TWI657137B - Method and device for making alkaline functional liquor - Google Patents

Abstract

The invention relates to a method and a device for preparing an alkaline functional liquor, and the obtained alkaline liquor is composed of Use a common small amount of gas to replace the original organic acid in the wine, and use a stable body mineral supplement in the production, and seal it with a small amount of gas; after pouring into the cup, a small amount of gas contained in the wine Will be released quickly, and the balance of atmospheric concentration, so that the pH of the wine continues to rise to within the calibration range, and the reverse reaction of aroma loss and pH drop is not easy to occur during the storage period, and in the production, can not be added because it is weak acid Or a weakly basic material or extract improves many of the problems of alkaline functional wines in the prior art.

Description

Method and device for preparing alkaline functional liquor

The invention belongs to the technical field of wine brewing, and particularly relates to a method and a device for preparing alkaline functional liquor.

The pH of most wines is acidic; the pH of distilled liquor and fermented wine is 4.5~5.5, and the pH of beer is 4.2~4.4; during the decomposition of alcohol in alcohol, a large amount of acetaldehyde produced by enzyme metabolism stays in the liver and blood. And organs, can not be quickly metabolized and accumulated, causing great harm to the human body, and after drinking alcohol will produce a hangover reaction, such as alcohol to reduce the ability of the gastrointestinal mucosa to resist stomach acid (stomach pain), the liver produced by the continued metabolism of ethanol Hypoglycemia, acetaldehyde produced after metabolism damage liver cells (liver burden), lactic acid accumulation causes lower limbs or body aches (after enzyme metabolism, alcohol is converted into acid substances, more alkaline substances are needed to achieve body digestion and acid-base Balanced); alkaline alcohols are produced to prevent the above problems. Compared with ordinary alcoholic beverages, they will accelerate metabolism after drinking, and prevent the occurrence of hangover reaction and electrolyte loss in the body, and promote the acid-base circulation balance; During the brewing process, many kinds of organic acids and organic ester compounds are produced, and the tradition has led to the development of various white wines of different brewing processes. A variety of flavoring substances are combined in different proportions to form the main flavor of various liquors, thereby developing a variety of liquor flavors; for the production of alkaline liquors in the past, the addition of organic acids in liquors (acetic acid, lactic acid, caproic acid, etc.), but its aroma substances (ethyl acetate, ethyl lactate, ethyl acrylate, etc.) are in the weakly alkaline semi-finished products or in the factory environment, some will Occurrence of organic ester compounds The reverse reaction of hydrolysis (the amount of esters determines the degree of classification of liquor products) and the decrease of pH value. The above two conditions are mainly as follows: 1. The main material used to neutralize organic acids in wine is grass ash. Alkaline inorganic substances contained in (potassium carbonate); and formation of different organic ester compounds (ethyl acetate, ethyl lactate, ethyl acrylate, etc.), which are ethanol and its organic acid components (acetic acid, Lactic acid, caproic acid, etc.) are slowly reacted in a fermentation and storage environment. When the semi-finished product or the alkaline alkaline wine is in a weakly alkaline environment, the different organic ester compounds can be reversely reacted, so that the semi-finished products or the excipient substances in the ex-factory products are reversely reacted into organic acids, and the alkalinity therein is The ionic substance continues to react, resulting in the calibration quality (decreased pH value) of the semi-finished or ex-factory product of the alkaline wine and the hydrolysis reaction of the aroma substance in the accelerated product (the content of the organic ester compound is reduced and becomes an organic acid) The quality is unstable; 2. The main material used to neutralize the organic acids in the wine is the alkaline inorganic substances (calcium carbonate or calcium hydroxide) contained in the calcium carbonate; the alkaline wine produced by the wine must avoid contact with the air. The carbon dioxide in the product, once contacted or exposed to the air, its product properties are rapidly decreasing (the pH value is rapidly decreased, and the above-mentioned use of materials such as grass ash is related to the instability of the fragrance), thereby There are some areas for improvement in alkaline quality and quality and its shelf life; and in the past, in the production of alkaline wines, long-term soaking is often used. For the solids inspection of the wine inspection standard, it is often added with substances that are easily soluble and difficult to filter, and affect the inspection standards, such as calcium bicarbonate, magnesium bicarbonate and other inorganic salts, which are evaporated to dryness during the test. After that, it can produce inorganic solids such as calcium carbonate and magnesium hydroxide, and greatly increase the detection value of its products.

The object of the present invention is to overcome the defects of the prior art and to provide a method and a device for preparing an alkaline functional liquor.

The technical scheme of the present invention is as follows: a method for preparing an alkaline functional liquor, comprising the following steps:

1. The raw wine is pumped into the first reaction tank through the first wine inlet, and 0.01-5.0 wt of magnesium hydrogencarbonate and 0.01-5.0 wt of calcium hydroxide are fed through the first feed port in the reaction tank. The raw material wine and the feed are uniformly mixed by the first stirring mechanism, and the reaction is carried out for 10 seconds to 100 minutes, and the pH of the raw material wine is controlled to be 5.0 to 10.0, so that the dissolved magnesium hydrogencarbonate in the raw wine is precipitated as magnesium hydroxide, and the calcium hydroxide is The form of calcium carbonate is precipitated, and then the solid matter and the semi-solid matter are filtered by a first filtration extraction device connected thereto, and pumped into the second reaction tank through a pipe.

