TWI714133B - Manufacturing method of knitted fabric and structure thereof - Google Patents
Manufacturing method of knitted fabric and structure thereof Download PDFInfo
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- 239000004744 fabric Substances 0.000 title claims abstract description 170
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 45
- 238000004043 dyeing Methods 0.000 claims abstract description 41
- 238000009940 knitting Methods 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000009941 weaving Methods 0.000 claims description 35
- 210000004177 elastic tissue Anatomy 0.000 claims description 24
- 238000009960 carding Methods 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 13
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- -1 polyethylene terephthalate Polymers 0.000 claims description 3
- 210000001161 mammalian embryo Anatomy 0.000 claims 3
- 230000000052 comparative effect Effects 0.000 description 16
- 229920002334 Spandex Polymers 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000004759 spandex Substances 0.000 description 4
- 238000007730 finishing process Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本發明是有關一種針織布料之製造方法及其結構,且特別是有關於一種可減少工序、降低成本且縮短製造時程的針織布料之製造方法及其結構。 The present invention relates to a method for manufacturing knitted fabric and its structure, and in particular to a method for manufacturing knitted fabric and its structure, which can reduce the number of processes, reduce costs, and shorten the manufacturing time.
在製造彈性布料之傳統的染整工藝中,為了使布料具有良好的回彈性,往往會選用或加入彈性纖維進行織造,如氨綸裸膠絲,並在進行染整作業前,需經過預定型步驟的處理,以令彈性布料獲得良好的尺寸安定性及達到平整的布面外觀。 In the traditional dyeing and finishing process of manufacturing elastic fabrics, in order to make the fabrics have good resilience, elastic fibers are often selected or added for weaving, such as spandex bare rubber yarn, and pre-determined steps are required before dyeing and finishing operations. The treatment to make the elastic fabric obtain good dimensional stability and achieve a smooth fabric appearance.
然,進行預定型處理時所需的高溫將影響及破壞紗線的狀態,進而影響針織布料的手感,使針織布料變得硬挺,穿著舒適性差。另外,預定型處理的流程長、耗能高,因而降低彈性針織布料的製造效率,也增加額外的費用及成本。 However, the high temperature required for the pre-sizing process will affect and destroy the state of the yarn, and then affect the feel of the knitted fabric, making the knitted fabric stiff and poor wearing comfort. In addition, the pre-processing has a long process and high energy consumption, which reduces the manufacturing efficiency of elastic knitted fabrics and also increases additional expenses and costs.
是以,如何製造具彈性特性的針織布料,及提升其製造效能,遂成相關業者共同努力之目標。 Therefore, how to make knitted fabrics with elastic properties and improve its manufacturing efficiency has become the goal of the joint efforts of related industries.
本發明提供一種針織布料之製造方法及其結構,本發明之針織布料結構在不包含任何彈性紗線的情況下,透過省略習知染整織造工藝中的預定步驟,藉此令本發明之針織布料結構仍保有良好的彈性及回復性,並藉以提高針織布料之整體的製造效率。 The present invention provides a method for manufacturing knitted fabric and its structure. The knitted fabric structure of the present invention does not contain any elastic yarns by omitting predetermined steps in the conventional dyeing, finishing and weaving process, thereby making the knitted fabric of the present invention The fabric structure still maintains good elasticity and resilience, thereby improving the overall manufacturing efficiency of knitted fabrics.
依據本發明之一態樣提供一種針織布料之製造方法,包含織造步驟、染色步驟及成定步驟。織造步驟係利用編織機將一地梳紗線組織與一提花紗線組織編織成一胚布,且胚布為賈卡提花織物。染色步驟係將胚布進行染色。成定步驟係將染色後之胚布進行尺寸定型,並獲得一針織布料,其中,地梳紗線組織之材質與提花紗線組織之材質為加工絲。 According to one aspect of the present invention, a method for manufacturing a knitted fabric is provided, which includes a weaving step, a dyeing step, and a setting step. The weaving step is to use a knitting machine to knit a ground carded yarn structure and a jacquard yarn structure into a green fabric, and the green fabric is a jacquard fabric. The dyeing step is to dye the fabric. The setting step is to size and shape the dyed fabric to obtain a knitted fabric, wherein the material of the ground card yarn structure and the material of the jacquard yarn structure are processed silk.
