TWI814110B - Heater Coating Agent for False Twisting Machine - Google Patents
Heater Coating Agent for False Twisting Machine Download PDFInfo
- Publication number
- TWI814110B TWI814110B TW110138532A TW110138532A TWI814110B TW I814110 B TWI814110 B TW I814110B TW 110138532 A TW110138532 A TW 110138532A TW 110138532 A TW110138532 A TW 110138532A TW I814110 B TWI814110 B TW I814110B
- Authority
- TW
- Taiwan
- Prior art keywords
- heater
- coating agent
- false
- false twisting
- fatty acid
- Prior art date
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 69
- -1 fatty acid ester Chemical class 0.000 claims abstract description 62
- 238000012545 processing Methods 0.000 claims abstract description 36
- 239000002480 mineral oil Substances 0.000 claims abstract description 33
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 32
- 239000000194 fatty acid Substances 0.000 claims abstract description 32
- 229930195729 fatty acid Natural products 0.000 claims abstract description 32
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 150000002222 fluorine compounds Chemical class 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 abstract description 26
- 229920002994 synthetic fiber Polymers 0.000 abstract description 26
- 238000000926 separation method Methods 0.000 abstract description 4
- 229920001296 polysiloxane Polymers 0.000 description 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 5
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 210000002268 wool Anatomy 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- BTGGRPUPMPLZNT-PGEUSFDPSA-N 2,2-bis[[(z)-octadec-9-enoyl]oxymethyl]butyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC BTGGRPUPMPLZNT-PGEUSFDPSA-N 0.000 description 2
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 description 2
- NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- QTIMEBJTEBWHOB-PMDAXIHYSA-N [3-[(z)-octadec-9-enoyl]oxy-2,2-bis[[(z)-octadec-9-enoyl]oxymethyl]propyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COC(=O)CCCCCCC\C=C/CCCCCCCC)(COC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC QTIMEBJTEBWHOB-PMDAXIHYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- GHKVUVOPHDYRJC-UHFFFAOYSA-N didodecyl hexanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCC GHKVUVOPHDYRJC-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- MOJYYOPFOKMPCJ-UHFFFAOYSA-L dipotassium;6-methylheptyl phosphate Chemical compound [K+].[K+].CC(C)CCCCCOP([O-])([O-])=O MOJYYOPFOKMPCJ-UHFFFAOYSA-L 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- SRBSSROHORQGBO-UHFFFAOYSA-N 11-methyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C SRBSSROHORQGBO-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- UMXHKSZXFNVTQV-UHFFFAOYSA-N 1h-imidazole;phosphane Chemical compound P.C1=CNC=N1 UMXHKSZXFNVTQV-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- GSAHAZJWNMHSNI-UHFFFAOYSA-N 2,2-bis(dodecanoyloxymethyl)butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC GSAHAZJWNMHSNI-UHFFFAOYSA-N 0.000 description 1
- FMNZBNCPTJEVDS-KVVVOXFISA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;(z)-octadec-9-enoic acid Chemical class CCC(CO)(CO)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O FMNZBNCPTJEVDS-KVVVOXFISA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- LGIKGVKQJCNPAI-UHFFFAOYSA-N 6-decanoyloxyhexyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCCCCOC(=O)CCCCCCCCC LGIKGVKQJCNPAI-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- UGHVFDVVZRNMHY-NXVVXOECSA-N Oleyl laurate Chemical compound CCCCCCCCCCCC(=O)OCCCCCCCC\C=C/CCCCCCCC UGHVFDVVZRNMHY-NXVVXOECSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229940067597 azelate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
- AXRSHKZFNKUGQB-UHFFFAOYSA-N octyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC)OC1=CC=CC=C1 AXRSHKZFNKUGQB-UHFFFAOYSA-N 0.000 description 1
- IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- AIMUHNZKNFEZSN-UHFFFAOYSA-M sodium;decane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCS([O-])(=O)=O AIMUHNZKNFEZSN-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
- D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
- D02G1/0266—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting false-twisting machines
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Abstract
本發明之課題在於提供一種假撚加工機用加熱器塗布劑，其可抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離。作為解決手段，本發明提供一種假撚加工機用加熱器塗布劑，其特徵在於含有選自脂肪酸酯(A)及礦物油(B)中之至少一種。An object of the present invention is to provide a heater coating agent for a false twist processing machine, which can inhibit the separation of synthetic fiber filament yarn from the heater in the false twist processing machine. As a solution, the present invention provides a heater coating agent for a false twisting machine, which is characterized by containing at least one selected from the group consisting of fatty acid ester (A) and mineral oil (B).
Description
本發明係關於一種假撚加工機用加熱器塗布劑，其係為了抑制紗於假撚加工機中自加熱器脫離而塗布於加熱器。The present invention relates to a heater coating agent for a false twisting machine, which is applied to a heater in order to prevent a yarn from being detached from the heater in a false twisting machine.
近年來，服裝之多樣化、時尚化之趨勢日益發展，其中，對於具有適度之伸縮性及蓬鬆度，因良好之質感而舒適且貼合身體之運動用服裝或女性用貼身內衣服裝等功能性衣物之需求越來越高。於該功能性衣物之製造中，假撚加工紗是不可缺少的。 一般而言，假撚加工紗(Draw Textured Yarn；以下，有時會被稱為DTY)係藉由以下方式而獲得：賦予合成纖維用處理劑而生產出作為半延伸絲紗(Partially Oriented Yarn；以下，有時會被稱為POY)之合成纖維長絲紗線後，利用假撚裝置之加熱裝置(加熱器)對合成纖維長絲紗線進行加熱，同時，一面對長絲紗線進行加撚一面進行延伸。關於對半延伸絲紗(POY)賦予之合成纖維用處理劑，尤其對乳化劑或抗靜電劑等進行研究，從而完成抑制加熱器污垢、細毛紗斷裂、靜電產生之設計(例如專利文獻1、2等)。 然而，即便是被賦予了此種合成纖維用處理劑之半延伸絲紗(POY)，亦存在以下等問題：合成纖維長絲紗線自加熱裝置(加熱器)脫離或錯位，發生細毛紗斷裂，此外，由於加熱不足及導眼之錯位而導致其無法進行充分之加撚或延伸。 先前技術文獻 專利文獻 In recent years, the trend of clothing diversification and fashion has been increasingly developed. Among them, functional clothing such as sportswear or women's underwear that have moderate stretchability and fluffiness, are comfortable and fit the body due to good texture, etc. The demand for clothing is getting higher and higher. In the manufacture of this functional clothing, false twist processed yarn is indispensable. Generally speaking, false-twisted yarn (Draw Textured Yarn; hereafter, sometimes referred to as DTY) is obtained by adding a treatment agent for synthetic fibers to produce a semi-extended yarn (Partially Oriented Yarn); Hereinafter, after the synthetic fiber filament yarn is sometimes called POY), the synthetic fiber filament yarn is heated using the heating device (heater) of the false twisting device, and at the same time, the filament yarn is Twist one side to extend. Regarding synthetic fiber treatment agents provided to semi-extended yarn (POY), especially emulsifiers and antistatic agents, research has been conducted to complete designs that suppress heater fouling, breakage of fine wool yarns, and generation of static electricity (for example, Patent Document 1, 2 etc.). However, even semi-extended yarn (POY) provided with such a synthetic fiber treatment agent has the following problems: the synthetic fiber filament yarn is separated from the heating device (heater) or misaligned, and the fine yarn breaks. , In addition, due to insufficient heating and misalignment of the guide eyes, it cannot be fully twisted or stretched. Prior art documents Patent documents
專利文獻1：日本專利特開2005-042208號公報 專利文獻2：日本專利特開平11-315480號公報 Patent Document 1: Japanese Patent Application Publication No. 2005-042208 Patent Document 2: Japanese Patent Application Laid-Open No. 11-315480
[發明所欲解決之問題][Problem to be solved by the invention]
本發明之課題在於提供一種假撚加工機用加熱器塗布劑，其可抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離。 [解決問題之技術手段] An object of the present invention is to provide a heater coating agent for a false twist processing machine, which can inhibit the separation of synthetic fiber filament yarn from the heater in the false twist processing machine. [Technical means to solve problems]
本發明人為了解決上述問題而反覆進行了銳意研究，結果發現，藉由在假撚加工機之加熱器部分塗布特定之成分，可抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離，從而解決了上述問題。The inventors of the present invention have repeatedly conducted intensive research in order to solve the above problems. As a result, they have found that by coating the heater part of the false twisting machine with a specific component, the synthetic fiber filament yarn can be inhibited from self-heating in the false twisting machine. disengage, thereby solving the above problem.
