TWI649791B - Electronic device manufacturing equipment and its control technology, and electronic device and its manufacturing method - Google Patents

Electronic device manufacturing equipment and its control technology, and electronic device and its manufacturing method Download PDF

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TWI649791B
TWI649791B TW106130384A TW106130384A TWI649791B TW I649791 B TWI649791 B TW I649791B TW 106130384 A TW106130384 A TW 106130384A TW 106130384 A TW106130384 A TW 106130384A TW I649791 B TWI649791 B TW I649791B
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manufacturing equipment
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/20Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy

Abstract

提供處理剝離/結合高品質、高效率或低成本的磊晶膜薄膜的製造設備。 Provide manufacturing equipment for processing peeling / combining high quality, high efficiency or low cost epitaxial film.

例如,裝備了:具有:維持取得磊晶膜的薄膜14的成長用基板13的基板維持體12、和支持基板維持體的基板支持體11、和維持自成長用基板剝離的薄膜的薄膜維持體16、和支持薄膜維持體的薄膜支持體15、和基板支持體及薄膜維持體形成的第1艙室200、和基板維持體及基板支持體形成的第2艙室210、和薄膜維持體及薄膜支持體形成的第3艙室220、的剝離裝置;與施加個別對應第1、第2和第3艙室的第1、第2和第3氣體壓力的壓力裝置50;的製造設備。 For example, it is equipped with: a substrate holder 12 for maintaining a growth substrate 13 for obtaining a thin film 14 of an epitaxial film, a substrate holder 11 for supporting the substrate holder, and a film holder for maintaining a thin film peeled from the substrate for growth 16. The film holder 15 supporting the film holder, the first chamber 200 formed with the substrate support and the film holder, the second chamber 210 formed with the substrate holder and the substrate support, and the film holder and film support The peeling device for the third compartment 220 formed by the body; the manufacturing equipment for the pressure device 50 for applying the first, second, and third gas pressures corresponding to the first, second, and third compartments;

Description

電子器件的製造設備及其控制技術、以及電子 器件及其製造方法 Electronic device manufacturing equipment and its control technology, and electronics Device and its manufacturing method

本發明係有關於電子器件(electronic device)的製造設備(manufacturing equipment)及其控制技術(control techniques)、以及電子器件及其製造方法。電子器件也包含半導體器件,製造電子器件的製造設備也包含製造半導體的製造設備,舉例來說,係關聯於將從基板(substrate)成長的磊晶膜(epitaxial film)《以下稱為『薄膜』》分離的技術、或將分離出來的磊晶膜《薄膜》黏合(bonding)到其他基板《或轉錄材料(transcription material)》的技術。The present invention relates to manufacturing equipment for electronic devices and their control techniques, as well as electronic devices and methods for manufacturing the same. Electronic devices also include semiconductor devices, and manufacturing equipment for manufacturing electronic devices also includes semiconductor manufacturing equipment. For example, it is related to an epitaxial film that will grow from a substrate (hereinafter referred to as "thin film") 》 The separation technology, or the technology of bonding the separated epitaxial film “thin film” to other substrates “or transcription material”.

做為將磊晶膜從基板分離的設備,例如專利文獻1所揭示之構造《圖3》,在專利文獻1所揭示之設備,其構造為具有吸槽(suction groove),藉由真空抽吸(vacuum suction)使半導體基板彎折,維持在彎曲的抽吸面上的基板維持部門;靠著將楔子(wedge)壓進半導體基板和半導體薄膜之間的層《多孔層(porous)端邊(edge)》使半導體薄膜從半導體基板剝離的楔子部門;以及,具有抽吸孔和緩衝部門,藉由真空抽吸半導體薄膜而抽吸維持的半導體薄膜維持部門;以及這些部門的結構,都揭示出來。As an apparatus for separating the epitaxial film from the substrate, for example, the structure disclosed in Patent Document 1 "FIG. 3", and the apparatus disclosed in Patent Document 1 are configured to have a suction groove (suction groove) by vacuum suction (Vacuum suction) the semiconductor substrate that bends the semiconductor substrate and maintains it on the curved suction surface; by pressing the wedge into the layer between the semiconductor substrate and the semiconductor thin film, the "porous" edge ( edge) "a wedge section that peels the semiconductor film from the semiconductor substrate; and a semiconductor film maintenance section that has a suction hole and a buffer section that is sucked and maintained by vacuum suction of the semiconductor film; and the structures of these sections are revealed .

其次,專利文獻2所揭示的構造《圖4》中,從Si基體剝離網狀膜的剝離裝置中,揭示在Si基體成長的網狀膜上面施予壓力,真空吸引剝離裝置的內部時吸引網狀膜,從剝離裝置吸引到上面的構造。Next, in the structure "FIG. 4" disclosed in Patent Document 2, in the peeling device that peels the mesh film from the Si substrate, it is revealed that a pressure is applied to the mesh film grown on the Si substrate, and the mesh is sucked when the inside of the peeling device is vacuum suctioned. The film-like structure is drawn from the peeling device to the top.

其次,專利文獻3所揭示的構造《圖3》中,具有加熱板(hot plate)等的加熱部門,在第1基板上使磊晶(epitaxial)成長的氮化物類半導體結晶(nitride semiconductor crystal)處,給予熱衝擊(thermal shock),將薄膜剝離,揭示這種構造。另外,也揭示藉由機械衝擊(mechanical shock)《流體噴出(fluid spout)》而進行剝離、藉由震動衝擊(vibration shock)《超音波震盪器(ultrasonic wave oscillator)》而進行剝離的構造。Next, in the structure "FIG. 3" disclosed in Patent Document 3, a nitride semiconductor crystal that grows epitaxially on the first substrate by a heating section such as a hot plate At this point, thermal shock is given to peel off the film to reveal this structure. In addition, a structure in which peeling is performed by mechanical shock (fluid spout) and vibration shock (ultrasonic wave oscillator) is disclosed.

其次,專利文獻4所揭示的構造《圖1》中,係以非接觸方式檢測黏貼在基板表面的薄膜的剝離的膜剝離檢測裝置,揭示:將雷射光束(laser beam)照射在基板的激光輻照光學系統(laser irradiation optical system)、和靠著薄膜接受散射光(scattered light),以光學方法檢測包含於散射光的散斑圖樣(speckle pattern)的影像感測器(image sensor),以及以影像感測器的輸出為基礎,判斷薄膜剝離的剝離判斷方法(peeling judgment method)。 【專利文獻】Next, the structure "FIG. 1" disclosed in Patent Document 4 is a film peeling detection device that detects peeling of a film adhered to the surface of a substrate in a non-contact manner, and reveals: a laser beam that irradiates a laser beam on the substrate A laser irradiation optical system and an image sensor that detects scattered light contained in the scattered light and detects the speckle pattern contained in the scattered light optically, and Based on the output of the image sensor, peeling judgment method to judge the peeling of the film (peeling judgment method). 【Patent Literature】

【專利文獻1】特開2004-128148號  【專利文獻2】特開2001-85725號  【專利文獻3】特開2007-220899號  【專利文獻4】特開2002-005816號[Patent Document 1] JP 2004-128148 [Patent Document 2] JP 2001-85725 [Patent Document 3] JP 2007-220899 [Patent Document 4] JP 2002-005816

【發明所要解決的問題】[Problems to be solved by the invention]

剝離裝置和彎折裝置《已彎折的薄膜朝向成為產品一部分的其餘部分基板彎折的彎折裝置》,藉由各自的高精準度( high-precision),需要使薄膜的可靠性(reliability)提高;又,處理已剝離薄膜的處理作業(handling process)《從剝離作業到彎折作業》,從提高已剝離薄膜的可靠性的觀點來看,也是必要的;再者,使已剝離薄膜的可靠性一直提高,必須降低這些裝置的成本。The peeling device and the bending device "Bending device for bending the film toward the rest of the substrate that becomes part of the product", with their respective high-precision, it is necessary to make the reliability of the film (reliability) Improve; In addition, the handling process of peeling film (handling process) "From peeling operation to bending operation" is also necessary from the viewpoint of improving the reliability of the peeled film; Reliability has been improving, and the cost of these devices must be reduced.

舉例來說,專利文獻1所揭示的製造設備,含有控制器(controller),該控制器因應作為分離層的多孔層的不同剝離強度《難剝離的點、易剝離的點》,必須調整剝離用晶圓(wafer)的恆速旋轉(constant speed rotation)、楔子插入量、和楔子的壓入壓力。製造設備的部件個數增加,則招致成本增加。For example, the manufacturing equipment disclosed in Patent Document 1 includes a controller, which must be adjusted for peeling in accordance with the different peel strengths of the porous layer as a separation layer, "difficult to peel, easy to peel". Constant speed rotation of wafer, insertion amount of wedge, and press-in pressure of wedge. The increase in the number of parts of manufacturing equipment will increase costs.

