CN111910328A - Moisture-absorbing and sweat-releasing fabric and preparation process thereof - Google Patents

Moisture-absorbing and sweat-releasing fabric and preparation process thereof Download PDF

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Publication number
CN111910328A
CN111910328A CN201910374971.5A CN201910374971A CN111910328A CN 111910328 A CN111910328 A CN 111910328A CN 201910374971 A CN201910374971 A CN 201910374971A CN 111910328 A CN111910328 A CN 111910328A
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yarn
fiber
dyeing
sweat
moisture
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黄庆强
薛永亮
徐国华
钟家彰
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Dongguan Shili Textile Co ltd
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Dongguan Shili Textile Co ltd
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
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    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507Polyesters
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6131Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
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    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
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    • D10B2401/00Physical properties
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Abstract

The invention relates to the technical field of garment fabrics, in particular to a moisture absorption and sweat releasing fabric and a preparation process thereof, wherein the moisture absorption and sweat releasing fabric is formed by laminating surface yarns, elastic fiber yarns and bottom yarns, the back yarns formed by lamination form a surface layer, the elastic fiber yarns form an elastic middle layer, and the bottom yarns form a bottom layer; the veil is formed by blending 60-80% of viscose fiber and 20-40% of acrylic fiber with yarn count of 40-50S/1; the elastic fiber yarn is low-temperature spandex with the fineness of 30-60D; the ground yarn is a polypropylene fiber with fineness of 45-75D and hole number of 45-75F. According to the invention, three yarn layers are formed in the prepared fabric by blending and weaving three yarn fibers, the middle layer has elasticity, the wearing comfort and the skin-friendly performance of the fabric are improved, the fabric has the functions of environmental protection, heat preservation, machine washing, non-ironing and the like, and the fabric is good in air permeability, high in moisture volatilization rate, good in quick-drying performance, free of stuffy feeling and skin-sticking feeling, and comfortable to wear.

Description

Moisture-absorbing and sweat-releasing fabric and preparation process thereof
Technical Field
The invention relates to the technical field of clothing fabrics, in particular to a moisture-absorbing and sweat-releasing fabric and a preparation process thereof.
Background
The fabric on the market at present is mostly formed by weaving two threads, the fabric is usually formed by a drawing frame yarn and a polyester yarn, the fabric formed by weaving three threads is not common, meanwhile, the polyester yarn is a long fiber yarn, and the fabric woven by the polyester yarn has poor fitting performance and comfort, so that the wearing comfort of the fabric is influenced; the quick-drying property is low, and the volatility of the moisture after the moisture is absorbed on the surface of the fabric is not high, so that the fabric has an adhesive feeling, and the wearing comfort is reduced; on the other hand, the dyeing effect of the fabrics such as the conventional two-wire knitted stentering yarns, polyester yarns and the like is poor, and the problems of color loss, color change and the like are easily caused after washing or sweat stain absorption.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide the moisture-absorbing and sweat-releasing fabric, the three yarn layers are sequentially formed on the prepared fabric by blending and weaving three yarn fibers, the middle layer has elasticity, the wearing comfort and the skin-friendly performance of the fabric are improved, the fabric has the functions of environmental protection, heat preservation, machine washing, non-ironing and the like, and the fabric is good in air permeability, high in moisture volatilization rate, good in quick-drying performance, free of stuffy feeling and skin-sticking feeling and comfortable to wear.
The invention also aims to provide a preparation process of the moisture-absorbing and sweat-releasing fabric, which has the advantages of convenient operation control, stable quality, high production efficiency and low production cost, can ensure that the prepared fabric is soft and comfortable, is skin-friendly and breathable, has high color fastness, is not easy to deform or decolor after washing, has high stability and is suitable for large-scale industrial production by strictly controlling all steps and condition parameters.
The purpose of the invention is realized by the following technical scheme: the moisture-absorbing and sweat-releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns, elastic fiber yarns and bottom yarns, the surface yarns form a surface layer after the composite yarns are laminated and formed, the elastic fiber yarns form an elastic middle layer, and the bottom yarns form a bottom layer.
The moisture-absorbing and sweat-releasing fabric is formed by blending and weaving the three yarn fibers, the three yarn layers are sequentially formed on the prepared fabric, the middle layer has elasticity, the wearing comfort and the skin-friendly performance of the fabric are improved, the moisture-absorbing and sweat-releasing fabric has the functions of environmental protection, heat preservation, machine washing, non-ironing and the like, and is good in air permeability, high in moisture volatilization rate, good in quick-drying performance, free of stuffy feeling and skin-sticking feeling and comfortable to wear.
Preferably, the veil is formed by blending 60-80% of viscose fiber and 20-40% of acrylic fiber with yarn count of 40-50S/1 according to the weight percentage; the elastic fiber yarn is low-temperature spandex with the fineness of 30-60D; the bottom yarn is polypropylene fiber with fineness of 45-75D and hole number of 45-75F.
The face yarn is formed by compounding and blending the acrylic fibers and the viscose fibers, is soft and skin-friendly, can improve the elasticity and the skin-friendly property of the fabric, can ensure that the prepared fabric has higher hygroscopicity and moisture quick-drying property, is comfortable to wear, and does not generate skin-sticky feeling; the adopted acrylic fiber is fluffy and soft, light in weight, warm-keeping, easy to wash and dry, bright in dyeing, excellent in sunlight resistance and weather resistance, good in light resistance, and capable of reducing the strength by only 20% after being exposed to the sun for one year in the open, and the sun-proof durability of the fabric can be improved, and the acrylic fiber is resistant to acid, oxidant and organic solvent, so that the prepared fabric is not easy to corrode and damage and is good in durability; the viscose fibers are fiber molecules extracted and remolded from natural wood cellulose, have excellent hygroscopicity, the hygroscopicity meets the physiological requirements of human skin, and the viscose fibers have the characteristics of smoothness, coolness, air permeability, static resistance, ultraviolet resistance, gorgeous color, good dyeing fastness and the like, and can improve the moisture absorption and sweat releasing performance of the fabric.