本發明具體而言以下述事項為主旨。 1.一種假撚加工機用加熱器塗布劑，其特徵在於：含有選自脂肪酸酯(A)及礦物油(B)中之至少一種。 2.如1.所記載之假撚加工機用加熱器塗布劑，其相對於上述假撚加工機用加熱器塗布劑之總質量，含有至少50質量%以上之選自上述脂肪酸酯(A)及上述礦物油(B)中之至少一種。 3.如1.或2.所記載之假撚加工機用加熱器塗布劑，其含有質量平均分子量為300～1000之脂肪酸酯(a1)作為上述脂肪酸酯(A)。 4.如1.或2.所記載之假撚加工機用加熱器塗布劑，其含有60～600雷氏秒之礦物油(b1)作為上述礦物油(B)。 5.如1.或2.所記載之假撚加工機用加熱器塗布劑，其含有質量平均分子量為300～1000之脂肪酸酯(a1)作為上述脂肪酸酯(A)，且含有60～600雷氏秒之礦物油(b1)作為上述礦物油(B)。 6.如1.至5.中任一項所記載之假撚加工機用加熱器塗布劑，其進而含有界面活性劑(C)。 7.一種假撚加工紗之製造方法，其特徵在於：將如1.至6.中任一項所記載之假撚加工機用加熱器塗布劑塗布於假撚加工機之加熱器。 8.如7.所記載之假撚加工紗之製造方法，其中上述加熱器為接觸型加熱器。 [發明之效果] Specifically, the present invention is based on the following matters. 1. A heater coating agent for a false twisting machine, characterized in that it contains at least one selected from the group consisting of fatty acid ester (A) and mineral oil (B). 2. The heater coating agent for a false twisting machine as described in 1., which contains at least 50% by mass or more of the fatty acid ester (A) selected from the group consisting of the above-mentioned heater coating agent for a false twisting machine. ) and at least one of the above mineral oils (B). 3. The heater coating agent for a false twisting machine according to 1. or 2., which contains a fatty acid ester (a1) with a mass average molecular weight of 300 to 1000 as the fatty acid ester (A). 4. The heater coating agent for false twisting machines as described in 1. or 2., which contains mineral oil (b1) of 60 to 600 Rays seconds as the mineral oil (B). 5. The heater coating agent for false twisting machines as described in 1. or 2., which contains a fatty acid ester (a1) with a mass average molecular weight of 300 to 1000 as the fatty acid ester (A), and contains 60 to Mineral oil (b1) of 600 Rays seconds was used as the above-mentioned mineral oil (B). 6. The heater coating agent for a false twisting machine according to any one of 1. to 5., which further contains a surfactant (C). 7. A method of manufacturing a false-twisted yarn, characterized in that the heater coating agent for a false-twisting machine described in any one of 1. to 6. is applied to a heater of a false-twisting machine. 8. The method for manufacturing a false-twisted yarn according to 7., wherein the heater is a contact heater. [Effects of the invention]
本發明之假撚加工機用加熱器塗布劑、及將該假撚加工機用加熱器塗布劑塗布於假撚加工機之加熱器的假撚加工紗之製造方法發揮以下效果：抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」，防止由「脫紗」導致之細毛紗斷裂及合成纖維長絲紗線之加熱不足，從而獲得被良好地加撚延伸之假撚加工紗。 又，本發明之假撚加工機用加熱器塗布劑亦具有優異之在短時間內於假撚加工機之加熱器上展開之擴展性，因此除了可於短時間內完成供油作業以外，於供油後亦可立即使假撚加工機進行運轉，並且，可使本發明之假撚加工機用加熱器塗布劑均勻地附著於假撚加工機之加熱器上而提高抑制「脫紗」之效果，故有用。 The heater coating agent for a false twisting processing machine of the present invention and the method for manufacturing a false twisting yarn by applying the heater coating agent for a false twisting processing machine to a heater of a false twisting processing machine exhibit the following effects: Suppressing the growth of synthetic fibers The silk yarn is detached from the heater in the false twist processing machine, that is, "yarn-off" to prevent the breakage of the fine wool yarn and the insufficient heating of the synthetic fiber filament yarn caused by the "yarn-off", thereby obtaining good twist and elongation. False twist processed yarn. In addition, the heater coating agent for false twisting machines of the present invention also has excellent scalability in spreading on the heater of the false twisting machine in a short time. Therefore, in addition to completing the oil supply operation in a short time, it can also The false twisting machine can be operated immediately after the oil is supplied, and the heater coating agent for the false twisting machine of the present invention can be evenly adhered to the heater of the false twisting machine to improve the effect of suppressing "yarn stripping" , so it is useful.
