TWI753666B - Moisture-sensed deforming fabric - Google Patents

Moisture-sensed deforming fabric Download PDF

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TWI753666B
TWI753666B TW109141019A TW109141019A TWI753666B TW I753666 B TWI753666 B TW I753666B TW 109141019 A TW109141019 A TW 109141019A TW 109141019 A TW109141019 A TW 109141019A TW I753666 B TWI753666 B TW I753666B
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Taiwan
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moisture
fabric
sensitive
patterns
ink
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TW109141019A
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Chinese (zh)
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TW202221194A (en
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林嘉儀
阮巽雯
蔡榮裕
林俊宏
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財團法人紡織產業綜合研究所
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Priority to TW109141019A priority Critical patent/TWI753666B/en
Priority to CN202110021793.5A priority patent/CN114523777B/en
Priority to US17/347,674 priority patent/US20220162797A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/0047Digital printing on surfaces other than ordinary paper by ink-jet printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

Abstract

A moisture-sensed deforming fabric includes a base cloth and a moisture-sensed shrinking ink. The moisture-sensed shrinking ink is jetted on any surface of the base cloth by a digital printing process, and the moisture-sensed shrinking ink forms a hydrophilic area on the surface of the base cloth.

Description

感濕變形織物Wet textured fabric

本揭露內容是有關於一種感濕變形織物,且特別是有關於一種利用數位噴印製程製備而成的感濕變形織物。The present disclosure relates to a moisture-sensitive textured fabric, and more particularly, to a moisture-sensitive textured fabric prepared by a digital jet printing process.

隨著現今社會生活水準的提升,人們對於機能性紡織品的需求越來越高,且隨著各種機能性紡織品不斷地問世,具有特定目的的機能性紡織品的發展亦日趨完善。With the improvement of living standards in today's society, people's demand for functional textiles is getting higher and higher, and with the continuous advent of various functional textiles, the development of functional textiles with specific purposes is also becoming more and more perfect.

對於穿戴型紡織品而言,其常隨著使用者的汗液或環境濕度的提升而黏附在使用者皮膚,造成穿戴舒適感大幅地降低。因此,如何降低穿戴型紡織品與使用者身體間的黏附並從而提升穿戴舒適感為紡織業者積極研究的重要課題。For wearable textiles, they often adhere to the user's skin as the user's sweat or ambient humidity increases, resulting in greatly reduced wearing comfort. Therefore, how to reduce the adhesion between the wearable textile and the user's body and thereby improve the wearing comfort is an important topic of active research by textile manufacturers.

本揭露提供一種感濕變形織物,其可於吸濕後局部地產生變形,有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。The present disclosure provides a moisture-sensitive deformable fabric, which can be deformed locally after absorbing moisture, which helps to volatilize sweat and reduce the stickiness of the user's body, thereby providing the user with a good wearing comfort.

根據本揭露一些實施方式,感濕變形織物包括基布以及感濕收縮墨水。感濕收縮墨水利用數位噴印製程噴塗於基布的任一表面,且感濕收縮墨水於基布的表面形成親水區。According to some embodiments of the present disclosure, a moisture-sensitive textured fabric includes a base fabric and a moisture-sensitive shrinkage ink. The moisture-sensitive shrinkage ink is sprayed on any surface of the base cloth by a digital jet printing process, and the moisture-sensitive shrinkage ink forms a hydrophilic area on the surface of the base cloth.

在本揭露一些實施方式中,感濕收縮墨水可具有介於2.5cP至10.0cP間的黏度以及介於22dyne/cm至32dyne/cm間的表面張力,且感濕收縮墨水包括15至35重量份的感濕收縮樹脂以及65至85重量份的水。In some embodiments of the present disclosure, the moisture shrinkage ink may have a viscosity between 2.5 cP and 10.0 cP and a surface tension between 22 dyne/cm and 32 dyne/cm, and the moisture shrinkage ink includes 15 to 35 parts by weight of moisture-sensitive resin and 65 to 85 parts by weight of water.

在本揭露一些實施方式中,感濕收縮樹脂可以是藉由包括以下試劑製備而成:多元醇、多元胺、第一交聯劑以及第二交聯劑。第一交聯劑及第二交聯劑各自包括異氰酸酯嵌段。In some embodiments of the present disclosure, the moisture shrinkable resin may be prepared by including the following reagents: polyol, polyamine, a first cross-linking agent, and a second cross-linking agent. The first crosslinking agent and the second crosslinking agent each include an isocyanate block.

在本揭露一些實施方式中,親水區可包括多個空心圓形圖案,且所述空心圓形圖案呈間隔排列。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of hollow circular patterns, and the hollow circular patterns are arranged at intervals.

在本揭露一些實施方式中,空心圓形圖案可呈陣列排列。In some embodiments of the present disclosure, the hollow circular patterns may be arranged in an array.

在本揭露一些實施方式中,空心圓形圖案可沿第一方向及第二方向排列,且第一方向與第二方向的夾角介於40度至50度間。In some embodiments of the present disclosure, the hollow circular patterns may be arranged along the first direction and the second direction, and the included angle between the first direction and the second direction is between 40 degrees and 50 degrees.

在本揭露一些實施方式中,親水區可包括多個空心六邊形圖案,且相鄰的兩空心六邊形圖案共用各自的其中一邊。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of hollow hexagonal patterns, and two adjacent hollow hexagonal patterns share one side of each.

在本揭露一些實施方式中,空心六邊形圖案的每一邊長可皆相等。In some embodiments of the present disclosure, each side of the hollow hexagonal pattern may be equal in length.

在本揭露一些實施方式中,親水區可包括多個長條形圖案,且長條形圖案呈平行排列。In some embodiments of the present disclosure, the hydrophilic region may include a plurality of elongated patterns, and the elongated patterns are arranged in parallel.

在本揭露一些實施方式中,長條形圖案可呈等距排列。In some embodiments of the present disclosure, the elongated patterns may be arranged at equal distances.

根據本揭露上述實施方式,本揭露的感濕變形織物具有由感濕收縮墨水噴塗而成的親水區。透過親水區的配置,感濕變形織物可在吸濕後局部地產生變形,以於感濕變形織物與使用者身體間產生立體空間,從而減少感濕變形織物與使用者身體間的接觸。如此一來,可有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。According to the above embodiments of the present disclosure, the moisture-sensitive deformation fabric of the present disclosure has a hydrophilic region sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic area, the moisture-sensitive textured fabric can be deformed locally after absorbing moisture, so as to create a three-dimensional space between the moisture-sensitive textured fabric and the user's body, thereby reducing the contact between the moisture-sensitive textured fabric and the user's body. In this way, the volatilization of sweat can be facilitated and the stickiness of the user's body can be reduced, thereby providing the user with a good wearing comfort.

以下將以圖式揭露本揭露之複數個實施方式,為明確地說明起見,許多實務上的細節將在以下敘述中一併說明。然而,應瞭解到,這些實務上的細節不應用以限制本揭露。也就是說,在本揭露部分實施方式中,這些實務上的細節是非必要的,因此不應用以限制本揭露。此外,為簡化圖式起見,一些習知慣用的結構與元件在圖式中將以簡單示意的方式繪示之。另外,為了便於讀者觀看,圖式中各元件的尺寸並非依實際比例繪示。Several embodiments of the present disclosure will be disclosed in the following drawings, and for the sake of clarity, many practical details will be described together in the following description. It should be understood, however, that these practical details should not be used to limit the present disclosure. That is to say, in some embodiments of the present disclosure, these practical details are unnecessary, and therefore should not be used to limit the present disclosure. In addition, for the purpose of simplifying the drawings, some well-known structures and elements will be shown in a simple and schematic manner in the drawings. In addition, for the convenience of the reader, the size of each element in the drawings is not drawn according to the actual scale.

