TWI760950B - Pallet applied to a thin film deposition device - Google Patents

Pallet applied to a thin film deposition device Download PDF

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TWI760950B
TWI760950B TW109142231A TW109142231A TWI760950B TW I760950 B TWI760950 B TW I760950B TW 109142231 A TW109142231 A TW 109142231A TW 109142231 A TW109142231 A TW 109142231A TW I760950 B TWI760950 B TW I760950B
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Taiwan
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tray
diameter
slots
wafer
hole
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TW109142231A
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Chinese (zh)
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TW202125696A (en
Inventor
馬迎功
董博宇
郭冰亮
武學偉
武樹波
趙晨光
翟洪濤
楊依龍
楊健
甄梓楊
宋玲彦
孫魯陽
李新穎
劉玉傑
許文學
張璐
崔亞欣
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大陸商北京北方華創微電子裝備有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/687Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
    • H01L21/68714Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
    • H01L21/68757Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by a coating or a hardness or a material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021Reactive sputtering or evaporation
    • C23C14/0036Reactive sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0617AIII BV compounds, where A is Al, Ga, In or Tl and B is N, P, As, Sb or Bi
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/687Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
    • H01L21/68714Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
    • H01L21/68735Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by edge profile or support profile
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/687Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
    • H01L21/68714Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
    • H01L21/68771Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by supporting more than one semiconductor substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/687Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
    • H01L21/68714Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
    • H01L21/68785Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by the mechanical construction of the susceptor, stage or support

Abstract

A pallet applied to a thin film deposition device, comprising: a first pallet body, a second pallet body and a connecting component. The first pallet body includes a plurality of through holes for carrying wafer, and a plurality of first slots arranged on a lower surface of the first pallet body. A size of the second pallet body corresponds to a size of the first pallet body. A plurality of second slots is arranged on an upper surface of the second pallet body. The shape and position of the second slots correspond to the shape and position of the first slots. The connecting component is located between the first slots and the second slots one by one, and used to provide the fixed connection between the first pallet body and the second pallet body. The first pallet body is implemented by a first material, and the second pallet body is implemented by a second material, The relative deviation between s thermal expansion coefficient of the first material and s thermal expansion coefficient of the film to be deposited is less than 20%; the volume resistivity of the first material is greater than that of the second material.

Description

應用於薄膜沉積裝置的托盤Trays for thin film deposition equipment

本發明涉及半導體領域,具體來說,是有關於一種應用於薄膜沉積裝置的托盤。The present invention relates to the field of semiconductors, in particular, to a tray applied to a thin film deposition device.

現有半導體技術中,廣泛地對晶圓進行氮化鋁薄膜沉積以形成壓電層或緩衝層。然而,在薄膜沉積的過程中,一般使用單一材質(如碳化矽SiC)托盤承載主要以藍寶石(Al2 O3 )材質製成的晶圓。由於各個材料間的熱膨脹係數不同,將導致氮化鋁薄膜在高溫生長過程存在一定的應力,而此應力在高溫的外延爐中顯現更明顯,放大了氮化鋁薄膜成形過程中的應力影響,從而導致了外延均一性的差異,影響氮化鋁薄膜的品質;另外,碳化矽在高溫(如攝氏500度)時已從絕緣體轉變為非絕緣體,所以在氮化鋁薄膜沉積過程中,電場和磁場的雙重影響導致離化後的離子(原子)到達晶圓的能量減小,從而沉積在晶圓上的氮化鋁薄膜的結晶品質變差。In the current semiconductor technology, aluminum nitride thin film deposition is widely performed on wafers to form piezoelectric layers or buffer layers. However, in the thin film deposition process, a single material (eg, silicon carbide SiC) tray is generally used to carry wafers made mainly of sapphire (Al 2 O 3 ). Due to the different thermal expansion coefficients between materials, there will be a certain stress in the aluminum nitride film during the high temperature growth process, and this stress is more obvious in the high temperature epitaxial furnace, which amplifies the stress effect during the forming process of the aluminum nitride film. This leads to the difference in epitaxial uniformity, which affects the quality of the aluminum nitride film; in addition, silicon carbide has changed from an insulator to a non-insulator at high temperature (such as 500 degrees Celsius), so during the deposition process of the aluminum nitride film, the electric field and the The dual effects of the magnetic field lead to a decrease in the energy of the ionized ions (atoms) reaching the wafer, resulting in poorer crystalline quality of the aluminum nitride film deposited on the wafer.

本發明的目的之一在於提供一種應用於薄膜沉積裝置的托盤來解決背景技術中的問題。例如,在薄膜沉積的過程中降低氮化鋁薄膜的應力,以及,降低由於托盤轉變為非絕緣體後電場變化帶來的影響,借此提高氮化鋁薄膜的品質。One of the objectives of the present invention is to provide a tray applied to a thin film deposition apparatus to solve the problems in the background art. For example, reducing the stress of the aluminum nitride film during film deposition and reducing the influence of electric field changes after the tray is transformed into a non-insulator, thereby improving the quality of the aluminum nitride film.

依據本發明的一實施例,揭露一種應用於薄膜沉積裝置的托盤,該托盤包括:一第一盤體、一第二盤體以及一連接組件。該第一盤體包括用於承載晶圓的多個通孔,且該第一盤體的一下表面設置有多個第一槽位。該第二盤體的尺寸與該第一盤體的尺寸相對應,且該第二盤體的一上表面設置有多個第二槽位,其中,該多個第二槽位的形狀及位置與該多個第一槽位的形狀及位置相對應。該連接組件位於一一對應的該第一槽位及該第二槽位之間,用於實現所述第一盤體和第二盤體的固定連接。該第一盤體採用一第一材質製備,該第二盤體採用一第二材質製備,且該第一材質的熱膨脹係數與待沉積薄膜的熱膨脹係數的相對偏差值小於20%,以減少對該晶圓沉積薄膜時的應力影響;該第一材質的體積電阻率大於該第二材質的體積電阻率,以使在對該晶圓沉積該薄膜時該第一盤體形成一緣體。According to an embodiment of the present invention, a tray used in a thin film deposition device is disclosed. The tray includes: a first tray body, a second tray body and a connecting assembly. The first tray body includes a plurality of through holes for carrying wafers, and a lower surface of the first tray body is provided with a plurality of first slots. The size of the second disk body corresponds to the size of the first disk body, and a plurality of second grooves are disposed on an upper surface of the second disk body, wherein the shapes and positions of the plurality of second grooves Corresponding to the shapes and positions of the plurality of first slots. The connecting assembly is located between the first slot and the second slot in one-to-one correspondence, and is used to realize the fixed connection of the first disc body and the second disc body. The first disk is made of a first material, the second disk is made of a second material, and the relative deviation between the thermal expansion coefficient of the first material and the thermal expansion coefficient of the film to be deposited is less than 20%, so as to reduce the impact on The stress when depositing the thin film on the wafer is affected; the volume resistivity of the first material is greater than the volume resistivity of the second material, so that the first disk body forms an edge when the thin film is deposited on the wafer.