本發明係關於一種含有選自脂肪酸酯(A)及礦物油(B)中之至少一種之假撚加工機用加熱器塗布劑、及將該假撚加工機用加熱器塗布劑塗布於假撚加工機之加熱器的假撚加工紗之製造方法。 以下，對本發明進行詳細說明。 The present invention relates to a heater coating agent for a false twisting machine containing at least one selected from a fatty acid ester (A) and a mineral oil (B), and coating the heater coating agent for a false twisting machine on a false twisting machine. A method for manufacturing false-twisted yarn for a heater of a twisting machine. Hereinafter, the present invention will be described in detail.
＜脂肪酸酯(A)＞ 作為本發明之假撚加工機用加熱器塗布劑之一態樣，本發明之假撚加工機用加熱器塗布劑含有脂肪酸酯(A)作為必須成分。 本發明中之脂肪酸酯(A)只要為脂肪族烴之一元或多元醇、與作為脂肪族烴之一元或多元羧酸的脂肪酸之羧基進行酯鍵結而成之化合物，便可為任一化合物。具體而言，可例舉：(1)月桂酸丁酯、硬脂酸丁酯、棕櫚酸辛酯、硬脂酸辛酯、月桂酸油酯、油酸油酯、硬脂酸異十三烷基酯、異硬脂酸異二十五烷基酯等脂肪族一元醇與脂肪族單羧酸之酯；(2)1,6-己二醇二癸酸酯、三羥甲基丙烷單油酸酯單月桂酸酯、三羥甲基丙烷三月桂酸酯、三羥甲基丙烷三油酸酯、季戊四醇四油酸酯、蓖麻油等天然油脂等脂肪族多元醇與脂肪族單羧酸之酯；(3)己二酸二月桂酯、壬二酸二油酯等脂肪族一元醇與脂肪族多元羧酸之酯；等。可使用其等中之一種或併用兩種以上。 其中，藉由含有質量平均分子量為300～1000之脂肪酸酯(a1)作為本發明中之脂肪酸酯(A)，可進一步抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」。 ＜Fatty acid ester (A)＞ As one aspect of the heater coating agent for false twisting machines of the present invention, the heater coating agent for false twisting machines of the present invention contains a fatty acid ester (A) as an essential component. The fatty acid ester (A) in the present invention may be any compound as long as it is a compound in which a monovalent or polyhydric aliphatic hydrocarbon is ester-bonded with the carboxyl group of a fatty acid which is a monovalent or polyhydric aliphatic hydrocarbon. compound. Specific examples include: (1) Butyl laurate, butyl stearate, octyl palmitate, octyl stearate, oleyl laurate, oleyl oleate, and isotridecyl stearate , isostearate and other aliphatic monohydric alcohols and aliphatic monocarboxylic acid esters; (2) 1,6-hexanediol didecanoate, trimethylolpropane monooleate Esters of aliphatic polyols and aliphatic monocarboxylic acids such as monolaurate, trimethylolpropane trilaurate, trimethylolpropane trioleate, pentaerythritol tetraoleate, castor oil and other natural oils; (3) Esters of aliphatic monohydric alcohols such as dilauryl adipate and dioleyl azelate and aliphatic polycarboxylic acids; etc. One of these may be used, or two or more may be used in combination. Among them, by containing a fatty acid ester (a1) with a mass average molecular weight of 300 to 1000 as the fatty acid ester (A) in the present invention, the separation of the synthetic fiber filament yarn from the heater in the false twist processing machine can be further suppressed. , that is, "taking off the yarn".
＜礦物油(B)＞ 作為本發明之假撚加工機用加熱器塗布劑之一態樣，本發明之假撚加工機用加熱器塗布劑含有作為源自地下資源之烴化合物之礦物油(B)作為必須成分。具體而言，可例舉：芳香族系烴、石蠟系烴、環烷系烴等。更具體而言，例如可例舉：錠子油、液態石蠟等。該等礦物油可適宜地採用市售品。可其等中之一種或併用兩種以上。 其中，藉由含有60～600雷氏秒之礦物油(b1)作為本發明中之礦物油(B)，可進一步抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」。此處，雷氏秒表示礦物油之黏度，其係指以如下方式使試樣掉落而50 cm 3之試樣落下所需之時間(秒)：關閉位於容器底部之細孔，放入試樣直至達到容器內之一定高度，於達到試驗溫度30℃時打開孔而使試樣掉落。 <Mineral oil (B)> As one aspect of the heater coating agent for false twisting machines of the present invention, the heater coating agent for false twisting machines of the present invention contains mineral oil (which is a hydrocarbon compound derived from underground resources). B) as an essential ingredient. Specific examples include aromatic hydrocarbons, paraffinic hydrocarbons, naphthenic hydrocarbons, and the like. More specifically, examples thereof include spindle oil, liquid paraffin, and the like. Commercially available mineral oils can be suitably used. One of these may be used alone, or two or more may be used in combination. Among them, by containing the mineral oil (b1) of 60 to 600 Reykjavik seconds as the mineral oil (B) in the present invention, the separation of the synthetic fiber filament yarn from the heater in the false twisting machine can be further suppressed, that is, " Take off the yarn." Here, Ray's seconds represent the viscosity of mineral oil, which refers to the time (seconds) required for a 50 cm3 sample to fall when the sample is dropped in the following manner: Close the pore at the bottom of the container and put the sample into it. The sample is placed until it reaches a certain height in the container. When the test temperature reaches 30°C, the hole is opened and the sample is dropped.
本發明之假撚加工機用加熱器塗布劑只要含有選自脂肪酸酯(A)及礦物油(B)中之至少一種即可，可為含有脂肪酸酯(A)之態樣、含有礦物油(B)之態樣、及含有脂肪酸酯(A)及礦物油(B)之態樣中之任一態樣。 要想抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」，本發明之假撚加工機用加熱器塗布劑較佳為相對於該加熱器塗布劑之總質量含有至少50質量%以上之選自脂肪酸酯(A)及礦物油(B)中之至少一種，更佳為含有60質量%以上，進而較佳為含有70重量%以上。 The heater coating agent for false twisting machines of the present invention only needs to contain at least one selected from fatty acid ester (A) and mineral oil (B). It may be in a state containing fatty acid ester (A) or mineral oil. Either the form of oil (B) or the form containing fatty acid ester (A) and mineral oil (B). In order to prevent the synthetic fiber filament yarn from being detached from the heater in the false twisting processing machine, that is, "yarn-off", the heater coating agent for the false twisting processing machine of the present invention is preferably the total amount of the heater coating agent. It contains at least 50 mass % or more of at least one selected from fatty acid ester (A) and mineral oil (B), more preferably 60 mass % or more, and still more preferably 70 mass % or more.
