TWI737747B - Semiconductor package and method for manufacturing the same - Google Patents

Semiconductor package and method for manufacturing the same Download PDF

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TWI737747B
TWI737747B TW106119688A TW106119688A TWI737747B TW I737747 B TWI737747 B TW I737747B TW 106119688 A TW106119688 A TW 106119688A TW 106119688 A TW106119688 A TW 106119688A TW I737747 B TWI737747 B TW I737747B
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mask layer
metal particles
semiconductor package
layer
substrate
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TW201810466A (en
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閔丙國
趙成日
崔宰熏
金時經
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南韓商三星電子股份有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/552Protection against radiation, e.g. light or electromagnetic waves
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/31Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/28Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
    • H01L23/31Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape
    • H01L23/3107Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the arrangement or shape the device being completely enclosed
    • H01L23/3135Double encapsulation or coating and encapsulation
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • H05K9/0073Shielding materials
    • H05K9/0081Electromagnetic shielding materials, e.g. EMI, RFI shielding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16151Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/16221Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/16225Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/93Batch processes
    • H01L2224/95Batch processes at chip-level, i.e. with connecting carried out on a plurality of singulated devices, i.e. on diced chips
    • H01L2224/97Batch processes at chip-level, i.e. with connecting carried out on a plurality of singulated devices, i.e. on diced chips the devices being connected to a common substrate, e.g. interposer, said common substrate being separable into individual assemblies after connecting
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/151Die mounting substrate
    • H01L2924/153Connection portion
    • H01L2924/1531Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
    • H01L2924/15311Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/181Encapsulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/181Encapsulation
    • H01L2924/1815Shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/30Technical effects
    • H01L2924/301Electrical effects
    • H01L2924/3025Electromagnetic shielding

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
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Abstract

Embodiments of the inventive concepts provide a semiconductor package and a method for manufacturing the same. The method includes providing a package comprising a substrate, a semiconductor chip, and a molding layer, the substrate comprising a ground pattern exposed at one surface of the substrate; and applying a solution including metal particles and a conductive carbon material onto the molding layer to form a shielding layer. The shielding layer comprises: the metal particles; and the conductive carbon material connected to at least one of the metal particles. The shielding layer extends onto the one surface of the substrate and is electrically connected to the ground pattern.

Description

半導體封裝和用於製造半導體封裝的方法Semiconductor package and method for manufacturing semiconductor package

本揭露的實例實施例涉及半導體封裝和用於製造半導體封裝的方法,且更特定來說,涉及包含遮罩層的半導體封裝和用於製造所述半導體封裝的方法。Example embodiments of the present disclosure relate to semiconductor packages and methods for manufacturing semiconductor packages, and more particularly, to semiconductor packages including mask layers and methods for manufacturing the semiconductor packages.

包含積體電路晶片的半導體封裝可以用於在電子產品中使用積體電路晶片的合適形式呈現。在一般半導體封裝中,半導體晶片可以安裝在印刷電路板(printed circuit board, PCB)上且可以通過接線(bonding wires)或凸塊電性連接到PCB。隨著電子行業的發展,已經開發了高性能、高速和小型電子元件。因此,在半導體封裝與其它電子元件之間可能會發生電磁干擾現象。The semiconductor package containing the integrated circuit chip can be used for the presentation of a suitable form for using the integrated circuit chip in an electronic product. In general semiconductor packaging, the semiconductor chip can be mounted on a printed circuit board (PCB) and can be electrically connected to the PCB through bonding wires or bumps. With the development of the electronics industry, high-performance, high-speed and small electronic components have been developed. Therefore, electromagnetic interference may occur between the semiconductor package and other electronic components.

實例實施例提供一種半導體封裝和一種用於製造半導體封裝的方法。Example embodiments provide a semiconductor package and a method for manufacturing a semiconductor package.

根據實例實施例的一方面,一種用於製造半導體封裝的方法可以包含:提供包含接地圖案的封裝;以及形成安置在封裝的頂部表面和側壁上且電性連接到接地圖案的遮罩層。遮罩層可以包含彼此連接的金屬粒子,和連接到金屬粒子中的至少一個金屬粒子的導電碳材料。金屬粒子可以包含第一粒子和具有大於第一粒子的高寬比的第二粒子。According to an aspect of example embodiments, a method for manufacturing a semiconductor package may include: providing a package including a ground pattern; and forming a mask layer disposed on a top surface and sidewalls of the package and electrically connected to the ground pattern. The mask layer may include metal particles connected to each other, and a conductive carbon material connected to at least one of the metal particles. The metal particles may include first particles and second particles having an aspect ratio greater than that of the first particles.

根據另一實例實施例的另一方面,一種用於製造半導體封裝的方法可以包含:提供包含基底、半導體晶片和模塑層的封裝;以及將包含金屬粒子和導電碳材料的溶液塗覆到模塑層上以形成遮罩層。基底可以包含在基底的一個表面處暴露的接地圖案。遮罩層可以包含金屬粒子和連接到金屬粒子中的至少一個金屬粒子的導電碳材料。遮罩層可以延伸到基底的一個表面上且電性連接到接地圖案。基底的一個表面可以是基底的底部表面和側壁中的一個。According to another aspect of another example embodiment, a method for manufacturing a semiconductor package may include: providing a package including a substrate, a semiconductor wafer, and a mold layer; and applying a solution including metal particles and a conductive carbon material to the mold On the plastic layer to form a mask layer. The substrate may include a ground pattern exposed at one surface of the substrate. The mask layer may include metal particles and a conductive carbon material connected to at least one of the metal particles. The mask layer may extend to a surface of the substrate and be electrically connected to the ground pattern. One surface of the base may be one of the bottom surface and the sidewall of the base.

根據另一實例實施例的另一方面,一種半導體封裝可以包含:包含接地結構的基底,接地結構在基底的一個表面處暴露;基底上的半導體晶片;提供在基底上的模塑層,模塑層覆蓋半導體晶片;以及提供在模塑層和基底的一個表面上的遮罩層。遮罩層可以接觸接地結構。遮罩層可以包含彼此連接的金屬粒子,和連接到金屬粒子中的至少一個金屬粒子的導電碳材料。According to another aspect of another example embodiment, a semiconductor package may include: a substrate including a ground structure, the ground structure being exposed at one surface of the substrate; a semiconductor wafer on the substrate; a molding layer provided on the substrate, and molding The layer covers the semiconductor wafer; and a mask layer is provided on one surface of the mold layer and the substrate. The mask layer can contact the ground structure. The mask layer may include metal particles connected to each other, and a conductive carbon material connected to at least one of the metal particles.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。In order to make the above-mentioned features and advantages of the present invention more comprehensible, the following specific embodiments are described in detail in conjunction with the accompanying drawings.

將在下文中描述根據一些實例實施例的半導體封裝和製造半導體封裝的方法。A semiconductor package and a method of manufacturing a semiconductor package according to some example embodiments will be described hereinafter.

圖1A為說明根據實例實施例的半導體封裝的平面圖。圖1B為沿著圖1A的線I-II截取的剖面圖。FIG. 1A is a plan view illustrating a semiconductor package according to example embodiments. Fig. 1B is a cross-sectional view taken along the line I-II of Fig. 1A.

參考圖1A和1B,半導體封裝1可以包含基底100、半導體晶片200、模塑層300和遮罩層400。基底100可以是印刷電路板(printed circuit board, PCB)、矽基底、重分佈基底或柔性基底。基底100可以包含絕緣層130、接地結構110、111和112、訊號結構120、121和122以及端子131和132。接地結構110、111和112可以包括接地圖案110、上部接地通孔111和下部接地通孔112。訊號結構120、121和122可以包括訊號圖案120、上部訊號通孔121和下部訊號通孔122。端子131和132可以安置在絕緣層130的底部表面上。端子131和132可以包含導電材料且可以具有焊球形狀。端子131和132可以包含接地端子131和訊號端子132。接地端子131可以與訊號端子132絕緣。1A and 1B, the semiconductor package 1 may include a substrate 100, a semiconductor wafer 200, a molding layer 300, and a mask layer 400. The substrate 100 may be a printed circuit board (PCB), a silicon substrate, a redistribution substrate, or a flexible substrate. The substrate 100 may include an insulating layer 130, ground structures 110, 111, and 112, signal structures 120, 121, and 122, and terminals 131 and 132. The ground structures 110, 111, and 112 may include a ground pattern 110, an upper ground via 111, and a lower ground via 112. The signal structures 120, 121 and 122 may include a signal pattern 120, an upper signal via 121 and a lower signal via 122. The terminals 131 and 132 may be disposed on the bottom surface of the insulating layer 130. The terminals 131 and 132 may include a conductive material and may have a solder ball shape. The terminals 131 and 132 may include a ground terminal 131 and a signal terminal 132. The ground terminal 131 may be insulated from the signal terminal 132.

絕緣層130可以包含多個層。接地圖案110可以在絕緣層130中提供。接地圖案110可以包含例如金屬的導電材料。當從平面圖看時,接地圖案110可以安置在基底100的邊緣部分中。接地圖案110可以暴露在基底100的側壁100c處。下部接地通孔112可以在絕緣層130中安置在接地圖案110與接地端子131之間。接地圖案110可以通過下部接地通孔112電性連接到接地端子131。在本說明書中,將理解到當元件被稱作“電性連接”到另一元件時,其可以直接連接到另一元件或可能存在介入元件。上部接地通孔111可以提供在接地圖案110上且可以連接到接地圖案110。上部接地通孔111可能不在垂直方向上與下部接地通孔112對準。此處,垂直方向可以是垂直於基底100的頂部表面的方向。下部接地通孔112、接地圖案110和上部接地通孔111的數目不限於圖1A和1B中所說明的那些數目。The insulating layer 130 may include multiple layers. The ground pattern 110 may be provided in the insulating layer 130. The ground pattern 110 may include a conductive material such as metal. When viewed from a plan view, the ground pattern 110 may be disposed in the edge portion of the substrate 100. The ground pattern 110 may be exposed at the sidewall 100c of the substrate 100. The lower ground via 112 may be disposed between the ground pattern 110 and the ground terminal 131 in the insulating layer 130. The ground pattern 110 may be electrically connected to the ground terminal 131 through the lower ground via 112. In this specification, it will be understood that when an element is referred to as being "electrically connected" to another element, it can be directly connected to the other element or an intervening element may be present. The upper ground via 111 may be provided on the ground pattern 110 and may be connected to the ground pattern 110. The upper ground via 111 may not be aligned with the lower ground via 112 in the vertical direction. Here, the vertical direction may be a direction perpendicular to the top surface of the substrate 100. The numbers of the lower ground via 112, the ground pattern 110, and the upper ground via 111 are not limited to those illustrated in FIGS. 1A and 1B.

當從平面圖看時,訊號圖案120可以安置在基底100的中心部分中。訊號圖案120可以與基底100的側壁100c隔開。訊號圖案120可以包含例如金屬的導電材料。訊號圖案120可以與接地圖案110絕緣。訊號圖案120可以通過下部訊號通孔122電性連接到訊號端子132。When viewed from a plan view, the signal pattern 120 may be disposed in the central portion of the substrate 100. The signal pattern 120 may be separated from the sidewall 100c of the substrate 100. The signal pattern 120 may include a conductive material such as metal. The signal pattern 120 may be insulated from the ground pattern 110. The signal pattern 120 can be electrically connected to the signal terminal 132 through the lower signal through hole 122.

半導體晶片200可以安裝在基底100的頂部表面上。半導體晶片200可以包含安置在其底部表面上的積體電路層250。中介物210和220可以提供在基底100與半導體晶片200之間。中介物210和220可以包含導電材料(例如,金屬),且可以具有焊球形狀、凸塊形狀或支柱形狀。中介物210和220可以包含接地中介物210和訊號中介物220。接地中介物210可以連接到上部接地通孔111。半導體晶片200的積體電路層250可以通過接地中介物210、上部接地通孔111、接地圖案110、下部接地通孔112和接地端子131接地。訊號中介物220可以連接到上部訊號通孔121。當半導體晶片200操作時,產生於積體電路層250的電訊號可以通過訊號中介物220、上部訊號通孔121、訊號圖案120、下部訊號通孔122和訊號端子132傳輸到外部系統。同樣地,外部電訊號可以通過訊號圖案120傳輸到積體電路層250。在某些實施例中,中介物210和220可以包含在基底100的頂部表面上提供的接線,且可以電性連接到基底100。The semiconductor wafer 200 may be mounted on the top surface of the substrate 100. The semiconductor wafer 200 may include an integrated circuit layer 250 disposed on the bottom surface thereof. The interposers 210 and 220 may be provided between the substrate 100 and the semiconductor wafer 200. The interposers 210 and 220 may include a conductive material (for example, metal), and may have a solder ball shape, a bump shape, or a pillar shape. The intermediary objects 210 and 220 may include a grounding intermediary object 210 and a signal intermediary object 220. The ground interposer 210 may be connected to the upper ground via 111. The integrated circuit layer 250 of the semiconductor wafer 200 may be grounded through the ground interposer 210, the upper ground via 111, the ground pattern 110, the lower ground via 112, and the ground terminal 131. The signal intermediary 220 may be connected to the upper signal through hole 121. When the semiconductor chip 200 is in operation, the electrical signals generated on the integrated circuit layer 250 can be transmitted to the external system through the signal intermediary 220, the upper signal via 121, the signal pattern 120, the lower signal via 122 and the signal terminal 132. Similarly, external electrical signals can be transmitted to the integrated circuit layer 250 through the signal pattern 120. In some embodiments, the interposers 210 and 220 may include wiring provided on the top surface of the substrate 100 and may be electrically connected to the substrate 100.