依據本發明的一實施例,該第二材質的熱傳導係數大於該第一材質的熱傳導係數。According to an embodiment of the present invention, the thermal conductivity of the second material is greater than the thermal conductivity of the first material.

依據本發明的一實施例,該第一盤體的該上表面在鄰近該通孔處設置有一倒角結構。According to an embodiment of the present invention, a chamfered structure is disposed on the upper surface of the first disk body adjacent to the through hole.

依據本發明的一實施例,該倒角結構與該第一盤體的該上表面之間的夾角的範圍為30度至60度,該倒角結構的直角邊長度範圍為0.3毫米至2毫米。According to an embodiment of the present invention, the included angle between the chamfered structure and the upper surface of the first disk body ranges from 30 degrees to 60 degrees, and the length of the right-angled side of the chamfered structure ranges from 0.3 mm to 2 mm. .

依據本發明的一實施例,該倒角結構與該第一盤體的該上表面之間的夾角為45度,該倒角結構的直角邊長度為0.5毫米。According to an embodiment of the present invention, the angle between the chamfered structure and the upper surface of the first disk body is 45 degrees, and the length of the right-angled side of the chamfered structure is 0.5 mm.

依據本發明的一實施例,該第一盤體的高度範圍為2毫米至4毫米。According to an embodiment of the present invention, the height of the first disk body ranges from 2 mm to 4 mm.

依據本發明的一實施例,該通孔具有一上部及一下部,該上部的直徑大於該下部的直徑。According to an embodiment of the present invention, the through hole has an upper portion and a lower portion, and the diameter of the upper portion is larger than the diameter of the lower portion.

依據本發明的一實施例,該上部的直徑範圍為100.5毫米至102毫米,該上部的縱深範圍為1毫米至3毫米。According to an embodiment of the present invention, the diameter of the upper portion ranges from 100.5 mm to 102 mm, and the depth of the upper portion ranges from 1 mm to 3 mm.

依據本發明的一實施例,該下部的直徑範圍為80毫米至98毫米,該下部的縱深範圍為1毫米至3毫米。According to an embodiment of the present invention, the diameter of the lower portion ranges from 80 mm to 98 mm, and the depth of the lower portion ranges from 1 mm to 3 mm.

依據本發明的一實施例,該連接組件的高度範圍為2毫米至3毫米。According to an embodiment of the present invention, the height of the connecting element ranges from 2 mm to 3 mm.

依據本發明的一實施例,該第一材質為氮化鋁,該第二材質為碳化矽。According to an embodiment of the present invention, the first material is aluminum nitride, and the second material is silicon carbide.

本發明所提出的托盤採用複合結構,提高了對晶圓進行氮化鋁薄膜沉積的製程穩定性,詳細來說,本發明所提出的托盤在製程中能有效地減小氮化鋁薄膜形成時的應力,並且,減小了電場和磁場變化對形成氮化鋁薄膜的影響,進而改善氮化鋁薄膜的結晶品質。The tray proposed by the present invention adopts a composite structure, which improves the process stability of the deposition of the aluminum nitride film on the wafer. In addition, the influence of electric and magnetic field changes on the formation of the aluminum nitride film is reduced, thereby improving the crystal quality of the aluminum nitride film.

以下揭露提供用於實施本揭露之不同構件之許多不同實施例或實例。下文描述組件及配置之特定實例以簡化本揭露。當然,此等僅為實例且非意欲限制。舉例而言,在以下描述中之一第一構件形成於一第二構件上方或上可包含其中該第一構件及該第二構件經形成為直接接觸之實施例,且亦可包含其中額外構件可形成在該第一構件與該第二構件之間,使得該第一構件及該第二構件可不直接接觸之實施例。另外,本揭露可在各個實例中重複參考數字及/或字母。此重複出於簡化及清楚之目的且本身不指示所論述之各個實施例及/或組態之間的關係。The following disclosure provides many different embodiments or examples of different components for implementing the present disclosure. Specific examples of components and configurations are described below to simplify the present disclosure. Of course, these are only examples and are not intended to be limiting. For example, in the following description a first member is formed over or on a second member may include embodiments in which the first member and the second member are formed in direct contact, and may also include additional members An embodiment may be formed between the first member and the second member so that the first member and the second member may not be in direct contact. Additionally, the present disclosure may repeat reference numerals and/or letters in various instances. This repetition is for the purpose of simplicity and clarity and does not in itself indicate a relationship between the various embodiments and/or configurations discussed.

此外,為便於描述,諸如「下面」、「下方」、「下」、「上方」、「上」及類似者之空間相對術語可在本文中用於描述一個元件或構件與另一(些)元件或構件之關係,如圖中圖解說明。空間相對術語意欲涵蓋除在圖中描繪之定向以外之使用或操作中之裝置之不同定向。設備可以其他方式定向(旋轉90度或按其他定向)且因此可同樣解釋本文中使用之空間相對描述詞。Furthermore, for ease of description, spatially relative terms such as "below," "below," "under," "above," "over," and the like may be used herein to describe one element or component and another(s) The relationship of elements or components, as illustrated in the figure. Spatially relative terms are intended to encompass different orientations of the device in use or operation other than the orientation depicted in the figures. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and thus the spatially relative descriptors used herein may likewise be interpreted.

儘管陳述本揭露之寬泛範疇之數值範圍及參數係近似值,然儘可能精確地報告特定實例中陳述之數值。然而,任何數值固有地含有必然由於見於各自測試量測中之標準偏差所致之某些誤差。再者,如本文中使用,術語「大約」通常意謂在一給定值或範圍之10%、5%、1%或0.5%內。替代地,術語「大約」意謂在由此項技術之一般技術者考量時處於平均值之一可接受標準誤差內。除在操作/工作實例中以外,或除非以其他方式明確指定,否則諸如針對本文中揭露之材料之數量、時間之持續時間、溫度、操作條件、數量之比率及其類似者之全部數值範圍、數量、值及百分比應被理解為在全部例項中由術語「大約」修飾。相應地,除非相反地指示,否則本揭露及隨附發明申請專利範圍中陳述之數值參數係可根據需要變化之近似值。至少,應至少鑑於所報告有效數位之數目且藉由應用普通捨入技術解釋各數值參數。範圍可在本文中表達為從一個端點至另一端點或在兩個端點之間。本文中揭露之全部範圍包含端點,除非另有指定。Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the disclosure are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contain certain errors necessarily resulting from the standard deviation found in their respective testing measurements. Also, as used herein, the term "about" generally means within 10%, 5%, 1%, or 0.5% of a given value or range. Alternatively, the term "about" means within an acceptable standard error of the mean when considered by one of ordinary skill in the art. Except in operating/working examples, or unless expressly specified otherwise, such as for amounts of materials disclosed herein, durations of time, temperatures, operating conditions, ratios of amounts, and the like, all numerical ranges, Amounts, values and percentages should be understood to be modified by the term "about" in all instances. Accordingly, unless indicated to the contrary, the numerical parameters set forth in the present disclosure and the accompanying claims are approximations that may vary as desired. At the very least, each numerical parameter should be interpreted by applying ordinary rounding techniques at least in view of the number of reported significant digits. A range may be expressed herein as from one endpoint to the other or between the two endpoints. All ranges disclosed herein include endpoints unless otherwise specified.