The low-temperature spandex is used as the elastic fiber of the middle layer, belongs to a linear block copolymer, and has high elasticity, good low-temperature setting effect, good anti-curling property, good moldability, low carbon, environmental protection and environmental friendliness; the molecular structure of the low-temperature spandex contains two chain segments, wherein one chain segment is a soft chain segment, so that the fiber has higher elasticity, the elastic elongation performance and the soft habit of the fabric are improved, and the other chain segment is a hard chain segment, so that the fiber has higher intermolecular interaction force, the breaking strength and the heat setting performance of the fabric are improved, and the fabric is ensured to have certain use strength.
When the same heat setting efficiency is achieved, the low-temperature spandex with the same denier number is 15-20 ℃ lower than the conventional spandex, so that the processing efficiency of the low-temperature spandex is improved, the processing energy consumption and cost are reduced, and the low-carbon and environment-friendly effects are achieved; in addition, the fabric adopting low-temperature spandex does not generate the phenomenon of curling in the processing process, but the fabric adopting conventional spandex has serious curling; after washing, the low-temperature spandex has low shrinkage and good dimensional stability, the setting effect is good, wrinkles are not easy to generate, and the non-ironing effect is achieved.
The polypropylene fiber is used as the ground yarn, so that the elastic and size stability is better, the pilling and deformation are not easy to occur after the fabric is worn for many times and washed by water, the initial modulus and the friction coefficient are lower, the abrasion resistance is better, the antistatic performance is good, the hand feeling is fine and soft, the prepared ground yarn has better softness and skin-friendly performance, and the wearing comfort of the fabric is improved.
Preferably, the yarn length density of the face yarn is 26-36cm/100g, the yarn length density of the elastic fiber yarn is 10-15cm/100g, and the yarn length density of the ground yarn is 25-35cm/100 g.
The invention can lead the prepared fabric to have better weaving tightness, difficult fracture or wiredrawing, high elasticity, good skin-friendly property, comfortable wearing, environment protection, warm keeping, machine washing, non-ironing and other functions, good air permeability, high moisture retention, fast water volatilization, no feeling of stuffiness and skin adhesion and comfortable wearing by strictly controlling the yarn length and the density of each yarn.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively blending the surface yarn, the elastic fiber yarn and the bottom yarn, and carrying out three-thread weaving to obtain a blank cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 90-100 ℃ for heat treatment for 15-25 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
The preparation process of the moisture-absorbing and sweat-releasing fabric has the advantages of convenience in operation and control, stable quality, high production efficiency and low production cost, and can ensure that the prepared fabric is soft and comfortable, is skin-friendly and breathable, has high moisture absorption, high color fastness and high stability, is not easy to deform or decolor during washing by strictly controlling various steps and condition parameters, and is suitable for large-scale industrial production.
The fabric blank is pre-shaped, so that the low-temperature spandex fiber in the fabric blank can be subjected to blank fixing, the phenomena of uneven shrinkage and excessive shrinkage of the spandex fiber in the subsequent dyeing process are prevented, the phenomena of shrinkage, wrinkle generation, pull mark, chicken mark grabbing and the like of the fabric are avoided, the wool fiber, the acrylic fiber, the viscose fiber and the polypropylene fiber are subjected to blank fixing, the problems of shrinkage or wrinkle and the like of the fiber in subsequent dyeing, shaping and washing in use are prevented, the fabric is flat, straight and smooth, and the effect of non-ironing is achieved.
Wherein, the grey cloth is boiled in the dyeing process, so that the color absorbing capacity of the cloth in the subsequent dyeing can be improved; the subsequent twice dyeing of the cloth can enable the cloth to efficiently absorb the dye after the cloth is boiled, and the dyeing efficiency is improved, wherein the acrylic fiber is dyed by adopting the first dye solution, the viscose fiber is dyed by adopting the second dye solution, and the acrylic fiber and the viscose fiber of the veil layer can be uniformly dyed by adopting the respective dyeing treatment which is carried out twice, if a single dye is adopted to dye different fibers, if only the cationic fiber is adopted to dye, the adhesive force of the dye to the viscose fiber is lower, so that the dyeing rate of the viscose fiber is lower, the dye is easy to fall off from the viscose fiber in the subsequent process or the using process of the product, and the color fastness of the finished product is obviously reduced; similarly, if the face yarn layer is dyed by adopting the reactive dye, the adhesion of the dye to the acrylic fiber and the internal diffusion performance of the fiber are low, the dye is easy to fall off from the acrylic fiber in the subsequent process or the using process, and the color fastness of the finished product is obviously reduced.
And the dyeing is followed by peracid cold line treatment, soaping and non-softening cold line treatment, so that the dye system in the dyeing process can be neutralized, the adhesion of the dye on the fiber and the color fastness of a finished product are improved, the dye which is not stably and firmly attached to the fiber is washed away, and the color floating phenomenon is avoided (for example, a first dye solution which is not stably attached to the viscose fiber and part of a second dye solution are washed away, and a second dye solution which is not stably attached to the acrylic fiber and part of the first dye solution are washed away).
The temperature and time of the cloth boiling, dyeing and shaping treatments are strictly controlled, so that the absorption efficiency of the cloth to the dye can be improved, and the color fastness of the cloth can be improved; if the temperature is too low and the time is too short, the absorption efficiency of the dye by the cloth is reduced.
Preferably, in the step B, the pre-setting temperature of the temperature-rising heat-setting treatment is 110-130 ℃, and the pre-setting speed is 15-25 m/min. In the step E, the setting temperature is 100-.
The invention can effectively shape the fiber in the fabric by strictly controlling the temperature and speed of pre-shaping, improve the strength of the fiber and prevent the fiber from shrinking, generating wrinkles, drawing marks, chicken-catching marks and other bad phenomena in the subsequent dyeing, shaping and washing processes.
The invention can effectively fix and shape the dyed cloth by strictly controlling the shaping temperature and speed, and can be crosslinked with dye and fiber, thereby improving the adhesive force of the dye on the cloth fiber and effectively improving the color fastness of the cloth.
Preferably, in the step D, the peracid cold line treatment is carried out for 10-20min by using glacial acetic acid; the soaping treatment adopts a GC-9001 type soaping agent in a megaday; the non-softening cold line treatment adopts citric acid for cold line for 15-25 min.
The method adopts glacial acetic acid to perform peracid cooling, neutralizes alkalinity released in the dyeing process of the reactive dye, and avoids the problem that the reactive dye is difficult to attach to fibers due to the excess alkalinity; by soaping the cloth after peracid cold running, the reactive dye which is not firmly combined with the fiber can be fully washed away, the loose color of the cloth is removed, and the color fastness is improved; and citric acid is adopted to carry out non-softening cold treatment, and the citric acid is crosslinked with fibers, so that the mechanical properties of the fibers, such as the stretching lightness, are improved.