模塑層300可以在基底100上提供且可以覆蓋半導體晶片200。模塑層300可以延伸到基底100與半導體晶片200之間的間隙中。替代地,底膠層可以填充基底100與半導體晶片200之間的間隙。模塑層300可以包含例如環氧模塑化合物(epoxy molding compound, EMC)的絕緣聚合物材料。在一些實施例中,親水性官能團可以提供在模塑層300的頂部表面和側壁上。凹陷350可以提供在模塑層300的頂部表面上。不同於圖1B,凹陷350可以提供在模塑層300的側壁上。The molding layer 300 may be provided on the substrate 100 and may cover the semiconductor wafer 200. The molding layer 300 may extend into the gap between the substrate 100 and the semiconductor wafer 200. Alternatively, the primer layer may fill the gap between the substrate 100 and the semiconductor wafer 200. The molding layer 300 may include an insulating polymer material such as an epoxy molding compound (EMC). In some embodiments, hydrophilic functional groups may be provided on the top surface and sidewalls of the molding layer 300. The recess 350 may be provided on the top surface of the molding layer 300. Unlike FIG. 1B, the recess 350 may be provided on the sidewall of the molding layer 300.

遮罩層400可以提供在模塑層300的頂部表面、模塑層300的側壁和基底100的側壁100c上。遮罩層400可以環繞模塑層300。由於遮罩層400具有導電性,因此遮罩層400可以阻斷電磁干擾(electromagnetic interference, EMI)。電磁干擾(electromagnetic interference, EMI)意指從電子元件輻射或傳輸的電磁波會干擾另一電子元件的訊號接收/傳輸。根據一些實施例,由於半導體封裝1包含遮罩層400,因此半導體封裝1可能不會干擾另一電子裝置(例如,傳輸器或接收器)的操作。遮罩層400可以吸收從半導體晶片200的積體電路層250、中介物210和220或基底100產生的電磁波600。接地圖案110可以在基底100的側壁100c處暴露,且因此遮罩層400可以電性連接到接地圖案110。遮罩層400中所吸收的電磁波600可以通過接地圖案110和接地端子131傳輸到半導體封裝1的外部,如圖1B中的箭頭所說明。訊號圖案120可能不在基底100的側壁100c處暴露,且因此遮罩層400可能並不電性連接到訊號圖案120。在下文中,將更詳細地描述遮罩層400。The mask layer 400 may be provided on the top surface of the molding layer 300, the sidewalls of the molding layer 300, and the sidewalls 100c of the substrate 100. The mask layer 400 may surround the molding layer 300. Since the mask layer 400 has conductivity, the mask layer 400 can block electromagnetic interference (EMI). Electromagnetic interference (EMI) means that electromagnetic waves radiated or transmitted from an electronic component will interfere with the signal reception/transmission of another electronic component. According to some embodiments, since the semiconductor package 1 includes the mask layer 400, the semiconductor package 1 may not interfere with the operation of another electronic device (for example, a transmitter or a receiver). The mask layer 400 may absorb electromagnetic waves 600 generated from the integrated circuit layer 250 of the semiconductor wafer 200, the interposers 210 and 220, or the substrate 100. The ground pattern 110 may be exposed at the sidewall 100c of the substrate 100, and thus the mask layer 400 may be electrically connected to the ground pattern 110. The electromagnetic wave 600 absorbed in the mask layer 400 may be transmitted to the outside of the semiconductor package 1 through the ground pattern 110 and the ground terminal 131, as illustrated by the arrow in FIG. 1B. The signal pattern 120 may not be exposed at the sidewall 100c of the substrate 100, and therefore the mask layer 400 may not be electrically connected to the signal pattern 120. Hereinafter, the mask layer 400 will be described in more detail.

圖1C為圖1B的區域III的放大圖。FIG. 1C is an enlarged view of area III of FIG. 1B.

參考圖1B和1C,遮罩層400可以包含金屬粒子410、導電碳材料420和聚合物430。遮罩層400可以通過其中包含的金屬粒子410和導電碳材料420而具有導電性。在一些實施例中,金屬粒子410可以包含銀(Ag)。在某些實施例中,金屬粒子410可以包含金(Au)、銅(Cu)、鎳(Ni)、鐵(Fe)、鋁(Al)或其任何組合。當金屬粒子410彼此隔開時,電子可能在金屬粒子410之間緩慢移動,或可能難以在金屬粒子410之間移動。根據一些實施例,金屬粒子410可以結團聚集在一起(agglomerate together)以便彼此物理連接。因此,電子可以在金屬粒子410之間快速移動。結果,可以降低遮罩層400的電阻。由於遮罩層400的電阻降低,因此遮罩層400中所吸收的電磁波可以快速地傳輸到半導體封裝1的外部。為容易且便利地進行解釋和說明,在圖1B和1C中在金屬粒子410之間說明了介面表面。然而,本發明概念的實施例並不限於此。在某些實施例中,不同於圖1B和1C,金屬粒子410可能彼此連接,且因此可能並不區別或示出金屬粒子410之間的介面表面。金屬粒子410在遮罩層400中的含量可以介於40 wt%到60 wt%的範圍內。如果金屬粒子410在遮罩層400中的含量低於40 wt%,則遮罩層400可能不能充分防止半導體封裝1的電磁干擾。如果金屬粒子410在遮罩層400中的含量高於60 wt%,則遮罩層400的重量或製造成本可能增加。1B and 1C, the mask layer 400 may include metal particles 410, a conductive carbon material 420, and a polymer 430. The mask layer 400 may have conductivity by the metal particles 410 and the conductive carbon material 420 contained therein. In some embodiments, the metal particles 410 may include silver (Ag). In some embodiments, the metal particles 410 may include gold (Au), copper (Cu), nickel (Ni), iron (Fe), aluminum (Al), or any combination thereof. When the metal particles 410 are separated from each other, electrons may move slowly between the metal particles 410, or it may be difficult to move between the metal particles 410. According to some embodiments, the metal particles 410 may be agglomerated together so as to be physically connected to each other. Therefore, electrons can quickly move between the metal particles 410. As a result, the resistance of the mask layer 400 can be reduced. Since the resistance of the mask layer 400 is reduced, electromagnetic waves absorbed in the mask layer 400 can be quickly transmitted to the outside of the semiconductor package 1. For easy and convenient explanation and description, the interface surface between the metal particles 410 is illustrated in FIGS. 1B and 1C. However, the embodiment of the inventive concept is not limited thereto. In some embodiments, unlike FIGS. 1B and 1C, the metal particles 410 may be connected to each other, and therefore, the interface surface between the metal particles 410 may not be distinguished or shown. The content of the metal particles 410 in the mask layer 400 may be in the range of 40 wt% to 60 wt%. If the content of the metal particles 410 in the mask layer 400 is less than 40 wt %, the mask layer 400 may not sufficiently prevent electromagnetic interference of the semiconductor package 1. If the content of the metal particles 410 in the mask layer 400 is higher than 60 wt%, the weight or manufacturing cost of the mask layer 400 may increase.

導電碳材料420可以物理地連接到金屬粒子410並電性連接到所述金屬粒子。即使金屬粒子410彼此隔開,金屬粒子410仍可以通過導電碳材料420彼此電性連接。由於導電碳材料420的電導率低於金屬粒子410的電導率,因此遮罩層400的電阻可以因導電碳材料420而進一步降低。導電碳材料420可以共價鍵結到金屬粒子410。導電碳材料420與金屬粒子410之間的電阻可以因共價鍵進一步降低。結果,遮罩層400的電阻可以進一步降低。導電碳材料420在遮罩層400中的含量可以是0.5 wt%或更多,且更特定來說,在遮罩層400中的含量可以介於0.5 wt%到3 wt%的範圍內。如果導電碳材料420在遮罩層400中的含量低於0.5 wt%,則遮罩層400的電阻可能增加。如果導電碳材料420在遮罩層400中的含量高於3 wt%,則金屬粒子410在遮罩層400中的含量可能減少。The conductive carbon material 420 may be physically connected to the metal particles 410 and electrically connected to the metal particles. Even if the metal particles 410 are separated from each other, the metal particles 410 can still be electrically connected to each other through the conductive carbon material 420. Since the conductivity of the conductive carbon material 420 is lower than that of the metal particles 410, the resistance of the mask layer 400 can be further reduced by the conductive carbon material 420. The conductive carbon material 420 may be covalently bonded to the metal particles 410. The electrical resistance between the conductive carbon material 420 and the metal particles 410 can be further reduced due to the covalent bond. As a result, the resistance of the mask layer 400 can be further reduced. The content of the conductive carbon material 420 in the mask layer 400 may be 0.5 wt% or more, and more specifically, the content in the mask layer 400 may be in the range of 0.5 wt% to 3 wt%. If the content of the conductive carbon material 420 in the mask layer 400 is less than 0.5 wt%, the resistance of the mask layer 400 may increase. If the content of the conductive carbon material 420 in the mask layer 400 is higher than 3 wt %, the content of the metal particles 410 in the mask layer 400 may decrease.

彼此共價鍵結的導電碳材料420與金屬粒子410之間的相互作用的強度可能大於彼此接觸但並無共價鍵的導電碳材料420與金屬粒子410之間的相互作用的強度。在導電碳材料420與金屬粒子410之間的相互作用的強度(例如,鍵結強度)增加時,導電碳材料420與外部材料之間的親和力和金屬粒子410與外部材料之間的親和力可能降低。舉例來說,外部材料可以是親水性材料,且遮罩層400可以具有疏水性性質。遮罩層400可以具有80度到110度的接觸角。特定來說,遮罩層400可以具有90度到110度的接觸角。因此,遮罩層400可能不被外部材料污染。The strength of the interaction between the conductive carbon material 420 and the metal particles 410 that are covalently bonded to each other may be greater than the strength of the interaction between the conductive carbon material 420 and the metal particles 410 that are in contact with each other but are not covalently bonded. When the strength of the interaction (for example, bonding strength) between the conductive carbon material 420 and the metal particles 410 increases, the affinity between the conductive carbon material 420 and the external material and the affinity between the metal particles 410 and the external material may decrease . For example, the external material may be a hydrophilic material, and the mask layer 400 may have hydrophobic properties. The mask layer 400 may have a contact angle of 80 degrees to 110 degrees. Specifically, the mask layer 400 may have a contact angle of 90 degrees to 110 degrees. Therefore, the mask layer 400 may not be contaminated by external materials.

導電碳材料420可能具有高導熱性。導電碳材料420的導熱性可能高於模塑層300和金屬粒子410的導熱性。舉例來說,導電碳材料420可能具有約3000 W/mK的導熱性。金屬粒子410可能具有約350 W/mK到約500 W/mK的導熱性。模塑層300可能具有約0.88 W/mK的導熱性。由於遮罩層400包含導電碳材料420,因此當半導體封裝1操作時,半導體晶片200所產生的熱量可以快速釋放到半導體封裝1的外部。如果導電碳材料420在遮罩層400中的含量低於0.5 wt%,則半導體晶片200的熱量可能更緩慢地釋放到半導體封裝1的外部。在此狀況下,半導體晶片200的操作可靠性可能退化。在一些實施例中,導電碳材料420可以包含碳奈米管(例如,多層碳奈米管)。在某些實施例中,導電碳材料420可以包含石墨、碳黑或碳纖維。The conductive carbon material 420 may have high thermal conductivity. The thermal conductivity of the conductive carbon material 420 may be higher than the thermal conductivity of the molding layer 300 and the metal particles 410. For example, the conductive carbon material 420 may have a thermal conductivity of about 3000 W/mK. The metal particles 410 may have a thermal conductivity of about 350 W/mK to about 500 W/mK. The molding layer 300 may have a thermal conductivity of about 0.88 W/mK. Since the mask layer 400 includes the conductive carbon material 420, the heat generated by the semiconductor wafer 200 can be quickly released to the outside of the semiconductor package 1 when the semiconductor package 1 is operated. If the content of the conductive carbon material 420 in the mask layer 400 is less than 0.5 wt %, the heat of the semiconductor wafer 200 may be released to the outside of the semiconductor package 1 more slowly. In this situation, the operational reliability of the semiconductor wafer 200 may be degraded. In some embodiments, the conductive carbon material 420 may include carbon nanotubes (eg, multilayer carbon nanotubes). In some embodiments, the conductive carbon material 420 may include graphite, carbon black, or carbon fiber.

