TWI733120B - Thin film resistor - Google Patents

Thin film resistor Download PDF

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TWI733120B
TWI733120B TW108118625A TW108118625A TWI733120B TW I733120 B TWI733120 B TW I733120B TW 108118625 A TW108118625 A TW 108118625A TW 108118625 A TW108118625 A TW 108118625A TW I733120 B TWI733120 B TW I733120B
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thin film
film resistor
layer
substrate
resistance layer
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TW202044538A (en
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張鼎張
林志陽
曾懿霆
陳穩仲
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國立中山大學
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Abstract

A thin film resistor is provided to solve the problem where the conventional film resistor tends to suffer from electrochemical erosion and has a low cooling efficiency. The thin film resistor includes a substrate having a mounting face, a resistor layer on the mounting face, and a metallic protection layer on a face of the resistor layer opposite to the mounting face of the substrate. The metallic protection layer forms from tantalum, hafnium, tungsten, silver, platinum, palladium, ruthenium or an alloy thereof.

Description

薄膜電阻 Thin film resistors

本發明係關於一種電子元件,尤其是一種防電化學腐蝕、降低厚度及提升散熱性的薄膜電阻。 The present invention relates to an electronic component, especially a thin film resistor which prevents electrochemical corrosion, reduces thickness and improves heat dissipation.

在薄膜或半導體製程中,係可以將電阻材料以奈米等級之厚度沉積於晶片上,而形成面積遠大於厚度的薄膜電阻,由於薄膜電阻的溫度係數低,使其電阻值穩定而不易隨溫度變化,係能夠應用於測量儀器、醫療器材、數位產品等精密器械。 In the thin film or semiconductor manufacturing process, the resistive material can be deposited on the wafer with a thickness of nanometers to form a thin film resistor with an area much larger than the thickness. Due to the low temperature coefficient of the thin film resistor, its resistance value is stable and difficult to change with temperature. Changes can be applied to precision instruments such as measuring instruments, medical equipment, and digital products.

上述習知的薄膜電阻,通常由鎳鉻合金(Nichrome)材料作為電阻層,並覆蓋環氧樹脂(Epoxy)於電阻層上,用以防止發生電化學腐蝕而導致鎳鉻合金受損,係可以避免薄膜電阻的電阻值改變。惟,環氧樹脂為有機材料,其導熱性相對於金屬物質差,係影響薄膜電阻的散熱性且增加整體結構之厚度。 The above-mentioned conventional thin film resistors usually use Nichrome as the resistance layer and cover the epoxy resin (Epoxy) on the resistance layer to prevent electrochemical corrosion from causing damage to the Nichrome alloy. Avoid changing the resistance value of the thin film resistor. However, epoxy resin is an organic material, and its thermal conductivity is poorer than that of metal materials, which affects the heat dissipation of thin film resistors and increases the thickness of the overall structure.

有鑑於此,習知的薄膜電阻確實仍有加以改善之必要。 In view of this, there is indeed still a need to improve the conventional thin film resistors.

為解決上述問題,本發明的目的是提供一種薄膜電阻,係可以抵抗電化學腐蝕。 In order to solve the above problems, the purpose of the present invention is to provide a thin film resistor which can resist electrochemical corrosion.

本發明的次一目的是提供一種薄膜電阻,係可以提升元件散熱 性。 The second objective of the present invention is to provide a thin film resistor, which can improve the heat dissipation of the element sex.

本發明的又一目的是提供一種薄膜電阻,係可以降低元件整體厚度。 Another object of the present invention is to provide a thin film resistor, which can reduce the overall thickness of the element.

本發明全文所記載的元件及構件使用「一」或「一個」之量詞,僅是為了方便使用且提供本發明範圍的通常意義;於本發明中應被解讀為包括一個或至少一個,且單一的概念也包括複數的情況,除非其明顯意指其他意思。 The elements and components described in the full text of the present invention use the quantifiers "one" or "one" for convenience and to provide the general meaning of the scope of the present invention; in the present invention, it should be construed as including one or at least one, and single The concept of also includes the plural, unless it clearly implies other meanings.