現有半導體技術中,廣泛地使用磁控濺射裝置來對晶圓進行薄膜沉積以形成壓電層或緩衝層。特別地,是對晶圓進行氮化鋁薄膜沉積。詳細來說,磁控濺鍍裝置具有鋁材質的靶材,並且先在真空腔室內通入氬氣和氮氣的混合氣體以進行反應濺射。氬氣在電場的作用下被電離成氬離子,通過靶材施加的負電壓驅使氬離子去轟擊靶材,從而得到鋁原子或者原子團。鋁原子或者原子團在重力的作用下向下遷移至晶圓表面,同時在高溫的作用下與氮原子結合形成氮化鋁薄膜。In the prior art semiconductor technology, magnetron sputtering apparatuses are widely used to deposit thin films on wafers to form piezoelectric layers or buffer layers. In particular, aluminum nitride film deposition is performed on wafers. In detail, the magnetron sputtering device has an aluminum target, and a mixed gas of argon and nitrogen is first introduced into the vacuum chamber to perform reactive sputtering. The argon gas is ionized into argon ions under the action of the electric field, and the negative voltage applied by the target material drives the argon ions to bombard the target material, thereby obtaining aluminum atoms or atomic groups. The aluminum atoms or atomic groups migrate down to the wafer surface under the action of gravity, and at the same time combine with nitrogen atoms under the action of high temperature to form an aluminum nitride film.

然而,在薄膜沉積的製程中,一般使用單一材質(如碳化矽)托盤來承載主要由氧化鋁、矽、碳化矽等材料組成的晶圓。各個材料間的熱膨脹係數關係為氧化鋁>氮化鋁>碳化矽,如此一來,在沉積氮化鋁薄膜的高溫過程中,薄膜存在一定的應力。此應力在高溫的外延爐中顯現更明顯,放大了薄膜成形過程中的應力影響,從而導致了外延均一性的差異,影響氮化鋁薄膜的品質。However, in the thin film deposition process, a single-material (eg, silicon carbide) tray is generally used to carry wafers mainly composed of aluminum oxide, silicon, silicon carbide, and other materials. The thermal expansion coefficient relationship between the various materials is aluminum oxide>aluminum nitride>silicon carbide. As a result, during the high temperature process of depositing the aluminum nitride film, the film has a certain stress. This stress is more obvious in the epitaxial furnace at high temperature, which amplifies the influence of stress in the film forming process, which leads to the difference of epitaxial uniformity and affects the quality of the aluminum nitride film.

另外,碳化矽在高溫(如攝氏500度)時其體積電阻率大致為10Ω•cm,換言之,碳化矽將從絕緣體轉變為非絕緣體。因此,在氮化鋁薄膜沉積過程中,電場和磁場的雙重影響導致離化後的離子(原子)到達晶圓的能量減小,從而沉積在晶圓上的氮化鋁薄膜的結晶品質變差。本發明提出一種應用於薄膜沉積裝置的托盤,能夠在製程中有效地減小氮化鋁薄膜形成時的應力,並且,減小了電場和磁場變化對形成氮化鋁薄膜的影響,進而改善氮化鋁薄膜的結晶品質。In addition, silicon carbide has a volume resistivity of approximately 10Ω·cm at high temperatures (eg, 500 degrees Celsius), in other words, silicon carbide will change from an insulator to a non-insulator. Therefore, during the deposition of the aluminum nitride film, the dual effects of the electric field and the magnetic field lead to a decrease in the energy of the ionized ions (atoms) reaching the wafer, thereby deteriorating the crystalline quality of the aluminum nitride film deposited on the wafer. . The invention provides a tray applied to a film deposition device, which can effectively reduce the stress during the formation of the aluminum nitride film during the manufacturing process, and reduce the influence of electric and magnetic field changes on the formation of the aluminum nitride film, thereby improving nitrogen The crystalline quality of aluminum films.

圖1是依據本發明一實施例之應用於薄膜沉積裝置的托盤1的示意圖。在本實施例中,所述薄膜沉積裝置是一種磁控濺鍍裝置,托盤1在磁控濺鍍裝置中用於承載晶圓,使磁控濺鍍裝置可以對托盤1上的晶圓進行薄膜沉積製程。在本實施例中,磁控濺鍍裝置是對晶圓進行氮化鋁薄膜沉積。如圖1所示,托盤1包括第一盤體11、第二盤體12以及多個連接組件13。第一盤體11與第二盤體12的尺寸相對應,其中第一盤體11的下表面設置有多個第一槽位21而第二盤體12的上表面設置有與第一槽位的數量、位置、形狀相對應的多個第二槽位22。連接組件13以卡榫的形式固定在第一槽位21與第二槽位22之間,使得第一盤體11與第二盤體12固定連接形成完整的托盤1。FIG. 1 is a schematic diagram of a tray 1 applied to a thin film deposition apparatus according to an embodiment of the present invention. In this embodiment, the thin film deposition device is a magnetron sputtering device, and the tray 1 is used to carry wafers in the magnetron sputtering device, so that the magnetron sputtering device can thin-film the wafers on the tray 1 deposition process. In this embodiment, the magnetron sputtering device is used to deposit aluminum nitride films on wafers. As shown in FIG. 1 , the tray 1 includes a first tray body 11 , a second tray body 12 and a plurality of connecting components 13 . The size of the first disc body 11 corresponds to the size of the second disc body 12 , wherein the lower surface of the first disc body 11 is provided with a plurality of first slots 21 and the upper surface of the second disc body 12 is provided with a plurality of first slots 21 . A plurality of second slots 22 corresponding to the number, position and shape. The connecting assembly 13 is fixed between the first slot 21 and the second slot 22 in the form of a tenon, so that the first tray 11 and the second tray 12 are fixedly connected to form a complete tray 1 .