聚合物430可以包含親水性聚合物。舉例來說,聚合物430可以包含環氧基聚合物或聚氨基甲酸酯中的至少一種。然而,實施例並不限於此。在某些實施例中,聚合物430可以包含其它各種親水性聚合物中的至少一種。聚合物430可以在導電碳材料420與金屬粒子410之間的間隙中提供。聚合物430可以充當黏結劑(binder)。舉例來說,金屬粒子410和導電碳材料420可以由聚合物430黏附到模塑層300。親水性官能團可以提供在模塑層300上,且因此聚合物430與模塑層300之間的鍵結強度可以得到進一步的增加。因此,遮罩層400可以更堅固地黏附到模塑層300。The polymer 430 may include a hydrophilic polymer. For example, the polymer 430 may include at least one of epoxy-based polymer or polyurethane. However, the embodiment is not limited to this. In certain embodiments, the polymer 430 may include at least one of various other hydrophilic polymers. The polymer 430 may be provided in the gap between the conductive carbon material 420 and the metal particles 410. The polymer 430 may act as a binder. For example, the metal particles 410 and the conductive carbon material 420 may be adhered to the molding layer 300 by the polymer 430. The hydrophilic functional group may be provided on the molding layer 300, and thus the bonding strength between the polymer 430 and the molding layer 300 may be further increased. Therefore, the mask layer 400 can be adhered to the molding layer 300 more firmly.

如圖1B中所說明,標記450可以提供在半導體封裝1上。標記450可以是遮罩層400的一部分,其提供在模塑層300的凹陷350上。在下文中,將更詳細地描述半導體封裝1的標記450。As illustrated in FIG. 1B, the mark 450 may be provided on the semiconductor package 1. The mark 450 may be a part of the mask layer 400 which is provided on the recess 350 of the molding layer 300. Hereinafter, the marking 450 of the semiconductor package 1 will be described in more detail.

圖1D為說明根據實例實施例的遮罩層的頂部表面的放大平面圖。圖1E為圖1B的區域IV的放大剖面圖,且對應於沿著圖1D的線V-VI截取的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到對如上文所提到的相同技術特徵的描述。FIG. 1D is an enlarged plan view illustrating the top surface of the mask layer according to example embodiments. FIG. 1E is an enlarged cross-sectional view of the area IV of FIG. 1B, and corresponds to the cross-sectional view taken along the line V-VI of FIG. 1D. In the following, for easy and convenient explanation, the description of the same technical features as mentioned above will be omitted or briefly mentioned.

參考圖1B、1D和1E,凹陷350可以在模塑層300的頂部表面300a上提供。凹陷350可以具有傾斜側壁350a。傾斜側壁350a可以相對於模塑層300的頂部表面300a傾斜。術語“傾斜”可以取決於元件的兩端之間的平均坡度而確定。在圖1D和1E中,模塑層300的頂部表面300a被界定為模塑層300的(凹陷350非形成於其中的)部分的頂部表面。凹陷350可以具有V形橫截面。舉例來說,凹陷350的傾斜側壁350a可以彼此相接。替代地,在某些實施例中,凹陷350可以具有U形橫截面。凹陷350的深度D1可以是20μm或更多。特定來說,凹陷350的深度D1可以是25μm或更多。在本說明書中,凹陷350的深度D1可以意指從模塑層300的頂部表面300a到凹陷350的底端的垂直深度。凹陷350的深度D1可以小於模塑層300的頂部表面300a與半導體晶片200之間的距離,且因此半導體晶片200可能並未暴露。Referring to FIGS. 1B, 1D, and 1E, a recess 350 may be provided on the top surface 300a of the molding layer 300. The recess 350 may have an inclined sidewall 350a. The inclined sidewall 350a may be inclined with respect to the top surface 300a of the molding layer 300. The term "tilt" may be determined depending on the average slope between the two ends of the element. In FIGS. 1D and 1E, the top surface 300a of the molding layer 300 is defined as the top surface of the portion of the molding layer 300 (in which the recess 350 is not formed). The recess 350 may have a V-shaped cross section. For example, the inclined sidewalls 350a of the recess 350 may meet each other. Alternatively, in some embodiments, the recess 350 may have a U-shaped cross-section. The depth D1 of the recess 350 may be 20 μm or more. Specifically, the depth D1 of the recess 350 may be 25 μm or more. In this specification, the depth D1 of the recess 350 may mean the vertical depth from the top surface 300 a of the molding layer 300 to the bottom end of the recess 350. The depth D1 of the recess 350 may be smaller than the distance between the top surface 300a of the molding layer 300 and the semiconductor wafer 200, and therefore the semiconductor wafer 200 may not be exposed.

遮罩層400可以提供在模塑層300上且可以延伸到凹陷350中。遮罩層400可以共形地覆蓋凹陷350的傾斜側壁350a和模塑層300的頂部表面300a,從而使得遮罩層400的頂部表面在遮罩層400覆蓋凹陷350處凹陷。遮罩層400可以包含第一部分401和第二部分402。第一部分401可以提供在模塑層300的在凹陷350外部的頂部表面300a上。第二部分402可以提供在凹陷350上。第二部分402可以從第一部分401延伸。第二部分402的材料可以相同於第一部分401的材料。遮罩層400的第一部分401的構成比可以大體上相同於遮罩層400的第二部分402的構成比。術語“大體上相等”可以包含在過程期間可能發生的容限。遮罩層400的第一部分401和第二部分402可以分別具有第一頂部表面401a和第二頂部表面402a。遮罩層400的第二部分402可以具有對應於凹陷350的橫截面的橫截面。在一些實施例中,遮罩層400的第二部分402可以具有V形橫截面。替代地,在某些實施例中,遮罩層400的第二部分402可以具有U形橫截面。The mask layer 400 may be provided on the molding layer 300 and may extend into the recess 350. The mask layer 400 may conformally cover the inclined sidewalls 350 a of the recess 350 and the top surface 300 a of the molding layer 300, so that the top surface of the mask layer 400 is recessed where the mask layer 400 covers the recess 350. The mask layer 400 may include a first part 401 and a second part 402. The first part 401 may be provided on the top surface 300 a of the molding layer 300 outside the recess 350. The second part 402 may be provided on the recess 350. The second part 402 may extend from the first part 401. The material of the second part 402 may be the same as the material of the first part 401. The composition ratio of the first part 401 of the mask layer 400 may be substantially the same as the composition ratio of the second part 402 of the mask layer 400. The term "substantially equal" can encompass tolerances that may occur during the process. The first portion 401 and the second portion 402 of the mask layer 400 may have a first top surface 401a and a second top surface 402a, respectively. The second portion 402 of the mask layer 400 may have a cross section corresponding to the cross section of the recess 350. In some embodiments, the second portion 402 of the mask layer 400 may have a V-shaped cross section. Alternatively, in some embodiments, the second portion 402 of the mask layer 400 may have a U-shaped cross-section.

遮罩層400的第二頂部表面402a可以相對於遮罩層400的第一頂部表面401a傾斜。遮罩層400的第二頂部表面402a與第一頂部表面401a之間的角度θ1可以介於約130度到約160度的範圍內。The second top surface 402 a of the mask layer 400 may be inclined with respect to the first top surface 401 a of the mask layer 400. The angle θ1 between the second top surface 402a of the mask layer 400 and the first top surface 401a may be in the range of about 130 degrees to about 160 degrees.

由於遮罩層400的第二頂部表面402a相對於遮罩層400的第一頂部表面401a傾斜,因此當光在相同方向上入射於第一頂部表面401a和第二頂部表面402a上時,從遮罩層400的第二部分402反射的光的反射角度可能不同於從遮罩層400的第一部分401反射的光的反射角度。結果,從遮罩層400的第二部分402反射的光的強度可能不同於從遮罩層400的第一部分401反射的光的強度。舉例來說,從遮罩層400的第一部分401反射的光的強度可能弱於從遮罩層400的第二部分402反射的光的強度。此處,光的強度可以意指單位時間期間每單位面積所接收光的量,且可以是垂直于光行進方向所測量的值。在第一部分401的反射光與第二部分402的反射光之間的強度差異增加時,遮罩層400的第一部分401與第二部分402之間的亮度(brightness)差異可能增加。當凹陷350的深度D1為20μm或更多(特定來說,25μm或更多)且第一頂部表面401a與第二頂部表面402a之間的角度θ1介於130度到160度的範圍時,從第一部分401反射的光的強度可能完全不同於從第二部分402反射的光的強度。因此,遮罩層400的第二部分402的亮度可以清晰地區別於遮罩層400的第一部分401的亮度。換句話說,遮罩層400的第二部分402可以通過第一部分401與第二部分402之間的亮度差異而具有可視性。舉例來說,遮罩層400的第一部分401可能具有爐灰色,而遮罩層400的第二部分402可能具有黑色。因此,遮罩層400的第二部分402可以充當標記450,且標記450可以具有可視性。在本說明書中,可視性可以意指顏色的可視性,且顏色可以包含色相(hue)或亮度。標記450的平面形狀可能並不限於圖1D中所說明的形狀而是可以不同地修改。不同於圖1B,凹陷350和標記450可以提供在模塑層300的側壁上。Since the second top surface 402a of the mask layer 400 is inclined with respect to the first top surface 401a of the mask layer 400, when light is incident on the first top surface 401a and the second top surface 402a in the same direction, the The reflection angle of the light reflected by the second portion 402 of the mask layer 400 may be different from the reflection angle of the light reflected from the first portion 401 of the mask layer 400. As a result, the intensity of light reflected from the second portion 402 of the mask layer 400 may be different from the intensity of light reflected from the first portion 401 of the mask layer 400. For example, the intensity of light reflected from the first portion 401 of the mask layer 400 may be weaker than the intensity of light reflected from the second portion 402 of the mask layer 400. Here, the intensity of light may mean the amount of light received per unit area during a unit time, and may be a value measured perpendicular to the traveling direction of light. When the difference in intensity between the reflected light of the first portion 401 and the reflected light of the second portion 402 increases, the difference in brightness between the first portion 401 and the second portion 402 of the mask layer 400 may increase. When the depth D1 of the recess 350 is 20 μm or more (specifically, 25 μm or more) and the angle θ1 between the first top surface 401a and the second top surface 402a is in the range of 130 degrees to 160 degrees, from The intensity of the light reflected from the first part 401 may be completely different from the intensity of the light reflected from the second part 402. Therefore, the brightness of the second portion 402 of the mask layer 400 can be clearly distinguished from the brightness of the first portion 401 of the mask layer 400. In other words, the second part 402 of the mask layer 400 may have visibility through the difference in brightness between the first part 401 and the second part 402. For example, the first portion 401 of the mask layer 400 may have a furnace gray color, and the second portion 402 of the mask layer 400 may have a black color. Therefore, the second portion 402 of the mask layer 400 may serve as the mark 450, and the mark 450 may have visibility. In this specification, visibility may mean the visibility of colors, and colors may include hue or brightness. The planar shape of the mark 450 may not be limited to the shape illustrated in FIG. 1D but may be variously modified. Unlike FIG. 1B, the recess 350 and the mark 450 may be provided on the sidewall of the molding layer 300.

圖2A到2C為說明用於製造根據實例實施例的半導體封裝的方法的剖面圖。圖2D為圖2C的區域III'的放大圖。在下文中,為容易且便利地解釋,將省略或簡單提到對如上文所提到的相同技術特徵的描述。2A to 2C are cross-sectional views illustrating a method for manufacturing a semiconductor package according to example embodiments. FIG. 2D is an enlarged view of area III' of FIG. 2C. In the following, for easy and convenient explanation, the description of the same technical features as mentioned above will be omitted or briefly mentioned.

參考圖2A,半導體晶片200可以安裝在封裝基底101上。封裝基底101可以是晶圓級基底。可以提供多個半導體晶片200在封裝基底101上。模塑圖案301可以形成在封裝基底101上以覆蓋半導體晶片200。雷射可以照射到模塑圖案301上以形成凹陷350。雷射可以是紅外線雷射。凹陷350的深度可以是20μm或更多。多個凹陷350可以形成在模塑圖案301中。端子131和132可以形成在封裝基底101的底部表面上。此後,可以沿著圖2A中所說明的交替長虛線和短虛線鋸割模塑圖案301和封裝基底101,借此形成多個單位封裝10。封裝基底101可以通過鋸割過程劃分成基底100,且模塑圖案301可以通過鋸割過程劃分成模塑層300。單位封裝10可以包含基底100、半導體晶片200和模塑層300。在下文中,將詳細地描述在單位封裝10中的每一個上執行的過程。Referring to FIG. 2A, the semiconductor wafer 200 may be mounted on the packaging substrate 101. The packaging substrate 101 may be a wafer-level substrate. A plurality of semiconductor chips 200 may be provided on the packaging substrate 101. The molding pattern 301 may be formed on the package substrate 101 to cover the semiconductor wafer 200. The laser may be irradiated onto the molded pattern 301 to form the depression 350. The laser may be an infrared laser. The depth of the recess 350 may be 20 μm or more. A plurality of recesses 350 may be formed in the molding pattern 301. The terminals 131 and 132 may be formed on the bottom surface of the package substrate 101. Thereafter, the molding pattern 301 and the package substrate 101 can be sawed along the alternate long and short dashed lines illustrated in FIG. 2A, thereby forming a plurality of unit packages 10. The packaging substrate 101 may be divided into the substrate 100 through a sawing process, and the molding pattern 301 may be divided into the molding layer 300 through the sawing process. The unit package 10 may include a substrate 100, a semiconductor wafer 200 and a molding layer 300. Hereinafter, the process performed on each of the unit packages 10 will be described in detail.

