TWI737615B - Apparatus for treating exhaust gas comprising hydrogen - Google Patents

Apparatus for treating exhaust gas comprising hydrogen Download PDF

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TWI737615B
TWI737615B TW105118177A TW105118177A TWI737615B TW I737615 B TWI737615 B TW I737615B TW 105118177 A TW105118177 A TW 105118177A TW 105118177 A TW105118177 A TW 105118177A TW I737615 B TWI737615 B TW I737615B
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hydrogen
exhaust gas
treatment device
treatment
containing exhaust
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TW201707771A (en
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朴商權
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南韓商圓益Ips股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/869Multiple step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
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    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/20784Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2255/20Metals or compounds thereof
    • B01D2255/209Other metals
    • B01D2255/2092Aluminium

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  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
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Abstract

本發明公開一種含氫廢氣處理裝置。本發明涉及的含氫廢氣處理裝置的特徵在於,包括:處理部,其至少一側連接有供半導體表面改性工藝中產生的含氫廢氣流入的含氫廢氣流入管以及供含氧空氣流入的含氧空氣流入管,並且所述處理部包括多個催化劑載體部,所述催化劑載體部包含與含氫廢氣發生催化反應的催化劑。 The invention discloses a hydrogen-containing waste gas treatment device. The hydrogen-containing waste gas treatment device according to the present invention is characterized by comprising: a treatment part, at least one side of which is connected with a hydrogen-containing waste gas inflow pipe into which the hydrogen-containing waste gas generated in the semiconductor surface modification process flows, and an oxygen-containing air inflow tube. The oxygen-containing air flows into the pipe, and the processing part includes a plurality of catalyst carrier parts containing a catalyst that catalytically reacts with the hydrogen-containing exhaust gas.

Description

含氫廢氣處理裝置 Hydrogen-containing waste gas treatment device 發明領域 Field of invention

本發明涉及一種含氫廢氣處理裝置。具體而言,涉及一種通過催化反應能夠處理在半導體表面改性工藝中產生的含氫廢氣的含氫廢氣處理裝置。 The invention relates to a hydrogen-containing waste gas treatment device. Specifically, it relates to a hydrogen-containing exhaust gas treatment device capable of treating hydrogen-containing exhaust gas generated in a semiconductor surface modification process through a catalytic reaction.

發明背景 Background of the invention

在半導體製造工藝中的諸如擴散氧化工藝的表面改性工藝中,為了形成必要的薄膜而使用氫氣、氮氣、氨氣等。其中,氫氣在大約4~75%時會被點燃,因此如果直接排放到大氣中時,可能引起爆炸。因此,需降低廢氣中氫氣的濃度。 In a surface modification process such as a diffusion oxidation process in a semiconductor manufacturing process, hydrogen, nitrogen, ammonia, etc. are used in order to form necessary thin films. Among them, hydrogen will be ignited at about 4~75%, so if it is directly discharged into the atmosphere, it may cause an explosion. Therefore, it is necessary to reduce the concentration of hydrogen in the exhaust gas.

以往含氫廢氣的處理方法包括利用熱量的燃燒法、利用水的濕法等。燃燒法是指在1000℃以上的超高溫條件下燃燒氫氣而處理氫氣的方法,濕法是指噴射大量的水,以使一部分氫氣溶解,從而處理氫氣的方法,由於燃燒法比濕法的處理效率高,因此主要採用燃燒法。 Conventional methods for treating hydrogen-containing waste gas include a combustion method using heat, a wet method using water, and the like. Combustion method refers to a method of burning hydrogen at an ultra-high temperature above 1000°C to process hydrogen. Wet method refers to a method of injecting a large amount of water to dissolve a part of hydrogen to process hydrogen. Because the combustion method is better than wet processing The efficiency is high, so the combustion method is mainly used.

圖1是示出利用現有的燃燒法的含氫廢氣處理裝置20的側視圖。 FIG. 1 is a side view showing a hydrogen-containing exhaust gas treatment device 20 using a conventional combustion method.

參照圖1,半導體處理裝置10的氣體排放部11連接至含氫廢氣處理裝置20,因此含氫廢氣HG能夠流入腔體內部。在腔體內部,為了燃燒而瞬間產生高溫熱量的點燃部21與氣體排放部11相鄰。並且,通過工藝氣體供給管25,可以由外部的工藝氣體供給裝置供給燃燒含氫廢氣HG所需的氧氣等工藝氣體OG。完成氫氣處理工藝後,包含水蒸氣等的排放氣體可以通過排放部26排放到外部。 1, the gas discharge part 11 of the semiconductor processing device 10 is connected to the hydrogen-containing exhaust gas processing device 20, so the hydrogen-containing exhaust gas HG can flow into the cavity. Inside the cavity, the ignition part 21 that instantly generates high-temperature heat for combustion is adjacent to the gas discharge part 11. In addition, through the process gas supply pipe 25, a process gas OG such as oxygen required for combusting the hydrogen-containing exhaust gas HG can be supplied from an external process gas supply device. After the hydrogen treatment process is completed, exhaust gas including water vapor and the like may be discharged to the outside through the exhaust part 26.

如上所述的現有的含氫廢氣處理裝置20具有能夠以高效率處理氫氣的優點,但是在含氫廢氣HG的濃度由高變低時,不發生燃燒或變得不穩定,存在含氫廢氣HG中的氫氣未經處理就直接被排放到外部的問題。並且,由於採用燃燒,因此一直存在裝置內部的爆炸危險,並且需要始終以高溫維持腔體內部,因此存在工藝成本增加,難以維護、管理加熱器的問題。 The conventional hydrogen-containing exhaust gas treatment device 20 as described above has the advantage of being able to treat hydrogen with high efficiency. However, when the concentration of the hydrogen-containing exhaust gas HG changes from high to low, combustion does not occur or becomes unstable, and there is hydrogen-containing exhaust gas HG. The problem that the hydrogen in the gas is directly discharged to the outside without treatment. In addition, due to the use of combustion, there is always a danger of explosion inside the device, and it is necessary to maintain the inside of the cavity at a high temperature at all times. Therefore, there are problems that the process cost increases and it is difficult to maintain and manage the heater.

