TWI707779B - Stretch sheet for absorbent articles and manufacturing method thereof - Google Patents
Stretch sheet for absorbent articles and manufacturing method thereof Download PDFInfo
- Publication number
- TWI707779B TWI707779B TW108111577A TW108111577A TWI707779B TW I707779 B TWI707779 B TW I707779B TW 108111577 A TW108111577 A TW 108111577A TW 108111577 A TW108111577 A TW 108111577A TW I707779 B TWI707779 B TW I707779B
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- Taiwan
- Prior art keywords
- sheet
- stretch sheet
- less
- yarn
- elastic
- Prior art date
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- 230000002745 absorbent Effects 0.000 title claims description 89
- 239000002250 absorbent Substances 0.000 title claims description 89
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- 238000007373 indentation Methods 0.000 claims description 22
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- 238000009987 spinning Methods 0.000 description 110
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Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Landscapes
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Abstract
本發明係一種以互不交叉地於一方向延伸之方式排列之複數條彈性絲(4)以實質上非伸長狀態遍及其等之全長接合於能夠伸長之片材(2、3)之吸收性物品用伸縮片(1)。複數條彈性絲(4)中之一部分或全部係於與長度方向(Y)正交之剖面中具有1個以上之內縮部(40k)之內縮絲(40)。較佳為內縮絲(40)之與長度方向(Y)正交之剖面之形狀具有複數個圓呈一部分重複之狀態相連之形狀,且較佳為相鄰之圓之中心間距離較其中一個圓之半徑與另一個圓之半徑之和更短,且較該一個圓之半徑及該另一個圓之半徑中之較短者之半徑更長。The present invention is a kind of absorptive properties of a plurality of elastic yarns (4) arranged in a manner of extending in one direction without crossing each other in a substantially non-stretched state and joined to an extensible sheet (2, 3) over its entire length. Stretching sheet for articles (1). Part or all of the plurality of elastic yarns (4) are connected to the indented yarns (40) with more than one indented part (40k) in the cross section orthogonal to the longitudinal direction (Y). It is preferable that the shape of the cross-section orthogonal to the length direction (Y) of the inner shrinkage wire (40) has a shape in which a plurality of circles are connected in a partially repeated state, and it is preferable that the distance between the centers of adjacent circles is shorter than one of them The sum of the radius of the circle and the radius of the other circle is shorter and longer than the radius of the shorter of the radius of the one circle and the radius of the other circle.
Description
本發明係關於一種吸收性物品用伸縮片及其製造方法。 The present invention relates to a stretch sheet for absorbent articles and a manufacturing method thereof.
作為伸縮片,本申請人提出有一種以互不交叉地於一方向延伸之方式排列之複數條彈性絲以實質上非伸長狀態遍及其等之全長接合於能夠伸長之片材之伸縮片(參照專利文獻1)。 As a stretch sheet, the applicant proposes a stretch sheet in which a plurality of elastic yarns arranged in a manner extending in one direction without crossing each other are joined to a stretchable sheet in a substantially non-stretched state over its entire length (see Patent Document 1).
專利文獻1所記載之伸縮片係經過如下步驟而製造,即,使經熔融之彈性樹脂自複數個紡絲噴嘴紡出,而獲得複數條熔融或軟化狀態之彈性絲,一面將該等複數條彈性絲以特定速度捲取並延伸,一面於其固化前使其熔合於片材。
The stretch sheet described in
又,關於該伸縮片之製造方法,申請人提出有使用具有呈所謂鋸齒狀配置有複數個紡出噴嘴之鋸齒狀配置部之紡絲頭的伸縮片之製造方法(參照專利文獻2)。於專利文獻2中記載有如下內容,即,使用將紡出噴嘴呈鋸齒狀配置之紡絲頭,具體而言,使用如下紡絲頭,即,複數個紡出噴嘴於一方向上隔開特定間隔配置而成之噴嘴行於與一方向正交之方向配置複數行,且於與一方向正交之方向上鄰接之噴嘴行彼此中,相互之紡出噴嘴錯開。
In addition, regarding the manufacturing method of the stretch sheet, the applicant has proposed a method of manufacturing a stretch sheet using a spinning head having a zigzag arrangement portion in which a plurality of spinning nozzles are arranged in a so-called zigzag shape (refer to Patent Document 2).
[專利文獻1]日本專利特開2008-179128號公報 [Patent Document 1] Japanese Patent Laid-Open No. 2008-179128
[專利文獻2]日本專利特開2017-61064號公報 [Patent Document 2] Japanese Patent Laid-Open No. 2017-61064
本發明係一種以互不交叉地於一方向延伸之方式排列之複數條彈性絲以實質上非伸長狀態遍及其等之全長接合於能夠伸長之片材之伸縮片。於實施形態中,伸縮片係吸收性物品用伸縮片。於實施形態中,上述彈性絲中之一部分或全部係於與該彈性絲延伸之延伸方向正交之剖面中具有1個以上之內縮部之內縮絲。 The present invention is a stretch sheet in which a plurality of elastic yarns arranged in a manner of extending in one direction without crossing each other are joined to a stretchable sheet material in a substantially non-stretched state over its entire length. In the embodiment, the stretch sheet is a stretch sheet for absorbent articles. In the embodiment, part or all of the above-mentioned elastic yarns are indented yarns having one or more indented parts in a cross section orthogonal to the extending direction of the elastic yarn.
又,本發明係一種收縮片之製造方法,該方法具備熔合步驟,該熔合步驟係使自複數個紡絲噴嘴噴出之熔融或軟化狀態之複數條彈性絲於該彈性絲之固化前與片材之原料片接觸,並與該原料片熔合。於實施形態中,伸縮片係吸收性物品用伸縮片。於實施形態中,於上述熔合步驟中,在第1方向隔開間隔而配置有複數個上述紡絲噴嘴之噴嘴行於與該第1方向正交之第2方向形成有複數行。於實施形態中,使用於在上述第2方向相鄰之該噴嘴行彼此中上述紡絲噴嘴之位置於上述第1方向錯開之紡絲頭。於實施形態中,使用將自上述紡絲頭之紡絲噴嘴紡出之彈性絲捲取之捲取機構。於實施形態中,將自上述紡絲噴嘴紡出之熔融或軟化狀態之上述彈性絲以40m/min以上200m/min以下之捲取速度捲取。 In addition, the present invention is a method for manufacturing a shrinkable sheet. The method includes a fusion step that causes a plurality of elastic yarns in a molten or softened state ejected from a plurality of spinning nozzles to be combined with the sheet before the elastic yarn is solidified. The raw material sheet is in contact with and fused with the raw material sheet. In the embodiment, the stretch sheet is a stretch sheet for absorbent articles. In the embodiment, in the fusion step, the nozzle rows in which the plurality of spinning nozzles are arranged at intervals in the first direction are formed in a plurality of rows in the second direction orthogonal to the first direction. In the embodiment, it is used for a spinning head in which the positions of the spinning nozzles in the nozzle rows adjacent to each other in the second direction are shifted from the first direction. In the embodiment, a winding mechanism for winding the elastic yarn spun from the spinning nozzle of the above-mentioned spinning head is used. In the embodiment, the elastic yarn in the molten or softened state spun from the spinning nozzle is wound at a winding speed of 40 m/min or more and 200 m/min or less.
1:伸縮片 1: Stretch film
1':複合片 1': composite sheet
2:片材 2: sheet
3:片材 3: sheet
4:彈性絲 4: Elastic yarn
10:紡絲裝置 10: Spinning device
11:紡絲頭 11: Spinning head
11a:下端面 11a: Lower end
11L:底壁部 11L: bottom wall
11S:側壁部 11S: side wall
12:紡絲噴嘴 12: Spinning nozzle
12A:鋸齒狀配置部 12A: Serrated configuration part
12L:噴嘴行 12L: Nozzle row
13:貯存部 13: Storage Department
15:夾輥 15: nip roller
16:夾輥 16: nip roller
17:齒槽輥 17: Cogged roller
18:夾輥 18: nip roller
40:內縮絲 40: Inner shrink wire
40k:內縮部 40k: indentation
41:單絲 41: Monofilament
42:絲 42: Silk
43:絲 43: Silk
c1:圓 c1: circle
c2:圓 c2: circle
c3:圓 c3: circle
c4:圓 c4: circle
c5:圓 c5: circle
D:直徑 D: diameter
L1:寬度方向之長度 L1: Length in the width direction
L2:厚度方向之長度 L2: Length in thickness direction
L3:厚度方向之最小長度 L3: Minimum length in thickness direction
L4:寬度方向之長度 L4: Length in the width direction
L5:厚度方向之長度 L5: Length in thickness direction
L6:厚度方向之最小長度 L6: Minimum length in thickness direction
P:端部間距離 P: Distance between ends
P1:中心間距離 P1: Distance between centers
p1:間距 p1: pitch
P2:中心間距離 P2: Distance between centers
p2:間距 p2: pitch
P3:中心間距離 P3: Distance between centers
r1:半徑 r1: radius
r2:半徑 r2: radius
r3:半徑 r3: radius
r4:半徑 r4: radius
r5:半徑 r5: radius
X:寬度方向 X: width direction
x1:第1方向 x1: 1st direction
Y:長度方向 Y: length direction
y1:第2方向 y1: second direction
Z:厚度方向 Z: thickness direction
圖1(a)係表示本發明之較佳之一實施形態之伸縮片之伸長狀態的立體圖,圖1(b)係模式性地表示將該伸縮片分解為2片片材及複數條彈性絲之狀態的立體圖。 Figure 1 (a) is a perspective view showing the stretched state of the stretch sheet in a preferred embodiment of the present invention, and FIG. 1 (b) schematically shows the split of the stretch sheet into two sheets and a plurality of elastic threads A perspective view of the state.
圖2係模式性地表示本實施形態之伸縮片之剖面之剖視圖(相當於圖1所示之伸縮片之A-A剖面之部分之剖視圖)。 Fig. 2 is a cross-sectional view schematically showing a cross-section of the stretch sheet of this embodiment (equivalent to the cross-sectional view of the A-A section of the stretch sheet shown in Fig. 1).
圖3(a)係模式性地表示圖2所示之單絲之前視圖,圖3(b)係模式性地表示圖2所示之具有1個內縮部之內縮絲之前視圖,圖3(c)係模式性地表示圖2所示之具有2個內縮部之內縮絲之前視圖。 Fig. 3(a) schematically shows the front view of the monofilament shown in Fig. 2, and Fig. 3(b) schematically shows the front view of the inner shrinkable yarn with one inner shrinkage portion shown in Fig. 2, and Fig. 3 (c) is a schematic diagram showing the front view of the inwardly shrinkable wire having two inwardly-shaped portions shown in FIG. 2.
圖4係模式性地表示本實施形態之伸縮片之製造方法中之熔合步驟之實施所使用之紡絲裝置之主要部分的立體圖。 Fig. 4 is a perspective view schematically showing the main part of the spinning device used in the implementation of the fusion step in the manufacturing method of the stretch sheet of this embodiment.
圖5係將圖4所示之紡絲裝置中之紡絲頭之下端面(噴嘴設置面)側繪製為上側而模式性地表示之立體圖。 Fig. 5 is a perspective view schematically showing the lower end surface (nozzle installation surface) side of the spinning head in the spinning device shown in Fig. 4 as the upper side.
圖6係模式性地表示圖5所示之紡絲頭之下端面之俯視圖。 Fig. 6 is a plan view schematically showing the lower end surface of the spinning head shown in Fig. 5.
圖7係模式性地表示本實施形態之伸縮片之製造方法中之伸縮性賦予步驟之實施所使用之延伸裝置之主要部分的立體圖。 Fig. 7 is a perspective view schematically showing the main part of the stretching device used in the implementation of the stretchability imparting step in the manufacturing method of the stretch sheet of this embodiment.