根據前述態樣之針織布料之製造方法,其中加工絲可為非彈性纖維。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, the processed yarn may be an inelastic fiber.
根據前述態樣之針織布料之製造方法,其中加工絲可為聚對苯二甲酸乙二酯(Polyethylene Terephthalate:PET)纖維或陽離子可染(Cationic Dyeable Polyester;CDP)纖維。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, the processed yarn may be a polyethylene terephthalate (PET) fiber or a cationic dyeable polyester (CDP) fiber.
根據前述態樣之針織布料之製造方法,其中在織造步驟中,編織機可以一經編方式將地梳紗線組織與提花紗線組織編織成胚布。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, in the weaving step, the knitting machine can knit the ground carded yarn structure and the jacquard yarn structure into a green fabric in a warp knitting manner.
根據前述態樣之針織布料之製造方法,其中在織造步驟中,編織機可藉由一單針床結構將地梳紗線組織與提花紗線組織編織成胚布。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, in the weaving step, the knitting machine can knit the ground carded yarn structure and the jacquard yarn structure into a green fabric through a single needle bed structure.
根據前述態樣之針織布料之製造方法,其中在織造步驟中,編織機可藉由一雙針床結構將地梳紗線組織與提花紗線組織編織成胚布。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, in the weaving step, the knitting machine can knit the ground carded yarn structure and the jacquard yarn structure into a green fabric through a double needle bed structure.
根據前述態樣之針織布料之製造方法,其中染色步驟透過一染色溫度將胚布進行染色,染色溫度可為98℃至135℃。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, the dyeing step dyes the fabric through a dyeing temperature, and the dyeing temperature can be 98°C to 135°C.
根據前述態樣之針織布料之製造方法,其中染色步驟經過一染色時間完成,染色時間可為4小時至5小時。 According to the manufacturing method of the knitted fabric of the aforementioned aspect, the dyeing step is completed after a dyeing time, and the dyeing time can be 4 hours to 5 hours.
根據前述態樣之針織布料之製造方法,其中成定步驟透過一成定溫度將胚布進行尺寸定型,成定溫度可為140℃至160℃。 According to the method of manufacturing a knitted fabric of the aforementioned aspect, the fabric is sized by a predetermined temperature in the setting step, and the predetermined temperature can be 140°C to 160°C.
根據前述態樣之針織布料之製造方法,其中成定步驟透過一超喂速度將胚布進行尺寸定型,超喂速度可為15m/min至25m/min。 According to the manufacturing method of the knitted fabric of the aforementioned aspect, in the setting step, the embryonic fabric is dimensioned through an overfeeding speed, and the overfeeding speed can be 15m/min to 25m/min.
根據前述態樣之針織布料之製造方法,其中成定步驟可維持60秒至90秒。 According to the manufacturing method of the knitted fabric of the aforementioned aspect, the setting step can be maintained for 60 to 90 seconds.
根據前述態樣之針織布料之製造方法,其中胚布具有一織造密度,織造密度可為10CPCM至15CPCM。 According to the manufacturing method of the knitted fabric of the aforementioned aspect, the fabric has a weaving density, and the weaving density can be 10CPCM to 15CPCM.
根據前述態樣之針織布料之製造方法,其中針織布料之製造方法不包含一預定步驟,預定步驟係使用化學藥劑以及高溫環境加工於針織布料。 According to the method for manufacturing knitted fabric of the aforementioned aspect, the method for manufacturing knitted fabric does not include a predetermined step, and the predetermined step is to process the knitted fabric using chemicals and a high temperature environment.