發明概要 Summary of the invention

本發明是為了解決上述問題而提出的,其目的在於提供一種含氫廢氣處理裝置,能夠與含氫廢氣濃度無關地執行氫氣處理工藝。 The present invention is proposed to solve the above-mentioned problems, and its purpose is to provide a hydrogen-containing waste gas treatment device that can perform a hydrogen treatment process regardless of the concentration of the hydrogen-containing waste gas.

另外,本發明的目的在於提供一種含氫廢氣處理裝置,使含氫廢氣的氫氣處理效率最大化。 In addition, an object of the present invention is to provide a hydrogen-containing waste gas treatment device that maximizes the hydrogen treatment efficiency of hydrogen-containing waste gas.

另外,本發明的目的在於提供一種含氫廢氣處理裝置,提高裝置的耐久性,減少工藝成本,並且在氫氣處理 工藝中能夠減少危險發生要素。 In addition, the object of the present invention is to provide a hydrogen-containing waste gas treatment device, which improves the durability of the device, reduces the process cost, and is used in hydrogen treatment. The process can reduce the risk factors.

為了達成上述目的,本發明的一實施例涉及的含氫廢氣處理裝置的特徵在於,包括:處理部,其至少一側連接有供半導體表面改性工藝中產生的含氫廢氣流入的含氫廢氣流入管以及供含氧空氣流入的含氧空氣流入管,並且所述處理部包括多個催化劑載體部,所述催化劑載體部包含與所述含氫廢氣發生催化反應的催化劑。 In order to achieve the above object, a hydrogen-containing waste gas treatment device according to an embodiment of the present invention is characterized by comprising: a treatment part connected to at least one side of the hydrogen-containing waste gas into which the hydrogen-containing waste gas generated in the semiconductor surface modification process flows. An inflow pipe and an oxygen-containing air inflow pipe into which the oxygen-containing air flows, and the processing part includes a plurality of catalyst carrier parts, and the catalyst carrier part contains a catalyst that catalytically reacts with the hydrogen-containing exhaust gas.

根據按照上述構成的本發明,其效果在於,與含氫廢氣的濃度無關地執行氫氣處理工藝。 According to the present invention constructed as described above, the effect is that the hydrogen treatment process is performed regardless of the concentration of the hydrogen-containing exhaust gas.

另外,本發明的效果在於,可以使含氫廢氣的氫氣處理效率最大化。 In addition, the effect of the present invention is that the hydrogen treatment efficiency of hydrogen-containing exhaust gas can be maximized.

另外,本發明的效果在於,提高裝置的耐久性,減少工藝成本,並且在氫氣處理工藝中能夠減少危險發生要素。 In addition, the effect of the present invention is to improve the durability of the device, reduce process costs, and reduce risk factors in the hydrogen treatment process.

10、100‧‧‧半導體處理裝置 10, 100‧‧‧Semiconductor processing equipment

11‧‧‧氣體排放部 11‧‧‧Air Emissions Department

20、200‧‧‧含氫廢氣處理裝置 20, 200‧‧‧Hydrogen-containing waste gas treatment device

21‧‧‧點燃部 21‧‧‧Lighting Department

25‧‧‧工藝氣體供給管 25‧‧‧Process gas supply pipe

26‧‧‧排放部 26‧‧‧Emissions Department

110‧‧‧含氫廢氣流入管 110‧‧‧Hydrogen-containing waste gas inflow pipe

210‧‧‧第一處理部 210‧‧‧First Processing Department

211‧‧‧氣體流入部 211‧‧‧Gas inflow part

212‧‧‧導入部 212‧‧‧Introduction Department

213、213a、213b‧‧‧混合板 213、213a、213b‧‧‧Mixed board

214、214a、214b‧‧‧混合口 214, 214a, 214b‧‧‧mixing port

215‧‧‧反應部 215‧‧‧Reaction Department

216、256、256a、256b‧‧‧催化劑載體部 216, 256, 256a, 256b‧‧‧Catalyst carrier part

217、257、257a、257b‧‧‧催化過濾部 217, 257, 257a, 257b‧‧‧Catalytic filter

218、258、258a、258b‧‧‧催化反應部 218, 258, 258a, 258b‧‧‧Catalytic reaction section

230‧‧‧含氧空氣供給部 230‧‧‧Oxygenated air supply unit

231‧‧‧含氧空氣流入管 231‧‧‧Oxygenated air inlet pipe

240‧‧‧第一排水口 240‧‧‧First drain

250‧‧‧第二處理部 250‧‧‧Second Processing Department

260‧‧‧排出口 260‧‧‧Exhaust outlet

270‧‧‧吹掃用氣體流入管 270‧‧‧Purge gas inlet pipe

275‧‧‧空氣流入管 275‧‧‧Air inflow pipe

280‧‧‧冷卻單元 280‧‧‧cooling unit

290‧‧‧第二排水口 290‧‧‧Second drain

A‧‧‧含氧空氣 A‧‧‧Oxygenated air

HG、HG1、HG2、HG3‧‧‧含氫廢氣 HG, HG1, HG2, HG3‧‧‧Hydrogen-containing waste gas

OG‧‧‧工藝氣體 OG‧‧‧Process gas

P‧‧‧吹掃用氣體 P‧‧‧Purge gas

RA‧‧‧空氣 RA‧‧‧Air

W‧‧‧被冷凝的水蒸氣、水 W‧‧‧Condensed water vapor, water

圖1是示出利用現有的燃燒法的含氫廢氣處理裝置的側視圖。 Fig. 1 is a side view showing a hydrogen-containing exhaust gas treatment device using a conventional combustion method.

圖2是示出本發明的一實施例涉及的含氫廢氣處理裝置的整體結構的側視圖。 Fig. 2 is a side view showing the overall structure of a hydrogen-containing exhaust gas treatment device according to an embodiment of the present invention.

