TWI740118B - Carbonizing furnace - Google Patents
Carbonizing furnace Download PDFInfo
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- TWI740118B TWI740118B TW108108931A TW108108931A TWI740118B TW I740118 B TWI740118 B TW I740118B TW 108108931 A TW108108931 A TW 108108931A TW 108108931 A TW108108931 A TW 108108931A TW I740118 B TWI740118 B TW I740118B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B1/00—Retorts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
Abstract
Description
本發明係有關於一種碳化爐,其具有由滾筒構成之作為乾餾容器的蒸餾器並藉由乾餾處理來碳化被供應至蒸餾器內部的待處理的材料。具體地,本發明係有關於一種碳化爐,其能夠在高溫下適當地執行碳化處理。 The present invention relates to a carbonization furnace, which has a distiller constituted by a drum as a dry distillation vessel and carbonizes the material to be processed supplied to the interior of the distiller through dry distillation treatment. Specifically, the present invention relates to a carbonization furnace that can appropriately perform carbonization treatment at high temperatures.
從家庭等排放之含有機物質的廢水通常在污水處理廠經過廢水處理,並且在廢水處理期間產生含有機物質的污水污泥。在處置污水污泥時,污水污泥包含大量的水,因而無法依原樣來處置。於是,為了減量,目前已執行像冷凝及脫水處理的各種處理、進一步的焚化及熔化。 Wastewater containing organic substances discharged from households, etc. is usually treated in a sewage treatment plant, and sewage sludge containing organic substances is produced during the wastewater treatment. When disposing of sewage sludge, the sewage sludge contains a large amount of water and cannot be disposed of as it is. Therefore, in order to reduce weight, various treatments such as condensation and dehydration treatment, and further incineration and melting have been performed.
然而,在焚化污水污泥的情況下,可以實現解毒及體積的減少,但是很難回收利用污泥中所包含的能量及有效成分。因此,已執行碳化處理來作為用於處理污水污泥的另一個方法,其中其生成物的各種有效使用係可預期的。 However, in the case of incineration of sewage sludge, detoxification and volume reduction can be achieved, but it is difficult to recycle the energy and effective components contained in the sludge. Therefore, carbonization treatment has been performed as another method for treating sewage sludge, in which various effective uses of its products are expected.
污水污泥在基質中按質量計包含約45%的碳含量。不像焚化及熔化,碳化處理沒有完全消耗污泥中的碳含量,但是藉由熱解(碳化)污泥來使碳含量處於無氧或低氧狀態中,以產生具有新合成物的碳化材料(碳化生成物)。 Sewage sludge contains about 45% carbon content by mass in the substrate. Unlike incineration and melting, carbonization treatment does not completely consume the carbon content in the sludge, but pyrolyzes (carbonizes) the sludge to make the carbon content in an oxygen-free or low-oxygen state to produce carbonized materials with new compounds (Carbonization product).
具體地,例如,藉由利用下面專利文件1所示的碳化處理設備 使碳化材料成為約幾毫米大小的粒狀而產生這樣的碳化材料。如此獲得的碳化生成物具有接近木炭的物理特性且目前已使用在像燃料、肥料(土壤改良劑)及水泥骨料等應用中。 Specifically, for example, such a carbonized material is produced by making the carbonized material into a granular shape with a size of about several millimeters by using a carbonization processing apparatus shown in
專利文件1:JP-A-2008-238129 Patent Document 1: JP-A-2008-238129
在像土壤改良劑的應用中使用碳化材料之情況下,包含在碳化材料中的氯化物可能會造成問題。為了從含鹽的污泥產生包含減少的氯化物的碳化材料,必須在碳化處理期間將溫度增加至約1,000℃至1,200℃。然而,因為耐熱鋼至今已使用於作為碳化爐之乾餾容器的圓筒形滾筒(蒸餾器),所以可用溫度之上限為約900℃,因而很難將溫度增加至能夠移除氯化物的溫度。 In the case of using carbonized materials in applications like soil amendments, the chloride contained in the carbonized materials may cause problems. In order to produce carbonized materials containing reduced chlorides from salt-containing sludge, the temperature must be increased to approximately 1,000°C to 1,200°C during the carbonization treatment. However, because heat-resistant steel has been used in the cylindrical drum (distiller) as the retort container of the carbonization furnace so far, the upper limit of the usable temperature is about 900°C, and it is difficult to increase the temperature to a temperature that can remove chlorides.
為了能夠在約1,000℃至1,200℃的高溫度下進行處理,必須使用一種用陶瓷取代耐熱鋼的蒸餾器。然而,陶瓷製管件隨著其尺寸的增加而難以生產,並且很難生產具有等於或大於傳統蒸餾器尺寸(例如,1公尺直徑及10公尺長度)的陶瓷製蒸餾器。此外,陶瓷製蒸餾器在韌性方面比金屬製蒸餾器差且在熱衝擊特性方面係較差的。因此,會有下面的問題:當供應低溫污泥時,蒸餾器無法承受溫差而破裂。 In order to be able to process at a high temperature of about 1,000°C to 1,200°C, a distiller that replaces heat-resistant steel with ceramics must be used. However, ceramic pipe fittings are difficult to produce as their size increases, and it is difficult to produce a ceramic distiller having a size equal to or larger than that of a conventional distiller (for example, a diameter of 1 meter and a length of 10 meters). In addition, ceramic distiller is inferior to metal distiller in toughness and inferior in thermal shock characteristics. Therefore, there will be the following problem: When supplying low-temperature sludge, the distiller cannot withstand the temperature difference and breaks.