根據前述態樣之針織布料之製造方法,其中針織布料不包含一彈性纖維。 According to the method for manufacturing a knitted fabric of the aforementioned aspect, the knitted fabric does not contain an elastic fiber.
依據本發明之另一態樣提供一種利用前述之製造方法所製成的針織布料結構,其為一賈卡提花織物,並包含一地梳紗線組織及一提花紗線組織。地梳紗線組織包含一第一地梳紗線單元及複數個第二地梳紗線單元,第二地梳紗線單元與第一地梳紗線單元相互交織。提花紗線組織設置於地梳紗線組織之一表面且包含第一提花紗線單元,第一提花紗線單元與第二地梳紗線單元交錯編織,其中,地梳紗線組織之材質及提花紗線組織之材質為一加工絲。 According to another aspect of the present invention, there is provided a knitted fabric structure made by the aforementioned manufacturing method, which is a jacquard fabric and includes a ground card yarn structure and a jacquard yarn structure. The ground carding yarn structure includes a first ground carding unit and a plurality of second ground carding units. The second ground carding unit and the first ground carding unit are interwoven. The jacquard yarn structure is arranged on a surface of the ground carded yarn structure and includes a first jacquard yarn unit, the first jacquard yarn unit and the second ground carded yarn unit are interlaced weaving, wherein the material of the ground carded yarn structure is The material of jacquard yarn is a processed silk.
根據前述態樣之針織布料結構,其中針織布料結構不包含一彈性纖維。 According to the knitted fabric structure of the aforementioned aspect, the knitted fabric structure does not include an elastic fiber.
100、300‧‧‧針織布料之製造方法 100, 300‧‧‧Method of manufacturing knitted fabric
110、320‧‧‧織造步驟 110、320‧‧‧Weaving steps
120、330‧‧‧染色步驟 120、330‧‧‧Dyeing steps
130、340‧‧‧成定步驟 130, 340‧‧‧ set steps
310‧‧‧繪製步驟 310‧‧‧Drawing steps
200‧‧‧針織布料 200‧‧‧Knitted fabric
210‧‧‧地梳紗線組織 210‧‧‧Ground carded yarn organization
211‧‧‧第一地梳紗線單元 211‧‧‧First carding unit
212‧‧‧第二地梳紗線單元 212‧‧‧Second carding unit
220‧‧‧提花紗線組織 220‧‧‧Jacquard yarn weave
221‧‧‧第一提花紗線單元 221‧‧‧First Jacquard Yarn Unit
第1圖繪示依照本發明一實施例之針織布料之製造方法的流程示意圖;第2圖繪示依照第1圖實施方式之針織布料結構的梳櫛組織示意圖;以及第3圖繪示依照本發明另一實施例之針織布料之製造方法的流程示意圖。 Fig. 1 is a schematic diagram of the process of manufacturing a knitted fabric according to an embodiment of the present invention; Fig. 2 is a schematic diagram of a bar weave of the knitted fabric structure according to the embodiment of Fig. 1; Invented another embodiment of the process flow diagram of the manufacturing method of knitted fabric.
以下將參照圖式說明本發明之實施例。為明確說明起見,許多實務上的細節將在以下敘述中一併說明。然而,閱讀者應瞭解到,這些實務上的細節不應用以限制本發明。也就是說,在本發明部分實施例中,這些實務上的細節是非必要的。此外,為簡化圖式起見,一些習知慣用的結構與元件在圖式中將以簡單示意的方式繪示;並且重複之元件將可能使用相同的編號或類似的編號表示。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. For the sake of clarity, many practical details will be explained in the following description. However, the reader should understand that these practical details should not be used to limit the present invention. That is to say, in some embodiments of the present invention, these practical details are unnecessary. In addition, for the sake of simplification of the drawings, some conventionally used structures and elements will be drawn in a simple schematic manner in the drawings; and repeated elements may be represented by the same number or similar numbers.