在本實施例中,第一盤體11包括用於承載晶圓的多個通孔111,並且,第一盤體11是採用第一材質製備。第一材質的熱膨脹係數與薄膜的熱膨脹係數大致相等,以減少對晶圓沉積薄膜時的應力影響。第二盤體12是採用與第一材質不同的第二材質製備,其中第一材質的體積電阻率大於第二材質的體積電阻率,使得第一盤體11在沉積薄膜的過程中也能維持絕緣體,避免因成為非絕緣體後磁場與電場的改變影響了薄膜的品質。另外,第二材質的熱傳導係數大於第一材質的熱傳導係數,使得熱能得以順利傳導到放置於第一盤體11上的晶圓。In this embodiment, the first tray body 11 includes a plurality of through holes 111 for carrying wafers, and the first tray body 11 is made of a first material. The thermal expansion coefficient of the first material is approximately equal to the thermal expansion coefficient of the thin film, so as to reduce the influence of stress on the wafer when the thin film is deposited. The second disk body 12 is made of a second material different from the first material, wherein the volume resistivity of the first material is greater than the volume resistivity of the second material, so that the first disk body 11 can also maintain the film deposition process. It is an insulator to avoid the quality of the film being affected by the change of the magnetic field and electric field after becoming a non-insulator. In addition, the thermal conductivity of the second material is greater than that of the first material, so that the thermal energy can be smoothly conducted to the wafer placed on the first disk body 11 .

詳細來說,第一盤體11是由氮化鋁製備,而第二盤體12是由碳化矽製備。參考下方表1,碳化矽具有較高的熱傳導係數、抗折強度、楊氏模量和維氏硬度,而氮化鋁具有較高的耐熱衝擊和熱膨脹係數。另外,不論在室溫下、攝氏300度、攝氏500度的環境下,氮化鋁的體積電阻率都高於碳化矽的體積電阻率。 表1 類別 氮化鋁 碳化矽 體積密度(g/cm3 3.31 3.1 抗折強度(Mpa) 345 490 楊氏模量(GPa) 320 400 維氏硬度(GPa) 11 22 耐熱衝擊(△T(℃)) 400 300 熱膨脹係數(1×10-6/℃) (室溫~500℃)  4.4 (室溫~400℃)  3.8 熱傳導係數(W/m.K) 150(室溫) 170(室溫) 體積電阻率(Ω·cm) 室溫  1.00E+14  300℃1.00E+10 500℃1.00E+07 室溫      1.00E+4 300℃    1.00E+2 500℃         10 In detail, the first disk body 11 is made of aluminum nitride, and the second disk body 12 is made of silicon carbide. Referring to Table 1 below, silicon carbide has higher thermal conductivity, flexural strength, Young's modulus, and Vickers hardness, while aluminum nitride has higher thermal shock and thermal expansion coefficients. In addition, the volume resistivity of aluminum nitride is higher than that of silicon carbide at room temperature, 300 degrees Celsius, and 500 degrees Celsius. Table 1 category Aluminum Nitride Silicon Carbide Bulk density (g/cm 3 ) 3.31 3.1 Flexural strength (Mpa) 345 490 Young's modulus (GPa) 320 400 Vickers hardness (GPa) 11 twenty two Thermal shock (△T(℃)) 400 300 Thermal expansion coefficient (1×10-6/℃) (room temperature~500℃) 4.4 (room temperature~400℃) 3.8 Thermal conductivity (W/mK) 150 (room temperature) 170 (room temperature) Volume resistivity (Ω·cm) Room temperature 1.00E+14 300℃1.00E+10 500℃1.00E+07 Room temperature 1.00E+4 300℃ 1.00E+2 500℃ 10

因此,使用氮化鋁製備的第一盤體11具有較好的絕緣效果,而碳化矽材質的第二盤體12具有較好的導熱勻熱效果。如此一來,採用第一盤體11與第二盤體12的複合托盤1可以在高溫下保持高電阻率的特性,同時保有容易導熱的優點,借此提升薄膜的結晶品質,穩定薄膜生產。Therefore, the first disk body 11 made of aluminum nitride has better insulating effect, while the second disk body 12 made of silicon carbide has better thermal conductivity and heat distribution effect. In this way, the composite tray 1 using the first disc body 11 and the second disc body 12 can maintain the characteristics of high resistivity at high temperature, and at the same time maintain the advantage of easy heat conduction, thereby improving the crystal quality of the film and stabilizing the film production.

另外,由於第一盤體11是使用氮化鋁製備,若晶圓上所沉積的薄膜同樣是氮化鋁時,第一材質與薄膜的熱膨脹係數相等。如此一來,當磁控濺射裝置對放置在通孔111中的晶圓進行薄膜沉積時,由於第一盤體11與薄膜的材質相同,可有效地降低薄膜在沉積的過程中所感受的應力。In addition, since the first disk body 11 is made of aluminum nitride, if the film deposited on the wafer is also made of aluminum nitride, the thermal expansion coefficients of the first material and the film are equal. In this way, when the magnetron sputtering device performs thin film deposition on the wafer placed in the through hole 111, since the material of the first disk body 11 is the same as that of the thin film, it can effectively reduce the feeling of the thin film during the deposition process. stress.

然而,本發明並不限定以氮化鋁來製備第一盤體11。本技術領域人員應能理解,只要第一材質與形成薄膜材質的熱膨脹係數大致相等,即可降低薄膜在沉積的過程中所感受的應力。在本發明中,第一材質的熱膨脹係數與薄膜材質的熱膨脹係數的相對偏差值限定在一特定值內。舉例來說,假設第一材質的熱膨脹係數為TA、薄膜材質的熱膨脹係數為TB,則在本發明中限定(TA-TB)/TA小於20%。如此一來,即便第一材質與薄膜材質不同,也同樣可以降低薄膜在沉積的過程中所感受的應力。However, the present invention is not limited to preparing the first disk body 11 with aluminum nitride. Those skilled in the art should understand that as long as the thermal expansion coefficients of the first material and the film-forming material are approximately equal, the stress experienced by the film during deposition can be reduced. In the present invention, the relative deviation between the thermal expansion coefficient of the first material and the thermal expansion coefficient of the film material is limited to a specific value. For example, assuming that the thermal expansion coefficient of the first material is TA and the thermal expansion coefficient of the film material is TB, it is defined in the present invention that (TA-TB)/TA is less than 20%. In this way, even if the first material is different from the film material, the stress experienced by the film during deposition can also be reduced.