有鑑於上述這樣的情況,本發明的一個目的欲提供一種碳化爐,其能夠在高於1,000℃的溫度下進行碳化處理,同時可避免在作為乾餾容器的蒸餾器使用陶瓷材料之情況下可能引起的生產力及熱衝擊的問題。 In view of the above-mentioned circumstances, an object of the present invention is to provide a carbonization furnace that can perform carbonization treatment at a temperature higher than 1,000°C, while avoiding the possibility of causing problems when ceramic materials are used as a retort vessel for retorting. The problem of productivity and thermal shock.
本發明之碳化爐係一種包括一爐體及一蒸餾器之碳化爐,該蒸餾器具有一通過該爐體的內部之滾筒,該碳化爐係構造 成使得一待處理的材料從該蒸餾器之軸向上的一端側的入口供應至該蒸餾器的內部,該待處理的材料在旋轉該蒸餾器的同時在該軸向上移動,在移動過程期間該待處理的材料藉由一乾餾處理而被碳化,並且所獲得的碳化材料從該蒸餾器的出口排放,其中該蒸餾器包括一第一蒸餾器及一第二蒸餾器,該爐體的內部區分成包括一第一溫控區及一第二溫控區的區域,該第一蒸餾器係設置在該第一溫控區中,該第二蒸餾器係設置在該第二溫控區中,該第二蒸餾器包含一陶瓷材料,該第二溫控區係構造成被控制為具有比該第一溫控區的溫度還高的溫度,以及該碳化爐係構造成使得該待處理的材料在該第一溫控區中被加熱至一預定溫度,並且已加熱之該待處理的材料接著被供應至該第二蒸餾器的內部。 The carbonization furnace of the present invention is a carbonization furnace including a furnace body and a distiller. The distiller has a drum passing through the inside of the furnace body. The upward inlet at one end side is supplied to the inside of the distiller, the material to be treated moves in the axial direction while rotating the distiller, and the material to be treated is carbonized by a dry distillation process during the moving process, And the obtained carbonized material is discharged from the outlet of the distiller, wherein the distiller includes a first distiller and a second distiller, and the interior of the furnace body is divided into a first temperature control zone and a second temperature control zone. Control zone, the first still is arranged in the first temperature control zone, the second still is arranged in the second temperature control zone, the second still contains a ceramic material, the second The temperature control zone is configured to be controlled to have a temperature higher than the temperature of the first temperature control zone, and the carbonization furnace system is configured so that the material to be processed is heated to a predetermined temperature in the first temperature control zone The temperature and the heated material to be processed is then supplied to the inside of the second still.
本發明之碳化爐包含在一第一溫控區中之一第一蒸餾器及在一第二溫控區中之一第二蒸餾器,該第二溫控區的溫度被控制成高於該第一溫控區的溫度。每個蒸餾器可以由能夠應付個別處理溫度之材料製成。 The carbonization furnace of the present invention includes a first distiller in a first temperature control zone and a second distiller in a second temperature control zone, and the temperature of the second temperature control zone is controlled to be higher than the The temperature of the first temperature control zone. Each distiller can be made of materials that can cope with the individual processing temperature.
該第二蒸餾器可以具有只配置在第二溫控區中之尺寸,故相較於只在一個蒸餾器中完成碳化處理的情況,可以實現第二蒸餾器的小型化。因此,可以改善含有陶瓷材料之該第二蒸餾器的生產力。在此,可用之陶瓷材料的實例包括氧化鋁、碳化矽、氮化矽等等。 The second distiller can have a size that is only arranged in the second temperature control zone. Therefore, compared with the case where the carbonization treatment is completed in only one distiller, the second distiller can be miniaturized. Therefore, the productivity of the second distiller containing the ceramic material can be improved. Here, examples of ceramic materials that can be used include alumina, silicon carbide, silicon nitride, and the like.
此外,在本發明之碳化爐中,該待處理的材料事先被 加熱至一預定溫度,然後供應至該第二蒸餾器。因此,可以使該高溫第二蒸餾器與該待處理的材料(被供應至該第二蒸餾器的內部)之間的溫差變小,因而可以減緩由溫差造成的熱衝擊。因此可以防止含有陶瓷材料的該第二蒸餾器因熱衝擊而破裂。 In addition, in the carbonization furnace of the present invention, the material to be processed is previously heated to a predetermined temperature, and then supplied to the second still. Therefore, the temperature difference between the high-temperature second distiller and the material to be processed (which is supplied to the inside of the second distiller) can be reduced, and thus the thermal shock caused by the temperature difference can be alleviated. Therefore, the second distiller containing the ceramic material can be prevented from being broken due to thermal shock.
在本發明之如此構造的碳化爐中,可以將處理溫度增加至可以移除污泥中所含有之氯化物的溫度。因此,例如,甚至在污泥含有大量氯化物之情況下,可以適當地執行碳化處理。含有大量氯化物的污泥係例如在固體含量中具有約0.5至3%之氯的比例的污泥。由本發明之碳化爐所產生的碳化生成物具有例如約0.05質量%或更少的最終氯濃度。 In the thus-structured carbonization furnace of the present invention, the treatment temperature can be increased to a temperature at which the chloride contained in the sludge can be removed. Therefore, for example, even in the case where the sludge contains a large amount of chloride, the carbonization treatment can be appropriately performed. The sludge containing a large amount of chloride is, for example, sludge having a chlorine ratio of about 0.5 to 3% in the solid content. The carbonization product produced by the carbonization furnace of the present invention has a final chlorine concentration of, for example, about 0.05% by mass or less.