在本文中,有時以鍵線式(skeleton formula)表示聚合物或基團的結構。這種表示法可省略碳原子、氫原子以及碳氫鍵。當然,結構式中有明確繪出原子或原子基團的,則以繪示者為準。Herein, the structure of a polymer or group is sometimes represented by a skeleton formula. This representation can omit carbon atoms, hydrogen atoms, and carbon-hydrogen bonds. Of course, where atoms or atomic groups are clearly drawn in the structural formula, the drawing shall prevail.

本揭露內容提供一種感濕變形織物,其具有由感濕收縮墨水噴塗而成的親水區。透過親水區的配置,感濕變形織物可在吸濕(例如,吸收汗水)後局部地產生變形,以於感濕變形織物與使用者身體間產生立體空間,從而減少感濕變形織物與使用者身體間的接觸。如此一來,可有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。The present disclosure provides a moisture-sensitive textured fabric having a hydrophilic region sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic area, the moisture-sensitive deformable fabric can be locally deformed after absorbing moisture (for example, absorbing sweat), so as to create a three-dimensional space between the moisture-sensitive deformable fabric and the user's body, thereby reducing the moisture-sensitive deformable fabric and the user's body. physical contact. In this way, the volatilization of sweat can be facilitated and the stickiness of the user's body can be reduced, thereby providing the user with a good wearing comfort.

第1圖繪示根據本揭露一些實施方式的感濕變形織物100的側視示意圖。感濕變形織物100包括基布110以及感濕收縮墨水120。感濕收縮墨水120利用數位噴印製程噴塗於基布110的任一表面111,以於基布110的表面111形成親水區A1。在一些實施方式中,基布110可例如是由彈性纖維、非彈性纖維或其組合織造而成。舉例而言,基布110可例如是由92%的聚脂纖維與8%的聚氨酯纖維共同織造而成的針織布或梭織布。在一些實施方式中,感濕收縮墨水120可噴塗於基布110面對外界環境的表面111,且由感濕收縮墨水120所形成的親水區A1可具有多種圖案,從而良好地達到感濕變形的效果,此將於下文中進行更詳細的說明。FIG. 1 is a schematic side view of a moisture deformable fabric 100 according to some embodiments of the present disclosure. The moisture-sensitive deformation fabric 100 includes a base fabric 110 and a moisture-sensitive shrinkage ink 120 . The moisture-sensitive shrinkage ink 120 is sprayed on any surface 111 of the base fabric 110 by a digital printing process, so as to form a hydrophilic area A1 on the surface 111 of the base fabric 110 . In some embodiments, the base fabric 110 may be woven from elastic fibers, inelastic fibers, or a combination thereof, for example. For example, the base fabric 110 can be, for example, a knitted fabric or a woven fabric that is co-woven with 92% polyester fiber and 8% polyurethane fiber. In some embodiments, the moisture-sensitive shrinkable ink 120 can be sprayed on the surface 111 of the base fabric 110 facing the external environment, and the hydrophilic area A1 formed by the moisture-sensitive shrinkable ink 120 can have various patterns, so as to well achieve moisture-sensitive deformation effect, which will be described in more detail below.

具體而言,當使用者將感濕變形織物100穿戴於身體時,由於基布110相對於由感濕收縮墨水120所形成的親水區A1具有較高的疏水性,且親水區A1又是形成於基布110面對外界環境的表面111,因此由使用者身體所產生的汗水會受到一拉力(如第1圖的箭頭方向)以由基布110面對使用者身體的表面113導引至基布110面對外界環境的表面111,從而有利於汗水的揮發。另一方面,導引至基布110的表面111的汗水可進入親水區A1,使得親水區A1因吸濕而產生變形,從而使感濕變形織物100局部地拱起或凹陷以於感濕變形織物100與使用者身體間產生立體空間。藉此,可減少感濕變形織物100與使用者身體間的接觸,有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。Specifically, when the user wears the moisture-sensitive deformable fabric 100 on the body, since the base fabric 110 has higher hydrophobicity relative to the hydrophilic area A1 formed by the moisture-sensitive shrinkable ink 120, and the hydrophilic area A1 is formed again Since the surface 111 of the base fabric 110 faces the external environment, the sweat generated by the user's body will be subjected to a pulling force (such as the arrow direction in FIG. 1 ) to be guided from the surface 113 of the base fabric 110 facing the user's body to The base cloth 110 faces the surface 111 of the external environment, thereby facilitating the volatilization of sweat. On the other hand, the sweat guided to the surface 111 of the base fabric 110 can enter the hydrophilic area A1, so that the hydrophilic area A1 is deformed due to moisture absorption, so that the moisture-sensitive deformable fabric 100 is partially arched or dented for moisture-sensitive deformation A three-dimensional space is created between the fabric 100 and the user's body. Thereby, the contact between the moisture-sensitive deformable fabric 100 and the user's body can be reduced, which is helpful for the volatilization of sweat and reduces the stickiness of the user's body, thereby providing the user with a good wearing comfort.

在一些實施方式中,感濕收縮墨水120主要包括15重量份至35重量份的感濕收縮樹脂以及65重量份至85重量份的水。感濕收縮樹脂具有多個胺基與羥基,並可牢固地配置於基布110上,從而賦予以其所製得的感濕收縮墨水120及感濕變形織物100良好的感濕收縮性。在一些實施方式中,感濕收縮樹脂可以藉由包括以下試劑製備而成:多元醇、多元胺、第一交聯劑以及第二交聯劑。在一些實施方式中,多元醇的添加量可介於0.5重量份至1.5重量份間,多元胺的添加量可介於40重量份至50重量份間,第一交聯劑的添加量可介於2.2重量份至2.6重量份間,且第二交聯劑的添加量可介於0.4重量份至0.8重量份間。In some embodiments, the moisture shrinkage ink 120 mainly includes 15 to 35 parts by weight of the moisture shrinkable resin and 65 to 85 parts by weight of water. The moisture-shrinkable resin has a plurality of amine groups and hydroxyl groups, and can be firmly disposed on the base fabric 110 , thereby imparting good moisture-shrinkage properties to the moisture-shrinkable ink 120 and the moisture-textured fabric 100 prepared therefrom. In some embodiments, the moisture shrinkable resin can be prepared by including the following reagents: a polyol, a polyamine, a first cross-linking agent, and a second cross-linking agent. In some embodiments, the addition amount of polyol may be between 0.5 parts by weight and 1.5 parts by weight, the addition amount of polyamine may be between 40 parts by weight and 50 parts by weight, and the addition amount of the first crosslinking agent may be between In the range of 2.2 parts by weight to 2.6 parts by weight, and the addition amount of the second crosslinking agent may be in the range of 0.4 parts by weight to 0.8 parts by weight.

在一些實施方式中,多元醇可提供感濕收縮樹脂良好的感濕收縮性,使得感濕收縮墨水120具有良好的感濕收縮性。如此一來,以感濕收縮墨水120所製得的感濕變形織物100可具有高的單位面積收縮率。在一些實施方式中,多元醇可例如是含醚基的多元醇,包括聚乙二醇、聚丙二醇或聚四亞甲基醚二醇。在一些實施方式中,多元醇的重量平均分子量可介於200g/mole至600g/mole之間。具體而言,若多元醇的重量平均分子量小於200g/mole,可能導致所形成的感濕收縮樹脂無法牢固地配置於基布110上,從而使得感濕變形織物100具有差的感濕收縮性以及水洗牢度;而若多元醇的重量平均分子量大於600g/mole,可能導致感濕收縮墨水120的黏度過高,從而不易噴塗於基布110上。In some embodiments, the polyol can provide the moisture-sensitive resin with good moisture-shrinkability, so that the moisture-shrinkable ink 120 has good moisture-shrinkability. In this way, the moisture sensitive textured fabric 100 prepared with the moisture sensitive shrinkage ink 120 can have a high unit area shrinkage rate. In some embodiments, the polyol may be, for example, an ether group-containing polyol, including polyethylene glycol, polypropylene glycol, or polytetramethylene ether glycol. In some embodiments, the polyol may have a weight average molecular weight between 200 g/mole and 600 g/mole. Specifically, if the weight-average molecular weight of the polyol is less than 200 g/mole, the formed moisture-shrinkable resin may not be firmly arranged on the base fabric 110, so that the moisture-deformable fabric 100 has poor moisture-shrinkability and Washing fastness; and if the weight-average molecular weight of the polyol is greater than 600 g/mole, the viscosity of the moisture shrinkage ink 120 may be too high, so that it is difficult to be sprayed on the base fabric 110 .

