TWI772656B - Sputtering film forming apparatus - Google Patents
Sputtering film forming apparatus Download PDFInfo
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- TWI772656B TWI772656B TW108122913A TW108122913A TWI772656B TW I772656 B TWI772656 B TW I772656B TW 108122913 A TW108122913 A TW 108122913A TW 108122913 A TW108122913 A TW 108122913A TW I772656 B TWI772656 B TW I772656B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/56—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
- C23C14/564—Means for minimising impurities in the coating chamber such as dust, moisture, residual gases
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/34—Gas-filled discharge tubes operating with cathodic sputtering
- H01J37/3411—Constructional aspects of the reactor
- H01J37/3441—Dark space shields
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Abstract
本發明係提供一種在藉由磁控管濺鍍進行成膜時,能夠對在濺鍍靶材的外周部處產生非侵蝕區域一事作抑制的技術。本發明係一種濺鍍成膜裝置,其係於真空中藉由磁控管濺鍍法來對於一個成膜對象物進行成膜。於本發明中,係具有:磁控管產生用磁鐵裝置(10),係相對於一個濺鍍靶材(7)而被配置於與濺鍍面(7a)相反側,並於放電時在沿著該濺鍍靶材(7)的濺鍍面(7a)之方向上移動、和內側遮蔽部(21),係被接近配置於濺鍍靶材(7)之外周部的周圍並被設為浮動電位、以及外側遮蔽部(22),係被設置於該內側遮蔽部(21)的周圍並被設為接地電位且由導電性材料所構成。The present invention provides a technique capable of suppressing the occurrence of a non-eroded region at the outer peripheral portion of a sputtering target when a film is formed by magnetron sputtering. The present invention relates to a sputtering film-forming apparatus for forming a film on one film-forming object by a magnetron sputtering method in a vacuum. In the present invention, there is provided a magnet device (10) for generating a magnetron, which is arranged on the opposite side of the sputtering surface (7a) with respect to one sputtering target (7), and is arranged along the side of the sputtering surface (7a) during discharge. The sputtering target (7) moves in the direction of the sputtering surface (7a), and the inner shielding portion (21) is arranged close to the periphery of the outer peripheral portion of the sputtering target (7) and is set as The floating potential and the outer shielding portion (22) are provided around the inner shielding portion (21), are set to ground potential, and are made of a conductive material.
Description
本發明,係關於濺鍍裝置,尤其是關於藉由磁控管濺鍍來進行成膜的濺鍍成膜裝置之技術。The present invention relates to a sputtering apparatus, particularly a technique for a sputtering film-forming apparatus for forming a film by magnetron sputtering.
以往,於磁控管濺鍍裝置中,起因於產生磁場之磁鐵裝置的構造,於濺鍍靶材(以下,適宜稱為「靶材」)上產生的磁場會成為不均勻,因此濺鍍氣體的離子會集中在磁通密度高的部分處,而存在有該部分會較磁通密度低的部分更早被削去的問題。Conventionally, in a magnetron sputtering apparatus, due to the structure of a magnet apparatus that generates a magnetic field, the magnetic field generated on a sputtering target (hereinafter, appropriately referred to as a "target") becomes non-uniform. Therefore, the sputtering gas The ions of the ions are concentrated in the part with high magnetic flux density, and there is a problem that the part is cut off earlier than the part with low magnetic flux density.
為了防止這種靶材產生局部性地被削去之部分(侵蝕)的情形,以往是一邊使磁鐵裝置移動一邊進行濺鍍。In order to prevent the occurrence of locally chipped parts (erosion) of such a target, conventionally, sputtering has been performed while moving the magnet device.
但,若使用這種手段來進行濺鍍,則當藉由放電而產生並被磁鐵裝置所致之磁場而捕捉的電漿與被電性接地的導電構件相接觸的情況時,電漿中之離子的電荷會通過導電構件來流動至接地部位,而使電漿消失。為了避免這種事態,係必須使磁鐵裝置,在外周磁鐵之環的外周全體會位置於較濺鍍面之外周部更內側的範圍內移動。However, when sputtering is performed using such a method, when the plasma generated by the discharge and captured by the magnetic field caused by the magnet device comes into contact with the electrically grounded conductive member, the plasma The charge of the ions flows to the ground through the conductive member, and the plasma disappears. In order to avoid such a situation, it is necessary to move the magnet device so that the entire outer circumference of the outer circumference magnet ring is located more inward than the outer circumference of the sputtered surface.