本發明的薄膜電阻,包含:一基板,具有一承載面;一電阻層,位於該承載面;及一金屬保護層,位於該電阻層相對於該承載面的另一表面,該金屬保護層係由鉭、鉿、鎢、銀、鉑、鈀、釕或上述元素的合金所構成。 The thin film resistor of the present invention includes: a substrate having a bearing surface; a resistance layer located on the bearing surface; and a metal protective layer located on the other surface of the resistance layer opposite to the bearing surface, and the metal protective layer is It is composed of tantalum, hafnium, tungsten, silver, platinum, palladium, ruthenium or alloys of the above elements.

據此,本發明的薄膜電阻,以具有活性低之金屬構成電阻層或包覆保護電阻的保護層,藉由不受電化學腐蝕影響之金屬或金屬氧化物,可以防止薄膜電阻受腐蝕而改變電阻值,具有穩定電阻值及提高元件散熱性等功效。 Accordingly, the thin-film resistor of the present invention uses a metal with low activity to form a resistance layer or a protective layer covering the resistance. The metal or metal oxide that is not affected by electrochemical corrosion can prevent the thin-film resistor from being corroded and changing the resistance. It has the functions of stabilizing the resistance value and improving the heat dissipation of the component.

其中,該電阻層為鎳鉻合金或鉻矽合金。如此,係具有提高電阻層熔點及強度的功效。 Wherein, the resistance layer is made of nickel-chromium alloy or chromium-silicon alloy. In this way, it has the effect of increasing the melting point and strength of the resistance layer.

其中,該基板具有二電極部,該二電極部分別位於該承載面之兩端,該電阻層分別電性連結該二電極部。如此,係具有導引電流作用於電阻層的功效。 Wherein, the substrate has two electrode parts, the two electrode parts are respectively located at two ends of the carrying surface, and the resistance layer is electrically connected to the two electrode parts respectively. In this way, it has the effect of guiding current to act on the resistive layer.

其中,該電阻層之厚度小於10微米。如此,係具有降低元件厚度及提升散熱效率的功效。 Wherein, the thickness of the resistance layer is less than 10 microns. In this way, it has the effect of reducing the thickness of the device and improving the heat dissipation efficiency.

本發明的薄膜電阻,包含:一基板,具有一承載面;及一電阻層,位於該承載面,該電阻層係由鉭、鉿、鎢、銀、鉑、鈀、釕或上述元素的合金所構成。係可以防止薄膜電阻受腐蝕而改變電阻值,具有穩定電阻值、 降低元件厚度及提高元件散熱性等功效。 The thin film resistor of the present invention includes: a substrate having a bearing surface; and a resistance layer located on the bearing surface, the resistance layer is made of tantalum, hafnium, tungsten, silver, platinum, palladium, ruthenium or alloys of the above elements constitute. The system can prevent the film resistor from being corroded and change the resistance value, and has a stable resistance value, Reduce component thickness and improve component heat dissipation and other effects.

1‧‧‧基板 1‧‧‧Substrate

11‧‧‧電極部 11‧‧‧Electrode

2‧‧‧電阻層 2‧‧‧Resistance layer

3‧‧‧金屬保護層 3‧‧‧Metal protective layer

S‧‧‧承載面 S‧‧‧Loading surface

〔第1圖〕本發明第一實施例的側視剖面圖。 [Figure 1] A side cross-sectional view of the first embodiment of the present invention.

〔第2圖〕本發明第二實施例的側視剖面圖。 [Figure 2] A side cross-sectional view of the second embodiment of the present invention.