在一些實施方式中,多元胺可提供感濕收縮樹脂良好的感濕收縮性,使得感濕收縮墨水120具有良好的感濕收縮性。如此一來,以感濕收縮墨水120所製得的感濕變形織物100可具有高的單位面積收縮率。在一些實施方式中,多元胺可包括聚醚胺、聚醯胺或聚醯亞胺。在另一些實施方式中,多元胺可包括脂肪族胺,以較佳地提供感濕收縮樹脂良好的感濕收縮性。更具體而言,脂肪族胺可例如是己二胺、二乙基己二胺、三甲基己二胺、庚二胺、三甲基乙二胺、四乙基乙二胺、四甲基乙二胺、壬二胺、月桂胺二亞丙基二胺、二乙烯三胺、三乙烯四胺或聚乙烯亞胺。在一些實施方式中,多元胺的重量平均分子量可介於600g/mole至8000g/mole間,且較佳地可介於800g/mole至5500g/mole間。In some embodiments, the polyamine can provide the moisture-sensitive resin with good moisture-shrinkability, so that the moisture-shrinkable ink 120 has good moisture-shrinkability. In this way, the moisture sensitive textured fabric 100 prepared with the moisture sensitive shrinkage ink 120 can have a high unit area shrinkage rate. In some embodiments, the polyamine may include polyetheramine, polyamide, or polyimide. In other embodiments, the polyamines may include aliphatic amines to preferably provide good moisture shrinkage properties of the moisture shrinkable resin. More specifically, the aliphatic amine may be, for example, hexamethylenediamine, diethylhexamethylenediamine, trimethylhexamethylenediamine, heptanediamine, trimethylethylenediamine, tetraethylethylenediamine, tetramethylethylenediamine Ethylenediamine, nonanediamine, laurylaminedipropylenediamine, diethylenetriamine, triethylenetetramine or polyethyleneimine. In some embodiments, the weight average molecular weight of the polyamine may be between 600 g/mole and 8000 g/mole, and preferably between 800 g/mole and 5500 g/mole.

在一些實施方式中,第一交聯劑可包括異氰酸酯三聚體。具體而言,第一交聯劑可包括如式(1)所示的結構單元,

Figure 02_image001
式(1)。在一些實施方式中,第一交聯劑可包括脂肪族異氰酸酯(例如是HDI、TMDI或XDI)三聚體、脂環族異氰酸酯(例如是IPDI、HMDI或HTDI)三聚體、芳香族異氰酸酯(例如是TDI或MDI)三聚體或其組合。第一交聯劑可包括異氰酸酯嵌段。舉例而言,異氰酸酯三聚體的至少兩末端可具有異氰酸酯嵌段。具體而言,在以式(1)表示的第一交聯劑中,R 1、R 2及R 3中任兩者以上包括異氰酸酯嵌段。 In some embodiments, the first crosslinking agent can include an isocyanate trimer. Specifically, the first cross-linking agent may comprise a structural unit as shown in formula (1),
Figure 02_image001
Formula 1). In some embodiments, the first crosslinking agent may include trimers of aliphatic isocyanates (eg, HDI, TMDI, or XDI), trimers of cycloaliphatic isocyanates (eg, IPDI, HMDI, or HTDI), aromatic isocyanates ( For example TDI or MDI) trimers or combinations thereof. The first crosslinking agent may include an isocyanate block. For example, at least both ends of the isocyanate trimer may have isocyanate blocks. Specifically, in the first crosslinking agent represented by formula (1), any two or more of R 1 , R 2 and R 3 include an isocyanate block.

在一些實施方式中,第二交聯劑與第一交聯劑可具有相同的分子結構。在一些實施方式中,第二交聯劑的添加量與第一交聯劑的添加量的比例可例如介於1:5至1:3間。在一些實施方式中,第二交聯劑與第一交聯劑中的異氰酸酯嵌段的總量與多元醇中羥基的總量的比值可介於1.0至2.5間。In some embodiments, the second cross-linking agent may have the same molecular structure as the first cross-linking agent. In some embodiments, the ratio of the added amount of the second cross-linking agent to the added amount of the first cross-linking agent may be, for example, between 1:5 and 1:3. In some embodiments, the ratio of the total amount of isocyanate blocks in the second and first crosslinking agents to the total amount of hydroxyl groups in the polyol may be between 1.0 and 2.5.

在一些實施方式中,感濕收縮墨水120的黏度可介於2.5cP至10.0cP間,使得噴印出的墨水液滴可具有合適的大小,並可使感濕收縮墨水120具有合適的流動性以利於數位噴印製程。另一方面,感濕收縮墨水120的表面張力可介於22dyne/cm至32dyne/cm間,有利於墨水液滴於噴頭處成形,並可使感濕收縮墨水120具有良好的滲透性。在一些實施方式中,感濕收縮墨水120中的分散質的粒徑(D90)可介於90nm至360nm間,以避免在進行數位噴印製程的過程中發生噴頭阻塞的問題,且可以使感濕收縮墨水120具有較佳的穩定性。上述分散質的粒徑(D90)會影響感濕收縮墨水120的黏度。舉例而言,感濕收縮墨水120中較小的分散質粒徑可使感濕收縮墨水120具有較低的黏度。在一些實施方式中,感濕收縮墨水120在25℃時的pH值可介於6.0至8.5間,從而避免腐蝕噴印裝置的噴頭,且可避免墨水液滴沉積於噴頭處而造成堵塞,有利於數位噴印製程。In some embodiments, the viscosity of the moisture-shrinkable ink 120 can be between 2.5 cP and 10.0 cP, so that the ink droplets printed can have a suitable size and the moisture-shrinkable ink 120 can have a suitable fluidity In order to facilitate the digital printing process. On the other hand, the surface tension of the moisture shrinkable ink 120 can be between 22 dyne/cm and 32 dyne/cm, which is beneficial to the formation of ink droplets at the nozzle and enables the moisture shrinkage ink 120 to have good permeability. In some embodiments, the particle size (D90) of the dispersoid in the moisture-sensitive shrinkage ink 120 may be between 90 nm and 360 nm, so as to avoid the problem of nozzle clogging during the digital printing process, and to make the The wet shrinkage ink 120 has better stability. The particle size (D90) of the above-mentioned dispersoid will affect the viscosity of the moisture-shrinking ink 120 . For example, the smaller particle size of the dispersoid in the moisture-shrinkable ink 120 can make the moisture-shrinkable ink 120 have a lower viscosity. In some embodiments, the pH value of the moisture-sensitive shrinkable ink 120 at 25° C. can be between 6.0 and 8.5, so as to avoid corrosion of the print head of the printing device and prevent ink droplets from depositing at the print head to cause clogging, which is beneficial. in the digital printing process.