上述伸縮片被用於各種用途,但可能會產生根據其用途等而調整應力之必要性。於提高該伸縮片之應力之情形時,例如,若增加接合於片材之彈性絲之條數,則伸縮片中之不存在彈性絲之區域變小。上述伸縮片由於係使彈性絲熔合於片材而獲得,故而若彈性絲之非存在區域、即彈性絲 之非接合區域變小,則伸縮片之厚度變薄,肌膚觸感產生改善之餘地,該彈性絲係使彈性樹脂以熔融或軟化之狀態延伸而獲得。 The above-mentioned stretch sheet is used for various purposes, but there may be a need to adjust the stress according to its purpose. When the stress of the stretch sheet is increased, for example, if the number of elastic threads joined to the sheet is increased, the area in the stretch sheet where there are no elastic threads becomes smaller. The above-mentioned stretch sheet is obtained by fusing the elastic filament to the sheet, so if the non-existent area of the elastic filament, that is, the elastic filament When the non-joining area becomes smaller, the thickness of the stretch sheet becomes thinner, and there is room for improvement in the touch of the skin. The elastic yarn is obtained by extending the elastic resin in a molten or softened state.
又,例如,若欲增大彈性絲之直徑從而提高伸縮片之應力,則彈性絲與片材之接觸面積變大,例如,於進行對片材賦予伸縮性之加工時,片材可能會產生開孔等,外觀有改善之餘地。 Also, for example, if the diameter of the elastic yarn is to be increased to increase the stress of the stretch sheet, the contact area between the elastic yarn and the sheet becomes larger. For example, when the sheet is processed to impart stretchability, the sheet may produce There is room for improvement in appearance such as holes.
本發明人等發現,於提高應力之情形時,藉由使用在與彈性絲延伸之延伸方向正交之剖面具有1個以上之內縮部之彈性絲,可獲得肌膚觸感良好且可不降低表觀而提高應力之伸縮片。又,本發明人等發現,藉由將紡絲噴嘴配置成鋸齒狀且將彈性絲之捲取速度設為特定之速度範圍,可有效率地獲得該具有內縮部之彈性絲。而且,於專利文獻1及2中,關於伸縮片包含此種具有內縮部之彈性絲、以及將彈性絲之樹脂紡出速度及捲取速度設定為特定之速度範圍,並無任何記載。
The inventors of the present invention found that when the stress is increased, by using an elastic yarn having one or more indentations in a cross section orthogonal to the extension direction of the elastic yarn, a good touch of the skin can be obtained without reducing the surface. It is a stretch sheet that can improve the stress. In addition, the inventors of the present invention have found that by arranging the spinning nozzle in a zigzag shape and setting the winding speed of the elastic yarn in a specific speed range, the elastic yarn with the indented portion can be efficiently obtained. Moreover, in
因此,本發明係關於一種可消除先前技術所具有之待解決課題之伸縮片及其製造方法。 Therefore, the present invention relates to a stretch sheet and its manufacturing method that can eliminate the problems to be solved in the prior art.
以下,針對本發明,基於其較佳之實施形態,一面參照圖式一面進行說明。於圖1及圖2中示出有本發明之較佳之一實施形態之伸縮片1,於圖3中示出有伸縮片1所包含之彈性絲4。伸縮片較佳為吸收性物品用伸縮片。
Hereinafter, the present invention will be described with reference to the drawings based on its preferred embodiments. 1 and FIG. 2 show a
如圖1及圖2所示,伸縮片1具有於2片片材2、3接合有複數條絲狀之彈性絲4之構成,該等複數條彈性絲4以互不交叉地於一方向延伸之方式排列。複數條彈性絲4分別以夾持於2片片材2、3間之狀態遍及伸縮片1之一方向(符號Y所示之長度方向)之全長以實質上非伸長狀態接合於2片片材2、3。於本說明書中,所謂「彈性」係指可拉伸且於自拉伸之力解放時收縮之性質,所謂「實質上非伸長狀態」係指於將外力解除時不會收縮之狀態。
As shown in Figures 1 and 2, the
伸縮片1之伸縮性係因彈性絲4之彈性而表現。若將伸縮片1於與彈性絲4延伸之方向相同之方向上拉伸,則彈性絲4及片材2、3伸長。而且,若解除伸縮片1之拉伸,則彈性絲4收縮,隨著其收縮,片材2、3恢復為拉伸前之狀態。於伸縮片1中,不存在以與彈性絲4正交之狀態結合之其他彈性絲,因此,於將伸縮片1在與彈性絲4延伸之方向相同之方向上拉伸時,該伸縮片1幾乎不發生於與其拉伸方向正交之方向收縮之所謂寬度收縮而伸長。
The stretchability of the
雖亦視具體之用途而定,但伸縮片1之整體之基重較佳為10g/m2以上,更佳為20g/m2以上,而且,較佳為80g/m2以下,更佳為70g/m2以下,具體而言,較佳為10g/m2以上80g/m2以下,更佳為20g/m2以上70g/m2以下。
Although it also depends on the specific application, the overall basis weight of the
關於伸縮片1之厚度,就表現良好之肌膚觸感之觀點而言,較佳為0.32mm以上,更佳為0.36mm以上,進而較佳為0.39mm以上,而且,較佳為0.5mm以下,更佳為0.4mm以下,具體而言,較佳為0.32mm以
上0.5mm以下,更佳為0.36mm以上0.5mm以下,進而較佳為0.39mm以上0.4mm以下。伸縮片1之厚度之測定係以如下方式測定。即,將測定對象之片以0.5cN/cm2之荷重夾於平板間,並測定平板間之距離,藉此,可測定該測定對象片之厚度。
The thickness of the
關於伸縮片1之剝離強度(各片材2、3相對於彈性絲4之剝離強度),就防止於下述伸縮性賦予步驟中對複合片1'賦予伸縮性時之開孔等表現之觀點而言,較佳為5cN/條以上,更佳為10cN/條以上,而且,較佳為30cN/條以下,更佳為20cN/條以下,進而較佳為18cN/條以下,具體而言,較佳為5cN/條以上30cN/條以下,更佳為10cN/條以上20cN/條以下,進而較佳為10cN/條以上18cN/條以下。伸縮片1之剝離強度之測定係以如下方式測定。即,將作為測定對象片之伸縮片1之2片片材2、3分別夾緊之後,以300mm/min之速度使一片材2剝離。藉由測定此時之最大荷重,可測定伸縮片1之剝離強度。
Regarding the peeling strength of the stretch sheet 1 (the peel strength of the
關於伸縮片1,就使之表現充分之伸縮特性之觀點而言,使之沿著彈性絲4延伸之方向伸長100%並自該狀態復原50%時之荷重(以下亦稱為50%復原荷重)與使之沿著彈性絲4延伸之方向伸長50%時之荷重(以下亦稱為50%進展荷重)之比(50%復原荷重/50%進展荷重)較佳為成為45%以上,特佳為成為50%以上,而且,較佳為成為100%以下,具體而言,較佳為成為45%以上100%以下,更佳為成為50%以上100%以下。
Regarding the
作為50%復原荷重,就同樣之觀點而言,較佳為80cN/50mm以上,更佳為120cN/50mm以上,而且,較佳為150cN/50mm以下,更佳為135cN/50mm以下,具體而言,較佳為80cN/50mm以上150cN/50mm 以下,更佳為120cN/50mm以上135cN/50mm以下。 As a 50% recovery load, from the same viewpoint, it is preferably 80 cN/50mm or more, more preferably 120 cN/50mm or more, and more preferably 150 cN/50mm or less, more preferably 135 cN/50mm or less, specifically , Preferably above 80cN/50mm, 150cN/50mm Below, it is more preferably 120 cN/50mm or more and 135 cN/50mm or less.
作為50%進展荷重,就同樣之觀點而言,較佳為80cN/50mm以上,更佳為120cN/50mm以上,進而較佳為245cN/50mm以上,而且,較佳為600cN/50mm以下,更佳為300cN/50mm以下,進而較佳為250cN/50mm以下,具體而言,較佳為80cN/50mm以上600cN/50mm以下,更佳為120cN/50mm以上300cN/50mm以下,進而較佳為245cN/50mm以上250cN/50mm以下。 As the 50% progress load, from the same viewpoint, it is preferably 80cN/50mm or more, more preferably 120cN/50mm or more, still more preferably 245cN/50mm or more, and more preferably 600cN/50mm or less, more preferably 300cN/50mm or less, more preferably 250cN/50mm or less, specifically, preferably 80cN/50mm or more and 600cN/50mm or less, more preferably 120cN/50mm or more and 300cN/50mm or less, and still more preferably 245cN/50mm Above 250cN/50mm or less.
使用拉力試驗機(島津製作所股份有限公司製AG-IS)進行伸縮片之100%伸長循環試驗。具體而言,首先,準備用於100%伸長循環試驗之伸縮片之樣品,使彈性絲延伸之延伸方向與拉伸方向一致,將該樣品安裝於拉力試驗機。此時之夾頭間距離設為150mm。使該樣品向樣品之伸縮方向以300mm/min之速度伸長150mm(夾頭間距離成為總計300mm),並立即以300mm/min之速度復原至初始長度。再者,關於夾頭間之初始長度,可根據成為對象之樣品之長度變更。 A tensile tester (AG-IS manufactured by Shimadzu Corporation) was used to perform a 100% elongation cycle test of the stretch sheet. Specifically, first, prepare a sample of the stretch sheet used in the 100% extension cycle test, make the extension direction of the elastic yarn stretch consistent with the stretching direction, and install the sample in a tensile testing machine. The distance between the chucks at this time is set to 150mm. The sample was extended by 150 mm in the direction of extension and contraction of the sample at a speed of 300 mm/min (the distance between the chucks became 300 mm in total), and immediately returned to the original length at a speed of 300 mm/min. Furthermore, the initial length between the chucks can be changed according to the length of the target sample.
再者,於100%伸長循環試驗中,所謂伸長率100%係指將樣品拉伸至初始長度之2倍之狀態。又,於使之伸長至伸長率100%之過程中,將伸長率成為50%之時點、即成為初始長度之1.5倍之時點之拉伸力設為「50%進展荷重」,於伸長至伸長率100%後復原至初始長度之過程中,將伸長率成為50%之時點之拉伸力設為「50%復原荷重」。 Furthermore, in the 100% elongation cycle test, the so-called 100% elongation refers to the state where the sample is stretched to twice the initial length. Also, in the process of elongating to 100% elongation, the elongation at the point when the elongation becomes 50%, that is, the point when it becomes 1.5 times the initial length, is set as the "50% progressive load", and the elongation reaches the elongation. In the process of recovering to the initial length after the rate of 100%, the tensile force at the point when the elongation becomes 50% is set to "50% recovery load".
又,於測定組裝於市售之尿布等吸收性物品之伸縮片之情形時,藉由有機溶劑將用於該吸收性物品之接著劑溶解,取出伸縮片。此時使用之 有機溶劑係使用彈性體不會溶解者。然後,於使所取出之伸縮片乾燥後,利用上述測定方法對該伸縮片進行測定。關於本說明書中所記載之其他測定,亦係於使以上述方式取出之伸縮片乾燥之後供於各測定。 In addition, when measuring the condition of a stretch sheet assembled in an absorbent article such as a commercially available diaper, the adhesive used for the absorbent article is dissolved with an organic solvent, and the stretch sheet is taken out. Use it at this time Organic solvents will not dissolve elastomers. Then, after drying the taken-out stretch sheet, the stretch sheet is measured by the above-mentioned measuring method. Regarding other measurements described in this manual, it is also provided for each measurement after drying the stretch sheet taken out as described above.