圖3是示出本發明的一實施例涉及的第一處理部的側視圖。 Fig. 3 is a side view showing a first processing unit according to an embodiment of the present invention.

圖4是示出本發明的一實施例涉及的混合板的俯視圖。 Fig. 4 is a plan view showing a mixing plate according to an embodiment of the present invention.

圖5是示出本發明的一實施例涉及的反應部的俯視圖。 Fig. 5 is a plan view showing a reaction unit according to an embodiment of the present invention.

詳細說明 Detailed description

後述的對於本發明的詳細說明參照將能夠實施本發明的特定實施例作為示例示出的附圖。這些實施例的詳細說明,使本領域的技術人員能夠充分地實施本發明。應當理解,本發明的各種實施例雖然彼此不同,但是無需相互排斥。例如,這裡所記載的特定形狀、結構以及特性與一實施例相關,在不超出本發明的精神以及範圍的情況下,可以由其他實施例實現。另外,應當理解,對於各個公開的實施例內的個別結構要素的位置或配置,在不超出本發明的精神以及範圍的情況下能夠變更。因此,後述的詳細說明並非旨在限定本發明,本發明的保護範圍僅由所附的申請專利範圍及其等同的所有範圍限定。在附圖中相似的附圖標記在多方面指示相同或相似的功能,為了方便起見,長度以及面積、厚度等和其形狀有可能被誇大示出。 The detailed description of the present invention described later refers to the accompanying drawings showing specific embodiments capable of implementing the present invention as examples. The detailed description of these embodiments enables those skilled in the art to fully implement the present invention. It should be understood that, although the various embodiments of the present invention are different from each other, they need not be mutually exclusive. For example, the specific shapes, structures, and characteristics described herein are related to one embodiment, and can be implemented by other embodiments without departing from the spirit and scope of the present invention. In addition, it should be understood that the position or arrangement of individual structural elements in each disclosed embodiment can be changed without departing from the spirit and scope of the present invention. Therefore, the following detailed description is not intended to limit the present invention, and the protection scope of the present invention is only limited by the scope of the attached patent application and all equivalent scopes. Similar reference numerals in the drawings indicate the same or similar functions in many aspects. For convenience, the length, area, thickness, etc., and the shape thereof may be exaggeratedly shown.

另外,本說明書中的氫氣處理工藝可以理解為包括全部的如下所述的連續工藝,即將包含於含氫廢氣內的氫氣轉換為水蒸氣等其它物質以降低氫氣濃度。 In addition, the hydrogen treatment process in this specification can be understood to include all the continuous processes described below, that is, converting the hydrogen contained in the hydrogen-containing waste gas into other substances such as water vapor to reduce the hydrogen concentration.

另外,本說明書闡述了含氫廢氣處理裝置除了半導體處理裝置以外,還可以用於對核能發電冷卻堆中生成的氫氣的處理、汽車消音器的廢氣處理等領域中。 In addition, this specification explains that in addition to semiconductor processing devices, hydrogen-containing exhaust gas treatment devices can also be used in fields such as the treatment of hydrogen generated in nuclear power generation cooling reactors, and the treatment of exhaust gas from automobile mufflers.

下面,將參照附圖詳細說明本發明的實施例涉及的含氫廢氣處理裝置。 Hereinafter, the hydrogen-containing waste gas treatment device according to the embodiment of the present invention will be described in detail with reference to the drawings.

圖2是示出本發明的一實施例涉及的含氫廢氣處理裝 置200的整體結構的側視圖,圖3是示出本發明的一實施例涉及的第一處理部210的側視圖。 Figure 2 shows a hydrogen-containing waste gas treatment device according to an embodiment of the present invention A side view of the overall structure of the device 200, and FIG. 3 is a side view showing the first processing unit 210 according to an embodiment of the present invention.

參照圖2以及圖3,本實施例涉及的含氫廢氣處理裝置200可以包括處理部210、250。 Referring to FIGS. 2 and 3, the hydrogen-containing exhaust gas treatment device 200 according to this embodiment may include treatment parts 210 and 250.

處理部210、250可以包括多個催化劑載體部216、256,各個催化劑載體部216、256包括與含氫廢氣HG發生催化反應的催化劑。處理部可以包括位於下部的第一處理部210和位於上部的第二處理部250。 The treatment parts 210 and 250 may include a plurality of catalyst carrier parts 216 and 256, and each of the catalyst carrier parts 216 and 256 includes a catalyst for catalytically reacting with the hydrogen-containing exhaust gas HG. The processing part may include a first processing part 210 located in the lower part and a second processing part 250 located in the upper part.

第一處理部210可以提供能夠有效率地處理含氫廢氣HG中的高濃度氫氣的空間,第二處理部250可以提供能夠有效率地處理經第一處理部210處理相當部分氫氣的含氫廢氣HG1中的低濃度氫氣的空間。 The first processing unit 210 can provide a space capable of efficiently processing high-concentration hydrogen in the hydrogen-containing exhaust gas HG, and the second processing unit 250 can provide a hydrogen-containing exhaust gas capable of efficiently processing a considerable part of the hydrogen in the first processing unit 210 The space of low-concentration hydrogen in HG1.

在半導體處理裝置100內,由於半導體表面改性工藝等而產生含氫廢氣HG,其可以通過半導體處理裝置100的氣體排放部(附圖標記未圖示)排放。並且,含氫廢氣HG可以通過含氫廢氣流入管110流入到第一處理部210內部,所述含氫廢氣流入管110的一端與氣體排放部相連,另一端與第一處理部210的一側相連。 In the semiconductor processing apparatus 100, hydrogen-containing exhaust gas HG is generated due to a semiconductor surface modification process or the like, which can be discharged through a gas discharge part (reference numeral not shown) of the semiconductor processing apparatus 100. In addition, the hydrogen-containing waste gas HG can flow into the first treatment part 210 through the hydrogen-containing waste gas inflow pipe 110. One end of the hydrogen-containing waste gas inflow pipe 110 is connected to the gas discharge part, and the other end is connected to one side of the first treatment part 210. Connected.