在一些實施方式中,感濕收縮墨水120可更包括5重量份至10重量份的保濕劑、0.004重量份至0.060重量份的界面活性劑及/或0.002重量份至0.020重量份的消泡劑。保濕劑可確保感濕收縮墨水120在噴印的過程中不會因凝結而沉積或阻塞噴頭;界面活性劑可維持感濕收縮墨水120中的粒子(例如感濕收縮樹脂、保濕劑等)的尺寸安定;消泡劑則可以確保感濕收縮墨水120中不具有泡沫。在一些實施方式中,保濕劑可例如是丙三醇、二甘醇、丙二醇甲醚或其組合。在一些實施方式中,界面活性劑可例如是聚二甲基矽氧烷、聚醚改性矽氧烷、聚醚改性聚二甲基矽氧烷或其組合。在一些實施方式中,消泡劑可例如是聚醚改性聚二甲基矽氧烷、破泡聚矽氧烷、溶於聚乙二醇中的破泡聚矽氧烷與憎水顆粒混合物或其組合。In some embodiments, the moisture shrinkage ink 120 may further include 5 to 10 parts by weight of a moisturizing agent, 0.004 to 0.060 parts by weight of a surfactant, and/or 0.002 to 0.020 parts by weight of a defoaming agent . The humectant can ensure that the hygroscopic ink 120 will not deposit or block the nozzle due to condensation during the printing process; the surfactant can maintain the particles (such as hygroscopic resin, moisturizing agent, etc.) The size is stable; the defoamer can ensure that there is no foam in the moisture shrinkable ink 120 . In some embodiments, the humectant may be, for example, glycerol, diethylene glycol, propylene glycol methyl ether, or a combination thereof. In some embodiments, the surfactant may be, for example, polydimethylsiloxane, polyether-modified siloxane, polyether-modified polydimethylsiloxane, or a combination thereof. In some embodiments, the defoaming agent may be, for example, a polyether-modified polydimethylsiloxane, a foam-breaking polysiloxane, a foam-breaking polysiloxane dissolved in polyethylene glycol, and a mixture of hydrophobic particles or a combination thereof.

在一些實施方式中,感濕收縮墨水120可更包括適量的分散劑、適量的酸鹼調整劑以及適量的抑菌劑。分散劑可確保感濕收縮墨水120中的分散質完全地分散,避免產生沉澱物或凝聚物而阻塞噴頭;酸鹼調整劑可確保感濕收縮墨水120的pH值介於6.0至8.5間,以避免感濕收縮墨水120因過度偏酸性或偏鹼性而影響感濕收縮墨水中各成份的溶解性,從而容易形成沉澱物使得噴頭阻塞或造成噴頭腐蝕;抑菌劑可有效地抑制細菌生長。In some embodiments, the moisture-sensitive shrinkage ink 120 may further include an appropriate amount of a dispersant, an appropriate amount of an acid-base modifier, and an appropriate amount of a bacteriostatic agent. The dispersing agent can ensure that the dispersoid in the moisture-shrinking ink 120 is completely dispersed, so as to avoid the formation of precipitates or agglomerates to block the nozzle; the acid-base adjusting agent can ensure that the pH value of the moisture-shrinking ink 120 is between 6.0 and 8.5, so that It is avoided that the moisture-sensitive shrinkage ink 120 is too acidic or alkaline to affect the solubility of each component in the moisture-sensitive shrinkage ink, thereby easily forming sediments that block the nozzle or cause the nozzle to corrode; the bacteriostatic agent can effectively inhibit the growth of bacteria.

在一些實施方式中,感濕收縮墨水120可更包括適量的色料,以使欲噴印的織物呈現出合適的色彩。在一些實施方式中,感濕收縮墨水120中的色料的粒徑(D90)可小於或等於250nm,以使色料有效地滲入至欲噴印的織物中,從而提升色牢度。在一些實施方式中,色料可例如是顏料或染料,且染料可例如是分散染料、高溫型分散性染料、反應性染料或酸性染料。當感濕收縮墨水120中含有色料時,感濕收縮墨水120可藉由數位噴印製程一次性地賦予織物局部或全面的色彩及感濕收縮性能,有效地解決傳統二次加工時因染料遷徙所導致的色牢度下降的問題。In some embodiments, the moisture shrinkable ink 120 may further include an appropriate amount of colorant, so that the fabric to be printed can present a suitable color. In some embodiments, the particle size (D90) of the colorant in the moisture shrinkable ink 120 may be less than or equal to 250 nm, so that the colorant can effectively penetrate into the fabric to be printed, thereby improving color fastness. In some embodiments, the colorant may be, for example, a pigment or dye, and the dye may be, for example, a disperse dye, a high temperature type disperse dye, a reactive dye, or an acid dye. When the moisture-sensitive ink 120 contains a colorant, the moisture-sensitive ink 120 can impart partial or comprehensive color and moisture-shrinking properties to the fabric at one time through the digital jet printing process, effectively solving the problems caused by dyes in traditional secondary processing. The problem of color fastness decline caused by migration.

如前所述,由感濕收縮墨水120所形成的親水區A1可具有多種圖案,以良好地達到感濕變形的效果。請參閱第2A圖、第2B圖、第2C圖以及第2D圖,其繪示根據本揭露不同實施方式的感濕變形織物100的親水區A1的圖案的上視示意圖。在以下敘述中,將針對親水區A1的各種圖案進行更詳細的說明。As mentioned above, the hydrophilic area A1 formed by the moisture-sensitive shrinkage ink 120 can have various patterns, so as to achieve the effect of moisture-sensitive deformation. Please refer to FIGS. 2A , 2B, 2C, and 2D, which are schematic top views of patterns of the hydrophilic area A1 of the moisture-sensitive textured fabric 100 according to various embodiments of the present disclosure. In the following description, various patterns of the hydrophilic region A1 will be described in more detail.

首先,請同時參閱第1圖及第2A圖。在一些實施方式中,親水區A1可包括多個空心圓形圖案P1。換句話說,感濕收縮墨水120經噴塗以於基布110的表面111形成多個空心圓形圖案P1。在一些實施方式中,多個空心圓形圖案P1可呈間隔排列,從而預留空間以供感濕變形織物100產生變形。在一些實施方式中,相鄰的兩空心圓形圖案P1間的最短距離D1可介於4mm至12mm間,且相鄰的兩空心圓形圖案P1各自的圓心O1間的距離D2可介於10mm至14mm間。如此一來,可確保感濕變形織物100整體具有足夠的變形量,並預留足夠的空間以供感濕變形織物100產生變形。詳細而言,若相鄰的兩空心圓形圖案P1間的最短距離D1小於4mm或者兩空心圓形圖案P1各自的圓心O1間的距離D2小於10mm,可能導致兩空心圓形圖案P1間不具有足夠的空間供感濕變形織物100產生變形,易使感濕變形織物100因變形而過度地扭曲,影響使用者的穿戴舒適感;若相鄰的兩空心圓形圖案P1間的最短距離D1大於12mm或者兩空心圓形圖案P1各自的圓心O1間的距離D2大於14mm,可能導致空心圓形圖案P1分佈的密度過低,使得感濕變形織物100整體的變形量不足。First, please refer to both Figure 1 and Figure 2A. In some embodiments, the hydrophilic region A1 may include a plurality of hollow circular patterns P1. In other words, the moisture shrinkable ink 120 is sprayed to form a plurality of hollow circular patterns P1 on the surface 111 of the base fabric 110 . In some embodiments, a plurality of hollow circular patterns P1 may be arranged at intervals, so as to reserve a space for the wet deformation sensitive fabric 100 to be deformed. In some embodiments, the shortest distance D1 between two adjacent hollow circular patterns P1 may be between 4 mm and 12 mm, and the distance D2 between the respective centers O1 of the two adjacent hollow circular patterns P1 may be 10 mm to 14mm. In this way, it can be ensured that the entire wet deformation sensitive fabric 100 has a sufficient deformation amount, and sufficient space is reserved for the wet deformation sensitive fabric 100 to be deformed. In detail, if the shortest distance D1 between the two adjacent hollow circular patterns P1 is less than 4 mm or the distance D2 between the respective centers O1 of the two hollow circular patterns P1 is less than 10 mm, there may be no space between the two hollow circular patterns P1. There is enough space for deformation of the moisture-sensitive deformable fabric 100, which is easy to cause the moisture-sensitive deformable fabric 100 to be excessively twisted due to the deformation, which affects the wearing comfort of the user; if the shortest distance D1 between the adjacent two hollow circular patterns P1 is greater than 12 mm or the distance D2 between the centers O1 of the two hollow circular patterns P1 is greater than 14 mm, which may cause the distribution density of the hollow circular patterns P1 to be too low, resulting in insufficient deformation of the wet deformable fabric 100 as a whole.