2. The raw wine is pumped into the second reaction tank through the pipeline, and the carbon dioxide is introduced into the pipeline connected to the lower part of the reaction tank through the second gas circulation device for 10 seconds to 100 minutes to control the pH of the raw wine to 4.5. ~8.0, the dissolved calcium hydroxide in the raw wine is precipitated in the form of calcium carbonate, and then the solid matter and the semi-solid matter of the raw wine are filtered through a second filtering and extracting device connected, and pumped into the third reaction tank through the pipeline. .

3. The raw wine is pumped into the third reaction tank through the pipeline, and the human mineral supplementation material of at least one of the hydroxide radicals can be increased by feeding 0.01~5.0wt‰ through the third feed port in the reaction tank, and the third stirring mechanism is used. The raw wine is mixed with the feed evenly, reacting for 10 seconds to 100 minutes, controlling the pH of the raw wine to be 5.0~10.0, and then filtering the solid matter and the semi-solid matter through the third filtering and extracting device connected, and pumping the fourth reaction through the pipeline. In the can.

4. To the raw material wine in the fourth reaction tank, through the fourth gas circulation device, through the fourth gas circulation device, the pipeline connected from the lower part of the reaction tank is continuously introduced with carbon dioxide, or the fourth feed port is ventilated to adjust the raw materials. The pH of the wine is controlled to control the pH of the raw wine to be 4.5 to 8.0. After the raw wine is stabilized, the subsequent filtration or canning can be completed through the first discharge port.

In an optional technical embodiment of the present invention, in the first to third filter extraction devices of the plurality of reaction tanks, the diameter of the filter core is selected from 1 to 200,000 nm; and further, the material of the filter element is selected. Including: activated carbon for wine, paper roll, quartz sand, diatomaceous earth, magnet, ceramic, stainless steel fiber, polypropylene (PP), phenolic resin (PF), titanium rod (pure titanium or titanium alloy), polyether rayon fiber (PES), bismuth phosphorus crystal (polyphosphate), KDF (zinc copper alloy), manganese sand (manganese dioxide), ion exchange resin or ultrafiltration membrane; and at least one of the constituent elements of the human mineral supplement Including calcium, potassium, magnesium, sodium or alkaloid; further selected, at least one of the human mineral supplements include: calcium hydroxide, calcium hydrogencarbonate, calcium acetate, calcium propionate, calcium butyrate, calcium gluconate , amino acid calcium, potassium hydrogencarbonate, potassium carbonate, potassium acetate, potassium propionate, potassium valproate, potassium lactate, potassium tartrate, potassium gluconate, potassium amino acid, magnesium carbonate, magnesium hydrogencarbonate, magnesium propionate, valproic acid Magnesium, magnesium lactate, magnesium tartrate, magnesium gluconate , amino acid magnesium, amino acid calcium magnesium, sodium hydrogencarbonate, sodium carbonate, sodium acetate, sodium propionate, sodium valproate, sodium butyrate, sodium lactate, sodium tartrate, sodium potassium tartrate, sodium gluconate, sodium or alkaloids The sources of alkaloids include: human cockroach, ganoderma lucidum, Solanum nigrum, oats, Changchunxin, Huanglian, lotus seeds, Dendrobium, Motherwort, colchicum, Camptotheca, sage, mulberry or lotus leaf.