請一併參閱第1圖與第2圖,其中第1圖繪示依照本發明一實施例之針織布料之製造方法100的流程示意圖。第2圖繪示依照第1圖實施方式之針織布料200之結構的梳櫛組織示意圖。針織布料之製造方法100包含織造步驟110、染色步驟120及成定步驟130。織造步驟110係利用一編織機將一地梳紗線組織210與一提花紗線組織220編織成一胚布,且胚布為一賈卡提花織物,其中,地梳紗線組織210之材質與提花紗線組織220之材質為加工絲。染色步驟120係將胚布進行染色。成定步驟130係將染色後之胚布進行尺寸定型,並獲得一針織布料200。
Please refer to FIG. 1 and FIG. 2 together. FIG. 1 is a schematic flowchart of a
再者,本發明之針織布料之製造方法100之織造步驟110不包含彈性纖維。針織布料之製造方法100不包含製造彈性布料之傳統工藝中的預定步驟,預定步驟係使用化學藥劑以及高溫環境加工於針織布料。
Furthermore, the
詳細而言,在製造彈性布料之傳統的染整工藝中,為了使布料具有良好的回彈性,往往會選用或加入彈性纖維進行織造,如氨綸裸膠絲,並在進行染整作業前,會先 進行一高溫的水洗步驟,以令布料中的彈性纖維回縮,再經過一預定步驟,以使布料的彈性趨於穩定。然而,預定步驟中的化學藥劑以及高溫環境會破壞布料之紗線,使得布料過於硬挺,手感舒適性差,且預定步驟耗時、耗能,其增加製造的成本。 In detail, in the traditional dyeing and finishing process of manufacturing elastic fabrics, in order to make the fabrics have good resilience, elastic fibers are often selected or added for weaving, such as spandex bare rubber yarn. first Perform a high-temperature water washing step to shrink the elastic fibers in the fabric, and then go through a predetermined step to stabilize the elasticity of the fabric. However, the chemicals in the predetermined step and the high temperature environment will damage the yarns of the cloth, making the cloth too stiff, with poor hand feel, and the predetermined step is time-consuming and energy-consuming, which increases the manufacturing cost.
有鑑於此,透過上述針織布料之製造方法100,胚布在不包含任何彈性纖維的情況下,於染色步驟120前可省略傳統染整工藝上的預定步驟。透過省略預定步驟,可避免預定步驟中的化學藥劑及高溫破壞胚布之紗線(地梳紗線組織210及提花紗線組織220)的結構,藉以使胚布之紗線仍保有其蓬鬆的特性,並藉此令針織布料200達到良好的回彈性,並更可提升針織布料200之手感的舒適性。除此之外,針織布料之製造方法100不但可減少傳統工序的預定步驟而縮短製造時程,還能大幅地降低製造成本並提高生產效能。
In view of this, through the above-mentioned
在織造步驟110中,編織機可透過單針床結構或雙針床結構,以經編方式將地梳紗線組織210與提花紗線組織220編織成胚布。詳細來說,在第2圖中,地梳紗線組織210包含一第一地梳紗線單元211及複數個第二地梳紗線單元212,第二地梳紗線單元212與第一地梳紗線單元211相互交織;提花紗線組織220設置於地梳紗線組織210之表面,且包含第一提花紗線單元221,第一提花紗線單元221與第二地梳紗線單元212交錯編織。
In the
進一步來說,第一地梳紗線單元211、第二地梳紗線單元212及第一提花紗線單元221皆以全穿紗線的方式進行編織,且在織造步驟110中所織出的胚布,其織造密度可為10CPCM至15CPCM。藉由上述結構,可有利於使地梳紗線組織210及提花紗線組織220保有足夠的拉伸空間,並藉以使針織布料200具有良好的回彈性。
Furthermore, the first
藉由上述織造步驟110之編織方法,可製成一具有網眼孔洞的賈卡提花織物,且針織布料200可任意開孔提花。藉此,可增加針織布料200的透氣性,且針織布料200之網眼孔洞形狀可呈現菱形、方形、圓形或六角形之任意形狀,並使針織布料200具有視覺上的層次感,但本發明不以此揭示內容為限,可依操作需求以不同之編織方法製成一具有網眼孔洞的賈卡提花織物。
By the weaving method of the weaving