再者,在本發明中,該第二蒸餾器可以配置在該第一蒸餾器下方,並且該碳化爐可以構造成使得該待處理的材料在該第二蒸餾器內朝與該待處理的材料在該第一蒸餾器內之移動方向相反的方向移動。在兩個蒸餾器配置在上方及下方且該待處理的材料之移動路徑設置成近似U形之情況下,可以縮短該碳化爐的長度。此外,可以減少該碳化爐的安裝空間。 Furthermore, in the present invention, the second distiller may be arranged below the first distiller, and the carbonization furnace may be configured such that the material to be treated faces the material to be treated in the second distiller. In the first distiller, the moving direction is opposite to the moving direction. When two distillers are arranged above and below and the moving path of the material to be processed is set to be approximately U-shaped, the length of the carbonization furnace can be shortened. In addition, the installation space of the carbonization furnace can be reduced.
在本發明中,該碳化爐可以進一步包括一連接容器,該連接容器包圍第一蒸餾器的一端部且在該連接容器的內部容納第一蒸餾器的出口,其中該連接容器具有一向下開口,該向下開口形成在一下端處且構造成連接至在該第二蒸餾器之入口側的一開口。 In the present invention, the carbonization furnace may further include a connection container that surrounds one end of the first distiller and accommodates the outlet of the first distiller inside the connection container, wherein the connection container has a downward opening, The downward opening is formed at the lower end and is configured to be connected to an opening on the inlet side of the second still.
這樣的連接容器可以將該待處理的材料引導至該第二蒸餾器之入口側的開口,同時防止從第一蒸餾器排放之該待處理的材料因與外部空氣接觸而冷卻。 Such a connection container can guide the material to be processed to the opening on the inlet side of the second distiller, while preventing the material to be processed discharged from the first distiller from being cooled due to contact with outside air.
此外,在本發明中,該第一溫控區可以配置在由該待處理的材料所產生之可燃氣體的流動方向的上游側,以及該第二溫控區可以配置在該流動方向的下游側。這樣的結構可以將在該第一溫控區中被加熱至一預定溫度的高溫可燃氣體引入該第二溫控區,以致於可以輕易地增加該第二溫控區中的環境溫度。 In addition, in the present invention, the first temperature control zone may be arranged on the upstream side of the flow direction of the combustible gas generated by the material to be treated, and the second temperature control zone may be arranged on the downstream side of the flow direction . Such a structure can introduce the high-temperature combustible gas heated to a predetermined temperature in the first temperature control zone into the second temperature control zone, so that the ambient temperature in the second temperature control zone can be easily increased.
再者,在本發明中,該蒸餾器可以包含複數個第二蒸餾器,每個第二蒸餾器係平行配置在該第二溫控區中,以及該碳化爐進一步包括一分配手段,該分配手段係構造成使得從該第一蒸餾器排放之該待處理的材料被分配及供應至該複數個第二蒸餾器中之每一者。這樣的構造可以實現在高溫處理中所使用之該第二蒸餾器的進一步小型化,同時維持該整個碳化爐的處理能力。此外,可以使含有陶瓷材料之第二蒸餾器的生產力更令人滿意。 Furthermore, in the present invention, the distiller may include a plurality of second distillers, each of the second distillers is arranged in parallel in the second temperature control zone, and the carbonization furnace further includes a distribution means, the distribution The means is configured such that the material to be processed discharged from the first still is distributed and supplied to each of the plurality of second stills. Such a structure can realize further miniaturization of the second still used in high-temperature processing, while maintaining the processing capacity of the entire carbonization furnace. In addition, the productivity of the second distiller containing the ceramic material can be made more satisfactory.
上述本發明可以提供一種碳化爐,其能夠在高於1,000℃的溫度下進行碳化處理,同時可避免在作為乾餾容器的蒸餾器使用陶瓷材料之情況下可能產生的生產力及熱衝擊的問題。 The above-mentioned present invention can provide a carbonization furnace that can perform carbonization treatment at a temperature higher than 1,000°C, while avoiding problems of productivity and thermal shock that may occur when ceramic materials are used as a retort vessel as a dry distillation vessel.