構成伸縮片1之2片片材2、3均能夠伸長。2片片材2、3包含實質上非彈性之纖維而成,典型而言係包含非彈性纖維而成者,實質上為非彈性,典型而言為非彈性。各片材2、3能夠於與彈性絲4延伸之方向(圖1中符號Y所示之長度方向)相同之方向伸長。於本說明書中,所謂「能夠伸長」包含如下情形:(A)片材2、3之構成纖維本身伸長;(B)即便構成纖維本身不伸長,於交點處結合之纖維彼此分離,或藉由纖維彼此之結合等而由複數條纖維形成之立體結構於結構上產生變化,或構成纖維斷開,或纖維之鬆弛被拉伸,從而作為不織布整體亦伸長。
Both
構成伸縮片1之複數條彈性絲4分別遍及伸縮片1之全長而實質上連續,典型而言,如圖1所示之實施形態般,遍及全長而連續。各彈性絲4包含彈性樹脂。複數條彈性絲4以於與延伸方向正交之方向上互不交叉地於一方向延伸之方式排列。各彈性絲4只要互不交叉,則可呈直線狀延伸,或者亦可一面蜿蜒一面延伸。又,作為彈性絲延伸之方向之延伸方向典型而言與長度方向Y一致,與延伸方向正交之方向典型而言與寬度方向X一致。
The plurality of
各彈性絲4以實質上非伸長狀態接合於片材2、3。由於彈性絲4以未伸長之狀態接合於片材2、3,故而伸縮片1不會產生因伸長所致之鬆弛(蠕
變),而有伸縮性不易降低之優點。又,有能夠伸長至片材2、3所能夠伸長之長度或彈性絲4之最大伸長率之優點。較佳為各彈性絲4以實質上非伸長狀態遍及其等之全長熔合於能夠伸長之片材2、3。此處,所謂「熔合」,並非彈性絲4與片材2、3經由接著劑等第三成分而接合,而是指藉由構成彈性絲4之樹脂與構成片材2、3之樹脂之至少一者熔融而將兩者接合。
Each
關於在寬度方向X相鄰之彈性絲4彼此之端部間距離P(參照圖2),就表現良好之肌膚觸感之觀點而言,較佳為0.4mm以上,更佳為0.6mm以上,又,較佳為1.2mm以下,更佳為1mm以下,進而較佳為0.8mm以下,又,較佳為0.4mm以上1.2mm以下,更佳為0.6mm以上1mm以下,進而較佳為0.6mm以上0.8mm以下。端部間距離P可於所有彈性絲間固定,亦可如圖2所示般,於一彈性絲間與其他彈性絲間不同。於端部間距離P不固定之情形時,較佳為彈性絲間之端部間距離之平均值為上述較佳之範圍內,進而較佳為所有彈性絲間之端部間距離為上述較佳之範圍內。
Regarding the distance P between the ends of the
相鄰之彈性絲4彼此之端部間距離P係利用顯微鏡放大將伸縮片之樣品於寬度方向切斷所得之切斷面而測定。測定係於任意之100個部位進行,將其平均值設為端部間距離之平均值。又,測定係切出複數個長度方向之位置不同之切斷面,並測定該複數個切斷面中相鄰之彈性絲彼此之端部間距離。
The distance P between the ends of adjacent
伸縮片1所包含之彈性絲4中,一部分彈性絲係於與該彈性絲延伸之延伸方向(長度方向Y)正交之剖面(以下亦稱為寬度方向剖面)中具有1個以上之內縮部40k之內縮絲40,作為彈性絲4,具備不具有內縮部40k之單絲41、及具有1個以上之該內縮部40k之內縮絲40而構成。此處,所謂絲於與延伸方向正交之剖面具有1個內縮部係指於觀察與該絲之延伸方向正交之剖面時,存在一對自該絲之周面朝向該剖面之內側凹陷之部位。例如,所謂具有2個內縮部係指該凹陷部位存在兩對。更具體而言,於圖2所示之實施形態中,內縮絲40具備具有1個內縮部40k之絲42、及具有2個內縮部40k之絲43。再者,本發明之吸收性物品用伸縮片亦可所包含之彈性絲4全部為具有1個以上之內縮部之內縮絲40。
Among the
單絲41係使自下述紡絲噴嘴12噴出之熔融樹脂於紡絲線上延伸而獲得者。如圖3(a)所示,作為單絲41之直徑D,並無特別限制,但就伸縮片1之質感與彈性絲4之生產性之平衡之觀點而言,較佳為40μm以上,更佳為80μm以上,又,較佳為200μm以下,更佳為180μm以下,又,為40μm以上200μm以下,更佳為80μm以上180μm以下。單絲41之直徑由下述紡絲噴嘴12之直徑決定。
The
內縮絲40例如係自相鄰之2個以上之紡絲噴嘴12噴出之2條以上之單絲彼此於延伸中途黏結而獲得者。內縮絲40之寬度方向剖面之形狀具有複數個圓呈一部分重複之狀態於寬度方向X相連之形狀。具體而言,具有1個內縮部之絲42之寬度方向剖面之形狀如圖3(b)所示般,成為2個圓c1、c2呈一部分重複之狀態於寬度方向X相連之形狀,具有2個內縮部之絲43
之寬度方向剖面之形狀如圖3(c)所示般,成為3個圓c3、c4、c5呈一部分重複之狀態於寬度方向X相連之形狀。相連之圓之一部分重複之部分係圖3(b)及圖3(c)中存在於相鄰之圓與圓之連結部分之以虛線之圓弧包圍之部分。
The inner shrinkage yarn 40 is obtained by bonding two or more monofilaments ejected from two or more
如此,藉由將寬度方向剖面之形狀設為複數個圓呈一部分重複之狀態相連之形狀、即於寬度方向剖面設置1個以上之內縮部40k,例如,與增加單絲41之條數之情形不同,可一面抑制相鄰之彈性絲4彼此之端部間距離變小,一面提高伸縮片1之應力。亦即,藉由將伸縮片1之厚度保持得較厚,可一面使肌膚觸感良好,一面提高伸縮片1之應力。又,與增大單絲41之直徑而增加截面面積之情形相比,可抑制片材2、3與彈性絲4之接觸面積之增大。亦即,可一面增大彈性絲4之截面面積,提高伸縮片1之應力,一面於下述伸縮性賦予步驟中抑制開孔等而保持外觀良好。如此,根據本實施形態之伸縮片,肌膚觸感良好,且可一面保持外觀良好,一面提高彈性絲4之應力。
In this way, by setting the shape of the cross section in the width direction to a shape in which a plurality of circles are partially repeated, that is, providing one or
內縮絲40所具有之內縮部40k如圖1(b)所示般沿著彈性絲4之延伸方向(長度方向Y)延伸。伸縮片1藉由內縮絲40具有沿著彈性絲4之延伸方向延伸之內縮部40k,可使肌膚觸感良好,且可一面保持外觀良好,一面進一步提高彈性絲4之應力。
The
關於內縮絲40,就表現良好之肌膚觸感並保持外觀良好之觀點而言,較佳為於寬度方向剖面之外形中,相鄰之圓之中心間距離P1較其中一個圓之半徑與另一個圓之半徑之和更小,且較其中一個圓之半徑及另一個 圓之半徑中之較短者之半徑更長。具體而言,如圖3(b)所示,於具有1個內縮部之絲42中,較佳為於寬度方向剖面之外形中,相鄰之圓c1、c2之中心間距離P1較其中一個圓c1之半徑r1與另一個圓c2之半徑r2之和(r1+r2)更小,且較其中一個圓c1之半徑r1及另一個圓c2之半徑r2中之較短者之半徑(例如其中一個圓c1之半徑r1)更長。圓c1之半徑r1及圓c2之半徑r2較佳為沿著寬度方向X之方向之半徑。 Regarding the shrinkage yarn 40, from the viewpoint of expressing a good skin touch and maintaining a good appearance, it is preferable that the distance between the centers of adjacent circles P1 is larger than the radius of one circle and another The sum of the radii of one circle is smaller than the radius of one circle and the other The shorter of the radii of the circle has the longer radius. Specifically, as shown in Fig. 3(b), in the wire 42 with one indentation, it is preferable to have a cross-sectional shape in the width direction. The distance P1 between the centers of adjacent circles c1 and c2 is longer The sum of the radius r1 of one circle c1 and the radius r2 of the other circle c2 (r1+r2) is smaller, and is smaller than the radius of the shorter one of the radius r1 of one circle c1 and the radius r2 of the other circle c2 (for example The radius r1) of one of the circles c1 is longer. The radius r1 of the circle c1 and the radius r2 of the circle c2 are preferably radii along the width direction X.
同樣地,如圖3(c)所示,具有2個內縮部之絲43較佳為於寬度方向剖面中,相鄰之圓c3、c4之中心間距離P2較其中一個圓c3之半徑r3與另一個圓c4之半徑r4之和(r3+r4)更小,且較其中一個圓c3之半徑r3及另一個圓c4之半徑r4中之較短者之半徑(例如其中一個圓c3之半徑r3)更長。而且,較佳為相鄰之圓c4、c5之中心間距離P3較其中一個圓c4之半徑r4與另一個圓c5之半徑r5之和(r4+r5)更小,且較其中一個圓c4之半徑r4及另一個圓c5之半徑r5中之較短者之半徑(例如其中一個圓c4之半徑r4)更長。圓c3之半徑r3及圓c5之半徑r5較佳為沿著寬度方向之方向之半徑,圓c4之半徑r4較佳為沿著厚度方向Z之方向之半徑。 Similarly, as shown in Fig. 3(c), the wire 43 with two indentations is preferably in the cross section in the width direction. The distance P2 between the centers of adjacent circles c3 and c4 is larger than the radius r3 of one of the circles c3. The sum of the radius r4 with the other circle c4 (r3+r4) is smaller, and is smaller than the radius r3 of one circle c3 and the radius r4 of the other circle c4 (for example, the radius of one circle c3) r3) Longer. Moreover, it is preferable that the distance P3 between the centers of adjacent circles c4 and c5 is smaller than the sum (r4+r5) of the radius r4 of one of the circles c4 and the radius r5 of the other circle c5, and is smaller than that of the one of the circles c4 The radius of the shorter one of the radius r4 and the radius r5 of the other circle c5 (for example, the radius r4 of one of the circles c4) is longer. The radius r3 of the circle c3 and the radius r5 of the circle c5 are preferably the radius along the width direction, and the radius r4 of the circle c4 is preferably the radius along the thickness direction Z.
於內縮絲40之寬度方向剖面(與延伸方向正交之剖面)中,該內縮絲之寬度方向X之最大長度較佳為100μm以上,更佳為200μm以上,而且,較佳為800μm以下,更佳為400μm以下,進而較佳為500μm以下,特佳為270μm以下,具體而言,較佳為100μm以上800μm以下,更佳為100μm以上400μm以下,進而較佳為200μm以上500μm以下,特佳為200μm以下270μm以下。上述內縮絲之寬度方向X之最大長度係於該內縮絲之寬度方向剖面中寬度方向之長度成為最大之長度,利用以下方法測定。 In the cross section in the width direction of the inward filament 40 (the cross section orthogonal to the extending direction), the maximum length in the width direction X of the inward filament is preferably 100 μm or more, more preferably 200 μm or more, and more preferably 800 μm or less , More preferably 400 μm or less, still more preferably 500 μm or less, particularly preferably 270 μm or less, specifically, preferably 100 μm or more and 800 μm or less, more preferably 100 μm or more and 400 μm or less, and more preferably 200 μm or more and 500 μm or less. It is preferably 200 μm or less and 270 μm or less. The maximum length in the width direction X of the above-mentioned inner shrinkage yarn is the maximum length in the width direction cross section of the inner shrinkage yarn, which is measured by the following method.
內縮絲40之寬度方向X之最大長度係利用顯微鏡放大將伸縮片之樣品於寬度方向切斷時之切斷面而測定。測定係針對1條內縮絲於長度方向之位置不同之任意30個部位進行,將其平均值設為內縮絲40之寬度方向之最大長度。 The maximum length in the width direction X of the inner shrinkage yarn 40 is measured by magnifying the cut surface when the sample of the stretch sheet is cut in the width direction with a microscope. The measurement is performed on any 30 locations where the position of one inner shrinkage yarn in the longitudinal direction is different, and the average value is set as the maximum length of the inner shrinkage yarn 40 in the width direction.