在一些實施方式中,空心圓形圖案P1的直徑H可介於5mm至8mm間,且空心圓形圖案P1的線條寬度W可介於1.5mm至3.0mm間。空心圓形圖案P1的直徑H及空心圓形圖案P1的線條寬度W1可影響空心圓形圖案P1的面積,以影響感濕變形織物100整體於吸濕後的變形量。詳細而言,若空心圓形圖案P1的直徑H小於5mm且空心圓形圖案P1的線條寬度W1大於3.0mm,可能導致感濕變形織物100整體的變形面積太大,影響使用者的穿戴舒適感;若空心圓形圖案P1的直徑H大於8mm且空心圓形圖案P1的線條寬度W1小於1.5mm,則可能導致感濕變形織物100整體的變形面積太小,使得感濕變形織物100整體的變形量不足。在一些實施方式中,多個空心圓形圖案P1可進一步呈陣列排列,從而提升感濕變形織物100的變形均勻度。In some embodiments, the diameter H of the hollow circular pattern P1 may be between 5 mm and 8 mm, and the line width W of the hollow circular pattern P1 may be between 1.5 mm and 3.0 mm. The diameter H of the hollow circular pattern P1 and the line width W1 of the hollow circular pattern P1 can affect the area of the hollow circular pattern P1 to affect the deformation amount of the moisture-sensitive deformable fabric 100 as a whole after moisture absorption. In detail, if the diameter H of the hollow circular pattern P1 is less than 5 mm and the line width W1 of the hollow circular pattern P1 is greater than 3.0 mm, the entire deformation area of the moisture-sensitive deformable fabric 100 may be too large, affecting the wearing comfort of the user. ; If the diameter H of the hollow circular pattern P1 is greater than 8 mm and the line width W1 of the hollow circular pattern P1 is less than 1.5 mm, the deformation area of the entire moisture-sensitive deformation fabric 100 may be too small, causing the overall deformation of the moisture-sensitive deformation fabric 100. Insufficient amount. In some embodiments, the plurality of hollow circular patterns P1 can be further arranged in an array, so as to improve the deformation uniformity of the wet deformation-sensitive fabric 100 .

接著,請同時參閱第1圖及第2B圖。在一些實施方式中,多個空心圓形圖案P1可例如呈交錯排列。具體而言,多個空心圓形圖案P1可沿第一方向X1以及第二方向X2排列,且第一方向X1與第二方向X2的夾角θ介於40度至50度間。在一些實施方式中,多個空心圓形圖案P1可沿第一方向X1及第二方向X2等距地排列。基於上述配置,可使多個空心圓形圖案P1以合適的密度分佈於基布110的表面111,以確保感濕變形織物100於吸濕後具有一定程度的變形量。應瞭解到,相鄰的兩空心圓形圖案P1間的最短距離D1、相鄰的兩空心圓形圖案P1各自的圓心O1間的距離D2以及空心圓形圖案P1的直徑H與線條寬度W1皆可參照第2A圖的實施方式,於此便不再贅述。Next, please refer to Figure 1 and Figure 2B at the same time. In some embodiments, the plurality of hollow circular patterns P1 may be arranged in a staggered manner, for example. Specifically, the plurality of hollow circular patterns P1 can be arranged along the first direction X1 and the second direction X2, and the included angle θ between the first direction X1 and the second direction X2 is between 40 degrees and 50 degrees. In some embodiments, the plurality of hollow circular patterns P1 may be arranged at equal distances along the first direction X1 and the second direction X2. Based on the above configuration, a plurality of hollow circular patterns P1 can be distributed on the surface 111 of the base fabric 110 at a suitable density to ensure that the moisture-sensitive deformable fabric 100 has a certain degree of deformation after absorbing moisture. It should be understood that the shortest distance D1 between the two adjacent hollow circular patterns P1, the distance D2 between the respective circle centers O1 of the two adjacent hollow circular patterns P1, and the diameter H and line width W1 of the hollow circular pattern P1 are all Reference may be made to the embodiment in FIG. 2A , which will not be repeated here.

隨後,請同時參閱第1圖及第2C圖。在一些實施方式中,親水區A1可包括多個空心六邊形圖案P2,且相鄰的兩空心六邊形圖案P2共用各自的其中一個邊。換句話說,多個空心六邊形圖案P2於基布110的表面111形成蜂巢狀的圖案。在一些實施方式中,相鄰的兩空心六邊形圖案P2各自的中心O2間的距離D3可介於8mm至16mm間。如此一來,可確保感濕變形織物100整體具有足夠的變形量,並預留足夠的空間以供感濕變形織物100產生變形。在一些實施方式中,空心六邊形圖案P2的線條寬度W2可介於1.5mm至3.0mm間。詳細而言,若空心六邊形圖案P2的線條寬度W1大於3.0mm,可能導致感濕變形織物100整體的變形面積太大,影響使用者的穿戴舒適感;若空心六邊形圖案P2的線條寬度W2小於1.5mm,則可能導致感濕變形織物100整體的變形面積太小,使得感濕變形織物100整體的變形量不足。在一些實施方式中,空心六邊形圖案P2的每一個邊長皆相等,亦即空心六邊形圖案P2是空心正六邊形,從而提升感濕變形織物100的變形均勻度。Afterwards, please refer to both Figure 1 and Figure 2C. In some embodiments, the hydrophilic region A1 may include a plurality of hollow hexagonal patterns P2, and two adjacent hollow hexagonal patterns P2 share one of their respective sides. In other words, the plurality of hollow hexagonal patterns P2 form a honeycomb-like pattern on the surface 111 of the base fabric 110 . In some embodiments, the distance D3 between the respective centers O2 of two adjacent hollow hexagonal patterns P2 may be between 8 mm and 16 mm. In this way, it can be ensured that the entire wet deformation sensitive fabric 100 has a sufficient deformation amount, and sufficient space is reserved for the wet deformation sensitive fabric 100 to be deformed. In some embodiments, the line width W2 of the hollow hexagonal pattern P2 may be between 1.5 mm and 3.0 mm. In detail, if the line width W1 of the hollow hexagonal pattern P2 is greater than 3.0 mm, the overall deformation area of the moisture-sensitive deformation fabric 100 may be too large, which affects the wearing comfort of the user; if the lines of the hollow hexagonal pattern P2 If the width W2 is less than 1.5 mm, the deformation area of the entire moisture-deformable fabric 100 may be too small, resulting in insufficient deformation of the entire moisture-deformable fabric 100 . In some embodiments, the length of each side of the hollow hexagonal pattern P2 is equal, that is, the hollow hexagonal pattern P2 is a hollow regular hexagon, so as to improve the deformation uniformity of the wet deformation sensitive fabric 100 .