圖2是依據本發明一實施例之第一盤體11的示意圖。在本實施例中,第一盤體11的直徑範圍為300mm至480mm,厚度H1範圍為2mm至4mm。若第一盤體11的尺寸越大,為了避免盤體容易破碎,厚度H1則相對越厚。然而,若厚度H1越厚則導熱性越差,將會影響薄膜結晶的生成。優選地,第一盤體11的直徑是300mm,第一盤體11的厚度H1是2mm。FIG. 2 is a schematic diagram of the first disk body 11 according to an embodiment of the present invention. In this embodiment, the diameter of the first disc body 11 is in the range of 300 mm to 480 mm, and the thickness H1 is in the range of 2 mm to 4 mm. If the size of the first disk body 11 is larger, in order to prevent the disk body from being easily broken, the thickness H1 is relatively thicker. However, if the thickness H1 is thicker, the thermal conductivity will be poorer, which will affect the formation of thin film crystals. Preferably, the diameter of the first disc body 11 is 300 mm, and the thickness H1 of the first disc body 11 is 2 mm.

如圖1實施例所述,第一盤體11包括用於承載晶圓的多個通孔111(如圖1所示,第一盤體11具有5個通孔111),其中通孔111可以降低晶圓在製程中由於受熱產生的應力。如圖2所示,詳細來說,通孔111分為上部111_1和下部111_2,其中上部111_1為俯瞰第一盤體11的上表面時所觀察到的通孔111的樣貌,而下部111_2為仰視第一盤體11的下表面時所觀察到的通孔111的樣貌。在本實施例中,通孔上部111_1的直徑R1大於通孔下部111_2的直徑R2。晶圓的直徑一般為100mm,厚度為0.6mm,若通孔上部111_1的直徑R1太小,則晶圓不易放入或取出,若直徑R1太大則晶圓容易滑動。因此,在本實施例中,通孔上部111_1的直徑R1範圍為100.5mm至102mm,孔深H2範圍為1mm至3mm。優選地,通孔上部111_1的直徑R1為111mm。通孔上部111_1的孔深則依據第一盤體11的厚度進行調整。As shown in the embodiment of FIG. 1 , the first tray body 11 includes a plurality of through holes 111 for carrying wafers (as shown in FIG. 1 , the first tray body 11 has five through holes 111 ), wherein the through holes 111 may be Reduce the stress of the wafer due to heat during the process. As shown in FIG. 2 , in detail, the through hole 111 is divided into an upper part 111_1 and a lower part 111_2 , wherein the upper part 111_1 is the appearance of the through hole 111 observed when overlooking the upper surface of the first plate body 11 , and the lower part 111_2 is the appearance of the through hole 111 . The appearance of the through hole 111 observed when the lower surface of the first disk body 11 is viewed from the bottom. In this embodiment, the diameter R1 of the upper part 111_1 of the through hole is larger than the diameter R2 of the lower part 111_2 of the through hole. The diameter of the wafer is generally 100mm and the thickness is 0.6mm. If the diameter R1 of the upper part 111_1 of the through hole is too small, the wafer will not be easily put in or taken out, and if the diameter R1 is too large, the wafer will slide easily. Therefore, in this embodiment, the diameter R1 of the upper through hole 111_1 is in the range of 100.5 mm to 102 mm, and the hole depth H2 is in the range of 1 mm to 3 mm. Preferably, the diameter R1 of the upper part 111_1 of the through hole is 111 mm. The hole depth of the upper part 111_1 of the through hole is adjusted according to the thickness of the first plate body 11 .

另外,通孔下部111_2的直徑R2若太小則不利於傳導熱量,直徑R2若太大則無法承載晶圓。因此,在本實施例中,通孔下部111_2的直徑R2範圍為80mm至98mm,孔深H3範圍為1mm至3mm。優選地,通孔下部111_2的直徑R2為94mm,孔深H3為1mm。In addition, if the diameter R2 of the lower part 111_2 of the through hole is too small, it is not conducive to heat conduction, and if the diameter R2 is too large, the wafer cannot be supported. Therefore, in the present embodiment, the diameter R2 of the lower part 111_2 of the through hole is in the range of 80 mm to 98 mm, and the hole depth H3 is in the range of 1 mm to 3 mm. Preferably, the diameter R2 of the lower part 111_2 of the through hole is 94 mm, and the hole depth H3 is 1 mm.

進一步地,如圖2所示,第一盤體11的上表面在鄰近通孔111處設置有一圈倒角結構300,其中倒角結構300可在製程中有效地防止顆粒的堆積,避免晶圓的污染。在本實施例中,倒角結構300呈現角度θ,其中角度θ範圍為30度至60度,並且倒角結構300的直角邊L範圍為0.3mm至2mm。優選地,倒角結構300的角度θ是45度,直角邊L是0.5mm。Further, as shown in FIG. 2 , the upper surface of the first disk body 11 is provided with a circle of chamfered structures 300 adjacent to the through holes 111 , wherein the chamfered structures 300 can effectively prevent the accumulation of particles during the process and avoid the wafer pollution. In this embodiment, the chamfered structure 300 presents an angle θ, wherein the angle θ ranges from 30 degrees to 60 degrees, and the right-angle side L of the chamfered structure 300 ranges from 0.3 mm to 2 mm. Preferably, the angle θ of the chamfered structure 300 is 45 degrees, and the right-angled side L is 0.5 mm.

如圖1實施例所述,第一盤體11的下表面具有多個第一槽位21,第二盤體12的上表面具有多個第二槽位22,而連接組件13以卡榫的形式固定在第一槽位21與第二槽位22之間。第一槽位21的直徑R3若偏小將導致連接組件13支撐受力偏大,造成第一盤體11損壞;直徑R3若偏大則會與通孔111互相干涉,同時不易於導熱。在本實施例中,第一槽位21的直徑R3範圍為10mm至50mm。優選地,第一槽位21的直徑R3是22mm。在本實施例中,第一槽位21的孔深H4範圍為0.5mm至3mm。優選地,第一槽位21的孔深H4是1mm。As shown in the embodiment of FIG. 1 , the lower surface of the first disc body 11 has a plurality of first slots 21 , the upper surface of the second disc body 12 has a plurality of second slots 22 , and the connecting component 13 is formed by a tenon. The form is fixed between the first slot 21 and the second slot 22 . If the diameter R3 of the first slot 21 is too small, the supporting force of the connecting element 13 will be too large, resulting in damage to the first disk body 11; In this embodiment, the diameter R3 of the first slot 21 ranges from 10 mm to 50 mm. Preferably, the diameter R3 of the first slot 21 is 22 mm. In this embodiment, the hole depth H4 of the first slot 21 ranges from 0.5 mm to 3 mm. Preferably, the hole depth H4 of the first slot 21 is 1 mm.