1‧‧‧碳化處理設備 1‧‧‧Carbonization processing equipment
10‧‧‧入料斗 10‧‧‧Into the hopper
12‧‧‧中間儲存槽 12‧‧‧Intermediate storage tank
14‧‧‧定量給料機 14‧‧‧Dosing feeder
15‧‧‧輸送機 15‧‧‧Conveyor
16‧‧‧乾燥機 16‧‧‧Dryer
18‧‧‧滾筒 18‧‧‧Drum
20‧‧‧攪拌軸 20‧‧‧Mixing shaft
22‧‧‧攪拌葉片 22‧‧‧Mixing blade
24‧‧‧板形提升器 24‧‧‧Plate Lifter
26‧‧‧輸送機 26‧‧‧Conveyor
28‧‧‧碳化爐 28‧‧‧Carbonization furnace
28B‧‧‧碳化爐 28B‧‧‧Carbonization Furnace
30‧‧‧爐體 30‧‧‧Furnace body
31‧‧‧廢氣處理室 31‧‧‧Exhaust gas treatment room
32‧‧‧第一蒸餾器 32‧‧‧The first still
33‧‧‧噴射管 33‧‧‧Injection tube
34‧‧‧第二蒸餾器 34‧‧‧Second Distiller
34A‧‧‧第二蒸餾器 34A‧‧‧Second Distiller
34B‧‧‧第二蒸餾器 34B‧‧‧Second Distiller
35‧‧‧噴射管 35‧‧‧Injection tube
36‧‧‧出料口 36‧‧‧Discharge port
40‧‧‧熱空氣產生爐 40‧‧‧Hot air generator
42‧‧‧集塵器 42‧‧‧Dust Collector
44‧‧‧循環風扇 44‧‧‧Circulating fan
46‧‧‧碳化爐-廢氣-熱交換器 46‧‧‧Carbonization Furnace-Exhaust Gas-Heat Exchanger
47‧‧‧熱空氣爐-廢氣-熱交換器 47‧‧‧Hot air furnace-exhaust gas-heat exchanger
48‧‧‧分支路徑 48‧‧‧Branch Path
49‧‧‧熱空氣爐-廢氣-風扇 49‧‧‧Hot Air Furnace-Exhaust Gas-Fan
50‧‧‧煙囪 50‧‧‧Chimney
52‧‧‧廢氣路徑 52‧‧‧Exhaust gas path
54‧‧‧碳化爐-廢氣-風扇 54‧‧‧Carbonization Furnace-Exhaust Gas-Fan
56‧‧‧第一溫控區 56‧‧‧The first temperature control zone
57‧‧‧第二溫控區 57‧‧‧Second temperature control zone
58‧‧‧連接口 58‧‧‧Connecting port
60‧‧‧環體 60‧‧‧ring body
61‧‧‧環體 61‧‧‧Ring body
63‧‧‧鏈輪 63‧‧‧Sprocket
64‧‧‧供應設備 64‧‧‧Supply equipment
64a‧‧‧螺旋輸送機 64a‧‧‧Screw conveyor
64b‧‧‧料斗 64b‧‧‧ Hopper
66‧‧‧出口 66‧‧‧Exit
68‧‧‧補充燃燒燃燒器 68‧‧‧Supplementary combustion burner
70‧‧‧空氣引入口 70‧‧‧Air inlet
72‧‧‧空氣供應路徑 72‧‧‧Air supply path
74‧‧‧空氣供應風扇 74‧‧‧Air supply fan
75‧‧‧控制部 75‧‧‧Control Department
76‧‧‧熱電耦 76‧‧‧Thermocouple
77‧‧‧調整閥 77‧‧‧Adjusting valve
80‧‧‧連接容器 80‧‧‧Connecting container
80a‧‧‧圓周壁 80a‧‧‧Circumferential wall
80B‧‧‧連接容器 80B‧‧‧Connecting container
81‧‧‧水平開口 81‧‧‧Horizontal opening
82‧‧‧向下開口 82‧‧‧Open downward
82A‧‧‧向下開口 82A‧‧‧Open downward
82B‧‧‧向下開口 82B‧‧‧Open downward
83‧‧‧旋轉閥 83‧‧‧Rotary valve
85‧‧‧環體 85‧‧‧ring body
86‧‧‧環體 86‧‧‧ring body
87‧‧‧鏈輪 87‧‧‧Sprocket
88‧‧‧供應設備 88‧‧‧Supply equipment
88a‧‧‧螺旋輸送機 88a‧‧‧Screw conveyor
88b‧‧‧料斗 88b‧‧‧ Hopper
88c‧‧‧向上開口 88c‧‧‧Open upward
90‧‧‧補充燃燒燃燒器 90‧‧‧Supplementary combustion burner
92‧‧‧空氣引入口 92‧‧‧Air inlet
93‧‧‧空氣供應路徑 93‧‧‧Air supply path
95‧‧‧控制部 95‧‧‧Control Department
96‧‧‧熱電耦 96‧‧‧Thermocouple
97‧‧‧調整閥 97‧‧‧Adjusting valve
99‧‧‧排氣口 99‧‧‧Exhaust port
100A‧‧‧向上開口 100A‧‧‧Open upward
100B‧‧‧向上開口 100B‧‧‧Open upward
102‧‧‧支撐點 102‧‧‧Support point
104‧‧‧導板(分配手段) 104‧‧‧Guide (distribution means)
圖1係繪示包括本發明之一具體例之碳化爐的碳化處理設備的整體構造之示圖。 FIG. 1 is a diagram showing the overall structure of a carbonization treatment equipment including a carbonization furnace according to a specific example of the present invention.
圖2係繪示圖1中之乾燥機的結構之示圖。 Fig. 2 is a diagram showing the structure of the dryer in Fig. 1.
圖3係繪示圖1中之碳化爐的結構之示圖。 Fig. 3 is a diagram showing the structure of the carbonization furnace in Fig. 1.
圖4係繪示包括圖3中碳化爐之第一溫控區的上半部之示圖。 FIG. 4 is a diagram showing the upper half of the first temperature control zone of the carbonization furnace in FIG. 3.
圖5係繪示包括圖3中碳化爐之第二溫控區的下半部之示圖。 FIG. 5 is a diagram showing the lower half of the second temperature control zone including the carbonization furnace in FIG. 3.
圖6係繪示本發明之另一具體例的主要部分之示圖。 Fig. 6 is a diagram showing the main part of another specific example of the present invention.