舉例來說,專利文獻1所揭示的構造中,半導體薄膜維持部門係設計為經常維持朝上方向的張力(tension)、壓縮彈簧(compression spring)則將軸壓上去,抽吸半導體薄膜後,從半導體基板剝離半導體薄膜的方向的張力經常維持,變成促進剝離的構造;也就是說,壓縮彈簧藉由楔子持續剝離的薄膜,和控制器的控制無關連,因為單一方地促進剝離,招致薄膜可靠性降低。專利文獻2所揭示的構造也是相同。For example, in the structure disclosed in Patent Document 1, the semiconductor film maintenance department is designed to constantly maintain the upward tension and the compression spring to press the shaft up, after sucking the semiconductor film, from The tension of the semiconductor substrate in the direction of peeling the semiconductor film is often maintained, and it becomes a structure that promotes peeling; that is, the film that the compression spring continuously peels through the wedge is not related to the control of the controller, because the peeling is promoted unilaterally, which results in reliable film Sexuality is reduced. The structure disclosed in Patent Document 2 is also the same.

舉例來說,專利文獻3所揭示的構造中,也是揭示用3個方法《熱衝擊(thermal shock)、機械衝擊(mechanical shock)、震動衝擊(vibration shock)》來剝離薄膜的構造,但未揭示持續剝離的薄膜的可靠性維持的方法、和其構造。至少前述複數的課題之一,從持續提高已剝離薄膜的可靠性、或這些設備的成本降低的觀點來看,都是希望解決的問題。 【解決課題所採取的方法】For example, the structure disclosed in Patent Document 3 also discloses the structure of peeling the film by three methods "thermal shock (mechanical shock), mechanical shock (vibration shock)", but does not disclose A method for maintaining the reliability of a continuously peeled film, and its structure. At least one of the aforementioned multiple issues is a problem to be solved from the viewpoint of continuously improving the reliability of the peeled film or reducing the cost of these devices. [Methods taken to solve the problem]

本發明的製造設備(manufacturing equipment)係裝備了剝離裝置和壓力裝置。剝離裝置包含:維持得到薄膜的成長用基板的基板維持體、和支持基板維持體的基板支持體、和維持從成長用基板剝離的薄膜的薄膜維持體、和支持薄膜維持體的薄膜支持體、和由基板支持體與薄膜維持體構成的第1艙室(chamber)、和由基板維持體與基板支持體構成的第2艙室、和由薄膜維持體與薄膜支持體的第3艙室,以上構成剝離裝置;壓力裝置施加(apply)於個別對應第1、第2和第3艙室的第1、第2和第3氣體壓力(pressure force);本發明以此為特徵。The manufacturing equipment of the present invention is equipped with a peeling device and a pressure device. The peeling device includes a substrate holder for maintaining the growth substrate on which the film is obtained, a substrate holder for supporting the substrate holder, a film holder for maintaining the film peeled from the growth substrate, and a film holder for supporting the film holder, And a first chamber composed of a substrate support and a film holder, a second chamber composed of a substrate holder and a substrate support, and a third chamber composed of a film holder and a film support, the above constitutes peeling Device; the pressure device is applied to the first, second and third gas pressure (pressure force) corresponding to the first, second and third compartments respectively; the invention is characterized by this.

【實施例1】[Example 1]

圖1係簡單顯示本發明的製造設備的剖面圖的複數個實施例中的一個實施例。圖1所揭示的製造設備1包含剝離裝置10、結合裝置20、壓力裝置50、和薄膜支持體運送機制(carry mechanism)30、以機箱(chassis)40。FIG. 1 simply shows one of the plural embodiments of the cross-sectional view of the manufacturing equipment of the present invention. The manufacturing apparatus 1 disclosed in FIG. 1 includes a peeling device 10, a bonding device 20, a pressure device 50, and a film carrier transport mechanism 30 and a chassis 40.

以下簡要演示本發明的幾個特徵,但是,這些特徵並不是用來限制專利申請範圍所表示之發明的特別特徵。The following briefly demonstrates several features of the present invention, but these features are not intended to limit the special features of the invention represented by the scope of the patent application.

作為第1特徵,剝離裝置10係藉由基板支持體11和可以活動的薄膜支持體15所構成;結合裝置20係藉由可以活動的轉錄支持體21和可以活動的薄膜支持體15所構成。亦即,一個薄膜支持體15供剝離裝置10和結合裝置20兩方使用。一個薄膜支持體15連接薄膜支持體運送機制30,因為被剝離的薄膜14也在結合裝置20使用,因此可以期待被剝離的薄膜14的品質提高、製造作業的通流(throughput)縮短。As a first feature, the peeling device 10 is constituted by the substrate support 11 and the movable film support 15; the coupling device 20 is constituted by the movable transcription support 21 and the movable film support 15. That is, one film support 15 is used by both the peeling device 10 and the bonding device 20. One film support 15 is connected to the film support transport mechanism 30. Since the peeled film 14 is also used in the bonding apparatus 20, it is expected that the quality of the peeled film 14 is improved and the throughput of the manufacturing operation is shortened.

作為第2特徵,壓力裝置50供應剝離裝置10所具有的3個艙室《第1、第2、和第3艙室》各自最適當的氣體壓力,將薄膜14剝離。施予第1艙室200比大氣壓稍高《約1千克力/平方釐米(kgf/cm2 )》的第1氣體壓力,第2艙室和第3艙室則施予比大氣壓稍低的第2和第3氣體壓力,至少第1和第3氣體壓力的差要放在薄膜14的兩面;藉此,持續剝離的薄膜14和薄膜維持體16的相互吸附(adsorption)程度升高,又藉由成長用基板13和基板維持體12的相互黏著(adhesion)程度提高,使持續剝離的薄膜14的相互剝離程度提高。其結果,使剝離時間加速;又,其結果,可以實現薄膜14的品質提升。As a second feature, the pressure device 50 supplies the most suitable gas pressures of the three compartments "first, second, and third compartments" of the peeling device 10 to peel the film 14. The first chamber 200 is applied with the first gas pressure of "approximately 1 kilogram-force per square centimeter (kgf / cm 2 )" which is slightly higher than atmospheric pressure, and the second and third chambers are applied with the second and third chambers which are slightly lower than atmospheric pressure. 3 gas pressure, at least the difference between the first and third gas pressure should be placed on both sides of the film 14; thereby, the degree of mutual adsorption between the film 14 and the film maintenance body 16 that are continuously peeled off increases, and the growth The degree of mutual adhesion between the substrate 13 and the substrate maintenance body 12 is increased, and the degree of mutual peeling of the continuously peeled film 14 is improved. As a result, the peeling time is accelerated; and as a result, the quality of the film 14 can be improved.

作為第3特徵,將氫氣(hydrogen gas)供給第1艙室200。舉例來說,氫氣在剝離區域擴散,因為使擴散部分的間隙(interstice)的應變變形增大,氮化鎵(gallium nitride;GaN)和磊晶膜(epitaxial film)的薄膜之間的晶格子(lattice)數不同的剝離區域《緩衝(buffer)層》的相互悖離(defect)程度更進而提高,可以實現從成長用基板13將薄膜14剝離的開裂(cleavage)高速化和薄膜14的品質提升兩方面。所謂剝離係表示向結合力較弱的方向裂開的性質、現象。As a third feature, hydrogen gas is supplied to the first compartment 200. For example, hydrogen gas diffuses in the peeling region because the strain deformation of the interstice of the diffusion part increases, and the crystal lattice between the thin film of gallium nitride (GaN) and epitaxial film (epitaxial film) The "buffer layer" of the peeling regions with different numbers of lattices has a further increased degree of defection, which can achieve high-speed cleavage of the peeling of the film 14 from the growth substrate 13 and the improvement of the quality of the film 14 Two aspects. The peeling system refers to the nature and phenomenon of cracking in the direction where the bonding force is weak.

作為第4特徵,薄膜支持體15配設了彈性應變變形部門(elastic strain deformation portion)17。藉由比大氣壓更高的第1氣體壓力,使彈性應變變形部門17上升《圖1剖面圖的向上方向》,可以實現從成長用基板13將薄膜14剝離的開裂高速化。彈性應變變形部門17則藉由思考薄膜支持體15的厚度和形狀可以做出來,舉例來說,剪切部門(cut-out portion)18就是其中一例。彈性應變變形部門17也有簡單地稱為變形部門17。As a fourth feature, the thin film support 15 is provided with an elastic strain deformation portion 17. By raising the first gas pressure higher than atmospheric pressure, the elastic strain deformation section 17 is raised "upward in the cross-sectional view of FIG. 1", and the cracking of the thin film 14 peeled from the growth substrate 13 can be accelerated. The elastic strain deformation section 17 can be made by thinking about the thickness and shape of the film support 15, for example, a cut-out portion 18 is one example. The elastic strain deformation section 17 is also simply called a deformation section 17.