關於具有1個內縮部之絲42,就使之表現良好之肌膚觸感之觀點而言,如圖3(b)所示,厚度方向Z之長度L2相對於寬度方向X之長度L1之比率((L2/L1)×100)較佳為10%以上,更佳為30%以上,而且,較佳為60%以下,更佳為50%以下,具體而言,較佳為10%以上60%以下,更佳為30%以上50%以下。再者,具有1個內縮部之絲42之寬度方向X之長度L1係指寬度方向X上之最大長度,具有1個內縮部之絲42之厚度方向Z之長度L2係指厚度方向Z上之最大長度、即直徑。 Regarding the silk 42 with one indentation, from the viewpoint of making it express a good skin touch, as shown in Figure 3(b), the ratio of the length L2 in the thickness direction Z to the length L1 in the width direction X ((L2/L1)×100) is preferably 10% or more, more preferably 30% or more, more preferably 60% or less, more preferably 50% or less, specifically, preferably 10% or more 60 % Or less, more preferably 30% or more and 50% or less. Furthermore, the length L1 in the width direction X of the thread 42 with one indentation refers to the maximum length in the width direction X, and the length L2 in the thickness direction Z of the thread 42 with one indentation refers to the thickness direction Z The maximum length of the upper part is the diameter.
具有1個內縮部之絲42就同樣之觀點而言,內縮部40k之厚度方向Z之最小長度L3相對於厚度方向Z之長度L2之比率((L3/L2)×100)較佳為5%以上,更佳為10%以上,而且,較佳為50%以下,更佳為30%以下,具體而言,較佳為5%以上50%以下,更佳為10%以上30%以下。
From the same point of view, the ratio of the minimum length L3 in the thickness direction Z of the
具有1個內縮部之絲42之寬度方向X之長度L1就同樣之觀點而言,較佳為100μm以上,更佳為200μm以上,而且,較佳為400μm以下,更佳為300μm以下,具體而言,較佳為100μm以上400μm以下,更佳為200μm以上300μm以下。 From the same point of view, the length L1 in the width direction X of the thread 42 with one inwardly-shaped portion is preferably 100 μm or more, more preferably 200 μm or more, and more preferably 400 μm or less, more preferably 300 μm or less. In particular, it is preferably from 100 μm to 400 μm, and more preferably from 200 μm to 300 μm.
內縮絲40之厚度方向Z之長度L2就同樣之觀點而言,較佳為80μm以 上,更佳為100μm以上,而且,較佳為200μm以下,更佳為180μm以下,具體而言,較佳為80μm以上200μm以下,更佳為100μm以上180μm以下。 From the same point of view, the length L2 in the thickness direction Z of the inner shrinkage yarn 40 is preferably 80 μm or less Above, it is more preferably 100 μm or more, and more preferably 200 μm or less, more preferably 180 μm or less, specifically, preferably 80 μm or more and 200 μm or less, and more preferably 100 μm or more and 180 μm or less.
內縮絲40之內縮部40k處之厚度方向Z之最小長度L3就同樣之觀點而言,較佳為5μm以上,更佳為10μm以上,而且,較佳為60μm以下,更佳為50μm以下,具體而言,較佳為5μm以上60μm以下,更佳為10μm以上50μm以下。
From the same point of view, the minimum length L3 in the thickness direction Z of the
關於具有2個內縮部之絲43,就使之表現良好之肌膚觸感之觀點而言,如圖3(c)所示,厚度方向Z之長度L5相對於寬度方向X之長度L4之比率((L5/L4)×100)較佳為5%以上,更佳為10%以上,而且,較佳為60%以下,更佳為50%以下,具體而言,較佳為5%以上60%以下,更佳為10%以上50%以下。再者,具有2個內縮部之絲43之寬度方向X之長度L4係指寬度方向X上之最大長度,具有2個內縮部之絲43之厚度方向Z之長度L5係指厚度方向Z上之最大長度。 Regarding the silk 43 with two indentations, from the viewpoint of making it express a good skin touch, as shown in Fig. 3(c), the ratio of the length L5 in the thickness direction Z to the length L4 in the width direction X ((L5/L4)×100) is preferably 5% or more, more preferably 10% or more, more preferably 60% or less, more preferably 50% or less, specifically, preferably 5% or more 60 % Or less, more preferably 10% or more and 50% or less. Furthermore, the length L4 in the width direction X of the thread 43 with two indentations refers to the maximum length in the width direction X, and the length L5 in the thickness direction Z of the thread 43 with two indentations refers to the thickness direction Z The maximum length above.
具有2個內縮部之絲43就同樣之觀點而言,內縮部40k處之厚度方向Z之最小長度L6相對於厚度方向Z之長度L5之比率((L6/L5)×100)較佳為5%以上,更佳為10%以上,而且,較佳為50%以下,更佳為30%以下,具體而言,較佳為5%以上50%以下,更佳為10%以上30%以下。
For the yarn 43 with two indentations, from the same point of view, the ratio of the minimum length L6 in the thickness direction Z at the
具有2個內縮部之絲43之寬度方向X之長度L4就同樣之觀點而言,較佳為200μm以上,更佳為300μm以上,而且,較佳為600μm以下,更佳為500μm以下,具體而言,較佳為200μm以上600μm以下,更佳為300 μm以上500μm以下。 From the same point of view, the length L4 of the width direction X of the thread 43 having two indentations is preferably 200 μm or more, more preferably 300 μm or more, and more preferably 600 μm or less, more preferably 500 μm or less. In general, it is preferably 200 μm or more and 600 μm or less, more preferably 300 Above μm and below 500 μm.
具有2個內縮部之絲43之厚度方向Z之長度L5就同樣之觀點而言,較佳為80μm以上,更佳為100μm以上,而且,較佳為200μm以下,更佳為180μm以下,具體而言,較佳為80μm以上200μm以下,更佳為100μm以上180μm以下。 From the same point of view, the length L5 of the thickness direction Z of the thread 43 having two indentations is preferably 80 μm or more, more preferably 100 μm or more, and more preferably 200 μm or less, more preferably 180 μm or less. In particular, it is preferably 80 μm or more and 200 μm or less, and more preferably 100 μm or more and 180 μm or less.
具有2個內縮部之絲43之內縮部40k處之厚度方向Z之最小長度L6就同樣之觀點而言,較佳為5μm以上,更佳為10μm以上,而且,較佳為60μm以下,更佳為50μm以下,具體而言,較佳為5μm以上60μm以下,更佳為10μm以上50μm以下。
From the same point of view, the minimum length L6 in the thickness direction Z at the
於伸縮片1中,就表現良好之肌膚觸感且亦抑制外觀降低之觀點而言,內縮絲40之條數相對於彈性絲4之條數之比率((內縮絲40之條數/彈性絲4之條數)×100)較佳為5%以上,更佳為20%以上,進而較佳為50%以上,而且,較佳為90%以下,更佳為80%以下,進而較佳為70%以下,具體而言,較佳為5%以上90%以下,更佳為20%以上80%以下,進而較佳為50%以上70%以下。再者,圖2等所示之實施形態之內縮絲40係剛紡絲之後為複數條之絲接著而形成者,但作為「彈性絲之條數」,直接以剛紡絲之後之狀態納入伸縮片1之絲、具有1個內縮部之絲42、具有2個內縮部之絲43均分別作為「1條」計數。
In the
於複數條彈性絲4包含複數條內縮絲40之情形時,具有1個內縮部之絲42之條數相對於內縮絲40之條數之比率((具有1個內縮部之絲42之條數/內縮絲40之條數)×100)就同樣之觀點而言,較佳為50%以上,更佳為60%
以上,進而較佳為90%以上,而且,較佳為100%以下,具體而言,較佳為50%以上100%以下,更佳為60%以上100%以下,進而較佳為90%以上100%以下。
In the case where the plurality of
其次,若對伸縮片1之形成材料進行說明,則作為片材2、3,例如,可使用熱風不織布,熱軋不織布、水刺不織布、紡黏不織布、熔噴不織布等不織布。該等不織布可為連續絲或短纖維之不織布。片材2、3可為相同種類者,亦可為不同種類者。此處所謂「相同種類之片材」係指片材之製造過程、片材之構成纖維之種類、構成纖維之纖維直徑或長度、片材之厚度或基重等均相同之片材彼此。於其等中之至少一者不同之情形時,則係「不同種類之片材」。
Next, if the material for forming the
片材2、3之厚度較佳為0.05mm以上,更佳為0.1mm以上,進而較佳為0.15mm以上,較佳為5mm以下,更佳為1mm以下,進而較佳為0.5mm以下,具體而言,較佳為0.05mm以上5mm以下,更佳為0.1mm以上1mm以下,進而較佳為0.15mm以上0.5mm以下。厚度之測定能以0.5cN/cm2之荷重夾於平板間,利用顯微鏡以50~200倍之倍率觀察伸縮片1之剖面,於各視野下分別求出平均厚度,並作為3視野之厚度之平均值求出。片整體之厚度係藉由測定平板間之距離而求出。關於片材2、3之基重,就質感、厚度及設計性等觀點而言,分別較佳為3g/m2以上,更佳為5g/m2以上,而且,較佳為100g/m2以下,更佳為30g/m2以下,具體而言,較佳為3g/m2以上100g/m2以下,更佳為5g/m2以上30g/m2以下。
The thickness of the
作為片材2、3之構成纖維,例如,可使用實質上非彈性之非彈性纖
維,於此情形時,片材2、3可成為以該非彈性纖維為主體之能夠伸長之纖維層。作為該非彈性纖維,例如可列舉包含聚乙烯(PE)、聚丙烯(PP)、聚對苯二甲酸乙二酯(PET)或聚對苯二甲酸丁二酯(PBT)等聚酯、聚醯胺等之纖維等。片材2、3之構成纖維可為短纖維亦可為長纖維,可為親水性亦可為撥水性。又,亦可使用芯鞘型或並排型之複合纖維、分割纖維、異形剖面纖維、捲縮纖維、熱收縮纖維等。該等纖維可單獨使用1種或組合2種以上而使用。
As the constituent fibers of the
作為片材2、3之構成纖維之較佳之一例,可列舉包含低熔點成分及高熔點成分之2種成分以上者。於此情形時,至少藉由低熔點成分之熱熔合而將其構成纖維彼此於纖維交點接合。作為包含低熔點成分及高熔點成分之2種成分以上之芯鞘型之複合纖維,較佳為芯係高熔點PET、PP且鞘係低熔點PET、PP、PE者。尤其是,若使用該等複合纖維,則與彈性絲4之熔合變強,兩者間之剝離變得不易發生,故而較佳。
A preferable example of the constituent fibers of the
彈性絲4係例如以熱塑性彈性體或橡膠等彈性樹脂為原料者。尤其是,若將熱塑性彈性體用作原料,則可與通常之熱塑性樹脂同樣地進行使用擠出機之熔融紡絲,又,以此方式獲得之彈性絲容易熱熔合,因此,適用於伸縮片1。作為熱塑性彈性體,例如可列舉SBS(苯乙烯-丁二烯-苯乙烯)、SIS(苯乙烯-異戊二烯-苯乙烯)、SEBS(苯乙烯-乙烯-丁二烯-苯乙烯)、SEPS(苯乙烯-乙烯-丙烯-苯乙烯)等苯乙烯系彈性體、烯烴系彈性體(乙烯系之α-烯烴彈性體、將乙烯‧丁烯‧辛烯等共聚所得之丙烯系彈性體)、聚酯系彈性體、聚胺基甲酸酯系彈性體等,可單獨使用其等之1種或
組合2種以上使用。
The
其次,以上述一實施形態之伸縮片1之製造方法為例,參照圖4~圖7對本發明之伸縮片1之製造方法進行說明。於圖4~圖7中示出有該伸縮片1之較佳之一實施形態之製造方法中使用之紡絲裝置10及延伸裝置。
Next, taking the manufacturing method of the