另外,為了在第一處理部210內部控制與含氫廢氣HG的反應性、氫氣濃度,還可以流入其它工藝氣體,而在本發明中,可以流入包含氧氣的空氣A(含氧空氣A)。含氧空氣A可以通過連接於第一處理部210一側的含氧空氣流入管231,由外部的含氧空氣供給部230供給到第一處理部210內部。 In addition, in order to control the reactivity with the hydrogen-containing exhaust gas HG and the hydrogen concentration in the first processing unit 210, other process gases may be flowed. In the present invention, oxygen-containing air A (oxygen-containing air A) may be flowed. The oxygen-containing air A can be supplied to the inside of the first processing portion 210 from the external oxygen-containing air supply portion 230 through the oxygen-containing air inflow pipe 231 connected to the side of the first processing portion 210.

第一處理部210可以被分隔為氣體流入部211以及反應部215,所述氣體流入部211位於下部,以供含氫廢氣HG和含氧空氣A流入並混合,所述反應部215位於上部,並且配置有多個催化劑載體部216。當然,含氫廢氣流入管110和含氧空氣流入管231應該連接於氣體流入口211的一側。 The first processing part 210 may be divided into a gas inflow part 211 and a reaction part 215. The gas inflow part 211 is located at the lower part for the inflow and mixing of the hydrogen-containing waste gas HG and the oxygen-containing air A. The reaction part 215 is located at the upper part. In addition, a plurality of catalyst carrier portions 216 are arranged. Of course, the hydrogen-containing exhaust gas inflow pipe 110 and the oxygen-containing air inflow pipe 231 should be connected to one side of the gas inflow port 211.

圖4是示出本發明的一實施例涉及的混合板213的俯視圖。 Fig. 4 is a plan view showing a mixing plate 213 according to an embodiment of the present invention.

參照圖2至圖4,氣體流入部211可以包括導入部212和多個混合板213(213a、213b)。 2 to 4, the gas inflow part 211 may include an introduction part 212 and a plurality of mixing plates 213 (213a, 213b).

導入部212可以提供含氫廢氣HG以及含氧空氣A的流入空間,所述含氫廢氣HG以及含氧空氣A從含氫廢氣流入管110和含氧空氣流入管231流入。在導入部212中可以第一次混合含氫廢氣HG以及含氧空氣A。 The introduction part 212 may provide an inflow space for the hydrogen-containing exhaust gas HG and the oxygen-containing air A, which flow in from the hydrogen-containing exhaust gas inflow pipe 110 and the oxygen-containing air inflow pipe 231. In the introduction part 212, the hydrogen-containing exhaust gas HG and the oxygen-containing air A can be mixed for the first time.

多個混合板213(213a、213b)可以以沿垂直方向彼此隔著間距的方式,沿水平方向配置在導入部212上。在混合板213上可以沿著橫向以及縱向形成多個混合口214a、214b。雖然示出的混合板213為213a和213b兩個,但是也可以是其以上,還可以適當地調節混合口214a、214b的數量。 The plurality of mixing plates 213 (213a, 213b) may be arranged on the introduction part 212 in the horizontal direction so as to be spaced apart from each other in the vertical direction. A plurality of mixing ports 214a and 214b may be formed on the mixing plate 213 along the transverse direction and the longitudinal direction. Although two mixing plates 213 are shown as 213a and 213b, there may be more than that, and the number of mixing ports 214a and 214b can also be adjusted appropriately.

已經在導入部212第一次混合的含氫廢氣HG以及含氧空氣A在通過混合板213的混合口214a、214b並且上升移動的過程中,可以更好地發生第二次混合。這樣,均勻混合的氣體能夠向反應部215移動。 The hydrogen-containing waste gas HG and the oxygen-containing air A that have been mixed for the first time in the introduction part 212 may be better mixed for the second time during the process of passing through the mixing ports 214a and 214b of the mixing plate 213 and moving upward. In this way, the uniformly mixed gas can move to the reaction part 215.

特別是有必要延長流路,以使含氫廢氣HG以及含氧空氣A更好地混合。為此,優選使沿著橫向以及縱向形成在各 個混合板213a和213b上的多個混合口214a和214b相互錯開形成。圖4的(a)和圖4的(b)示出位於下部的混合板213a的混合口214a與位於上部的混合板213b的混合口214b相互錯開形成的結構。即,由於混合口214a、214b形成為不佔據同一垂直軸上的空間,因此具有可以延長流路的優點。 In particular, it is necessary to extend the flow path to better mix the hydrogen-containing exhaust gas HG and the oxygen-containing air A. For this reason, it is preferable to form in each of the horizontal and vertical directions The multiple mixing ports 214a and 214b on the two mixing plates 213a and 213b are formed staggered from each other. 4(a) and 4(b) show a structure in which the mixing port 214a of the lower mixing plate 213a and the mixing port 214b of the upper mixing plate 213b are offset from each other. That is, since the mixing ports 214a and 214b are formed so as not to occupy the space on the same vertical axis, there is an advantage that the flow path can be extended.

反應部215位於氣體流入部211或混合板213的上部,可以包括多個催化劑載體部216。催化劑載體部216包括可以與含氫廢氣HG所包含的氫氣發生催化反應的催化劑。可以發生如下催化反應,即含氫廢氣HG內的氫氣和含氧空氣A內的氧氣與催化劑載體部216的催化劑接觸,形成為自由基(radical),並且形成為自由基的氫氣與氧氣發生反應生成水蒸氣(或水)。從而可以處理(除去)氫氣。 The reaction part 215 is located at the upper part of the gas inflow part 211 or the mixing plate 213 and may include a plurality of catalyst carrier parts 216. The catalyst carrier part 216 includes a catalyst that can catalytically react with the hydrogen contained in the hydrogen-containing exhaust gas HG. The following catalytic reaction can occur, that is, the hydrogen in the hydrogen-containing exhaust gas HG and the oxygen in the oxygen-containing air A contact the catalyst of the catalyst carrier part 216 to form radicals, and the hydrogen formed as radicals react with oxygen. This produces water vapor (or water). Thus, hydrogen can be processed (removed).