作為第5特徵,在結合裝置20中,使用3個支持體《轉錄支持體21、薄膜支持體15、和第2薄膜支持體115(圖13)》,轉錄已剝離薄膜14兩次;因為以轉錄支持體21為基準而轉錄兩次,可以反轉已剝離薄膜14的表面,因此,製造作業的通流(throughput)的縮短可以預期。此處所謂反轉,係指相對於轉錄材料的結合面或產品基板的結合面,已剝離的開裂面《B面》及其相反面(opposing surface),可以自由地設定。As a fifth feature, in the bonding device 20, three supports "transcription support 21, film support 15, and second film support 115 (FIG. 13)" are used, and the film 14 has been peeled off twice; The transcription support 21 is transcribed twice as a reference, and the surface of the peeled film 14 can be reversed. Therefore, a reduction in throughput of the manufacturing operation can be expected. The term “reversal” here means that the cleaved surface “B side” and the opposing surface (opposing surface) that have been peeled off can be set freely with respect to the bonding surface of the transcription material or the bonding surface of the product substrate.

作為第6特徵,可以利用轉錄材料23或第2轉錄材料123作為最後產品的產品基板160,可以預期已剝離的薄膜14的品質提高、和製造作業的通流(throughput)的縮短。As a sixth feature, the transcription material 23 or the second transcription material 123 can be used as the product substrate 160 of the final product, and it is expected that the quality of the peeled film 14 is improved and the throughput of the manufacturing operation is shortened.

作為第7特徵,將剝離裝置10上下翻轉《薄膜維持體16轉向下,基板維持體轉向上》,藉由薄膜維持體16搭配第3轉錄材料《例如,產品基板》成為一組,可以將成長用基板剝離的薄膜14直接轉錄並結合至產品基板,可以預期已剝離的薄膜14的品質提高、和製造作業的通流的縮短。As a seventh feature, turning the peeling device 10 up and down "the film maintenance body 16 turns downwards, and the substrate maintenance body turns upwards", by combining the film maintenance body 16 with the third transcription material "e.g., product substrate" into a group, growth The film 14 peeled off with the substrate is directly transcribed and bonded to the product substrate, and it is expected that the quality of the peeled film 14 is improved and the flow of the manufacturing operation is shortened.

作為第8特徵,壓力裝置50供給結合裝置30所具有的3個艙室《第3、第4、和第5艙室》中的第3艙室最適當的氣體壓力,將薄膜14轉錄至轉錄材料23。對第3艙室施予比大氣壓更高的第3氣體壓力;薄膜14和薄膜支持體16的固定、以及成長用基板13和基板維持體12的固定成為確實,其結果,可以實現轉錄時間高速化及其品質提高這二者。As an eighth feature, the pressure device 50 supplies the most suitable gas pressure to the third compartment of the three compartments "third, fourth, and fifth compartments" of the coupling device 30, and transcribes the film 14 to the transcription material 23. A third gas pressure higher than atmospheric pressure is applied to the third compartment; the fixing of the film 14 and the film support 16 and the fixing of the growth substrate 13 and the substrate holder 12 are confirmed, and as a result, the transcription time can be speeded up And improve their quality.

於圖1中,處理的薄膜14《磊晶膜》適用於製造設備1、例如以下所示的各種電子零件和配備了那些電子零件的系統,例如,有:太陽能電池模組(solar cell module)、發光二極體燈泡(LED lamp;LED light bulb)、顯示器《電漿顯示器(PDP,plasma display panel)、液晶顯示器(LCD,liquid crystal display)、有機發光二極體(organic light-emitting diode)》、半導體雷射《半導體雷射(semiconductor laser)、半導體二極管(semiconductor diode)》、光學影像傳感器(optical image sensor)《光子成像器(Photonic Imager)》、二維/三維投影顯示裝置(2D/3D projection display)、虛擬實境.三維投影顯示器《量子光子成像器(Quantum Photonic Imager)、虛擬實境顯示器(virtual reality display;VR)、擴增實境顯示器(Augmented Reality display;AR)、混合實境顯示器(Mixed Reality display;MR)、替代實境顯示器(Substitutional Reality display;SR)》、非揮發性快閃記憶體(NAND flash memory)等的非揮發性記憶體顯示器(non-volatile memory display)及其系統《固態硬碟(solid state drive;SSD)》。後述的產品基板160《圖19、圖25和圖28》也是與薄膜14相同,適用於電子零件和配備了那些電子零件的系統。In FIG. 1, the processed thin film 14 "epitaxial film" is suitable for manufacturing equipment 1, such as various electronic parts shown below and systems equipped with those electronic parts, for example: solar cell module (solar cell module) , LED lamp; LED light bulb, display "plasma display panel (PDP, plasma display panel), liquid crystal display (LCD, liquid crystal display), organic light-emitting diode (organic light-emitting diode) ", Semiconductor laser" semiconductor laser (semiconductor laser), semiconductor diode (semiconductor diode) ", optical image sensor (optical image sensor)" photonic imager (Photonic Imager) ", 2D / 3D projection display device (2D / 3D projection display), virtual reality. Three-dimensional projection display "Quantum Photonic Imager (Quantum Photonic Imager), virtual reality display (virtual reality display; VR), augmented reality display (Augmented Reality display; AR), mixed reality display (Mixed Reality display; MR) , Substitutional Reality display (SR), non-volatile memory display (NAND flash memory) and other non-volatile memory display (non-volatile memory display) and its system "solid-state hard drive (solid state drive; SSD) ". The product substrate 160 (FIG. 19, FIG. 25, and FIG. 28) described later is also the same as the thin film 14, and is suitable for electronic parts and systems equipped with those electronic parts.

於圖1中,剝離裝置10係將在成長用基板13的表面做成的磊晶膜即薄膜14剝離的機制和構造。成長用基板13和薄膜14係在剝離裝置10的外部做成,剝離裝置10具有維持成長用基板13的基板維持體12;剝離裝置10具有支持基板維持體12的基板支持體11。基板支持體11被固定在機箱(chassis)40《固定處未顯示於圖內》。剝離裝置10具有吸附從成長用基板13剝離的薄膜14的薄膜維持體16;剝離裝置10具有支持薄膜維持體16的薄膜支持體15;薄膜支持體15係以可附著和分離(attaching and detaching)的方式連接基板支持體11。In FIG. 1, the peeling device 10 is a mechanism and structure for peeling a thin film 14 that is an epitaxial film made on the surface of the growth substrate 13. The growth substrate 13 and the thin film 14 are made outside the peeling device 10. The peeling device 10 has a substrate holder 12 that supports the growth substrate 13; the peeling device 10 has a substrate holder 11 that supports the substrate holder 12. The substrate support 11 is fixed to a chassis 40 (the fixing place is not shown in the figure). The peeling device 10 has a film holder 16 that adsorbs the film 14 peeled from the growth substrate 13; the peeling device 10 has a film holder 15 that supports the film holder 16; the film holder 15 is attachable and detachable的 方法 连接 atib substrate 11.

剝離裝置10裝備了3個艙室。第1艙室200係藉由基板支持體11和薄膜支持體15所形成的空間;第2艙室210係藉由基板支持體11和基板維持體12所形成的空間;第3艙室係藉由薄膜支持體15和薄膜維持體16所形成的空間。第1艙室200內配置了基板維持體12和薄膜維持體16、以及成長用基板13和薄膜14。The stripping device 10 is equipped with 3 cabins. The first compartment 200 is a space formed by the substrate support 11 and the film support 15; the second compartment 210 is a space formed by the substrate support 11 and the substrate support 12; the third compartment is supported by the film The body 15 and the thin film maintain the space formed by the body 16. The substrate holding body 12 and the film holding body 16 and the growth substrate 13 and the film 14 are arranged in the first compartment 200.

薄膜支持體15包含彈性應變變形部門(elastic strain deformation portion)17;彈性應變變形部門17包含剪切部門(cut-out portion)18。彈性應變變形部門17和剪切部門18,隨著第1艙室200內的氣體壓力等的條件,其形狀暫時性地做彈性變形。其詳細內容將於後說明。The film support 15 includes an elastic strain deformation portion 17; the elastic strain deformation portion 17 includes a cut-out portion 18. The elastic deformation section 17 and the shear section 18 temporarily elastically deform their shapes in accordance with conditions such as the gas pressure in the first compartment 200. The details will be explained later.

薄膜支持體運送機制30包含薄膜支持體移動材料31;薄膜支持體移動材料31在剝離裝置10和結合裝置20之間搬送《移動》薄膜支持體15。The film support transport mechanism 30 includes a film support moving material 31; the film support moving material 31 transports the "moving" film support 15 between the peeling device 10 and the bonding device 20.