其結果,電漿並不會到達靶材之濺鍍面的外周部處,而存在有殘留並未被濺鍍之非侵蝕區域的問題。 若是濺鍍粒子附著在這種靶材的非侵蝕區域處,則會因異常放電等而剝離,並成為微粒之產生原因,而造成問題。 [先前技術文獻] [專利文獻]As a result, the plasma does not reach the outer peripheral portion of the sputtered surface of the target, and there is a problem that a non-eroded region that is not sputtered remains. If sputtered particles adhere to the non-eroded region of such a target, they are peeled off due to abnormal discharge or the like, and become a cause of generation of particles, thereby causing a problem. [Prior Art Literature] [Patent Literature]
[專利文獻1] 日本特開2015-92025號公報[Patent Document 1] Japanese Patent Application Laid-Open No. 2015-92025
[發明所欲解決之課題][The problem to be solved by the invention]
本發明係考慮上述之以往的技術課題而完成者,其目的為,提供一種在藉由磁控管濺鍍進行成膜時,能夠對在濺鍍靶材的外周部處產生非侵蝕區域一事作抑制的技術。 [用以解決課題之手段]The present invention has been made in consideration of the above-mentioned conventional technical problems, and an object of the present invention is to provide a method capable of preventing a non-eroded region from being generated in the outer peripheral portion of a sputtering target when a film is formed by magnetron sputtering. Suppression techniques. [means to solve the problem]
為了達成上述目的而完成之本發明,係一種濺鍍成膜裝置,其係於真空中藉由磁控管濺鍍法來對於一個成膜對象物進行成膜,該濺鍍成膜裝置,係具有:磁控管產生用磁鐵裝置,係相對於一個濺鍍靶材而被配置於與濺鍍面相反側,並於放電時在沿著該濺鍍靶材的濺鍍面之方向上移動、和內側遮蔽部,係被接近配置於前述濺鍍靶材之外周部的周圍並被設為浮動電位、以及外側遮蔽部,係被設置於該內側遮蔽部的周圍並被設為接地電位且由導電性材料所構成。 本發明係濺鍍成膜裝置,其中,係於前述內側遮蔽部設置有以覆蓋前述濺鍍靶材之濺鍍面的方式而重疊的重複部。 本發明係濺鍍成膜裝置,其中,前述內側遮蔽部之重複部,係被設置成涵蓋前述濺鍍靶材之濺鍍面的外周部之全區域。 本發明係濺鍍成膜裝置,其中,前述內側遮蔽部之重複部,係被設置成與被形成為矩形狀之前述濺鍍靶材之相對向的一對之角部重疊。 本發明係濺鍍成膜裝置,其中,前述內側遮蔽部,係設置有朝前述濺鍍靶材之濺鍍面的方向突出的突出部。 本發明係濺鍍成膜裝置,其中,前述內側遮蔽部之突出部,係被設置成涵蓋前述濺鍍靶材之濺鍍面的外周部之全區域。 本發明係濺鍍成膜裝置,其中,前述內側遮蔽部之突出部,係被設置於被形成為矩形狀之前述濺鍍靶材之相對向的一對之角部。 本發明係濺鍍成膜裝置,其中,前述濺鍍靶材,係以使其外徑較前述成膜對象物的外徑更大的方式來形成。 [發明效果]The present invention, which has been accomplished in order to achieve the above object, is a sputtering film-forming apparatus for forming a film on a film-forming object by a magnetron sputtering method in a vacuum, and the sputtering film-forming apparatus is a The magnetron generating magnet device is arranged on the opposite side of the sputtering surface with respect to one sputtering target, and moves in the direction along the sputtering surface of the sputtering target during discharge, and an inner shielding portion, which is arranged close to the periphery of the outer peripheral portion of the sputtering target and is set to a floating potential, and an outer shielding portion is provided around the inner shielding portion and is set to a ground potential and is set by Made of conductive material. The present invention relates to a sputtering film-forming apparatus, wherein the inner shielding portion is provided with an overlapping portion overlapping so as to cover the sputtering surface of the sputtering target. The present invention is a sputtering film-forming apparatus, wherein the overlapping portion of the inner shielding portion is provided so as to cover the entire area of the outer peripheral portion of the sputtering surface of the sputtering target. The present invention is a sputtering film-forming apparatus, wherein the overlapping portion of the inner shielding portion is provided so as to overlap with a pair of opposite corners of the sputtering target formed in a rectangular shape. The present invention is a sputtering film-forming apparatus, wherein the inner shielding portion is provided with a protruding portion that protrudes in the direction of the sputtering surface of the sputtering target. The present invention is a sputtering film-forming apparatus, wherein the protruding portion of the inner shielding portion is provided so as to cover the entire area of the outer peripheral portion of the sputtering surface of the sputtering target. The present invention is a sputtering film-forming apparatus, wherein the protruding portion of the inner shielding portion is provided at a pair of opposite corners of the sputtering target formed in a rectangular shape. The present invention is a sputtering film-forming apparatus, wherein the sputtering target is formed so that its outer diameter is larger than the outer diameter of the film-forming object. [Inventive effect]
於本發明中,由於在放電時所產生並被磁鐵裝置所致之磁場而捕捉的電漿,會藉由被接近配置於靶材之外周部的周圍並被設為浮動電位的內側遮蔽部而被遮蔽,因此可阻止其到達被設置於內側遮蔽部的周圍並被設為接地電位且由導電性材料所構成之外側遮蔽部而相接觸的情形。In the present invention, the plasma captured by the magnetic field generated at the time of discharge and by the magnet device is disposed close to the inner shielding portion of the outer peripheral portion of the target and set as a floating potential. Since it is shielded, it can be prevented from reaching the outer shielding portion which is provided around the inner shielding portion, is set to the ground potential, and is made of a conductive material and comes into contact with the outer shielding portion.
其結果,若依據本發明,則由於可避免因電漿中之離子的電荷接觸到接地電位之外側遮蔽部所導致之電漿的消失,因此電漿會到達靶材之濺鍍面的外周部,藉由此,而可對靶材之濺鍍面的外周部處之非侵蝕區域的產生作抑制,故可防止起因於附著於靶材之非侵蝕區域的濺鍍粒子之剝離所導致的成膜特性之降低。As a result, according to the present invention, since the disappearance of the plasma due to the contact of the electric charge of the ions in the plasma to the shielding portion outside the ground potential can be avoided, the plasma reaches the outer peripheral portion of the sputtering surface of the target. In this way, the generation of the non-erosion region at the outer peripheral portion of the sputtering surface of the target can be suppressed, so that the formation of the sputtering particles caused by the peeling of the sputtering particles adhering to the non-erosion region of the target can be prevented. Decreased film properties.
於本發明中,於在內側遮蔽部處,設置有以覆蓋濺鍍靶材之濺鍍面的方式而重疊的重複部或是朝濺鍍靶材之濺鍍面的方向突出的突出部的情況時,由於藉由此重複部而可更確實地阻止電漿到達外側遮蔽部,因此可對起因於電漿之消失的靶材之濺鍍面的外周部處之非侵蝕區域的產生作進一步抑制而縮小非侵蝕區域,並且由於可阻止濺鍍粒子附著於靶材的非侵蝕區域,因此可進一步防止起因於濺鍍粒子之剝離的成膜特性之降低。In the present invention, when the inner shielding portion is provided with a repeating portion overlapping so as to cover the sputtering surface of the sputtering target, or a protruding portion protruding in the direction of the sputtering surface of the sputtering target In this case, since the overlapping portion can more reliably prevent the plasma from reaching the outer shielding portion, it is possible to further suppress the generation of a non-eroded region at the outer peripheral portion of the sputtering surface of the target due to the disappearance of the plasma. The non-erosion area is reduced, and since the sputtered particles can be prevented from adhering to the non-eroded area of the target, it is possible to further prevent the deterioration of the film-forming properties due to the peeling of the sputtered particles.