Preferably, the first soaking and dyeing temperature is 90-100 ℃, the soaking time is 40-50min, the dyeing water bath ratio is 28-32, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000051
Figure BDA0002051327020000061
the raw materials of the types are used as the first dye solution, so that the acrylic fiber dyeing solution can be stably attached to acrylic fibers, the dyeing effect and the color fastness of cloth are improved, the washing resistance is realized, the color is not easy to fade, and the dyeing and coloring of the acrylic fibers of the veil layer are realized; the adopted cationic dye is green and environment-friendly, is dissolved in water to be ionized by combining with a controlled water bath ratio, generates a colored ionic dye with positive charges, is adsorbed on the surface of the acrylic fiber, then is diffused to the inside of the surface of the acrylic fiber, and is combined with an anionic group in the acrylic fiber to form a salt bond, so that the prepared acrylic fiber is dyed, and has high light fastness; the adopted glacial acetic acid and sodium acetate can play a weak-acidic buffering role on a dye system, so that the dissociation of acidic groups in the acrylic fiber caused by over-acidity is avoided, the reduction of the number of anionic groups on the acrylic fiber, the reduction of the Coulomb attraction between the dye and the fiber and the reduction of the dyeing rate caused by the reduction of the number of the anionic groups on the acrylic fiber are avoided; the adopted anti-settling agent can prevent the ionic dye from coagulating and precipitating, has strong dispersing capacity, can improve the dyeing rate of the particle dye on the fiber, and has better acid resistance, alkali resistance, hard water resistance and emulsifying property; the adopted accelerating agent can increase the adsorption quantity of dye anions and fiber molecules, and promote the absorption efficiency of the cloth to the dye and the adhesive force of the dye.
Because the acrylic fiber contains-NH2Radical, in the acid system of the dye, hydrogen ions H + in glacial acetic acid quickly diffuse into the acrylic fiber and NH2Is combined into NH3+To make the fiber belt straightElectric charge, while the pigment ion of the cationic dye is positively charged D+Because the fiber and pigment ion have the same charge and generate repulsion force between the two, the anhydrous sodium sulfate used is sodium sulfate and sulfate ion SO with negative charge4 2-And NH in fibres3+The cationic dye is adsorbed on the surface of the fiber, and the repulsive force borne by the cationic dye is greatly reduced when the cationic dye is close to the surface of the fiber, so that the energy resistance generated by coulomb force is reduced, the combination of the dye and the fiber is promoted, and the dye-uptake rate is improved.
Preferably, each part of the cationic dye comprises 10-20 parts of cationic golden yellow X-GL, 20-30 parts of cationic red X-RS and 1-4 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 2-5: 1.5-4.5.
The cationic golden yellow X-GL, the cationic red X-RS and the cationic blue X-BS are used as cationic dyes, are easily dissolved in water and ionized in an aqueous solution to form colored ionic dyes with positive charges, are stably combined with acid groups in acrylic fibers, have high light fastness and are not easy to separate, and the cationic golden yellow X-GL, the cationic red X-RS and the cationic blue X-BS are listed cationic dye types, and other cationic dyes have the same combining capacity with the acid groups in the acrylic fibers; the fatty alcohol-polyoxyethylene ether is used as the anti-settling agent, so that the effects of dispersing and emulsifying the dye system are achieved, the dispersion uniformity of the dye is promoted, and the coagulation and precipitation of the dye are prevented; the adopted sodium chloride and sodium sulfate are compounded to be used as a dyeing accelerant, so that the adhesive force and the permeability of the dye can be obviously improved, the dye absorption efficiency of the cloth is promoted, and the dyeing degree is high; the adopted sodium chloride can improve the permeability and dyeing promotion performance of the dye, the adopted fiber has negative charges in aqueous solution, the sodium chloride and sodium sulfate can be ionized in the aqueous solution, cations generated by ionization are small in physical quality and high in activity in the aqueous solution, and the cations are easy to adsorb around fiber molecules, so that negative charges on the surface of the fiber molecules are reduced, the adsorption quantity of dye anions and cellulose molecules is relatively increased, and the dyeing promotion effect is achieved.
Preferably, in the step D, the temperature of the second soaking and dyeing is 55-65 ℃, the soaking time is 55-65min, the dyeing water-bath ratio is 28-32, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000071
each part of the reactive dye comprises 0.5-1.0 part of reactive bright yellow 4GL and 1.0-1.5 parts of reactive emerald G266.
The raw materials of the types are used as the second dye solution, so that the dyeing agent can be stably attached to viscose fibers, the dyeing effect and the color fastness of cloth are improved, the cloth is washable, the color is not easy to fade, and the viscose fibers of the veil layer are dyed and colored; the adopted reactive dye contains a group (active group) capable of reacting with hydroxyl or amino on cellulose fiber (viscose fiber) in a molecular structure, is combined with fiber molecules through a covalent bond, has higher bond energy of the covalent bond and high combination degree with the fiber, can effectively improve the color fastness, the washing fastness and the rubbing fastness of cloth, and is resistant to chlorine bleaching and other oxidation bleaching, and is not easy to fade after being washed for many times.
The adopted Homekator C can improve the solubility and the dispersibility of the dye, promote the fiber swelling and improve the color fixing rate of the dye, and compared with urea in the traditional dye, the Homekator C is biodegradable, green and environment-friendly, can reduce the use of an auxiliary dye, reduce the discharge of nitrogen-containing wastewater and reduce the treatment cost of sewage; the anhydrous sodium sulphate is adopted, because viscose fiber and active dye in the system are both provided with negative charges, repulsive force is generated between the viscose fiber and the active dye, after the anhydrous sodium sulphate of neutral electrolyte is added, ionized cations are adsorbed on the surface of the fiber, the fiber is wrapped by the cations, and the repulsive force borne by dye anions close to the surface of the fiber is greatly weakened, so that the adopted anhydrous sodium sulphate can reduce energy resistance generated by coulomb force and improve dye-uptake rate, and compared with the traditional method of adopting salt to accelerate the active dye, the dyed product is more bright and brighter; and because the cross-linking reaction between the reactive dye and the fiber is carried out in an alkaline medium, the adopted calcium carbonate is alkalescent in a reactive dye system, the hydrolysis of the dye is reduced, the stability of the dye is improved, if the alkalinity of the dye system is too strong, uneven dyeing is easily caused, the dye is hydrolyzed, and the ability of dyeing the fiber is lost after the reactive dye is hydrolyzed.
