TWI747604B - Deodorizing methods using sugarcane bagasse and deodorizing and cleaning composition comprising sugarcane bagasse - Google Patents

Deodorizing methods using sugarcane bagasse and deodorizing and cleaning composition comprising sugarcane bagasse Download PDF

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TWI747604B
TWI747604B TW109139357A TW109139357A TWI747604B TW I747604 B TWI747604 B TW I747604B TW 109139357 A TW109139357 A TW 109139357A TW 109139357 A TW109139357 A TW 109139357A TW I747604 B TWI747604 B TW I747604B
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bagasse
powder
odor
composition
deodorizing
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TW109139357A
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TW202218654A (en
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陳郁璇
黃怡仁
張哲誠
劉保林
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台灣糖業股份有限公司
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Abstract

This invention discloses that sugarcane bagasse can be used in deodorization. Also disclosed herein is the use of sugarcane bagasse in the manufacture of a deodorizing and cleaning composition.

Description

使用甘蔗渣來除臭的方法以及包含有甘蔗渣的除臭清潔組成物Method for deodorizing using bagasse and deodorizing cleaning composition containing bagasse

本發明是有關於使用甘蔗渣(sugarcane bagasse)來除臭的方法。The present invention relates to a method for deodorizing using sugarcane bagasse.

生活環境中的異味通常來自於交通、工業或家庭的廢棄物與汙染物以及動物與人類身體的分泌物當中的揮發性物質(volatile matter),而此又被稱為異味分子(odor component)。在台灣的《空氣汙染防制法施行細則》中,將異味污染物列於空氣污染物中,並且定義為:具有氣味,足以引起厭惡或其他不良情緒反應之污染物。而在日本的《惡臭防止法》中,則將導致不愉快的臭味而有損生活環境的物質定義為惡臭物質,並且規範了包括醛類等22種物質。The odor in the living environment usually comes from volatile matter in the wastes and pollutants of transportation, industry, or households, and the secretions of animals and humans, which are also called odor components. In Taiwan’s "Enforcement Regulations of the Air Pollution Prevention and Control Law", odor pollutants are listed as air pollutants, and are defined as: pollutants that have an odor and are sufficient to cause disgust or other adverse emotional reactions. In Japan's "Odor Prevention Act", substances that cause unpleasant odors and harm the living environment are defined as odorous substances, and 22 substances including aldehydes are regulated.

生活環境中常見的異味分子主要可以區分為: (i)      有機氮化合物,諸如氨(ammonia)、三甲基胺(Trimethyl amine)、甲基胺(Methyl amine)、乙基胺(Ethyl amine)等分子,通常具有如廚餘、排泄物或下水道的臭味; (ii)    有機硫化合物,諸如硫化氫、甲硫醇等,通常具有如腐敗蔬菜、排泄物或下水道的臭味; (iii)   短鏈脂肪酸,諸如異戊酸(Isovaleric)、戊酸(Valeric acid)、丁酸等分子,通常具有如汗、襪子、洗濯物的臭味; (iv)   醛類,諸如乙醛、2-壬醯醛(2-nonenal)等分子,通常具有如吸菸或酒醉者的口臭、加齡臭(又稱老人臭)的臭味;以及 (v)     芳香族碳氫化合物,諸如苯乙烯(styrene)、二甲苯(Xylene)、甲苯等分子,通常具有如瓦斯或汽油的臭味。 The common odor molecules in the living environment can be divided into: (i) Organic nitrogen compounds, such as ammonia, trimethyl amine, methyl amine, ethyl amine and other molecules, usually have food waste, excrement or sewer Smell (ii) Organic sulfur compounds, such as hydrogen sulfide, methyl mercaptan, etc., usually have the smell of spoiled vegetables, excrement or sewers; (iii) Short-chain fatty acids, such as Isovaleric, Valeric acid, butyric acid and other molecules, usually have the smell of sweat, socks, and laundry; (iv) Aldehydes, such as acetaldehyde, 2-nonenal (2-nonenal) and other molecules, usually have bad odors such as the bad breath of smokers or drunken people, and the odor of aging (also known as the odor of the elderly); and (v) Aromatic hydrocarbons, such as styrene, xylene, toluene and other molecules, usually have the smell of gas or gasoline.

目前用於除臭的方法包括:(1)利用物理性吸附來移除異味分子;(2)以臭氧(ozone)來分解異味分子;(3)利用微生物來分解異味分子;以及(4)利用紫外線(ultraviolet)來將異味分子進行光催化分解。然而,針對人體所分泌的汗液與皮脂(sebum)因氧化或被細菌分解所產生的頭皮臭、汗臭、腋下臭以及加齡臭等,卻僅能利用體香劑或抑菌劑等個人除臭清潔產品來加以掩蓋、阻隔,或是透過抑制細菌生長來預防臭味產生,因此效果通常十分有限。The methods currently used for deodorization include: (1) using physical adsorption to remove odor molecules; (2) using ozone to decompose odor molecules; (3) using microorganisms to decompose odor molecules; and (4) using Ultraviolet (ultraviolet) to photocatalytically decompose odor molecules. However, for the scalp odor, sweat odor, underarm odor and aging odor caused by the oxidation or decomposition of sweat and sebum (sebum) secreted by the human body, only deodorants or antibacterial agents can be used for individuals. Deodorant cleaning products can be used to cover up, block, or prevent odor generation by inhibiting the growth of bacteria, so the effect is usually very limited.

近年來,市面上亦出現多種不同型態的乾洗髮(dry shampoo)產品,例如,呈乾粉狀的乾洗髮產品,其主要是利用澱粉(starch)、矽酸鋁鹽(aluminosilicates)或滑石(talc)等成分來吸附頭皮過多皮脂;以及噴霧型乾洗髮產品,其通常僅是透過有機溶劑與香氛來使頭皮產生冰涼與清爽的感覺,因此,該等乾洗髮產品在去除異味上的效果有限,同時還容易黏附殘留於頭皮而不易將油脂或異味分子移除,於是可能產生皮膚過敏、皮脂腺阻塞等現象,甚至導致毛囊炎。In recent years, many different types of dry shampoo products have appeared on the market. For example, dry shampoo products in dry powder form mainly use starch, aluminum silicate or talc. talc) and other ingredients to absorb excessive sebum on the scalp; and spray-type dry hair products, which usually only use organic solvents and fragrances to make the scalp feel cool and refreshing. Therefore, these dry hair products are effective in removing odors. It is limited, and it is easy to stick to the scalp and not easy to remove oil or odor molecules, so it may cause skin allergies, sebaceous glands, and even cause folliculitis.

另一方面,日本三井製糖公司於2010年曾公開發表利用富含有甘蔗多酚(sugarcane polyphenols)之甘蔗萃取物來除臭的方法及其產品。該甘蔗萃取物經實驗證實能夠有效吸附有機氮化物、有機硫化物以及芳香族碳氫化合物等異味分子,而適用於去除肉類或魚類的腥味、菸味以及寢具的臭味。On the other hand, Japan's Mitsui Sugar Co., Ltd. published in 2010 a method and its products for deodorizing using sugarcane extracts rich in sugarcane polyphenols. The sugarcane extract has been experimentally confirmed to be able to effectively adsorb organic nitrogen compounds, organic sulfides, aromatic hydrocarbons and other odor molecules, and is suitable for removing the fishy odor, smoke odor of meat or fish, and the odor of bedding.