於此情況中,在涵蓋靶材之外周部的全區域地設置有內側遮蔽部之重複部或是突出部的情況時,由於能夠使阻止電漿到達外側遮蔽部的能力以及阻止濺鍍粒子附著於靶材之非侵蝕區域的能力提昇,因此可涵蓋靶材之外周部的全區域地而抑制起因於電漿之消失所導致的靶材之濺鍍面的非侵蝕區域之產生,而縮小非侵蝕區域,並且可涵蓋靶材之濺鍍面的外周部之全區域地來阻止濺鍍粒子附著於靶材之非侵蝕區域。In this case, when a repeating portion or a protruding portion of the inner shielding portion is provided over the entire outer peripheral portion of the target, the ability to prevent the plasma from reaching the outer shielding portion and the adhesion of sputtering particles can be prevented. The ability to improve the non-erosion area of the target material can cover the entire area of the outer periphery of the target material to suppress the generation of the non-erosion area of the sputtered surface of the target material due to the disappearance of the plasma, and to reduce the non-erosion area of the target material. The eroded area can cover the entire area of the outer periphery of the sputtering surface of the target to prevent sputtering particles from adhering to the non-eroded area of the target.
又,在內側遮蔽部之重複部被設置成與被形成為矩形狀之靶材之相對向的一對之角部重疊的情況,或是突出部被設置於被形成為矩形狀之靶材之相對向的一對之角部的情況時,例如,在電漿的軌道於靶材的一對之角部處局部性地從靶材超出的情況等中,係可對靶材之濺鍍面的外周部處之非侵蝕區域的產生,而確實地且以少量的材料來作更有效的抑制。In addition, when the overlapping portion of the inner shielding portion is provided so as to overlap with a pair of opposite corners of the target formed in a rectangular shape, or the protruding portion is provided between the target formed in a rectangular shape In the case of the opposite pair of corners, for example, in the case where the orbit of the plasma partially protrudes from the target at the pair of corners of the target, etc., the sputtering surface of the target can be The generation of non-eroded areas at the outer periphery of the radiator can be suppressed more effectively with a small amount of material.
以下,參照圖面,對本發明之實施形態作詳細說明。 第1圖(a)(b),係為對於本發明之濺鍍成膜裝置之第1例作展示者,第1圖(a),係為對於內部構成作展示之部分剖面圖,第1圖(b),係為對於重要部分之內部構成作展示之平面圖。Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. Fig. 1(a)(b) is the one showing the first example of the sputtering film forming apparatus of the present invention, Fig. 1(a) is a partial cross-sectional view showing the internal structure, the first Figure (b) is a plan view showing the internal structure of important parts.
本例之濺鍍成膜裝置1,係為磁控管濺鍍方式者,且具有如後述般地被設為接地電位的真空槽2。The sputtering film-forming
如第1圖(a)所示般地,真空槽2,係被連接於進行真空槽2內之真空排氣的真空排氣裝置3,並且於真空槽2內連接有可導入氬(Ar)氣體等之濺鍍氣體的濺鍍氣體源4。As shown in FIG. 1( a ), the
在真空槽2內,係配置有被基板保持具5所保持的基板(成膜對象物)6,並設置有以與此基板6相對向的方式來被安裝於背板8的靶材7。In the
如第1圖(a)(b)所示般地,靶材7,係以使其外徑較基板6的外徑更大的方式來形成。又,背板8的外徑係被設定成較靶材7的外徑更大。As shown in FIGS. 1( a ) and ( b ), the
此靶材7,例如,係為由金屬或金屬氧化物所構成,並露出於真空槽2內且以使被濺鍍的濺鍍面7a與基板6相對向的方式被作配置。This
背板8,係經由絕緣物8a而被安裝在真空槽2之壁面,藉由此,背板8,係對於真空槽2而被作電性絕緣。The
背板8,係被電性連接於電源裝置9,被構成為經由此背板8來對於靶材7施加特定的電力(電壓)。The
從電源裝置9來對靶材7施加之電力的種類並無特別限定,亦可為直流、交流(包含高頻、脈衝狀者)之任一種。The type of electric power applied to the
於靶材7(背板8)之外周部的周圍處,係被設置有於以下作說明的內側遮蔽部21與外側遮蔽部22。In the periphery of the outer peripheral part of the target material 7 (back plate 8), the
如第1圖(b)所示一般地,本例的內側遮蔽部21及外側遮蔽部22,係以分別包圍靶材7及背板8的方式來被作設置。As generally shown in FIG. 1( b ), the
在此,內側遮蔽部21,例如,係為由氧化鋁(Al2
O3
)等之絕緣性的材料或鈦(Ti)、鋁(Al)、不鏽鋼等之導電性的金屬材料所構成者,並被接近配置於靶材7(背板8)的外周部。Here, the
並且,此內側遮蔽部21,係在真空槽2內與其他部分絕緣,其電位係被設定成為浮動電位。In addition, the
本例之內側遮蔽部21,係被形成為矩形的框形狀(參照第1圖(b)),並被構成為,其前端部(如第1圖(a)中所示之上部),係較靶材7之濺鍍面7a更朝向基板6側突出,而使相對於真空槽2之後述的磁鐵裝置10側之內壁2a的距離較相對於濺鍍面7a的距離更大。The