By adopting the active bright yellow 4GL and the active turquoise blue G266 as the active dyes, the activity is high, the covalent bonding bond energy between the active bright yellow 4GL and the active turquoise blue G266 is higher, the combination degree is high, the color fastness is high, and the fiber has better fastness to washing, rubbing, chlorine bleaching and other oxidation bleaching, and is not easy to fade after being washed for many times.
Preferably, in the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000081
Figure BDA0002051327020000091
according to the invention, the setting agent is prepared from the raw materials, so that the cloth can be effectively set after being dyed for the second time, the crosslinking property of the dye and the fiber is improved, and the color fastness of the cloth is improved; the moisture absorption and perspiration agent has better hydrophilicity and compatibility of auxiliary agents, can improve the water absorption, moisture permeability, quick drying and other properties of the fabric, and enables the prepared fabric to have fluffy and soft texture, good elasticity, comfortable hand feeling, air permeability and perspiration absorption.
The antistatic agent can reduce the friction coefficient of the cloth, so that static electricity is difficult to generate between fibers, and a conductive channel is formed between the fibers, so that charges can be quickly removed from the surfaces of the fibers, and the antistatic effect of the cloth is improved. The citric acid can adjust the pH value of the setting agent, improve the pH value of the soaped cloth and improve the stability, water washing resistance and color fastness of the cloth.
Preferably, the moisture-absorbing and sweat-discharging agent is a polyester-polyether block copolymer; each part of the antistatic agent comprises 0.5-2.5 parts of alkyl bis (alpha-hydroxyethyl amine phosphate), 2-6 parts of polystyrene benzene sulfonic acid and 3-7 parts of alkyl dicarboxymethyl ammonium ethyl lactone.
The polyester-polyether block copolymer is used as the moisture absorption and perspiration agent, the benzene ring with the same structure as the acrylic fiber is arranged in the molecular structure, the molecular chain segment is anchored on the surface of the acrylic fiber under the action of high temperature, so that the original hydrophobic surface of the acrylic fiber is changed into a durable hydrophilic surface, but the water repellency of the acrylic fiber is not changed, so that the absorbed water can be quickly diffused into the atmosphere, the effects of strong moisture absorption and quick water volatilization are achieved, the antistatic property and the water washing resistance of the fabric can be improved by the polyester-polyether block copolymer, and the resistance of the fabric is reduced by 5-8 orders of magnitude compared with the fabric without the polyester-polyether block copolymer.
By adopting the antistatic agent, the friction coefficient of the cloth can be reduced, so that static electricity is difficult to generate between fibers, and a conductive channel is formed between the fibers, so that charges can be quickly removed from the surfaces of the fibers, and the antistatic effect of the cloth is improved; the adopted alkyl bis (alpha-hydroxyethyl amine phosphate) belongs to a multifunctional anionic antistatic agent and has no stimulation to skin, the adopted polystyrene benzene sulfonic acid is a high-molecular anionic antistatic agent, and the alkyl bis (alpha-hydroxyethyl amine phosphate) and the polystyrene benzene sulfonic acid react with an amphoteric antistatic agent (alkyl dicarboxymethyl ammonium ethyl lactone), so that the adhesive force of the antistatic agent to fiber polymers is improved, and the antistatic property of the fiber polymers can be improved.
The invention has the beneficial effects that: the moisture-absorbing and sweat-releasing fabric is formed by blending and weaving the three yarn fibers, the three yarn layers are sequentially formed on the prepared fabric, the middle layer has elasticity, the wearing comfort and the skin-friendly performance of the fabric are improved, the moisture-absorbing and sweat-releasing fabric has the functions of environmental protection, heat preservation, machine washing, non-ironing and the like, and is good in air permeability, high in moisture volatilization rate, good in quick-drying performance, free of stuffy feeling and skin-sticking feeling and comfortable to wear.
The preparation process of the moisture-absorbing and sweat-releasing fabric has the advantages of convenience in operation and control, stable quality, high production efficiency and low production cost, and can ensure that the prepared fabric is soft and comfortable, is skin-friendly and breathable, has high color fastness, is not easy to deform or decolor after washing, has high stability and is suitable for large-scale industrial production by strictly controlling each step and condition parameters.
Drawings
FIG. 1 is a perspective view of the present invention;
FIG. 2 is an enlarged schematic view of portion B of FIG. 1 in accordance with the present invention;
FIG. 3 is an enlarged schematic view of portion B of FIG. 2 in accordance with the present invention;
the reference signs are: 1-face yarn, 2-elastic fiber yarn and 3-bottom yarn.
Detailed Description
For the understanding of those skilled in the art, the present invention will be further described with reference to the following examples and accompanying drawings 1 to 3, and the content of the embodiments is not intended to limit the present invention.
Example 1
Referring to fig. 1-3, the moisture absorption and sweat releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns 1, elastic fiber yarns 2 and bottom yarns 3, the surface yarns 1 form a surface layer after lamination, the elastic fiber yarns 2 form an elastic middle layer, and the bottom yarns 3 form a bottom layer; the veil 1 is formed by blending 70 percent of viscose fiber and 30 percent of acrylic fiber with 40S/1 yarn count according to the weight percentage; the elastic fiber yarn 2 is low-temperature spandex with the fineness of 33D; the ground yarn 3 is a polypropylene fiber having a fineness of 50D and a hole number of 72F.
The yarn length density of the face yarn 1 is 26cm/100g, the yarn length density of the elastic fiber yarn 2 is 13.5cm/100g, and the yarn length density of the ground yarn 3 is 25cm/100 g.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 90 ℃ for heat treatment for 25 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 110 ℃, and the presetting speed is 25 m/min. And in the step E, the setting temperature is 100 ℃, and the setting speed is 22 m/min.
In the step D, the first soaking and dyeing temperature is 90 ℃, the soaking time is 50min, the dyeing water-bath ratio is 28, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000111
each part of the cationic dye comprises 10 parts of cationic golden yellow X-GL, 20 parts of cationic red X-RS and 1 part of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 2: 1.5.