參考圖2B,模塑層300的頂部表面和側壁可以用電漿處理。可以使用氧氣電漿和/或氬氣電漿來執行電漿處理過程。因此,親水性官能團可以形成在模塑層300的頂部表面和側壁上。舉例來說,親水性官能團可以包含羥基(-OH)。電漿處理過程可以進一步執行在基底100的側壁100c上。在一些實施例中,模塑層300的頂部表面和側壁的表面粗糙度可以經由電漿處理過程增加。Referring to FIG. 2B, the top surface and sidewalls of the molding layer 300 may be treated with plasma. The plasma treatment process can be performed using oxygen plasma and/or argon plasma. Therefore, hydrophilic functional groups may be formed on the top surface and sidewalls of the molding layer 300. For example, the hydrophilic functional group may include a hydroxyl group (-OH). The plasma treatment process may be further performed on the sidewall 100c of the substrate 100. In some embodiments, the surface roughness of the top surface and sidewalls of the molding layer 300 may be increased through a plasma treatment process.

參考圖2C和2D,塗佈溶液可以被塗覆到模塑層300的頂部表面、模塑層300的側壁和基底100的側壁100c以形成初步遮罩層400P。初步遮罩層400P可以與基底100的接地圖案110物理接觸。初步遮罩層400P可以延伸到凹陷350上。塗佈溶液可以包含金屬粒子410、導電碳材料420、聚合物430和溶劑。金屬粒子410、導電碳材料420和聚合物430的種類可以相同於參考圖1A和1B的相關描述。金屬粒子410可以具有約50nm的平均直徑。聚合物430可以是親水性聚合物。導電碳材料420可以具有親水性性質。溶劑可以包含丙二醇甲醚乙酸酯(PGMEA)、水和乙醇中的至少一種。溶劑可以具有親水性性質。因此,導電碳材料420可以均勻地分散在溶劑中。塗佈溶液可以由噴塗法塗覆到模塑層300上。2C and 2D, a coating solution may be applied to the top surface of the molding layer 300, the sidewalls of the molding layer 300, and the sidewall 100c of the substrate 100 to form a preliminary mask layer 400P. The preliminary mask layer 400P may be in physical contact with the ground pattern 110 of the substrate 100. The preliminary mask layer 400P may extend to the recess 350. The coating solution may include metal particles 410, conductive carbon material 420, polymer 430, and a solvent. The types of the metal particles 410, the conductive carbon material 420, and the polymer 430 may be the same as the related descriptions with reference to FIGS. 1A and 1B. The metal particles 410 may have an average diameter of about 50 nm. The polymer 430 may be a hydrophilic polymer. The conductive carbon material 420 may have hydrophilic properties. The solvent may include at least one of propylene glycol methyl ether acetate (PGMEA), water, and ethanol. The solvent may have hydrophilic properties. Therefore, the conductive carbon material 420 can be uniformly dispersed in the solvent. The coating solution may be applied to the molding layer 300 by a spraying method.

初步遮罩層400P可以包含相同于塗佈溶液的材料。如圖2D中所說明,導電碳材料420可能並不鍵結到金屬粒子410。金屬粒子410可能並不彼此物理接觸。由於塗佈溶液具有親水性質,因此初步遮罩層400P可以具有親水性質。初步遮罩層400P可以與由圖2B的電漿處理過程形成在模塑層300上的親水性官能團相互作用。因此,初步遮罩層400P可以良好地黏附到模塑層300。The preliminary mask layer 400P may include the same material as the coating solution. As illustrated in FIG. 2D, the conductive carbon material 420 may not be bonded to the metal particles 410. The metal particles 410 may not be in physical contact with each other. Since the coating solution has hydrophilic properties, the preliminary mask layer 400P may have hydrophilic properties. The preliminary mask layer 400P may interact with the hydrophilic functional groups formed on the molding layer 300 by the plasma treatment process of FIG. 2B. Therefore, the preliminary mask layer 400P can adhere to the molding layer 300 well.

初步遮罩層400P(例如,初步遮罩層400P的聚合物)可以被硬化。初步遮罩層400P可以在90攝氏度到190攝氏度的條件下硬化。溶劑可以在硬化初步遮罩層400P的過程中揮發。The preliminary mask layer 400P (for example, the polymer of the preliminary mask layer 400P) may be hardened. The preliminary mask layer 400P can be cured at 90 degrees Celsius to 190 degrees Celsius. The solvent may volatilize during the hardening of the preliminary mask layer 400P.

參考圖1B和1C,初步遮罩層400P可以經熱處理以形成遮罩層400。初步遮罩層400P的熱處理過程可以在約150攝氏度或更多(例如,150攝氏度到300攝氏度的溫度)下執行。在一些實施例中,初步遮罩層400P的熱處理過程可以由使用紅外線加熱器的紅外線回焊過程(infrared reflow process)執行。在某些實施例中,可以使用電漿或高溫氮氣來熱處理初步遮罩層400P。在某些實施例中,可以在真空下使用鹵素光燈來熱處理初步遮罩層400P。1B and 1C, the preliminary mask layer 400P may be heat-treated to form the mask layer 400. The heat treatment process of the preliminary mask layer 400P may be performed at about 150 degrees Celsius or more (for example, a temperature of 150 degrees Celsius to 300 degrees Celsius). In some embodiments, the heat treatment process of the preliminary mask layer 400P may be performed by an infrared reflow process using an infrared heater. In some embodiments, plasma or high temperature nitrogen may be used to heat treat the preliminary mask layer 400P. In some embodiments, a halogen light lamp may be used to heat treat the preliminary mask layer 400P under vacuum.

金屬粒子410可以由熱處理過程結團聚集在一起以便彼此物理連接。導電碳材料420可以鍵結(例如,共價鍵結)到金屬粒子410。因此,遮罩層400的電阻可能降低。如果初步遮罩層400P是在低於150攝氏度的溫度下經熱處理,則金屬粒子410可能並不彼此充分連接或導電碳材料420可能並不鍵結到金屬粒子410。如果初步遮罩層400P是在高於300攝氏度的溫度下經熱處理,則模塑層300可能受損。The metal particles 410 may be agglomerated together by the heat treatment process so as to be physically connected to each other. The conductive carbon material 420 may be bonded (for example, covalently bonded) to the metal particles 410. Therefore, the resistance of the mask layer 400 may decrease. If the preliminary mask layer 400P is heat-treated at a temperature lower than 150 degrees Celsius, the metal particles 410 may not be sufficiently connected to each other or the conductive carbon material 420 may not be bonded to the metal particles 410. If the preliminary mask layer 400P is heat-treated at a temperature higher than 300 degrees Celsius, the molding layer 300 may be damaged.

由於導電碳材料420共價鍵結到遮罩層400中的金屬粒子410,因此相比於圖2D的初步遮罩層400P,遮罩層400可能具有疏水性性質。水相對於遮罩層400的接觸角可能大於水相對於初步遮罩層400P的接觸角。舉例來說,水相對於遮罩層400的接觸角可能大於90度,水相對於初步遮罩層400P的接觸角可能小於90度。Since the conductive carbon material 420 is covalently bonded to the metal particles 410 in the mask layer 400, the mask layer 400 may have hydrophobic properties compared to the preliminary mask layer 400P of FIG. 2D. The contact angle of water with respect to the mask layer 400 may be greater than the contact angle of water with respect to the preliminary mask layer 400P. For example, the contact angle of water relative to the mask layer 400 may be greater than 90 degrees, and the contact angle of water relative to the preliminary mask layer 400P may be less than 90 degrees.

如參考圖1D和1E所描述,遮罩層400的第一頂部表面401a與第二頂部表面402a之間的角度θ1可以介於約130度到約160度的範圍內。因此,具有可視性的標記450可以形成在半導體封裝1上而無需額外塗漆過程。As described with reference to FIGS. 1D and 1E, the angle θ1 between the first top surface 401a and the second top surface 402a of the mask layer 400 may range from about 130 degrees to about 160 degrees. Therefore, the mark 450 with visibility can be formed on the semiconductor package 1 without an additional painting process.

圖3A為用以說明根據實例實施例的半導體封裝的對應於圖1A的線I-II的剖面圖。圖3B和3C為用以說明用於形成根據實例實施例的半導體封裝的標記的方法的對應於圖3A的區域IV'的放大剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到對如上文所提到的相同技術特徵的描述。FIG. 3A is a cross-sectional view corresponding to the line I-II of FIG. 1A for explaining a semiconductor package according to example embodiments. 3B and 3C are enlarged cross-sectional views corresponding to the region IV′ of FIG. 3A for explaining a method for forming a mark of a semiconductor package according to example embodiments. In the following, for easy and convenient explanation, the description of the same technical features as mentioned above will be omitted or briefly mentioned.

參考圖3A和3B,半導體封裝2可以包含基底100、半導體晶片200、模塑層300和遮罩層400。基底100、半導體晶片200和模塑層300可以由如參考圖2A所描述的相同方法形成。然而,不同於圖2A,凹陷350可能並不形成在模塑層300上。遮罩層400可以形成在模塑層300上。遮罩層400可以由如參考圖2B到2D所描述的相同方法形成。此處,塗佈溶液可以進一步包含氧化鈦,且因此遮罩層400可以包含金屬粒子410、導電碳材料420、聚合物430和氧化鈦(TiO2)。遮罩層400可以包含第一部分401和第二部分402。遮罩層400的第一部分401的第一頂部表面401a可以大體上平行於遮罩層400的第二部分402的第二頂部表面402a。3A and 3B, the semiconductor package 2 may include a substrate 100, a semiconductor wafer 200, a mold layer 300, and a mask layer 400. The substrate 100, the semiconductor wafer 200, and the mold layer 300 may be formed by the same method as described with reference to FIG. 2A. However, unlike FIG. 2A, the recess 350 may not be formed on the molding layer 300. The mask layer 400 may be formed on the molding layer 300. The mask layer 400 may be formed by the same method as described with reference to FIGS. 2B to 2D. Here, the coating solution may further include titanium oxide, and thus the mask layer 400 may include metal particles 410, a conductive carbon material 420, a polymer 430, and titanium oxide (TiO2). The mask layer 400 may include a first part 401 and a second part 402. The first top surface 401 a of the first portion 401 of the mask layer 400 may be substantially parallel to the second top surface 402 a of the second portion 402 of the mask layer 400.

參考圖3A和3C,光可以照射到遮罩層400的第二部分402上。遮罩層400的第一部分401可能並不暴露於光。舉例來說,光可能具有綠色區域的波長,例如495nm到570nm的波長。可以使用雷射器設備來照射光。雷射器設備可以具有(但不限於)4W到6W的輸出功率。氧化鈦可以充當光催化劑。當照射光時,氧化鈦可以與聚合物430反應以形成凹陷於第二部分402中的經改質聚合物431。經改質聚合物431可以形成在遮罩層400的第二部分402的上部部分中。因此,從遮罩層400的第二部分402反射的光的波長可能不同於從遮罩層400的第一部分401反射的光的波長,且因此第二部分402的色相可能不同於第一部分401的色相。此時,第二部分402的色相可能以某種方式不同於第一部分401的色相,使得第二部分402的色相能完全區別於第一部分401的色相。舉例來說,遮罩層400的第一部分401可能具有爐灰色,而遮罩層400的第二部分402可能具有棕色。結果,遮罩層400的第二部分402可以充當標記450,且標記450可以具有可視性。Referring to FIGS. 3A and 3C, light may be irradiated on the second portion 402 of the mask layer 400. The first portion 401 of the mask layer 400 may not be exposed to light. For example, the light may have a wavelength in the green region, such as a wavelength of 495 nm to 570 nm. A laser device can be used to illuminate the light. The laser device can have (but not limited to) 4W to 6W output power. Titanium oxide can act as a photocatalyst. When irradiated with light, the titanium oxide may react with the polymer 430 to form a modified polymer 431 recessed in the second part 402. The modified polymer 431 may be formed in the upper part of the second part 402 of the mask layer 400. Therefore, the wavelength of the light reflected from the second portion 402 of the mask layer 400 may be different from the wavelength of the light reflected from the first portion 401 of the mask layer 400, and therefore the hue of the second portion 402 may be different from that of the first portion 401. Hue. At this time, the hue of the second part 402 may be different from the hue of the first part 401 in some way, so that the hue of the second part 402 can be completely different from the hue of the first part 401. For example, the first portion 401 of the mask layer 400 may have a furnace gray color, and the second portion 402 of the mask layer 400 may have a brown color. As a result, the second portion 402 of the mask layer 400 may serve as the mark 450, and the mark 450 may have visibility.