另一方面,外側遮蔽部22,例如,係為由鈦(Ti)、鋁(Al)、不鏽鋼等之導電性的金屬等之材料所構成者,並被設置於內側遮蔽部21的周圍。On the other hand, the
並且,本例之外側遮蔽部22,係被形成為矩形的框形狀(參照第1圖(b)),並被構成為,其前端部(如第1圖(a)中所示之上部),係較靶材7之濺鍍面7a更朝向基板6側突出,而使相對於真空槽2之後述的磁鐵裝置10側之內壁2a的距離較相對於濺鍍面7a的距離更大。In addition, in this example, the
此外側遮蔽部22,例如,係與真空槽2一起被設定為接地電位,而發揮用以將濺鍍粒子引導至基板6之所謂接地遮蔽的作用。The
於背板8的裏面側係設置有磁鐵裝置10。
如第1圖(a)(b)及後述之第3圖(a)所示般地,磁鐵裝置10,係具有以在靶材7的濺鍍面7a上產生磁場的朝向而被作設置之中心磁鐵11、和在中心磁鐵11的周圍而被以連續的形狀來作設置之外周磁鐵12。A
中心磁鐵11,係在與背板8相平行之磁鐵固定板13上被配置成例如長方體形狀,外周磁鐵12,係在磁鐵固定板13上,從中心磁鐵11之周緣部而空出有特定距離地被形成為環狀,並以包圍中心磁鐵11的方式來被作配置。The
將中心磁鐵11之周圍作包圍之環狀的外周磁體12,並不一定是指一個無中繼點的環形狀。亦即,只要是將中心磁鐵11之周圍作包圍之形狀,則亦可為由複數個零件所構成者,且亦可為在某一部分具有直線性之形狀者。又,亦可為作了閉鎖的圓環或者是在將圓環維持為閉鎖的狀態下而使其作了變形的形狀(於本例中,係以矩形形狀者作展示)。
另外,本例之磁鐵裝置10,係以使外周磁鐵12(磁鐵固定板13)的外徑較靶材7的外徑更小的方式來設定其尺寸。The ring-shaped outer
外周磁鐵12和中心磁鐵11,係使互為相異之極性的磁極相對向地來作配置。亦即,中心磁鐵11和外周磁鐵12,係以相對於靶材7的濺鍍面7a而使互為相異之極性的磁極作朝向的方式來作配置。The outer
在磁鐵裝置10之磁鐵固定板13的背面側處,例如係配置有XY平台等之移動裝置14,磁鐵裝置10係被安裝在移動裝置14上。
移動裝置14係被連接於控制部15,並被構成為,若是藉由來自控制部15的控制訊號,而使磁鐵裝置10沿著靶材7之濺鍍面7a而在相對於中心磁鐵11之延伸的方向(長邊方向)而相正交的方向上來回移動。On the back side of the
於本例中,控制部15,係被構成為使磁鐵裝置10,在「外周磁鐵12之外周部全體均進入至較靶材7之濺鍍面7a的外周部更內側處的位置」和「外周磁鐵12之外周部的一部分(於本例中係磁鐵裝置10之移動方向側的部分121
及122
)超出到靶材7之濺鍍面7a的外周部之外側的位置」,此兩者的位置之間來回移動(參照第1圖(a))。In this example, the
並且,在與上述之內側遮蔽部21的關係中,磁鐵裝置10,係被構成為在「外周磁鐵12之外周部全體均相對於包圍靶材7之濺鍍面7a的周圍之內側遮蔽部21的內周部而進入至內側的位置」和「外周磁鐵12之外周部的一部分(於本例中係磁鐵裝置10之移動方向側的部分121
及122
)相對於內側遮蔽部21之內周部而超出到外周部側的位置」,此兩者的位置之間移動。In addition, in relation to the above-mentioned
於具有這種構成之本例中,於在基板6上藉由濺鍍來進行成膜的情況時,係將真空槽2內進行真空排氣,並且於真空槽2內導入濺鍍氣體,從電源裝置9經由背板8來對靶材7施加特定的負電壓。In this example having such a configuration, when a film is formed on the
並且,如上述般地,使磁鐵裝置10,在「外周磁鐵12之外周部全體均相對於包圍靶材7之濺鍍面7a的周圍之內側遮蔽部21的內周部而進入至內側的位置」和「外周磁鐵12之外周部的一部分相對於內側遮蔽部21之內周部而超出到外周部側的位置」,此兩者的位置之間來回移動。In addition, as described above, the
藉由以上的動作,而在靶材7與基板6之間產生放電,靶材7上的電漿氣體係被電離而電漿化。
存在於此電漿中之濺鍍氣體的離子,會被藉由磁鐵裝置10所產生的磁場所捕捉。By the above operation, discharge is generated between the
於本例中,係對靶材7施加負電壓,濺鍍氣體之離子係與負電位之靶材7的濺鍍面7a相碰撞,並將靶材材料的粒子(濺鍍粒子)彈飛。
此濺鍍粒子會到達上述之基板6的表面並作附著,而在基板6形成靶材材料之膜。In this example, a negative voltage is applied to the
另一方面,從靶材7的濺鍍面7a所彈飛的濺鍍粒子之一部分,係再度附著在靶材7的濺鍍面7a上。On the other hand, a part of the sputtering particles bounced from the sputtering
於以上所述之本例的濺鍍成膜裝置1中,係由於在放電時所產生並被磁鐵裝置10所致之磁場而捕捉的濺鍍氣體之電漿,會藉由被接近配置於靶材7之外周部的周圍並被設為浮動電位的內側遮蔽部21而被遮蔽,因此可阻止其到達被設置於內側遮蔽部21的周圍並被設為接地電位且由導電性材料所構成之外側遮蔽部22而相接觸的情形。In the sputtering film-forming
其結果,若依據本例,則由於可避免因電漿中之離子的電荷接觸到接地電位之外側遮蔽部22所導致之電漿的消失,因此電漿會到達靶材7之濺鍍面7a的外周部,藉由此,而可對靶材7之濺鍍面7a的外周部處之非侵蝕區域的產生作抑制,故可防止起因於附著於靶材7之非侵蝕區域的濺鍍粒子之剝離所導致的成膜特性之降低。As a result, according to this example, since the disappearance of the plasma caused by the electric charge of the ions in the plasma coming into contact with the ground potential
第2圖(a)(b),係為對於本發明之濺鍍成膜裝置之第2例作展示者,第2圖(a),係為對於內部構成作展示之部分剖面圖,第2圖(b)係為對於重要部分之內部構成作展示之平面圖。以下,針對與上述第1例相對應之部分,係附加相同之符號,並省略其之詳細說明。Fig. 2(a)(b) is for showing the second example of the sputtering film forming apparatus of the present invention, Fig. 2(a) is a partial cross-sectional view showing the internal structure, and Fig. 2 Figure (b) is a plan view showing the internal structure of important parts. Hereinafter, the parts corresponding to those of the first example described above are assigned the same reference numerals, and detailed descriptions thereof will be omitted.