剝離裝置10具有分別控制複數的艙室內的氣體壓力的壓力裝置50;壓力裝置50,包含第1壓力裝置51和第2壓力裝置52。第1壓力裝置51分別控制第2艙室210和第3艙室220的氣體壓力;第2壓力裝置52控制第1艙室的氣體壓力。再者,壓力裝置50控制結合裝置20的複數個艙室的氣體壓力。在圖1中,描述從壓力裝置50輸入/輸出(input and output)的複數箭頭符號(arrow symbol),係個別對應於相同箭頭符號所對應的圖1描述的複數個艙室。各艙室的氣體壓力的控制支詳細情形,將於後說明。又,絕對值比大氣壓《1大氣壓,約1千克力/平方釐米》較低的氣體壓力,定義為負壓力;真空《0氣體壓力》也是負壓力範圍的一部分;絕對值比大氣壓《1大氣壓》較大的氣體壓力,定義為正壓力。The peeling device 10 includes a pressure device 50 that controls the gas pressure in a plurality of compartments, respectively; the pressure device 50 includes a first pressure device 51 and a second pressure device 52. The first pressure device 51 controls the gas pressure of the second compartment 210 and the third compartment 220, respectively; the second pressure device 52 controls the gas pressure of the first compartment. Furthermore, the pressure device 50 controls the gas pressure of the plurality of compartments of the coupling device 20. In FIG. 1, a plurality of arrow symbols input and output from the pressure device 50 are described, respectively corresponding to the plurality of compartments described in FIG. 1 corresponding to the same arrow symbol. The details of the control pressure of the gas pressure in each compartment will be explained later. In addition, the absolute value is lower than the atmospheric pressure "1 atm, about 1 kgf / cm2", which is defined as negative pressure; the vacuum "0 gas pressure" is also part of the negative pressure range; the absolute value is less than atmospheric "1 atm" The larger gas pressure is defined as positive pressure.

作為本發明的實施例,成長用基板13和薄膜14,例如是異質外延(heteroepitaxial)的關係,二者的晶格常數(lattice constant)不同,因此,具有開裂性(cleavage)。單晶基板(single-crystal substrate)的例示,有藍寶石(sapphire);矽類半導體有矽(silicone;Si)等。其他,還有氮化物類半導體有氮化鎵(gallium nitride;GaN);化合物類半導體有碳化矽(silicon carbide;SiC)和砷化鎵(gallium arsenide;GaAs)等。可以選擇這些素材。薄膜14是從成長用基板13長成磊晶的層,薄膜14的厚度《層的厚度》是從亞微米(submicron)到10微米(micron)《μm》程度;又,藍寶石基板《成長基板》上也可以成長氮化鎵磊晶的薄膜。稍後敘述的產品基板160也可以選擇與成長用基板130相同的素材,產品基板160,比薄膜14的厚度更厚10倍以上,是從10微米至500微米程度。As an embodiment of the present invention, the growth substrate 13 and the thin film 14 have, for example, a heteroepitaxial relationship, and the two have different lattice constants, and therefore have cleavage. Examples of single-crystal substrates include sapphire; silicon-based semiconductors include silicon (Si) and so on. In addition, there are nitride semiconductors such as gallium nitride (GaN); compound semiconductors include silicon carbide (SiC) and gallium arsenide (GaAs). These materials can be selected. The thin film 14 is an epitaxial layer that grows from the growth substrate 13, and the thickness of the thin film 14 "thickness of the layer" is from submicron to 10 microns (micron) "μm"; It is also possible to grow GaN epitaxial thin films. The product substrate 160 described later can also be selected from the same material as the growth substrate 130. The product substrate 160 is more than 10 times thicker than the thickness of the thin film 14 and is from about 10 microns to 500 microns.

於圖1中,結合裝置20係將已剝離的薄膜14轉錄至轉錄材料23的機制及構造。薄膜支持體15含有吸附於在剝離裝置10中的薄膜維持體16的薄膜14,轉錄至在結合裝置20中的轉錄材料23。結合裝置20具有支持轉錄維持體22的轉錄支持體21;轉錄支持體21被固定於機箱40《固定處未顯示於圖內》。結合裝置20具有支持薄膜支持體15的第1滑動器(slider)130;薄膜支持體15以1滑動器為介質,以可以附著和分離(attaching and detaching)的方式連接轉錄支持體21。In FIG. 1, the binding device 20 is a mechanism and structure for transcribing the peeled film 14 to the transcription material 23. The film support 15 contains the film 14 adsorbed on the film holding body 16 in the peeling device 10, and is transcribed into the transcription material 23 in the bonding device 20. The coupling device 20 has a transcription support 21 that supports the transcription maintenance body 22; the transcription support 21 is fixed to the cabinet 40 (the fixing place is not shown in the figure). The bonding device 20 has a first slider 130 that supports the film support 15; the film support 15 uses the one slider as a medium, and is connected to the transcription support 21 so as to be attachable and detachable.

結合裝置20具備了3個艙室;第4艙室300係藉由轉錄支持體21和薄膜支持體15以及第1滑動器130所形成的空間;第5艙室310係藉由轉錄支持體21和轉錄材料23以及轉錄維持體22所形成的空間;第3艙室係藉由薄膜支持體15和薄膜維持體16所形成的空間。第4艙室300內配置了轉錄材料23和薄膜維持體16、以及轉錄維持體22和薄膜14。The coupling device 20 is provided with three compartments; the fourth compartment 300 is a space formed by the transcription support 21 and the film support 15 and the first slider 130; the fifth compartment 310 is provided by the transcription support 21 and the transcription material 23 and the space formed by the transcription maintenance body 22; the third compartment is a space formed by the film support 15 and the film maintenance body 16. In the fourth compartment 300, the transcription material 23 and the film maintenance body 16, and the transcription maintenance body 22 and the film 14 are arranged.

壓力裝置50分別控制複數的艙室內的氣體壓力;第1壓力裝置51控制第3艙室220的氣體壓力,關於第3艙室220的氣體壓力的控制的詳細內容,將於後說明。The pressure device 50 controls the gas pressure in a plurality of compartments, respectively. The first pressure device 51 controls the gas pressure in the third compartment 220. Details of the control of the gas pressure in the third compartment 220 will be described later.

結合裝置20配置了氣體壓力計(pressure manometer)120;氣體壓力計120監測第5艙室310內的氣體壓力。The combination device 20 is provided with a gas manometer 120; the gas manometer 120 monitors the gas pressure in the fifth compartment 310.

圖2係剝離裝置10的放大圖。剝離裝置10,以重力方向G的地面E為基準,在地面E側配置了基板支持體11,天側配置了薄膜支持體15。圖2的剝離裝置10,將圖1未圖示的其他複數個部件(parts)更進一步揭示。剝離裝置10包含密封(seal)複數艙室《第1、第2和第3艙室》的個別的氣體壓力的第1密封料(sealer)60、第3密封料62、和第2密封料61;剝離裝置10具有藉由加熱基板維持體12使基板維持體12彈性變形的加熱器(heater)90;剝離裝置10具有紅外線局部加熱器(infrared localized heater)91;剝離裝置10具有超音波探傷器(ultrasonic flaw detector)81;剝離裝置10具有照相機(camera)170;剝離裝置10具有聲頻發射測定器(acoustic emission measuring instrument)80。 藉由加熱器90,使基板維持體和成長用基板13慢慢彎曲,對成長用基板13的周圍、以及成長用基板13和薄膜14的周圍邊界面施予會聚性的(convergent)拉引外力,也可以在薄膜14附近的成長用基板13的側面再加上雷射等的紅外線局部加熱器91。靠著超音波探傷器81,也可以在成長用基板13和薄膜14的邊界面(boundary surface)施加超音波衝擊(ultrasonic impact)。藉由這些部件,薄膜14的周圍產生開裂;藉由照相機170、聲頻發射測定器80和超音波探傷器81,監測開裂及其位置、以及開裂的程度。聲頻發射測定器80,在材料變形或破壞之際,內部蓄存的彈性能量變成音波噴出的現象,用壓電感測器(piezoelectric sensor)等監測,靠著這些監測值,控制裝置《未圖示》可以控制加熱器90等。剝離裝置10具有活動式連接基板支持體11和薄膜支持體15的連接器(connector)70、連接薄膜支持體15和薄膜維持體16的連接器72、以及連接基板支持體11和基板維持體12的連接器71;連接器71具有靈活對應基板維持體12的彎曲的特性。FIG. 2 is an enlarged view of the peeling device 10. In the peeling apparatus 10, the substrate support 11 is arranged on the ground E side, and the film support 15 is arranged on the sky side with the ground E in the gravity direction G as a reference. The peeling device 10 of FIG. 2 further discloses a plurality of other parts (not shown) of FIG. 1. The stripping device 10 includes a first sealer 60, a third sealant 62, and a second sealant 61 that seal individual gas pressures of the plurality of compartments "first, second, and third compartments"; The device 10 has a heater 90 that elastically deforms the substrate holder 12 by heating the substrate holder 12; the peeling device 10 has an infrared localized heater 91; the peeling device 10 has an ultrasonic flaw detector (ultrasonic) flaw detector) 81; the peeling device 10 has a camera 170; the peeling device 10 has an acoustic emission measuring instrument 80. The heater 90 slowly bends the substrate holder and the growth substrate 13 to apply a convergent external force to the periphery of the growth substrate 13 and the boundary surfaces of the growth substrate 13 and the film 14 Alternatively, an infrared local heater 91 such as a laser may be added to the side of the growth substrate 13 near the film 14. With the ultrasonic flaw detector 81, an ultrasonic impact may be applied to the boundary surface of the growth substrate 13 and the film 14. With these components, a crack is generated around the film 14; with the camera 170, the audio emission measuring device 80, and the ultrasonic flaw detector 81, the crack and its position and the degree of the crack are monitored. The acoustic emission measuring device 80, when the material is deformed or destroyed, the elastic energy stored inside becomes a phenomenon of sonic ejection, which is monitored by a piezoelectric sensor (piezoelectric sensor), etc. Based on these monitoring values, the control device "not shown" It can control heater 90 and so on. The peeling device 10 has a connector 70 that movably connects the substrate support 11 and the film support 15, a connector 72 that connects the film support 15 and the film support 16, and connects the substrate support 11 and the substrate support 12 Connector 71; the connector 71 has the characteristic of flexibly responding to the bending of the substrate maintaining body 12.