＜界面活性劑(C)＞ 本發明之假撚加工機用加熱器塗布劑亦可進而含有界面活性劑(C)。作為可含有之界面活性劑(C)，可為非離子性界面活性劑(c1)、陰離子性界面活性劑(c2)、陽離子性界面活性劑(c3)、及兩性界面活性劑(c4)中之任一者，較佳為含有選自非離子性界面活性劑(c1)及陰離子性界面活性劑(c2)中之一種以上，其中，進而較佳為含有非離子性界面活性劑(c1)與陰離子性界面活性劑(c2)兩者。 本發明之假撚加工機用加熱器塗布劑中之界面活性劑(C)之含量並無特別限制，可相對於該加熱器塗布劑之總質量在未達50質量%之範圍內含有界面活性劑(C)，較佳為在未達40質量%之範圍內含有界面活性劑(C)，要想抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」，進而較佳為在未達30質量%之範圍內含有界面活性劑(C)。 ＜Surfactant (C)＞ The heater coating agent for false twisting machines of the present invention may further contain a surfactant (C). The surfactant (C) that may be contained may be a nonionic surfactant (c1), an anionic surfactant (c2), a cationic surfactant (c3), and an amphoteric surfactant (c4). Any one of them preferably contains one or more types selected from the group consisting of nonionic surfactant (c1) and anionic surfactant (c2), and among these, it is more preferred that it contains nonionic surfactant (c1) and anionic surfactant (c2). The content of the surfactant (C) in the heater coating agent for false twisting machines of the present invention is not particularly limited, and the surfactant content may be within a range of less than 50% by mass relative to the total mass of the heater coating agent. Agent (C), preferably containing surfactant (C) in a range of less than 40% by mass, is to prevent the synthetic fiber filament yarn from detaching from the heater in the false twist processing machine, that is, "yarn-off" , and further preferably contains the surfactant (C) in a range of less than 30% by mass.
＜非離子性界面活性劑(c1)＞ 作為可調配於本發明之假撚加工機用加熱器塗布劑中之非離子性界面活性劑(c1)之具體例，並無特別限制，例如可例舉：(聚)氧伸烷基烷基醚、(聚)氧伸烷基烷基苯醚、(聚)氧伸烷基烯丙基苯醚、(聚)氧伸烷基苯乙烯基苯醚、(聚)氧伸烷基烷基苯醚甲醛縮合物、(聚)氧乙烯-(聚)氧丙烯嵌段聚合物、(聚)氧乙烯-(聚)氧丙烯無規聚合物、(聚)氧乙烯-(聚)氧丙烯嵌段聚合物烷基苯醚、(聚)氧伸烷基脂肪酸酯、(聚)氧伸烷基山梨醇酐脂肪酸酯、(聚)氧伸烷基硬化蓖麻油、(聚)伸烷基二醇脂肪酸酯、(聚)伸烷基二醇脂肪酸醚等。其等可單獨使用一種，亦可將兩種以上組合使用。 ＜Nonionic surfactant (c1)＞ Specific examples of the nonionic surfactant (c1) that can be blended into the heater coating agent for false twisting machines of the present invention are not particularly limited, and examples thereof include: (poly)oxyalkylenealkyl Ether, (poly)oxyalkylene alkyl phenyl ether, (poly)oxyalkylene allyl phenyl ether, (poly)oxyalkylene styrene vinyl phenyl ether, (poly)oxyalkylene alkyl phenyl ether Ether formaldehyde condensate, (poly)oxyethylene-(poly)oxypropylene block polymer, (poly)oxyethylene-(poly)oxypropylene random polymer, (poly)oxyethylene-(poly)oxypropylene block Polymer alkyl phenyl ether, (poly)oxyalkylene fatty acid ester, (poly)oxyalkylene sorbitan fatty acid ester, (poly)oxyalkylene hardened castor oil, (poly)alkylene di Alcohol fatty acid esters, (poly)alkylene glycol fatty acid ethers, etc. These may be used individually by 1 type, and may be used in combination of 2 or more types.
＜陰離子性界面活性劑(c2)＞ 作為可調配於本發明之假撚加工機用加熱器塗布劑中之陰離子性界面活性劑(c2)之具體例，並無特別限制，例如可例舉：(1)烷基磷酸酯鈉鹽、烷基磷酸酯鉀鹽、烷基磷酸酯二乙醇胺鹽、烷基磷酸酯三乙醇胺鹽等烷基之碳數為4～18之烷基磷酸酯鹽；(2)烷基磺酸鈉鹽、烷基磺酸鉀鹽、二烷基磺基琥珀酸鈉鹽、二烷基磺基琥珀酸鉀鹽等碳數為5～30之磺酸鹽；(3)烷基硫酸鈉鹽、烷基硫酸鉀鹽等碳數為5～30之硫酸鹽；(4)羧酸鈉鹽、羧酸鉀鹽等羧酸鹽等。其等可單獨使用一種，亦可將兩種以上組合使用。 ＜Anionic surfactant (c2)＞ Specific examples of the anionic surfactant (c2) that can be blended in the heater coating agent for false twisting machines of the present invention are not particularly limited, and examples thereof include: (1) alkyl phosphate sodium salt, Alkyl phosphate potassium salt, alkyl phosphate diethanolamine salt, alkyl phosphate triethanolamine salt and other alkyl phosphate salts with an alkyl group having a carbon number of 4 to 18; (2) Alkyl sulfonate sodium salt, alkyl sulfonate sodium salt, alkyl phosphate triethanolamine salt, etc. Potassium sulfonate, sodium dialkyl sulfosuccinate, potassium dialkyl sulfosuccinate and other sulfonates with carbon numbers of 5 to 30; (3) Sodium alkyl sulfate, potassium alkyl sulfate Salts and other sulfates with a carbon number of 5 to 30; (4) Carboxylic acid sodium salts, carboxylic acid potassium salts and other carboxylic acid salts, etc. These may be used individually by 1 type, and may be used in combination of 2 or more types.
＜陽離子性界面活性劑(c3)＞ 作為可調配於本發明之假撚加工機用加熱器塗布劑中之陽離子性界面活性劑(c3)之具體例，並無特別限制，例如可例舉：胺鹽、銨鹽、鏻鹽、咪唑啉鹽、咪唑啉鎓鹽等。其等可單獨使用一種，亦可將兩種以上組合使用。 ＜兩性界面活性劑(c4)＞ 作為可調配於本發明之假撚加工機用加熱器塗布劑中之兩性界面活性劑(c4)之具體例，並無特別限制，例如可例舉甜菜鹼等兩性界面活性劑等。該等成分可單獨使用一種，亦可將兩種以上組合使用。 ＜Cationic surfactant (c3)＞ Specific examples of the cationic surfactant (c3) that can be blended into the heater coating agent for false twisting machines of the present invention are not particularly limited, and examples thereof include: amine salts, ammonium salts, phosphonium salts, and imidazole phosphine salt, imidazolinium salt, etc. These may be used individually by 1 type, and may be used in combination of 2 or more types. ＜Ampholytic surfactant (c4)＞ Specific examples of the amphoteric surfactant (c4) that can be blended into the heater coating agent for false twisting machines of the present invention are not particularly limited, and examples thereof include amphoteric surfactants such as betaine. These components may be used individually by 1 type, or in combination of 2 or more types.
