TWI799564B - 用於生產正丁醇、異丁醇及2-烷基烷醇之方法 - Google Patents

用於生產正丁醇、異丁醇及2-烷基烷醇之方法 Download PDF

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TWI799564B
TWI799564B TW108112422A TW108112422A TWI799564B TW I799564 B TWI799564 B TW I799564B TW 108112422 A TW108112422 A TW 108112422A TW 108112422 A TW108112422 A TW 108112422A TW I799564 B TWI799564 B TW I799564B
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Taiwan
Prior art keywords
butanol
iso
production
alkyl alkanol
normal
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TW108112422A
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TW201945329A (zh
Inventor
費爾瑟 阿奇貝爾德
雅卓安 羅德
馬汀 施密特
大衛 衛爾奇
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英商強生瑪西大維科技公司
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B01D3/146—Multiple effect distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW108112422A 2018-04-13 2019-04-10 用於生產正丁醇、異丁醇及2-烷基烷醇之方法 TWI799564B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1806127.5A GB201806127D0 (en) 2018-04-13 2018-04-13 Process
GB1806127.5 2018-04-13

Publications (2)

Publication Number Publication Date
TW201945329A TW201945329A (zh) 2019-12-01
TWI799564B true TWI799564B (zh) 2023-04-21

Family

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TW108112422A TWI799564B (zh) 2018-04-13 2019-04-10 用於生產正丁醇、異丁醇及2-烷基烷醇之方法

Country Status (11)

Country Link
US (1) US11312674B2 (zh)
EP (1) EP3774705B1 (zh)
JP (1) JP7250039B2 (zh)
KR (1) KR102688820B1 (zh)
CN (1) CN111989308B (zh)
EA (1) EA202092321A1 (zh)
GB (2) GB201806127D0 (zh)
PL (1) PL3774705T3 (zh)
TW (1) TWI799564B (zh)
WO (1) WO2019197831A1 (zh)
ZA (1) ZA202006388B (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113929558B (zh) * 2021-10-13 2023-12-22 中国海洋石油集团有限公司 一种高碳醇生产中废醇提纯回用的方法和装置系统
WO2023161884A1 (en) * 2022-02-27 2023-08-31 Petrosakht Chehelsoton Engineering Technical Company An integrated process for producing oxo alcohols from natural gas
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3119876A (en) * 1960-01-25 1964-01-28 Exxon Research Engineering Co Production of aldehydes and alcohols
CN105189426A (zh) * 2013-05-03 2015-12-23 沙特基础工业公司 用于同时生产含氧醇和增塑剂的集成方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2763693A (en) 1951-10-13 1956-09-18 Eastman Kodak Co Oxo process-separation and recovery of products and reaction vehicle
DE2040501C3 (de) 1970-08-14 1984-01-05 Basf Ag, 6700 Ludwigshafen Verfahren zur Durchführung von exothermen Reaktionen zwischen einem Gas und einer Flüssigkeit
DE2713434C3 (de) 1977-03-26 1980-10-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von 2-Äthylhexanol
DE3168398D1 (en) * 1980-11-20 1985-02-28 Monsanto Co Preparation of plasticizer alcohols from propylene-butene mixtures
CA1257294A (en) * 1982-04-28 1989-07-11 George E. Barker Preparation of 2-propylheptanol and other alcohols
US5227544A (en) * 1991-02-15 1993-07-13 Basf Corporation Process for the production of 2-ethylhexanol
US5877358A (en) * 1996-09-23 1999-03-02 Exxon Chemical Patents Inc. Alcohol hydrogenation with intermediate recycle
GB0019245D0 (en) * 2000-08-04 2000-09-27 Bp Chem Int Ltd Process for removing a ketone and/or aldehyde impurity
CN101522598B (zh) * 2006-11-09 2012-06-27 三菱化学株式会社 正丁醇和异丁醛的联产方法
WO2012008717A2 (en) * 2010-07-14 2012-01-19 Lg Chem, Ltd. Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus
KR101089488B1 (ko) * 2010-07-14 2011-12-02 주식회사 엘지화학 올레핀으로부터 이소타입의 알데히드와 알콜의 병산 장치 및 이를 이용한 병산 방법
CN106103399B (zh) 2013-12-19 2019-07-09 陶氏技术投资有限责任公司 氢甲酰化方法
CN104961624B (zh) 2015-06-02 2016-08-24 天津大学 丁辛醇生产废液的回收利用方法
CN105237350B (zh) 2015-09-21 2017-03-22 天津渤化永利化工股份有限公司 丁辛醇生产装置工业废料综合利用方法
CN105820037A (zh) 2016-04-28 2016-08-03 张家港市华昌新材料科技有限公司 一种辛醇轻组分排放的方法
GB201617463D0 (en) * 2016-10-14 2016-11-30 Johnson Matthey Davy Technologies Limited Process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3119876A (en) * 1960-01-25 1964-01-28 Exxon Research Engineering Co Production of aldehydes and alcohols
CN105189426A (zh) * 2013-05-03 2015-12-23 沙特基础工业公司 用于同时生产含氧醇和增塑剂的集成方法

Also Published As

Publication number Publication date
US11312674B2 (en) 2022-04-26
EP3774705A1 (en) 2021-02-17
JP2021519795A (ja) 2021-08-12
JP7250039B2 (ja) 2023-03-31
EA202092321A1 (ru) 2021-01-15
GB2575146B (en) 2021-12-22
ZA202006388B (en) 2024-02-28
CN111989308B (zh) 2023-04-28
PL3774705T3 (pl) 2023-03-20
GB2575146A (en) 2020-01-01
KR20210005034A (ko) 2021-01-13
WO2019197831A1 (en) 2019-10-17
TW201945329A (zh) 2019-12-01
US20210078924A1 (en) 2021-03-18
GB201905133D0 (en) 2019-05-29
EP3774705B1 (en) 2023-01-25
KR102688820B1 (ko) 2024-07-29
GB201806127D0 (en) 2018-05-30
CN111989308A (zh) 2020-11-24

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