雖然已有上述的除臭產品,本領域的相關研究人員仍致力於開發出具有更佳除臭功效的材料。在先前研究中,申請人意外發現經去糖與乾燥處理的甘蔗渣(sugarcane bagasse)對於油脂以及臭味皆有優異的吸附能力,並且具有容易清除、不易殘留於人體的優異性質,因此被預期可供作為一種用於吸附油脂與除臭的清潔產品。Although the above-mentioned deodorizing products are available, relevant researchers in the field are still committed to developing materials with better deodorizing effects. In previous research, the applicant unexpectedly discovered that sugarcane bagasse (sugarcane bagasse) after de-sweetening and drying has excellent adsorption capacity for oils and odors, and has excellent properties of being easy to remove and not easy to remain in the human body. Therefore, it is expected It can be used as a cleaning product for absorbing grease and deodorizing.

發明概要Summary of the invention

於是,在第一個方面,本發明提供一種用於除臭的方法,其包含下列步驟: 提供一包含有甘蔗渣的組成物; 對一需要除臭之含有異味分子的區域施用該組成物,而使得該組成物吸附該異味分子;以及 移除吸附有該異味分子的組成物。 Therefore, in the first aspect, the present invention provides a method for deodorization, which includes the following steps: Provide a composition containing bagasse; Apply the composition to an area containing odor molecules that needs to be deodorized, so that the composition absorbs the odor molecules; and Remove the composition that has adsorbed the odor molecules.

在第二個方面,本發明提供一種甘蔗渣供用於製備一用於去除異味分子的清潔組成物的用途。In the second aspect, the present invention provides a use of bagasse for preparing a cleaning composition for removing odor molecules.

在第三個方面,本發明提供一種除臭清潔組成物,其包含有甘蔗渣,以及一選自於由下列所構成之群組中的吸附材料:多孔性纖維材料、澱粉、矽酸鋁鹽礦物,以及它們的組合。In a third aspect, the present invention provides a deodorizing cleaning composition comprising bagasse and an adsorbent selected from the group consisting of porous fibrous materials, starch, and aluminum silicate Minerals, and their combinations.

發明的詳細說明Detailed description of the invention

要被瞭解的是:若有任何一件前案刊物在此被引述,該前案刊物不構成一個下述承認:在台灣或任何其他國家之中,該前案刊物形成本技藝中的常見一般知識之一部分。It should be understood that if any previous case publication is quoted here, the previous case publication does not constitute a recognition: in Taiwan or any other country, the previous case publication forms a common general in this art. Part of knowledge.

為了這本說明書之目的,將被清楚地瞭解的是:文字“包含有(comprising)”意指“包含但不限於”,以及文字“包括(comprises)”具有一對應的意義。For the purpose of this specification, it will be clearly understood that the word "comprising" means "including but not limited to", and the word "comprises" has a corresponding meaning.

除非另外有所定義,在本文中所使用的所有技術性與科學術語具有熟悉本發明所屬技藝的人士所共同瞭解的意義。一熟悉本技藝者會認知到許多與那些被描述於本文中者相似或等效的方法和材料,它們可被用於實施本發明。當然,本發明決不受到所描述的方法和材料之限制。Unless otherwise defined, all technical and scientific terms used in this article have meanings commonly understood by those familiar with the art of the present invention. A person familiar with the art will recognize that many methods and materials similar or equivalent to those described herein can be used to implement the present invention. Of course, the present invention is by no means restricted by the described methods and materials.

在開發可用於除臭的材料上,申請人意外地發現到:甘蔗渣(sugarcane bagasse)除了對於油脂亦對於臭味具有優異的吸附能力,並且還具有容易清除、不易黏附殘留之特性,因此甘蔗渣被預期可供用於除臭產品之開發。In the development of materials that can be used for deodorization, the applicant unexpectedly discovered that sugarcane bagasse not only has excellent absorption capacity for fats and odors, but also has the characteristics of being easy to remove and not sticking to residues. Therefore, sugarcane bagasse The slag is expected to be used in the development of deodorizing products.

因此,本發明提供一種用於除臭的方法,其包含下列步驟: 提供一包含有甘蔗渣的組成物; 對一需要除臭之含有異味分子(odor component)的區域施用該組成物,而使得該組成物吸附該異味分子;以及 移除吸附有該異味分子的組成物。 Therefore, the present invention provides a method for deodorization, which includes the following steps: Provide a composition containing bagasse; Apply the composition to an area containing odor components that needs to be deodorized, so that the composition absorbs the odor components; and Remove the composition that has adsorbed the odor molecules.

如本文中所使用的,術語“除臭(deodorization)”意指減少(reduce)、消除(eliminate)或移除(remove)一區域所含有的異味分子(odor component)[亦即引起異味的物質(odor-causing materials)],藉此減少、消除或移除該區域的空氣中的異味(odors)、惡臭(malodors)或氣味(scents)。As used herein, the term "deodorization" means to reduce, eliminate, or remove odor components contained in an area (that is, substances that cause odors (odor-causing materials)], thereby reducing, eliminating or removing odors, malodors or scents in the air in the area.

依據本發明,該異味分子是選自於由下列所構成的群組:有機氮化合物[例如氨、三甲基胺(Trimethyl amine)、甲基胺(Methyl amine)以及乙基胺(Ethyl amine)]、有機硫化合物(例如硫化氫和甲硫醇)、短鏈脂肪酸[例如異戊酸(Isovaleric)、戊酸(Valeric acid)以及丁酸]、醛類[例如乙醛和2-壬醯醛(2-nonenal)],以及它們的組合。較佳地,該異味分子是醛類。更佳地,該異味分子是2-壬醯醛(2-nonenal)。According to the present invention, the odor molecule is selected from the group consisting of organic nitrogen compounds [such as ammonia, trimethyl amine, Methyl amine, and Ethyl amine) ], organic sulfur compounds (such as hydrogen sulfide and methyl mercaptan), short-chain fatty acids (such as isovaleric, Valeric acid and butyric acid), aldehydes (such as acetaldehyde and 2-nonanal) (2-nonenal)], and their combinations. Preferably, the off-flavor molecules are aldehydes. More preferably, the off-flavor molecule is 2-nonenal (2-nonenal).

依據本發明,該甘蔗渣可以採用熟習此項技藝者所詳知且慣用的技術來對一甘蔗屬植物(plant of Saccharumgenus)的莖進行加工處理而被製得。 According to the present invention, the bagasse can be prepared by processing the stem of a plant of Saccharum genus using a technique well-known and commonly used by those skilled in the art.

適用於本發明的甘蔗屬植物包括,但不限於:白甘蔗、紅甘蔗、細稈甘蔗,以及它們的雜交種。較佳地,該甘蔗屬植物是白甘蔗雜交種。Plants of the genus Saccharum suitable for the present invention include, but are not limited to: white sugarcane, red sugarcane, thin-stalked sugarcane, and their hybrids. Preferably, the sugarcane plant is a white sugarcane hybrid.

較佳地,該加工處理至少包括乾燥處理以及粉碎處理。在本發明的一個較佳具體例中,該加工處理包括依序進行的壓榨處理、水煮去糖處理、乾燥處理以及粉碎處理。Preferably, the processing treatment includes at least drying treatment and crushing treatment. In a preferred embodiment of the present invention, the processing treatment includes squeezing treatment, water boiling sugar removal treatment, drying treatment, and crushing treatment in sequence.

可瞭解到的是,該加工處理的種類與操作條件會隨著所使用的甘蔗品種、處理的順序以及甘蔗的用量比例等因素而被變動。而這些操作條件的選擇是熟習此項技藝者能例行性地自行決定的。It can be understood that the type of processing and operating conditions will vary with factors such as the sugarcane variety used, the sequence of the processing, and the ratio of the amount of sugarcane used. The choice of these operating conditions is routinely determined by those who are familiar with the art.