圖2揭示薄膜支持體15的變形量Z1,Z1在天側《重力方向G的相反側》產生變形《以虛線表示》,變形量Z1係0.3毫米(mm)~0.5毫米程度。由於也是藉由連接器72連接薄膜支持體15的變形部門17,可以得到與變形量Z1相同的效果;已剝離的薄膜14,與第3艙室220的負壓力效果同時地附帶於薄膜維持體16上,移動到天側。薄膜支持體15是例如不銹鋼(stainless steel)。Fig. 2 reveals that the deformation amount Z1 of the film support 15 is deformed on the sky side "the opposite side of the gravity direction G" "represented by a dotted line", and the deformation amount Z1 is about 0.3 millimeters (mm) to 0.5 millimeters. Since the deformation section 17 of the film support 15 is also connected by the connector 72, the same effect as the amount of deformation Z1 can be obtained; the peeled film 14 is attached to the film maintenance body 16 at the same time as the negative pressure effect of the third compartment 220 Go to the sky side. The film support 15 is, for example, stainless steel (stainless steel).

圖2揭示壓力裝置50供給3個艙室《第1、第2和第3艙室》個別最適當的氣體壓力。第1艙室200施加比大氣壓《約1千克力/平方釐米(kgf/cm2 )》更高的第1氣體壓力《比大氣壓絕對值大的正壓力》,較理想的是,施加1.5氣體壓力~3氣體壓力。薄膜支持體15的變形部門17,藉由第1艙室的氣體壓力《1.5~3氣體壓力》和對應的薄膜支持體15的外側的氣體壓力《例如,氣體壓力=1大氣壓》的差壓(differential pressure)氣體壓力《0.5~2氣體壓力》而發生變形。又,前述薄膜支持體15的的外側的氣體壓力也可以藉由壓力裝置50來控制。靠著該外側的氣體壓力的控制,幅度寬廣的差壓氣體壓力就可以控制。 對第2艙室210被施加比大氣壓更低的第2氣體壓力《比大氣壓絕對值小的負壓力》,較理想的是,施加0氣體壓力《真空》;對第3艙室220被施加比大氣壓更低的第3氣體壓力《比大氣壓絕對值小的負壓力》,較理想的是,施加0氣體壓力《真空》~0.8氣體壓力;靠著負壓力而剝離的薄膜14被吸引至第3艙室。開裂開始後的薄膜14的兩面處,施加第1氣體壓力和第3氣體壓力的差壓氣體壓力,差壓氣體壓力至少設定為1.1氣體壓力以上,藉此提高持續剝離的薄膜14和薄膜維持體16的相互吸附度(adsorbability),又,藉著提高成長用基板13和基板維持體12的相互吸附度,提高持續剝離的薄膜14的相互剝離度,其結果,可以預期剝離時間快速化;再者,藉由控制差壓氣體壓力的設定可以預期薄膜14的品質提高。 又,藉由外側的氣體壓力的控制,加寬第3氣體壓力和差壓氣體壓力的設定範圍,薄膜支持體15的變形量的設定範圍擴大;也就是說,藉由第1艙室200的第1氣體壓力、第3艙室220的第3氣體壓力和外側的氣體壓力的組合(combination),薄膜14的剝離時間、薄膜的品質提高、和變形部門17的變形量的個別設定範圍,可以隨使用者之意設定。更進而,藉由加熱器90或紅外線局部加熱器91所致之熱衝擊、或是超音波探傷器81所致之音響衝擊《機械衝擊》、和第1艙室200的第1氣體壓力的組合,薄膜14的剝離時間和薄膜的品質提高的個別設定範圍,可以隨使用者之意設定。Fig. 2 reveals that the pressure device 50 supplies the most suitable gas pressures of the three compartments "1st, 2nd and 3rd compartments" individually. In the first compartment 200, a first gas pressure "positive pressure greater than the absolute value of atmospheric pressure" higher than atmospheric pressure "about 1 kilogram force per square centimeter (kgf / cm 2 )" is applied. Preferably, a gas pressure of 1.5 is applied ~ 3 Gas pressure. The deformation section 17 of the membrane support 15 is based on the differential pressure of the gas pressure of the first compartment "1.5 to 3 gas pressure" and the corresponding gas pressure outside the membrane support 15 "for example, gas pressure = 1 atmosphere" (differential pressure) gas pressure "0.5 ~ 2 gas pressure" and deformed. In addition, the gas pressure outside the film support 15 may be controlled by the pressure device 50. By controlling the gas pressure outside, a wide range of differential pressure gas pressure can be controlled. To the second chamber 210, a second gas pressure "negative pressure smaller than the absolute value of atmospheric pressure" that is lower than atmospheric pressure is applied, ideally, 0 gas pressure "vacuum" is applied; to the third chamber 220, a pressure greater than atmospheric pressure is applied. The low third gas pressure "negative pressure smaller than the absolute value of atmospheric pressure" is ideally applied with 0 gas pressure "vacuum" to 0.8 gas pressure; the film 14 peeled off by the negative pressure is attracted to the third compartment. After the cracking starts, a differential gas pressure of the first gas pressure and the third gas pressure is applied to both sides of the film 14, the differential gas pressure is set to at least 1.1 gas pressure, thereby improving the continuous peeling of the film 14 and the film support The mutual adsorption degree of 16, and by increasing the mutual adsorption degree of the growth substrate 13 and the substrate maintenance body 12, the mutual peeling degree of the continuously peeling film 14 is increased, as a result, the peeling time can be expected to be quick; Furthermore, by controlling the setting of the differential pressure gas pressure, the quality of the membrane 14 can be expected to improve. Moreover, by controlling the gas pressure outside, the setting range of the third gas pressure and the differential pressure gas is widened, and the setting range of the deformation amount of the film support 15 is expanded; that is, by the first compartment 200 1 The combination of the gas pressure, the third gas pressure of the third compartment 220 and the outside gas pressure, the peeling time of the film 14, the improvement of the quality of the film, and the individual setting range of the deformation amount of the deformation section 17, can be used as needed The intention of the person is set. Furthermore, the combination of the thermal shock caused by the heater 90 or the infrared local heater 91, or the acoustic shock "mechanical shock" caused by the ultrasonic flaw detector 81, and the first gas pressure of the first compartment 200, The individual setting range of the peeling time of the film 14 and the improvement of the film quality can be set according to the user's intention.