〔第3a~3d圖〕本發明進行電化學腐蝕水滴測試之數據相關圖。 [Figures 3a~3d] The data correlation diagram of the electrochemical corrosion water drop test performed in the present invention.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式,作詳細說明如下:請參照第1圖所示,其係本發明薄膜電阻的第一實施例,係包含一基板1、一電阻層2及一金屬保護層3,該電阻層2及該金屬保護層3係位於該基板1上,該電阻層2係由該金屬保護層3及該基板1上下包覆。 In order to make the above and other objects, features and advantages of the present invention more comprehensible, the preferred embodiments of the present invention will be described in detail in conjunction with the accompanying drawings as follows: Please refer to Figure 1. It is the first embodiment of the thin film resistor of the present invention, which includes a substrate 1, a resistance layer 2 and a metal protection layer 3. The resistance layer 2 and the metal protection layer 3 are located on the substrate 1, and the resistance layer 2 It is covered by the metal protective layer 3 and the substrate 1 up and down.

該基板1係用於承載各種電子元件及線路,藉由濺射、蒸鍍、雷射沉積等技術係可以將金屬材料成形於該基板1之承載面S,該基板1還可以具有二電極部11,該二電極部11係分別位於該承載面S之兩端。該基板1可以是矽晶圓、氧化鋁、氮化鋁等晶體材料,該二電極部11可以是金屬導體。 The substrate 1 is used to carry various electronic components and circuits. Metal materials can be formed on the carrying surface S of the substrate 1 by sputtering, evaporation, laser deposition and other techniques. The substrate 1 can also have two electrode parts. 11. The two electrode parts 11 are respectively located at two ends of the bearing surface S. The substrate 1 may be a crystalline material such as silicon wafer, aluminum oxide, aluminum nitride, etc., and the two electrode portions 11 may be a metal conductor.

該電阻層2係以厚度小於10微米的薄膜型態形成於該承載面S,該電阻層2分別電性連結該二電極部11。該電阻層2可以是鎳鉻合金、鉻矽合金(Chromium-Silicon)。 The resistance layer 2 is formed on the supporting surface S in a thin film with a thickness of less than 10 microns, and the resistance layer 2 is electrically connected to the two electrode portions 11 respectively. The resistance layer 2 can be a nickel-chromium alloy or a chromium-silicon alloy (Chromium-Silicon).

該金屬保護層3係位於該電阻層2相對於該承載面S的另一表面,使該金屬保護層3及該基板1可以覆蓋該電阻層2,減少溶液侵入該電 阻層2的機率,該金屬保護層3可以是鉭(Ta)、鉿(Hf)、鎢(W)等高抗腐蝕性之4、5、6族金屬元素,還可以是金(Au)、銀(Ag)、鉑(Pt)、鈀(Pd)、釕(Ru)等活性低之貴重金屬,該金屬保護層3可以是複數金屬材料以特定比例形成之合金,藉由在該金屬保護層3之表面形成金屬氧化物,係可以防止內部的該電阻層2發生電化學腐蝕。 The metal protection layer 3 is located on the other surface of the resistance layer 2 opposite to the carrying surface S, so that the metal protection layer 3 and the substrate 1 can cover the resistance layer 2 and reduce the intrusion of solution into the electric Probability of the barrier layer 2, the metal protective layer 3 can be tantalum (Ta), hafnium (Hf), tungsten (W) and other high corrosion resistance group 4, 5, 6 metal elements, or gold (Au), Silver (Ag), platinum (Pt), palladium (Pd), ruthenium (Ru) and other precious metals with low activity, the metal protective layer 3 can be an alloy formed by a plurality of metal materials in a specific ratio, by applying the metal protective layer Metal oxide is formed on the surface of 3, which can prevent the internal resistance layer 2 from being electrochemically corroded.