依據本發明,該甘蔗渣可具有一範圍落在100 nm至1,100 μm的粒徑。較佳地,該甘蔗渣具有一範圍落在270 μm至550 μm的粒徑。According to the present invention, the bagasse may have a particle size ranging from 100 nm to 1,100 μm. Preferably, the bagasse has a particle size ranging from 270 μm to 550 μm.

本發明所適用的區域包括,但不限於:動物或人體、公共場所(public places)或工業、居家或醫學的環境中的表面。The applicable areas of the present invention include, but are not limited to: animals or human bodies, public places, or industrial, home, or medical environments.

較佳地,該區域是動物或人體的表面。Preferably, the area is the surface of an animal or human body.

較佳地,該區域進一步含有油脂,而該組成物可同時吸附該區域的異味分子與油脂。適用於本發明的油脂包括,但不限於:人類皮脂(sebum)、動物油(animal oil)、植物油(plant oil)以及礦物油(mineral oil)。更佳地,該油脂是人類皮脂。Preferably, the area further contains grease, and the composition can simultaneously adsorb odor molecules and grease in the area. Oils and fats suitable for the present invention include, but are not limited to: human sebum (sebum), animal oil (animal oil), plant oil (plant oil) and mineral oil (mineral oil). More preferably, the oil is human sebum.

依據本發明,該組成物對該區域的施用可以透過噴霧(spraying)、噴灑(sprinkling)、塗抹(wiping)、放置或掩蓋(covering)等方式來進行,並經歷一段適當的時間以達所欲的吸附效果。According to the present invention, the application of the composition to the area can be carried out by spraying, spraying, wiping, placing or covering, etc., and after an appropriate period of time to achieve the desired The adsorption effect.

本發明亦提供一種甘蔗渣供用於製備一用於去除異味分子的清潔組成物的用途。The present invention also provides a use of bagasse for preparing a cleaning composition for removing odor molecules.

依據本發明,該清潔組成物可進一步包含有一選自於由下列所構成之群組中的吸附材料:多孔性纖維材料(porous fiber material)、澱粉、矽酸鋁鹽礦物(aluminosilicates),以及它們的組合。According to the present invention, the cleaning composition may further include an absorbent material selected from the group consisting of porous fiber materials, starch, aluminum silicate minerals (aluminosilicates), and them The combination.

如此處所使用的,術語“吸附材料(adsorbent material)”、“吸附劑(adsorbent)”以及“吸附劑(adsorber)”可被交換地使用。可視欲進一步賦予或增強該清潔組成物對某種分子或物質的吸附能力來選用對應的吸附材料。As used herein, the terms "adsorbent material", "adsorbent" and "adsorber" may be used interchangeably. The corresponding adsorption material can be selected according to the desire to further endow or enhance the adsorption capacity of the cleaning composition for a certain molecule or substance.

如此處所使用的,術語“多孔性纖維材料”意指具有孔洞結構(porous structure)的無機或有機材料,其藉由該孔洞結構所帶來的大比表面積而被賦予了對於液體和/或氣體的吸附能力。適用於本發明的多孔性纖維材料包括,但不限於:植物纖維(plant fiber)、活性炭(activated charcoal)、竹炭(bamboo charcoal)以及多孔性矽膠(porous silica)。As used herein, the term "porous fibrous material" means an inorganic or organic material with a porous structure, which is endowed with resistance to liquid and/or gas due to the large specific surface area brought by the porous structure. The adsorption capacity. The porous fibrous materials suitable for the present invention include, but are not limited to: plant fiber, activated charcoal, bamboo charcoal, and porous silica.

適用於本發明的澱粉包括,但不限於:玉米澱粉(corn starch)、馬鈴薯澱粉(potato starch)以及樹薯澱粉(tapioca starch)。The starches suitable for the present invention include, but are not limited to: corn starch, potato starch and tapioca starch.

適用於本發明的矽酸鋁鹽礦物包括,但不限於:高嶺土(kaolinite)、沸石(zeolite)以及蒙脫石(montmorillonite)。The aluminum silicate minerals suitable for the present invention include, but are not limited to: kaolinite, zeolite, and montmorillonite.

較佳地,該吸附材料是選自於由下列所構成之群組:植物纖維[衍生自桉屬物種( Eucalyptusspp.)、千層樹屬物種( Melaleucaspp.)或茶樹( Camellia sinensis)]、高嶺土、竹炭粉、苦茶粉,以及它們的組合。 Preferably, the adsorbent material is selected from the group consisting of: plant fibers [derived from Eucalyptus spp., Melaleuca spp. or Camellia sinensis ] , Kaolin, bamboo charcoal powder, bitter tea powder, and combinations thereof.

依據本發明,該清潔組成物是用於同時去除一如上所述的異味分子以及油脂。According to the present invention, the cleaning composition is used to simultaneously remove the above-mentioned odor molecules and grease.

本發明亦提供一種除臭清潔組成物,其包含有甘蔗渣,以及一如上所述的吸附材料。The present invention also provides a deodorizing cleaning composition, which contains bagasse and an adsorbent as described above.

依據本發明,在該除臭清潔組成物之中,該吸附材料具有一範圍落在10至50 wt%內的含量。較佳地,該吸附材料具有一範圍落在20至30 wt%內的含量。更佳地,該吸附材料是高嶺土、竹炭粉以及苦茶粉的組合,並且高嶺土具有一範圍落在0.5至20 wt%內的含量,竹炭粉具有一範圍落在4.5至10 wt%內的含量,以及苦茶粉具有一範圍落在5至20 wt%內的含量。According to the present invention, in the deodorizing and cleaning composition, the adsorbent has a content ranging from 10 to 50 wt%. Preferably, the adsorbent material has a content ranging from 20 to 30 wt%. More preferably, the adsorbent is a combination of kaolin, bamboo charcoal powder and bitter tea powder, and the kaolin has a content ranging from 0.5 to 20 wt%, and the bamboo charcoal powder has a content ranging from 4.5 to 10 wt% , And bitter tea powder has a content ranging from 5 to 20 wt%.

依據本發明,在該除臭清潔組成物之中,該甘蔗渣具有大於1且小於100 wt%的含量。較佳地,該甘蔗渣具有一範圍落在50至80 wt%內的含量。According to the present invention, in the deodorizing cleaning composition, the bagasse has a content greater than 1 and less than 100 wt%. Preferably, the bagasse has a content ranging from 50 to 80 wt%.

在本發明的一較佳具體例中,該除臭清潔組成物中含有50 wt%的甘蔗渣、48 wt%的苦茶粉,以及2 wt%的竹炭粉。In a preferred embodiment of the present invention, the deodorizing cleaning composition contains 50 wt% bagasse, 48 wt% bitter tea powder, and 2 wt% bamboo charcoal powder.

在本發明的又一較佳具體例中,該除臭清潔組成物中含有72.5 wt%的甘蔗渣、0.5 wt%的高嶺土、2 wt%的竹炭粉,以及10 wt%的苦茶粉。In another preferred embodiment of the present invention, the deodorizing cleaning composition contains 72.5 wt% bagasse, 0.5 wt% kaolin, 2 wt% bamboo charcoal powder, and 10 wt% bitter tea powder.