大約在500℃下執行催化反應,在催化反應過程中生成的一部分水蒸氣可以被冷凝。被冷凝的水蒸氣w(或水w)可以通過連接於第一處理部210的一側的第一排水口240向外部排放。 The catalytic reaction is performed at approximately 500°C, and a part of the water vapor generated during the catalytic reaction can be condensed. The condensed water vapor w (or water w) may be discharged to the outside through the first drain port 240 connected to one side of the first treatment part 210.

催化劑載體部216可以是其自身為催化金屬,也可以是在一部分上塗布催化金屬而成。另一方面,鑒於用作催化劑的物質大都昂貴這一點,催化劑載體部216優選在廉價的金屬或陶瓷的表面塗布催化金屬。塗布在催化劑載體部216的至少一部分上的催化金屬可以採用鉑(Pt)、釕(Ru)、銠(Rh)、銥(Ir)、鋨(Os)等的鉑類金屬和鋁(Al)、鉻(Cr)、銅(Cu)等。 The catalyst carrier part 216 may be a catalyst metal itself, or may be formed by coating a part of the catalyst metal. On the other hand, in view of the fact that most of the materials used as catalysts are expensive, the catalyst carrier part 216 preferably coats the surface of an inexpensive metal or ceramic with a catalytic metal. The catalytic metal coated on at least a part of the catalyst carrier portion 216 can be platinum (Pt), ruthenium (Ru), rhodium (Rh), iridium (Ir), osmium (Os), and other platinum-based metals and aluminum (Al), Chromium (Cr), copper (Cu), etc.

本發明的特徵在於,在第一處理部210(或反應部215) 中沿著水平方向配置催化劑載體部216。 The present invention is characterized in that in the first processing section 210 (or reaction section 215) The catalyst carrier portion 216 is arranged along the horizontal direction.

優選將第一處理部210設計成水平面積大於後述的第二處理部250。由於第一處理部210的水平面積大於第二處理部250,並且在第一處理部210(或反應部215)內沿水平方向配置催化劑載體部216,因此從氣體流入部211上升移動的含氫廢氣HG以及含氧空氣A在被大範圍、均勻分散的狀態下與多個催化劑載體部216接觸,從而可以執行氫氣處理。因而可以在第一處理部210中有效率地處理含氫廢氣HG中的高濃度氫氣。在第一處理部210內可以處理含氫廢氣HG中的大約95%的氫氣。 Preferably, the first processing unit 210 is designed to have a larger horizontal area than the second processing unit 250 described later. Since the horizontal area of the first treatment part 210 is larger than that of the second treatment part 250, and the catalyst carrier part 216 is arranged in the horizontal direction in the first treatment part 210 (or the reaction part 215), the hydrogen that moves up from the gas inflow part 211 contains hydrogen. The exhaust gas HG and the oxygen-containing air A are in contact with the plurality of catalyst carrier portions 216 in a state where they are uniformly dispersed in a wide range, so that hydrogen treatment can be performed. Therefore, the high-concentration hydrogen in the hydrogen-containing exhaust gas HG can be efficiently processed in the first processing unit 210. About 95% of the hydrogen in the hydrogen-containing waste gas HG can be processed in the first processing part 210.

圖5是示出本發明的一實施例涉及的反應部215的俯視圖。 FIG. 5 is a plan view showing the reaction unit 215 according to an embodiment of the present invention.

參照圖3以及圖5,催化劑載體部216可以佔據反應部215內的幾乎全部空間。各個催化劑載體部216可以包括催化過濾部217以及催化反應部218。 Referring to FIGS. 3 and 5, the catalyst carrier part 216 can occupy almost all the space in the reaction part 215. Each catalyst carrier part 216 may include a catalytic filter part 217 and a catalytic reaction part 218.

催化過濾部217可以發揮催化反應部218的支撐體作用,同時提供可以使與催化劑載體部216接觸的含氫廢氣HG發生催化反應的較寬廣的表面積。為了提供寬廣的表面積,催化過濾部217可以具有在多孔性的金屬或陶瓷上塗布有催化金屬的形狀。催化過濾部217的厚度優選小於催化反應部218。 The catalytic filter part 217 can function as a support of the catalytic reaction part 218 and at the same time provide a wide surface area that can cause the hydrogen-containing exhaust gas HG in contact with the catalyst carrier part 216 to undergo a catalytic reaction. In order to provide a wide surface area, the catalytic filter part 217 may have a shape in which a porous metal or ceramic is coated with catalytic metal. The thickness of the catalytic filter part 217 is preferably smaller than that of the catalytic reaction part 218.

催化反應部218配置於催化過濾部217上,可以提供能夠更加順利地發生催化反應的空間。催化反應部218可以是在金屬或陶瓷上塗布有催化金屬的狀態,所述金屬或陶瓷 具有沿垂直方向形成中孔的蜂巢(honeycomb)(或正六棱柱)結構。經由催化過濾部217的含氫廢氣HG以及含氧空氣A在通過沿蜂巢結構的垂直方向形成的中孔並且上升移動的過程中,能夠與塗布於內側壁上的催化金屬接觸並發生催化反應。並且,催化反應部218由於具有提供最大表面積的蜂巢結構,所以具有可以使催化反應的效率極大化的優點。 The catalytic reaction part 218 is disposed on the catalytic filter part 217 and can provide a space where the catalytic reaction can occur more smoothly. The catalytic reaction part 218 may be in a state where a catalytic metal is coated on a metal or ceramic, the metal or ceramic It has a honeycomb (or regular hexagonal prism) structure with mesopores formed in the vertical direction. The hydrogen-containing exhaust gas HG and the oxygen-containing air A passing through the catalytic filter part 217 can contact the catalytic metal coated on the inner sidewall and undergo a catalytic reaction during the process of passing through the mesopores formed in the vertical direction of the honeycomb structure and moving upward. In addition, since the catalytic reaction part 218 has a honeycomb structure that provides the largest surface area, it has an advantage that the efficiency of the catalytic reaction can be maximized.