如圖4所示,紡絲裝置10具備:紡絲頭11,其將熔融樹脂自紡絲噴嘴紡出而製成熔融或軟化狀態之彈性絲4;及一對夾輥15、15,其等係作為將自紡絲頭11噴出之複數條彈性絲4捲取之捲取機構。一對夾輥15、15典型而言係表面平滑之輥。該紡絲裝置10係藉由所謂熔噴法進行紡絲之裝置,除具備紡絲頭11以外,還具備將彈性樹脂碎片熔融並送出至紡絲頭11之熔融擠出機(未圖示)等,基本構成與公知之熔噴方式之紡絲裝置相同。又,紡絲頭11及一對夾輥15、15電性連接於未圖示之控制部,可藉由控制部分別調整紡絲頭11之樹脂噴出速度及一對夾輥15、15之捲取速度。
As shown in FIG. 4, the
如圖5所示,紡絲頭11係包含形成該頭11之下端面11a之俯視長方形形狀之底壁部11L、及連接於該底壁部11L之周緣之側壁部11S而構成,由該等壁部11L、11S劃分形成之紡絲頭11之內部空間成為自上述熔融擠出機供給之熔融樹脂之貯存部13。於紡絲頭11之下端面11a穿設有複數個紡絲噴嘴12,紡絲頭11之貯存部13經由各紡絲噴嘴12而與外部連通。紡絲頭11之材質可與公知者同樣地設定,通常為金屬。
As shown in FIG. 5, the spinning
如圖5及圖6所示,於紡絲頭11之噴嘴設置面即下端面11a設置有呈鋸
齒狀配置有複數個紡絲噴嘴12之鋸齒狀配置部12A。於鋸齒狀配置部12A中,於下端面11a之第1方向x1隔開間隔而配置有複數個紡絲噴嘴12之噴嘴行12L(圖6中以虛線包圍之部分)於與該第1方向x1正交之第2方向y1、即下端面11a之寬度方向形成複數行(本實施態樣中為2行),且於第1方向x1,於相鄰之噴嘴行12L、12L彼此中紡絲噴嘴12之位置相互錯開半個間距大小。於本說明書中,「呈鋸齒狀配置」不僅包含複數個紡絲噴嘴12如上述之說明般完美地配置之態樣,亦包含產生製造上不可避免之偏差等並非有意之配置之微小偏差之態樣。
As shown in Figures 5 and 6, the nozzle setting surface of the spinning
紡絲頭11中之紡絲噴嘴12為俯視圓形狀,但於本發明中,紡絲噴嘴之俯視形狀並無特別限定,可設為多邊形形狀等任意之形狀。俯視圓形狀之紡絲噴嘴12之直徑會對彈性絲4之直徑及延伸倍率造成影響。就該觀點而言,紡絲噴嘴12之直徑較佳為0.1mm以上,更佳為0.2mm以上,而且,較佳為2mm以下,更佳為0.6mm以下,具體而言,較佳為0.1mm以上2mm以下,更佳為0.2mm以上0.6mm以下。
The spinning
於紡絲噴嘴12之直徑處於上述範圍內之情形時,於鋸齒狀配置部12A中之噴嘴行12L中,相鄰之紡絲噴嘴12、12彼此之第1方向x1之中心間距離(間距p1)就應力表現之觀點而言,較佳為0.5mm以上,更佳為0.8mm以上,而且,較佳為2mm以下,更佳為1.5mm以下,具體而言,較佳為0.5mm以上2mm以下,更佳為0.8mm以上1.5mm以下。於各噴嘴行12L中,所有紡絲噴嘴12以等間距配置。
When the diameter of the spinning
於紡絲噴嘴12之直徑處於上述範圍內之情形時,於在第2方向y1相鄰之噴嘴行12L、12L中,其中一噴嘴行12L中之任意1個紡絲噴嘴12(以下稱為特定噴嘴12)與另一噴嘴行12L中之最接近該特定噴嘴12之紡絲噴嘴12之第1方向x1之中心間距離(間距p2)就肌膚觸感之觀點而言,較佳為0.3mm以上,更佳為0.5mm以上,而且,較佳為1mm以下,更佳為0.8mm以下,具體而言,較佳為0.3mm以上1mm以下,更佳為0.5mm以上0.8mm以下。
When the diameter of the spinning
本實施形態之伸縮片1之製造方法具備熔合步驟,又,具備伸縮性賦予步驟,該熔合步驟係如圖4所示般,一面將自複數個紡絲噴嘴12噴出之熔融或軟化狀態之複數條彈性絲4捲取並延伸,一面於彈性絲4之固化前使之熔合於片材2、3之原料片2'、3',該伸縮性賦予步驟係如圖7所示般,對藉由熔合步驟而獲得之複合片1'實施延伸加工。
The manufacturing method of the
首先,藉由連接於紡絲頭11之未圖示之熔融擠出機,將作為彈性絲4之原料之彈性樹脂碎片熔融混練,將該熔融狀態之彈性樹脂供給至紡絲頭11內之貯存部13(參照圖5)。如此供給之熔融狀態之彈性樹脂如圖4所示般自穿設於紡絲頭11之下端面之複數個紡絲噴嘴12作為熔融或軟化狀態之彈性絲4以樹脂噴出速度V1噴出。如上述般,複數個紡絲噴嘴12呈鋸齒狀配置,因此,於自各紡絲噴嘴12紡出之複數條彈性絲4互不交叉地保持單一之彈性絲4之形態延伸後至到達至與片材2、3之原料片2'、3'之合流位置為止之期間,一部分相鄰之單一之彈性絲4彼此黏結。相鄰之單一之彈性絲4彼此以於上游側以某種程度被冷卻之狀態於下游側一面冷卻一面黏
結。
First, by a melt extruder (not shown) connected to the spinning
如圖4所示,所噴出之熔融或軟化狀態之複數條彈性絲4分別與自原片以相同速度卷出之原料片2'、3'合流,並夾持於兩原料片2'、3'間以捲取速度V2由一對夾輥15、15捲取。
As shown in Fig. 4, the ejected plural
彈性絲4之樹脂噴出速度V1及捲取速度V2除對彈性絲4之直徑及延伸倍率造成影響以外,還對相鄰之單一之彈性絲4之黏結性造成影響。為了有效率地製造圖2及圖3所示之內縮絲40,使用上述紡絲頭11自不待言,但調整該彈性絲4之樹脂噴出速度V1及捲取速度V2亦較為有效。於紡絲頭11之複數個紡絲噴嘴12如先前般呈直線狀配置成一行之情形時,存在相鄰之單一之彈性絲4彼此於上游側、即紡絲噴嘴剛噴出之後之較高之熔融狀態下黏結而變為粗直徑之情況,與原料片2'、3'之接著面積變大,開孔等產生改善之餘地。又,若僅使用將紡絲噴嘴12配置成鋸齒狀之紡絲頭11,則保持單一之彈性絲4之形態延伸,而未形成內縮絲40之情況較多。然而,藉由如本實施形態般使用將複數個紡絲噴嘴12配置成鋸齒狀之紡絲頭11,並且將捲取速度V2、尤其是樹脂噴出速度V1及捲取速度V2調整為下述速度,可有效率地製造內縮絲40。
The resin ejection speed V1 and the winding speed V2 of the
關於一對夾輥15、15之捲取速度V2相對於紡絲頭11之樹脂噴出速度V1之比率((V2/V1)×100),就有效率地製造內縮絲40之觀點而言,較佳為500%以上,更佳為1000%以上,而且,較佳為2500%以下,更佳為2000%以下。
Regarding the ratio of the winding speed V2 of the pair of nip
關於紡絲頭11之樹脂噴出速度V1,就同樣之觀點而言,較佳為5m/min以上,更佳為8m/min以上,而且,較佳為30m/min以下,更佳為25m/min以下,具體而言,較佳為5m/min以上30m/min以下,更佳為8m/min以上25m/min以下。
Regarding the resin ejection speed V1 of the spinning
關於一對夾輥15、15之捲取速度V2,就同樣之觀點而言,較佳為40m/min以上,更佳為70m/min以上,而且,較佳為200m/min以下,更佳為180m/min以下,具體而言,較佳為40m/min以上200m/min以下,更佳為70m/min以上180m/min以下。
Regarding the winding speed V2 of the pair of nip
尤其是,為了有效率地製造具有1個內縮部之絲42,一對夾輥15、15之捲取速度V2較佳為50m/min以上,更佳為70m/min以上,而且,較佳為180m/min以下,更佳為150m/min以下,具體而言,較佳為50m/min以上180m/min以下,更佳為70m/min以上150m/min以下。
In particular, in order to efficiently manufacture the thread 42 with one indentation, the winding speed V2 of the pair of nip
熔融或軟化狀態之彈性絲4於其固化前、即以可熔合之狀態與原料片2'、3'合流。其結果,彈性絲4以被原料片2'、3'夾持之狀態熔合於該等原料片2'、3'。亦即,藉由使固化前之彈性絲4熔合於所搬送之原料片2'、3',彈性絲4被捲取並延伸。於彈性絲4熔合時,未自外部對原料片2'、3'賦予熱。亦即,彈性絲4與兩原料片2'、3'僅藉由可熔合之彈性絲4產生之熔融熱而熔合。其結果,兩原料片2'、3'之構成纖維中僅存在於彈性絲4周圍之纖維與彈性絲4熔合,存在於較其更遠之位置之纖維不熔合。其結果,施加至兩原料片2'、3'之熱控制於最小限度,因此,若兩原料片2'、3'為例如不織布,則該不織布本身本來所具有之良好之質感得以維持。藉此,所獲得之伸縮片1之質感變得良好。
The
於所紡出之熔融或軟化狀態之彈性絲4與原料片2'、3'合流之前之期間,該彈性絲4延伸且分子於延伸方向上配向。又,直徑變小。就使彈性絲4充分地延伸之觀點及防止彈性絲4之斷絲之觀點而言,亦可對所紡出之彈性絲4吹送特定溫度之風(熱風、冷風),來調整彈性絲4之溫度。又,彈性絲4之延伸不僅為構成彈性絲4之樹脂組合物(彈性樹脂)於熔融狀態下之延伸(熔融延伸),亦可為其冷卻過程中之軟化狀態之延伸(軟化延伸)。
Before the spun
為了確實地進行纖維熔合,使彈性絲4與原料片2'、3'合流時之彈性絲4之溫度較佳為100℃以上,更佳為120℃以上。又,就保持彈性絲4之形狀並獲得伸縮特性良好之伸縮片1之觀點而言,該合流時之彈性絲4之溫度較佳為180℃以下,更佳為160℃以下。該合流時之彈性絲4之溫度具體而言較佳為100℃以上180℃以下,更佳為120℃以上160℃以下。該合流時、即彈性絲4與原料片2'、3'接合時之溫度可藉由如下方法測定:使用包含具有與構成彈性絲4之樹脂組合物之熔點不同之熔點之改性聚乙烯或改性聚丙烯等之膜作為與彈性絲4接合之層壓基材,並觀察其接合狀態。此時,若彈性絲4與層壓基材熔合,則接合溫度為層壓基材之熔點以上。
In order to perform fiber fusion reliably, the temperature of the
於彈性絲4與原料片2'、3'合流時(接合時),彈性絲4為實質上非伸長狀態(於解除外力時不會收縮之狀態)。於兩者之接合狀態下,原料片2'、3'之構成纖維之至少一部分向彈性絲4熔合,或者,進而更佳為彈性絲4與原料片2'、3'之構成纖維之至少一部分之兩者熔合。其原因在於可獲得充分之接合強度。所獲得之伸縮片1之伸縮特性受到彈性絲4與原料片2'、3'
之接合點之密度影響。又,伸縮特性除可藉由接合溫度、接合壓力調整以外,亦可藉由利用下述彈性表現處理所進行之原料片2'、3'之延伸(參照圖7)而調整。藉由使原料片2'、3'之構成纖維熔合於彈性絲4,一個個接合點之接合強度變高。若降低接合點之密度,則原料片2'、3'之伸縮阻礙變少,且可獲得具有充分之接合強度之伸縮片1,故而較佳。
When the
於使複數條彈性絲4與原料片2'、3'合流時,使各彈性絲4(單絲41及各內縮絲40)互不交叉地於一方向排列。然後,於使彈性絲4與原料片2'、3'合流並使彈性絲4夾持於兩原料片2'、3'間之狀態下,藉由一對夾輥15、15夾壓該等三者。夾壓之條件會對所獲得之伸縮片1之質感造成影響。若夾壓力較大,則彈性絲4容易陷入至兩原料片2'、3'內。因此,就質感之觀點而言,一對夾輥15、15之夾壓力只要係彈性絲4與兩原料片2'、3'接觸之程度即可,不需要過高之夾壓力。藉由經過以上之熔合步驟,而獲得於2片原料片2'、3'間夾持固定有彈性絲4之複合片1'。
When the plurality of
於圖7中示出有伸縮性賦予步驟(彈性表現處理)之一實施態樣之實施情況。伸縮性賦予步驟係如下步驟,即,於使彈性絲4熔合於原料片2'、3'之後,於該彈性絲4之延伸方向上對該原料片2'、3'進行延伸加工,藉由該步驟,對本來不具有伸長性之原料片2'、3'賦予伸長性。伸縮性賦予步驟之處理對象物係經過圖4所示之熔合步驟而獲得之使彈性絲4熔合於原料片2'、3'而成之複合片1'。
FIG. 7 shows the implementation of one aspect of the scalability imparting step (flexibility performance processing). The stretchability imparting step is the following step, that is, after the
圖7所示之伸縮性賦予步驟係藉由使用具備於圓周方向交替地形成有
齒及齒底之一對齒槽輥17、17之延伸裝置,將複合片1'導入至兩輥17、17間並搬送該複合片1'而實施,藉此,複合片1'沿著其搬送方向、即彈性絲4之延伸方向延伸,而成為作為目標之伸縮片1。該延伸裝置形成為:具備相對於齒槽輥17配置於複合片1'之搬送方向之上游側之一對夾輥16、16、及相對於齒槽輥17配置於該搬送方向之下游側之一對夾輥18、18作為用以使複合片1'通過齒槽輥17、17間之機構,且可藉由利用兩輥16、18適當調整複合片1'之搬送速度而調整複合片1'之延伸程度。
The stretchability imparting step shown in FIG. 7 is formed by alternately forming the
The extension device of one of the teeth and the tooth bottom to the
延伸裝置形成為:具有使一對齒槽輥17、17之一者或兩者之樞支部上下位移之公知之升降機構(未圖示),且能夠調節兩輥17、17間之間隔。例如,將一對齒槽輥17、17以其中一者之齒有間隙地插入至另一者之齒間,另一者之齒有間隙地插入至一者之齒間之方式組合,將複合片1'插入至該狀態之兩齒槽輥17、17間對其進行伸縮性賦予處理。可為一對齒槽輥17、17之兩者由驅動源驅動(共旋輥),亦可為僅一者由驅動源驅動(隨旋輥)。作為齒槽輥17之齒形,可使用普通之漸開線齒形、擺線齒形,特佳為使其等之齒寬較細者。關於上述彈性表現處理,可適當利用專利文獻1所記載之彈性表現處理。
The extension device is formed with a well-known lifting mechanism (not shown) for vertically displacing one or both of the pair of
藉由上述伸縮性賦予步驟,伸縮片1之厚度相對於該伸縮性賦予步驟前之複合片1'之厚度較佳為增加至1.1倍以上,特佳為增加至1.3倍以上,又,較佳為增加至4倍以下,特佳為增加至3倍以下,具體而言,較佳為增加至1.1倍以上4倍以下,更佳為增加至1.3倍以上3倍以下。藉此,兩片材2、3之構成纖維塑性變形並延伸,藉此,纖維變細。與此同時,兩片材
2、3變得更蓬鬆,肌膚觸感較佳,緩衝性變得良好。
Through the above-mentioned stretchability imparting step, the thickness of the
以上,針對本發明,基於其較佳之一實施形態進行了說明,但本發明並不限定於本實施形態。例如,本發明之紡絲頭中之紡絲噴嘴之配置並不限定於上述實施形態形體,可於不脫離本發明之主旨之範圍內適當地進行變更。例如,構成鋸齒狀配置部12A之噴嘴行12L之行數並無特別限制,除如圖5所示般設為2行以外,還可設為3行以上。又,紡絲噴嘴12之平面形狀等只要根據作為製造目標物之伸縮片之用途等適當調整即可,並無特別限制。