依據本發明,該除臭清潔組成物可以被併入下列的產品之中來發揮其除臭效用:清潔劑,如洗衣粉、廚房清潔劑、浴廁清潔劑;個人清潔產品,如肥皂、洗面乳、沐浴乳、洗手皂、乳液(lotion)、體香劑(deodorant)、制汗劑(antiperspirant)、足部除臭劑(foot deodorant);美髮或頭髮清潔產品,如洗髮精(shampoo)、粉末式乾洗髮(dry powder shampoo)、噴霧式乾洗髮(shampoo spray)、染髮劑(hair coloring agents)、髮蠟(wax)、髮膠(hairspray)、造型慕斯(mousse);衛生產品,如尿布(diapers)、護墊(pads)、衛生棉(sanitary napkins)、床單、毛巾與紙巾;居家清潔產品,如除臭劑、櫥櫃除臭劑、房間除臭劑、浴廁除臭劑、鞋內除臭劑、汽車除臭劑、冰箱除臭劑、衣物除臭劑、紡織品除臭劑、垃圾除臭劑、空氣潔淨劑、風扇或排氣裝置的過濾器(filters);除臭纖維(deodorant fibers);工廠或工業廢棄物用的除臭劑;以及其他各種形式的除臭劑。 較佳實施例之詳細說明 According to the present invention, the deodorizing cleaning composition can be incorporated into the following products to exert its deodorizing effect: detergents, such as washing powder, kitchen cleaners, bathroom cleaners; personal cleaning products, such as soap, face wash Milk, shower gel, hand soap, lotion, deodorant, antiperspirant, foot deodorant; hairdressing or hair cleaning products, such as shampoo , Dry powder shampoo, shampoo spray, hair coloring agents, wax, hairspray, mousse; hygiene products, such as diapers (diapers), pads, sanitary napkins (sanitary napkins), sheets, towels and paper towels; household cleaning products, such as deodorant, cabinet deodorant, room deodorant, bathroom deodorant, shoe interior Deodorant, car deodorant, refrigerator deodorant, clothing deodorant, textile deodorant, garbage deodorant, air cleaner, filters for fans or exhaust devices; deodorant fiber (deodorant) fibers); deodorizers for factory or industrial waste; and other deodorants in various forms. Detailed description of the preferred embodiment

本發明將就下面的實施例來做進一步說明,但應瞭解的是,該等實施例僅是供例示說明用,而不應被解釋為本發明的實施上的限制。 實施例 一般實驗材料: 1.  甘蔗渣粉末(sugarcane bagasse powder)的製備: The present invention will be further described with the following embodiments, but it should be understood that these embodiments are for illustrative purposes only, and should not be interpreted as limitations on the implementation of the present invention. Examples General experimental materials: 1. Preparation of sugarcane bagasse powder:

將5 kg之經壓榨的甘蔗渣(得自於台灣糖業公司台南市善化糖廠以及雲林縣虎尾糖廠)置於加熱槽內,並添加60 L的水,繼而於80℃下予以攪拌蒸煮歷時10分鐘,接著予以靜置沉澱並倒出蒸煮後的廢水,繼而測量廢水的錘度(degree Brix)(亦即,溶於廢水的蔗糖含量)。重複上述加水-蒸煮-倒出廢水步驟數次直到所測得的錘度為零。然後,再加水蒸煮一次,並予以靜置歷時1小時接而倒出廢水。之後,將所得到的去糖甘蔗渣置於一脫水槽中並以一大於1,000 rpm的轉速予以離心脫水歷時超過5分鐘,繼而於一溫度被設定為50℃的烘箱中進行烘乾歷時8小時。最後,以一粉碎機來對所得到的乾燥甘蔗渣進行粉碎處理,繼而依序使用孔徑為550 μm以及270 μm的篩網來進行過篩,藉此而得到三種不同粒徑(亦即,粒徑分別為<270 μm、270-550 μm以及>550 μm)之甘蔗渣粉末。 2.  吸附材料(adsorbent materials): Put 5 kg of squeezed bagasse (obtained from Taiwan Sugar Company Tainan Shanhua Sugar Factory and Yunlin County Huwei Sugar Factory) in a heating tank, add 60 L of water, and then put it at 80°C The stirring and cooking lasts for 10 minutes, and then it is allowed to stand to settle and the digested wastewater is poured out, and then the degree Brix of the wastewater (that is, the content of sucrose dissolved in the wastewater) is measured. Repeat the above steps of adding water-cooking-pouring out the waste water several times until the measured hammerness is zero. Then, add water to cook once, and let it stand for 1 hour to pick up the waste water. Afterwards, the obtained sugar-free bagasse was placed in a dehydration tank and centrifuged at a speed greater than 1,000 rpm for more than 5 minutes, and then dried in an oven set at 50°C for 8 hours . Finally, a pulverizer was used to pulverize the dried bagasse, and then sieved with sieves of 550 μm and 270 μm in order to obtain three different particle sizes (that is, granules). Bagasse powder with diameters of <270 μm, 270-550 μm and >550 μm respectively. 2. Adsorbent materials:

在下面的實施例中所使用的吸附材料包括:竹炭粉、玉米澱粉、樹薯澱粉(tapioca starch)、苦茶粉(上述材料購自於食品材料行)、碳酸氫鈉(sodium bicarbonate)(購自於Merck)、皂素(saponin)(購自於Sigma-Aldrich),以及高嶺土(Kaolinite)(由台灣糖業公司生物科技事業部所提供)。 一般實驗方法: 1.  頂空固相微萃取-氣相層析法(headspace solid-phase microextraction-gas chromatography, HS-SPME-GC)分析: The adsorption materials used in the following examples include: bamboo charcoal powder, corn starch, tapioca starch (tapioca starch), bitter tea powder (the above materials are purchased from the food material store), sodium bicarbonate (purchased) From Merck), saponin (purchased from Sigma-Aldrich), and Kaolinite (provided by the Biotechnology Division of Taiwan Sugar Company). General experimental methods: 1. Headspace solid-phase microextraction-gas chromatography (HS-SPME-GC) analysis:

首先,於37℃下使用一固相微萃取纖維(solid phase microextraction fiber)(50/30 μm, DVB/CAR/PDMS)來對一揮發性待測物質進行頂空固相微萃取(headspace solid phase microextraction)歷時5分鐘,而使得該待測物質吸附於該固相微萃取纖維上,接著使用氣相層析法(gas chromatography, GC)來分析該固相微萃取纖維所收集到的待測物質量。本實驗所使用的GC分析儀器為Thermo Fisher Scientific TRACE™ GC Ultra系統;以及其餘GC操作條件被顯示於下面的表1中。 表1.  GC的操作條件 操作參數 條件 分離管柱 Agilent J&W DB-5ms GC管柱,它具有一為30 m的長度以及一為0.25 mm的內徑(inside diameter),並且使用一具有一為0.25 µm之厚度的薄膜(film)。 管柱烘箱(column oven)的升溫程序 在一為40℃的起始溫度下維持歷時4分鐘;接著,將溫度上升至100℃ (20℃/分鐘),並在100℃下維持歷時1分鐘,然後再將溫度上升至170℃ (30℃/分鐘),並在170℃下維持歷時2.5分鐘。 載體氣體 (carrier gas) 氮氣 載體氣體流速 1.0 mL/分鐘 注射口溫度 (injector temperature) 250℃ 偵測器(detector) 火焰游離偵檢器 (flame ionization detector, FID) 偵測器溫度 (detector temperature) 250℃ 分流比 (split ratio) 1/10 實施例 1. 甘蔗渣粉末在除臭上的效用評估 First, use a solid phase microextraction fiber (50/30 μm, DVB/CAR/PDMS) at 37°C to perform headspace solid phase microextraction on a volatile substance to be tested. microextraction) lasted 5 minutes, so that the substance to be measured is adsorbed on the solid phase microextraction fiber, and then gas chromatography (GC) is used to analyze the substance to be measured collected by the solid phase microextraction fiber quantity. The GC analytical instrument used in this experiment is the Thermo Fisher Scientific TRACE™ GC Ultra system; and the remaining GC operating conditions are shown in Table 1 below. Table 1. GC operating conditions Operating parameters condition Separation column The Agilent J&W DB-5ms GC column has a length of 30 m and an inside diameter of 0.25 mm, and uses a film with a thickness of 0.25 µm. Heating program of column oven Maintained at an initial temperature of 40°C for 4 minutes; then, the temperature was increased to 100°C (20°C/min), and maintained at 100°C for 1 minute, and then the temperature was increased to 170°C (30 °C/min), and maintained at 170 °C for 2.5 minutes. Carrier gas Nitrogen Carrier gas flow rate 1.0 mL/min Injector temperature 250°C Detector Flame ionization detector (FID) Detector temperature 250°C Split ratio 1/10 Example 1. Evaluation of the effectiveness of bagasse powder in deodorization