圖3係說明剝離裝置10的非加熱時的狀態的圖示;圖4係說明剝離裝置10的加熱時的狀態的圖示。基板維持體12具有貫通的複數個孔(hole)24,藉由第2艙室210的負壓力,吸引成長用基板13;薄膜維持體16具有貫通的複數個孔(hole)25,薄膜維持體16包含相互層積的2層的多孔金屬墊(porous metallic pad)100和碳奈米墊(carbon nano pad)101;藉由第3艙室220的負壓力,以薄膜維持體16《含多孔金屬墊100和碳奈米墊101》為介質,吸附已剝離的薄膜14。 具有複數個孔25的薄膜維持體16的部份的厚度係5毫米;薄膜維持體16的複數個孔25,2毫米的孔《2毫米直徑》以4毫米單位在陣列(array)上展開來配置;具有複數個孔25的多孔金屬墊100的部份的厚度係1.5毫米,多孔金屬墊100的複數個孔25,20微米的孔《2微米直徑》以50微米單位在陣列上展開來配置;如同稍後描述,用纖維狀的微細纖維(microfiber)或奈米纖維(nanofiber)做成的碳奈米墊,具有微米單位《微米(μm)單位直徑》或奈米單位《奈米(ηm)單位直徑》的複數個的微細孔。薄膜維持體16和多孔金屬墊100,導電性是令人滿意的,可以防止剝離當中發生的薄膜14的靜電放電損壞(electrostatic discharge damage)。 薄膜維持體16和碳奈米墊101,係配置為挾住多孔金屬墊100;薄膜維持體16是從鋁(aluminum)或其合金、黃銅(brass)類、鋼(steel)、不銹鋼(stainless steel)選取;多孔金屬墊100係從銅、鋁或以其為主成分做成的合金等選取,希望是熱傳導(heat conduction)的良好材料。碳奈米墊101,希望是用纖維狀的微細纖維(microfiber)或奈米纖維(nanofiber)做成的材料;其形狀,可以從墊子(pad)、片狀(sheet)、和布(cloth)選用;可以從微細纖維碳奈米管(microfiber carbon nanotube)、碳奈米纖維(carbon nanofiber)、含碳粉末的碳纖維混紡纖維素奈米纖維(cellulose nanofiber)等選取使用。這些物質,具有線性熱膨脹係數(linear thermal expansion coefficient)比玻璃纖維(glass fiber)小、彈性模數(elastic modulus)比玻璃纖維高的優良特性,可以預期薄膜14的品質提高。FIG. 3 is a diagram illustrating the state of the peeling device 10 during non-heating; FIG. 4 is a diagram illustrating the state of the peeling device 10 during heating. The substrate holder 12 has a plurality of holes 24 penetrating through it, and the growth substrate 13 is attracted by the negative pressure of the second chamber 210; the film holder 16 has a plurality of holes 25 penetrating through the film holder 16 It consists of two layers of porous metallic pads 100 and carbon nano pads 101 stacked on top of each other; with the negative pressure of the third compartment 220, the membrane support 16 contains porous metal pads 100 With carbon nano pad 101 "as a medium, the peeled film 14 is adsorbed. The thickness of the portion of the film holding body 16 having a plurality of holes 25 is 5 mm; the plurality of holes 25 of the film holding body 16 and the holes 2 mm in diameter "2 mm diameter" spread out on the array in units of 4 mm Configuration; the thickness of the part of the porous metal pad 100 having a plurality of holes 25 is 1.5 mm, the plurality of holes 25 of the porous metal pad 100, the 20 micrometer holes "2 micrometer diameter" are deployed on the array in units of 50 micrometers ; As described later, carbon nano mats made of fibrous microfibers or nanofibers have a micron unit "micron (μm) unit diameter" or a nanometer unit "nano (ηm ) Unitary diameters "multiple fine holes. The thin film support 16 and the porous metal pad 100 have satisfactory electrical conductivity, and can prevent electrostatic discharge damage of the thin film 14 during peeling. The film holder 16 and the carbon nano-pad 101 are configured to hold the porous metal pad 100; the film holder 16 is made of aluminum or its alloy, brass, steel, steel, and stainless steel) selection; the porous metal pad 100 is selected from copper, aluminum, or alloys made of the main component thereof, and is expected to be a good material for heat conduction. Carbon nano pad 101 is expected to be made of fibrous microfiber or nanofiber; its shape can be selected from pad, sheet, and cloth ; Can be selected from microfiber carbon nanotubes, carbon nanofibers, carbon fiber-blended carbon fiber blended cellulose nanofibers, etc. These substances have the excellent characteristics that the linear thermal expansion coefficient is smaller than that of glass fiber and the elastic modulus is higher than that of glass fiber, and it is expected that the quality of the film 14 will be improved.

說明圖3的非加熱時的剝離裝置10的狀態。薄膜14和薄膜維持體16《含多孔金屬墊100和碳奈米墊101》之間具有0.1毫米程度的縫隙(gap)Z3,如同圖2所揭示,氣體(gas)被供給至第1艙室200,氣體可以選用乾燥空氣、惰性氣體(inert gas)的氮氣(N2 )、活性氣體(activated gas)的氫氣(H2 )。氫原子的波耳半徑(Bohr radius)αb=0.0539奈米(nm)是原子中最小的;氮化鎵(GaN)的晶格常数(lattice constant)係通過氫原子的充足的晶格常数0.539奈米;矽的晶格常数是0.5431奈米;缺陷晶格(defect lattice)更進而加速氫原子的擴散。 氫原子《H2 》以縫隙Z3和薄膜14為介質,侵入在成長用基板13的面和剝離膜14的面相互接觸的範圍處,該範圍處所含有的晶格圖樣(lattice pattern)不同的剝離區域《緩衝層(buffer)》,並擴散開來,原子的波耳半徑越小則擴散係數會變大,氫原子使薄膜14從成長用基板13剝離的開裂起始時間提早,更進而,因為也提早開裂完成的終了時間,可以縮短開裂期間的時間。 又,供應給第1艙室200的氣體,也可以是氦氣(helium;He);再者,供應給第1艙室200的氣體,也可以是比薄膜的波耳半徑還小的波耳半徑的原子或分子的氣體、和其他的氣體的混合物。又,0.1毫米以下的縫隙(gap)Z3,從薄膜14在薄膜維持體12的吸附性能的觀點來看,要在抵銷薄膜支持體15的變形量Z1《0.3~0.5毫米》的方向做工;但是,藉由前述控制差壓氣體壓力的設定,就可以克服。又,也可以用氮氣取代氫氣來供應;還有,取代氫氣而供應乾燥空氣的情形時,縫隙Z3也可能做成0.0毫米。The state of the peeling device 10 during non-heating in FIG. 3 will be described. There is a gap Z3 of about 0.1 mm between the film 14 and the film maintenance body 16 "containing porous metal pad 100 and carbon nano pad 101". As shown in FIG. 2, gas is supplied to the first compartment 200 For the gas, dry air, inert gas (nitrogen) (N 2 ), and activated gas (hydrogen gas) (H 2 ) can be used. The Bohr radius of hydrogen atoms (Bohr radius) αb = 0.0539 nanometers (nm) is the smallest of the atoms; the lattice constant of gallium nitride (GaN) is a sufficient lattice constant of 0.539 nanometers through hydrogen atoms M; the lattice constant of silicon is 0.5431 nm; the defect lattice accelerates the diffusion of hydrogen atoms. The hydrogen atom "H 2 " invades the area where the surface of the growth substrate 13 and the surface of the peeling film 14 are in contact with each other using the gap Z3 and the thin film 14, and the lattice pattern contained in this range is peeled off with different lattice patterns Area "buffer", and spread out, the smaller the Bohr radius of the atoms, the larger the diffusion coefficient, and the hydrogen atom will cause the film 14 to peel off from the growth substrate 13 and the crack start time is earlier, and further, because It is also possible to shorten the period of time during the cracking by early completion of the cracking. In addition, the gas supplied to the first compartment 200 may also be helium (He); furthermore, the gas supplied to the first compartment 200 may also be a Boer radius smaller than that of the film A mixture of atomic or molecular gases and other gases. In addition, the gap Z3 of 0.1 mm or less, from the viewpoint of the adsorption performance of the film 14 on the film maintenance body 12, work in the direction to offset the deformation Z1 "0.3-0.5 mm" of the film support 15; However, it can be overcome by controlling the setting of the differential pressure gas pressure as described above. In addition, it is also possible to supply nitrogen instead of hydrogen. In the case of supplying dry air instead of hydrogen, the gap Z3 may be made 0.0 mm.

又,供應給第1艙室200的氣體雖然是氫氣,但也可以是在艙室內白金(platinum)或鈀(palladium)催化作用(catalysis)所產生的氫原子,比氫分子H2 的擴散更快速擴散。比成長用基板13和剝離膜14的晶格常数還要小的波耳半徑的氣體,使薄膜14的剝離時間的縮短可以預期。In addition, although the gas supplied to the first compartment 200 is hydrogen, it may also be a hydrogen atom generated by platinum or palladium catalysis in the compartment, which diffuses faster than the hydrogen molecule H 2 diffusion. A gas with a Bohr radius smaller than the lattice constant of the growth substrate 13 and the peeling film 14 can shorten the peeling time of the thin film 14.