＜其他成分＞ 本發明之假撚加工機用加熱器塗布劑除了可調配矽酮油、抗氧化劑、防銹劑、防腐劑作為其他成分以外，考慮到抑制「脫紗」之效果，還可調配氟化物等作為其他成分。其他成分之調配量可於不損害本發明之效果之範圍內進行規定，較佳為相對於假撚加工機用加熱器塗布劑之總質量設為未達20質量%之調配量。 作為矽酮油，例如可例舉：二甲基矽酮、苯基改性矽酮、胺基改性矽酮、醯胺基改性矽酮、聚醚改性矽酮、胺基聚醚改性矽酮、烷基改性矽酮、烷基芳烷基改性矽酮、烷基聚醚改性矽酮、酯改性矽酮、環氧基改性矽酮、甲醇改性矽酮、巰基改性矽酮、聚氧伸烷基改性矽酮等。該等矽酮油可適宜地採用市售品。 作為抗氧化劑，可例舉：(1)異三聚氰酸1,3,5-三(3',5'-二-第三丁基-4-羥基苄基)酯、異三聚氰酸1,3,5-三(4-第三丁基-3-羥基-2,6-二甲基苄基)酯、1,3,5-三甲基-2,4,6-三(3,5-二-第三丁基-4-羥基苄基)苯、2,2'-亞甲基-雙(4-甲基-6-第三丁基苯酚)、1,1,3-三(2-甲基-4-羥基-5-第三丁基苯基)丁烷、四[亞甲基-3-(3',5'-二-第三丁基-4'-羥基苯基)丙酸酯]甲烷等酚系抗氧化劑；(2)亞磷酸辛基二苯酯、亞磷酸三壬基苯酯、四-十三烷基-4,4'-亞丁基-雙-(2-第三丁基-5-甲基苯酚)二亞磷酸酯等亞磷酸酯系抗氧化劑；(3)4,4'-硫代雙-(6-第三丁基-3-甲基苯酚)、3,3'-硫代二丙酸二月桂酯等硫醚系抗氧化劑；等。 ＜Other ingredients＞ In addition to silicone oil, antioxidants, rust inhibitors, and preservatives as other ingredients, the heater coating agent for false twisting machines of the present invention can also be formulated with fluoride, etc., in consideration of the effect of inhibiting "shedding". Other ingredients. The blending amounts of other components can be specified within a range that does not impair the effects of the present invention, but it is preferably a blending amount of less than 20% by mass relative to the total mass of the heater coating agent for false twisting machines. Examples of the silicone oil include dimethyl silicone, phenyl-modified silicone, amino-modified silicone, amide-modified silicone, polyether-modified silicone, and amino-polyether-modified silicone. Silicone, alkyl modified silicone, alkyl aralkyl modified silicone, alkyl polyether modified silicone, ester modified silicone, epoxy modified silicone, methanol modified silicone, Thiol-modified silicone, polyoxyalkyl-modified silicone, etc. Commercially available silicone oils can be suitably used. Examples of antioxidants include: (1) 1,3,5-tris(3',5'-di-tert-butyl-4-hydroxybenzyl)isocyanurate, isocyanurate 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) ester, 1,3,5-trimethyl-2,4,6-tris(3 ,5-di-tert-butyl-4-hydroxybenzyl)benzene, 2,2'-methylene-bis(4-methyl-6-tert-butylphenol), 1,1,3-tris (2-Methyl-4-hydroxy-5-tert-butylphenyl)butane, tetrakis[methylene-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl ) Propionate] methane and other phenolic antioxidants; (2) Octyldiphenyl phosphite, trinonylphenyl phosphite, tetrakis-tridecyl-4,4'-butylene-bis-(2) -Phosphite-based antioxidants such as -tert-butyl-5-methylphenol) diphosphite; (3) 4,4'-thiobis-(6-tert-butyl-3-methylphenol) , 3,3'-dilauryl thiodipropionate and other thioether antioxidants; etc.
＜假撚加工機用加熱器塗布劑之製備方法＞ 作為本發明之假撚加工機用加熱器塗布劑之製備方法，並無特別限定，可藉由將構成假撚加工機用加熱器塗布劑之上述各成分以任意順序添加並進行混合而製備。 ＜Preparation method of heater coating agent for false twisting machine＞ The preparation method of the heater coating agent for false twisting machines of the present invention is not particularly limited. It can be prepared by adding the above-mentioned components constituting the heater coating agent for false twisting machines in any order and mixing.
作為使用本發明之假撚加工機用加熱器塗布劑之假撚加工機，可例舉如下等假撚加工機：(1)接觸型加熱器之假撚加工機，其安裝有加熱器溫度為150～230℃、加熱器長度為150～250 cm之加熱器，且合成纖維長絲紗線在加熱板上以接觸方式移行；(2)非接觸型加熱器之假撚加工機，其安裝有加熱器溫度為300～600℃、加熱器長度為20～150 cm之加熱器，且合成纖維長絲紗線在加熱板上以非接觸方式移行。 其中，要想發揮抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」之效果，本發明之假撚加工機用加熱器塗布劑較佳為應用於接觸型加熱器之假撚加工機。 As a false twisting machine using the heater coating agent for a false twisting machine of the present invention, the following false twisting machines can be exemplified: (1) A false twisting machine with a contact type heater, which is equipped with a heater whose temperature is A heater with a temperature of 150 to 230°C and a heater length of 150 to 250 cm, and the synthetic fiber filament yarn moves in contact on the heating plate; (2) A false twist processing machine with a non-contact heater, which is installed with The heater temperature is 300~600℃, the heater length is 20~150 cm, and the synthetic fiber filament yarn moves on the heating plate in a non-contact manner. Among them, in order to exert the effect of inhibiting the detachment of the synthetic fiber filament yarn from the heater in the false twist processing machine, that is, "yarn removal", the heater coating agent for the false twist processing machine of the present invention is preferably applied to the contact type Heater false twist processing machine.
作為將本發明之假撚加工機用加熱器塗布劑塗布於加熱器之方法，可採用毛刷塗裝、淋塗、噴霧塗布、滾筒塗布、或浸漬塗布等方法，就形成於假撚加工機用加熱器上之塗布劑層之平滑性、均勻性、與加熱器面之密接性、及簡便性等方面而言，較佳為使毛刷、滾筒、布等塗布用具中含浸本發明之假撚加工機用加熱器塗布劑而進行塗布之方法。 [實施例] As a method for applying the heater coating agent for a false twist processing machine of the present invention to a heater, brush coating, shower coating, spray coating, roller coating, or dip coating can be used to form a false twist processing machine. In terms of the smoothness, uniformity, close contact with the heater surface, and simplicity of the coating agent layer on the heater, it is preferable to impregnate brushes, rollers, cloths, and other coating equipment with the fake material of the present invention. A method of applying coating agent to a twisting machine using a heater. [Example]
以下，列舉實施例對本發明進行說明，但本發明之技術範圍並不受其等限定。再者，於以下之實施例及比較例中，份係指質量份，又，%係指質量%。The present invention will be described below with reference to examples, but the technical scope of the present invention is not limited thereto. In addition, in the following Examples and Comparative Examples, parts refer to parts by mass, and % refers to mass %.