In the step D, the temperature of the second soaking and dyeing is 55 ℃, the soaking time is 65min, the dyeing water-bath ratio is 28, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000121
each part of the reactive dye comprises 0.5 part of reactive bright yellow 4GL and 1.0 part of reactive emerald G266.
In the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000122
the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 0.5 part of alkyl bis (alpha-hydroxyethylamine phosphate), 2 parts of polystyrene benzene sulfonic acid and 3 parts of alkyl dicarboxymethylammonium ethyl lactone.
Example 2
Referring to fig. 1-3, the moisture absorption and sweat releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns 1, elastic fiber yarns 2 and bottom yarns 3, the surface yarns 1 form a surface layer after lamination, the elastic fiber yarns 2 form an elastic middle layer, and the bottom yarns 3 form a bottom layer; the veil 1 is formed by blending 75 percent of viscose fiber and 25 percent of acrylic fiber with 45S/1 yarn count according to the weight percentage; the elastic fiber yarn 2 is low-temperature spandex with the fineness of 55D; the ground yarn 3 is a polypropylene fiber having a fineness of 50D and a hole number of 48F.
The yarn length density of the face yarn 1 is 28cm/100g, the yarn length density of the elastic fiber yarn 2 is 11cm/100g, and the yarn length density of the ground yarn 3 is 28cm/100 g.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: c, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 92 ℃ for heat treatment for 23 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 125 ℃, and the presetting speed is 23 m/min. And in the step E, the setting temperature is 115 ℃, and the setting speed is 20 m/min.
In the step D, the first soaking and dyeing temperature is 92 ℃, the soaking time is 48min, the dyeing water-bath ratio is 29, and the first dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000131
Figure BDA0002051327020000141
each part of the cationic dye comprises 12 parts of cationic golden yellow X-GL, 22 parts of cationic red X-RS and 2 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 3: 2.5.
In the step D, the temperature of the second soaking and dyeing is 58 ℃, the soaking time is 63min, the dyeing water-bath ratio is 30, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000142
each part of the reactive dye comprises 0.6 part of reactive bright yellow 4GL and 1.1 part of reactive emerald G266.
In the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000143
the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 0.8 parts of alkyl bis (alpha-hydroxyethylamine phosphate), 3 parts of polystyrene benzene sulfonic acid and 4 parts of alkyl dicarboxymethylammonium ethyl lactone.
Example 3
Referring to fig. 1-3, the moisture absorption and sweat releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns 1, elastic fiber yarns 2 and bottom yarns 3, the surface yarns 1 form a surface layer after lamination, the elastic fiber yarns 2 form an elastic middle layer, and the bottom yarns 3 form a bottom layer; the veil 1 is formed by blending 70 percent of viscose fiber and 30 percent of acrylic fiber with 45S/1 yarn count according to the weight percentage; the elastic fiber yarn 2 is low-temperature spandex with the fineness of 33D; the ground yarn 3 is a polypropylene fiber having a fineness of 50D and a hole number of 72F.
The yarn length density of the face yarn 1 is 30cm/100g, the yarn length density of the elastic fiber yarn 2 is 13cm/100g, and the yarn length density of the ground yarn 3 is 30cm/100 g.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 95 ℃ for heat treatment for 20 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 130 ℃, and the presetting speed is 20 m/min; and in the step E, the setting temperature is 120 ℃, and the setting speed is 16 m/min.
In the step D, the temperature of the first soaking and dyeing is 95 ℃, the soaking time is 45min, the dyeing water-bath ratio is 30, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000151
Figure BDA0002051327020000161
each part of the cationic dye comprises 15 parts of cationic golden yellow X-GL, 25 parts of cationic red X-RS and 2.5 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 3.5: 3.
In the step D, the temperature of the second soaking and dyeing is 60 ℃, the soaking time is 60min, the dyeing water-bath ratio is 30, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000162
each part of the reactive dye comprises 0.8 part of reactive bright yellow 4GL and 1.3 parts of reactive emerald G266.
In the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000163
the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 1.5 parts of alkyl bis (alpha-hydroxyethylamine phosphate), 4 parts of polystyrene benzene sulfonic acid and 5 parts of alkyl dicarboxymethylammonium ethyl lactone.
Example 4
Referring to fig. 1-3, the moisture absorption and sweat releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns 1, elastic fiber yarns 2 and bottom yarns 3, the surface yarns 1 form a surface layer after lamination, the elastic fiber yarns 2 form an elastic middle layer, and the bottom yarns 3 form a bottom layer; the veil 1 is formed by blending 65 percent of viscose fiber and 35 percent of acrylic fiber with 50S/1 yarn count according to the weight percentage; the elastic fiber yarn 2 is low-temperature spandex with the fineness of 55D; the ground yarn 3 is a polypropylene fiber having a fineness of 75D and a hole number of 48F.
The yarn length density of the face yarn 1 is 33cm/100g, the yarn length density of the elastic fiber yarn 2 is 10.5cm/100g, and the yarn length density of the ground yarn 3 is 32cm/100 g.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaped gray cloth prepared in the step B into hot water with the temperature of 98 ℃ for heat treatment for 18 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 125 ℃, and the presetting speed is 18 m/min; and in the step E, the setting temperature is 115 ℃, and the setting speed is 14 m/min.
In the step D, the first soaking and dyeing temperature is 98 ℃, the soaking time is 45min, the dyeing water-bath ratio is 31, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000171
Figure BDA0002051327020000181
each part of the cationic dye comprises 18 parts of cationic golden yellow X-GL, 28 parts of cationic red X-RS and 3 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 4: 3.5.
In the step D, the temperature of the second soaking and dyeing is 63 ℃, the soaking time is 58min, the dyeing water-bath ratio is 31, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000182
each part of the reactive dye comprises 0.9 part of reactive bright yellow 4GL and 1.4 parts of reactive emerald G266.
In the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000183
the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 2.0 parts of alkyl bis (alpha-hydroxyethylamine phosphate), 5 parts of polystyrene benzene sulfonic acid and 6 parts of alkyl dicarboxymethylammonium ethyl lactone.