當照射光時,遮罩層400的第二部分402可以是凹陷的。因此,遮罩層400的第二部分402的第二頂部表面402a可能相對於遮罩層400的第一部分401的第一頂部表面401a傾斜。然而,遮罩層400的第一頂部表面401a與第二頂部表面402a之間的角度θ2可能並不限於參考圖1D和1E所描述的角度θ1的範圍。遮罩層400的第一頂部表面401a與第二頂部表面402a之間的角度θ2可能大於0度。因此,遮罩層400的第二部分402的亮度可能不同於遮罩層400的第一部分401的亮度。When light is irradiated, the second portion 402 of the mask layer 400 may be recessed. Therefore, the second top surface 402 a of the second portion 402 of the mask layer 400 may be inclined with respect to the first top surface 401 a of the first portion 401 of the mask layer 400. However, the angle θ2 between the first top surface 401a and the second top surface 402a of the mask layer 400 may not be limited to the range of the angle θ1 described with reference to FIGS. 1D and 1E. The angle θ2 between the first top surface 401a and the second top surface 402a of the mask layer 400 may be greater than 0 degrees. Therefore, the brightness of the second portion 402 of the mask layer 400 may be different from the brightness of the first portion 401 of the mask layer 400.

圖3D為用以說明用於形成根據實例實施例的半導體封裝的標記的方法的對應於圖3A的區域IV'的放大剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到對如上文所提到的相同技術特徵的描述。FIG. 3D is an enlarged cross-sectional view corresponding to the region IV' of FIG. 3A for explaining a method for forming a mark of a semiconductor package according to example embodiments. In the following, for easy and convenient explanation, the description of the same technical features as mentioned above will be omitted or briefly mentioned.

參考圖3A和3D,光可以照射到遮罩層400的第二部分402上。舉例來說,可以由如參考圖3B所描述的大體上相同方法來執行光的照射。舉例來說,光可能具有綠色區域的波長,例如495nm到570nm的波長。因此,經改質聚合物431可以形成在第二部分402的上部部分中,如參考圖3B所描述。當過度照射光時,可以從遮罩層400的第二部分402移除聚合物430或經改質聚合物431,以在遮罩層400的第二頂部表面402a處暴露金屬粒子410。在此狀況下,遮罩層400的第二部分402可能示出金屬粒子410的顏色(例如,銀色)。Referring to FIGS. 3A and 3D, light may be irradiated on the second portion 402 of the mask layer 400. For example, the irradiation of light may be performed by substantially the same method as described with reference to FIG. 3B. For example, the light may have a wavelength in the green region, such as a wavelength of 495 nm to 570 nm. Therefore, the modified polymer 431 may be formed in the upper part of the second part 402, as described with reference to FIG. 3B. When the light is excessively irradiated, the polymer 430 or the modified polymer 431 may be removed from the second portion 402 of the mask layer 400 to expose the metal particles 410 at the second top surface 402a of the mask layer 400. In this situation, the second portion 402 of the mask layer 400 may show the color of the metal particles 410 (for example, silver).

遮罩層400的第一部分401可能並不暴露於光。金屬粒子410可能並不在遮罩層400的第一頂部表面401a處暴露,或第一頂部表面401a處暴露的金屬粒子410的密度可能小於第二頂部表面402a處暴露的金屬粒子410的密度。因此,第二部分402的顏色可能不同於第一部分401的顏色。遮罩層400的第一部分401可能具有爐灰色。結果,遮罩層400的第二部分402可以充當標記450,且標記450可以具有可視性。The first portion 401 of the mask layer 400 may not be exposed to light. The metal particles 410 may not be exposed at the first top surface 401a of the mask layer 400, or the density of the metal particles 410 exposed at the first top surface 401a may be less than the density of the metal particles 410 exposed at the second top surface 402a. Therefore, the color of the second part 402 may be different from the color of the first part 401. The first portion 401 of the mask layer 400 may have a furnace gray color. As a result, the second portion 402 of the mask layer 400 may serve as the mark 450, and the mark 450 may have visibility.

圖4A為用以說明根據本發明概念的一些實施例的半導體封裝的對應於圖1A的線I-II的剖面圖。圖4B為圖4A的區域III"的放大圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。4A is a cross-sectional view corresponding to the line I-II of FIG. 1A for explaining a semiconductor package according to some embodiments of the inventive concept. FIG. 4B is an enlarged view of the region III" of FIG. 4A. In the following, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or simply mentioned.

參考圖4A和4B,半導體封裝3可以包含基底100、半導體晶片200、模塑層300和遮罩層400'。基底100、半導體晶片200和模塑層300可以大體上相同於如參考圖1A和1B所描述。4A and 4B, the semiconductor package 3 may include a substrate 100, a semiconductor wafer 200, a molding layer 300, and a mask layer 400'. The substrate 100, the semiconductor wafer 200, and the mold layer 300 may be substantially the same as described with reference to FIGS. 1A and 1B.

遮罩層400'可以包含金屬粒子410'、導電碳材料420和聚合物430。金屬粒子410'、導電碳材料420和聚合物430可以包含分別相同於圖1A到1C或3A的實施例中所描述的金屬粒子410、導電碳材料420和聚合物430的材料。金屬粒子410'可以包含第一粒子411和第二粒子412。第一粒子411可以具有(但不限於)球形或橢圓形形狀。第一粒子411可以彼此連接。在一些實施例中,第一粒子411中的至少兩者可以彼此接觸。在某些實施例中,第一粒子411中的至少兩者可以聚集(aggregated)。第一粒子411在遮罩層400'中的含量可以介於2 wt%到20 wt%的範圍內。如果第一粒子411在遮罩層400'中的含量小於2 wt%或大於20 wt%,則遮罩層400'的電阻可能增加。The mask layer 400 ′ may include metal particles 410 ′, a conductive carbon material 420 and a polymer 430. The metal particles 410', the conductive carbon material 420, and the polymer 430 may include the same materials as the metal particles 410, the conductive carbon material 420, and the polymer 430 described in the embodiment of FIGS. 1A to 1C or 3A, respectively. The metal particles 410 ′ may include first particles 411 and second particles 412. The first particles 411 may have, but are not limited to, a spherical or elliptical shape. The first particles 411 may be connected to each other. In some embodiments, at least two of the first particles 411 may contact each other. In some embodiments, at least two of the first particles 411 may be aggregated. The content of the first particles 411 in the mask layer 400' may be in the range of 2 wt% to 20 wt%. If the content of the first particles 411 in the mask layer 400' is less than 2 wt% or greater than 20 wt%, the resistance of the mask layer 400' may increase.

第二粒子412的高寬比可以大於第一粒子411的高寬比。舉例來說,第二粒子412的高寬比可能介於為第一粒子411的高寬比的約5倍到約20倍的範圍內。此處,粒子的高寬比可以意指粒子的最大直徑與粒子的最小直徑的比率。第二粒子412由於其大的高寬比可能具有高的電導率。如果第二粒子412的高寬比小於第一粒子411的高寬比的5倍,則遮罩層400'可能具有低的電導率。如果第二粒子412的高寬比大於第一粒子411的高寬比的20倍,則遮罩層400'的尺寸可能過度增加。第二粒子412可以具有(但不限於)平板或薄片形狀。第二粒子412中的一些可以彼此直接連接。第一粒子411可以提供在第二粒子412之間。第二粒子412可以連接到第一粒子411。其中一個第二粒子412可以通過第一粒子411連接到另一個第二粒子412。換句話說,即使第二粒子412彼此隔開,第二粒子412仍可以通過第一粒子411彼此電性連接。第二粒子412可以包含相同於第一粒子411的金屬或不同金屬。第二粒子412在遮罩層400'中的含量可以介於70 wt%到90 wt%的範圍內。如果第二粒子412在遮罩層400'中的含量小於70 wt%,則遮罩層400'的電阻可能增加。如果第二粒子412在遮罩層400'中的含量大於90 wt%,則遮罩層400'與模塑層300之間的鍵結強度可能降低。The aspect ratio of the second particles 412 may be greater than the aspect ratio of the first particles 411. For example, the aspect ratio of the second particles 412 may be in the range of about 5 times to about 20 times the aspect ratio of the first particles 411. Here, the aspect ratio of the particle may mean the ratio of the maximum diameter of the particle to the minimum diameter of the particle. The second particle 412 may have high conductivity due to its large aspect ratio. If the aspect ratio of the second particles 412 is less than 5 times the aspect ratio of the first particles 411, the mask layer 400' may have low electrical conductivity. If the aspect ratio of the second particle 412 is greater than 20 times the aspect ratio of the first particle 411, the size of the mask layer 400' may be excessively increased. The second particles 412 may have, but are not limited to, a flat plate or flake shape. Some of the second particles 412 may be directly connected to each other. The first particles 411 may be provided between the second particles 412. The second particle 412 may be connected to the first particle 411. One of the second particles 412 can be connected to the other second particle 412 through the first particle 411. In other words, even if the second particles 412 are separated from each other, the second particles 412 can still be electrically connected to each other through the first particles 411. The second particle 412 may include the same metal as the first particle 411 or a different metal. The content of the second particles 412 in the mask layer 400' may be in the range of 70 wt% to 90 wt%. If the content of the second particles 412 in the mask layer 400' is less than 70 wt%, the resistance of the mask layer 400' may increase. If the content of the second particles 412 in the mask layer 400' is greater than 90 wt%, the bonding strength between the mask layer 400' and the molding layer 300 may decrease.

在一些實施例中,第二粒子412可以堆疊在模塑層300上。在第二粒子412提供在模塑層300的頂部表面上的情況下,第二粒子412的長軸可以大體上平行於模塑層300的頂部表面。在第二粒子412提供在模塑層300的側壁上的情況下,第二粒子412的長軸可以大體上平行於模塑層300的側壁。然而,第二粒子412的長軸的佈置不限於此。In some embodiments, the second particles 412 may be stacked on the molding layer 300. In the case where the second particles 412 are provided on the top surface of the molding layer 300, the long axis of the second particles 412 may be substantially parallel to the top surface of the molding layer 300. In the case where the second particles 412 are provided on the side walls of the molding layer 300, the long axis of the second particles 412 may be substantially parallel to the side walls of the molding layer 300. However, the arrangement of the long axis of the second particle 412 is not limited to this.

導電碳材料420可以物理地連接到並電性連接到金屬粒子410'中的至少一個金屬粒子。導電碳材料420在遮罩層400'中的含量可以介於0.05 wt%到5 wt%的範圍內。如果導電碳材料420在遮罩層400'中的含量小於0.05 wt%,則導電碳材料420可能不能將第二粒子412彼此充分電性連接。如果導電碳材料420在遮罩層400'中的含量大於5 wt%,則第二粒子412的含量可能減少且遮罩層400'的電阻可能增加。The conductive carbon material 420 may be physically and electrically connected to at least one of the metal particles 410'. The content of the conductive carbon material 420 in the mask layer 400' may be in the range of 0.05 wt% to 5 wt%. If the content of the conductive carbon material 420 in the mask layer 400' is less than 0.05 wt%, the conductive carbon material 420 may not be able to sufficiently electrically connect the second particles 412 to each other. If the content of the conductive carbon material 420 in the mask layer 400' is greater than 5 wt%, the content of the second particles 412 may decrease and the resistance of the mask layer 400' may increase.

聚合物430可以大體上相同於參考圖1A和1B所描述的聚合物430。舉例來說,聚合物430可以提供在第一粒子411、第二粒子412與導電碳材料420之間的間隙中。第一粒子411、第二粒子412和導電碳材料420可以由聚合物430鍵結到模塑層300。聚合物430在遮罩層400'中的含量可以介於7 wt%到12 wt%的範圍內。如果聚合物430在遮罩層400'中的含量小於7 wt%,則遮罩層400'與模塑層300之間的鍵結強度可能降低。如果聚合物430在遮罩層400'中的含量大於12 wt%,則遮罩層400'的電阻可能增加。The polymer 430 may be substantially the same as the polymer 430 described with reference to FIGS. 1A and 1B. For example, the polymer 430 may be provided in the gaps between the first particles 411, the second particles 412 and the conductive carbon material 420. The first particles 411, the second particles 412 and the conductive carbon material 420 may be bonded to the molding layer 300 by the polymer 430. The content of the polymer 430 in the mask layer 400' may be in the range of 7 wt% to 12 wt%. If the content of the polymer 430 in the mask layer 400' is less than 7 wt%, the bonding strength between the mask layer 400' and the molding layer 300 may decrease. If the content of the polymer 430 in the mask layer 400' is greater than 12 wt%, the resistance of the mask layer 400' may increase.

標記450可以提供在半導體封裝3上。標記450可以相同於圖1B、1D和1E的標記450。替代地,標記450可以相同於圖3A的標記450,且可以由如圖3B到3D的實施例中所描述的相同方法形成。The mark 450 may be provided on the semiconductor package 3. The mark 450 may be the same as the mark 450 of FIGS. 1B, 1D, and 1E. Alternatively, the mark 450 may be the same as the mark 450 of FIG. 3A, and may be formed by the same method as described in the embodiments of FIGS. 3B to 3D.