Another technical solution of the present invention is as follows: an apparatus for the above manufacturing method, comprising: a first reaction tank, a second reaction tank, a third reaction tank, a fourth reaction tank, first to third feed ports, and One discharge port, first to fourth feed ports, first to fourth valves, fifth to eighth valves, ninth to eighteenth valves, nineteenth to twenty-second valves, first to fifth Gas valve, first to fourth tank cleaning lines, first and second line cleaning valves, first to third filter extraction devices, ventilation control devices, carbon dioxide gas or gas cylinders, first to fourth gas circulation a first, a fourth, and a third agitating mechanism; First, second and third inlets are respectively provided with fifteenth, sixteenth and seventeenth valves, and The fourth reaction tank is provided with an eighteenth valve and a first discharge port; the first to fourth reaction tank upper portions are respectively provided with first to fourth feed ports, and first to fourth reaction tank inlet ports The first and fourth reaction tanks are respectively provided with first to fourth pH detecting and display devices, and the first to fourth reaction tanks are respectively provided with first to fourth a stirring mechanism; and the first to fourth valves, the ninth to eighteenth valves, and the first to fifth gas valves are two-way valves, and the first and second pipeline cleaning valves are three-way valves, and are respectively connected to the first The fourth and the ninth or the twelfth valve; the first reaction tank is connected to the liquid outlet through the first filter extraction device, the ninth and the second pipeline cleaning, the first pipeline cleaning, the fourth, the fourteenth And the third, or thirteenth, and second valves respectively communicate with the liquid inlet of the third or second reaction tank, or directly pass through the first filtering extraction device, the ninth, the twelfth and the second, or the tenth 3. The third valve is respectively connected to the liquid inlet of the second or third reaction tank; the second reaction tank is connected The liquid outlet is sequentially connected to the first filter through the second filter extraction device, the tenth, the twelfth and the first or the second pipeline cleaning, the first pipeline cleaning, the fourth, the fourteenth, and the third valve respectively, or The liquid inlet of the third reaction tank, or directly through the second filtration extraction device, the tenth, thirteenth and third, or the fourteenth, fourth, first pipeline cleaning, the second pipeline cleaning, the first a valve respectively communicates with the third or first liquid inlet of the reaction tank; the third reaction tank is connected to the liquid outlet through the third filter extraction device, the eleventh, the thirteenth and the second, or the twelfth The first valve is respectively connected to the second or first reaction tank inlet port, or directly through the third filter extraction device, the eleventh, the fourteenth, the fourth, the first pipeline cleaning, the second pipeline cleaning And the first or the twelfth and second valves respectively communicate with the liquid inlet of the first or second reaction tank; the fourth reaction tank passes through the eighteenth valve and the first discharge port of the connection, and the liquid is discharged downstream Filter extraction or filling equipment; carbon dioxide gas or gas cylinder in the ventilation control device Passing through the fifth, first to fourth gas valves, respectively connecting the upper portions of the first to fourth reaction tanks with the pipelines and respectively communicating the first to fourth gas circulation devices, and the first to fourth gas circulation devices to the tubes The road connects the first to fourth reactions respectively a lower portion of the canister, wherein the ventilation control device communicates with the first, second, third, and fourth gas valves through the fifth gas valve; and in another alternative embodiment of the present invention, the first to fourth reactions The first to fourth stirring mechanisms are respectively disposed in the tank, and the first to fourth tank cleaning pipelines are respectively disposed at the bottoms of the first to fourth tanks, and the first to fourth tank cleaning pipelines are respectively The nineteenth to twenty-second valves are respectively provided, and the first to fourth pH detecting display devices are respectively disposed in the first to fourth reaction tanks; and in another optional technical embodiment of the present invention, The apparatus for manufacturing the method further includes fifth to eighth valves, wherein the eighth valve is disposed at the liquid inlet of the fourth reaction tank, and is connected to the first through the fifth, sixth, and seventh valves respectively by the pipeline, a second or third filter extraction device, or a ninth, tenth, eleventh valve, and the fifth to eighth valves are two-way valves; the first reaction tank, the other liquid outlet is sequentially extracted by the first filter The device, the fifth and eighth valves are connected to the liquid inlet of the fourth reaction tank; The other liquid outlet of the tank is sequentially connected to the liquid inlet of the fourth reaction tank through the second filtering and extracting device, the sixth and eighth valves, and the third liquid discharging port is sequentially filtered by the third filtering. The device, the seventh and eighth valves are connected to the liquid inlet of the fourth reaction tank; the invention is forcibly dissolved in the wine and then sealed, and the pH of the wine is lowered, so that the organic ester compound continuously exists in the neutrality In the environment, the basic hydrolysis reaction of the organic ester compound is relatively less likely to occur, and the quality and stability of the alkaline alcohol product can be improved; and the obtained alkaline alcohol product contains a part of carbonic acid therein, and at the same time In the method, the human mineral supplement which can increase the hydroxide is dissolved in the wine, and potassium carbonate is taken as an example to make it contact with excess carbon dioxide, and then converted into potassium hydrogencarbonate. The potassium hydrogencarbonate is weak base compared with potassium carbonate, and is not easy. Neutralization reaction with carbonic acid; after the product is turned into the cup, the wine releases a small amount of carbon dioxide, which is quickly balanced with the concentration of carbon dioxide gas in the atmosphere. A carbonate, potassium bicarbonate loss, and Restored to potassium carbonate dissolved in wine; carbon dioxide dissolved in wine, contact with air and carbonic acid in the wine conversion: CO2+H2O→H2CO3, H2CO3→CO2+H2O, after which potassium bicarbonate is converted to potassium carbonate: 2KHCO3+ CO2↑=K2CO3+H2O; the pH in the wine continues to rise within the range of the product calibration standard. At this time, if the basic hydrolysis reaction of the organic ester compound occurs, the reverse reaction time is not fast enough to change the flavor of the product; Other human mineral supplements capable of increasing hydroxide, the nature of which is also due to the use of a small amount of carbon dioxide sequestration to produce a similar pH-increasing elastic characteristic. In other words, the method of the present invention solves the problem of alkaline liquor in the prior art. Many problems; and, regardless of the type of raw wine to be pretreated, it is white wine, rice wine, rice wine, beer, red wine, or other distilled and fermented wines, which can be modified by the production method and equipment. Alkaline quality; in the present invention, the treated beverage body is an environment in which a weak acid coexists with a small amount of bicarbonate and an organic acid salt, which can be regarded as a product demand. In the process of production, or in the latter stage, a small amount of addition and soaking, whether it contains neutral or weakly acidic (such as tea polyphenols, soy isoflavones, oats, milk thistle, and many other polyphenolic extracts or several acid groups) Amino acid, etc.), or neutral or weakly alkaline (such as amaranth, Ganoderma lucidum, Solanum nigrum, oats, Changchunxin, mulberry leaves, lotus leaves, etc., extraction of alkaloids and saponins, etc.), rich in human nutrient value of cereals a food such as a plant, a saponin, or an alkaloid or an effective substance thereof, and the alcohol and a small amount of the added effective substance are less likely to react with each other to cause a change in the quality of the product; and in the present invention, calcium hydroxide and hydrogen carbonate are used. Magnesium neutralizes the organic acid in the wine and then reacts it with carbon dioxide. The reaction product is solid or semi-solid calcium carbonate or magnesium hydroxide which is convenient for filtration. Therefore, in the solid matter standard for wine quality inspection, Compared with the past production process, it possesses the advantages of substances that are difficult to filter out and can affect the inspection standards (such as inorganic salts such as calcium bicarbonate and magnesium bicarbonate); In the present invention, the organic acid (such as acetic acid, lactic acid, caproic acid, etc.) originally contained in the wine is converted into a soluble organic acid calcium or magnesium salt, and the absorption rate of the inorganic calcium magnesium salt is relatively high in the human body. It is said to be higher and more effective, and to reduce the risk of stones in the body after excessive intake of inorganic calcium and magnesium salts; and the present invention consumes less energy (no need to be distilled) compared to the treatment method of alkaline alcohol in the past, and the production time Fast (no need to pass static precipitation), and a small amount of filtrate and sediment after the raw materials are put into the raw material, no need to undergo complicated neutralization treatment, which is more favorable to environmental protection and energy saving requirements; and the device of the invention It can guarantee the continuous production of alkaline alcohol products without interruption when some equipment needs to be repaired and replaced.

