TWI657075B - 用於控制和抑制脂肪族單體聚合的添加劑組合物，及其製備和使用方法 - Google Patents
用於控制和抑制脂肪族單體聚合的添加劑組合物，及其製備和使用方法 Download PDFInfo
- Publication number
- TWI657075B TWI657075B TW103110898A TW103110898A TWI657075B TW I657075 B TWI657075 B TW I657075B TW 103110898 A TW103110898 A TW 103110898A TW 103110898 A TW103110898 A TW 103110898A TW I657075 B TWI657075 B TW I657075B
- Authority
- TW
- Taiwan
- Prior art keywords
- butadiene
- composition
- additive composition
- polymerization
- ppm
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 145
- 239000000178 monomer Substances 0.000 title claims abstract description 78
- 239000000654 additive Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 53
- 230000000996 additive effect Effects 0.000 title claims abstract description 52
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 47
- 125000001931 aliphatic group Chemical group 0.000 title claims abstract description 45
- 230000005764 inhibitory process Effects 0.000 title description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 167
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims abstract description 72
- -1 ester derivative of quinone Chemical class 0.000 claims abstract description 56
- 239000004615 ingredient Substances 0.000 claims abstract description 42
- 238000006471 dimerization reaction Methods 0.000 claims abstract description 40
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 38
- 229920000768 polyamine Polymers 0.000 claims abstract description 24
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 28
- 150000003512 tertiary amines Chemical class 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 19
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 2
- VTWDKFNVVLAELH-UHFFFAOYSA-N 2-methylcyclohexa-2,5-diene-1,4-dione Chemical compound CC1=CC(=O)C=CC1=O VTWDKFNVVLAELH-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 39
- 150000001412 amines Chemical class 0.000 abstract description 27
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract description 17
- 125000005245 nitryl group Chemical group [N+](=O)([O-])* 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 10
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 7
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 7
- 238000003359 percent control normalization Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 229940126062 Compound A Drugs 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000001384 succinic acid Substances 0.000 description 3
- DZNMBUOUGMTZRA-UHFFFAOYSA-N OC1=CC=[N+]([O-])C=C1 Chemical compound OC1=CC=[N+]([O-])C=C1 DZNMBUOUGMTZRA-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- AMLFJZRZIOZGPW-NSCUHMNNSA-N (e)-prop-1-en-1-amine Chemical compound C\C=C\N AMLFJZRZIOZGPW-NSCUHMNNSA-N 0.000 description 1
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 1
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical group C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 description 1
- YOFWROLHDCVYLS-UHFFFAOYSA-N 1-hydroxypiperidin-4-ol Chemical compound OC1CCN(O)CC1 YOFWROLHDCVYLS-UHFFFAOYSA-N 0.000 description 1
- XUXUHDYTLNCYQQ-UHFFFAOYSA-N 4-amino-TEMPO Chemical compound CC1(C)CC(N)CC(C)(C)N1[O] XUXUHDYTLNCYQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
- C09K15/22—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing an amide or imide moiety
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN1165MU2013 IN2013MU01165A (enExample) | 2013-03-26 | 2013-03-26 | |
| IN1165/MUM/2013 | 2013-03-26 | ||
| ??PCT/IB2014/059998 | 2014-03-20 | ||
| PCT/IB2014/059998 WO2014155248A1 (en) | 2013-03-26 | 2014-03-20 | Additive composition for control and inhibition of polymerization of aliphatic monomers, and methods of preparation and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201446735A TW201446735A (zh) | 2014-12-16 |
| TWI657075B true TWI657075B (zh) | 2019-04-21 |
Family
ID=50489360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103110898A TWI657075B (zh) | 2013-03-26 | 2014-03-24 | 用於控制和抑制脂肪族單體聚合的添加劑組合物，及其製備和使用方法 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9598333B2 (enExample) |