＜假撚加工機用加熱器塗布劑之製備＞ ･實施例1 實施例1係僅含有棕櫚酸辛酯(質量平均分子量369)(A-1)之假撚加工機用加熱器塗布劑。 ･實施例19 將棕櫚酸辛酯(質量平均分子量369)(A-1)30份、礦物油(雷氏秒：800)(B-4)60份、聚氧乙烯(5莫耳)十二烷基醚(c1-1)9份、磷酸異辛酯鉀鹽(c2-1)1份、及二甲基聚矽氧烷(F-1)1份全部均勻地混合而製備實施例19之假撚加工機用加熱器塗布劑。 ＜Preparation of heater coating agent for false twisting machine＞ ･Example 1 Example 1 is a heater coating agent for false twisting machines containing only octyl palmitate (mass average molecular weight: 369) (A-1). ･Example 19 Mix 30 parts of octyl palmitate (mass average molecular weight 369) (A-1), 60 parts of mineral oil (Ray's seconds: 800) (B-4), polyoxyethylene (5 mol) lauryl ether (c1 -1) 9 parts, 1 part of isooctyl phosphate potassium salt (c2-1), and 1 part of dimethylpolysiloxane (F-1) were uniformly mixed to prepare the false twist processing machine of Example 19 Heater coating.
･實施例2～18及比較例1 按照下述表1所示之組成，以與上述實施例1或實施例19之製備方法相同之方式製備實施例2～18之假撚加工機用加熱器塗布劑。比較例1係未將假撚加工機用加熱器塗布劑塗布於加熱器之例。 將實施例1～19之假撚加工機用加熱器塗布劑之各組成彙總示於下述表1。 再者，表1中之其他成分之「調配量 *」係指相對於脂肪酸酯(A)、礦物油(B)、界面活性劑(C)之合計100質量份之質量份。 ･Examples 2 to 18 and Comparative Example 1 According to the composition shown in Table 1 below, heaters for false twisting machines of Examples 2 to 18 were prepared in the same manner as the preparation method of Example 1 or Example 19. Coating agent. Comparative Example 1 is an example in which the heater coating agent for a false twisting machine was not applied to the heater. The compositions of the heater coating agents for false twisting machines of Examples 1 to 19 are summarized and shown in Table 1 below. In addition, the "preparation amount * " of other components in Table 1 means parts by mass based on a total of 100 parts by mass of fatty acid ester (A), mineral oil (B), and surfactant (C).
[表1]
表1中之各符號表示下述成分。 ＜脂肪酸酯(A)＞ A-1：棕櫚酸辛酯(質量平均分子量369) A-2：己二酸二月桂酯(質量平均分子量483) A-3：三羥甲基丙烷三油酸酯(質量平均分子量928) A-4：月桂酸丁酯(質量平均分子量256) A-5：季戊四醇四油酸酯(質量平均分子量1194) 上述A-1～A-3係相當於本發明中之質量平均分子量為300～1000之脂肪酸酯(a1)之成分。 ＜礦物油(B)＞ B-1：礦物油(雷氏秒：80) B-2：礦物油(雷氏秒：500) B-3：礦物油(雷氏秒：40) B-4：礦物油(雷氏秒：800) 上述B-1、B-2係相當於本發明中之60～600雷氏秒之礦物油(b1)之成分。 ＜界面活性劑(C)＞ ･非離子性界面活性劑 c1-1：聚氧乙烯(5莫耳)十二烷基醚 ･陰離子性界面活性劑 c2-1：磷酸異辛酯鉀鹽 c2-2：2-十六烷基磷酸酯三乙醇胺鹽 c2-3：油酸鉀鹽 c2-4：二辛基磺基琥珀酸鈉鹽 ＜其他成分＞ F-1：二甲基聚矽氧烷 G-1：1,1,3-三(2-甲基-4-羥基-5-第三丁基苯基)丁烷(抗氧化劑) Each symbol in Table 1 represents the following components. ＜Fatty acid ester (A)＞ A-1: Octyl palmitate (mass average molecular weight 369) A-2: Dilauryl adipate (mass average molecular weight 483) A-3: Trimethylolpropane trioleate (mass average molecular weight 928) A-4: Butyl laurate (mass average molecular weight 256) A-5: Pentaerythritol tetraoleate (mass average molecular weight 1194) The above-mentioned A-1 to A-3 are components corresponding to the fatty acid ester (a1) with a mass average molecular weight of 300 to 1000 in the present invention. ＜Mineral oil (B)＞ B-1: Mineral oil (Ray's seconds: 80) B-2: Mineral oil (Ray's seconds: 500) B-3: Mineral oil (Ray's seconds: 40) B-4: Mineral oil (Ray's seconds: 800) The above-mentioned B-1 and B-2 are components corresponding to the mineral oil (b1) of 60 to 600 Ray's seconds in the present invention. ＜Surfactant (C)＞ ･Nonionic surfactant c1-1: Polyoxyethylene (5 mol) lauryl ether ･Anionic surfactant c2-1: Isooctyl phosphate potassium salt c2-2: 2-Hexadecylphosphate triethanolamine salt c2-3: Potassium oleate c2-4: Dioctyl sulfosuccinate sodium salt ＜Other ingredients＞ F-1: Dimethylpolysiloxane G-1: 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane (antioxidant)
＜假撚加工試驗＞ 使用接觸型加熱器假撚加工機(TMT Machinery公司製造之商品名ATF-21)，於加工速度＝650 m/分鐘、延伸倍率＝1.70、施撚方式＝三軸圓盤外接式摩擦方式(進入側導盤1個、輸出側導盤1個、硬質聚胺酯盤4個)、盤速度/紗速度(D/Y)＝1.7、加撚側加熱器＝長度2 m、表面溫度180℃、解撚側加熱器＝無之條件下，對賦予有下述合成纖維用處理劑A(油劑賦予量(OPU)：0.4%)之氧化鈦含量0.2%之聚對苯二甲酸乙二酯之128 dtex、36長絲之半延伸絲紗(POY)進行假撚加工。 再者，於假撚加工前，使用含浸有實施例1～19之各假撚加工機用加熱器塗布劑之布，以可塗布於加熱器整面之最低限量塗布於上述接觸型加熱器假撚加工機之加熱器。 ＜合成纖維用處理劑A＞ 將下述成分均勻地混合而製備合成纖維用處理劑A：使環氧乙烷(EO)與環氧丙烷(PO)以EO/PO＝50/50(質量比)之比例呈無規狀加成在丁醇上而獲得之質量平均分子量2000之聚醚一元醇45份、使環氧乙烷(EO)與環氧丙烷(PO)以EO/PO＝70/30(質量比)之比例呈無規狀加成在月桂醇上而獲得之質量平均分子量1500之聚醚一元醇42份、使10莫耳之環氧乙烷(EO)加成在月桂醇上而獲得之聚醚一元醇12份、癸烷磺酸鈉鹽0.5份、及月桂基磷酸酯鉀鹽0.5份。 ＜防脫紗性之評價＞ 於上述條件下，以12紡錠(一台假撚加工機之同時假撚加工數：12)進行10分鐘之假撚加工，測量產生脫紗之紡錠數。 [評價基準] ◎：產生紡錠數為0～1次 ○：產生紡錠數為2～4次 ×：產生紡錠數為5次以上 ＜擴展性評價＞ 使實施例1～19之各樣品0.15 g垂落至以45°之角度傾斜之表面溫度180℃之假撚加工機之加熱器，測定樣品歷時10秒鐘前進之距離。 [評價基準] ◎：30 cm以上 ○：未達30 cm 將關於實施例1～19之假撚加工機用加熱器塗布劑及比較例1之「防脫紗性之評價」及「擴展性評價」之結果彙總示於表2。 ＜False twist processing test＞ A contact heater false twisting machine (trade name ATF-21 manufactured by TMT Machinery Co., Ltd.) was used. The processing speed = 650 m/min, the elongation ratio = 1.70, and the twisting method = three-axis disc external friction method (enter 1 side guide disk, 1 output side guide disk, 4 rigid polyurethane disks), disk speed/yarn speed (D/Y) = 1.7, twisting side heater = length 2 m, surface temperature 180°C, untwisting 128 dtex of polyethylene terephthalate with a titanium oxide content of 0.2% and added with the following synthetic fiber treatment agent A (oil agent amount (OPU): 0.4%) under the condition that side heater = no , 36 filament semi-extended yarn (POY) is subjected to false twist processing. Furthermore, before the false twisting process, a cloth impregnated with the heater coating agent for each false twisting processing machine of Examples 1 to 19 was used to apply the minimum amount that can be applied to the entire surface of the heater on the contact type heater false Heater for twisting machine. ＜Treatment agent A for synthetic fibers＞ The following ingredients are uniformly mixed to prepare a synthetic fiber treatment agent A: ethylene oxide (EO) and propylene oxide (PO) are added randomly in a ratio of EO/PO=50/50 (mass ratio). Prepare 45 parts of polyether monool with a mass average molecular weight of 2000 obtained on butanol, so that ethylene oxide (EO) and propylene oxide (PO) are in a ratio of EO/PO=70/30 (mass ratio) 42 parts of polyether monool with a mass average molecular weight of 1500 obtained by randomly adding lauryl alcohol, and 12 parts of polyether monool obtained by adding 10 moles of ethylene oxide (EO) to lauryl alcohol. parts, 0.5 parts of decane sulfonate sodium salt, and 0.5 parts of lauryl phosphate potassium salt. ＜Evaluation of anti-yarn removal properties＞ Under the above conditions, perform false twisting processing for 10 minutes with 12 spindles (the number of simultaneous false twisting processes on one false twisting machine: 12), and measure the number of spindles that produce yarn loss. [Evaluation criteria] ◎: The number of spindles generated is 0 to 1 times ○: The number of spindles generated is 2 to 4 times ×: The number of spindles produced is more than 5 times ＜Extensibility Evaluation＞ Drop 0.15 g of each sample of Examples 1 to 19 onto the heater of a false twisting machine with a surface temperature of 180°C inclined at an angle of 45°, and measure the distance traveled by the sample in 10 seconds. [Evaluation criteria] ◎: 30 cm or more ○: Less than 30 cm The results of "evaluation of anti-yarning properties" and "evaluation of spreadability" of the heater coating agents for false twisting machines of Examples 1 to 19 and Comparative Example 1 are summarized and shown in Table 2.
[表2]
如表2所示，確認到作為本發明之假撚加工機用加熱器塗布劑之具體例的實施例1～19可良好地抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」，進而可防止由「脫紗」引起之細毛紗斷裂或合成纖維長絲紗線之加熱不足，從而獲得被良好地加撚延伸之假撚加工紗。 又，亦明確了實施例1～19之假撚加工機用加熱器塗布劑亦具有優異之在短時間內於假撚加工機之加熱器上展開之擴展性。 相對於此，亦明確了於不將本發明之假撚加工機用加熱器塗布劑塗布於假撚加工機之加熱器而使用附著有合成纖維用處理劑之半延伸絲紗(POY)時，無法抑制「脫紗」，從而產生由「脫紗」引起之細毛紗斷裂。 [產業上之可利用性] As shown in Table 2, it was confirmed that Examples 1 to 19, which are specific examples of the heater coating agent for false twisting processing machines of the present invention, can effectively suppress the detachment of the synthetic fiber filament yarn from the heater in the false twisting processing machine. , that is, "yarn-off", thereby preventing the breakage of fine wool yarns or insufficient heating of synthetic fiber filament yarns caused by "yarn-off", thereby obtaining a false-twisted yarn that is well twisted and stretched. Furthermore, it was also confirmed that the heater coating agents for false twisting machines of Examples 1 to 19 also have excellent spreadability in spreading on the heaters of false twisting machines in a short time. In contrast, it was also clarified that when semi-drawn yarn (POY) to which a treatment agent for synthetic fibers is attached is used instead of applying the heater coating agent for false twisting machines of the present invention to the heater of the false twisting machine, Unable to suppress "yarn-off", resulting in breakage of fine wool yarns caused by "yarn-off". [Industrial availability]
本發明之假撚加工機用加熱器塗布劑、及將該假撚加工機用加熱器塗布劑塗布於假撚加工機之加熱器的假撚加工紗之製造方法可抑制合成纖維長絲紗線於假撚加工機中自加熱器脫離、即「脫紗」，防止由「脫紗」引起之細毛紗斷裂或合成纖維長絲紗線之加熱不足，從而獲得被良好地加撚延伸之假撚加工紗，故非常有用。The heater coating agent for a false twisting processing machine of the present invention and the method for manufacturing a false twisting yarn by applying the heater coating agent for a false twisting processing machine to a heater of a false twisting processing machine can inhibit synthetic fiber filament yarns. In the false twist processing machine, it is separated from the heater, that is, "yarn-off" to prevent breakage of the fine wool yarn or insufficient heating of the synthetic fiber filament yarn caused by "yarn-off", thereby obtaining a false twist that is well twisted and extended. Processing yarn, so very useful.