(1)‧‧‧First reaction tank

(2) ‧‧‧Second reaction tank

(3) ‧‧‧ third reaction tank

(4) ‧‧‧fourth reaction tank

(10) ‧‧‧first feed inlet

(20)‧‧‧Second feed inlet

(30) ‧‧‧ third feed inlet

(11) ‧ ‧ first feeding port

(21) ‧‧‧second feeding port

(31) ‧ ‧ third feeding port

(41) ‧ ‧ fourth feeding port

(12)‧‧‧First pH detection display device

(22)‧‧‧Second pH detection display device

(32)‧‧‧ Third pH detection display device

(42) ‧‧‧ fourth pH detection display device

(13) ‧‧‧First gas circulation device

(23)‧‧‧Second gas circulation device

(33) ‧‧‧ Third gas circulation device

(43) ‧‧‧fourth gas circulation device

(14) ‧‧‧First tank cleaning line

(24) ‧‧‧Second tank cleaning line

(34) ‧‧‧ third tank cleaning line

(44) ‧‧‧fourth tank cleaning line

(15)‧‧‧First filter extraction device

(25)‧‧‧Second filter extraction device

(35) ‧‧‧ Third filter extraction device

(45) ‧‧‧first discharge opening

(16)‧‧‧First mixing mechanism

(26)‧‧‧Second mixing mechanism

(36)‧‧‧ Third mixing mechanism

(46) ‧‧‧fourth mixing mechanism

(5) ‧ ‧ ventilation control device

(50) ‧ ‧ carbon dioxide gas or cylinder

(51)‧‧‧First gas valve

(52) ‧‧‧Second gas valve

(53)‧‧‧ Third gas valve

(54) ‧‧‧fourth gas valve

(55) ‧‧‧ fifth gas valve

(61)‧‧‧First valve

(62)‧‧‧Second valve

(63)‧‧‧ Third valve

(64) ‧‧‧fourth valve

(65)‧‧‧ fifth valve

(66) ‧‧‧ sixth valve

(67)‧‧‧ seventh valve

(68) ‧ ‧ eighth valve

(69) ‧ ‧ ninth valve

(610)‧‧‧ tenth valve

(611) ‧ ‧ eleventh valve

(612) ‧ ‧ twelfth valve

(613) ‧ ‧ thirteenth valve

(614) ‧‧‧fourteenth valve

(615) ‧ ‧ fifteenth valve

(616) ‧ ‧ the sixteenth valve

(617)‧‧‧The seventeenth valve

(618)‧‧‧ Eighteenth valve

(619)‧‧‧The nineteenth valve

(620)‧‧‧ twentieth valve

(621)‧‧‧21st valve

(622)‧‧‧The twenty-second valve

(71)‧‧‧First line cleaning valve

(72)‧‧‧Second line cleaning valve

FIG. 1 is a schematic structural view of a device according to the present invention.

The selected technical solutions of the present invention will be further described and described below with reference to the accompanying drawings.