為了使催化反應更加順利地發生,優選蜂巢結構的直徑不超過4mm。但是,直徑並非必須限定於此,可以根據需要處理的含氫廢氣HG的量、濃度、目標處理濃度等來適當地調節。另外,除了蜂巢結構以外,在增加接觸面積的目的範圍內,可以採用其它結構。 In order to make the catalytic reaction occur more smoothly, it is preferable that the diameter of the honeycomb structure does not exceed 4 mm. However, the diameter is not necessarily limited to this, and can be appropriately adjusted according to the amount, concentration, target treatment concentration, etc. of the hydrogen-containing waste gas HG to be treated. In addition, in addition to the honeycomb structure, other structures may be adopted within the scope of the purpose of increasing the contact area.

當催化過濾部217與催化反應部218達到使用極限時,則通過分解一部分反應部215或者通過用於維護/管理的檢修門(未圖示)易於更換。 When the catalytic filter part 217 and the catalytic reaction part 218 reach the limit of use, they can be easily replaced by decomposing a part of the reaction part 215 or through an access door (not shown) for maintenance/management.

本發明的特徵在於,在第一處理部210的上部可以連通地配置第二處理部250。並且,第二處理部250的特徵在於,包括沿垂直方向配置的至少一個催化劑載體部256(256a、256b)。 The present invention is characterized in that the second processing unit 250 can be connected to be disposed on the upper portion of the first processing unit 210. In addition, the second processing section 250 is characterized by including at least one catalyst carrier section 256 (256a, 256b) arranged in a vertical direction.

再次參照圖2以及圖3,經由第一處理部210的含氫廢氣HG中,相當一部分氫氣被催化反應處理。處理大約95%的氫氣後包含剩餘大約5%的氫氣的含氫廢氣HG1繼續向上部移動,從而能夠進入到第二處理部250內。 2 and 3 again, in the hydrogen-containing exhaust gas HG passing through the first processing unit 210, a considerable part of the hydrogen is processed by the catalytic reaction. After processing about 95% of the hydrogen, the hydrogen-containing waste gas HG1, which contains about 5% of the remaining hydrogen, continues to move upward, so as to enter the second processing part 250.

第二處理部250對氫濃度低於第一處理部210的含氫廢氣HG1進行處理,因此無需具有如同第一處理部210寬廣的 水平面積。換言之,在對包含高濃度氫氣的含氫廢氣HG進行處理的第一處理部210中,需沿著水平方向配置多個催化劑載體部216,以處理大量的氫氣,但是在對包含低濃度氫氣的含氫廢氣HG1進行處理的第二處理部250中,則可以沿著垂直方向配置至少一個催化劑載體部256(256a、256b),以集中處理少量的氫氣而完成氫氣處理工藝。雖然圖2示出在第二處理部250上配置兩個催化劑載體部256a、256b的情形,但是根據工藝環境,可以配置一個或三個以上。 The second treatment part 250 processes the hydrogen-containing waste gas HG1 whose hydrogen concentration is lower than that of the first treatment part 210, so there is no need to have the same width as the first treatment part 210. Horizontal area. In other words, in the first processing section 210 for processing hydrogen-containing exhaust gas HG containing high-concentration hydrogen, it is necessary to arrange a plurality of catalyst carrier sections 216 in the horizontal direction to treat a large amount of hydrogen. In the second processing section 250 where the hydrogen-containing exhaust gas HG1 is processed, at least one catalyst carrier section 256 (256a, 256b) may be arranged along the vertical direction to centrally process a small amount of hydrogen to complete the hydrogen treatment process. Although FIG. 2 shows a case where two catalyst carrier parts 256a and 256b are arranged on the second processing part 250, one or more than three may be arranged according to the process environment.

與第一處理部210的催化劑載體部216同樣,第二處理部250的催化劑載體部256也可以包括催化過濾部257(257a、257b)以及催化反應部258(258a、258b)。由於催化過濾部257與催化反應部258的結構以及功能與第一處理部210的催化過濾部217以及催化反應部218相同,因此省略具體的說明。 Like the catalyst carrier section 216 of the first treatment section 210, the catalyst carrier section 256 of the second treatment section 250 may also include a catalytic filter section 257 (257a, 257b) and a catalytic reaction section 258 (258a, 258b). Since the structure and function of the catalytic filter unit 257 and the catalytic reaction unit 258 are the same as the catalytic filter unit 217 and the catalytic reaction unit 218 of the first processing unit 210, detailed descriptions are omitted.

含氫廢氣HG1在經由沿著第二處理部250的垂直方向配置的催化劑載體部256並且上升移動的過程中,與催化金屬接觸並發生催化反應,從第二處理部250排出的含氫廢氣HG2可以包含燃燒範圍以下(小於等於4%),優選小於等於0.1%的氫氣。 The hydrogen-containing exhaust gas HG1 is in contact with the catalytic metal and undergoes a catalytic reaction during the upward movement through the catalyst carrier portion 256 arranged in the vertical direction of the second processing portion 250, and the hydrogen-containing exhaust gas HG2 discharged from the second processing portion 250 It may contain hydrogen in the combustion range or less (4% or less), preferably 0.1% or less.

進一步參照圖2,在第二處理部250的上部與排出口260之間還可以設置有吹掃用氣體流入管270。吹掃用氣體流入管270從外部的吹掃用氣體供給部(未圖示)接收吹掃用氣體P後向第二處理部250的上部供給,從而進一步稀釋從第二處理部250排出的含氫廢氣HG2,同時可以增加朝向排出口 260的移動力。 Further referring to FIG. 2, a purge gas inflow pipe 270 may also be provided between the upper portion of the second processing part 250 and the discharge port 260. The purge gas inflow pipe 270 receives the purge gas P from an external purge gas supply part (not shown) and supplies it to the upper part of the second treatment part 250 to further dilute the content discharged from the second treatment part 250 Hydrogen waste gas HG2, at the same time can be increased towards the discharge port 260 mobile power.