| EP (1) | EP2978735B1 (enExample) |
| JP (1) | JP6433483B2 (enExample) |
| KR (1) | KR102058646B1 (enExample) |
| CN (2) | CN105102406B (enExample) |
| AR (1) | AR095709A1 (enExample) |
| BR (1) | BR112015024595B1 (enExample) |
| CA (1) | CA2907963C (enExample) |
| ES (1) | ES2813614T3 (enExample) |
| IN (1) | IN2013MU01165A (enExample) |
| MX (1) | MX350061B (enExample) |
| MY (1) | MY169124A (enExample) |
| PH (1) | PH12015502195A1 (enExample) |
| PL (1) | PL2978735T3 (enExample) |
| RU (1) | RU2725611C2 (enExample) |
| SG (1) | SG11201507999SA (enExample) |
| TW (1) | TWI657075B (enExample) |
| WO (1) | WO2014155248A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101644592B1 (ko) * | 2009-04-15 | 2016-08-01 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 고온 나프텐산 부식 억제에 효과적인 신규 비중합 및 논-파울링 첨가제, 및 이를 이용한 고온 나프텐산 부식 억제 방법 |
| IN2013MU01165A (enExample) | 2013-03-26 | 2015-04-24 | Dorf Ketal Chemicals India Private Ltd | |
| US10869444B2 (en) | 2018-07-13 | 2020-12-22 | Ecolab Usa Inc. | Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers |
| ES2971105T3 (es) | 2018-07-13 | 2024-06-03 | Ecolab Usa Inc | Composición para inhibir la polimerización de monómeros que comprende un inhibidor de nitróxido, un retardante de metida de quinona y un estabilizador de amina |
| TWI880966B (zh) | 2019-10-11 | 2025-04-21 | 美商藝康美國公司 | 醌甲基化物及銨鹽抗聚合劑組合物及方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI257929B (en) * | 2001-05-22 | 2006-07-11 | Betzdearborn Inc | Methods and compositions for inhibiting polymerization of vinyl monomers |
| TW200635894A (en) * | 2004-12-03 | 2006-10-16 | Chemtura Corp | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or c-nitrosanilines as polymerization inhibitors |
| CN101189203A (zh) * | 2005-06-17 | 2008-05-28 | 科聚亚公司 | 作为聚合抑制剂的邻亚硝基苯酚 |
| TW201035046A (en) * | 2009-02-05 | 2010-10-01 | Nalco Co | Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxomine combination |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5290888A (en) * | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| RU2129112C1 (ru) * | 1997-03-25 | 1999-04-20 | Открытое акционерное общество "Ангарский завод полимеров" | Способ ингибирования термополимеризации стирола |
| RU2152377C1 (ru) * | 1998-07-29 | 2000-07-10 | Открытое акционерное общество "Ангарский завод полимеров" | Ингибирующая композиция термополимеризации стирола |
| US6200461B1 (en) * | 1998-11-05 | 2001-03-13 | Betzdearborn Inc. | Method for inhibiting polymerization of ethylenically unsaturated hydrocarbons |
| CA2392526C (en) * | 1999-12-03 | 2010-07-27 | Uniroyal Chemical Company, Inc. | Composition and method for inhibiting polymerization and polymer growth |
| US6403850B1 (en) * | 2000-01-18 | 2002-06-11 | Uniroyal Chemical Company, Inc. | Inhibition of polymerization of unsaturated monomers |
| WO2002033026A1 (en) * | 2000-10-16 | 2002-04-25 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors |
| US6525147B1 (en) * | 2001-06-20 | 2003-02-25 | Baker Hughes Incorporated | Use of diamines and alkanolamines to inhibit unsaturated monomer polymerization |
| WO2003106390A1 (en) * | 2002-06-13 | 2003-12-24 | A H Marks & Company Limited | Polymerisation inhibitor |
| AU2005250152B2 (en) * | 2004-05-26 | 2011-04-21 | Basf Se | Flame-retardants |
| CN101102984A (zh) * | 2004-12-03 | 2008-01-09 | 科聚亚公司 | 作为聚合抑制剂的与含氮氧自由基的化合物或c-亚硝基苯胺结合的芳族磺酸、胺和硝基酚 |
| DE102007052891A1 (de) * | 2007-11-02 | 2009-05-07 | Evonik Degussa Gmbh | Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren |
| US9090526B2 (en) * | 2011-06-13 | 2015-07-28 | Nalco Company | Synergistic combination for inhibiting polymerization of vinyl monomers |
| MY167399A (en) * | 2011-08-26 | 2018-08-16 | Dorf Ketal Chemicals India Private Ltd | Additive composition for control and inhibition of polymerization of styrene, and method of preparation and use thereof |