A method for preparing an alkaline wine, the apparatus used is as shown in FIG. 1, comprising: a first reaction tank (1), a second reaction tank (2), a third reaction tank (3), and a fourth reaction tank (4) ), first to third feed ports (10, 20, 30), first discharge port (45), first to fourth feed ports (11, 21, 31, 41), first to fourth valves (61, 62, 63, 64), fifth to eighth valves (65, 66, 67, 68), ninth to eighteenth valves (69, 610, 611, 612, 613, 614, 615, 616, 617, 618), 19th to 22nd valves (619, 620, 621, 622), first to fifth gas valves (51, 52, 53, 54, 55), first to fourth tanks Cleaning pipelines (14, 24, 34, 44), first (71) and second pipeline cleaning valves (72), first to third filtration extraction devices (15, 25, 35), aeration control device (5), carbon dioxide gas or gas cylinder (50), first to fourth gas circulation devices (13, 23, 33, 43), first to fourth pH detection display devices (12, 22) , 32, 42), and first to fourth stirring mechanisms (16, 26, 36, 46); first (1), second (2) and third reaction tank (3) upper portions, respectively provided with a first (10), the second (20) and the third feed port (30), and the first (10), the second (20) and the third feed port (30) are respectively provided with a fifteenth (615), Sixteenth (616) and seventeenth valve (617), and the fourth reaction tank (4) is provided with an eighteenth valve (618) and a first discharge port (45); first to fourth reactions Upper portions of the tanks (1, 2, 3, 4) are provided with first to fourth feed ports (11, 21, 31, 41), respectively, and first to fourth reaction tanks (1, 2, 3, 4) The liquid inlets are located at the upper portion, and the liquid outlets are located at the lower portion; the first to fourth reaction tanks (1, 2, 3, 4) are respectively provided with first to fourth pH detecting display devices (12, 22, 32, 42), and in the first to fourth reaction tanks (1, 2, 3, 4), first to fourth stirring mechanisms (16, 26, 36, 46); and first to fourth valves ( 61, 62, 63, 64), ninth to eighteenth valves (69, 610, 611, 612, 613, 614, 615, 616, 617, 618), first to fifth gas valves (51, 52, 53, 54, 55) Both are two-way valves. The first (71) and second line cleaning valves (72) are three-way valves and are connected to the fourth (64) and ninth (69), or twelfth valves (612, respectively). In the first to third filter extraction devices (15, 25, 35), the diameter of the filter core is selected from 1 to 200,000 nm. Further, the material of the filter element includes: activated carbon for wine, paper roll, quartz Sand, diatomaceous earth, magnet, ceramic, stainless steel fiber, polypropylene (PP), phenolic resin (PF), titanium rod (pure titanium or titanium alloy), polyether strontium fiber (PES), bismuth phosphorus crystal (polyphosphate) ), KDF (zinc-copper alloy), manganese sand (manganese dioxide), ion exchange resin or ultrafiltration membrane; first reaction tank (1), which is connected to the liquid outlet through the first filter extraction device (15), Nine (69), second pipeline cleaning (72), first pipeline cleaning (71), fourth (64), fourteen (614) and third (63), or thirteenth (613), The second valve (62) is respectively connected to the third (3), Or the liquid inlet of the second reaction tank (2), or directly through the first filtration extraction device (15), ninth (69), twelfth (612) and second (62), or thirteenth ( 613), the third valve (63) is respectively connected to the liquid inlet of the second (2) or the third reaction tank (3); the second reaction tank (2) is connected to the liquid outlet and sequentially passes through the second filtering and extracting device. (25), tenth (610), twelfth (612) and first (61), or second pipeline cleaning (72), first pipeline cleaning (71), fourth (64), tenth The fourth (614) and the third valve (63) respectively communicate with the liquid inlet of the first (1) or the third reaction tank (3), or directly pass through the second filter extraction device (25), the tenth (610) , thirteenth (613) and third (63), or fourteenth (614), fourth (64), first pipeline cleaning (71), second pipeline cleaning (72), first valve ( 61) respectively connecting the third (3) or the liquid inlet of the first reaction tank (1); the third reaction tank (3), which is connected to the liquid outlet and sequentially passes through the third filter extraction device (35), the eleventh (611), the thirteenth (613) and the second (62), or the twelfth (612), the first valve (61) respectively communicate with the second (2) or the first reaction tank (1) Or direct The third filter extraction device (35), the eleventh (611), the fourteenth (614), the fourth (64), the first pipeline cleaning (71), the second pipeline cleaning (72), and the first 61), or the twelfth (612), the second valve (62) respectively communicate with the first (1) or the second reaction tank (2) inlet; the fourth reaction tank (4), which is connected through The eighteenth valve (618) and the first discharge port (45), the downstream filtration extraction or filling equipment; the ventilation control device (5) is provided with carbon dioxide gas or a gas cylinder (50), and respectively passed Five (55), first to fourth gas valves (51, 52, 53, 54), respectively connecting the upper portions of the first to fourth reaction tanks (1, 2, 3, 4) with the pipelines and respectively communicating with the first Up to the fourth gas circulation device (13, 23, 33, 43), and the first to fourth gas circulation devices (13, 23, 33, 43), respectively communicating the first to fourth reaction tanks with the pipeline (1) 2, 3, 4), wherein the ventilation control device (5) communicates with the first (51), second (52), third (52) and fourth valves (54) through the fifth air valve (55) ); In the first to fourth reaction tanks (1, 2, 3, 4), first to fourth stirring mechanisms (16, 26, 36, 46) are respectively provided, and first to fourth reaction tanks (1, 2) , 3, 4) bottom, respectively provided first to fourth tank cleaning lines (14, 24, 34, 44), and first to fourth tank cleaning lines (14, 24, 34, 44) , respectively, the nineteenth to twenty-second valves (619, 620, 621, 622), and the first to fourth reaction tanks (1, 2, 3, 4), respectively, first to fourth a pH detecting display device (12, 22, 32, 42); and an apparatus in another optional technical solution of the present invention, further comprising fifth to eighth valves (65, 66, 67, 68), wherein the eighth The valve (68) is disposed