Above, the present invention has been described based on one of its preferred embodiments, but the present invention is not limited to this embodiment. For example, the arrangement of the spinning nozzles in the spinning head of the present invention is not limited to the above-mentioned embodiment, and can be appropriately changed within the scope not departing from the gist of the present invention. For example, the number of
藉由本發明之製造方法之實施而製造之吸收性物品用伸縮片例如較佳地用作短褲型拋棄式尿布之外包材。又,並不限於該用途,較佳地用作經期衛生棉或拋棄式尿布等吸收性物品之構成材料。作為吸收性物品之構成材料,例如,可列舉位於較吸收體更靠肌膚側之液體透過性之片(包含表面片、次層等)、或構成拋棄式尿布之外表面之片、用以對腰圍部或腰部、腿周部等賦予彈性伸縮性之片等。又,可用作形成衛生棉之翼之片等。又,即便係除此以外之部位,亦可用於欲賦予伸縮性之部位等。於將藉由本發明之製造方法之實施而製造之吸收性物品用伸縮片作為吸收性物品之構成材料之情形時,只要於伸縮性賦予步驟後具有與其他構成材料(例如吸收體)接合而將伸縮片組裝於吸收性物品之步驟即可。 The stretch sheet for absorbent articles manufactured by implementing the manufacturing method of the present invention is preferably used, for example, as an outer wrapper for shorts-type disposable diapers. Moreover, it is not limited to this use, and it is preferably used as a constituent material of absorbent articles such as menstrual sanitary napkins and disposable diapers. As the constituent material of the absorbent article, for example, a liquid-permeable sheet (including a surface sheet, sub-layer, etc.) located on the skin side of the absorbent body, or a sheet constituting the outer surface of a disposable diaper, is used for contrasting Waist circumference, waist, leg circumference, etc. to impart elastic stretchability, etc. Also, it can be used as a sheet forming the wings of a sanitary napkin. Moreover, even if it is a part other than this, it can also be used for the part to which stretchability is desired. When the stretch sheet for absorbent articles manufactured by the implementation of the manufacturing method of the present invention is used as the constituent material of the absorbent article, it is necessary to join with other constituent materials (for example, an absorbent body) after the stretchability imparting step The step of assembling the stretch sheet to the absorbent article is sufficient.
於本說明書中,於規定有數值之上限值或下限值或者上下限值之情形時,亦包含上限值及下限值本身之值。又,即便未特別明示,亦解釋為 記載有數值之上限值以下或下限值以上或者上下限值之範圍內之所有數值或數值範圍者。 In this manual, when a numerical upper limit, lower limit, or upper limit is specified, the upper limit and the lower limit itself are also included. Also, even if not specifically stated, it is interpreted as All numerical values or numerical ranges within the upper limit value or lower limit value are recorded.
可理解參照本說明書中之上述揭示,能實現本發明之各種變更形態或改變形態。因此,應理解,於基於申請專利範圍之記載之技術範圍內,對於未明確記載於本說明書中之實施形態,亦可實施本發明。 It is understood that various modifications or changes of the present invention can be realized by referring to the above disclosure in this specification. Therefore, it should be understood that the present invention can also be implemented for embodiments that are not explicitly described in this specification within the technical scope based on the description of the claimed scope.
上述專利文獻之記載內容全部作為本說明書之內容之一部分併入本說明書中。 The contents of the aforementioned patent documents are all incorporated into this specification as part of the content of this specification.
本案係主張基於在2018年8月6日提出申請之日本專利申請案2018-147827之優先權的申請案,日本專利申請案2018-147827之記載內容全部作為本說明書之一部分併入本說明書中。 This case is an application claiming priority based on the Japanese patent application 2018-147827 filed on August 6, 2018, and the contents of the Japanese patent application 2018-147827 are all incorporated into this specification as a part of this specification.
又,本發明進而揭示以下之伸縮片及其製造方法。 In addition, the present invention further discloses the following stretch sheet and its manufacturing method.
一種吸收性物品用伸縮片,其係以互不交叉地於一方向延伸之方式排列之複數條彈性絲以實質上非伸長狀態遍及其等之全長接合於能夠伸長之片材者,且複數條上述彈性絲中之一部分或全部係於與長度方向正交之剖面中具有1個以上之內縮部之內縮絲。 A stretch sheet for absorbent articles, wherein a plurality of elastic filaments arranged in a manner extending in one direction without crossing each other are joined to a stretchable sheet material in a substantially non-stretched state over its entire length, and a plurality of One part or all of the above-mentioned elastic yarn is an inward yarn having one or more indented parts in a cross section orthogonal to the longitudinal direction.
如上述<1>之吸收性物品用伸縮片,其中上述內縮絲之與上述長度方向正交之剖面之形狀具有複數個圓以一部分重複之狀態相連之形狀,相鄰之圓之中心間距離較其中一個圓之半徑與另一個圓之半徑之和更短,且較該一個圓之半徑及該另一個圓之半徑中之較短者之半徑更長。 The stretch sheet for absorbent articles as in the above item <1>, wherein the shape of the cross section of the inner shrinkage yarn perpendicular to the longitudinal direction has a shape in which a plurality of circles are connected in a partially repeated state, and the distance between the centers of adjacent circles It is shorter than the sum of the radius of one circle and the radius of the other circle, and is longer than the radius of the shorter one of the radius of the one circle and the radius of the other circle.
如上述<1>或上述<2>之吸收性物品用伸縮片,其中上述內縮絲之條數相對於上述彈性絲之條數之比率為5%以上90%以下。 The stretch sheet for absorbent articles according to the above-mentioned <1> or the above-mentioned <2>, wherein the ratio of the number of inwardly shrinking filaments to the number of elastic filaments is 5% to 90%.
如上述<1>至上述<3>中任一項之吸收性物品用伸縮片,其中上述內縮絲之條數相對於上述彈性絲之條數之比率為5%以上90%以下,較佳為20%以上80%以下,更佳為50%以上70%以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <3>, wherein the ratio of the number of shrinkable filaments to the number of elastic filaments is 5% or more and 90% or less, preferably It is 20% or more and 80% or less, more preferably 50% or more and 70% or less.
如上述<1>至上述<4>中任一項之吸收性物品用伸縮片,其中上述內縮絲之條數相對於上述彈性絲之條數之比率為50%以上70%以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <4>, wherein the ratio of the number of the inner shrinkable filaments to the number of the elastic filaments is 50% or more and 70% or less.
如上述<1>至上述<5>中任一項之吸收性物品用伸縮片,其包含複數條上述內縮絲,且具有1個內縮部之內縮絲之條數相對於上述內縮絲之條數之比率為50%以上。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <5>, which comprises a plurality of the above-mentioned shrinkage yarns, and the number of the inner shrinkage yarns having one shrinkage part is relative to the above-mentioned shrinkage The ratio of the number of threads is more than 50%.
如上述<1>至上述<6>中任一項之吸收性物品用伸縮片,其包含複數條上述內縮絲,且具有1個內縮部之內縮絲之條數相對於上述內縮絲之條數之比率為50%以上100%以下,較佳為60%以上100%以下,更佳為90%以上100%以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <6>, which includes a plurality of the above-mentioned shrinkable yarns, and the number of the inner shrinkable yarns having one shrinking portion is relative to the above-mentioned shrinking The ratio of the number of threads is 50% to 100%, preferably 60% to 100%, and more preferably 90% to 100%.
如上述<1>至上述<7>中任一項之吸收性物品用伸縮片,其包含複數 條上述內縮絲,且具有1個內縮部之內縮絲之條數相對於上述內縮絲之條數之比率為90%以上100%以下。 The stretch sheet for absorbent articles as in any one of the above <1> to the above <7>, which contains plural The ratio of the number of inward filaments with one inward shrinkage portion to the number of inward filaments is 90% to 100%.