下面將參考圖式來詳細描述本發明之具體例。 Specific examples of the present invention will be described in detail below with reference to the drawings.
圖1繪示包括本發明之一具體例之碳化爐的碳化處理設備1的整體構造。在圖中,由元件符號10所表示的構件係入料斗(用於脫水污泥的儲存槽)。含有有機物質的污水污泥被脫水成具有約70至85%(通常是約80%)的含水量,以及所獲得的脫水污泥先收容在入料斗10中。 FIG. 1 shows the overall structure of a
入料斗10中所收容的脫水污泥藉由定量給料機14及輸送機15經由中間儲存槽12輸送至乾燥機16,並且在乾燥機16中經過乾燥處理,以具有約35至45%(通常是約40%)的含水量。 The dewatered sludge contained in the
如圖2所示,乾燥機16在滾筒18內具有攪拌軸20。在此,攪拌軸20係設置在偏離滾筒18之中心的位置處,並且複數個攪拌葉片22以徑向方式從攪拌軸20延伸。 As shown in FIG. 2, the
複數個板形提升器24在與滾筒18一體地旋轉之狀態下以預定間隔沿著圓周方向設置在滾筒18的內圓周上。結果,在滾筒18內所供應的污泥(脫水污泥)隨著滾筒18的旋轉從底部被提升器24向上提起並因其自身重量而在靠近滾筒18之頂部的位置處落下。落下的污泥因位於落下位置下方之攪拌葉片22的高速旋轉而被精細地粉碎並再次落下至滾筒18的底部。 A plurality of plate-shaped
在接受這樣的攪拌動作的同時,使滾筒18內的污泥暴露於被引入內部的熱空氣並乾燥,因而污泥的含水量逐漸地減少。 While receiving such a stirring action, the sludge in the
在乾燥機16中,污泥因滾筒18的傾斜度且另外因攪拌葉片22所進行的粉碎及當時的分散動作而逐漸地朝滾筒18內的軸向輸送。 In the
乾燥機16中乾燥處理之後的乾燥污泥經由輸送機26輸送至碳化爐28,並且在碳化爐28中藉由乾餾處理來進行污泥的碳化。 The dried sludge after the drying process in the
碳化爐28係一種在無氧或低氧環境下(例如,在10%或更少的氧濃度下)使乾燥污泥脫水及熱解之爐。如後面所具體提及,作為乾餾容器的圓筒形蒸餾器32及34係設置在爐體30內。裝進第一蒸餾器32之內部的污泥在第一蒸餾器32內逐漸地移動,接著在第二蒸餾器34內移動,最後,從第二蒸餾器34的出料口36(亦即,從碳化爐28)排放乾餾殘渣(碳化生成物)。這樣的碳化操作可以將乾燥污泥轉變成具有細孔且具有包含約30至50%碳含量且其餘為無機物質之組成物的碳化生成物。 The
在圖1中,由元件符號40所表示之構件係熱空氣產生爐,並且在熱空氣產生爐40中所產生的熱空氣被供應至乾燥機16。 In FIG. 1, the member indicated by the
供應至乾燥機16的熱空氣通過該處並進一步通過集塵器42,然後,藉由循環風扇44,熱空氣經由碳化爐-廢氣-熱交換器46及熱空氣爐-廢氣-熱交換器47循環至熱空氣產生爐40。 The hot air supplied to the
在此循環系統中,熱空氣產生爐40中所產生之熱空氣的一部分經由延伸自熱空氣產生爐40的分支路徑48抽出。藉由熱空氣爐-廢氣-風扇49,抽出的熱空氣經由熱空氣爐-廢氣-熱交換器47從煙囪50釋放至外面。 In this circulation system, a part of the hot air generated in the hot
另一方面,在碳化爐28的爐體30之一側上設置廢氣處理室31。來自碳化爐28的廢氣被引入廢氣處理室31,並且在那裡二次燃燒廢氣中之未燃燒氣體。從廢氣處理室31延伸出廢氣路徑52。 藉由碳化爐-廢氣-風扇54,來自廢氣處理室31的廢氣經由碳化爐-廢氣-熱交換器46及廢氣路徑52從煙囪50釋放至外面。 On the other hand, an exhaust
下面將詳細描述本具體例之碳化爐28。 The
如圖3所示,碳化爐28係一種外部加熱旋轉窯爐,並且包含作為乾餾容器的第一蒸餾器32及第二蒸餾器34。在爐體30內,區分成第一溫控區56及其中溫度控制成高於第一溫控區56之溫度的第二溫控區57。這些溫控區56及57係構造成經由連接口58來相通。 As shown in FIG. 3, the
第一溫控區56係加熱乾燥污泥至約700℃至900℃之溫度的區域。設置成穿過第一溫控區56的第一蒸餾器32係由耐熱鋼構成。 The first
可用於第一蒸餾器32之耐熱鋼的實例包括沃斯田鐵系不鏽鋼、合金鋼等等。 Examples of heat-resistant steel that can be used in the
第一蒸餾器32在其一端部及另一端部處的外圓周上分別具有環體60及61,並且在其一端部處的外圓周上具有鏈輪63。第一蒸餾器32係構造成在環體60及61被未繪示於圖中之滾輪支撐且傳動鏈懸掛在鏈輪63上時旋轉。 The
在第一蒸餾器32的一端側(圖中的左側)上,附接裝備有螺旋輸送機64a及料斗64b之供應設備64。裝載料斗64b的乾燥污泥藉由螺旋輸送機64a裝進第一蒸餾器32的內部。 On one end side (left side in the figure) of the
第一蒸餾器32係稍微朝圖中右側向下傾斜。因而隨著第一蒸餾器32的旋轉,從乾燥機16輸送的乾燥污泥係朝圖中右側輸送並經由在第一蒸餾器32之圖中右端部處所形成之出口66排放至連接容器80。 The