圖3是依據本發明一實施例之第二盤體12的示意圖。如圖1實施例所述,第二盤體12的形狀、尺寸對應第一盤體11的形狀、尺寸,並且,第二槽位22的形狀、位置對應第一槽位21的形狀、位置。在本實施例中,第二盤體12的直徑範圍為300mm至480mm,第二盤體12的厚度H5範圍為1mm至4mm。第二盤體12的厚度H5若偏小則托盤1容易破碎,厚度H5若偏大則托盤1的重量過重,不易操作。優選地,第二盤體12的直徑與第一盤體11的直徑相同是300mm,厚度H5是2mm。FIG. 3 is a schematic diagram of the second disk body 12 according to an embodiment of the present invention. As shown in the embodiment of FIG. 1 , the shape and size of the second disk body 12 correspond to the shape and size of the first disk body 11 , and the shape and position of the second slot 22 correspond to the shape and position of the first slot 21 . In this embodiment, the diameter of the second disc body 12 is in the range of 300 mm to 480 mm, and the thickness H5 of the second disc body 12 is in the range of 1 mm to 4 mm. If the thickness H5 of the second tray body 12 is too small, the tray 1 is easily broken, and if the thickness H5 is too large, the weight of the tray 1 is too heavy and it is difficult to handle. Preferably, the diameter of the second disc body 12 is the same as the diameter of the first disc body 11 , which is 300 mm, and the thickness H5 is 2 mm.

與第一槽位21相對應,在本實施例中,第二槽位22的直徑R4範圍為10mm至50mm,孔深H6範圍為0.5mm至3mm。優選地,第二槽位22的直徑R4與第一槽位21的直徑R3相同是22mm,並且,第二槽位22的孔深H6與第一槽位21的孔深H4相同是1mm。Corresponding to the first slot 21 , in this embodiment, the diameter R4 of the second slot 22 ranges from 10 mm to 50 mm, and the hole depth H6 ranges from 0.5 mm to 3 mm. Preferably, the diameter R4 of the second slot 22 is 22 mm the same as the diameter R3 of the first slot 21 , and the hole depth H6 of the second slot 22 is 1 mm the same as the hole depth H4 of the first slot 21 .

在本實施例中,第一盤體11的下表面有6個均勻分佈的第一槽位21。相應地,第二盤體12的上表面有6個均勻分佈的第二槽位22。然而,本技術領域具有通常知識者應能輕易理解,只要能穩定的連接第一盤體11與第二盤體12,第一槽位21與第二槽位22的數量並非本發明的一限制。In this embodiment, the lower surface of the first disk body 11 has six uniformly distributed first slots 21 . Correspondingly, there are 6 evenly distributed second slots 22 on the upper surface of the second disk body 12 . However, those skilled in the art should easily understand that as long as the first disk body 11 and the second disk body 12 can be stably connected, the number of the first slot 21 and the second slot 22 is not a limitation of the present invention .

連接組件13以卡榫的形式位於第一槽位21和第二槽位22之間以使第一盤體11與第二盤體12固定連接形成托盤1。參考圖4,圖4是依據本發明一實施例之連接組件13的示意圖。作為卡榫的連接組件13若其直徑R5偏小則第一盤體11與第二盤體12之間容易滑動,若直徑R5偏大則不容易卡入第一槽位21和第二槽位22之間。在本實施例中,連接組件13的直徑R5範圍為21.6mm至21.8mm。優選地,連接組件13的直徑R5是21.8mm。在本實施例中,連接組件13的高度H7範圍為2mm至3mm。依據設計上的需要,托盤1可具有多組不同高度的連接組件13,並且依照製程需要更換連接組件13來進行高度調整,進而調整晶圓與靶材之間的距離,擴大了製程調試窗口。The connection assembly 13 is located between the first slot 21 and the second slot 22 in the form of a tenon, so that the first tray 11 and the second tray 12 are fixedly connected to form the tray 1 . Referring to FIG. 4 , FIG. 4 is a schematic diagram of the connecting assembly 13 according to an embodiment of the present invention. If the diameter R5 of the connecting element 13 as the tenon is too small, the first disk body 11 and the second disk body 12 are easy to slide, and if the diameter R5 is too large, it is not easy to be stuck into the first slot 21 and the second slot between 22. In this embodiment, the diameter R5 of the connecting component 13 is in the range of 21.6 mm to 21.8 mm. Preferably, the diameter R5 of the connecting assembly 13 is 21.8 mm. In this embodiment, the height H7 of the connecting component 13 ranges from 2 mm to 3 mm. According to design requirements, the tray 1 can have multiple sets of connecting components 13 with different heights, and the connecting components 13 can be replaced according to the process needs to adjust the height, thereby adjusting the distance between the wafer and the target, and expanding the process debugging window.

需注意的是,在上述實施例中連接組件13是圓柱狀,且第一槽位21與第二槽位22也相應地為圓柱狀空間。然而,本技術領域具有通常知識者應能輕易理解,作為卡榫的連接組件13可以是其他柱狀,而第一槽位21與第二槽位22也可以有相應的變化,此並非本發明的一限制。It should be noted that, in the above embodiment, the connecting component 13 is cylindrical, and the first slot 21 and the second slot 22 are correspondingly cylindrical spaces. However, those skilled in the art should easily understand that the connecting element 13 serving as the tenon can be other columnar shapes, and the first slot 21 and the second slot 22 can also have corresponding changes, which is not the present invention a limitation.

再次參考圖1,第一盤體11以及第二盤體12的上表面具有一標識符號(例如圖示中的三角形),第一盤體11以及第二盤體12的標識符號對齊後即可通過連接組件13將第一盤體11以及第二盤體12固定連接。圖5所示的托盤1是將第一盤體11與第二盤體12以連接組件13組合後的樣式。在本實施例中,組合後的托盤1的直徑R0與第一盤體11的直徑、第二盤體12的直徑相同。優選地,組合後的托盤1的直徑R0是300mm。在本實施例中,組合後的托盤1的厚度H0範圍為4mm至6mm。Referring to FIG. 1 again, the upper surfaces of the first disk body 11 and the second disk body 12 have an identification symbol (eg, a triangle in the figure), and the identification symbols of the first disk body 11 and the second disk body 12 can be aligned after the identification symbols are aligned. The first disc body 11 and the second disc body 12 are fixedly connected through the connecting assembly 13 . The tray 1 shown in FIG. 5 is a form in which the first tray body 11 and the second tray body 12 are combined with a connecting assembly 13 . In this embodiment, the diameter R0 of the combined tray 1 is the same as the diameter of the first tray 11 and the diameter of the second tray 12 . Preferably, the diameter R0 of the combined tray 1 is 300mm. In this embodiment, the thickness H0 of the combined tray 1 ranges from 4 mm to 6 mm.