如上述<1>至上述<8>中任一項之吸收性物品用伸縮片,其中相鄰之上述彈性絲彼此之端部間距離之平均值為0.3mm以上2mm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <8>, wherein the average value of the distance between the ends of the adjacent elastic yarns is 0.3 mm or more and 2 mm or less.
如上述<1>至上述<9>中任一項之吸收性物品用伸縮片,其中相鄰之上述彈性絲彼此之端部間距離之平均值為0.4mm以上1.2mm以下,較佳為0.6mm以上1mm以下,更佳為0.6mm0.8mm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <9>, wherein the average value of the distance between the ends of the adjacent elastic yarns is 0.4mm or more and 1.2mm or less, preferably 0.6 mm or more and 1mm or less, more preferably 0.6mm or 0.8mm or less.
如上述<1>至上述<10>中任一項之吸收性物品用伸縮片,其中相鄰之上述彈性絲彼此之端部間距離之平均值為0.6mm以上0.8mm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <10>, wherein the average value of the distance between the ends of the adjacent elastic yarns is 0.6 mm or more and 0.8 mm or less.
如上述<1>至上述<11>中任一項之吸收性物品用伸縮片,其中於上述內縮絲之與長度方向正交之剖面中,上述內縮絲之最大長度為100μm以上800μm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <11>, wherein in the cross section orthogonal to the longitudinal direction of the internal shrinkage yarn, the maximum length of the internal shrinkage yarn is 100 μm or more and 800 μm or less .
如上述<1>至上述<12>中任一項之吸收性物品用伸縮片,其中於上述內縮絲之與長度方向正交之剖面中,上述內縮絲之最大長度為100μm以上800μm以下,較佳為100μm以上400μm以下,更佳為200μm以上500μm以下,進而較佳為200μm以下270μm以下。 The stretch sheet for an absorbent article according to any one of the above <1> to the above <12>, wherein in the cross section orthogonal to the longitudinal direction of the internal shrinkable yarn, the maximum length of the internal shrinkable yarn is 100 μm or more and 800 μm or less It is preferably 100 μm or more and 400 μm or less, more preferably 200 μm or more and 500 μm or less, and still more preferably 200 μm or less and 270 μm or less.
如上述<1>至上述<13>中任一項之吸收性物品用伸縮片,其中於上述內縮絲之與長度方向正交之剖面中,上述內縮絲之最大長度為200μm以上270μm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <13>, wherein in the cross section orthogonal to the longitudinal direction of the internal shrinkable yarn, the maximum length of the internal shrinkable yarn is 200 μm or more and 270 μm or less .
如上述<1>至上述<14>中任一項之吸收性物品用伸縮片,其中以實質上非伸長狀態接合於片材之上述彈性絲係以於解除外力時不會收縮之狀態遍及其等之全長接合於能夠伸長之片材。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <14>, wherein the elastic yarn joined to the sheet in a substantially non-stretched state is in a state that does not shrink when the external force is released. The entire length of the same is joined to the stretchable sheet.
如上述<1>至上述<15>中任一項之吸收性物品用伸縮片,其中於具有1個內縮部之內縮絲,於觀察與該內縮絲之長度方向正交之剖面時,存在一對自該絲之周面朝向該剖面之內側凹陷之部位。 The stretch sheet for absorbent articles as described in any one of the above <1> to the above <15>, wherein when an indented yarn having one indented portion is observed, a cross section orthogonal to the longitudinal direction of the indented yarn is observed , There is a pair of parts recessed from the circumferential surface of the silk toward the inner side of the cross section.
如上述<1>至上述<16>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之厚度為0.32mm以上0.5mm以下,較佳為0.36mm以上0.5mm以下,更佳為0.39mm以上0.4mm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to <16>, wherein the thickness of the stretch sheet for absorbent articles is 0.32 mm or more and 0.5 mm or less, preferably 0.36 mm or more and 0.5 mm or less, More preferably, it is 0.39 mm or more and 0.4 mm or less.
如上述<1>至上述<17>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之厚度為0.39mm以上0.4mm以下。 The stretch sheet for absorbent articles according to any one of <1> to <17> above, wherein the thickness of the stretch sheet for absorbent articles is 0.39 mm or more and 0.4 mm or less.
如上述<1>至上述<18>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之剝離強度為5cN/條以上30cN/條以下,較佳為10cN/條以上20cN/條以下,更佳為10cN/條以上18cN/條以下。。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <18>, wherein the peel strength of the stretch sheet for absorbent articles is 5 cN/bar or more and 30 cN/bar or less, preferably 10 cN/bar or more 20 cN/line or less, more preferably 10 cN/line or more and 18 cN/line or less. .
如上述<1>至上述<19>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之剝離強度為10cN/條以上18cN/條以下。 The stretch sheet for an absorbent article according to any one of the above <1> to the above <19>, wherein the peel strength of the stretch sheet for the absorbent article is 10 cN/piece or more and 18 cN/piece or less.
如上述<1>至上述<20>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長100%並自該狀態復原50%時之荷重與沿著上述彈性絲之延伸方向伸長50%時之荷重之比為45%以上100%以下,較佳為50%以上100%以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <20>, wherein the stretch sheet for the absorbent article stretches 100% along the extension direction of the elastic yarn and recovers 50% from the state The ratio of the load to the load at 50% extension along the extension direction of the elastic yarn is 45% or more and 100% or less, preferably 50% or more and 100% or less.
如上述<1>至上述<21>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長100%並自該狀態復原50%時之荷重與沿著上述彈性絲之延伸方向伸長50%時之荷重之比為50%以上100%以下。 The stretch sheet for absorbent articles according to any one of <1> to <21> above, wherein the stretch sheet for absorbent articles stretches 100% along the extension direction of the elastic yarn and recovers 50% from this state The ratio of the load to the load at 50% extension along the extension direction of the elastic yarn is 50% or more and 100% or less.
如上述<1>至上述<22>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長100%並自該狀態復原50%時之荷重為80cN/50mm以上150cN/50mm以下,較佳為120cN/50mm以上135cN/50mm以下。 The stretch sheet for absorbent articles according to any one of <1> to <22> above, wherein the stretch sheet for absorbent articles stretches 100% along the extension direction of the elastic yarn and recovers 50% from this state The load is 80cN/50mm or more and 150cN/50mm or less, preferably 120cN/50mm or more and 135cN/50mm or less.
如上述<1>至上述<23>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長100%並自該狀態復原50%時之荷重為120cN/50mm以上135cN/50mm以下。 The stretch sheet for absorbent articles according to any one of <1> to <23> above, wherein the stretch sheet for absorbent articles stretches 100% along the extension direction of the elastic yarn and recovers 50% from this state The load is above 120cN/50mm and below 135cN/50mm.
如上述<1>至上述<24>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長50%時之荷重為80cN/50mm以上600cN/50mm以下,較佳為120cN/50mm以上300cN/50mm以下,更佳為245cN/50mm以上250cN/50mm以下。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <24>, wherein the stretch sheet for the absorbent article has a load of 80cN/50mm or more when it stretches 50% along the extension direction of the elastic yarn 600cN/50mm or less, preferably 120cN/50mm or more and 300cN/50mm or less, more preferably 245cN/50mm or more and 250cN/50mm or less.
如上述<1>至上述<25>中任一項之吸收性物品用伸縮片,其中上述吸收性物品用伸縮片之沿著上述彈性絲之延伸方向伸長50%時之荷重為245cN/50mm以上250cN/50mm以下。 The stretch sheet for an absorbent article according to any one of the above <1> to the above <25>, wherein the stretch sheet for the absorbent article has a load of 245cN/50mm or more when it stretches 50% along the extension direction of the elastic yarn Below 250cN/50mm.
如上述<1>至上述<26>中任一項之吸收性物品用伸縮片,其中作為上述彈性絲之條數,以剛紡絲之後之狀態直接納入上述吸收性物品用伸縮片之絲、具有1個內縮部之上述內縮絲、具有2個內縮部之上述內縮絲均分別作為1條計數。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <26>, wherein the number of elastic yarns is directly incorporated into the stretch sheet for absorbent articles in the state immediately after spinning. The above-mentioned indented yarn with one indented portion and the above-mentioned indented yarn with two indented portions are each counted as one.
如上述<1>至上述<27>中任一項之吸收性物品用伸縮片,其中上述內縮部於上述彈性絲之長度方向延伸。 The stretch sheet for absorbent articles according to any one of the above-mentioned <1> to the above-mentioned <27>, wherein the indented portion extends in the longitudinal direction of the elastic yarn.
如上述<1>至上述<28>中任一項之吸收性物品用伸縮片,其中複數條上述彈性絲以實質上非伸長狀態遍及其等之全長熔合於能夠伸長之片材。 The stretch sheet for absorbent articles according to any one of the above <1> to the above <28>, wherein a plurality of the elastic yarns are fused to the stretchable sheet material in a substantially non-stretched state over its entire length.
一種吸收性物品,其具有如上述<1>至上述<29>中任一項之吸收性物品用伸縮片。 An absorbent article having the stretch sheet for an absorbent article according to any one of the above <1> to the above <29>.
一種短褲型拋棄式尿布,其將如上述<1>至上述<29>中任一項之吸收性物品用伸縮片用於外包材。 A shorts-type disposable diaper which uses the stretch sheet for absorbent articles as described in any one of the above <1> to the above <29> as an outer covering material.
一種吸收性物品用伸縮片之製造方法,其具備熔合步驟,該熔合步驟係使自複數個紡絲噴嘴紡出之熔融或軟化狀態之複數條彈性絲於該彈性絲固化前與片材之原料片接觸,並與該原料片熔合,於上述熔合步驟中,使用紡絲頭及捲取機構,該紡絲頭係於第1方向隔開間隔配置有複數個上述紡絲噴嘴之噴嘴行於與該第1方向正交之第2方向形成複數行,且於在該第2方向相鄰之該噴嘴行彼此中,上述紡絲噴嘴之位置於上述第1方向錯開,該捲取機構將自該紡絲頭之紡絲噴嘴紡出之彈性絲捲取,且將自上述紡絲噴嘴紡出之熔融或軟化狀態之上述彈性絲以40m/min以上200m/min以下之捲取速度捲取。 A method for manufacturing a stretch sheet for absorbent articles, which has a fusion step that makes a plurality of elastic filaments in a molten or softened state spun from a plurality of spinning nozzles and the raw material of the sheet before the elastic filaments solidify The sheet is brought into contact with and fused with the raw sheet. In the above fusion step, a spinning head and a winding mechanism are used. The spinning head is arranged in the first direction at intervals with a plurality of nozzles of the spinning nozzles. The second direction orthogonal to the first direction forms a plurality of rows, and among the nozzle rows adjacent to each other in the second direction, the positions of the spinning nozzles are staggered in the first direction, and the winding mechanism The elastic yarn spun from the spinning nozzle of the spinning head is wound, and the elastic yarn in the molten or soft state spun from the spinning nozzle is wound at a winding speed of 40m/min or more and 200m/min or less.
如上述<32>之吸收性物品用伸縮片之製造方法,其中於上述熔合步驟中,將熔融或軟化狀態之上述彈性絲自上述紡絲噴嘴以5m/min以上30m/min以下之樹脂噴出速度紡出。 The manufacturing method of the stretch sheet for absorbent articles as in the above <32>, wherein in the above fusion step, the above-mentioned elastic yarn in a molten or softened state is ejected from the above-mentioned spinning nozzle at a resin ejection speed of 5m/min or more and 30m/min or less Spun out.
如上述<32>或上述<33>之吸收性物品用伸縮片之製造方法,其中上述捲取速度為75m/min以上150m/min以下。 The manufacturing method of the stretch sheet for absorbent articles according to the above <32> or the above <33>, wherein the winding speed is 75m/min or more and 150m/min or less.