第二處理部250的上部與排出口260之間還可以設置有用於冷卻含氫廢氣HG2的冷卻單元280。冷卻單元280可以無限制地使用圍繞第二處理部250的上部與排出口260之間的配管的冷卻管或冷阱(cold trap)等。 A cooling unit 280 for cooling the hydrogen-containing waste gas HG2 may also be provided between the upper portion of the second processing part 250 and the discharge port 260. The cooling unit 280 can use a cooling pipe or a cold trap surrounding the piping between the upper portion of the second processing part 250 and the discharge port 260 without limitation.

含氫廢氣HG2朝向排出口260方向移動,並且可以使一部分水蒸氣自然冷凝,或者被冷卻單元280所冷凝。被冷凝的水蒸氣w(或水w)可以通過連接於第二處理部250的上部與排出口260之間的第二排水口290向外部排出。 The hydrogen-containing waste gas HG2 moves toward the discharge port 260, and can cause a part of the water vapor to be condensed naturally, or be condensed by the cooling unit 280. The condensed water vapor w (or water w) may be discharged to the outside through the second drain port 290 connected between the upper portion of the second processing part 250 and the discharge port 260.

第二處理部250的上部與排出口260之間還可以設置有空氣流入管275。在通過排出口260向外部排放含氫廢氣HG2之前,空氣流入管275使空氣(room air:室內空氣)流入,從而可以通過排出口260排放使濃度進一步稀釋的含氫廢氣HG3。 An air inflow pipe 275 may also be provided between the upper portion of the second processing part 250 and the discharge port 260. Before the hydrogen-containing exhaust gas HG2 is discharged to the outside through the exhaust port 260, the air inflow pipe 275 allows air (room air) to flow in, so that the hydrogen-containing exhaust gas HG3 whose concentration is further diluted can be discharged through the exhaust port 260.

如上所述,本發明的效果在於,由於在第一處理部210和第二處理部250連續處理氫氣,所以與含氫廢氣HG的濃度無關地執行工藝,由於利用催化反應,因此在氫氣處理工藝中能夠減少危險發生要素。並且,本發明的效果在於,由於在沿著水平方向配置有催化劑載體部216的第一處理部210中處理大量的氫氣,並且在沿著垂直方向配置有催化劑載體部256的第二處理部中集中處理氫氣,因此可以使含氫廢氣的氫氣處理效率極大化。 As described above, the effect of the present invention is that, since hydrogen is continuously processed in the first processing section 210 and the second processing section 250, the process is performed regardless of the concentration of the hydrogen-containing exhaust gas HG, and the catalytic reaction is used, so the process is performed in the hydrogen treatment process. Can reduce the risk factors. In addition, the effect of the present invention is that a large amount of hydrogen is processed in the first processing section 210 in which the catalyst carrier section 216 is arranged in the horizontal direction, and in the second processing section in which the catalyst carrier section 256 is arranged in the vertical direction Concentrate the treatment of hydrogen, so the efficiency of hydrogen treatment of hydrogen-containing exhaust gas can be maximized.

並且,本發明的效果在於,由於可以在不燃燒的情況下通過催化反應處理氫氣,因此可以提高裝置的耐久性, 並且可以通過僅更換催化劑載體部216、256來實現維護管理,因此可以減少整體工藝成本。 In addition, the effect of the present invention is that since hydrogen can be treated by a catalytic reaction without burning, the durability of the device can be improved, In addition, maintenance and management can be realized by only replacing the catalyst carrier parts 216 and 256, so the overall process cost can be reduced.

如上所述,本發明舉出優選實施例進行了圖示和說明,但是並非限定於所述實施例,在不超出本發明的精神的範圍內,該發明所屬技術領域的技術人員可進行各種變形和變更。這樣的變形例以及變更例應視為均屬於本發明的申請專利範圍範圍內。 As described above, the present invention has been illustrated and described with preferred embodiments, but is not limited to the embodiments, and various modifications can be made by those skilled in the art to which the present invention belongs within the scope that does not depart from the spirit of the present invention. And change. Such modifications and alterations should be regarded as falling within the scope of the patent application of the present invention.

100‧‧‧半導體處理裝置 100‧‧‧Semiconductor processing equipment

110‧‧‧含氫廢氣流入管 110‧‧‧Hydrogen-containing waste gas inflow pipe

200‧‧‧含氫廢氣處理裝置 200‧‧‧Hydrogen-containing waste gas treatment device

210‧‧‧第一處理部 210‧‧‧First Processing Department

211‧‧‧氣體流入部 211‧‧‧Gas inflow part

212‧‧‧導入部 212‧‧‧Introduction Department

213‧‧‧混合板 213‧‧‧Mixed board

215‧‧‧反應部 215‧‧‧Reaction Department

216、256、256a、256b‧‧‧催化劑載體部 216, 256, 256a, 256b‧‧‧Catalyst carrier part

217、257a、257b‧‧‧催化過濾部 217, 257a, 257b‧‧‧Catalytic filter

218、258a、258b‧‧‧催化反應部 218, 258a, 258b‧‧‧Catalytic reaction section

230‧‧‧含氧空氣供給部 230‧‧‧Oxygenated air supply unit

231‧‧‧含氧空氣流入管 231‧‧‧Oxygenated air inlet pipe

240‧‧‧第一排水口 240‧‧‧First drain

250‧‧‧第二處理部 250‧‧‧Second Processing Department

260‧‧‧排出口 260‧‧‧Exhaust outlet

270‧‧‧吹掃用氣體流入管 270‧‧‧Purge gas inlet pipe

275‧‧‧空氣流入管 275‧‧‧Air inflow pipe

280‧‧‧冷卻單元 280‧‧‧cooling unit

290‧‧‧第二排水口 290‧‧‧Second drain

A‧‧‧含氧空氣 A‧‧‧Oxygenated air

HG、HG2、HG3‧‧‧含氫廢氣 HG, HG2, HG3‧‧‧Hydrogen-containing waste gas

P‧‧‧吹掃用氣體 P‧‧‧Purge gas

RA‧‧‧空氣 RA‧‧‧Air

W‧‧‧被冷凝的水蒸氣、水 W‧‧‧Condensed water vapor, water

Claims (12)