在本實施例中,申請人選用人體異味中主要的異味分子2-壬醯醛作為代表,並且藉由測定甘蔗渣粉末對於2-壬醯醛的吸附能力來評估甘蔗渣粉末在除臭上的效用。此外,申請人亦選用市售個人清潔產品中常見用於除臭的吸附材料來進行比較。 實驗方法: In this example, the applicant selected 2-nonanal, the main odor molecule in human body odors, as a representative, and evaluated the ability of bagasse powder to deodorize by measuring the adsorption capacity of bagasse powder for 2-nonanal. utility. In addition, the applicant also selected absorbent materials commonly used for deodorization in commercially available personal cleansing products for comparison. experimental method:

首先,將96 ppm之2-壬醯醛(2-nonenal)溶液(購自於友和貿易股份有限公司)置於一密閉容器中,並於37℃水浴下歷時5分鐘。接著,利用“一般實驗方法”的第1項當中所述的方法來進行HS-SPME-GC分析,以測定沒有甘蔗渣粉末吸附下所萃取出的2-壬醯醛揮發量。First, a 96 ppm 2-nonenal (2-nonenal) solution (purchased from Youhe Trading Co., Ltd.) was placed in a closed container and placed in a water bath at 37°C for 5 minutes. Next, the HS-SPME-GC analysis was performed using the method described in Item 1 of the "General Experimental Methods" to determine the volatile amount of 2-nonanal extracted without the adsorption of bagasse powder.

接著,將上面“一般實驗材料”的第1項當中所製得之粒徑<270 μm以及270-550 μm的兩種甘蔗渣粉末分別與96 ppm之2-壬醯醛溶液置於一密閉容器中,並於37℃水浴下歷時5分鐘,以供甘蔗渣粉末吸附2-壬醯醛。接著,利用“一般實驗方法”的第1項當中所述的方法來進行HS-SPME-GC分析,以測定在甘蔗渣粉末吸附後所萃取出的2-壬醯醛揮發量。Next, place the two bagasse powders with particle size <270 μm and 270-550 μm prepared in item 1 of the above "General Experimental Materials" and 96 ppm 2-nonanal solution in a closed container. In the water bath at 37°C for 5 minutes, the bagasse powder can adsorb 2-nonanal. Next, the HS-SPME-GC analysis was performed using the method described in Item 1 of the "General Experimental Methods" to determine the volatile amount of 2-nonanal extracted after the bagasse powder was adsorbed.

甘蔗渣粉末對於2-壬醯醛的吸附率是藉由將有無吸附下所測得之2-壬醯醛揮發量代入下列公式(I)而被計算出: 公式 (I) A (B-C)/B × 100其中:A=吸附率(%) B=無吸附下所萃取出的2-壬醯醛揮發量 C=吸附後所萃取出的殘餘的2-壬醯醛揮發量 The adsorption rate of bagasse powder to 2-nonanal is calculated by substituting the volatile amount of 2-nonanal measured with or without adsorption into the following formula (I): Formula (I) : A = (BC )/B × 100 where: A = adsorption rate (%) B = the volatile amount of 2-nonanal extracted without adsorption C = the volatile amount of residual 2-nonanal extracted after adsorption

實驗分別被重複進行3次,而實驗數據是以“平均值(mean)±平均值的標準誤差(standard error of the mean, SEM)”來表示。The experiment was repeated 3 times, and the experimental data was expressed as "mean ± standard error of the mean (SEM)".

為供比較,竹炭粉以及玉米澱粉亦被拿來進行1次相同的實驗。 結果: For comparison, bamboo charcoal powder and corn starch were also used to perform the same experiment once. result:

有關兩種不同粒徑的甘蔗渣粉末以及其他2種吸附材料對於2-壬醯醛的吸附率分別被顯示於下面的表2中。 表2.   甘蔗渣粉末以及其他吸附材料對於2-壬醯醛的吸附率 測試材料 吸附率(%) 甘蔗渣粉末(<270 μm) 67.3±11.5 甘蔗渣粉末(270-550 μm) 71.8±7.5 竹炭粉 99.1 玉米澱粉 21.5 The adsorption rates of the two kinds of bagasse powders with different particle sizes and the other two adsorbents for 2-nonanal are shown in Table 2 below. Table 2. The adsorption rate of 2-nonanal by bagasse powder and other adsorbents Test material Adsorption rate(%) Bagasse powder (<270 μm) 67.3±11.5 Bagasse powder (270-550 μm) 71.8±7.5 Bamboo charcoal powder 99.1 corn starch 21.5

由表1可見,甘蔗渣粉末對於2-壬醯醛的吸附率僅略低於竹炭粉,並且皆顯著地優於玉米澱粉所具者。 實施例 2. 甘蔗渣在吸油上的效用評估 It can be seen from Table 1 that the adsorption rate of 2-nonanal by bagasse powder is only slightly lower than that of bamboo charcoal powder, and both are significantly better than those of corn starch. Example 2. Evaluation of the effectiveness of bagasse on oil absorption

在本實施例中,申請人選用椰子油(coconut oil)以及習知用於模擬人類皮脂的油脂混合物[又被稱為人工皮脂(artificial sebum)](Deeksha et al.(2014), Recent Pat. Inflamm. Allergy. Drug Discov., 8(1):48-58),並且藉由觀察甘蔗渣粉末對於椰子油油滴以及人工皮脂的吸附能力來評估甘蔗渣粉末在吸油上的效用。此外,申請人亦選用市售個人清潔產品中常見用於吸油的吸附材料來進行比較。 A、 油滴吸附能力之測定: 實驗方法: In this embodiment, the applicant selected coconut oil and a conventional oil mixture used to simulate human sebum [also known as artificial sebum] (Deeksha et al. (2014), Recent Pat. Inflamm. Allergy. Drug Discov. , 8(1):48-58), and evaluate the effect of bagasse powder on oil absorption by observing the ability of bagasse powder to absorb coconut oil droplets and artificial sebum. In addition, the applicant also selected absorbent materials commonly used for oil absorption in commercially available personal cleansing products for comparison. A. Determination of oil droplet adsorption capacity: experimental method:

取1 g甘蔗渣粉末(<270 μm),然後以滴管吸取50 μL的椰子油逐滴添加至甘蔗渣粉末上,同時觀察油滴吸附的情形。為供比較,樹薯澱粉、玉米澱粉、高嶺土以及竹炭粉亦被拿來進行相同的實驗。 結果: Take 1 g of bagasse powder (<270 μm), and then add 50 μL of coconut oil with a dropper to the bagasse powder, while observing the adsorption of oil droplets. For comparison, tapioca starch, corn starch, kaolin and bamboo charcoal powder were also used for the same experiment. result:

經由觀察而發現,油滴在滴至甘蔗渣粉末的當下立刻被吸附,展現快速的吸附速度;相較之下,油滴在滴至竹炭粉、玉米澱粉、高嶺土以及樹薯澱粉的當下並未馬上被吸附而維持完整的液滴形狀(參見圖1),並且在大約10秒後才被完全吸附。在油滴皆被完全吸附之後,甘蔗渣粉末可觀察到部分結塊的狀態而易於清除;相較之下,其他4種材料則仍呈粉末狀態(數據未顯示)。 B、 人工皮脂吸附能力之測定: 實驗材料: 1.  人工皮脂的製備: Through observation, it was found that the oil droplets were adsorbed immediately when they were dropped on the bagasse powder, showing a rapid adsorption speed; in contrast, the oil droplets were not absorbed when dropped on the bamboo charcoal powder, corn starch, kaolin, and tapioca starch. It is adsorbed immediately to maintain the complete droplet shape (see Figure 1), and is completely adsorbed after about 10 seconds. After the oil droplets are completely absorbed, the bagasse powder can be observed to be partially agglomerated and easy to remove; in contrast, the other four materials are still in the powder state (data not shown). B. Determination of the adsorption capacity of artificial sebum: Experimental materials: 1. Preparation of artificial sebum:

申請人依據下面表3所示配方來將各組分予以充分混合,接著置於70℃水浴下加熱至所有組分完全溶解,而製備得到一呈澄清溶液狀的人工皮脂。由此所得到的人工皮脂被拿來進行下面的吸附測試。 表3.    人工皮脂的配方 組分 含量(wt%) 角鯊烯(squalene) 5 蠟酯(wax esters) 石蠟(paraffin) 10 鯨蠟(spermaceti) 15 三酸甘油酯(triacylglycerides) 橄欖油(olive oil) 20 椰子油(coconut oil) 15 脂肪酸(fatty acids) 硬脂酸(stearic acid) 7.5 油酸(oleic acid) 10 膽固醇(cholesterol) 17.5 實驗方法: The applicant thoroughly mixed the components according to the formula shown in Table 3 below, and then heated it in a 70°C water bath until all the components were completely dissolved, thereby preparing an artificial sebum in the form of a clear solution. The artificial sebum thus obtained was used for the following adsorption test. Table 3. Formula of artificial sebum Component Content (wt%) Squalene 5 Wax esters Paraffin 10 Spermaceti 15 Triacylglycerides (triacylglycerides) Olive oil 20 Coconut oil 15 Fatty acids Stearic acid 7.5 Oleic acid 10 Cholesterol 17.5 experimental method:

上述三種不同粒徑之甘蔗渣粉末對於人工皮脂的吸附能力之測定主要是參考Deeksha et al.(2014)(同上述)當中所述的方法來進行,並略作修改。 The determination of the adsorption capacity of the three bagasse powders with different particle diameters for artificial sebum is mainly carried out with reference to the method described in Deeksha et al. (2014) (same as above) with slight modifications.

首先,取0.5 g的羊毛毛線來模擬人類毛髮,並以微量量吸管(micropipette)來將50 μL的人工皮脂逐滴添加至毛線上。待人工皮脂被毛線完全吸附之後,添加0.1 g的甘蔗渣粉末並予以搓揉,使甘蔗渣粉末與毛線充分接觸而可吸附其上的人工皮脂。在歷時1分鐘之後,輕拍毛線來去除甘蔗渣粉末,繼而使用市售之吸油面紙來吸取毛線上剩餘的人工皮脂,接著藉由吸油面紙的重量增加來估算毛線在甘蔗渣粉末吸附後的人工皮脂剩餘量(g)。First, take 0.5 g of wool wool to simulate human hair, and use a micropipette to add 50 μL of artificial sebum dropwise to the wool. After the artificial sebum is completely absorbed by the wool, 0.1 g of bagasse powder is added and kneaded so that the bagasse powder is in full contact with the wool so that the artificial sebum can be absorbed. After 1 minute, tap the wool to remove the bagasse powder, and then use a commercially available oil-absorbing facial paper to absorb the remaining artificial sebum on the wool, and then use the weight of the oil-absorbing facial paper to estimate that the wool is absorbed by the bagasse powder. The remaining amount of artificial sebum (g).

甘蔗渣粉末對於人工皮脂的吸附率是藉由將所測得之人工皮脂剩餘量代入下列公式(II)而被計算出: 公式 (II) E=[(F-G )/F] ×100其中:E=人工皮脂吸附率(%) F=人工皮脂原始量(40.5 g) G=人工皮脂剩餘量(g) The adsorption rate of bagasse powder to artificial sebum is calculated by substituting the measured residual amount of artificial sebum into the following formula (II): Formula (II) : E=[(FG )/F] × 100 where: E=Artificial sebum adsorption rate (%) F=The original amount of artificial sebum (40.5 g) G=The remaining amount of artificial sebum (g)

實驗分別被重複進行3次,而實驗數據是以“平均值(mean)±平均值的標準誤差(standard error of the mean, SEM)”來表示。The experiment was repeated 3 times, and the experimental data was expressed as "mean ± standard error of the mean (SEM)".

為供比較,皂素被拿來進行3次相同的實驗,而苦茶粉、樹薯澱粉、玉米澱粉、高嶺土、以及竹炭粉被拿來進行1次相同的實驗。 結果: For comparison, saponin was used for the same experiment three times, while bitter tea powder, tapioca starch, corn starch, kaolin, and bamboo charcoal powder were used for the same experiment once. result:

有關三種不同粒徑的甘蔗渣粉末以及其他6種吸附材料對於人工皮脂的吸附率分別被顯示於下面的表4中。 表4.   甘蔗渣粉末以及其他吸附材料對於人工皮脂的吸附率 測試材料 吸附率(%) 甘蔗渣粉末(<270 μm) 78.8±12.0 甘蔗渣粉末(270-550 μm) 88.9±11.0 甘蔗渣粉末(>550 μm) 92.1±9.1 皂素 83.9±5.2 苦茶粉 93.8 樹薯澱粉 86.1 玉米澱粉 85.3 高嶺土 84.0 竹炭粉 41.6 The adsorption rates of three kinds of bagasse powder with different particle sizes and other six kinds of adsorbents for artificial sebum are shown in Table 4 below. Table 4. Adsorption rate of bagasse powder and other adsorbent materials for artificial sebum Test material Adsorption rate(%) Bagasse powder (<270 μm) 78.8±12.0 Bagasse powder (270-550 μm) 88.9±11.0 Bagasse powder (>550 μm) 92.1±9.1 Saponin 83.9±5.2 Bitter tea powder 93.8 Tapioca starch 86.1 corn starch 85.3 Kaolin 84.0 Bamboo charcoal powder 41.6

由表4可見,甘蔗渣粉末對於人工皮脂的吸附率是近似於苦茶粉、樹薯澱粉、玉米澱粉、高嶺土以及皂素所具者,並且顯著高於竹炭粉所具者。 It can be seen from Table 4 that the adsorption rate of bagasse powder for artificial sebum is similar to that of bitter tea powder, tapioca starch, corn starch, kaolin and saponin, and is significantly higher than that of bamboo charcoal powder.