請參照第2圖所示,其係本發明薄膜電阻的第二實施例,係包含一基板1及一電阻層2,該電阻層2係位於該基板1之承載面S,該電阻層2可以是鉭(Ta)、鉿(Hf)、鎢(W)等高抗腐蝕性之4、5、6族金屬元素,還可以是金(Au)、銀(Ag)、鉑(Pt)、鈀(Pd)、釕(Ru)等活性低之貴重金屬,該電阻層2可以是複數金屬材料以特定比例形成之合金,藉由在該電阻層2之表面形成金屬氧化物,係可以防止該電阻層2發生電化學腐蝕。另外,該電阻層2之厚度小於10微米。 Please refer to Figure 2, which is the second embodiment of the thin film resistor of the present invention. It includes a substrate 1 and a resistive layer 2. The resistive layer 2 is located on the carrying surface S of the substrate 1, and the resistive layer 2 can be It is a group 4, 5, 6 metal element with high corrosion resistance such as tantalum (Ta), hafnium (Hf), and tungsten (W). It can also be gold (Au), silver (Ag), platinum (Pt), palladium ( Pd), ruthenium (Ru) and other precious metals with low activity. The resistance layer 2 can be an alloy formed of a plurality of metal materials in a specific ratio. By forming a metal oxide on the surface of the resistance layer 2, the resistance layer 2 can be prevented 2 Electrochemical corrosion occurs. In addition, the thickness of the resistance layer 2 is less than 10 microns.

請參照第3a~3d圖所示,其係以本發明的薄膜電阻進行電化學腐蝕水滴測試,將不同導電度之電解液定時定量滴於薄膜電阻上,所記錄取得的電阻值變化比率與經過時間之數據相關圖,其中,導電度較低的電解液(4μS/cm)可以是純水,而導電度較高的電解液(400μS/cm)可以是自來水。如第3a圖所示,薄膜電阻係由鉿所形成;如第3b圖所示,薄膜電阻係分別以50瓦及150瓦的功率,電鍍鉿及鉭所形成;如第3c圖所示,薄膜電阻係共同以100瓦的功率,電鍍鉿及鉭所形成;如第3d圖所示,薄膜電阻係分別以150瓦及50瓦的功率,電鍍鉿及鉭所形成。 Please refer to Figures 3a~3d, which is an electrochemical corrosion water drop test with the thin film resistor of the present invention. Electrolytes of different conductivity are dropped on the thin film resistor regularly and quantitatively, and the recorded resistance value change ratio and the process Time data correlation graph, where the electrolyte with lower conductivity (4μS/cm) can be pure water, and the electrolyte with higher conductivity (400μS/cm) can be tap water. As shown in Figure 3a, the thin film resistors are formed by hafnium; as shown in Figure 3b, the thin film resistors are formed by electroplating hafnium and tantalum at 50 watts and 150 watts respectively; as shown in Figure 3c, the thin film resistors are formed by electroplating hafnium and tantalum. The resistors are formed by electroplating hafnium and tantalum with a power of 100 watts; as shown in Figure 3d, the thin film resistors are formed by electroplating hafnium and tantalum with a power of 150 watts and 50 watts, respectively.

由第3a~3d圖可知,電阻變化比率與測試時間之相關曲線係在60秒後驅於平緩,係可以證明本發明的薄膜電阻能夠降低電化學腐蝕的影響,使薄膜電阻的電阻值穩定。 It can be seen from Figures 3a to 3d that the correlation curve between the resistance change ratio and the test time is smooth after 60 seconds, which can prove that the thin film resistor of the present invention can reduce the influence of electrochemical corrosion and stabilize the resistance value of the thin film resistor.

綜上所述,本發明的薄膜電阻,以具有活性低之金屬構成電阻 層或包覆保護電阻的保護層,藉由不受電化學腐蝕影響之金屬或金屬氧化物,可以防止薄膜電阻受腐蝕而改變電阻值,具有穩定電阻值、降低元件厚度及提高元件散熱性等功效。 In summary, the thin film resistor of the present invention is composed of a metal with low activity. The protective layer or coating that protects the resistor. With the metal or metal oxide that is not affected by electrochemical corrosion, it can prevent the film resistor from being corroded and change the resistance value. It has the effects of stabilizing the resistance value, reducing the thickness of the component, and improving the heat dissipation of the component. .