申請人通過實驗發現,托盤強度隨著製程次數的增多將會有所改變,進而影響薄膜結晶的品質。參考圖6,圖6顯示托盤強度相對於製程次數的變化圖。從圖6可觀察到,傳統單一材質(如碳化矽)的托盤隨著進行製程次數的增多,使用X射線衍射儀測量到的002強度逐漸下降,最終002強度下降達15%。此數據表明,隨著製程次數的增多,使用單一材質(如碳化矽)的托盤承載晶圓所生長的氮化鋁晶體品質略差,其導致發光二極體外延生長氮化鎵時生長反射率較低,表面粗糙不起振,進而有霧化的風險。另一方面,本發明所提出的複合結構的托盤1隨著製程次數的增多,002強度僅有約5%的波動。換句話說,使用托盤1進行薄膜沉積製程將改善氮化鋁的晶體品質,進而拓寬發光二極體外延生長的製程窗口。The applicant found through experiments that the strength of the tray will change with the increase of the number of manufacturing processes, thereby affecting the quality of the film crystallization. Referring to FIG. 6, FIG. 6 shows a graph of pallet strength versus number of processes. It can be observed from Figure 6 that the 002 intensity measured by the X-ray diffractometer gradually decreases with the increase of the number of processes performed for the tray of traditional single material (such as silicon carbide), and the final 002 intensity decreases by 15%. This data shows that with the increase of the number of processes, the quality of the aluminum nitride crystal grown on a single material (such as silicon carbide) tray-mounted wafer is slightly worse, which leads to the growth reflectivity of the light-emitting diode epitaxial growth of gallium nitride. Low, the surface is rough and does not vibrate, and there is a risk of fogging. On the other hand, the 002 strength of the pallet 1 of the composite structure proposed by the present invention only fluctuates by about 5% with the increase of the number of processes. In other words, using the tray 1 for the thin film deposition process will improve the crystal quality of the aluminum nitride, thereby widening the process window of the epitaxial growth of the light emitting diode.

另外,申請人檢測使用複合結構托盤1與傳統單一材質(如碳化矽)的托盤生成的薄膜結晶的表徵,並得到下方表2。由表2數據可知,利用複合托盤1進行濺射製備的氮化鋁薄膜晶體品質有一定的提升。從X射線衍射儀測試結果來看,複合托盤1所製備的氮化鋁薄膜的002和102強度數值可以提升10%以上,晶體品質優於使用傳統單一材質(如碳化矽)的托盤生成的薄膜結晶。 表2    氮化鋁002 氮化鋁102 半峰全寬 (arcsec) 強度 (CPS) 半峰全寬 (arcsec) 強度 (CPS) 傳統單一材質托盤 - - - - 複合托盤1 ↓1% ↑15% ↓10% ↑10% In addition, the applicant examined the characterization of the film crystallization produced using the composite structural tray 1 and a tray of a traditional single material (eg, silicon carbide), and obtained Table 2 below. It can be seen from the data in Table 2 that the crystal quality of the aluminum nitride thin film prepared by sputtering using the composite tray 1 is improved to a certain extent. From the test results of the X-ray diffractometer, the 002 and 102 intensity values of the aluminum nitride film prepared by the composite tray 1 can be increased by more than 10%, and the crystal quality is better than that of the film produced by the tray using a traditional single material (such as silicon carbide). crystallization. Table 2 Aluminum Nitride 002 Aluminum Nitride 102 Full width at half maximum (arcsec) Strength (CPS) Full width at half maximum (arcsec) Strength (CPS) Traditional Single Material Tray - - - - Composite tray 1 ↓1% ↑15% ↓10% ↑10%

接著,申請人比較使用複合托盤1以及傳統單一材質(如碳化矽)的托盤產生的氮化鎵發光二極體芯片的性能,並得到下方表3。由表3可知,由於複合托盤1所增加的倒角結構300和通孔111在生長製程中可降低薄膜的應力,從而改善了外延過程中的氮化鎵的翹曲現象,因此,使用複合托盤1所生成的氮化鋁薄膜來作為緩衝層時,氮化鎵波長均勻性(STD)相比使用傳統單一材質(如碳化矽)的托盤所生成的氮化鋁薄膜更加一致,並且,反向電壓和抗靜電通過率等都有大幅度的提升;同時,使用複合托盤1所生長的氮化鋁薄膜的結晶品質要優於使用傳統單一材質(如碳化矽)的托盤所生成的氮化鋁薄膜的結晶品質,進而促成了發光二極體外延氮化鎵品質的提升。 表3    波長均勻性 (STD) 亮度 (LOP) 正向電壓 (VF) 反向電壓 (VR) 抗靜電通過率 (ESD) 傳統單一材質托盤 1.3-1.9 正常 正常 正常 正常 複合托盤1 0.9-1.3 正常 正常 增高 增高 Next, the applicant compares the performance of the gallium nitride light emitting diode chips produced using the composite tray 1 and a tray made of a traditional single material (eg, silicon carbide), and obtains the following Table 3. It can be seen from Table 3 that the added chamfer structure 300 and the through hole 111 of the composite tray 1 can reduce the stress of the film during the growth process, thereby improving the warpage of gallium nitride during the epitaxy process. Therefore, the composite tray is used. 1 When the resulting aluminum nitride film is used as a buffer layer, the GaN wavelength uniformity (STD) is more consistent than that of the aluminum nitride film produced using a traditional single material (such as silicon carbide) tray, and the reverse The voltage and anti-static pass rate have been greatly improved; at the same time, the crystalline quality of the aluminum nitride film grown using the composite tray 1 is better than that of the aluminum nitride film produced by using a traditional single material (such as silicon carbide) tray The crystalline quality of the thin film further contributes to the improvement of the quality of the light-emitting diode epitaxial gallium nitride. table 3 Wavelength Uniformity (STD) Brightness (LOP) Forward Voltage (VF) Reverse Voltage (VR) Antistatic pass rate (ESD) Traditional Single Material Tray 1.3-1.9 normal normal normal normal Composite tray 1 0.9-1.3 normal normal increase increase

前述內容概括數項實施例之特徵,使得熟習此項技術者可更佳地理解本揭露之態樣。熟習此項技術者應瞭解,其等可容易地使用本揭露作為用於設計或修改用於實行本文中介紹之實施例之相同目的及/或達成相同優點之其他製程及結構之一基礎。熟習此項技術者亦應瞭解,此等等效構造不背離本揭露之精神及範疇,且其等可在不背離本揭露之精神及範疇之情況下在本文中作出各種改變、置換及更改。The foregoing summarizes features of several embodiments so that those skilled in the art may better understand aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments described herein. Those skilled in the art should also understand that these equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they can make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.