還有,製造設備1、或剝離裝置10內的第1艙室200中,也可以裝備氫添加時的作為負載型催化劑(supported catalyst)的支撐物(support),作為催化劑而使用的金屬,可以選擇鉑黑(platinum black)《黑色粉末狀的白金(black powdered platinum)》、鈀黑(palladium black)《表面有亞微米級(submicron level)明顯凹凸附著之物》、鈀碳(palladium on carbon;Pd/C)《將超微粒子的鈀金屬吸附在活性碳上之物》。作為支撐物,沸石(zeolite)是較合於理想的;使氫分子變成2個氫原子(2H)《重氫(heavy hydrogen;deuterium)》,可以預期更進一步擴散的加速。支撐物裝備在製造設備1的情形時,較合於理想的是如圖2所示之支撐物裝備在氣體供應機制中;支撐物裝備在第1艙室200的情形時,較合於理想的是如圖3所示之活動式裝備在薄膜維持體16和薄膜14之間《縫隙Z3》,基板維持體12被加熱的作業之前,活動式支撐物從縫隙Z3脫離。In addition, the first chamber 200 in the manufacturing facility 1 or the peeling device 10 may be equipped with a support as a supported catalyst at the time of hydrogen addition, and the metal used as the catalyst may be selected. Platinum black, "black powdered platinum," palladium black, "submicron level (submicron level) obvious irregularities attached to the surface", palladium on carbon; Pd / C) "Adsorption of ultrafine particles of palladium metal on activated carbon". As a support, zeolite is ideal; turning hydrogen molecules into 2 hydrogen atoms (2H) "heavy hydrogen (deuterium)" can be expected to accelerate further diffusion. When the support is equipped in the case of manufacturing equipment 1, it is preferable that the support is equipped in the gas supply mechanism as shown in FIG. 2; when the support is equipped in the first compartment 200, it is more ideal As shown in FIG. 3, the movable equipment is provided between the film holding body 16 and the film 14 with a "gap Z3". Before the substrate holding body 12 is heated, the movable support is detached from the gap Z3.

圖4中,說明加熱時的剝離裝置10的狀態。基板維持體12和成長用基板13,靠著加熱器90被加熱至200℃以下,慢慢彎曲。其結果,成長用基板13的四周邊緣開始開裂,生出縫隙Z2,縫隙Z2意指薄膜14從成長用基板13的剝離。In FIG. 4, the state of the peeling apparatus 10 at the time of heating is demonstrated. The substrate holding body 12 and the growth substrate 13 are heated by the heater 90 to 200 ° C. or lower, and are gradually bent. As a result, the peripheral edges of the growth substrate 13 begin to crack, and a gap Z2 is generated. The gap Z2 means the peeling of the thin film 14 from the growth substrate 13.

圖5係薄膜支持體15的放大剖面圖,揭示變形部門17和剪切部門18、以及薄膜支持體15的厚度。不銹鋼材質的薄膜支持體15具有不銹鋼材質的基本厚度t0《未變形部分的標準厚度》;變形部門17含有比t0更薄的厚度t1~t4《但,t2顯示是溝槽寬度的縫隙》,複數個厚度t1~t4的厚度,如後述之不等號表示《t4<t3<t2<t1》;剪切部門18包含最薄的厚度t4。剪切部門18配置在第2密封料61的外側,也就是說,剪切部門18係對應第1艙室200配置;剪切部門18係對應薄膜支持體15的外側而配置。剪切部門18是剪切不銹鋼材料的一部份在厚度方向做成的孔穴.溝槽.階梯等的部分,也就是說,是在應力集中(stress concentration)最容易顯現的地方。 剪切部門18具有2個溝槽;作為變形部門的構造,對於變形量Z1《0.3毫米~0.5毫米》最具效果的構造是相當於t0-t4的溝槽的深度《圖5中的Y軸方向》、和相當t2的溝槽的寬度《圖5中的X軸方向》。圖5所顯示之變形部門17的範圍19,大約是200毫米直徑,因此,薄膜維持體16和薄膜14、以及成長用基板13的直徑比200毫米小,例如,t0=10毫米、t1=6毫米、t2=5毫米、t3=4毫米、t4=2毫米,是合於理想的。FIG. 5 is an enlarged cross-sectional view of the film support 15, revealing the deformation section 17 and the shear section 18, and the thickness of the film support 15. The stainless steel film support 15 has a basic thickness t0 of stainless steel "standard thickness of undeformed part"; the deformation section 17 contains a thickness t1 to t4 which is thinner than t0 "however, t2 shows a gap of groove width", plural The thickness of each thickness t1 to t4, as the inequality sign described later means "t4 <t3 <t2 <t1"; the shear section 18 includes the thinnest thickness t4. The shearing section 18 is arranged outside the second sealing material 61, that is, the shearing section 18 is arranged corresponding to the first compartment 200; the shearing section 18 is arranged corresponding to the outside of the film support 15. The shear section 18 is a hole made by shearing a part of the stainless steel material in the thickness direction. Groove. Steps, etc., that is, where stress concentration is most likely to appear. The shear section 18 has 2 grooves; as the structure of the deformation section, the most effective structure for the deformation Z1 "0.3 mm to 0.5 mm" is the depth of the groove equivalent to t0-t4 "Y axis in FIG. 5 Direction ", and the width of the groove corresponding to t2" X-axis direction in FIG. 5 ". The range 19 of the deformation section 17 shown in FIG. 5 is approximately 200 mm in diameter. Therefore, the diameters of the film holder 16 and the film 14 and the growth substrate 13 are smaller than 200 mm, for example, t0 = 10 mm, t1 = 6 Mm, t2 = 5 mm, t3 = 4 mm, t4 = 2 mm, which is ideal.

圖6係薄膜支持體15的頂面圖;圖6以供應氣體壓力給第3艙室220的空洞部門為中心,揭示剪切部門18的形狀。圖6的空洞部門以圓形表示,例如矽等的晶圓(wafer)形狀的成長用基板13,薄膜14的形狀對應於該晶圓形狀,圖6的薄膜支持體15則對應薄膜14的形狀;產品基板160的形狀也是對應於該晶圓形狀。圖7係顯示圖6薄膜支持體15的變形例之薄膜支持體15A的頂面圖,以下圖7中,僅就與圖6相異點加以說明,圖7的剪切部門18A係以長方形形狀表示,例如顯示器(display)等的長方形形狀之成長用基板13,薄膜14的形狀對應於該長方形形狀,圖7的薄膜支持體15A則對應薄膜14的形狀;產品基板160的形狀也是對應於該長方形形狀。也就是說,關連到電子部件的形狀。再者,圖7的範圍19A對應於圖6的範圍19。FIG. 6 is a top view of the film support 15; FIG. 6 reveals the shape of the shearing section 18 centering on the hollow section that supplies gas pressure to the third compartment 220. The cavity portion of FIG. 6 is represented by a circle. For example, a wafer-shaped growth substrate 13 such as silicon, the shape of the film 14 corresponds to the shape of the wafer, and the film support 15 of FIG. 6 corresponds to the shape of the film 14 ; The shape of the product substrate 160 also corresponds to the shape of the wafer. FIG. 7 is a top view of the film support 15A of the modified example of the film support 15 of FIG. 6. In the following FIG. 7, only differences from FIG. 6 are explained. The shearing section 18A of FIG. 7 is in a rectangular shape. For example, a rectangular shaped growth substrate 13 such as a display, the shape of the film 14 corresponds to the rectangular shape, and the film support 15A of FIG. 7 corresponds to the shape of the film 14; the shape of the product substrate 160 also corresponds to this Rectangular shape. That is, it is related to the shape of the electronic component. Furthermore, the range 19A of FIG. 7 corresponds to the range 19 of FIG. 6.