如第2圖(a)(b)所示般地,本例之濺鍍成膜裝置1A,係具有內側遮蔽部21A,該內側遮蔽部21A,係設置有以覆蓋靶材7之濺鍍面7a的方式而重疊的重複部21a。As shown in FIGS. 2( a ) and ( b ), the sputtering
在此,內側遮蔽部21A之重複部21a,係被形成為相對於靶材之濺鍍面7a而具有些許間隙的矩形框狀,並被構成為使其開口部的緣部21b具有較靶材7的外徑稍微小的內徑。Here, the overlapping
而,藉由此,本例之內側遮蔽部21A的重複部21a,係被形成為將靶材7之濺鍍面7a的外周部涵蓋全區域地覆蓋。In this way, the overlapping
若依據具有這種構成之本例,則由於可藉由涵蓋靶材7之外周部的全區域地被作設置的內側遮蔽部21A之重複部21a,來涵蓋其內周部之全區域地確實阻止電漿到達外側遮蔽部22,因此可涵蓋靶材7之外周部的全區域地而抑制起因於電漿之消失所導致的靶材7之濺鍍面7a的外周部處之非侵蝕區域的產生,而縮小非侵蝕區域。又,由於可涵蓋靶材7之濺鍍面7a的外周部之全區域地而阻止濺鍍粒子附著於靶材7之非侵蝕區域,因此可進一步防止起因於濺鍍粒子之剝離所導致的成膜特性之降低。According to the present example having such a configuration, since the overlapping
關於其他之作用效果,由於係與上述之例相同,因此,係省略其之詳細說明。Since other functions and effects are the same as those in the above-mentioned example, the detailed description thereof will be omitted.
第3圖(a)(b),係為用以對於本發明之濺鍍成膜裝置的第3例之目的作說明之圖。 又,第4圖,係為對於同濺鍍成膜裝置之第3例的重要部分之內部構成作展示之平面圖。以下,針對與上述第1例、第2例相對應之部分,係附加相同之符號,並省略其之詳細說明。Fig. 3(a)(b) is a diagram for explaining the purpose of the third example of the sputtering film-forming apparatus of the present invention. In addition, FIG. 4 is a plan view showing the internal structure of an important part of the third example of the same sputtering film-forming apparatus. Hereinafter, the parts corresponding to the above-mentioned first and second examples are assigned the same reference numerals, and detailed descriptions thereof will be omitted.
於此種磁控管濺鍍裝置中,作為磁鐵裝置,係如第3圖(a)所示之上述之磁鐵裝置10般地,在使用組合有長方體狀之中心磁鐵11與框狀之外周磁鐵12的情況時,存在有以下的課題。In such a magnetron sputtering apparatus, as the magnet apparatus, as in the above-mentioned
亦即,若使用這種磁鐵裝置10來進行濺鍍,則藉由濺鍍時之放電所產生的電漿中之離子,會被藉由磁鐵裝置10所產生的磁場軌道所捕捉,而描繪出與磁鐵裝置10相對應的軌道地而運動。
於此情況中,由於磁鐵裝置10係被形成為矩形狀,因此所產生的磁場軌道也會變成近似矩形的形狀。That is, when sputtering is performed by using the
但,於實際的裝置中,係如第3圖(a)(b)所示般地,藉由放電所產生的電漿30中之離子,在從磁鐵裝置10之例如外周磁鐵12的短邊12s側朝長邊12l側改變方向來移動時,起因於電漿30之電漿密度變高等的理由,會變成沿著在「離子從磁鐵裝置10之外周磁鐵12的短邊12s側朝長邊12l側而改變方向並移動之角部12c、12d(離子從相對應的靶材7之短邊7s側朝長邊7l側而改變方向並移動的角部7c、7d)處所產生之超出到電漿30的外側之形狀的部分31、32」來進行運動。However, in an actual device, as shown in FIGS. 3 (a) and (b), the ions in the
其結果,若是離子沿著這種超出到電漿30的外側之形狀的部分31、32來運動,則若是與例如接地遮蔽等之接地電位的導電構件相接觸,則電漿30中之離子的電荷會通過導電構件來流動到接地部位,而導致電漿30的一部分消失,而存在有在靶材7的濺鍍面7a(參照第1圖a)中殘留有未被濺鍍的非侵蝕區域之課題。As a result, if the ions move along the
第4圖,係為對於用以解決上述之課題的手段作展示者。
如第4圖所示般地,於第3例之濺鍍成膜裝置1B中,係被構成為,於內側遮蔽部21B,以與被形成為矩形狀之靶材7之相對向的一對之角部7c、7d重疊的方式來設置重複部21c、21d。FIG. 4 shows the means for solving the above-mentioned problems.