Claims (8)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020-199276 | 2020-12-01 | ||
| JP2020199276A JP6895194B1 (en) | 2020-12-01 | 2020-12-01 | Heater coating agent for false twisting machine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202223196A TW202223196A (en) | 2022-06-16 |
| TWI814110B true TWI814110B (en) | 2023-09-01 |
Family
ID=76540403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW110138532A TWI814110B (en) | 2020-12-01 | 2021-10-18 | Heater Coating Agent for False Twisting Machine |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6895194B1 (en) |
| KR (1) | KR102673620B1 (en) |
| CN (1) | CN114846183B (en) |
| TW (1) | TWI814110B (en) |
| WO (1) | WO2022118527A1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5446923A (en) * | 1977-09-16 | 1979-04-13 | Takemoto Oil & Fat Co Ltd | Contamination preventing method of heat treating heater in treating process of thermoplastic synthetic fiber |
| TW200600622A (en) * | 2004-06-30 | 2006-01-01 | Ind Tech Res Inst | Nylon spin finish composition and the additive thereof |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5224148B1 (en) * | 1967-04-14 | 1977-06-29 | ||
| CA955024A (en) * | 1969-11-15 | 1974-09-24 | Masao Matsui | Synthetic fibers and methods for producing the same |
| JPS5095548A (en) * | 1973-12-28 | 1975-07-30 | ||
| JPH04676U (en) * | 1990-04-11 | 1992-01-07 | ||
| JPH06207334A (en) * | 1993-01-12 | 1994-07-26 | Noburo Shirai | Synthetic fiber false-twisting machine having hole opened in groove of hot plate |
| JP3907313B2 (en) | 1998-04-27 | 2007-04-18 | 竹本油脂株式会社 | Treatment agent for synthetic fiber used in false twisting process and method for treating synthetic fiber |
| EP1154054B1 (en) * | 1999-09-28 | 2010-11-10 | Toray Industries, Inc. | Polypropylene terephthalate twisted yarn and method for producing the same |
| JP4052771B2 (en) * | 1999-11-24 | 2008-02-27 | 竹本油脂株式会社 | Synthetic fiber treatment agent and synthetic fiber treatment method |
| TWI243223B (en) * | 2001-07-04 | 2005-11-11 | Sanyo Chemical Ind Ltd | Oil agent for spinning synthetic fiber |
| JP4093931B2 (en) | 2003-07-22 | 2008-06-04 | 竹本油脂株式会社 | Treatment agent for synthetic fiber used for false twisting and method for treating synthetic fiber |
| JP2005206989A (en) * | 2004-01-26 | 2005-08-04 | Mitsubishi Rayon Co Ltd | Yarn heating apparatus |
| JP4947796B2 (en) * | 2007-06-08 | 2012-06-06 | 竹本油脂株式会社 | Synthetic fiber straight-twisting agent, synthetic fiber false twisted yarn processing method using the same, and synthetic fiber false twisted yarn |
| WO2009034692A1 (en) * | 2007-09-10 | 2009-03-19 | Matsumoto Yushi-Seiyaku Co., Ltd. | Oil for friction false twisting of synthetic fiber and use of the same |
| KR101310008B1 (en) * | 2009-03-11 | 2013-09-24 | 도레이 카부시키가이샤 | Liquid crystal polyester fibers and method for producing the same |
| JP7006134B2 (en) * | 2017-10-27 | 2022-02-10 | 凸版印刷株式会社 | Manufacturing method of molded products |
-
2020
- 2020-12-01 JP JP2020199276A patent/JP6895194B1/en active Active
-
2021
- 2021-09-28 WO PCT/JP2021/035615 patent/WO2022118527A1/en active Application Filing
- 2021-09-28 CN CN202180004894.XA patent/CN114846183B/en active Active
- 2021-09-28 KR KR1020217039890A patent/KR102673620B1/en active IP Right Grant
- 2021-10-18 TW TW110138532A patent/TWI814110B/en active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5446923A (en) * | 1977-09-16 | 1979-04-13 | Takemoto Oil & Fat Co Ltd | Contamination preventing method of heat treating heater in treating process of thermoplastic synthetic fiber |
| TW200600622A (en) * | 2004-06-30 | 2006-01-01 | Ind Tech Res Inst | Nylon spin finish composition and the additive thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202223196A (en) | 2022-06-16 |
| KR102673620B1 (en) | 2024-06-07 |
| CN114846183B (en) | 2023-12-01 |
| CN114846183A (en) | 2022-08-02 |
| JP6895194B1 (en) | 2021-06-30 |
| WO2022118527A1 (en) | 2022-06-09 |
| KR20220079497A (en) | 2022-06-13 |
| JP2022087372A (en) | 2022-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4805428B2 (en) | Treatment agent for polyurethane elastic fiber and polyurethane elastic fiber | |
| JP4970187B2 (en) | Fiber treatment agent and method for producing synthetic fiber using the same | |
| CN101802295B (en) | Oil for friction false twisting of synthetic fiber and use of the same | |
| CN107208357B (en) | Treating agent for elastic fiber and use thereof | |
| CN104727142A (en) | Synthetic fiber treating agent and use thereof | |
| JP6542452B1 (en) | Processing agents for synthetic fibers and synthetic fibers | |
| JPH0360949B2 (en) | ||
| JP7126297B1 (en) | Synthetic fiber treatment agent and synthetic fiber | |
| TWI814110B (en) | Heater Coating Agent for False Twisting Machine | |
| JP5730144B2 (en) | Treatment agent for synthetic fibers and use thereof | |
| WO2019138866A1 (en) | Treatment agent for synthetic fiber and use thereof | |
| JP6784431B1 (en) | Treatment agent for sewing thread and sewing thread | |
| KR102606860B1 (en) | Treatment agents for elastic fibers and elastic fibers | |
| WO2023140375A1 (en) | Treatment agent for elastic fibers, and elastic fibers | |
| WO2015166603A1 (en) | Agent for treating short-staple fibers and use for said agent | |
| JP4181702B2 (en) | Treatment agent for polyamide-based synthetic fibers | |
| JPH0268370A (en) | Aqueous emulsion-type spinning lubricant and usage therefor | |
| JPH0247372A (en) | Treating agent for fiber | |
| JP6812703B2 (en) | Synthetic fiber smoothing agent composition | |
| JPH0390675A (en) | Lubricant for synthetic fiber | |
| JPH0127195B2 (en) | ||
| JP2955746B2 (en) | Oil agent for elastic fiber | |
| JPH1053962A (en) | Finishing oil for elastic fiber | |
| JP3420086B2 (en) | Synthetic fiber drawing false twist method | |
| JPS6247992B2 (en) |