at the liquid inlet of the fourth reaction tank (4), and communicates with the first (15), the first through the fifth (65), the sixth (66), and the seventh valve (67). Two (25), third filter extraction device (35), or ninth (69), tenth (610), eleventh valve (611), and fifth to eighth valves (65, 66, 67, 68) ) are two-way valves; the first reaction tank (1), the other liquid outlet passes through the first filter extraction device (15), the fifth (65) and the eighth valve (68) Connected to the liquid inlet of the fourth reaction tank (4); the second reaction tank (2), the other liquid outlet passes through the second filter extraction device (25), the sixth (66) and the eighth valve (68) Connected to the liquid inlet of the fourth reaction tank (4); the third reaction tank (3), the other liquid outlet passes through the third filter extraction device (35), the seventh (67) and the eighth valve (68) Connecting the liquid inlet of the fourth reaction tank (4); as can be seen from the above, the first reaction tank (1) and the second reaction tank (2) are the first group, the second reaction tank (2) and the third reaction tank ( 3) For the second group, the third reaction tank (3) and the first reaction tank (1) are the third group, and when any of the first to fourth (1, 2, 3, 4) reaction tanks need to be replaced Or maintenance, the other two groups can communicate through the pipeline to achieve the function of uninterrupted production of alkaline alcohol; and the production method specifically includes the following steps: 1. The raw wine is drawn through the first wine inlet (10) In the first reaction tank (1), 0.01 to 5.0 wt of magnesium hydrogencarbonate and 0.01 to 5.0 wt of hydrazine hydroxide are fed through the first feed port (11) in the reaction tank (1). Calcium, the raw material wine and the feed are uniformly mixed by the first stirring mechanism (16), and the reaction is carried out for 10 seconds to 100 minutes, and the pH of the raw material wine is controlled to be 5.0 to 10.0, so that the magnesium hydrogencarbonate Mg(HCO3)2 dissolved in the raw wine is hydrogen. Magnesium oxide is precipitated in the form of Mg(OH)2, and calcium hydroxide Ca(OH)2 is precipitated as calcium carbonate CaCO3, and then the solid matter and the semi-solid form of the raw material wine are filtered by the first filtration extraction device (15) connected thereto. And pumped into the second reaction tank (2) through the pipeline; in this step, a sufficient amount of calcium hydroxide Ca(OH)2 is fed into the raw wine to react with the organic acid in the raw wine, and acetic acid CH3COOH is used as Example: 2CH3COOH+Ca(OH)2==Ca(CH3COO)2+2H2O, the product is calcium acetate Ca(CH3COO)2 and water, and then the magnesium bicarbonate Mg(HCO3)2 and the remaining sufficient hydrogen Calcium oxide Ca(OH)2 reacts to form magnesium hydroxide Mg(OH)2, calcium carbonate CaCO3 and water: Mg(HCO3)2+2Ca(OH)2→Mg(OH)2↓+2CaCO3↓+2H2O; The raw wine is pumped into the second reaction tank (2) through a pipeline, and the carbon dioxide is introduced into the pipeline connected from the lower portion of the reaction tank (2) by the ventilation control device (5) through the second gas circulation device (23). 50) 10 seconds to 100 minutes, control raw materials The pH is 4.5~8.0, and the calcium hydroxide Ca(OH)2 dissolved in the raw wine is precipitated as calcium carbonate CaCO3: Ca(OH)2+CO2→CaCO3↓+H2O, and then connected through the second filtering and extracting device. (25) filtering the solid matter and the semi-solid matter of the raw material wine, and pumping into the third reaction tank (3) through the pipeline; 3. pumping the raw material wine into the third reaction tank (3) through the pipeline, in the reaction In the tank (3), the human mineral supplement material capable of increasing at least one of the hydroxides by adding 0.01 to 5.0 wt% through the third feed port (31) (the at least one of the constituent elements of the human mineral supplement including the calcium, Potassium, magnesium, sodium or alkaloid, further selected: calcium hydroxide, calcium hydrogencarbonate, calcium acetate, calcium propionate, calcium butyrate, calcium gluconate, calcium amino acid, potassium hydrogencarbonate, potassium carbonate, potassium acetate , potassium propionate, potassium valproate, potassium lactate, potassium tartrate, potassium gluconate, potassium amino acid, magnesium carbonate, magnesium hydrogencarbonate, magnesium propionate, magnesium valproate, magnesium lactate, magnesium tartrate, magnesium gluconate, amino acid Magnesium, amino acid calcium magnesium, sodium hydrogencarbonate, sodium carbonate, sodium acetate, sodium propionate, sodium valproate , sodium butyrate, sodium lactate, sodium tartrate, potassium tartrate Sodium, sodium gluconate, sodium amino acid or alkaloid, sources of alkaloids include: human cockroach, ganoderma lucidum, nightshade, oats, vinca xin, huanglian, lotus seed, medlar, motherwort, colchicum, camphor tree, cerule grass , mulberry leaves or lotus leaves. ), the raw material wine and the feed are uniformly mixed by the third stirring mechanism (36), and the reaction is carried out for 10 seconds to 100 minutes, and the pH of the raw material wine is controlled to be 5.0 to 10.0, and then the raw wine is filtered through the connected third filtering and extracting device (35). The solid matter and the semi-solid matter are pumped into the fourth reaction tank (4) through the pipeline; 4. the raw material wine in the fourth reaction tank (4), the ventilation control device (5), the fourth gas The circulation device (43) continuously feeds carbon dioxide (50) from the pipeline connected to the lower portion of the reaction tank (4) or ventilates through the fourth feed port (41) to adjust the pH of the raw wine to control the pH of the raw wine to 4.5. ~8.0, taking potassium carbonate K2CO3 as an example: K2CO3+H2O+CO2=2KHCO3, so that potassium carbonate reacts into potassium hydrogencarbonate KHCO3. After the raw wine is stabilized, the subsequent filtration can be completed through the first discharge port (45). The above description is only for the preferred embodiment of the present invention, and thus the scope of the present invention cannot be limited thereto, that is, the equivalent changes and modifications according to the scope of the present invention and the contents of the specification should still be It is within the scope of the present invention.