一種含氫廢氣處理裝置,其特徵在於,包括:處理部,其至少一側連接有供半導體表面改性工藝中產生的含氫廢氣流入的含氫廢氣流入管以及供含氧空氣流入的含氧空氣流入管,並且所述處理部包括多個催化劑載體部,所述催化劑載體部包含與所述含氫廢氣發生催化反應的催化劑,其中,所述處理部包括:第一處理部,包括多個沿著水平方向配置的所述催化劑載體部;以及第二處理部,配置在所述第一處理部的上部並與所述第一處理部連通,包括至少一個沿著垂直方向配置的所述催化劑載體部,其中,所述第一處理部的水平面積大於所述第二處理部。 A hydrogen-containing waste gas treatment device, which is characterized by comprising: a treatment part, at least one side of which is connected with a hydrogen-containing waste gas inflow pipe into which hydrogen-containing waste gas generated in a semiconductor surface modification process flows and an oxygen-containing gas into which oxygen-containing air flows. Air inflow pipe, and the treatment part includes a plurality of catalyst carrier parts, the catalyst carrier part contains a catalyst that catalytically reacts with the hydrogen-containing exhaust gas, wherein the treatment part includes: a first treatment part, including a plurality of The catalyst carrier portion arranged in a horizontal direction; and a second processing portion, which is arranged on the upper part of the first processing portion and communicates with the first processing portion, and includes at least one catalyst arranged in a vertical direction The carrier part, wherein the horizontal area of the first treatment part is larger than that of the second treatment part. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,所述第一處理部被分隔為上部的反應部和下部的氣體流入部,所述反應部中配置有所述催化劑載體部,所述氣體流入部的一側連接有所述含氫廢氣流入管以及所述含氧空氣流入管。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein the first treatment part is divided into an upper reaction part and a lower gas inflow part, and the catalyst carrier part is arranged in the reaction part, The hydrogen-containing exhaust gas inflow pipe and the oxygen-containing air inflow pipe are connected to one side of the gas inflow portion. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,所述催化劑載體部的至少一部分上塗布有鉑(Pt)、 鋁(Al)、鉻(Cr)、銅(Cu)、釕(Ru)、銠(Rh)、銥(Ir)、鋨(Os)中的至少一種催化金屬。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein at least a part of the catalyst carrier part is coated with platinum (Pt), At least one catalytic metal selected from aluminum (Al), chromium (Cr), copper (Cu), ruthenium (Ru), rhodium (Rh), iridium (Ir), and osmium (Os). 如請求項3所述的含氫廢氣處理裝置,其特徵在於,所述催化劑載體部包括:催化過濾部,在多孔性的金屬或陶瓷上塗布有所述催化金屬;以及催化反應部,配置於所述催化過濾部上,在沿著垂直方向形成有中孔的蜂巢結構的金屬或陶瓷上塗布有所述催化金屬。 The hydrogen-containing exhaust gas treatment device according to claim 3, wherein the catalyst carrier part includes: a catalytic filter part coated with the catalytic metal on porous metal or ceramic; and a catalytic reaction part arranged in The catalytic filter part is coated with the catalytic metal on metal or ceramic with a mesoporous honeycomb structure formed along the vertical direction. 如請求項4所述的含氫廢氣處理裝置,其特徵在於,在所述蜂巢結構中,單一蜂巢的直烴不超過4mm。 The hydrogen-containing waste gas treatment device according to claim 4, characterized in that, in the honeycomb structure, the straight hydrocarbon of a single honeycomb does not exceed 4 mm. 如請求項2所述的含氫廢氣處理裝置,其特徵在於,所述氣體流入部包括:導入部,所述含氫廢氣以及所述含氧空氣流入所述導入部;以及多個混合板,在所述導入部上彼此隔著間距,並且沿著水平方向配置,其中,所述混合板上沿著橫向以及縱向形成有多個混合口。 The hydrogen-containing exhaust gas treatment device according to claim 2, wherein the gas inflow portion includes: an introduction portion into which the hydrogen-containing exhaust gas and the oxygen-containing air flow into the introduction portion; and a plurality of mixing plates, The introduction part is spaced apart from each other and arranged along the horizontal direction, wherein a plurality of mixing ports are formed along the horizontal and vertical directions on the mixing plate. 如請求項6所述的含氫廢氣處理裝置,其特徵在於,位於下部的混合板的混合口與位於上部的混合板的混合口相互錯開形成。 The hydrogen-containing exhaust gas treatment device according to claim 6, characterized in that the mixing port of the mixing plate located in the lower part and the mixing port of the mixing plate located in the upper part are formed staggered from each other. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,在所述第一處理部的至少一側連接有第一排水 口,用於從所述第一處理部內部排出被冷凝的水蒸氣。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein a first drain is connected to at least one side of the first treatment part The port is used to discharge the condensed water vapor from the inside of the first treatment part. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,在所述第二處理部的上部與排出口之間還設置有冷卻單元,用於冷卻一部分所述含氫廢氣。 The hydrogen-containing waste gas treatment device according to claim 1, wherein a cooling unit is further provided between the upper portion of the second treatment part and the discharge port for cooling a part of the hydrogen-containing waste gas. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,在所述第二處理部的上部與排出口之間還設置有供給吹掃用氣體的吹掃用氣體流入管。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein a purge gas inflow pipe for supplying purge gas is further provided between the upper portion of the second treatment section and the discharge port. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,在所述第二處理部的上部與排出口之間連接有排出被冷凝的水蒸氣的第二排水口。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein a second drain port for discharging condensed water vapor is connected between the upper portion of the second treatment part and the discharge port. 如請求項1所述的含氫廢氣處理裝置,其特徵在於,在所述第二處理部的上部與排出口之間還設置有用於供給空氣的空氣流入管。 The hydrogen-containing exhaust gas treatment device according to claim 1, wherein an air inflow pipe for supplying air is further provided between the upper portion of the second treatment part and the discharge port.
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