Example 5
Referring to fig. 1-3, the moisture absorption and sweat releasing fabric is formed by weaving composite yarns, the composite yarns are formed by laminating surface yarns 1, elastic fiber yarns 2 and bottom yarns 3, the surface yarns 1 form a surface layer after lamination, the elastic fiber yarns 2 form an elastic middle layer, and the bottom yarns 3 form a bottom layer; the veil 1 is formed by blending 60 percent of viscose fiber and 40 percent of acrylic fiber with the yarn count of 50S/1 according to the weight percentage; the elastic fiber yarn 2 is low-temperature spandex with the fineness of 55D; the ground yarn 3 is a polypropylene fiber having a fineness of 75D and a hole number of 72F.
The yarn length density of the face yarn 1 is 36cm/100g, the yarn length density of the elastic fiber yarn 2 is 15cm/100g, and the yarn length density of the ground yarn 3 is 35cm/100 g.
The preparation process of the moisture absorption and sweat releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: c, adding the pre-shaped gray cloth prepared in the step B into hot water with the temperature of 100 ℃ for heat treatment for 15 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 120 ℃, and the presetting speed is 15 m/min; and in the step E, the setting temperature is 110 ℃, and the setting speed is 12 m/min.
In the step D, the first soaking and dyeing temperature is 100 ℃, the soaking time is 40min, the dyeing water-bath ratio is 32, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000191
Figure BDA0002051327020000201
each part of the cationic dye comprises 20 parts of cationic golden yellow X-GL, 30 parts of cationic red X-RS and 4 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 5: 4.5.
In the step D, the temperature of the second soaking and dyeing is 65 ℃, the soaking time is 55min, the dyeing water-bath ratio is 32, and the second dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000202
each part of the reactive dye comprises 1.0 part of reactive bright yellow 4GL and 1.5 parts of reactive emerald G266.
In the step E, the setting agent comprises the following raw materials in parts by weight:
Figure BDA0002051327020000203
the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 2.5 parts of alkyl bis (alpha-hydroxyethylamine phosphate), 6 parts of polystyrene benzene sulfonic acid and 8 parts of alkyl dicarboxymethylammonium ethyl lactone.
Comparative example 1
This embodiment differs from embodiment 3 described above in that:
the preparation process of the moisture-absorbing and sweat-releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. boiling cloth: b, adding the gray cloth prepared in the step B into hot water with the temperature of 95 ℃ for heat treatment for 20 min;
C. dyeing: b, performing primary soaking dyeing on the gray cloth subjected to cloth boiling treatment in the step B by using a first dye solution, and then performing water washing; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
D. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step C by using a setting agent to prepare the moisture absorption and sweat releasing fabric.
In the step D, the setting temperature is 120 ℃, and the setting speed is 16 m/min.
Comparative example 2
This embodiment differs from embodiment 3 described above in that:
the preparation process of the moisture-absorbing and sweat-releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 95 ℃ for heat treatment for 20 min;
D. dyeing: c, soaking and dyeing the pre-shaped gray cloth subjected to the cloth boiling treatment in the step C by using a first dye solution, then washing with water, then performing peracid cold line treatment, soaping and non-softening cold line treatment, and finally performing dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 130 ℃, and the presetting speed is 20 m/min; and in the step E, the setting temperature is 120 ℃, and the setting speed is 16 m/min.
In the step D, the temperature of soaking and dyeing is 95 ℃, the soaking time is 45min, the dyeing water bath ratio is 30, and the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000211
Figure BDA0002051327020000221
each part of the cationic dye comprises 15 parts of cationic golden yellow X-GL, 25 parts of cationic red X-RS and 2.5 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 3.5: 3.
Comparative example 3
This embodiment differs from embodiment 3 described above in that:
the preparation process of the moisture-absorbing and sweat-releasing fabric comprises the following steps:
A. weaving: respectively carrying out three-thread weaving on the surface yarn 1, the elastic fiber yarn 2 and the bottom yarn 3 to obtain a gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat-setting the grey cloth prepared in the step A to obtain preset grey cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 95 ℃ for heat treatment for 20 min;
D. dyeing: c, soaking and dyeing the pre-shaped gray cloth subjected to the cloth boiling treatment in the step C by using a second dye solution, then performing peracid cold line treatment, soaping and non-softening cold line treatment, and finally performing dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
In the step B, the presetting temperature of the heating and heat setting treatment is 130 ℃, and the presetting speed is 20 m/min; and in the step E, the setting temperature is 120 ℃, and the setting speed is 16 m/min.
In the step D, the temperature of soaking and dyeing is 60 ℃, the soaking time is 60min, the dyeing water-bath ratio is 30, and the second dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000231
each part of the reactive dye comprises 0.8 part of reactive bright yellow 4GL and 1.3 parts of reactive emerald G266.
Comparative example 4
This embodiment differs from embodiment 3 described above in that:
the first dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000232
each part of the cationic dye comprises 15 parts of cationic golden yellow X-GL, 25 parts of cationic red X-RS and 2.5 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 3.5: 3.
Comparative example 5
This embodiment differs from embodiment 3 described above in that:
the second dye solution comprises the following raw materials in parts by weight:
Figure BDA0002051327020000233
each part of the reactive dye comprises 0.8 part of reactive bright yellow 4GL and 1.3 parts of reactive emerald G266.
Comparative example 6
This embodiment differs from embodiment 3 described above in that:
in the step E, the setting agent comprises the following raw materials in parts by weight:
antistatic agent 1.5 parts
0.03 part of citric acid
And 85 parts of water.
Each part of the antistatic agent comprises 1.5 parts of alkyl bis (alpha-hydroxyethylamine phosphate), 4 parts of polystyrene benzene sulfonic acid and 5 parts of alkyl dicarboxymethylammonium ethyl lactone.
The fabrics prepared in the above examples 1 to 5 and comparative example 6 were subjected to the moisture absorption, quick drying and other related performance tests, and the test items and test results are as follows:
test items Water absorption/%) Drip spread time/S Evaporation Rate/(g/h)
Example 1 156 3.6 0.24
Example 2 162 3.2 0.27
Example 3 169 2.4 0.33
Example 4 166 2.8 0.31
Example 5 160 3.0 0.26
Comparative example 6 121 5.2 0.19
Wherein, the water absorption test, the drip diffusion time test and the evaporation rate test are all performance test tests according to the test method of the national standard GB/T21655.1-2008.