As shown in FIG. 4 , in the sputtering
尤其是在本例的情況中,係於內側遮蔽部21B中,以與和上述之突出到電漿30之外側的形狀之部分31、32相對應的靶材7之相對向的一對角部7c、7d(亦即是和第3圖(a)(b)所示之離子從磁鐵裝置10的外周磁鐵12之短邊12s側朝長邊12l側而改變方向並移動的角部12c、12d分別相對應的靶材7之角部7c、7d)重疊的方式,來分別設置有重複部21c、21d。In particular, in the case of this example, in the
若依據具有這種構成之本例,則能夠對在靶材7之濺鍍面7a的外周部處產生非侵蝕區域一事而確實地且以少量材料來作更有效地抑制。According to this example having such a configuration, the occurrence of a non-eroded region in the outer peripheral portion of the sputtering
第5圖(a)(b),係為對於本發明之濺鍍成膜裝置之第4例作展示者,第5圖(a),係為對於內部構成作展示之部分剖面圖,第5圖(b)係為對於重要部分之內部構成作展示之平面圖。Fig. 5(a)(b) shows the fourth example of the sputtering film forming apparatus of the present invention, Fig. 5(a) is a partial cross-sectional view showing the internal structure, and Fig. 5 Figure (b) is a plan view showing the internal structure of important parts.
又,第6圖,係為對於本發明之濺鍍成膜裝置之第5例之內部構成作展示之平面圖。以下,針對與上述第1例相對應之部分,係附加相同之符號,並省略其之詳細說明。In addition, FIG. 6 is a plan view showing the internal structure of the fifth example of the sputter deposition apparatus of the present invention. Hereinafter, the parts corresponding to those of the first example described above are assigned the same reference numerals, and detailed descriptions thereof will be omitted.
如第5圖(a)(b)所示般地,本例之濺鍍成膜裝置1C,係具有內側遮蔽部23,該內側遮蔽部23,係設置有往靶材7之濺鍍面7a的方向突出的突出部23a。As shown in FIGS. 5( a ) and ( b ), the sputtering
在此,內側遮蔽部23之突出部23a,係被形成為相對於靶材7之濺鍍面7a而具有些許間隙的矩形框狀,並被構成為使其開口部的緣部23b具有較靶材7的外徑稍微大的內徑。Here, the protruding
亦即,本例之內側遮蔽部23的突出部23a,係與上述之第2例相異,其係以並不與靶材7之濺鍍面7a重疊的方式來被作設置。That is, the protruding
於具有這種構成之本例中,由於可藉由涵蓋靶材7之外周部的全區域地而被作設置的內側遮蔽部23之突出部23a,而涵蓋其內周部之全區域地確實阻止電漿到達外側遮蔽部22,因此可涵蓋靶材7之外周部的全區域地而抑制起因於電漿之消失所導致的靶材7之濺鍍面7a的外周部處之非侵蝕區域的產生,而縮小非侵蝕區域。In this example having such a configuration, since the
另一方面,如第6圖所示般地,於第5例之濺鍍成膜裝置1D中,係被構成為,於內側遮蔽部23,在被形成為矩形狀且與上述之朝電漿30的外側突出的形狀之部分31、32相對應的靶材7之相對向的一對之角部7c、7d的附近,設置朝靶材7之濺鍍面7a的方向突出的突出部23c、23d。
於此情況中,突出部23c、23d,係以並不與靶材7之濺鍍面7a重疊的方式來被作設置。On the other hand, as shown in FIG. 6 , in the sputtering
若依據具有這種構成之第4例及第5例,則能夠對在靶材7之濺鍍面7a的外周部處產生非侵蝕區域一事而確實地且以少量材料來作更有效地抑制。According to the fourth and fifth examples having such a configuration, the occurrence of a non-eroded region in the outer peripheral portion of the sputtering
關於其他之作用效果,由於係與上述之例相同,因此,係省略其之詳細說明。Since other functions and effects are the same as those in the above-mentioned example, the detailed description thereof will be omitted.
另外,本發明,係並不被限定於上述實施形態,而可進行各種之變更。例如,在上述實施形態中,雖係以使用了一個磁鐵裝置的情況為例來作了說明,但是,本發明係並不被限定於此,而亦可如以下所說明般地,適用在將複數個磁鐵裝置排列作配置的情況中。In addition, this invention is not limited to the said embodiment, Various changes are possible. For example, in the above-mentioned embodiment, the case where one magnet device is used has been described as an example. However, the present invention is not limited to this, and can be applied to other applications as described below. In the case where a plurality of magnet devices are arranged in an arrangement.
第7圖,係為對於使用有複數個磁鐵裝置之濺鍍成膜裝置之例作展示的部分剖面圖,第8圖,係為對於該使用有複數個磁鐵裝置之濺鍍成膜裝置之例的重要部分之內部構成作展示之平面圖。以下,針對與上述例相對應之部分,係附加相同之符號,並省略其之詳細說明。FIG. 7 is a partial cross-sectional view showing an example of a sputtering film-forming apparatus using a plurality of magnet devices, and FIG. 8 is an example of a sputtering film-forming apparatus using a plurality of magnet devices. The internal composition of the important part of the plan is shown as a floor plan. Hereinafter, the parts corresponding to the above-mentioned examples are assigned the same reference numerals, and detailed descriptions thereof will be omitted.