最後,請同時參閱第1圖及第2D圖。在一些實施方式中,親水區A1可包括多個長條形圖案P3,且多個長條形圖案P3呈平行且間隔排列。在一些實施方式中,長條形圖案P3的線條寬度W3可介於5 mm至20mm間,且相鄰的兩長條形圖案P3間的最短距離D4可介於5mm至20mm間。在上述範圍內,可使感濕變形織物100整體具有足夠的變形量以及良好的變形均勻度。在一些實施方式中,長條形圖案P3的線條寬度W3可與相鄰的兩長條形圖案P3間的最短距離D4實質上相近或相同,且長條形圖案P3可呈等距排列,從而提供感濕變形織物100較佳的變形均勻度。Finally, please refer to both Figure 1 and Figure 2D. In some embodiments, the hydrophilic region A1 may include a plurality of elongated patterns P3, and the plurality of elongated patterns P3 are arranged in parallel and spaced apart. In some embodiments, the line width W3 of the elongated pattern P3 may be between 5 mm and 20 mm, and the shortest distance D4 between two adjacent elongated patterns P3 may be between 5 mm and 20 mm. Within the above range, the entire moisture deformation sensitive fabric 100 can have a sufficient deformation amount and a good deformation uniformity. In some embodiments, the line width W3 of the long strip patterns P3 can be substantially similar to or the same as the shortest distance D4 between two adjacent long strip patterns P3, and the long strip patterns P3 can be arranged at equal distances, so that Provides better deformation uniformity of the wet deformation fabric 100 .

在以下敘述中,將針對本揭露多個實施例的感濕變形織物進行各種測試與評估,以進一步驗證本揭露的功效。 >實驗例1:感濕變形織物的感濕收縮性評估> In the following description, various tests and evaluations will be carried out on the wet deformation fabrics of various embodiments of the present disclosure to further verify the efficacy of the present disclosure. >Experimental example 1: Evaluation of moisture-sensitive shrinkage of moisture-sensitive textured fabric>

在本實驗例中,利用數位噴印製程將感濕收縮墨水噴塗於基布的表面,以形成具有親水區的圖案的感濕變形織物。接著,將感濕變形織物於水中浸濕,並量測與計算感濕變形織物於變形後所產生的平均凹凸深度。在各實施例的感濕變形織物中,基布是由92%的聚脂(PET)纖維與8%的聚氨酯(OP)纖維共同織造而成的針織布,且基布重是180gsm。各實施例的感濕變形織物的其他詳細說明以及量測結果如表一所示。In this experimental example, the moisture-sensitive shrinkage ink was sprayed on the surface of the base fabric by a digital jet printing process to form a moisture-sensitive deformable fabric with a pattern of hydrophilic regions. Next, soak the wet-textured fabric in water, and measure and calculate the average depth of concavo-convex after the wet-textured fabric is deformed. In the wet textured fabrics of each embodiment, the base fabric is a knitted fabric co-woven with 92% polyester (PET) fibers and 8% polyurethane (OP) fibers, and the base fabric weighs 180 gsm. Table 1 shows other detailed descriptions and measurement results of the wet-textured fabrics of each embodiment.

表一 親水區的圖案 圓心間的距離 (mm) 圓的直徑 (mm) 線條寬度 (mm) 平均凹凸深度 (mm) 實施例1 空心圓形圖案 (如第2A圖所示) 10 7 3.0 1.10 實施例2 10 6 2.0 0.93 實施例3 10 5 1.5 0.74 實施例4 12 8 3.0 1.33 實施例5 14 8 3.0 1.34 實施例6 10 8 2.5 1.11 實施例7 10 8 2.0 0.95 實施例8 10 8 1.5 0.75 實施例9 空心圓形圖案 (如第2B圖所示) 10 7 3.0 0.97 實施例10 10 6 2.0 0.83 實施例11 10 5 1.5 0.72 實施例12 12 8 3.0 1.05 實施例13 14 8 3.0 1.05 實施例14 10 8 2.5 1.18 實施例15 10 8 2.0 1.08 實施例16 10 8 1.5 1.34   親水區的圖案 中心間的距離 (mm) 線條寬度 (mm) 平均凹凸深度 (mm) 實施例17 空心六邊形圖案 (如第2C圖所示) 10 3.0 0.37 實施例18 12 3.0 0.71 實施例19 14 3.0 1.10 實施例20 16 3.0 1.08 實施例21 8 2.0 0.41 實施例22 8 1.5 0.39   親水區的圖案 長條形圖案間的最短距離 (mm) 線條寬度 (mm) 平均凹凸深度 (mm) 實施例23 長條形圖案 (如第2D圖所示) 5 5 1.18 實施例24 10 10 3.29 實施例25 15 15 3.68 實施例26 20 20 2.12 實施例27 5 15 2.49 實施例28 10 15 3.86 實施例29 20 15 2.29 實施例30 5 10 2.56 實施例31 15 10 4.26 實施例32 20 10 4.11 Table I Pattern of the hydrophilic zone Distance between circle centers (mm) Diameter of circle (mm) Line width (mm) Average bump depth (mm) Example 1 Hollow circular pattern (as shown in Figure 2A) 10 7 3.0 1.10 Example 2 10 6 2.0 0.93 Example 3 10 5 1.5 0.74 Example 4 12 8 3.0 1.33 Example 5 14 8 3.0 1.34 Example 6 10 8 2.5 1.11 Example 7 10 8 2.0 0.95 Example 8 10 8 1.5 0.75 Example 9 Hollow circular pattern (as shown in Figure 2B) 10 7 3.0 0.97 Example 10 10 6 2.0 0.83 Example 11 10 5 1.5 0.72 Example 12 12 8 3.0 1.05 Example 13 14 8 3.0 1.05 Example 14 10 8 2.5 1.18 Example 15 10 8 2.0 1.08 Example 16 10 8 1.5 1.34 Pattern of the hydrophilic zone Distance between centers (mm) Line width (mm) Average bump depth (mm) Example 17 Hollow hexagon pattern (as shown in Figure 2C) 10 3.0 0.37 Example 18 12 3.0 0.71 Example 19 14 3.0 1.10 Example 20 16 3.0 1.08 Example 21 8 2.0 0.41 Example 22 8 1.5 0.39 Pattern of the hydrophilic zone Shortest distance between strip patterns (mm) Line width (mm) Average bump depth (mm) Example 23 Long bar pattern (as shown in Figure 2D) 5 5 1.18 Example 24 10 10 3.29 Example 25 15 15 3.68 Example 26 20 20 2.12 Example 27 5 15 2.49 Example 28 10 15 3.86 Example 29 20 15 2.29 Example 30 5 10 2.56 Example 31 15 10 4.26 Example 32 20 10 4.11

第3A圖、第3B圖、第3C圖及第3D圖分別繪示具有第2A圖、第2B圖、第2C圖及第2D圖的親水區的圖案的感濕變形織物於吸濕後的側視示意圖。由表一可知,各實施例的感濕變形織物於吸濕後的平均凹凸深度可介於0.37mm至4.26mm間,其中實施例1至16的感濕變形織物的親水區的圖案是空心圓形圖案,且其平均凹凸深度T1介於0.72mm至1.34mm間(如第3A圖以及第3B圖所示);實施例17至22的感濕變形織物的親水區的圖案是空心六邊形圖案,且其平均凹凸深度T2介於0.37mm至1.10mm間(如第3C圖所示);實施例23至32的感濕變形織物的親水區的圖案是長條形圖案,且其平均凹凸深度T3介於1.18mm至4.26mm間(如第3D圖所示),顯示各實施例的感濕變形織物於吸濕後皆具有一定程度的變形量,具有良好的感濕收縮性。整體而言,當親水區的圖案是長條形圖案時,感濕變形織物具有較佳的感濕收縮性。 >實驗例2:不同織物規格的感濕變形織物的感濕收縮性評估> Figures 3A, 3B, 3C and 3D respectively show the side of the moisture-sensitive textured fabric having the patterns of the hydrophilic regions of Figures 2A, 2B, 2C and 2D after moisture absorption View diagram. It can be seen from Table 1 that the average depth of concavo-convex after moisture absorption can be between 0.37 mm and 4.26 mm for the moisture-sensitive textured fabrics of each embodiment, wherein the patterns of the hydrophilic regions of the moisture-sensitive textured fabrics of Examples 1 to 16 are hollow circles. shape pattern, and the average concave-convex depth T1 is between 0.72mm and 1.34mm (as shown in Figure 3A and Figure 3B); the pattern of the hydrophilic area of the wet deformation fabrics of Examples 17 to 22 is a hollow hexagon patterns, and the average uneven depth T2 is between 0.37 mm and 1.10 mm (as shown in Figure 3C); the patterns of the hydrophilic regions of the wet-textured fabrics of Examples 23 to 32 are elongated patterns, and the average unevenness is The depth T3 is between 1.18mm and 4.26mm (as shown in Figure 3D), indicating that the moisture-sensitive textured fabrics of each embodiment have a certain degree of deformation after moisture absorption, and have good moisture-sensitive shrinkage. On the whole, when the pattern of the hydrophilic region is a long strip pattern, the moisture-sensitive deformation fabric has better moisture-sensitive shrinkage. >Experimental example 2: Evaluation of moisture-sensitive shrinkage of wet-textured fabrics with different fabric specifications>