| KR101625049B1 (ko) * | 2011-11-29 | 2016-05-27 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 스티렌의 중합의 조절 및 억제를 위한 아민 기반 첨가제 조성물 및 그 이용 방법 |
| MY167439A (en) * | 2011-12-02 | 2018-08-28 | Dorf Ketal Chemicals India Private Ltd | Amine and nitroxide based additive composition for control and inhibition of polymerization of styrene,and method of use thereof |
| WO2013108266A1 (en) * | 2011-12-09 | 2013-07-25 | Dorf Ketal Chemicals (India) Private Limited | Improved additives composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof |
| ES2547893T3 (es) * | 2011-12-26 | 2015-10-09 | Dorf Ketal Chemicals (India) Private Limited | Composición de aditivo mejorada a base de amina para el control y la inhibición de la polimerización de monómeros aromáticos de vinilo, y procedimiento para su uso |
| SG11201500774WA (en) | 2012-08-24 | 2015-02-27 | Dorf Ketal Chemicals India Private Ltd | Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof |
| IN2013MU01165A (enExample) | 2013-03-26 | 2015-04-24 | Dorf Ketal Chemicals India Private Ltd |
-
2013
- 2013-03-26 IN IN1165MU2013 patent/IN2013MU01165A/en unknown
-
2014
- 2014-03-20 PL PL14717873T patent/PL2978735T3/pl unknown
- 2014-03-20 MY MYPI2015002441A patent/MY169124A/en unknown
- 2014-03-20 WO PCT/IB2014/059998 patent/WO2014155248A1/en not_active Ceased
- 2014-03-20 ES ES14717873T patent/ES2813614T3/es active Active
- 2014-03-20 EP EP14717873.5A patent/EP2978735B1/en active Active
- 2014-03-20 CA CA2907963A patent/CA2907963C/en active Active
- 2014-03-20 KR KR1020157030584A patent/KR102058646B1/ko active Active
- 2014-03-20 JP JP2016504793A patent/JP6433483B2/ja active Active
- 2014-03-20 CN CN201480018900.7A patent/CN105102406B/zh not_active Expired - Fee Related
- 2014-03-20 US US14/779,843 patent/US9598333B2/en active Active
- 2014-03-20 MX MX2015013718A patent/MX350061B/es active IP Right Grant
- 2014-03-20 BR BR112015024595-1A patent/BR112015024595B1/pt active IP Right Grant
- 2014-03-20 RU RU2015145214A patent/RU2725611C2/ru active
- 2014-03-20 CN CN201711010294.6A patent/CN107814681A/zh active Pending
- 2014-03-20 SG SG11201507999SA patent/SG11201507999SA/en unknown
- 2014-03-21 AR ARP140101322A patent/AR095709A1/es active IP Right Grant
- 2014-03-24 TW TW103110898A patent/TWI657075B/zh active
-
2015
- 2015-09-21 PH PH12015502195A patent/PH12015502195A1/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI257929B (en) * | 2001-05-22 | 2006-07-11 | Betzdearborn Inc | Methods and compositions for inhibiting polymerization of vinyl monomers |
| TW200635894A (en) * | 2004-12-03 | 2006-10-16 | Chemtura Corp | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or c-nitrosanilines as polymerization inhibitors |
| CN101189203A (zh) * | 2005-06-17 | 2008-05-28 | 科聚亚公司 | 作为聚合抑制剂的邻亚硝基苯酚 |
| TW201035046A (en) * | 2009-02-05 | 2010-10-01 | Nalco Co | Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxomine combination |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2016520674A (ja) | 2016-07-14 |
| IN2013MU01165A (enExample) | 2015-04-24 |
| MX350061B (es) | 2017-08-25 |
| PH12015502195B1 (en) | 2016-01-25 |
| ES2813614T3 (es) | 2021-03-24 |
| JP6433483B2 (ja) | 2018-12-05 |
| BR112015024595A2 (pt) | 2017-08-22 |
| MY169124A (en) | 2019-02-18 |
| KR102058646B1 (ko) | 2019-12-23 |
| PL2978735T3 (pl) | 2020-11-16 |
| KR20150134404A (ko) | 2015-12-01 |
| SG11201507999SA (en) | 2015-10-29 |
| US20160083315A1 (en) | 2016-03-24 |
| RU2725611C2 (ru) | 2020-07-03 |
| PH12015502195A1 (en) | 2016-01-25 |
| TW201446735A (zh) | 2014-12-16 |
| CN105102406B (zh) | 2018-07-06 |
| WO2014155248A1 (en) | 2014-10-02 |
| RU2015145214A (ru) | 2017-04-25 |
| BR112015024595B1 (pt) | 2020-12-15 |
| CA2907963A1 (en) | 2014-10-02 |
| MX2015013718A (es) | 2016-07-06 |
| AR095709A1 (es) | 2015-11-04 |
| US9598333B2 (en) | 2017-03-21 |
| EP2978735A1 (en) | 2016-02-03 |
| EP2978735B1 (en) | 2020-06-24 |
| CA2907963C (en) | 2017-08-01 |
| CN107814681A (zh) | 2018-03-20 |
| CN105102406A (zh) | 2015-11-25 |
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