圖4係繪示包括碳化爐28之第一溫控區56的上半部之示圖。由元件符號68所表示之構件係設置在第一溫控區56中的補充燃燒燃燒器。燃料係與燃燒空氣一起供應至補充燃燒燃燒器68並燃燒。藉由補充燃燒燃燒器68的熱量來加熱第一溫控區56的環境。當加熱第一溫控區56的環境時,乾燥污泥中所含的可燃氣體經由第一蒸餾器32上所設置的噴射管33流出至外部加熱室,特別是流出至第一溫控區56,並且可燃氣體被點燃。之後,藉由可燃氣體的燃燒來加熱第一蒸餾器32內的污泥。 FIG. 4 is a diagram showing the upper half of the first
此外,在包圍第一溫控區56的爐體30上,形成有空氣引入口70,用於將燃燒空氣引入外部加熱室,亦即,在爐體30內及第一蒸餾器32外的第一溫控區56。適當地控制欲經由空氣引入口70引入的空氣量及補充燃燒燃燒器68的燃燒,使得第一溫控區56的溫度與預定目標溫度一致。在圖4中,由元件符號76所表示之構件係熱電耦,由元件符號75所表示之構件係控制部,由元件符號77所表示之構件係設置在空氣供應路徑72上之調整閥,以及由元件符號74所表示之構件係空氣供應風扇。 In addition, the
結果,對於被供應至第一蒸餾器32之內部的污泥,其內的水份在第一蒸餾器32的上游側有效地蒸發,並且在污泥移動至第一蒸餾器32的下游側之後,污泥被保持在接近第一溫控區56之環境溫度的溫度並接受乾餾處理。 As a result, for the sludge supplied to the inside of the
如圖3所示,連接容器80設置在第一蒸餾器32之圖中右側上,以便包圍第一蒸餾器32的端部。連接容器80係具有圓周壁80a的圓筒形垂直容器。在圖中右側處之第一蒸餾器32的包括其出口66的端部經由圓周壁80a上部處所形成之水平開口81容 納在連接容器80內。另一方面,向下開口82形成在連接容器80的下端處。從第一蒸餾器32的出口66排放至連接容器80內部的污泥在藉由圓周壁80a的內表面引導的同時因其自身重量而落下,並從下端處所形成之向下開口82向下排放污泥。 As shown in FIG. 3, the connecting
連接容器80係構造成使得開口81的邊緣部分經由耐熱密封布與第一蒸餾器32的外表面滑動接觸,以便不阻礙第一蒸餾器32的旋轉。此外,向下開口82經由旋轉閥83連接至在第二蒸餾器34側所設置之向上開口88c。如此構造的連接容器80可以抑制外部空氣侵入內部,因而可以防止連接容器80中之污泥的溫度因與外部空氣接觸而下降。 The
第二溫控區57係加熱乾燥污泥至約1,000℃至1,200℃之溫度的區域且設置在第一溫控區56下方。設置成穿過第二溫控區57的第二蒸餾器34係由陶瓷材料(在本具體例中是碳化矽)構成。 The second
第二蒸餾器34在其一端部及另一端部處的外圓周上分別具有環體85及86,並且在其另一端部(圖中的左側)處的外圓周上具有鏈輪87。第二蒸餾器34係構造成在環體85及86被未繪示於圖中之滾輪支撐且傳動鏈懸掛在鏈輪87上時旋轉。 The
在第二蒸餾器34的一端側(圖中的右側)處,附接用於供應已通過第一蒸餾器32且已被加熱至一預定溫度的污泥至第二蒸餾器34之供應設備88。 At one end side (right side in the figure) of the
供應設備88裝備有螺旋輸送機88a及料斗88b。如上所提及,料斗88b的向上開口88c經由旋轉閥83連接至連接容器80的向下開口82。在螺旋輸送機88a之排放側的端部插入第二 蒸餾器34的內部。污泥一旦被容納在料斗88b中,則藉由螺旋輸送機88a裝載至第二蒸餾器34的內部。 The
第二蒸餾器34係稍微朝圖中左側向下傾斜。隨著第二蒸餾器34的旋轉,從供應設備88側輸送的乾燥污泥係朝圖中左側輸送並從第二蒸餾器34之圖中左端部處所形成之出料口36排放至外面。 The
圖5係繪示包括碳化爐28之第二溫控區57的下半部之示圖。如同在第一溫控區56的情況,設置有補充燃燒燃燒器90,以及燃料係與燃燒空氣一起供應至補充燃燒燃燒器90並燃燒。 FIG. 5 is a diagram showing the lower half of the second
在包圍第二溫控區57的爐體30上,形成有空氣引入口92,用於將燃燒空氣引入外部加熱室,亦即,在爐體30內及第二蒸餾器34外的第二溫控區57。適當地控制欲經由空氣引入口92引入的空氣量及補充燃燒燃燒器90的燃燒,使得第二溫控區57的溫度與預定目標溫度一致。在圖5中,由元件符號96所表示之構件係熱電耦,由元件符號95所表示之構件係控制部,以及由元件符號97所表示之構件係設置在空氣供應路徑93上之調整閥。 On the
此外,如圖5所示,用於排放已燃燒可燃氣體至廢氣處理室31中之排氣口99設置在包圍第二溫控區57的爐體30上且在第二蒸餾器34的出口側的相鄰位置處。排氣口99係構造成使得在爐體30內的已燃燒可燃氣體藉由碳化爐-廢氣-風扇54的抽吸動作依序輸送至廢氣處理室31(參見圖1)。 In addition, as shown in FIG. 5, an
因此,在本具體例中,第一溫控區56變成可燃氣體流動方向的上游側,而第二溫控區57變成可燃氣體流動方向的下游側。在第一溫控區56中燃燒的高溫氣體經由連接口58被引入第 二溫控區57。在第二溫控區57中,藉由燃燒從第一溫控區56進來的高溫氣體(包含未燃燒氣體成分)及燃燒經由噴射管35流出至第二溫控區57的可燃氣體,進一步提高第二溫控區57的溫度。 Therefore, in this specific example, the first
結果,被供應至該第二蒸餾器34內部的污泥保持在接近第二溫控區57之環境溫度的溫度,亦即,約1,000℃至1,200℃,並且包含在污泥中的氯化物及重金屬熱解並作為乾餾氣體輸送至廢氣系統。氯化物及重金屬令人滿意地從如此形成的碳化材料中移除。此外,此一在超過1,000℃的高溫下之處理可以令人滿意地應用至用於擴大碳化材料之孔面積的碳化材料活化處理。 As a result, the sludge supplied to the inside of the