在本實驗例中,利用數位噴印製程將感濕收縮墨水噴塗於不同規格的基布的表面,以形成具有親水區的圖案的感濕變形織物。接著,將感濕變形織物於水中浸濕,並量測以及計算感濕變形織物於變形後所產生的平均凹凸深度。各實施例的感濕變形織物的詳細說明以及量測結果如表二所示。In this experimental example, the moisture-sensitive shrinkage ink was sprayed on the surface of base fabrics of different specifications by a digital spray printing process to form a moisture-sensitive textured fabric with a pattern of hydrophilic regions. Next, soak the moisture-textured fabric in water, and measure and calculate the average depth of concave-convex after the moisture-textured fabric is deformed. The detailed description and measurement results of the wet deformation fabrics of each embodiment are shown in Table 2.

表二   平均凹凸深度 (mm) 100%PET 單面針織布 230 gsm 92%PET+8%OP 單面針織布 180 gsm 92%PET+8%OP 單面針織布 292 gsm 92%PET+8%OP 單面針織布 250 gsm 100%PET 雙面針織布230 gsm 實施例33 (親水區的圖案同實施例4) 2.32 1.33 1.65 1.63 0.65 實施例34 (親水區的圖案同實施例5) 1.90 1.34 1.29 2.01 0.76 實施例35 (親水區的圖案同實施例6) 2.11 1.11 0.86 1.23 0.49 實施例36 (親水區的圖案同實施例12) 1.45 1.05 0.87 1.39 0.54 實施例37 (親水區的圖案同實施例16) 1.86 1.34 0.47 0.69 0.34 實施例38 (親水區的圖案同實施例25) 5.65 3.68 3.88 1.34 1.13 實施例39 (親水區的圖案同實施例28) 4.45 3.86 5.09 0.99 1.09 實施例40 (親水區的圖案同實施例31) 3.94 4.26 3.43 1.46 1.19 實施例41 (親水區的圖案同實施例32) 2.46 4.11 3.44 1.43 3.02 Table II Average bump depth (mm) 100%PET single jersey 230 gsm 92%PET+8%OP single jersey 180 gsm 92%PET+8%OP single jersey 292 gsm 92%PET+8%OP single jersey 250 gsm 100%PET Double Knit Fabric 230 gsm Example 33 (pattern of hydrophilic region is the same as Example 4) 2.32 1.33 1.65 1.63 0.65 Example 34 (pattern of hydrophilic region is the same as Example 5) 1.90 1.34 1.29 2.01 0.76 Example 35 (pattern of hydrophilic region is the same as Example 6) 2.11 1.11 0.86 1.23 0.49 Example 36 (the pattern of the hydrophilic region is the same as that of Example 12) 1.45 1.05 0.87 1.39 0.54 Example 37 (pattern of hydrophilic region is the same as Example 16) 1.86 1.34 0.47 0.69 0.34 Example 38 (the pattern of the hydrophilic region is the same as that of Example 25) 5.65 3.68 3.88 1.34 1.13 Example 39 (pattern of hydrophilic region is the same as Example 28) 4.45 3.86 5.09 0.99 1.09 Example 40 (pattern of hydrophilic region is the same as Example 31) 3.94 4.26 3.43 1.46 1.19 Example 41 (the pattern of the hydrophilic region is the same as that of Example 32) 2.46 4.11 3.44 1.43 3.02

由表二可知,實施例33至41的感濕變形織物於吸濕後所產生的平均凹凸深度可介於0.34至5.65間,顯示具有一定程度的變形量。換句話說,本揭露的感濕收縮墨水可利用數位噴印製程噴塗於不同規格的基布上,且所製得的感濕變形織物皆可具有良好的感濕收縮性。 >實驗例3:感濕變形織物的黏膩性評估> It can be seen from Table 2 that the moisture-sensitive textured fabrics of Examples 33 to 41 have an average concave-convex depth of 0.34 to 5.65 after moisture absorption, indicating a certain degree of deformation. In other words, the moisture-sensitive shrinkage ink of the present disclosure can be sprayed on base fabrics of different specifications by a digital jet printing process, and the obtained moisture-sensitive textured fabrics can all have good moisture-sensitive shrinkage properties. >Experimental Example 3: Evaluation of Tackiness of Wet Deformation Fabrics>

在本實驗例中,分別對比較例1的織物及表一中部分的實施例的感濕變形織物進行拉伸黏滯力測試,其中比較例1的織物是由92%的聚脂纖維與8%的聚氨酯纖維共同織造而成的針織布。測試方法是將比較例的織物以及各實施例的感濕變形織物於水中浸濕,並分別將比較例的織物及各實施例的感濕變形織物放置於人工皮膚上,接著對比較例的織物及各實施例的感濕變形織物進行拉伸,其中拉伸的方向平行於織物的羅紋(rib)方向。測試結果如表三所示。In this experimental example, the tensile viscosity test was performed on the fabric of Comparative Example 1 and the wet deformation fabric of some examples in Table 1, wherein the fabric of Comparative Example 1 was made of 92% polyester fiber and 8 % Polyurethane fiber co-woven knitted fabric. The test method is to soak the fabric of the comparative example and the moisture-deformable fabric of each example in water, and place the fabric of the comparative example and the moisture-deformable fabric of each example on the artificial skin, and then test the fabric of the comparative example. and the wet texturing fabrics of each example were stretched, wherein the direction of stretching was parallel to the rib direction of the fabric. The test results are shown in Table 3.

表三 拉伸黏滯力 (gf) 比較例1 480 實施例3 150 實施例5 170 實施例11 190 實施例16 250 實施例17 150 實施例19 130 實施例23 90 實施例31 150 Table 3 Tensile viscosity (gf) Comparative Example 1 480 Example 3 150 Example 5 170 Example 11 190 Example 16 250 Example 17 150 Example 19 130 Example 23 90 Example 31 150

由表三可知,相較於比較例的織物,各實施例的感濕變形織物皆可透過較小的拉伸黏滯力以與人工皮膚彼此分離。也就是說,各實施例的感濕變形織物於感濕變形後不易黏滯於使用者身體,有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。It can be seen from Table 3 that, compared with the fabrics of the comparative example, the moisture-sensitive and deformable fabrics of each example can be separated from the artificial skin through a smaller tensile viscous force. That is to say, the moisture-sensitive deformable fabric of each embodiment is not easy to stick to the user's body after the moisture-sensitive deformation, which is helpful for the volatilization of sweat and reduces the stickiness of the user's body, thereby providing the user with a good wearing comfort. .