如上述<32>至上述<34>中任一項之吸收性物品用伸縮片之製造方 法,其中於在上述第2方向相鄰之上述噴嘴行中,其中一噴嘴行中之任意噴嘴與另一噴嘴行中之最接近上述任意噴嘴之噴嘴於上述第1方向上之中心間距離為1mm以下。 The manufacturer of the stretch sheet for absorbent articles as in any one of the above <32> to the above <34> Method, wherein in the nozzle rows adjacent in the second direction, the distance between the centers of any nozzle in one nozzle row and the nozzle closest to the any nozzle in the other nozzle row in the first direction is Below 1mm.
如上述<32>至上述<35>中任一項之吸收性物品用伸縮片之製造方法,其具備伸縮性賦予步驟,該伸縮性賦予步驟係藉由使複數條上述彈性絲熔合於上述原料片所得之複合片通過於圓周方向交替地形成有齒及齒底之一對齒槽輥間,而對該複合片賦予伸縮性。 The manufacturing method of a stretch sheet for absorbent articles as described in any one of the above <32> to the above <35>, which includes a stretchability imparting step by fusing a plurality of the elastic filaments to the raw material The composite sheet obtained from the sheet is provided with a pair of tooth groove rollers alternately formed with teeth and tooth bottoms in the circumferential direction, thereby imparting stretchability to the composite sheet.
一種吸收性物品之製造方法,其具有將如上述<1>至上述<29>中任一項之吸收性物品用伸縮片組裝於吸收性物品之步驟。 A method for manufacturing an absorbent article, which has a step of assembling the stretch sheet for an absorbent article according to any one of the above <1> to the above <29> to the absorbent article.
一種吸收性物品之製造方法,其具有將利用如上述<32>至上述<36>中任一項之製造方法所製造之吸收性物品用伸縮片與其他構成材料接合之步驟。 A manufacturing method of an absorbent article, which has a step of joining the stretch sheet for an absorbent article manufactured by the manufacturing method of any one of the above-mentioned <32> to the above-mentioned <36> and other constituent materials.
以下,使用實施例對本發明更詳細地進行說明,但本發明並不受該實施例任何限定。 Hereinafter, the present invention will be described in more detail using examples, but the present invention is not limited in any way by the examples.
使用與圖4~圖6所示之紡絲裝置同樣之構成之裝置、及與圖7所示之延伸裝置同樣之構成之裝置,製造具有與圖1~圖2所示之伸縮片同樣之構
成且複數條彈性絲包含內縮絲之伸縮片。具體而言,使用具備如上述紡絲頭11般所有紡絲噴嘴呈鋸齒狀配置之紡絲頭的紡絲裝置獲得複合片,使該複合片如圖7所示般通過具備如一對齒槽輥17、17般於圓周方向交替地形成有齒及齒底之一對齒槽輥的延伸裝置,藉此,對該複合片賦予伸縮性,從而製造彈性絲中包含具有1個內縮部之絲之伸縮片。所使用之裝置中之紡絲噴嘴之間距、樹脂噴出速度及捲取速度如下述表1,所製造之伸縮片之彈性絲所包含之具有1個內縮部之絲之構成如下述表1。又,所使用之材料等如下所述。
Using a device with the same structure as the spinning device shown in Figs. 4 to 6 and a device with the same structure as the stretching device shown in Fig. 7 to produce the same structure as the stretch sheet shown in Figs. 1 to 2
A plurality of elastic filaments include stretch sheets with shrinkable filaments. Specifically, a spinning device equipped with a spinning head in which all spinning nozzles are arranged in a zigzag pattern like the above-mentioned
‧彈性絲:苯乙烯系熱塑性彈性體 ‧Elastic yarn: styrene-based thermoplastic elastomer
‧片材:包含芯部包含PET、鞘包含PE之複合纖維(非彈性纖維、纖維粗度3.3dtex)之基重20g/m2之熱風不織布 ‧Sheet: Hot-air non-woven fabric with a basis weight of 20g/m 2 including composite fiber (non-elastic fiber, fiber thickness 3.3dtex) containing PET in the core and PE in the sheath
‧伸縮片之基重:56g/m2 ‧Basis weight of stretch film: 56g/m 2
除變更樹脂噴出速度及捲取速度以外,與實施例1同樣地製造伸縮片。 Except for changing the resin ejection speed and the winding speed, a stretch sheet was produced in the same manner as in Example 1.
除變更樹脂噴出速度及捲取速度以外,與實施例1同樣地製造伸縮片。 Except for changing the resin ejection speed and the winding speed, a stretch sheet was produced in the same manner as in Example 1.
除使用所有紡絲噴嘴呈直線狀配置成一行之紡絲頭以外,與實施例1同樣地製造伸縮片。 Except for using a spinning head in which all the spinning nozzles are arranged in a line in a straight line, a stretch sheet was produced in the same manner as in Example 1.
除變更樹脂噴出速度、及使用所有紡絲噴嘴以間距1mm呈直線狀配置成 一行之紡絲頭以外,與實施例1同樣地製造伸縮片。 In addition to changing the resin ejection speed, and using all spinning nozzles to be arranged in a straight line with a pitch of 1mm Except for the spinning head of one row, the stretch sheet was manufactured in the same manner as in Example 1.
針對在實施例1~4中製造之伸縮片及在比較例1~3中製造之伸縮片,以0.5cN/cm2之荷重夾於平板間,使用基恩士股份有限公司製造之雷射厚度計測量平板間之距離,藉此,測定該伸縮片之厚度。又,將伸縮片之各片材夾緊之後,以300mm/min之速度使片材剝離,使用島津製作所股份有限公司製造之拉力試驗機測量此時之最大荷重,藉此,測定伸縮片之剝離強度。進而,利用上述方法測定100%伸長循環試驗中之伸縮片之伸縮力,藉此,測定伸縮片之50%復原荷重及50%進展荷重。然後,以下述評估基準,藉由目視對外觀進行評估。將以上結果示於表1。 For the stretch sheets manufactured in Examples 1 to 4 and the stretch sheets manufactured in Comparative Examples 1 to 3, sandwiched between the plates with a load of 0.5 cN/cm 2 , using the laser thickness manufactured by Keyence Corporation The meter measures the distance between the plates, thereby measuring the thickness of the stretch sheet. In addition, after clamping each sheet of the stretch sheet, the sheet was peeled off at a speed of 300 mm/min, and the maximum load at that time was measured using a tensile tester manufactured by Shimadzu Corporation to measure the peeling of the stretch sheet strength. Furthermore, the above-mentioned method was used to measure the stretching force of the stretch sheet in the 100% extension cycle test, thereby measuring the 50% recovery load and 50% progress load of the stretch sheet. Then, the appearance was evaluated visually based on the following evaluation criteria. The above results are shown in Table 1.
伸縮片之外觀之評估係藉由目視觀察評估對象伸縮片而實施,將無開孔等之情形設為A,將略微能看到開孔等之情形設為B,將觀察到開孔等之情形設為C。 The evaluation of the appearance of the stretch sheet is carried out by visually observing the stretch sheet of the evaluation target. The case where there is no hole etc. is set to A, the case where the hole is slightly visible is set to B, and the hole etc. is observed. The situation is set to C.
關於內縮絲之條數相對於彈性絲之條數之比率,利用基恩士股份有限公司製造之顯微鏡放大將伸縮片於寬度方向切斷所得之切斷面,於剖面方向觀察100條彈性絲,並對其中具有內縮部之絲之條數進行計數,將其作為內縮絲之條數來算出。對該內縮絲中內縮部為1個之內縮絲之條數進行計數,將其設為具有1個內縮部之絲之條數,算出具有1個內縮部之絲之條數相對於內縮絲之條數之比率。相鄰之彈性絲彼此之端部間距離係利用基恩士股份有限公司製造之顯微鏡放大將伸縮片於寬度方向切斷所得之切斷面,於任意之100個部位測定其端部間距離,將其平均值設為端部間距離。 Regarding the ratio of the number of shrinkage yarns to the number of elastic yarns, the cross section obtained by cutting the stretch sheet in the width direction using a microscope manufactured by Keyence Corporation was used to observe 100 elastic yarns in the cross-sectional direction , And count the number of filaments with internal shrinkage, and calculate it as the number of internal shrinkage. Count the number of inner shrinkage filaments with 1 inner shrinkage in the inner shrinkage yarn, set it as the number of filaments with 1 inner shrinkage portion, and calculate the number of filaments with 1 inner shrinkage portion Relative to the ratio of the number of shrinkable filaments. The distance between the ends of adjacent elastic yarns is a cross-section obtained by magnifying the stretch sheet in the width direction using a microscope manufactured by Keyence Corporation, and measuring the distance between the ends at any 100 locations. Let the average value be the distance between the ends.
如表1所示,實施例1~4之伸縮片包含內縮絲,50%復原荷重與比較例1之伸縮片相等或為其以上,但相較於比較例1之伸縮片,相鄰之彈性絲彼此之端部間距離(間距)變寬,厚度亦變厚。又,實施例1~4之伸縮片之50%復原荷重與比較例2之伸縮片相等或為其以上,但相較於比較例2之伸縮片,外觀得以良好地保持。實施例1~4之伸縮片與比較例3之伸縮片同樣地外觀得以良好地保持,但50%復原荷重大得多。 As shown in Table 1, the stretch sheets of Examples 1 to 4 include internal shrinkage filaments, and the 50% recovery load is equal to or higher than that of the stretch sheet of Comparative Example 1, but compared to the stretch sheet of Comparative Example 1, adjacent ones The distance (spacing) between the ends of the elastic yarns becomes wider and the thickness becomes thicker. In addition, the 50% recovery load of the stretch sheet of Examples 1 to 4 is equal to or higher than that of the stretch sheet of Comparative Example 2, but compared to the stretch sheet of Comparative Example 2, the appearance is maintained well. The stretch sheets of Examples 1 to 4 have the same appearance as the stretch sheets of Comparative Example 3, but the 50% recovery load is much larger.
由此,根據本發明之伸縮片可知,藉由包含內縮絲,可一面良好地維持肌膚觸感及外觀,一面提高應力。 Thus, according to the stretch sheet of the present invention, it can be seen that by including the inner shrinkable yarn, the touch and appearance of the skin can be maintained well, and the stress can be improved.
又,由實施例1~4中所採用之製造條件可知,藉由使用將紡絲噴嘴配 置成鋸齒狀之紡絲頭,將捲取速度、或樹脂噴出速度及捲取速度設定為特定之速度範圍,可高效率地製造包含內縮絲且肌膚觸感、外觀及50%復原荷重優異之伸縮片。 In addition, it can be seen from the manufacturing conditions used in Examples 1 to 4 that the spinning nozzle is equipped with The spinning head is set in a zigzag shape, and the winding speed, or the resin ejection speed and the winding speed are set to a specific speed range, which can efficiently produce shrinkage yarns with excellent skin touch, appearance and 50% recovery load The stretch film.
根據本發明之伸縮片,可提供一種能夠一面良好地維持肌膚觸感及外觀一面提高應力之伸縮片。又,根據本發明之伸縮片之製造方法,可提供一種能夠有效率地製造該伸縮片之伸縮片之製造方法。 According to the stretch sheet of the present invention, it is possible to provide a stretch sheet that can improve stress while maintaining good skin touch and appearance. Moreover, according to the method for manufacturing a stretch sheet of the present invention, a method for manufacturing a stretch sheet capable of efficiently manufacturing the stretch sheet can be provided.
1‧‧‧伸縮片 1‧‧‧Stretching film
2‧‧‧片材 2‧‧‧Sheet
3‧‧‧片材 3‧‧‧Sheet
4‧‧‧彈性絲 4‧‧‧Elastic yarn
40‧‧‧內縮絲 40‧‧‧Inner shrink wire
41‧‧‧單絲 41‧‧‧monofilament
42‧‧‧絲 42‧‧‧Si
43‧‧‧絲 43‧‧‧silk
X‧‧‧寬度方向 X‧‧‧Width direction
Y‧‧‧長度方向 Y‧‧‧Length direction
Z‧‧‧厚度方向 Z‧‧‧Thickness direction
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- 2019-04-01 US US16/613,091 patent/US20200383842A1/en not_active Abandoned
- 2019-04-01 DE DE112019000068.3T patent/DE112019000068T5/en active Pending
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