半導體封裝3可以由如參考圖2A到2D所描述的相同方法製造。然而,塗佈溶液可以包含金屬粒子410'、導電碳材料420、聚合物430和溶劑。在圖1B和2C的熱處理過程期間,導電碳材料420可以化學鍵結(例如,共價鍵結)到第一粒子411和第二粒子412中的其中一種。在某些實施例中,導電碳材料420可能並不化學鍵結到金屬粒子410',但可以接觸金屬粒子410'。The semiconductor package 3 can be manufactured by the same method as described with reference to FIGS. 2A to 2D. However, the coating solution may include metal particles 410', conductive carbon material 420, polymer 430, and a solvent. During the heat treatment process of FIGS. 1B and 2C, the conductive carbon material 420 may be chemically bonded (for example, covalently bonded) to one of the first particles 411 and the second particles 412. In some embodiments, the conductive carbon material 420 may not be chemically bonded to the metal particles 410', but may contact the metal particles 410'.

圖5為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 5 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖5,半導體封裝4可以包含基底100、半導體晶片200、模塑層300、第一遮罩層400A和第二遮罩層400B。基底100、半導體晶片200和模塑層300可以大體上相同於如參考圖1A和1B所描述。第一遮罩層400A可以大體上相同於參考圖1A和1B所描述的遮罩層400。第一遮罩層400A可以由形成圖2B到2D的遮罩層400的方法的大體上相同方法形成。舉例來說,第一遮罩層400A可以包含第一金屬粒子410A、第一導電碳材料420A和第一聚合物430A。第一金屬粒子410A可以由熱處理過程彼此物理連接。第一導電碳材料420A可以鍵結到第一金屬粒子410A。第一遮罩層400A可以電性連接到基底100的接地圖案110。5, the semiconductor package 4 may include a substrate 100, a semiconductor wafer 200, a molding layer 300, a first mask layer 400A, and a second mask layer 400B. The substrate 100, the semiconductor wafer 200, and the mold layer 300 may be substantially the same as described with reference to FIGS. 1A and 1B. The first mask layer 400A may be substantially the same as the mask layer 400 described with reference to FIGS. 1A and 1B. The first mask layer 400A may be formed by substantially the same method as the method of forming the mask layer 400 of FIGS. 2B to 2D. For example, the first mask layer 400A may include the first metal particles 410A, the first conductive carbon material 420A, and the first polymer 430A. The first metal particles 410A may be physically connected to each other through a heat treatment process. The first conductive carbon material 420A may be bonded to the first metal particles 410A. The first mask layer 400A may be electrically connected to the ground pattern 110 of the substrate 100.

第二遮罩層400B可以形成在第一遮罩層400A上。第二遮罩層400B可以在完成第一遮罩層400A的熱處理過程之後,由形成圖2B到2D的遮罩層400的方法的大體上相同方法形成。舉例來說,可以將塗佈溶液塗覆到第一遮罩層400A上以形成第二初步遮罩層,且第二初步遮罩層可以經熱處理以形成第二遮罩層400B。第二遮罩層400B可以包含第二金屬粒子410B、第二導電碳材料420B和第二聚合物430B。第二金屬粒子410B可以由熱處理過程彼此物理連接。第二導電碳材料420B可以鍵結到第二金屬粒子410B。第二遮罩層400B可以電性連接到第一遮罩層400A。舉例來說,第二金屬粒子410B可以連接到第一金屬粒子410A或第一導電碳材料420A,或第二導電碳材料420B可以連接到第一金屬粒子410A或第一導電碳材料420A。半導體封裝4可以包含多個遮罩層400A和400B,且因此可以更加充分地阻斷半導體封裝4的電磁干擾。第三遮罩層可以提供在第二遮罩層400B上。遮罩層400A和400B的數目可以不同地修改。遮罩層400A和400B的總厚度可以通過調整遮罩層400A和400B的數目來調整。The second mask layer 400B may be formed on the first mask layer 400A. The second mask layer 400B may be formed by substantially the same method as the method of forming the mask layer 400 of FIGS. 2B to 2D after the heat treatment process of the first mask layer 400A is completed. For example, the coating solution may be coated on the first mask layer 400A to form the second preliminary mask layer, and the second preliminary mask layer may be heat-treated to form the second mask layer 400B. The second mask layer 400B may include second metal particles 410B, a second conductive carbon material 420B, and a second polymer 430B. The second metal particles 410B may be physically connected to each other through a heat treatment process. The second conductive carbon material 420B may be bonded to the second metal particles 410B. The second mask layer 400B may be electrically connected to the first mask layer 400A. For example, the second metal particle 410B may be connected to the first metal particle 410A or the first conductive carbon material 420A, or the second conductive carbon material 420B may be connected to the first metal particle 410A or the first conductive carbon material 420A. The semiconductor package 4 may include a plurality of mask layers 400A and 400B, and therefore, the electromagnetic interference of the semiconductor package 4 may be blocked more fully. The third mask layer may be provided on the second mask layer 400B. The number of mask layers 400A and 400B can be variously modified. The total thickness of the mask layers 400A and 400B can be adjusted by adjusting the number of the mask layers 400A and 400B.

圖6為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 6 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖6,半導體封裝5可以包含襯半導體晶片200、模塑層300、第一遮罩層400A’ 和第二遮罩層400B’。第一遮罩層400A’可以包含金屬粒子410A’、導電碳材料420A和聚合物430A。金屬粒子410A’包括第一粒子411A和第二粒子412A。第二遮罩層400B’可以包含金屬粒子410B’、導電碳材料420B和聚合物430B。金屬粒子410B’包括第一粒子411B和第二粒子412B。金屬粒子410A’和410B’、導電碳材料420A和420B以及聚合物430A和430B可以分別大體上相同於如參考圖4A和4B所描述的金屬粒子410'、導電碳材料420和聚合物430。Referring to FIG. 6, the semiconductor package 5 may include a substrate semiconductor wafer 200, a molding layer 300, a first mask layer 400A' and a second mask layer 400B'. The first mask layer 400A' may include metal particles 410A', a conductive carbon material 420A, and a polymer 430A. The metal particles 410A' include first particles 411A and second particles 412A. The second mask layer 400B' may include metal particles 410B', a conductive carbon material 420B, and a polymer 430B. The metal particles 410B' include first particles 411B and second particles 412B. The metal particles 410A' and 410B', the conductive carbon materials 420A and 420B, and the polymers 430A and 430B may be substantially the same as the metal particles 410', the conductive carbon material 420, and the polymer 430 as described with reference to FIGS. 4A and 4B, respectively.

圖7為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 7 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖7,半導體封裝6可以包含基底100、半導體晶片200、模塑層300和遮罩層400。基底100可具有彼此相對的頂部表面100a與底部表面100b。半導體晶片200和模塑層300可以大體上相同於如參考圖1A和1B所描述。接地結構110、111和112可以包括接地圖案110、上部接地通孔111和下部接地通孔112A與112B。可以提供多個下部接地通孔112A和112B。下部接地通孔112A和112B可以包含第一下部接地通孔112A和第二下部接地通孔112B。第一下部接地通孔112A和第二下部接地通孔112B可以電性連接到接地圖案110。接地端子131可以提供在第二下部接地通孔112B的底部表面上。接地圖案110可以與基底100的側壁100c隔開。替代地,在某些實施例中,接地圖案110可以延伸到基底100的側壁100c,以便電性連接到遮罩層400。訊號圖案120可以與接地圖案110和遮罩層400電性隔離。Referring to FIG. 7, the semiconductor package 6 may include a substrate 100, a semiconductor wafer 200, a molding layer 300 and a mask layer 400. The substrate 100 may have a top surface 100a and a bottom surface 100b opposite to each other. The semiconductor wafer 200 and the molding layer 300 may be substantially the same as described with reference to FIGS. 1A and 1B. The ground structures 110, 111, and 112 may include a ground pattern 110, an upper ground via 111, and a lower ground via 112A and 112B. A plurality of lower ground vias 112A and 112B may be provided. The lower ground vias 112A and 112B may include a first lower ground via 112A and a second lower ground via 112B. The first lower ground via 112A and the second lower ground via 112B may be electrically connected to the ground pattern 110. The ground terminal 131 may be provided on the bottom surface of the second lower ground via 112B. The ground pattern 110 may be spaced apart from the sidewall 100c of the substrate 100. Alternatively, in some embodiments, the ground pattern 110 may extend to the sidewall 100 c of the substrate 100 so as to be electrically connected to the mask layer 400. The signal pattern 120 may be electrically isolated from the ground pattern 110 and the mask layer 400.

遮罩層400可以進一步延伸到基底100的底部表面100b上且可以連接到第一下部接地通孔112A。遮罩層400可以通過第一下部接地通孔112A、接地圖案110、第二下部接地通孔112B和接地端子131接地。遮罩層400可具有暴露端子131和132的孔115。遮罩層400可以與端子131和132隔開。The mask layer 400 may further extend onto the bottom surface 100b of the substrate 100 and may be connected to the first lower ground via 112A. The mask layer 400 may be grounded through the first lower ground via 112A, the ground pattern 110, the second lower ground via 112B, and the ground terminal 131. The mask layer 400 may have holes 115 exposing the terminals 131 and 132. The mask layer 400 may be separated from the terminals 131 and 132.

圖8為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 8 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖8,半導體封裝7可以包含基底100、半導體晶片200、模塑層300和遮罩層400’。半導體晶片200和模塑層300可以大體上相同於如參考圖1A和1B所描述。基底100可以大體上相同於如參考圖7所描述。Referring to FIG. 8, the semiconductor package 7 may include a substrate 100, a semiconductor wafer 200, a molding layer 300, and a mask layer 400'. The semiconductor wafer 200 and the molding layer 300 may be substantially the same as described with reference to FIGS. 1A and 1B. The substrate 100 may be substantially the same as described with reference to FIG. 7.

遮罩層400’可以包含導電碳材料420、聚合物430以及包括第一粒子411和第二粒子412的金屬粒子410’,其如圖4A與4B中所描述。遮罩層400’可以提供在模塑層300上。遮罩層400’可以延伸到基底100的底部表面100b上以連接到第一下部接地通孔112A。遮罩層400’可以通過第一下部接地通孔112A、接地圖案110、第二下部接地通孔112B和接地端子131接地。遮罩層400’可具有暴露端子131和132的孔115。遮罩層400’可以與端子131和132隔開。The mask layer 400' may include a conductive carbon material 420, a polymer 430, and metal particles 410' including first particles 411 and second particles 412, as described in FIGS. 4A and 4B. The mask layer 400' may be provided on the molding layer 300. The mask layer 400' may extend onto the bottom surface 100b of the substrate 100 to be connected to the first lower ground via 112A. The mask layer 400' may be grounded through the first lower ground via 112A, the ground pattern 110, the second lower ground via 112B, and the ground terminal 131. The mask layer 400' may have holes 115 exposing the terminals 131 and 132. The mask layer 400' may be separated from the terminals 131 and 132.

圖9為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 9 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖9,半導體封裝8可以包含基底100、半導體晶片200、模塑層300和遮罩層400。半導體晶片200可以大體上相同於如參考圖1A和1B所描述。Referring to FIG. 9, the semiconductor package 8 may include a substrate 100, a semiconductor wafer 200, a molding layer 300 and a mask layer 400. The semiconductor wafer 200 may be substantially the same as described with reference to FIGS. 1A and 1B.

接地結構110、111A、111B和112可以包括接地圖案110、上部接地通孔111A和111B和下部接地通孔112。上部接地通孔111A和111B可以包括第一上部接地通孔111A和第二上部接地通孔111B。第一上部接地通孔111A可以大體上相同於如參考圖1A和1B所描述上部接地通孔111。例如,第一上部接地通孔111A可以連接到接地中介物210。當從平面圖看時,第二上部接地通孔111B可以安置在基底100的邊緣部分中。當從平面圖看時,第二上部接地通孔111B可以與模塑層300隔開。接地圖案110可以包括多個接地圖案,且第一與第二上部接地通孔111A和111B可以連接到彼此不同的接地圖案110。與圖9不同,一個接地圖案110可以連接到第一上部接地通孔111A和第二上部接地通孔111B。The ground structures 110, 111A, 111B, and 112 may include a ground pattern 110, upper ground vias 111A and 111B, and a lower ground via 112. The upper ground vias 111A and 111B may include a first upper ground via 111A and a second upper ground via 111B. The first upper ground via 111A may be substantially the same as the upper ground via 111 as described with reference to FIGS. 1A and 1B. For example, the first upper ground via 111A may be connected to the ground interposer 210. When viewed from a plan view, the second upper ground via 111B may be disposed in the edge portion of the substrate 100. When viewed from a plan view, the second upper ground via 111B may be spaced apart from the molding layer 300. The ground pattern 110 may include a plurality of ground patterns, and the first and second upper ground vias 111A and 111B may be connected to ground patterns 110 different from each other. Unlike FIG. 9, one ground pattern 110 may be connected to the first upper ground via 111A and the second upper ground via 111B.

模塑層300可以安置於基底100的頂部表面100a。模塑層300的寬度可以小於基底100的寬度。也就是,模塑層300可能暴露部分(例如邊緣部分)的基底100。模塑層300可能暴露至少部分(例如第二上部接地通孔111B)的接地結構110、111A、111B和112。The molding layer 300 may be disposed on the top surface 100 a of the substrate 100. The width of the molding layer 300 may be smaller than the width of the substrate 100. That is, the molding layer 300 may expose a portion (for example, an edge portion) of the substrate 100. The molding layer 300 may expose at least a part (for example, the second upper ground via 111B) of the ground structures 110, 111A, 111B, and 112.