如上述,本具體例的碳化爐28包含設置在第一溫控區56中的第一蒸餾器32及設置在溫度被控制成高於第一溫控區56之溫度的第二溫控區57中的第二蒸餾器34。並且,每個蒸餾器可以由能夠應付個別處理溫度的材料製成。 As described above, the
第二蒸餾器34可以具有只配置在第二溫控區57中的尺寸,因而相較於只在一個蒸餾器中完成碳化處理的情況,可以實現第二蒸餾器34的小型化。因此,可以改善由陶瓷材料所構成之第二蒸餾器34的生產力。 The
此外,在碳化爐28中,待供應至第二蒸餾器34的污泥事先被加熱至約700℃至900℃。因此,可以使被加熱至約1,000℃至1,200℃的第二蒸餾器34與污泥之間的溫差變小,因而可以減緩由溫差造成的熱衝擊。因此,可以防止由陶瓷材料所構成的第二蒸餾器34因熱衝擊而破裂。 In addition, in the
再者,碳化爐28係構造成使得第二蒸餾器34配置在第一蒸餾器32下方以及被供應至第二蒸餾器34內部的污泥朝與在 第一蒸餾器32中之移動方向相反的方向移動。在兩個蒸餾器32及34配置在上方及下方且污泥的移動路徑設定成近似U形的情況下,可以縮短碳化爐28的長度。此外,可以減少碳化爐28的安裝空間。 Furthermore, the
另外,碳化爐28包含包圍第一蒸餾器32之一端部且在內部容納第一蒸餾器32之出口66的連接容器80。連接容器80具有向下開口82形成於下端處且在第二蒸餾器34的入口側連接至供應設備88的向上開口88c。因此,可以將污泥引導至第二蒸餾器34之入口側處的供應設備88的向上開口88c,同時防止從第一蒸餾器32排放之污泥因與外部空氣接觸而冷卻。 In addition, the
再者,在碳化爐28中,第一溫控區56配置在由污泥產生之可燃氣體之流動方向的上游側,並且第二溫控區57配置在可燃氣體之流動方向的下游側。因此,在第一溫控區56中被加熱至約700℃至900℃的高溫可燃氣體被引入第二溫控區57。因此,可輕易地提高第二溫控區57的溫度。 Furthermore, in the
圖6係繪示本發明之另一具體例的主要部分之示圖。 Fig. 6 is a diagram showing the main part of another specific example of the present invention.
在圖6的碳化爐28B中,兩個第二蒸餾器34A及34B係平行配置在第二溫控區57中。這兩個第二蒸餾器34A及34B配置在與位於上方之第一蒸餾器32之垂直方向上延伸的中心線對稱的位置處。在入口側之向上開口100A及100B向上地形成於個別蒸餾器上。 In the
對應於這些向上開口100A及100B,在內部容納第一蒸餾器32之出口66的連接容器80B的下端處形成有兩個向下開口82A及82B。向下開口82A及82B分別經由旋轉閥83連接至在 第二蒸餾器34A及34B側所設置之向上開口100A及100B。 Corresponding to these
此外,在連接容器80B內設置有構造成繞支撐點102擺動的導板104。導板104係構造成根據未繪示於圖中之驅動馬達的驅動力在圖6以實線所示的第一狀態與以雙點鏈線所示的第二狀態之間進行切換。本具體例之此一結構可以分配欲供應至第二蒸餾器34A及34B之每一者的從第一蒸餾器32所排放之污泥。亦即,導板104構成本發明之分配手段。 In addition, a
如此構造的碳化爐28B可以實現用於高溫處理之第二蒸餾器34A及34B的小型化,同時維持整個碳化爐的處理能力。此外,可以使由陶瓷材料構成之第二蒸餾器34A及34B的生產力更令人滿意。 The
如上述,已詳細描述本發明之具體例,但是它們僅僅是實例。例如,在具體例中,使用污水污泥作為待處理的材料,但是亦可以使用含有碳、生物質等等的其它廢料作為待處理的材料。此外,對於含有陶瓷材料之第二蒸餾器,亦可以使用整體模製的以及藉由組合事先形成之複數個分離體所製成的。再者,一部分第二蒸餾器亦可以由耐熱合金等構成。因此,本發明可以在不脫離其宗旨之情況下以各種變化模式來實施。 As described above, specific examples of the present invention have been described in detail, but they are only examples. For example, in a specific example, sewage sludge is used as the material to be processed, but other waste materials containing carbon, biomass, etc. may also be used as the material to be processed. In addition, for the second distiller containing ceramic material, it is also possible to use an integrally molded one and one made by combining a plurality of separated bodies formed in advance. Furthermore, a part of the second distiller may also be made of heat-resistant alloy or the like. Therefore, the present invention can be implemented in various modified modes without departing from its purpose.