值得一提的是,地梳紗線組織210之材質與提花紗線組織220之材質可為加工絲,且加工絲為非彈性纖維。較佳地,加工絲可為聚對苯二甲酸乙二酯(Polyethylene Terephthalate;PET)纖維或陽離子可染(Cationic Dyeable Polyester;CDP)纖維。另外,透過PET纖維及CDP纖維取代傳統之彈性布料的氨綸裸膠絲,可有利於提升針織布料200的手感舒適性,但本發明不以此為限。
It is worth mentioning that the material of the ground carded
將織造步驟110中產生的胚布進行染色步驟120,染色步驟120透過一染色溫度及一染色時間,將胚布進行染色,且此染色溫度可設定為98℃至135℃,染色
時間可設定為4小時至5小時。透過此染色時間及在此染色溫度之環境下,染料可均勻地附著於各紗線組織上,但本發明不以此為限。
The fabric produced in the weaving
值得一提的是,傳統之含彈性纖維的布料易有色牢度不高的狀況,針織布料之製造方法100藉由選用PET纖維及CDP纖維以取代彈性纖維,藉此可改善其色牢度不高的狀況,及改善彈性纖維容易溢色的問題,並有利於提升胚布於染色步驟120中染色的均勻度及色牢度。
It is worth mentioning that traditional fabrics containing elastic fibers tend to have low color fastness. The
為了獲得符合產品需求的針織布料200,需將染色後之胚布重新定型,成定步驟130係將染色後之胚布在一成定溫度下進行加熱定型,且此成定溫度可為140℃至160℃。值得一提的是,在成定步驟130中,可不對染色後的胚布進行拉伸,藉此能保護紗線之原有的延伸性及拉伸度,進而使針織布料200具有良好的回彈性。此外,成定步驟130透過一超喂速度對胚布進行尺寸定型,超喂速度可為15m/min至25m/min,且成定步驟130可維持60秒至90秒,成定溫度、超喂速度及成定步驟130之維持時間可依紗線狀態及操作需求調整,本發明不以此揭示內容為限。在此特別說明的是,上述染色步驟120與成定步驟130均為習知的技術,在此不另贅述。
In order to obtain the
請一併參閱第1圖與第3圖,第3圖繪示依照本發明另一實施例之針織布料之製造方法300的流程示意圖。針織布料之製造方法300包含繪製步驟310、織造步驟320、染色步驟330及成定步驟340。其中織造步驟320、染
色步驟330及成定步驟340分別與第1圖之織造步驟110、染色步驟120及成定步驟130相同,不再贅述。特別的是,針織布料之製造方法300可更包含一繪製步驟310,其係透過一繪圖軟體(如EAT)繪製一賈卡提花織物之花形圖案,並設定編織機之配紗數據。編織機係依據繪製步驟310之花形圖案及配紗數據進行織造步驟320。
Please refer to FIG. 1 and FIG. 3 together. FIG. 3 is a schematic flowchart of a
為了評估利用針織布料之製造方法100所製成的針織布料200的物理性質,係針對第2圖實施例之針織布料200、利用習知製造方法所製成的比較例1及含彈性纖維的比較例2之定點延伸度、克重進行試驗。表一列出第2圖實施例之針織布料200的實驗數據,表二列出比較例1的實驗數據,表三列出比較例2的實驗數據,其中,針織布料200不包含彈性纖維且無經過預定步驟,比較例1不包含彈性纖維並有經過預定步驟,比較例2包含彈性纖維並有經過預定步驟。
In order to evaluate the physical properties of the knitted
在此特別說明的是,針織布料200、比較例1及比較例2之織造方法皆為全穿方式,且表一、表二以及表三中GB表示地梳紗線組織210,JB表示提花紗線組織220,下面將詳述針織布料200、比較例1及比較例2之物理性質的比較。
It is specifically explained here that the weaving methods of knitted
表一可知,針織布料200在無經過預定步驟且不含彈性纖維的情況下,針織布料200之經方向的延伸度為35.2%,縱方向的延伸度為83%,其重量為302.1g/m2。
Table 1 shows that the
表二可知,比較例1無包含彈性纖維,且有經過預定步驟。由表一及表二的結果可知,在紗線之粗細及數量皆為相同的情況下,有經過預定步驟的比較例1之定點拉伸度較針織布料200差。
Table 2 shows that Comparative Example 1 does not contain elastic fibers and has undergone predetermined steps. From the results of Table 1 and Table 2, it can be seen that when the thickness and number of yarns are the same, the fixed-point stretch of Comparative Example 1 with predetermined steps is worse than that of knitted