基於上述,申請人認為:甘蔗渣粉末被預期具有可供用開發吸附油脂(特別是人類皮脂)的產品之潛力。 實施例 3. 甘蔗渣粉末使用後殘留情形之評估 Based on the above, the applicant believes that the bagasse powder is expected to have the potential to be used to develop products that absorb oil (especially human sebum). Example 3. Evaluation of the residue of bagasse powder after use

在本實施例中,同樣使用毛線來模擬人類毛髮,以評估甘蔗渣粉末在使用後殘留於毛髮上的情形。此外,申請人亦選用市售個人清潔用品中常見用於除臭吸油的吸附材料來進行比較。 實驗方法: In this embodiment, wool is also used to simulate human hair to evaluate the condition of bagasse powder remaining on the hair after use. In addition, the applicant also selected absorbent materials commonly used for deodorization and oil absorption in commercially available personal cleaning products for comparison. experimental method:

本實驗大體上是參照上面實施例2的第B項當中所述的方法來進行,不同之處在於:改為測量甘蔗渣粉末吸附後的總重以及毛線在甘蔗渣粉末吸附後的皮脂殘留量,接著代入下列公式(III)來計算出甘蔗渣粉末在使用後於毛髮上的殘留率: 公式 (III) H=[(I-J-K )/L] ×100其中:H=甘蔗渣粉末殘留率(%) I=吸附後總重(g) J=人工皮脂剩餘量(g) K=毛線重(0.5 g) L=甘蔗渣粉末原始量(0.1 g) This experiment is basically carried out with reference to the method described in item B of Example 2 above. The difference is: instead of measuring the total weight of bagasse powder after adsorption, and the amount of sebum residue of the wool yarn after adsorption of bagasse powder , And then substitute the following formula (III) to calculate the residue rate of bagasse powder on the hair after use: Formula (III) : H=[(IJK )/L] × 100 where: H= residue rate of bagasse powder ( %) I = total weight after adsorption (g) J = remaining amount of artificial sebum (g) K = weight of wool (0.5 g) L = original amount of bagasse powder (0.1 g)

實驗分別被重複進行3次,而實驗數據是以“平均值(mean)±平均值的標準誤差(standard error of the mean, SEM)”來表示。The experiment was repeated 3 times, and the experimental data was expressed as "mean ± standard error of the mean (SEM)".

為供比較,苦茶粉、樹薯澱粉、玉米澱粉、高嶺土、皂素以及竹炭粉被拿來進行1次相同的實驗 結果: For comparison, bitter tea powder, tapioca starch, corn starch, kaolin, saponin, and bamboo charcoal powder were used for the same experiment once . result:

有關三種不同粒徑的甘蔗渣粉末以及其他6種吸附材料於毛髮上的殘留率分別被顯示於下面的表5中。 表5.   甘蔗渣粉末以及其他吸附材料於毛髮上的的殘留率 測試材料 殘留率(%) 甘蔗渣粉末(<270 μm) 26.5±7.0 甘蔗渣粉末(270-550 μm) 9.0±13.0 甘蔗渣粉末(>550 μm) 20.0±10.5 苦茶粉 100 樹薯澱粉 100 玉米澱粉 100 高嶺土 76.4 皂素 98.3 竹炭粉 87.5 The residual rates of bagasse powder with three different particle sizes and six other adsorbents on the hair are respectively shown in Table 5 below. Table 5. Residual rate of bagasse powder and other absorbent materials on hair Test material Residual rate (%) Bagasse powder (<270 μm) 26.5±7.0 Bagasse powder (270-550 μm) 9.0±13.0 Bagasse powder (>550 μm) 20.0±10.5 Bitter tea powder 100 Tapioca starch 100 corn starch 100 Kaolin 76.4 Saponin 98.3 Bamboo charcoal powder 87.5

由表5可見,甘蔗渣粉末在使用後的殘留率是顯著低於其他吸附材料所具者。It can be seen from Table 5 that the residue rate of bagasse powder after use is significantly lower than that of other adsorbent materials.

綜合實施例2與3的結果可見,甘蔗渣粉末同時具有優異的除臭與吸油能力,並且使用後便於清除,不易殘留於毛髮上。相對地,其他吸附材料則無法同時具有這三種優點。例如,竹炭粉雖然具有優異的除臭能力但具有較差的吸油能力,並且使用後容易殘留。苦茶粉、樹薯澱粉以及玉米澱粉雖具有良好的吸油能力,但同時也最容易殘留。 實施例 4. 本發明清潔組成物的製備與效用評估 Combining the results of Examples 2 and 3, it can be seen that the bagasse powder has excellent deodorizing and oil absorption capabilities at the same time, and it is easy to remove after use, and it is not easy to remain on the hair. In contrast, other adsorbent materials cannot have these three advantages at the same time. For example, although bamboo charcoal powder has excellent deodorizing ability, it has poor oil absorption ability and is easy to remain after use. Although bitter tea powder, tapioca starch and corn starch have good oil absorption capacity, they are also the easiest to remain. Example 4. Preparation and effectiveness evaluation of the cleaning composition of the present invention

在本實施例中,申請人進一步將甘蔗渣粉末(270-550 μm)與習知吸附材料進行組合以製備出包含有甘蔗渣粉末的清潔組成物,並且將其拿來與市售的乾洗髮(dry shampoo)產品進行效用比較。 實驗方法: In this example, the applicant further combined bagasse powder (270-550 μm) with a conventional absorbent material to prepare a cleaning composition containing bagasse powder, and used it with a commercially available dry cleaning composition. (dry shampoo) products to compare their effectiveness. experimental method:

首先,依據下面表6中所示配方來製備3種包含有甘蔗渣粉末的清潔組成物(亦即組成物1至3)。 表6. 本發明的清潔組成物的配方 組分 組成物1 組成物2 組成物3 含量(wt%) 甘蔗渣粉末(270-550 μm) 1 20 50 苦茶粉 97 78 48 竹炭粉 2 2 2 First, according to the formula shown in Table 6 below, three cleaning compositions containing bagasse powder (ie, compositions 1 to 3) were prepared. Table 6. The formula of the cleaning composition of the present invention Component Composition 1 Composition 2 Composition 3 Content (wt%) Bagasse powder (270-550 μm) 1 20 50 Bitter tea powder 97 78 48 Bamboo charcoal powder 2 2 2

有關組成物1至3對於2-壬醯醛的吸附能力、對於人工皮脂的吸附能力以及使用後殘留情形分別是依照上面實施例1、實施例2的第B項以及實施例3當中所述的方法來進行評估。另外,市售產品La Focus 119救急乾洗髮蜜粉(La Focus)以及NATURIA乾洗髮霧(René Furterer)亦被拿來進行相同的實驗。實驗分別被重複進行3次,而實驗數據是以“平均值(mean)±平均值的標準誤差(standard error of the mean, SEM)”來表示。 結果: The adsorption capacity of compositions 1 to 3 for 2-nonanal, the adsorption capacity for artificial sebum, and the residual situation after use are as described in Example 1, Item B of Example 2, and Example 3, respectively. Method to evaluate. In addition, the commercial products La Focus 119 emergency dry hair powder (La Focus) and NATURIA dry hair mist (René Furterer) were also used in the same experiment. The experiment was repeated 3 times, and the experimental data was expressed as "mean ± standard error of the mean (SEM)". result:

有關本發明的清潔組成物以及市售之乾洗髮產品對於2-壬醯醛與人工皮脂的吸附率以及使用後的殘留率分別被顯示於下面的表7中。 表7.   本發明的清潔組成物以及市售乾洗髮產品的比較 測試產品 甘蔗渣含量(wt%) 對於2-壬醯醛的吸附率(%) 對於人工皮脂的吸附率(%) 清潔組成物1 1 未測得 62.8±18.9 清潔組成物2 20 46.1±1.9 76.0±5.2 清潔組成物3 50 56.5±2.3 76.8±2.3 La Focus 119救急乾洗髮蜜粉 未測得 14.2±3.5 NATURIA乾洗髮霧 未測得 77.2±11 The absorption rate of 2-nonanal and artificial sebum and the residual rate after use of the cleansing composition of the present invention and commercially available dry hair products are shown in Table 7 below, respectively. Table 7. Comparison of the cleansing composition of the present invention and commercial dry hair products Test product Bagasse content (wt%) Adsorption rate for 2-nonanal (%) Adsorption rate for artificial sebum (%) Cleaning composition 1 1 Not measured 62.8±18.9 Cleaning composition 2 20 46.1±1.9 76.0±5.2 Cleaning composition 3 50 56.5±2.3 76.8±2.3 La Focus 119 Emergency Dry Hair Loose Powder - Not measured 14.2±3.5 NATURIA Dry Hair Fog - Not measured 77.2±11

由表7可見,清潔組成物1至3對於人工皮脂皆具有優異的吸附能力,但只有清潔組成物2與3對於2-壬醯醛具有顯著地優異的吸附能力,而此吸附能力會隨著甘蔗渣粉末含量的增加而越趨明顯。這表示甘蔗渣粉末在清潔組成物的除臭能力上扮演極其重要的角色,只要略為添加甘蔗渣粉末即可賦予一組成物除臭能力並同時使其兼具優異的吸油能力。相對地,市售的乾洗髮產品的吸油能力差異甚大,並且皆不具有除臭能力。It can be seen from Table 7 that cleansing compositions 1 to 3 all have excellent adsorption capacity for artificial sebum, but only cleansing compositions 2 and 3 have significantly excellent adsorption capacity for 2-nonanal, and this adsorption capacity will increase with The increase of bagasse powder content becomes more and more obvious. This means that the bagasse powder plays an extremely important role in the deodorizing ability of the cleaning composition, and a slight addition of the bagasse powder can give a composition deodorizing ability and at the same time make it have excellent oil absorption ability. In contrast, the oil absorption capacity of commercially available dry hair products varies greatly, and none of them has the ability to deodorize.

本發明的上述以及其它目的、特徵與優點,在參照以下的詳細說明與較佳實施例和隨文檢附的圖式後,將變得明顯,其中: 圖1顯示甘蔗渣粉末、高嶺土、竹炭粉、玉米澱粉以及樹薯澱粉在接觸油滴瞬間的狀態,其中A代表甘蔗渣粉末;B代表高嶺土;C代表竹炭粉;D代表玉米澱粉;以及E代表樹薯澱粉。 The above and other objectives, features and advantages of the present invention will become apparent with reference to the following detailed description, preferred embodiments and drawings attached with the text, among which: Figure 1 shows the state of bagasse powder, kaolin, bamboo charcoal powder, corn starch and tapioca starch at the moment of contact with oil droplets, where A represents bagasse powder; B represents kaolin; C represents bamboo charcoal powder; D represents corn starch; and E represents Tapioca starch.

Claims (10)

一種用於除臭的方法,其包含下列步驟: 提供一包含有甘蔗渣的組成物; 對一需要除臭之含有異味分子的區域施用該組成物,而使得該組成物吸附該異味分子;以及 移除吸附有該異味分子的組成物。 A method for deodorization, which includes the following steps: Provide a composition containing bagasse; Apply the composition to an area containing odor molecules that needs to be deodorized, so that the composition absorbs the odor molecules; and Remove the composition that has adsorbed the odor molecules. 如請求項1的方法,其中,該區域是動物或人體的表面。The method of claim 1, wherein the area is the surface of an animal or a human body. 如請求項1的方法,其中,該區域進一步含有油脂,以及該組成物同時吸附該區域的異味分子與油脂。According to the method of claim 1, wherein the area further contains grease, and the composition simultaneously adsorbs odor molecules and grease in the area. 如請求項1的方法,其中,該異味分子是選自於由下列所構成的群組:有機氮化合物、有機硫化合物、短鏈脂肪酸、醛類,以及它們的組合。The method of claim 1, wherein the odor molecule is selected from the group consisting of organic nitrogen compounds, organic sulfur compounds, short-chain fatty acids, aldehydes, and combinations thereof. 如請求項4的方法,其中,該異味分子是2-壬醯醛。The method of claim 4, wherein the odor molecule is 2-nonanal. 一種甘蔗渣供用於製備一用於去除異味分子的清潔組成物的用途。A bagasse is used for preparing a cleaning composition for removing odor molecules. 如請求項6的用途,其中,該異味分子是2-壬醯醛。The use according to claim 6, wherein the odor molecule is 2-nonanal. 如請求項6的用途,其中,該清潔組成物是用於同時去除異味分子以及油脂。The use according to claim 6, wherein the cleaning composition is used to simultaneously remove odor molecules and grease. 一種除臭清潔組成物,其包含有甘蔗渣,以及一選自於由下列所構成之群組中的吸附材料:多孔性纖維材料、澱粉、矽酸鋁鹽礦物,以及它們的組合。A deodorizing cleaning composition comprising bagasse and an adsorbent selected from the group consisting of porous fiber materials, starch, aluminum silicate minerals, and combinations thereof. 如請求項9的除臭清潔組成物,其中,該吸附材料是選自於由下列所構成之群組:植物纖維、高嶺土、竹炭粉、苦茶粉,以及它們的組合。The deodorizing and cleaning composition according to claim 9, wherein the adsorbent is selected from the group consisting of plant fiber, kaolin, bamboo charcoal powder, bitter tea powder, and combinations thereof.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115106062A (en) * 2022-06-27 2022-09-27 湖北中烟工业有限责任公司 Composite natural solid phase extracting agent, preparation method thereof and resveratrol purification method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN210595368U (en) * 2019-07-10 2020-05-22 广东韶科环保科技有限公司 Adsorption type wastewater treatment device

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005187430A (en) * 2003-12-26 2005-07-14 Shikibo Ltd Deodorizing agent and antibacterial agent composed of blast-crushed natural plant fiber
JP7056903B2 (en) * 2017-07-20 2022-04-19 株式会社スタジオライン Deodorant liquid detergent composition and its manufacturing method
CN113164916A (en) * 2018-11-08 2021-07-23 斯瓦蒙卢森堡公司 Oil remediation composition, method of producing the same, and method of remediating oil spills

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN210595368U (en) * 2019-07-10 2020-05-22 广东韶科环保科技有限公司 Adsorption type wastewater treatment device

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Oil by-Product Removal from Aqueous Solution using Sugarcane Bagasse as Absorbent, International Journal of Emerging Science and Engineering (IJESE), ISSN: 2319–6378, Volume-2 Issue-9, July 2014 *
Oil by-Product Removal from Aqueous Solution using Sugarcane Bagasse as Absorbent, International Journal of Emerging Science and Engineering (IJESE), ISSN: 2319–6378, Volume-2 Issue-9, July 2014。

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115106062A (en) * 2022-06-27 2022-09-27 湖北中烟工业有限责任公司 Composite natural solid phase extracting agent, preparation method thereof and resveratrol purification method
CN115106062B (en) * 2022-06-27 2023-10-31 湖北中烟工业有限责任公司 Composite natural solid phase extractant, preparation method thereof and resveratrol purification method

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