Claims (10)

A method for preparing an alkaline functional liquor, comprising the steps of: 1. drawing a raw material wine into a first reaction tank through a first wine feed inlet, and passing a first feed in the reaction tank Oral feeding 0.01~5.0wt of magnesium hydrogencarbonate and 0.01~5.0wt of calcium hydroxide, mixing the raw wine with the feed by a first stirring mechanism, reacting for 10 seconds to 100 minutes, controlling the pH of the raw wine 5.0~10.0, the dissolved magnesium hydrogencarbonate in the raw wine is precipitated in the form of magnesium hydroxide, calcium hydroxide is precipitated in the form of calcium carbonate, and then the raw wine is filtered by connecting one of the first filtering and extracting devices. Solid matter and semi-solid matter, and drawn into a second reaction tank through a pipeline; 2. The raw material wine is pumped into the second reaction tank through a pipeline, and a ventilation control device is passed through a second gas circulation device. The carbon dioxide is introduced into the pipeline connected to the lower part of the reaction tank for 10 seconds to 100 minutes, and the pH of the raw material wine is controlled to be 4.5 to 8.0, so that the dissolved calcium hydroxide in the raw wine is precipitated as calcium carbonate, and the dissolved magnesium hydrogencarbonate is dissolved. Precipitated in the form of magnesium hydroxide, followed by Passing through a second filtering and extracting device, filtering solid matter and semi-solid matter of the raw material wine, and pumping into a third reaction tank through a pipeline; 3. pumping the raw material wine into the third reaction tank through a pipeline In the reaction tank, 0.01~5.0wt‰ is fed through a third feeding port to increase at least one kind of human mineral supplemental substance of the hydroxide, and the raw material wine is uniformly mixed with the feeding material through a third stirring mechanism, and the reaction is performed. 10 seconds to 100 minutes, the pH of the raw material wine is controlled to be 5.0 to 10.0, and then the solid matter and the semi-solid matter of the raw material wine are filtered by connecting a third filtering and extracting device, and pumped into a fourth reaction tank through a pipeline. 4. The raw material wine in the fourth reaction tank is continuously introduced into the pipeline connected by the lower portion of the reaction tank through the ventilation control device through a fourth gas circulation device, or through a fourth feed. The mouth ventilation cycle is to adjust the pH of the raw material wine, and the pH of the raw material wine is controlled to be 4.5 to 8.0. After the raw material wine is stabilized, the subsequent filtration extraction or canning can be completed through a first discharge port. The method for manufacturing an alkaline functional liquor according to the first aspect of the invention, wherein the plurality of filter tanks are connected to the first to third filter extraction devices, wherein the plurality of filter cartridge holes are selected The diameter is from 1 to 200,000 nm. The method for producing an alkaline functional alcohol according to the first aspect of the invention, wherein the plurality of filter cartridges are connected to the first to third filter extraction devices, wherein the plurality of filter cartridges are selected Materials include: activated carbon for wine, paper roll, quartz sand, diatomaceous earth, magnet, ceramic, stainless steel fiber, polypropylene, phenolic resin, titanium rod, polyether strontium fiber, strontium phosphate crystal, KDF, manganese sand, ion exchange Resin or ultrafiltration membrane. The method for producing an alkaline functional alcohol according to claim 1, wherein the at least one of the human mineral supplements comprises calcium, potassium, magnesium, sodium or an alkaloid. The method for preparing an alkaline functional alcohol according to claim 1, wherein the at least one human mineral supplement comprises: calcium hydroxide, calcium hydrogencarbonate, calcium acetate, calcium propionate. , calcium butyrate, calcium gluconate, calcium amino acid, potassium hydrogencarbonate, potassium carbonate, potassium acetate, potassium propionate, potassium valproate, potassium lactate, potassium tartrate, potassium gluconate, potassium amino acid, magnesium carbonate, magnesium hydrogencarbonate , magnesium propionate, magnesium valproate, magnesium lactate, magnesium tartrate, magnesium gluconate, magnesium amino acid, calcium and magnesium amino acid, sodium hydrogencarbonate, sodium carbonate, sodium acetate, sodium propionate, sodium valproate, sodium butyrate, Sodium lactate, sodium tartrate, sodium potassium tartrate, sodium gluconate, sodium amino acid or alkaloid. The sources of the alkaloid include: human cockroach, ganoderma lucidum, nightshade, oat, vinca, yellow lotus, lotus seed, sassafras, motherwort , colchicum, camphor tree, sage, mulberry or lotus leaf. An apparatus for producing an alkaline functional alcohol according to any one of claims 1 to 5, characterized by comprising a first reaction tank, a second reaction tank, a third reaction tank, and a first Four reaction tanks, a first to third feed port, a first discharge port, a first to fourth feed port, a first to fourth valve, a fifth to eighth valve, and a ninth to Eighteenth valve, one nineteenth to the first Twenty-two valves, a first