本申請案係基於2018年3月16日所提出之日本專利申請案第2018-049795號,在此以提及方式將其內容併入本文中。 This application is based on Japanese Patent Application No. 2018-049795 filed on March 16, 2018, the content of which is incorporated herein by reference.
28‧‧‧碳化爐 28‧‧‧Carbonization furnace
30‧‧‧爐體 30‧‧‧Furnace body
32‧‧‧第一蒸餾器 32‧‧‧The first still
33‧‧‧噴射管 33‧‧‧Injection tube
34‧‧‧第二蒸餾器 34‧‧‧Second Distiller
35‧‧‧噴射管 35‧‧‧Injection tube
36‧‧‧出料口 36‧‧‧Discharge port
56‧‧‧第一溫控區 56‧‧‧The first temperature control zone
57‧‧‧第二溫控區 57‧‧‧Second temperature control zone
58‧‧‧連接口 58‧‧‧Connecting port
60‧‧‧環體 60‧‧‧ring body
61‧‧‧環體 61‧‧‧Ring body
63‧‧‧鏈輪 63‧‧‧Sprocket
64‧‧‧供應設備 64‧‧‧Supply equipment
64a‧‧‧螺旋輸送機 64a‧‧‧Screw conveyor
64b‧‧‧料斗 64b‧‧‧ Hopper
66‧‧‧出口 66‧‧‧Exit
68‧‧‧補充燃燒燃燒器 68‧‧‧Supplementary combustion burner
80‧‧‧連接容器 80‧‧‧Connecting container
80a‧‧‧圓周壁 80a‧‧‧Circumferential wall
81‧‧‧水平開口 81‧‧‧Horizontal opening
82‧‧‧向下開口 82‧‧‧Open downward
83‧‧‧旋轉閥 83‧‧‧Rotary valve
85‧‧‧環體 85‧‧‧ring body
86‧‧‧環體 86‧‧‧ring body
87‧‧‧鏈輪 87‧‧‧Sprocket
88‧‧‧供應設備 88‧‧‧Supply equipment
88a‧‧‧螺旋輸送機 88a‧‧‧Screw conveyor
88b‧‧‧料斗 88b‧‧‧ Hopper
88c‧‧‧向上開口 88c‧‧‧Open upward
90‧‧‧補充燃燒燃燒器 90‧‧‧Supplementary combustion burner
99‧‧‧排氣口 99‧‧‧Exhaust port
Claims (6)
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JP2018-049795 | 2018-03-16 | ||
JP2018049795A JP7091740B2 (en) | 2018-03-16 | 2018-03-16 | Carbonization furnace |
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TW201940678A TW201940678A (en) | 2019-10-16 |
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KR (1) | KR102188473B1 (en) |
CN (1) | CN110272750A (en) |
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JP7200703B2 (en) * | 2019-01-30 | 2023-01-10 | 大同特殊鋼株式会社 | carbonization furnace |
CN110631347A (en) * | 2019-10-24 | 2019-12-31 | 宁夏恒辉活性炭有限公司 | Drying production system and method for active carbon molding material |
JP2021162168A (en) * | 2020-03-30 | 2021-10-11 | 日鉄エンジニアリング株式会社 | Carbide manufacturing method and carbide manufacturing facility |
CN115213999A (en) * | 2021-04-21 | 2022-10-21 | 买郁珊 | Carbonization template |
CN113604234B (en) * | 2021-07-09 | 2024-02-02 | 华北电力大学 | Multi-chamber organic solid waste pyrolysis reactor and pyrolysis method thereof |
CN113604232B (en) * | 2021-07-09 | 2024-02-02 | 华北电力大学 | Rotary cage type multi-chamber organic solid waste pyrolysis reactor and pyrolysis method thereof |
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JP4393628B2 (en) * | 1999-07-19 | 2010-01-06 | 圭一 熊川 | Multi-stage rotary kiln |
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CN103145307A (en) * | 2013-04-02 | 2013-06-12 | 湖北博实城乡环境能源工程有限公司 | High temperature carbonization system of sludge and carbonization process |
CN206207438U (en) * | 2016-11-30 | 2017-05-31 | 中冶华天南京工程技术有限公司 | The carbonization of sludge two-part plus CIU |
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PH12019000128A1 (en) | 2020-06-29 |
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JP2019157076A (en) | 2019-09-19 |
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