And the water absorption test is to take the fabric with the size of 10cm x 10cm, place the fabric in deionized water for absorbing water, naturally sink the test sample after absorbing water, take out the test sample after soaking in water for 5min, naturally hang the test sample flatly and vertically, naturally drip water, and take out the test sample with tweezers for weighing when the test sample does not drip any more. The measured water absorption of the sample is equal to the ratio of the difference between the wetted mass and the original mass to the original mass.
The dropping diffusion time test is that the fabric with the size of 10cm x 10cm is placed on a platform, a proper amount of deionized water is sucked by a burette, then 0.2ml (about 1 drop) of deionized water is dropped on a fabric sample, and the distance between the mouth of the burette and the surface of the sample is not more than 1 cm. And (4) observing the diffusion condition of the water drops, recording the time required by the water drops to contact the surface of the sample until the water drops are completely diffused, if the water drops are slowly diffused and still are not completely diffused after a certain time, stopping the test, and recording that the diffusion time is longer than the set time.
And the evaporation rate test is to take the fabric with the size of 10cm x 10cm, test the dripping diffusion time of a sample, immediately weigh the mass after the test is finished, naturally and straightly hang the mass in the standard atmosphere, weigh the mass once every (5 +/-0.5) min until the change rate of the weighed mass is not more than 1% for two times, end the test, and calculate the evaporation rate of the waterQuantity: delta mi=m-mi;Ei=△mi×100/m0
Wherein, Δ mi-water evaporation amount, g;
m0-the original mass of the sample, g;
m is the mass of the sample after being wetted by water dropping, g;
mi-mass of the sample at a certain moment after wetting with water, g;
Eiwater evaporation rate,%.
The comparison of the data shows that the setting agent of the invention adopts the moisture absorption and sweat discharge agent, the water absorption rate is up to 156-169%, and the water diffusion time period after dripping is high in evaporation rate, so that the moisture absorption performance and the quick drying performance of the cloth finished product can be obviously improved; in contrast, the setting agent in comparative example 6 does not adopt a moisture absorption and perspiration agent, the water absorption rate of the prepared fabric is significantly reduced (only 121%), the dripping diffusion time is longer, and the evaporation rate is lower, which indicates that the fabric of comparative example 6 has lower moisture absorption and quick drying performance and weaker moisture absorption and perspiration effects than those of the fabric of the invention.
The fabrics obtained in the above examples 1 to 5 and comparative examples 1 to 5 were subjected to the performance tests related to smoothness, color fastness and the like, the test items and the test results are as follows:
Figure BDA0002051327020000251
Figure BDA0002051327020000261
the flatness grade is tested according to the national standard GB T13769-2009 test method for the flatness of the appearance of the washed textile evaluation fabric, wherein the SA-5 grade is equivalent to a standard sample plate SA-5, which shows that the appearance is the most smooth and the original flatness maintenance is the best; the SA-1 grade is equivalent to a standard sample SA-1 and shows that the appearance is the least smooth and the original appearance has the worst flatness retentivity; level 4.5 is intermediate between the standard template SA-4 and SA-5 levels.
The washing fastness grade is measured according to AATCC61 standard A2 item, household or commercial machine washing is carried out at the temperature of 38 +/-3 ℃, and the color change and staining change before and after washing are measured by a color counter. And the perspiration color fastness grade is tested according to AATCC 15-2009 standard and a perspiration resistance tester, and the color change and the staining condition change of the perspiration color grade are tested by using a color counter. The color fastness to sunlight grade was tested according to AATCC16-2004 standard and a xenon arc tester, and the color change was tested using a color counter (wherein the fastness to sunlight grade was eight, 1 is the worst, and 8 is the best).
The color change and the staining condition change grades are respectively as follows:
Figure BDA0002051327020000262
Figure BDA0002051327020000271
the test data show that the fabric prepared by the invention is soft and comfortable, is skin-friendly and breathable, has high moisture absorption, high volatilization speed of absorbed moisture, high color fastness, difficult deformation or decoloration in washing and high stability.
In the fabric treatment process, the prepared fabric has the flatness test of 4.5 grade or above, and compared with the comparative example 1 without performing the grey cloth pre-setting treatment, the fabric has relatively high flatness grade, even reaches SA-5 grade, while the comparative example 1 only reaches SA-3 grade; the method can perform the embryo fixing on the low-temperature spandex fiber in the gray cloth by performing the pre-setting treatment on the woven gray cloth, prevent the spandex fiber from having the phenomena of uneven shrinkage and excessive shrinkage in the subsequent dyeing process, avoid the undesirable phenomena of shrinkage, wrinkle, pull mark, chicken mark and the like of the fabric, perform the embryo fixing on the wool fiber, the acrylic fiber, the viscose fiber and the polypropylene fiber, prevent the problems of shrinkage or wrinkle and the like of the fiber in the subsequent dyeing, setting and washing in use, enable the fabric to be straight and smooth, achieve the effect of non-ironing, and have high flatness.
In the fabric treatment process, the prepared fabric has the washing fastness grade of 4.5 grade or above, and compared with the comparative example 1 without performing grey cloth pre-setting treatment, the fabric has the washing fastness grade which is relatively higher and even reaches 5 grade, which indicates that the grey cloth is subjected to the pre-setting treatment before dyeing, is beneficial to the stable dye uptake and attachment in the subsequent dyeing process, and improves the color fastness of the fabric. Compared with comparative example 2 (the washing fastness grade is only 3 grades) which only adopts the first dye solution to dye for one time and compared with comparative example 3 (the washing fastness grade is only 3 grades) which only adopts the second dye solution to dye for one time, the washing fastness grade of the fabric is relatively higher, which shows that the invention can effectively improve the dye uptake and the dye attachment stability of two dyes on the fabric by respectively adopting the first dye solution and the second dye solution to dye for two times, wherein, the dye uptake of the first dye solution on acrylic fibers is higher than that on viscose fibers, the first dye solution can be stably attached on the acrylic fibers, and the second dye solution on viscose fibers is higher than that on the viscose fibers, the second dye solution can be stably attached on the viscose fibers and respectively dyed for two times, so that the acrylic fibers and the viscose fibers on the 1 layer of the veil can be uniformly dyed, the dye has stable attachment and high color fastness.