表三可知,比較例2有包含彈性纖維(氨綸),且有經過預定步驟。由表一及表三的結果可知,針織布料200在不包含任何彈性纖維的情況下,已具有接近含彈性纖維的比較例2的延伸度,且在紗線之粗細及數量皆為相同的情況下,針織布料200的重量明顯低於含彈性纖維的比較例2。
Table 3 shows that Comparative Example 2 contains elastic fiber (spandex) and has undergone predetermined steps. From the results of Table 1 and Table 3, it can be seen that the
總結上述,透過針織布料之製造方法100中省略預定步驟,可有效改善比較例1之布面過於硬挺且延伸性差的問題。再者,利用針織布料之製造方法100所製成的針織布料200在不包含任何彈性纖維的情況下,仍具有接近含彈性纖維之彈性布料的延伸性,且相較於傳統之彈性布料(如比較例2),針織布料200之重量較輕,且能達到更舒適的布料手感。藉此,本發明的針織布料200可被應用於鞋材類、運動服飾、家飾、箱包、醫療及車用方面物品,可被廣泛的應用於生活中常用的物品上,具有一定的實用性質。
To summarize the above, by omitting predetermined steps in the
雖然本揭示內容已以實施例揭露如上,然其並非用以限定本揭示內容,任何所屬技術領域中具有通常知識者,在不脫離本揭示內容的精神和範圍內,當可作些許的更動與潤飾,故本揭示內容的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present disclosure has been disclosed in the above embodiments, it is not intended to limit the present disclosure. Anyone with ordinary knowledge in the relevant technical field can make some changes and modifications without departing from the spirit and scope of the present disclosure. Retouching, therefore, the protection scope of this disclosure shall be subject to the scope of the attached patent application.
100‧‧‧針織布料之製造方法 100‧‧‧The manufacturing method of knitted fabric
110‧‧‧織造步驟 110‧‧‧Weaving steps
120‧‧‧染色步驟 120‧‧‧Dyeing steps
130‧‧‧成定步驟 130‧‧‧Definite Steps
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WO2009059596A1 (en) * | 2007-11-09 | 2009-05-14 | Rohleder Gmbh | Method for producing a woven fabric having at least two layers in some regions and woven fabric produced by said method |
CN105386229A (en) * | 2015-10-16 | 2016-03-09 | 江南大学 | Jacquard spacer forming vamp and production method thereof |
CN107916462A (en) * | 2017-12-14 | 2018-04-17 | 江苏恒力化纤股份有限公司 | A kind of sun washs composite filament and preparation method thereof |
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WO2009059596A1 (en) * | 2007-11-09 | 2009-05-14 | Rohleder Gmbh | Method for producing a woven fabric having at least two layers in some regions and woven fabric produced by said method |
CN105386229A (en) * | 2015-10-16 | 2016-03-09 | 江南大学 | Jacquard spacer forming vamp and production method thereof |
CN107916462A (en) * | 2017-12-14 | 2018-04-17 | 江苏恒力化纤股份有限公司 | A kind of sun washs composite filament and preparation method thereof |
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