖; 圖2為根據本發明之仿木紋理的形成系統的示意圖; 圖3為說明實際執行根據本發明之仿木紋理的形成方法的示意圖;以及 圖4為根據本發明第一實施例之成型機構的透視圖。 FIG1 is a block diagram of the method for forming the imitation wood texture of the present invention; FIG2 is a schematic diagram of the system for forming the imitation wood texture according to the present invention; FIG3 is a schematic diagram for explaining the actual implementation of the method for forming the imitation wood texture according to the present invention; and FIG4 is a perspective view of the molding mechanism according to the first embodiment of the present invention.
S1:粉碎步驟 S1: Crushing step
S2:添加步驟 S2: Add steps
S3:放置步驟 S3: Placement step
S4:造粒步驟 S4: Granulation step
S5:成型步驟 S5: Molding step
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