to fifth gas valve, a first to fourth tank cleaning line, a first and second line cleaning valve, a first to third filter extraction device, and a ventilation control a device, a carbon dioxide gas or gas cylinder, a first to fourth gas circulation device, a first to fourth pH detection display device, and a first to fourth agitation mechanism; the first, second, and third reactions The first, second and third feed ports are respectively arranged in the upper part of the tank, and the first, second and third feed ports are respectively provided with the fifteenth, sixteenth and seventeenth valves, and The first reaction tank is provided with the eighteenth valve and the first discharge port; the first to fourth reaction tank upper portions are respectively provided with the first to fourth feed ports, and the first to the fourth The liquid inlets of the four reaction tanks are all located at the upper portion, and the liquid outlets are located at the lower portion; the first to fourth reaction tanks are respectively provided with the first to fourth pH detecting display devices, and the first to fourth reaction tanks are respectively provided The first to fourth stirring mechanisms are respectively provided; the first to fourth valves, the ninth to eighteenth valves, and the first The first to fifth gas valves are two-way valves, the first and second pipeline cleaning valves are three-way valves, and are respectively connected to the fourth and ninth or the twelfth valve; the first reaction tank, Connecting the liquid outlet through the first filter extraction device, the ninth and second pipeline cleaning, the first pipeline cleaning, the fourth, the fourteenth and the third, or the thirteenth and second valves respectively Third, or the liquid inlet of the second reaction tank, or directly connected to the second through the first filter extraction device, the ninth, the twelfth and the second, or the thirteenth and third valves respectively Or the liquid inlet of the third reaction tank; the second reaction tank is connected to the liquid outlet through the second filter extraction device, the tenth, the twelfth and the first, or the second pipeline cleaning, a pipeline cleaning, fourth, fourteenth, and third valves respectively communicate with the first or the third reaction tank inlet, or directly through the second filtration extraction device, tenth, thirteenth and Third, or the fourteenth, fourth, first pipeline cleaning, second pipeline cleaning, first valve respectively Passing the third or the inlet port of the first reaction tank; the third reaction tank is connected to the liquid outlet through the third filter extraction device, the eleventh, the thirteenth and the second, or the first 12. The first valve is respectively connected to the second or the liquid inlet of the first reaction tank, Or directly through the third filter extraction device, the eleventh, the fourteenth, the fourth, the first pipeline cleaning, the second pipeline cleaning, and the first, or the twelfth and second valves respectively communicate with the first Or the liquid inlet of the second reaction tank; the fourth reaction tank is connected to the eighteenth valve and the first discharge port, and the liquid is pumped downstream to extract or fill the device; in the ventilation control device, Providing the carbon dioxide gas or gas cylinder, and respectively passing through the fifth, first to fourth gas valves, respectively connecting the upper portions of the first to fourth reaction tanks with the pipelines and respectively communicating the first to fourth gas circulations And the first to fourth gas circulation devices are respectively connected to the lower portions of the first to fourth reaction tanks by pipes, wherein the ventilation control device communicates with the first, second, and second portions through the fifth air valve Third and the fourth gas valve. The apparatus according to claim 6, wherein the first to fourth stirring mechanisms are respectively disposed in the first to fourth reaction tanks. The apparatus of claim 6, wherein the first to fourth tank bottoms are respectively provided with the first to fourth tank cleaning lines, and the first to fourth The tank cleaning pipeline is provided with the nineteenth to twenty-second valves, respectively. The apparatus according to claim 6, wherein the first to fourth pH detecting display devices are respectively disposed in the first to fourth reaction tanks. The apparatus of claim 6, further comprising a fifth to eighth valve, wherein the eighth valve is disposed at a liquid inlet of the fourth reaction tank and passes through the pipeline The fifth, sixth, and seventh valves are connected to the first, second, and third filter extraction devices, or the ninth, tenth, and eleventh valves; the fifth to eighth valves are two-way valves; a reaction tank, the other liquid outlet is sequentially connected to the liquid inlet of the fourth reaction tank through the first filter extraction device, the fifth and the eighth valve; the second reaction tank has another liquid outlet Connecting the liquid inlet of the fourth reaction tank through the second filter extraction device, the sixth and the eighth valve; the third reaction tank, The other liquid outlet is connected to the liquid inlet of the fourth reaction tank through the third filter extraction device, the seventh and the eighth valve.