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed using the above-mentioned preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with the art without departing from the spirit and scope of the present invention may make various changes and modifications relative to the above-mentioned embodiments. The technical scope of the invention is protected. Therefore, the scope of protection of the invention shall be subject to the scope of the attached patent application.

1‧‧‧基板 1‧‧‧Substrate

11‧‧‧電極部 11‧‧‧Electrode

2‧‧‧電阻層 2‧‧‧Resistance layer

3‧‧‧金屬保護層 3‧‧‧Metal protective layer

S‧‧‧承載面 S‧‧‧Loading surface

Claims (4)

一種薄膜電阻,包含:一基板,具有一承載面;一電阻層,位於該承載面;及一金屬保護層,位於該電阻層相對於該承載面的另一表面,該金屬保護層係由鉿、鎢、銀、鉑、鈀、釕或上述元素的合金所構成。 A thin film resistor, comprising: a substrate with a bearing surface; a resistance layer located on the bearing surface; and a metal protective layer located on the other surface of the resistance layer opposite to the bearing surface, the metal protective layer made of hafnium , Tungsten, silver, platinum, palladium, ruthenium or alloys of the above elements. 如申請專利範圍第1項所述之薄膜電阻,其中,該電阻層為鎳鉻合金或鉻矽合金。 For the thin film resistor described in item 1 of the scope of patent application, wherein the resistor layer is a nickel-chromium alloy or a chromium-silicon alloy. 如申請專利範圍第1或2項所述之薄膜電阻,其中,該基板具有二電極部,該二電極部分別位於該承載面之兩端,該電阻層分別電性連結該二電極部。 The thin film resistor described in item 1 or 2 of the scope of patent application, wherein the substrate has two electrode portions, the two electrode portions are respectively located at two ends of the carrying surface, and the resistance layer is electrically connected to the two electrode portions respectively. 如申請專利範圍第1或2項所述之薄膜電阻,其中,該電阻層之厚度小於10微米。 The thin film resistor described in item 1 or 2 of the scope of patent application, wherein the thickness of the resistor layer is less than 10 microns.
TW108118625A 2019-05-29 2019-05-29 Thin film resistor TWI733120B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200503263A (en) * 2004-03-17 2005-01-16 Ta I Technology Co Ltd A thin film resistance manufacturing method
TWM321576U (en) * 2007-05-23 2007-11-01 Walsin Technology Corp Thin-film resistor
TWM503637U (en) * 2014-07-04 2015-06-21 shi-long Wei Corrosion resistance thin film resistor structure
CN205451956U (en) * 2016-03-03 2016-08-10 赵传辉 Novel high temperature resistant film resistor
TW201802960A (en) * 2016-07-06 2018-01-16 欣興電子股份有限公司 Method of forming package substrate
TWI641001B (en) * 2018-01-22 2018-11-11 國立屏東科技大學 Alloy thin film resistor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200503263A (en) * 2004-03-17 2005-01-16 Ta I Technology Co Ltd A thin film resistance manufacturing method
TWM321576U (en) * 2007-05-23 2007-11-01 Walsin Technology Corp Thin-film resistor
TWM503637U (en) * 2014-07-04 2015-06-21 shi-long Wei Corrosion resistance thin film resistor structure
CN205451956U (en) * 2016-03-03 2016-08-10 赵传辉 Novel high temperature resistant film resistor
TW201802960A (en) * 2016-07-06 2018-01-16 欣興電子股份有限公司 Method of forming package substrate
TWI641001B (en) * 2018-01-22 2018-11-11 國立屏東科技大學 Alloy thin film resistor

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