1:托盤 11:第一盤體 12:第二盤體 13:連接組件 21:第一槽位 22:第二槽位 111:通孔 111_1:通孔上部 111_2:通孔下部 R0、R1、R2、R3、R4、R5:直徑 H0、H1:厚度 H2、H3、H4、H5、H6:孔深 H7:高度1: Tray 11: The first plate 12: The second plate 13: Connect Components 21: The first slot 22: The second slot 111: Through hole 111_1: Upper part of through hole 111_2: lower part of through hole R0, R1, R2, R3, R4, R5: Diameter H0, H1: Thickness H2, H3, H4, H5, H6: hole depth H7: height

當結合附圖閱讀時,從以下詳細描述最佳理解本揭露之態樣。應注意,根據產業中之標準實踐,各種構件未按比例繪製。事實上,為了論述的清楚起見可任意增大或減小各種構件之尺寸。 圖1是依據本發明一實施例之托盤的示意圖。 圖2是依據本發明一實施例之第一盤體的示意圖。 圖3是依據本發明一實施例之第二盤體的示意圖。 圖4是依據本發明一實施例之連接組件的示意圖。 圖5是依據本發明一實施例之組合後托盤的示意圖。 圖6是依據本發明一實施例之托盤的002強度相對製程次數的變化示意圖。Aspects of the present disclosure are best understood from the following detailed description when read in conjunction with the accompanying drawings. It should be noted that in accordance with standard practice in the industry, the various components are not drawn to scale. In fact, the dimensions of the various components may be arbitrarily increased or decreased for clarity of discussion. FIG. 1 is a schematic diagram of a tray according to an embodiment of the present invention. FIG. 2 is a schematic diagram of a first disk body according to an embodiment of the present invention. 3 is a schematic diagram of a second disk body according to an embodiment of the present invention. FIG. 4 is a schematic diagram of a connection assembly according to an embodiment of the present invention. FIG. 5 is a schematic diagram of a combined tray according to an embodiment of the present invention. FIG. 6 is a schematic diagram illustrating the variation of the 002 strength of the tray with respect to the number of processes according to an embodiment of the present invention.

1:托盤 1: Tray

11:第一盤體 11: The first plate

12:第二盤體 12: The second plate

13:連接組件 13: Connect Components

21:第一槽位 21: The first slot

22:第二槽位 22: The second slot

111:通孔 111: Through hole

Claims (11)

一種應用於一薄膜沉積裝置的托盤,包括:一第一盤體,該第一盤體包括多個通孔,每一通孔的尺寸對應晶圓的尺寸,且每一通孔用於容納一晶圓,且該第一盤體的一下表面設置有多個第一槽位;一第二盤體,該第二盤體的尺寸與該第一盤體的尺寸相對應,且該第二盤體的一上表面設置有多個第二槽位,其中該多個第二槽位的形狀及位置與該多個第一槽位的形狀及位置相對應;以及一連接組件,位於一一對應的該第一槽位及該第二槽位之間,用於實現該第一盤體和第二盤體的固定連接;其中該第一盤體採用一第一材質製備,該第二盤體採用一第二材質製備,且該第一材質的熱膨脹係數與一待沉積薄膜的熱膨脹係數的相對偏差值小於20%,以減少對該晶圓沉積薄膜時的應力影響;其中該第一材質的體積電阻率大於該第二材質的體積電阻率,以使在對該晶圓沉積該薄膜時該第一盤體形成一絕緣體。 A tray applied to a thin film deposition device, comprising: a first tray body, the first tray body includes a plurality of through holes, the size of each through hole corresponds to the size of a wafer, and each through hole is used for accommodating a wafer , and the lower surface of the first plate body is provided with a plurality of first slots; a second plate body, the size of the second plate body is corresponding to the size of the first plate body, and the second plate body is A plurality of second slots are disposed on an upper surface, wherein the shapes and positions of the plurality of second slots correspond to the shapes and positions of the plurality of first slots; and a connecting component is located in the one-to-one corresponding The first slot and the second slot are used to realize the fixed connection of the first disc body and the second disc body; wherein the first disc body is made of a first material, and the second disc body is made of a A second material is prepared, and the relative deviation between the thermal expansion coefficient of the first material and the thermal expansion coefficient of a film to be deposited is less than 20%, so as to reduce the influence of stress when depositing a film on the wafer; wherein the volume resistance of the first material The ratio is greater than the volume resistivity of the second material, so that the first disk body forms an insulator when the thin film is deposited on the wafer. 如請求項1所述的托盤,其中該第二材質的熱傳導係數大於該第一材質的熱傳導係數。 The tray of claim 1, wherein the thermal conductivity of the second material is greater than the thermal conductivity of the first material. 如請求項1所述的托盤,其中該第一盤體的該上表面在鄰近該通孔處設置有一倒角結構。 The tray of claim 1, wherein the upper surface of the first tray body is provided with a chamfer structure adjacent to the through hole. 如請求項3所述的托盤,其中該倒角結構與該第一盤體的上表面之間的夾角的範圍為30度至60度,該倒角結構的直角邊長度範圍為0.3毫米至2毫米。 The tray of claim 3, wherein the angle between the chamfered structure and the upper surface of the first tray body is in the range of 30 degrees to 60 degrees, and the length of the right-angle side of the chamfered structure is in the range of 0.3 mm to 2 mm. 如請求項4所述的托盤,其中該倒角結構與該第一盤體的該上表面之間的夾角為45度,該倒角結構的直角邊長度為0.5毫米。 The tray of claim 4, wherein the angle between the chamfered structure and the upper surface of the first tray body is 45 degrees, and the length of the right-angled side of the chamfered structure is 0.5 mm. 如請求項1所述的托盤,其中該第一盤體的高度範圍為2毫米至4毫米。 The tray of claim 1, wherein the height of the first tray body ranges from 2 mm to 4 mm. 如請求項1所述的托盤,其中該通孔具有一上部及一下部,該上部的直徑大於該下部的直徑。 The tray of claim 1, wherein the through hole has an upper portion and a lower portion, and the diameter of the upper portion is larger than the diameter of the lower portion. 如請求項7所述的托盤,其中該上部的直徑範圍為100.5毫米至102毫米,該上部的縱深範圍為1毫米至3毫米。 The pallet of claim 7, wherein the diameter of the upper portion ranges from 100.5 mm to 102 mm, and the depth of the upper portion ranges from 1 mm to 3 mm. 如請求項7所述的托盤,其中該下部的直徑範圍為80毫米至98毫米,該下部的縱深範圍為1毫米至3毫米。 The pallet of claim 7, wherein the diameter of the lower portion ranges from 80 mm to 98 mm, and the depth of the lower portion ranges from 1 mm to 3 mm. 如請求項1所述的托盤,其中該連接組件的高度範圍為2毫米至3毫米。 The pallet of claim 1, wherein the height of the connecting assembly is in the range of 2 mm to 3 mm. 如請求項1所述的托盤,其中該第一材質為氮化鋁,該第二材質為碳 化矽。 The tray of claim 1, wherein the first material is aluminum nitride, and the second material is carbon Silicon.
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