遮罩層400可以安置在模塑層300上。遮罩層400可以延伸到模塑層300所露出的基底100的頂部表面100a上,且可以連接到第二上部接地通孔111B。遮罩層400可以通過第二上部接地通孔111B、接地圖案110、下部接地通孔112和接地端子131接地。某些實施例中,遮罩層400可以進一步延伸到基底100的側壁100c上。但是發明概念不限於此。The mask layer 400 may be disposed on the molding layer 300. The mask layer 400 may extend onto the top surface 100a of the substrate 100 exposed by the molding layer 300, and may be connected to the second upper ground via 111B. The mask layer 400 may be grounded through the second upper ground via 111B, the ground pattern 110, the lower ground via 112, and the ground terminal 131. In some embodiments, the mask layer 400 may further extend to the sidewall 100c of the substrate 100. But the inventive concept is not limited to this.

圖10為說明根據實例實施例的半導體封裝的剖面圖。在下文中,為容易且便利地解釋,將省略或簡單提到如上文所提到的相同元件的描述。FIG. 10 is a cross-sectional view illustrating a semiconductor package according to example embodiments. Hereinafter, for easy and convenient explanation, the description of the same elements as mentioned above will be omitted or briefly mentioned.

參看圖10,半導體封裝9可以包含基底100、半導體晶片200、模塑層300和遮罩層400’。半導體晶片200可以大體上相同於如參考圖1A和1B所描述。基底100、接地結構110、111A、111B和112以及模塑層300可以大體上相同於如參考圖9所描述。10, the semiconductor package 9 may include a substrate 100, a semiconductor wafer 200, a mold layer 300, and a mask layer 400'. The semiconductor wafer 200 may be substantially the same as described with reference to FIGS. 1A and 1B. The substrate 100, the ground structures 110, 111A, 111B, and 112, and the molding layer 300 may be substantially the same as described with reference to FIG. 9.

遮罩層400’可以包含導電碳材料420、聚合物430以及包括第一粒子411和第二粒子412的金屬粒子410’,其如圖4A與4B中所描述。遮罩層400’可以延伸到模塑層300所露出的基底100的頂部表面100a上,且可以連接到第二上部接地通孔111B。遮罩層400’可以通過第二上部接地通孔111B、接地圖案110、下部接地通孔112和接地端子131接地。某些實施例中,遮罩層400’可以進一步延伸到基底100的側壁100c上。但是發明概念不限於此。The mask layer 400' may include a conductive carbon material 420, a polymer 430, and metal particles 410' including first particles 411 and second particles 412, as described in FIGS. 4A and 4B. The mask layer 400' may extend to the top surface 100a of the substrate 100 exposed by the molding layer 300, and may be connected to the second upper ground via 111B. The mask layer 400' may be grounded through the second upper ground via 111B, the ground pattern 110, the lower ground via 112, and the ground terminal 131. In some embodiments, the mask layer 400' may further extend to the sidewall 100c of the substrate 100. But the inventive concept is not limited to this.

根據一些實例實施例,遮罩層可以防止半導體封裝的電磁干擾(electromagnetic interference, EMI)。金屬粒子可以彼此物理連接。導電碳材料可以物理性連接到金屬粒子並電性連接到所述金屬粒子。因此,遮罩層的電阻可能降低。由於遮罩層的電阻得到減少,因此有可能改進遮罩層的EMI遮罩特性。According to some example embodiments, the mask layer may prevent electromagnetic interference (EMI) of the semiconductor package. The metal particles can be physically connected to each other. The conductive carbon material may be physically connected to the metal particles and electrically connected to the metal particles. Therefore, the resistance of the mask layer may decrease. Since the resistance of the mask layer is reduced, it is possible to improve the EMI shielding characteristics of the mask layer.

根據一些實例實施例,具有可視性的標記可以形成在半導體封裝上。According to some example embodiments, a mark having visibility may be formed on the semiconductor package.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present invention. The protection scope of the present invention shall be subject to those defined by the attached patent application scope.

1、2、3、4、5、6、7、8、9‧‧‧半導體封裝10‧‧‧單位封裝100‧‧‧基底100a‧‧‧頂部表面100b‧‧‧底部表面100c‧‧‧側壁101‧‧‧封裝基底110‧‧‧接地圖案111‧‧‧上部接地通孔111A‧‧‧第一上部接地通孔111B‧‧‧第二上部接地通孔112‧‧‧下部接地通孔112A‧‧‧第一下部接地通孔112B‧‧‧第二下部接地通孔115‧‧‧孔120‧‧‧訊號圖案121‧‧‧上部訊號通孔122‧‧‧下部訊號通孔130‧‧‧絕緣層131‧‧‧接地端子132‧‧‧訊號端子200‧‧‧半導體晶片210‧‧‧接地中介物220‧‧‧訊號中介物250‧‧‧積體電路層300‧‧‧模塑層300a‧‧‧頂部表面301‧‧‧模塑圖案350‧‧‧凹陷350a‧‧‧傾斜側壁400、400'‧‧‧遮罩層400A、400A’‧‧‧第一遮罩層400B、400B’‧‧‧第二遮罩層400P‧‧‧初步遮罩層401‧‧‧第一部分401a‧‧‧第一頂部表面402‧‧‧第二部分402a‧‧‧第二頂部表面410、410'‧‧‧金屬粒子410A、410A’‧‧‧第一金屬粒子410B、410B’‧‧‧第二金屬粒子411、411A‧‧‧第一粒子412、412B‧‧‧第二粒子420‧‧‧導電碳材料420A‧‧‧第一導電碳材料420B‧‧‧第二導電碳材料430‧‧‧聚合物430A‧‧‧第一聚合物430B‧‧‧第二聚合物431‧‧‧經改質聚合物450‧‧‧標記600‧‧‧電磁波D1‧‧‧深度θ1、θ2‧‧‧角度。1, 2, 3, 4, 5, 6, 7, 8, 9. 101‧‧‧Packaging substrate 110‧‧‧Ground pattern 111‧‧‧Upper ground via 111A‧‧‧First upper ground via 111B‧‧‧Second upper ground via 112‧‧‧Lower ground via 112A‧ ‧‧First lower ground through hole 112B‧‧‧Second lower ground through hole 115‧‧‧Hole 120‧‧‧Signal pattern 121‧‧‧Upper signal through hole 122‧‧‧Lower signal through hole 130‧‧‧ Insulation layer 131. ‧‧‧Top surface 301‧‧‧Molded pattern 350‧‧‧Concavity 350a‧‧‧Slanted sidewall 400, 400'‧‧‧Mask layer 400A, 400A'‧‧‧First mask layer 400B, 400B'‧ ‧‧Second mask layer 400P‧‧‧Preliminary mask layer 401‧‧‧First part 401a‧‧‧First top surface 402‧‧‧Second part 402a‧‧‧Second top surface 410, 410'‧‧ ‧Metal particles 410A, 410A'‧‧‧First metal particles 410B, 410B'‧‧‧Second metal particles 411, 411A‧‧‧First particles 412, 412B‧‧‧Second particles 420‧‧‧Conductive carbon materials 420A‧‧‧First conductive carbon material 420B‧‧‧Second conductive carbon material 430‧‧‧Polymer 430A‧‧‧First polymer 430B‧‧‧Second polymer 431‧‧‧Modified polymer 450 ‧‧‧Mark 600‧‧‧Electromagnetic wave D1‧‧‧Depth θ1, θ2‧‧‧Angle.

通過參考附圖來描述某些實例實施例將更加清楚上文和/或其它方面,在附圖中: 圖1A為說明根據實例實施例的半導體封裝的平面圖。 圖1B為沿著圖1A的線I-II截取的剖面圖。 圖1C為圖1B的區域III的放大圖。 圖1D為說明根據實例實施例的遮罩層的頂部表面的放大平面圖。 圖1E為圖1B的區域IV的放大圖。 圖2A、2B和2C為說明用於製造根據實例實施例的半導體封裝的方法的剖面圖。 圖2D為圖2C的區域III'的放大圖。 圖3A為說明根據實例實施例的半導體封裝的剖面圖。 圖3B和3C為說明用於形成根據實例實施例的半導體封裝的標記的方法的放大剖面圖。 圖3D為說明用於形成根據實例實施例的半導體封裝的標記的方法的放大剖面圖。 圖4A為說明根據實例實施例的半導體封裝的剖面圖。 圖4B為圖4A的區域III"的放大圖。 圖5為說明根據實例實施例的半導體封裝的剖面圖。 圖6為說明根據實施例的半導體封裝的剖面圖。 圖7為說明根據實施例的半導體封裝的剖面圖。 圖8為說明根據實施例的半導體封裝的剖面圖。 圖9為說明根據實施例的半導體封裝的剖面圖。 圖10為說明根據實施例的半導體封裝的剖面圖。The above and/or other aspects will become clearer by describing certain example embodiments with reference to the accompanying drawings, in which: FIG. 1A is a plan view illustrating a semiconductor package according to an example embodiment. Fig. 1B is a cross-sectional view taken along the line I-II of Fig. 1A. FIG. 1C is an enlarged view of area III of FIG. 1B. FIG. 1D is an enlarged plan view illustrating the top surface of the mask layer according to example embodiments. FIG. 1E is an enlarged view of area IV of FIG. 1B. 2A, 2B, and 2C are cross-sectional views illustrating a method for manufacturing a semiconductor package according to example embodiments. FIG. 2D is an enlarged view of area III' of FIG. 2C. FIG. 3A is a cross-sectional view illustrating a semiconductor package according to example embodiments. 3B and 3C are enlarged cross-sectional views illustrating a method for forming a mark of a semiconductor package according to example embodiments. 3D is an enlarged cross-sectional view illustrating a method for forming a mark of a semiconductor package according to example embodiments. 4A is a cross-sectional view illustrating a semiconductor package according to example embodiments. 4B is an enlarged view of region III" of FIG. 4A. FIG. 5 is a cross-sectional view illustrating a semiconductor package according to an example embodiment. FIG. 6 is a cross-sectional view illustrating a semiconductor package according to an embodiment. FIG. 7 is an illustration according to an embodiment Cross-sectional view of a semiconductor package. Fig. 8 is a cross-sectional view illustrating a semiconductor package according to an embodiment. Fig. 9 is a cross-sectional view illustrating a semiconductor package according to an embodiment. Fig. 10 is a cross-sectional view illustrating a semiconductor package according to an embodiment.

9‧‧‧半導體封裝 9‧‧‧Semiconductor packaging

100‧‧‧基底 100‧‧‧Base

100a‧‧‧頂部表面 100a‧‧‧Top surface

100b‧‧‧底部表面 100b‧‧‧Bottom surface

100c‧‧‧側壁 100c‧‧‧ side wall

110‧‧‧接地圖案 110‧‧‧Ground pattern

111A‧‧‧第一上部接地通孔 111A‧‧‧First upper ground through hole

111B‧‧‧第二上部接地通孔 111B‧‧‧Second upper ground through hole

112‧‧‧下部接地通孔 112‧‧‧Bottom ground through hole

120‧‧‧訊號圖案 120‧‧‧Signal pattern

121‧‧‧上部訊號通孔 121‧‧‧Upper signal through hole

122‧‧‧下部訊號通孔 122‧‧‧Lower signal through hole

130‧‧‧絕緣層 130‧‧‧Insulation layer

131‧‧‧接地端子 131‧‧‧Ground terminal

132‧‧‧訊號端子 132‧‧‧Signal terminal

200‧‧‧半導體晶片 200‧‧‧Semiconductor chip

210‧‧‧接地中介物 210‧‧‧Grounding Intermediary

220‧‧‧訊號中介物 220‧‧‧Signal Intermediary

250‧‧‧積體電路層 250‧‧‧Integrated circuit layer

300‧‧‧模塑層 300‧‧‧Molding layer

350‧‧‧凹陷 350‧‧‧Sag

400'‧‧‧遮罩層 400'‧‧‧Mask layer

410'‧‧‧金屬粒子 410'‧‧‧Metal particles

411‧‧‧第一粒子 411‧‧‧The first particle

412‧‧‧第二粒子 412‧‧‧Second Particle

420‧‧‧導電碳材料 420‧‧‧Conductive carbon material

430‧‧‧聚合物 430‧‧‧Polymer

450‧‧‧標記 450‧‧‧Mark

Claims (25)