根據本揭露上述實施方式,本揭露的感濕變形織物具有由感濕收縮墨水噴塗而成的親水區。透過親水區的配置,感濕變形織物可在吸濕後局部地產生變形,以於感濕變形織物與使用者身體間產生立體空間,從而減少感濕變形織物與使用者身體間的接觸。如此一來,可有助於汗水的揮發並降低使用者身體的黏膩感,從而提供使用者良好的穿戴舒適感。另一方面,透過親水區的圖案的設計,可進一步提升感濕變形織物的感濕收縮性。According to the above embodiments of the present disclosure, the moisture-sensitive deformation fabric of the present disclosure has a hydrophilic region sprayed with moisture-sensitive shrinkage ink. Through the configuration of the hydrophilic area, the moisture-sensitive textured fabric can be deformed locally after absorbing moisture, so as to create a three-dimensional space between the moisture-sensitive textured fabric and the user's body, thereby reducing the contact between the moisture-sensitive textured fabric and the user's body. In this way, the volatilization of sweat can be facilitated and the stickiness of the user's body can be reduced, thereby providing the user with a good wearing comfort. On the other hand, through the design of the pattern of the hydrophilic area, the moisture shrinkage of the moisture sensitive textured fabric can be further improved.

雖然本揭露已以實施方式揭露如上,然其並非用以限定本揭露,任何熟習此技藝者,在不脫離本揭露之精神和範圍內,當可作各種之更動與潤飾,因此本揭露之保護範圍當視後附之申請專利範圍所界定者為準。Although the present disclosure has been disclosed as above in embodiments, it is not intended to limit the present disclosure. Anyone skilled in the art can make various changes and modifications without departing from the spirit and scope of the present disclosure. Therefore, the present disclosure protects The scope shall be determined by the scope of the appended patent application.

100:感濕變形織物 110:基布 111,113:表面 120:感濕收縮墨水 A1:親水區 P1:圓形圖案 P2:六邊形圖案 P3:長條形圖案 O1:圓心 O2:中心 D1,D4:最短距離 D2,D3:距離 H:直徑 W1,W2,W3:線條寬度 T1~T3:平均凹凸深度 X1:第一方向 X2:第二方向 θ:夾角100: Moisture textured fabric 110: base cloth 111, 113: Surface 120: Moisture shrinkage ink A1: Hydrophilic area P1: circular pattern P2: Hexagonal pattern P3: long strip pattern O1: center of circle O2: Center D1, D4: shortest distance D2, D3: distance H: diameter W1,W2,W3: Line width T1~T3: Average bump depth X1: first direction X2: the second direction θ: included angle

為讓本揭露之上述和其他目的、特徵、優點與實施例能更明顯易懂,所附圖式之說明如下: 第1圖繪示根據本揭露一些實施方式的感濕變形織物的側視示意圖; 第2A圖、第2B圖、第2C圖及第2D圖繪示根據本揭露不同實施方式的感濕變形織物的親水區的圖案的上視示意圖;以及 第3A圖、第3B圖、第3C圖及第3D圖分別繪示具有第2A圖、第2B圖、第2C圖及第2D圖的親水區的圖案的感濕變形織物於吸濕後的側視示意圖。 In order to make the above and other objects, features, advantages and embodiments of the present disclosure more clearly understood, the accompanying drawings are described as follows: FIG. 1 is a schematic side view of a moisture-sensitive textured fabric according to some embodiments of the present disclosure; Figures 2A, 2B, 2C, and 2D are schematic top views illustrating patterns of hydrophilic regions of moisture-textured fabrics according to various embodiments of the present disclosure; and Figures 3A, 3B, 3C and 3D respectively show the side of the moisture-sensitive textured fabric having the patterns of the hydrophilic regions of Figures 2A, 2B, 2C and 2D after moisture absorption View diagram.

國內寄存資訊(請依寄存機構、日期、號碼順序註記) 無 國外寄存資訊(請依寄存國家、機構、日期、號碼順序註記) 無 Domestic storage information (please note in the order of storage institution, date and number) none Foreign deposit information (please note in the order of deposit country, institution, date and number) none

100:感濕變形織物 100: Moisture textured fabric

110:基布 110: base cloth

111,113:表面 111, 113: Surface

120:感濕收縮墨水 120: Moisture shrinkage ink

A1:親水區 A1: Hydrophilic area

Claims (10)

一種感濕變形織物,包括: 基布;以及 感濕收縮墨水,利用數位噴印製程噴塗於所述基布的任一表面,其中所述感濕收縮墨水於所述基布的所述表面形成親水區。 A wet textured fabric comprising: base cloth; and The moisture-sensitive shrinkage ink is sprayed on any surface of the base fabric by a digital printing process, wherein the moisture-sensitive shrinkage ink forms a hydrophilic area on the surface of the base fabric. 如請求項1所述的感濕變形織物,其中所述感濕收縮墨水具有介於2.5cP至10.0cP間的黏度以及介於22dyne/cm至32dyne/cm間的表面張力,且所述感濕收縮墨水包括15重量份至35重量份的感濕收縮樹脂以及65重量份至85重量份的水。The moisture-sensitive texturing fabric of claim 1, wherein the moisture-sensitive shrinkage ink has a viscosity between 2.5 cP and 10.0 cP and a surface tension between 22 dyne/cm and 32 dyne/cm, and the moisture-sensitive shrinkage ink has a viscosity between 2.5 cP and 10.0 cP. The shrinkage ink includes 15 to 35 parts by weight of a moisture-sensitive shrinkage resin and 65 to 85 parts by weight of water. 如請求項2所述的感濕變形織物,其中所述感濕收縮樹脂是藉由包括以下試劑製備而成: 多元醇; 多元胺; 第一交聯劑,包括異氰酸酯嵌段;以及 第二交聯劑,包括異氰酸酯嵌段。 The moisture-sensitive textured fabric according to claim 2, wherein the moisture-sensitive shrinkage resin is prepared by including the following reagents: Polyol; polyamine; a first crosslinking agent, including an isocyanate block; and The second crosslinking agent includes an isocyanate block. 如請求項1所述的感濕變形織物,其中所述親水區包括多個空心圓形圖案,且所述空心圓形圖案呈間隔排列。The moisture deformable fabric according to claim 1, wherein the hydrophilic region comprises a plurality of hollow circular patterns, and the hollow circular patterns are arranged at intervals. 如請求項4所述的感濕變形織物,其中所述空心圓形圖案呈陣列排列。The moisture deformable fabric of claim 4, wherein the hollow circular patterns are arranged in an array. 如請求項4所述的感濕變形織物,其中所述空心圓形圖案沿第一方向及第二方向排列,且所述第一方向與所述第二方向的夾角介於40度至50度間。The moisture deformable fabric according to claim 4, wherein the hollow circular patterns are arranged along a first direction and a second direction, and the included angle between the first direction and the second direction is between 40 degrees and 50 degrees. between. 如請求項1所述的感濕變形織物,其中所述親水區包括多個空心六邊形圖案,且相鄰的兩所述空心六邊形圖案共用各自的其中一邊。The moisture deformable fabric according to claim 1, wherein the hydrophilic region comprises a plurality of hollow hexagonal patterns, and two adjacent hollow hexagonal patterns share one side of each. 如請求項7所述的感濕變形織物,其中所述空心六邊形圖案的每一邊長皆相等。The wet textured fabric of claim 7, wherein each side of the hollow hexagonal pattern is equal in length. 如請求項1所述的感濕變形織物,其中所述親水區包括多個長條形圖案,且所述長條形圖案呈平行排列。The moisture deformable fabric according to claim 1, wherein the hydrophilic region comprises a plurality of elongated patterns, and the elongated patterns are arranged in parallel. 如請求項9所述的感濕變形織物,其中所述長條形圖案呈等距排列。The moisture-textured fabric of claim 9, wherein the elongated patterns are equidistantly arranged.
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