如第7圖及第8圖所示般地,本例之濺鍍成膜裝置1E,係為具有和第1圖(a)(b)所示之第1例的濺鍍成膜裝置1相同的被設置有內側遮蔽部21與外側遮蔽部22的真空槽2者,於此真空槽2內的背板8之裏面側設置有磁鐵裝置10a。As shown in Figs. 7 and 8, the sputtering
本例中之磁鐵裝置10a,係於上述之磁鐵固定板13上設置有複數個(於本例中為5個)之磁鐵手段10A~10E。In the
該等磁鐵手段10A~10E,係具有相同的構成,且分別在與背板8相平行之細長的板狀之磁鐵固定部16a上,具備有以在靶材7的濺鍍面7a上產生磁場的朝向而被作設置之中心磁鐵11a、和在中心磁鐵11a的周圍而被以連續的形狀來作設置之外周磁鐵12a。These magnet means 10A to 10E have the same configuration, and are provided with a
中心磁鐵11a,係被配置成朝與磁石固定部16a相同方向作延伸之細長的例如長方體形狀,外周磁鐵12a,係被形成為於磁鐵固定部16a上朝與磁鐵固定部16a相同方向作延伸之細長的環狀,且被配置成相對於中心磁鐵11a之周緣部而空出特定距離來包圍中心磁鐵11a。The
於各磁鐵手段10A~10E中,包圍中心磁鐵11a之周圍的環狀之外周磁鐵12a,係與上述之磁鐵裝置10同樣地,並不一定是指一個無中繼點的環形狀。亦即,只要是將中心磁鐵11a之周圍作包圍之形狀,則亦可為由複數個零件所構成者,且亦可為在某一部分而具有直線性之形狀者。又,亦可為作了閉鎖的圓環或者是在將圓環維持為閉鎖的狀態下而使其作了變形的形狀(於本例中,係以矩形形狀者作展示)。In each of the
各磁鐵手段10A~10E之外周磁鐵12a與中心磁鐵11a,係使互為相異之極性的磁極相對向地作配置,藉由此,中心磁鐵11a與外周磁鐵12a,係以相對於靶材7之濺鍍面7a而使互為相異之極性的磁極作朝向的方式來構成。In each of the magnet means 10A to 10E, the outer peripheral magnets 12 a and the
並且,具有這種構成之磁鐵手段10A~10E,係以使相鄰接之外周磁鐵12a的長邊方向之側部相對向的方式來朝向同一方向地作接近配置。And the magnet means 10A-10E which have such a structure are arrange|positioned close to the same direction so that the side part of the longitudinal direction of the adjacent outer periphery magnet 12a may oppose.
於本例之磁鐵裝置10a中,係與上述第1例的情況同樣地,磁鐵固定板13被安裝於上述之移動裝置14,並構成為,藉由來自控制部15的控制訊號,使磁鐵裝置10a沿著靶材7之濺鍍面7a而在相對於各磁鐵手段10A~10E之延伸的方向(長邊方向)而相正交的方向上來回移動。In the
並且,於本例中,在磁鐵裝置10a之磁鐵手段10A~10E中,係以使位置於磁鐵裝置10a之移動方向的兩側之磁鐵手段10A及磁鐵手段10E處之外周磁鐵12a之移動方向側的部分12a1
及12a2
的緣部間之距離成為較針對該移動方向之靶材7的該移動方向之緣部間的長度而更小的方式,來設定各磁鐵手段10A~10E的尺寸及配置位置(參照第8圖)。In addition, in this example, among the magnet means 10A to 10E of the
另外,於本例中,針對磁鐵裝置10a之各磁鐵手段10A~10E的外周磁鐵12a之各者,係以使相對於磁鐵裝置10a之移動方向而相正交的方向之緣部間的距離會成為較靶材7的相對於該移動方向而相正交之緣部間的長度而更小的方式,來設定各磁鐵手段10A~10E的尺寸及配置位置。In addition, in this example, with respect to each of the outer peripheral magnets 12a of the magnet means 10A to 10E of the
並且,係構成為使磁鐵裝置10a,在「外周磁鐵12a之外周部全體均進入至較靶材7之濺鍍面7a的外周更內側處的位置」和「外周磁鐵12a之外周部的一部分(於本例中係磁鐵裝置10a之移動方向側的部分12a1
及12a2
)超出到靶材7之濺鍍面7a的外周部之外側的位置」,此兩者的位置之間來回移動。In addition, the
另一方面,在與上述之內側遮蔽部21的關係中,磁鐵裝置10a,係被構成為在「外周磁鐵12a之外周部全體均相對於包圍靶材7之濺鍍面7a的周圍之內側遮蔽部21的內周部而進入至內側的位置」和「外周磁鐵12a之外周部的一部分(於本例中係移動方向側的部分12a1
及12a2
)相對於內側遮蔽部21之內周部而超出到外周部側的位置」,此兩者的位置之間移動。On the other hand, in relation to the above-described
於以上所述之本例的濺鍍成膜裝置1E中,係由於在放電時所產生並被磁鐵裝置10a之各磁鐵手段10A~10E所致之磁場而捕捉的濺鍍氣體之電漿,會藉由被接近配置於靶材7之外周部的周圍並被設為浮動電位的內側遮蔽部21而被遮蔽,因此可阻止其到達被設置於內側遮蔽部21的周圍並被設為接地電位且由導電性材料所構成之外側遮蔽部22並相接觸的情形。In the sputtering film-forming
其結果,若依據本例,則與上述之第1~第4例的情況同樣地,由於可避免因電漿中之離子的電荷接觸到接地電位之外側遮蔽部22所導致之電漿的消失,因此電漿會到達靶材7之濺鍍面7a的外周部,藉由此,而可對靶材7之濺鍍面7a的外周部處之非侵蝕區域的產生作抑制,故可防止起因於附著於靶材7之非侵蝕區域的濺鍍粒子之剝離所導致的成膜特性之降低。As a result, according to this example, as in the cases of the first to fourth examples described above, it is possible to avoid the disappearance of the plasma caused by the electric charge of the ions in the plasma coming into contact with the shielding
進而,於本例中,由於是使用具有複數個磁鐵手段10A~10E的磁鐵裝置10a,因此可緩和對於磁場的電力集中,藉由此,而具有可增大投入電力的效果。Furthermore, in this example, since the
另外,於上述之例中,雖係以設置具有5個磁鐵手段10A~10E之磁鐵裝置10a的情況為例來作了說明,但是,本發明係並不被限定於此,而亦可適用在具有6個以上之磁鐵手段的情況中。In addition, in the above-mentioned example, the case where the
又,本例之磁鐵裝置10a,係亦可適用於上述之第2例~第5例的濺鍍成膜裝置1A~1D中。In addition, the
尤其,在使用本例之磁鐵裝置10a來進行濺鍍的情況中,當電漿中的離子,沿著在「離子從磁鐵裝置10a之各磁鐵手段10A~10E的外周磁鐵12a之短邊側朝長邊側而改變方向並移動之相對向的角部處所產生之朝電漿的外側突出之形狀的部分」來進行運動時,與上述之第3例的濺鍍成膜裝置1B以及第5例之濺鍍成膜裝置1D作組合一事係為有效。In particular, in the case of sputtering using the