If different fibers are dyed by a single dye, if only the cationic fibers are used for dyeing, the adhesive force of the dye to the viscose fibers is low, so that the dye-uptake of the viscose fibers is low, the dye of a product is easy to fall off from the viscose fibers in the subsequent process or use process, and the color fastness of the finished product is obviously reduced; similarly, if the reactive dye is adopted to dye the 1 layer of the veil, the adhesion of the dye to the acrylic fiber and the internal diffusion performance of the fiber are low, the dye is easy to fall off from the acrylic fiber in the subsequent process or the using process, and the color fastness of the finished product is obviously reduced.
The first dye liquor adopted by the invention has higher dye-uptake rate to acrylic fibers in the fabric, and the prepared fabric is not easy to fade or change color after being washed by water for many timesWhile the first dye liquor in the comparative example 4 does not adopt anhydrous sodium sulphate, the obtained fabric has obviously reduced washing fastness level, perspiration color fastness level and light fastness level and lower color fastness, which indicates that the first dye liquor of the invention adopts anhydrous sodium sulphate in which sulfate ions SO with negative charges4 2-With NH in acrylic fibres3+The cationic dye is adsorbed on the surface of the fiber after combination, and the repulsive force borne by the cationic dye when the cationic dye is close to the surface of the fiber is greatly weakened, so that the energy resistance generated due to coulomb force is reduced, the combination of the dye and the fiber is promoted, and the dye-uptake rate is improved. Similarly, the same effect of accelerating the dyeing and improving the color fastness is also achieved for the anhydrous sodium sulphate in the second dye solution, and the ionized cation Na of the anhydrous sodium sulphate+The active dye with negative points is adsorbed on the surface of the viscose fiber with negative points, the fiber is wrapped by cations, and the repulsive force borne by the active dye with negative points is greatly weakened when the active dye with negative points is close to the surface of the fiber, so that the energy resistance generated by coulomb force is reduced, and the dye-uptake rate is improved.
The second dye solution adopted by the invention has higher dye-uptake to viscose fibers, the prepared fabric is not easy to fade or change color after being washed by water for many times, and the second dye solution in the comparative example 5 does not adopt Homekatol C, so that the washing color fastness level, the perspiration color fastness level and the light fastness level of the prepared fabric are obviously reduced, and the color fastness is lower.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit and scope of the present invention.

Claims (10)

1. A moisture absorption and sweat releasing fabric is characterized in that: the moisture-absorbing and sweat-releasing fabric is woven by composite yarns, the composite yarns are formed by laminating surface yarns, elastic fiber yarns and bottom yarns, the surface yarns form a surface layer after lamination forming, the elastic fiber yarns form an elastic middle layer, and the bottom yarns form a bottom layer; the veil is formed by blending 60-80% of viscose fiber and 20-40% of acrylic fiber with yarn count of 40-50S/1 according to the weight percentage; the elastic fiber yarn is low-temperature spandex with the fineness of 30-60D; the bottom yarn is polypropylene fiber with fineness of 45-75D and hole number of 45-75F.
2. The moisture-absorbing and sweat-releasing fabric according to claim 1, wherein: the yarn length density of the face yarn is 26-36cm/100g, the yarn length density of the elastic fiber yarn is 10-15cm/100g, and the yarn length density of the ground yarn is 25-35cm/100 g.
3. A process for preparing the moisture-absorbing and sweat-releasing fabric as claimed in claim 1 or 2, wherein: the method comprises the following steps:
A. weaving: respectively weaving the surface yarn, the elastic fiber yarn and the bottom yarn in three lines to obtain gray cloth;
B. pre-setting treatment of the gray cloth: c, heating and heat setting the gray cloth prepared in the step A to obtain pre-set gray cloth;
C. boiling cloth: b, adding the pre-shaping gray cloth prepared in the step B into hot water with the temperature of 90-100 ℃ for heat treatment for 15-25 min;
D. dyeing: c, performing primary soaking dyeing on the pre-shaped gray cloth subjected to cloth boiling treatment in the step C by using a first dye solution, and then washing with water; carrying out secondary soaking dyeing by using a second dye solution, carrying out peracid cold line treatment, soaping and non-softening cold line treatment, and finally carrying out dehydration and drying treatment to obtain dyed cloth;
E. shaping treatment: and D, carrying out heat setting treatment on the dyed fabric prepared in the step D by using a setting agent to prepare the moisture-absorbing and sweat-releasing fabric.
4. The preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 3, characterized in that: in the step B, the presetting temperature of the heating and heat setting treatment is 110-; in the step E, the setting temperature is 100-.
5. The preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 4, characterized in that: in the step D, the first soaking and dyeing temperature is 90-100 ℃, the soaking time is 40-50min, the dyeing water-bath ratio is 28-32, and the first dyeing solution comprises the following raw materials in parts by weight:
Figure FDA0002051327010000021
6. the preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 5, characterized in that: each part of the cationic dye comprises 10-20 parts of cationic golden yellow X-GL, 20-30 parts of cationic red X-RS and 1-4 parts of cationic blue X-BS; the anti-precipitation agent is fatty alcohol-polyoxyethylene ether; the accelerant is a mixture of sodium chloride and sodium sulfate in a weight ratio of 2-5: 1.5-4.5.
7. The preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 3, characterized in that: in the step D, the temperature of the second soaking and dyeing is 55-65 ℃, the soaking time is 55-65min, the dyeing water-bath ratio is 28-32, and the second dyeing solution comprises the following raw materials in parts by weight:
Figure FDA0002051327010000022
8. the preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 7, characterized in that: each part of the reactive dye comprises 0.5-1.0 part of reactive bright yellow 4GL and 1.0-1.5 parts of reactive emerald G266.
9. The preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 3, characterized in that: in the step E, the setting agent comprises the following raw materials in parts by weight:
Figure FDA0002051327010000031
10. the preparation process of the moisture-absorbing and sweat-releasing fabric according to claim 9, characterized in that: the moisture absorption and sweat discharge agent is a polyester-polyether segmented copolymer; each part of the antistatic agent comprises 0.5-2.5 parts of alkyl bis (alpha-hydroxyethyl amine phosphate), 2-6 parts of polystyrene benzene sulfonic acid and 3-7 parts of alkyl dicarboxymethyl ammonium ethyl lactone.
CN201910374971.5A 2019-05-07 2019-05-07 Moisture-absorbing and sweat-releasing fabric and preparation process thereof Pending CN111910328A (en)

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Application publication date: 20201110