一種用於製造半導體封裝的方法,所述方法包括:提供包括接地圖案的封裝;以及形成遮罩層,所述遮罩層安置在所述封裝的頂部表面和側壁上且電性連接到所述接地圖案,其中所述遮罩層包括:金屬粒子,其彼此連接,所述金屬粒子包含:第一粒子;和第二粒子,其具有大於所述第一粒子的高寬比;以及導電碳材料,其連接到所述金屬粒子中的至少一個金屬粒子。 A method for manufacturing a semiconductor package, the method comprising: providing a package including a ground pattern; and forming a mask layer disposed on the top surface and sidewalls of the package and electrically connected to the The ground pattern, wherein the mask layer includes: metal particles connected to each other, the metal particles including: first particles; and second particles, which have an aspect ratio greater than that of the first particles; and a conductive carbon material , Which is connected to at least one of the metal particles. 如申請專利範圍第1項所述用於製造半導體封裝的方法,更包括:在所述遮罩層的所述形成之前,在所述封裝的所述頂部表面上形成凹陷,其中所述遮罩層的第一部分提供在所述封裝的在所述凹陷外部的所述頂部表面上,其中所述遮罩層的第二部分提供在所述凹陷上,以及其中所述第一部分具有第一頂部表面,且所述第二部分具有在相對於所述第一頂部表面傾斜的方向上延伸的第二頂部表面。 The method for manufacturing a semiconductor package as described in the first item of the scope of patent application further includes: before the formation of the mask layer, forming a recess on the top surface of the package, wherein the mask A first portion of the layer is provided on the top surface of the package outside the recess, wherein the second portion of the mask layer is provided on the recess, and wherein the first portion has a first top surface , And the second part has a second top surface extending in an oblique direction with respect to the first top surface. 如申請專利範圍第2項所述用於製造半導體封裝的方法,其中從所述遮罩層的所述第二部分反射的光的強度不同於從所述遮罩層的所述第一部分反射的光的強度,其中所述凹陷的深度至少為20μm,以及其中所述第一頂部表面與所述第二頂部表面之間的角度介於130度到160度的範圍。 The method for manufacturing a semiconductor package as described in the scope of the patent application, wherein the intensity of the light reflected from the second part of the mask layer is different from the intensity of the light reflected from the first part of the mask layer The intensity of light, wherein the depth of the recess is at least 20 μm, and wherein the angle between the first top surface and the second top surface is in the range of 130 degrees to 160 degrees. 如申請專利範圍第3項所述用於製造半導體封裝的方法,其中所述遮罩層的所述第一部分和所述遮罩層的所述第二部分中的每一部分包括所述金屬粒子和所述導電碳材料,以及其中所述第一部分的構成比與所述第二部分的構成比相同。 The method for manufacturing a semiconductor package as described in claim 3, wherein each of the first part of the mask layer and the second part of the mask layer includes the metal particles and The conductive carbon material, and wherein the composition ratio of the first part is the same as the composition ratio of the second part. 如申請專利範圍第1項所述用於製造半導體封裝的方法,其中所述遮罩層包括第一部分和第二部分,其中所述方法進一步包括將光照射到所述遮罩層的所述第二部分上,而不將所述遮罩層的所述第一部分暴露於所述光,其中所述光具有495nm到570nm的波長,其中所述遮罩層更包括氧化鈦,其中所述遮罩層的所述第一部分反射具有第一波長的光,以及其中所述遮罩層的所述第二部分反射具有不同於所述第一波長的第二波長的光。 The method for manufacturing a semiconductor package as described in claim 1, wherein the mask layer includes a first part and a second part, and wherein the method further includes irradiating light to the first part of the mask layer On the second part without exposing the first part of the mask layer to the light, wherein the light has a wavelength of 495nm to 570nm, wherein the mask layer further includes titanium oxide, and wherein the mask The first portion of the layer reflects light having a first wavelength, and wherein the second portion of the mask layer reflects light having a second wavelength different from the first wavelength. 如申請專利範圍第1項所述用於製造半導體封裝的方法,其中所述第二粒子的所述高寬比介於為所述第一粒子的所述高寬比的5倍到20倍的範圍。 The method for manufacturing a semiconductor package as described in claim 1, wherein the aspect ratio of the second particle is 5 to 20 times the aspect ratio of the first particle Scope. 如申請專利範圍第1項所述用於製造半導體封裝的方法,其中所述遮罩層更包括親水性聚合物,以及其中所述遮罩層具有疏水性性質。 The method for manufacturing a semiconductor package as described in the first item of the scope of the patent application, wherein the mask layer further includes a hydrophilic polymer, and wherein the mask layer has a hydrophobic property. 如申請專利範圍第1項所述用於製造半導體封裝的方法,其中所述導電碳材料共價鍵結到所述金屬粒子。 The method for manufacturing a semiconductor package as described in item 1 of the scope of patent application, wherein the conductive carbon material is covalently bonded to the metal particles. 一種用於製造半導體封裝的方法,所述方法包括:提供包括基底、半導體晶片和模塑層的封裝,所述基底包括在所述基底的一個表面處暴露的接地圖案;以及 將包含金屬粒子和導電碳材料的溶液塗覆到所述模塑層上以形成遮罩層,其中所述遮罩層包括:所述金屬粒子,其中至少一些金屬粒子彼此直接連接;以及連接到所述金屬粒子中的至少一個金屬粒子的所述導電碳材料,以及其中所述遮罩層延伸到所述基底的所述一個表面上且電性連接到所述接地圖案。 A method for manufacturing a semiconductor package, the method comprising: providing a package including a substrate, a semiconductor wafer, and a molding layer, the substrate including a ground pattern exposed at one surface of the substrate; and A solution containing metal particles and a conductive carbon material is coated on the molding layer to form a mask layer, wherein the mask layer includes: the metal particles, in which at least some of the metal particles are directly connected to each other; and connected to The conductive carbon material of at least one of the metal particles, and wherein the mask layer extends to the one surface of the substrate and is electrically connected to the ground pattern. 如申請專利範圍第9項所述用於製造半導體封裝的方法,其更包括在所述溶液的所述塗覆之前,在所述模塑層的表面上形成凹陷,以及其中從提供在所述凹陷上的所述遮罩層反射的光的強度弱於從提供在所述凹陷外部的所述遮罩層反射的光的強度。 The method for manufacturing a semiconductor package as described in item 9 of the scope of patent application, which further includes forming a depression on the surface of the molding layer before the coating of the solution, and wherein the method is provided in the The intensity of light reflected by the mask layer on the recess is weaker than the intensity of light reflected from the mask layer provided outside the recess. 如申請專利範圍第9項所述用於製造半導體封裝的方法,更包括:在150攝氏度到300攝氏度的溫度下熱處理所述遮罩層。 As described in item 9 of the scope of patent application, the method for manufacturing a semiconductor package further includes: heat-treating the mask layer at a temperature of 150 degrees Celsius to 300 degrees Celsius. 如申請專利範圍第9項所述用於製造半導體封裝的方法,其更包括在所述模塑層上形成親水性官能團,其中所述溶液具有親水性性質。 As described in item 9 of the scope of patent application, the method for manufacturing a semiconductor package further includes forming a hydrophilic functional group on the molding layer, wherein the solution has hydrophilic properties. 如申請專利範圍第12項所述用於製造半導體封裝的方法,其中所述親水性官能團的所述形成包括在所述模塑層上執行電漿處理過程,其中所述遮罩層更包括親水性聚合物,以及其中所述親水性聚合物提供在所述模塑層與所述導電碳材料之間的間隙中和在所述模塑層與所述金屬粒子之間的間隙中。 The method for manufacturing a semiconductor package as described in claim 12, wherein the formation of the hydrophilic functional group includes performing a plasma treatment process on the molding layer, wherein the mask layer further includes hydrophilic And wherein the hydrophilic polymer is provided in the gap between the molded layer and the conductive carbon material and in the gap between the molded layer and the metal particles. 如申請專利範圍第9項所述用於製造半導體封裝的方法,其中所述基底更包括與所述遮罩層電絕緣的訊號圖案,以及其中所述訊號圖案並不在所述基底的所述一個表面處暴露。 The method for manufacturing a semiconductor package as described in item 9 of the scope of patent application, wherein the substrate further includes a signal pattern electrically insulated from the mask layer, and wherein the signal pattern is not located on the one of the substrates. The surface is exposed. 如申請專利範圍第9項所述用於製造半導體封裝的方法,其中所述金屬粒子包括:第一金屬粒子;以及第二金屬粒子,其具有大於所述第一金屬粒子的高寬比,其中所述第二金屬粒子與所述第一金屬粒子接觸。 According to the method for manufacturing a semiconductor package according to claim 9, wherein the metal particles include: first metal particles; and second metal particles having an aspect ratio greater than that of the first metal particles, wherein The second metal particles are in contact with the first metal particles. 如申請專利範圍第9項所述用於製造半導體封裝的方法,更包括:熱處理所述遮罩層以將所述導電碳材料鍵結到所述金屬粒子,其中所述金屬粒子中的至少一些在所述遮罩層的所述熱處理期間彼此直接連接。 As described in item 9 of the scope of patent application, the method for manufacturing a semiconductor package further includes: heat-treating the mask layer to bond the conductive carbon material to the metal particles, wherein at least some of the metal particles They are directly connected to each other during the heat treatment of the mask layer. 一種半導體封裝,包括:基底,其包括接地結構,所述接地結構在所述基底的一個表面處暴露;半導體晶片,在所述基底上;模塑層,提供在所述基底上,所述模塑層覆蓋所述半導體晶片;以及遮罩層,提供在所述模塑層和所述基底的所述一個表面上,所述遮罩層與所述接地圖案接觸,其中所述遮罩層包括:金屬粒子,其彼此直接連接;以及 導電碳材料,其連接到所述金屬粒子中的至少一個金屬粒子。 A semiconductor package includes: a substrate including a ground structure exposed at one surface of the substrate; a semiconductor wafer on the substrate; a molding layer provided on the substrate, the mold A plastic layer covering the semiconductor wafer; and a mask layer provided on the one surface of the mold layer and the substrate, the mask layer being in contact with the ground pattern, wherein the mask layer includes : Metal particles, which are directly connected to each other; and The conductive carbon material is connected to at least one of the metal particles. 如申請專利範圍第17項所述的半導體封裝,其中所述模塑層的表面具有深度為至少20μm的凹陷,其中所述遮罩層的第一部分提供在所述凹陷外部,其中所述遮罩層的第二部分提供在所述凹陷上,以及其中所述第一遮罩層的所述第一部分的頂部表面與所述第一遮罩層的所述第二部分的頂部表面之間的角度介於130度到160度的範圍。 The semiconductor package according to claim 17, wherein the surface of the molding layer has a recess with a depth of at least 20 μm, wherein the first part of the mask layer is provided outside the recess, wherein the mask The second portion of the layer is provided on the recess, and the angle between the top surface of the first portion of the first mask layer and the top surface of the second portion of the first mask layer It ranges from 130 degrees to 160 degrees. 如申請專利範圍第18項所述的半導體封裝,其中提供在所述凹陷上的所述遮罩層的所述第二部分反射光光的波長不同於從提供在所述凹陷外部的所述遮罩層的所述第一部分反射的光的波長,以及其中所述遮罩層更包括氧化鈦。 The semiconductor package described in claim 18, wherein the second portion of the mask layer provided on the recess has a wavelength different from that of the light reflected from the mask provided outside the recess The wavelength of the light reflected by the first part of the mask layer, and wherein the mask layer further includes titanium oxide. 如申請專利範圍第17項所述的半導體封裝,其中所述金屬粒子包括:第一粒子;以及第二粒子,其具有大於所述第一粒子的高寬比,其中所述第二粒子接觸所述第一粒子。 The semiconductor package according to claim 17, wherein the metal particles include: a first particle; and a second particle having an aspect ratio greater than that of the first particle, wherein the second particle contacts the The first particle. 如申請專利範圍第17項所述的半導體封裝,其中所述導電碳材料共價鍵結到所述金屬粒子中的至少一個金屬粒子,以及其中所述金屬粒子中的至少兩者彼此聚集。 The semiconductor package according to claim 17, wherein the conductive carbon material is covalently bonded to at least one metal particle among the metal particles, and wherein at least two of the metal particles aggregate with each other. 如申請專利範圍第17項所述的半導體封裝,其中所述基底更包括:安置其中的訊號圖案,其中所述訊號圖案與所述遮罩層電絕緣。 According to the semiconductor package described in claim 17, wherein the substrate further includes: a signal pattern disposed therein, wherein the signal pattern is electrically insulated from the mask layer. 如申請專利範圍第17項所述的半導體封裝,其中所述基底的所述一個表面包括所述基底的側壁,以及其中所述半導體晶片與所述模塑層安置在所述基底的頂部表面上。 The semiconductor package according to claim 17, wherein the one surface of the substrate includes a sidewall of the substrate, and wherein the semiconductor wafer and the mold layer are disposed on the top surface of the substrate . 如申請專利範圍第17項所述的半導體封裝,其中所述基底的所述一個表面包括所述基底的底部表面,以及其中所述半導體晶片與所述模塑層安置在所述基底的頂部表面上。 The semiconductor package according to claim 17, wherein the one surface of the substrate includes the bottom surface of the substrate, and wherein the semiconductor wafer and the mold layer are disposed on the top surface of the substrate superior. 如申請專利範圍第17項所述的半導體封裝,其中所述模塑層安置在所述基底的所述一個表面上且暴露出所述接地結構的至少一部分。The semiconductor package according to claim 17, wherein the molding layer is disposed on the one surface of the substrate and exposes at least a part of the ground structure.
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