亦即,此係因為,於本例之磁鐵裝置10a中,在離子相對於各磁鐵手段10A~10E而從短邊側朝長邊側來改變方向並移動之相對向的角部處,雖然離子是沿著如上述般之朝電漿的外側突出之形狀的部分來運動,但是,此電漿中的離子,係由於即使是針對磁鐵裝置10a之全體,也是如例如第8圖所示般地,在離子從磁鐵裝置10a之移動方向兩端的磁鐵手段10A、10E之外周磁鐵12a的短邊側朝長邊側而改變方向並移動之相對向的角部12c、12d處,係沿著朝電漿的外側突出的形狀之部分來進行運動之故。That is, this is because, in the
1:濺鍍成膜裝置
2:真空槽
6:基板(成膜對象物)
7:濺鍍靶材
7a:濺鍍面
7c、7d:角部
7l:長邊
7s:短邊
8:背板
10:磁鐵裝置
11:中心磁鐵
12:外周磁鐵
21:內側遮蔽部
22:外側遮蔽部1: Sputtering film forming device
2: Vacuum tank
6: Substrate (object for film formation)
7: Sputtering
[第1圖] (a)、(b):係為對於本發明之濺鍍成膜裝置之第1例作展示者,第1圖(a),係為對於內部構成作展示之部分剖面圖,第1圖(b)係為對於重要部分之內部構成作展示之平面圖 [第2圖] (a)、(b):係為對於本發明之濺鍍成膜裝置之第2例作展示者,第2圖(a),係為對於內部構成作展示之部分剖面圖,第2圖(b)係為對於重要部分之內部構成作展示之平面圖 [第3圖] (a)、(b):係為用以對於本發明之濺鍍成膜裝置的第3例之目的作說明之圖 [第4圖] 係為對於該濺鍍成膜裝置之第3例的重要部分之內部構成作展示之平面圖 [第5圖] (a)、(b):係為對於本發明之濺鍍成膜裝置之第4例作展示者,第5圖(a),係為對於內部構成作展示之部分剖面圖,第5圖(b)係為對於重要部分之內部構成作展示之平面圖 [第6圖] 係為對於本發明之濺鍍成膜裝置之第5例之內部構成作展示之平面圖 [第7圖] 係為對於使用有複數個磁鐵裝置之濺鍍成膜裝置之例作展示之部分剖面圖 [第8圖] 係為對於該使用有複數個磁鐵裝置之濺鍍成膜裝置之例的重要部分之內部構成作展示之平面圖[FIG. 1] (a), (b): It shows the first example of the sputtering film forming apparatus of the present invention, and FIG. 1(a) is a partial cross-sectional view showing the internal structure. , Figure 1(b) is a plan view showing the internal structure of important parts [FIG. 2] (a), (b): It shows the second example of the sputtering film forming apparatus of the present invention, and FIG. 2(a) is a partial cross-sectional view showing the internal structure , Figure 2(b) is a plan view showing the internal structure of important parts [FIG. 3] (a), (b): It is a drawing for explaining the purpose of the third example of the sputtering film-forming apparatus of the present invention [FIG. 4] It is a plan view showing the internal structure of important parts of the third example of the sputtering film forming apparatus [FIG. 5] (a), (b): It shows the fourth example of the sputtering film forming apparatus of the present invention, and FIG. 5(a) is a partial cross-sectional view showing the internal structure. , Figure 5(b) is a plan view showing the internal structure of important parts [FIG. 6] It is a plan view showing the internal structure of the fifth example of the sputtering film-forming apparatus of the present invention [FIG. 7] It is a partial cross-sectional view showing an example of a sputtering film forming apparatus using a plurality of magnet devices [FIG. 8] It is a plan view showing the internal structure of an important part of the example of the sputter deposition apparatus using a plurality of magnet devices
1:濺鍍成膜裝置 1: Sputtering film forming device
2:真空槽 2: Vacuum tank
2a:內壁 2a: inner wall
3:真空排氣裝置 3: Vacuum exhaust device
4:濺鍍氣體源 4: Sputtering gas source
5:基板保持具 5: Substrate holder
6:基板(成膜對象物) 6: Substrate (object for film formation)
7:濺鍍靶材 7: Sputtering target
7a:濺鍍面 7a: Sputtering surface
8:背板 8: Backplane
8a:絕緣物 8a: Insulation
9:電源裝置 9: Power supply unit
10:磁鐵裝置 10: Magnet device
11:中心磁鐵 11: Center magnet
12:外周磁鐵 12: Peripheral magnet
121、122:移動方向側的部分 12 1 , 12 2 : Portions on the moving direction side
13:磁鐵固定板 13: Magnet fixing plate
14:移動裝置 14: Mobile Devices
15:控制部 15: Control Department
21:內側遮蔽部 21: inner shield
22:外側遮蔽部 22: Outer shield
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US5736021A (en) * | 1996-07-10 | 1998-04-07 | Applied Materials, Inc. | Electrically floating shield in a plasma reactor |
US20080110747A1 (en) * | 1999-10-08 | 2008-05-15 | Applied Materials, Inc. | Self-ionized and inductively-coupled plasma for sputtering and resputtering |
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