圖8~圖10係個別為與圖5不同構造的薄膜支持體15B、15C、15D的放大剖面圖;於圖8~圖10中,關於與圖5相同的元件,使用相同的符號,而省略重複的說明;圖8~圖10個別揭示變形部門17B、17C、17D和薄膜支持體15 B、15C、15D的厚度。於圖8中,不銹鋼材質的薄膜支持體15B具有不銹鋼材質的基本厚度t5;變形部門17B含有比t5更薄的厚度t6;複數個的厚度t5、t6的厚度,以不等號表示;厚度t6的不銹鋼材料是彎曲的構造。於図9中,不銹鋼材質的薄膜支持體15C具有不銹鋼材質的基本厚度t7;變形部門17C含有比t7更薄的厚度t8~t10;複數個的厚度t7~t10,如後述之不等號表示《t10<t9<t8<t7》;變形部門17C是t8~t10慢慢變薄的厚度的構造。於図10中,不銹鋼材質的薄膜支持體15D具有有不銹鋼材質的基本厚度;變形部門17D含有比基本厚度更薄的厚度t11、t12,含有作為彈性體(elastic body)的彈簧(spring)110;複數個的厚度t11、t12,如後述之不等號表示《t12<t11》;變形部門17D是藉由厚度t11、t12和彈簧110的組合得到變形量Z1的構造。又,彈簧(spring)110是彈性體的一個例子。8 to 10 are enlarged cross-sectional views of thin film supports 15B, 15C, and 15D with different structures from FIG. 5; in FIGS. 8 to 10, the same symbols are used for the same elements as in FIG. 5 and are omitted. Repeated description; Figures 8 to 10 individually disclose the thickness of the deformation sections 17B, 17C, 17D and the film support 15B, 15C, 15D. In FIG. 8, the stainless steel film support 15B has a basic thickness t5 of stainless steel; the deformation section 17B contains a thinner thickness t6 than t5; a plurality of thicknesses t5 and t6 are indicated by unequal signs; the thickness t6 The stainless steel material is of curved construction. In Fig. 9, the stainless steel film support 15C has a basic thickness t7 of stainless steel; the deformation section 17C contains a thickness t8 to t10 that is thinner than t7; a plurality of thicknesses t7 to t10. t10 <t9 <t8 <t7 >>; the deformation section 17C is a structure with a thickness gradually thinning from t8 to t10. In FIG. 10, the stainless steel film support 15D has a basic thickness of stainless steel; the deformation section 17D contains thicknesses t11 and t12 that are thinner than the basic thickness, and contains a spring 110 as an elastic body. A plurality of thicknesses t11 and t12, as the inequality sign described later means "t12 <t11"; the deformation section 17D is a structure in which the amount of deformation Z1 is obtained by the combination of the thicknesses t11, t12 and the spring 110. Moreover, the spring (spring) 110 is an example of an elastic body.

圖11和圖12揭示包含薄膜支持體15的結合裝置20的剖面圖。結合裝置20裝配了可沿著天地方向《重力方向G》上下移動(vertical movement)轉錄支持體21的上下機制(up and down mechanism)140;結合裝置20,相對於轉錄支持體21,裝配薄膜支持體15和第1滑動器130,具有使它們各自沿著重力方向G滑動的軸承(bearing)131。圖11顯示已剝離的薄膜14被吸附在薄膜維持體16上的薄膜支持體15,定位(setting)在轉錄支持體21的第1狀態。 圖12顯示藉由上下機制140,轉錄支持體21向天側方向上升,薄膜14和轉錄材料23相接觸的第2狀態。藉由照相機170,監測薄膜14和轉錄材料23間的距離,控制上下機制140;薄膜14和轉錄材料23間的距離達到預定的值以後,控制第3艙室220的氣體壓力從負壓力轉為正壓力,將薄膜14轉錄至轉錄材料23;氣體壓力計120,藉由監測第5艙室310內的氣體壓力,間接地掌握轉錄狀態,控制第3艙室220的氣體壓力或上下機制140;又,調整第4艙室300內的氣體壓力的供應口,並未圖示出來。該供應口連接壓力裝置50,壓力裝置50在轉錄支持體21向天側方向上升的時候,調整第4艙室300內的氣體壓力。再者,第4艙室300內的氣體壓力,與第3艙室220的氣體壓力連動,可以聯繫在一起,舉例來說,控制第3艙室220的氣體壓力從負壓力轉為正壓力,將薄膜14轉錄到轉錄材料23;此時,第4艙室300內的氣體壓力控制為負壓力,藉此可以預期轉錄品質和轉錄速度提高。還有,第4艙室300內的氣體壓力和第3艙室220的氣體壓力,也可以只用負壓力控制,轉錄時的第4艙室300內的氣體壓力和第3艙室220的氣體壓力的差壓氣體壓力是重要的。 轉錄材料23,較理想的是:薄膜狀(film)或窄帶狀(tape)的支持體《基材》上,相對於支持體,在垂直方向配置碳奈米管或石墨烯(graphene)的具纖維結構體的可以吸附和剝離的轉錄材料。轉錄材料23,不使用黏著劑,靠著原子或分子間做工的凡得瓦爾力(Van der Waals force)將薄膜14吸附,因此,轉錄材料23可以防止薄膜14的污染;具有導電性的轉錄材料23防止薄膜14的靜電放電損壞(electrostatic discharge damage),因此,轉錄材料23可以提高薄膜14的品質;轉錄材料23可以再使用,因此,轉錄材料23對削減成本有用。 再說,薄膜狀(film)或窄帶狀(tape)的支持體《基材》上,具有微級(microlevel)的吸盤功能,可以吸附和剝離,因此選擇能再使用的轉錄材料23也是可以的。轉錄材料23也可以取代產品基板《藍寶石(sapphire);矽(silicone;Si)、氮化鎵(gallium nitride;GaN)、碳化矽(silicon carbide;SiC)或砷化鎵(gallium arsenide;GaAs)等》。11 and 12 disclose cross-sectional views of the bonding device 20 including the film support 15. The coupling device 20 is equipped with an up and down mechanism 140 that can move the transcription support 21 up and down along the heaven and earth direction "gravity direction G"; the coupling device 20, relative to the transcription support 21, is equipped with a film support The body 15 and the first slider 130 have a bearing 131 that slides each along the gravity direction G. FIG. 11 shows that the peeled film 14 is adsorbed on the film support 15 on the film support 16 and is set in the first state of the transcription support 21. FIG. 12 shows the second state in which the transcription support 21 rises to the sky side by the up-down mechanism 140 and the film 14 and the transcription material 23 are in contact. With the camera 170, the distance between the film 14 and the transcription material 23 is monitored to control the up and down mechanism 140; after the distance between the film 14 and the transcription material 23 reaches a predetermined value, the gas pressure of the third compartment 220 is controlled from negative pressure to positive Pressure to transcribe the film 14 to the transcription material 23; the gas pressure gauge 120, by monitoring the gas pressure in the fifth compartment 310, indirectly grasp the transcription status, control the gas pressure in the third compartment 220 or the up and down mechanism 140; The gas pressure supply port in the fourth compartment 300 is not shown. A pressure device 50 is connected to the supply port. The pressure device 50 adjusts the gas pressure in the fourth compartment 300 when the transcription support 21 rises in the skyward direction. Furthermore, the gas pressure in the fourth compartment 300 can be linked to the gas pressure in the third compartment 220. For example, the gas pressure in the third compartment 220 can be controlled from negative pressure to positive pressure to change the membrane 14 Transcribed to the transcription material 23; at this time, the gas pressure in the fourth compartment 300 is controlled to a negative pressure, whereby the transcription quality and transcription speed can be expected to increase. In addition, the gas pressure in the fourth compartment 300 and the gas pressure in the third compartment 220 may be controlled by only negative pressure. The difference between the gas pressure in the fourth compartment 300 and the gas pressure in the third compartment 220 during transcription Gas pressure is important. The transcription material 23 is preferably: a film or narrow tape support "substrate", and a carbon nanotube or graphene is arranged in a vertical direction relative to the support Transcription material with fiber structure that can be adsorbed and peeled off. The transcription material 23 does not use an adhesive, and the thin film 14 is adsorbed by the Van der Waals force of work between atoms or molecules. Therefore, the transcription material 23 can prevent the contamination of the thin film 14; the conductive transcription material 23 prevents electrostatic discharge damage of the thin film 14. Therefore, the transcription material 23 can improve the quality of the thin film 14; the transcription material 23 can be reused. Therefore, the transcription material 23 is useful for cost reduction. Furthermore, the film or narrow tape support "substrate" has a microlevel sucker function, which can be adsorbed and peeled off, so it is also possible to choose a reusable transcription material 23 . The transcription material 23 can also replace the product substrate "sapphire"; silicon (Si), gallium nitride (GaN), silicon carbide (SiC) or gallium arsenide (GaAs), etc. ".

圖13和圖14揭示包含第2薄膜支持體115的結合裝置20的剖面圖。結合裝置20,取代圖11和圖12的薄膜支持體15,具有第2薄膜支持體115;結合裝置20,相對於轉錄支持體21,裝備第2薄膜支持體115和第2滑動器150,具有使這些沿著重力方向G滑動的軸承;結合裝置20,具有第2薄膜支持體115和第2轉錄材料123、以及第2薄膜維持體116,第2薄膜維持體116係連接器,挾在第2薄膜支持體115和第2滑動器150之間維持在那裏;第2滑動器150具有貫通的孔151。 第2轉錄維持體122,以該孔151為介質,在壓力裝置50中控制為負壓力,吸附在第2滑動器150處;包含第2薄膜支持體115的結合裝置20,具有第2薄膜支持體115、第2滑動器150、第2轉錄維持體122、和第2轉錄材料123所做成的第6艙室320;第2薄膜維持體116係配置在第6艙室320內。第2薄膜支持體115具有孔153,例如,壓力裝置50包含的第1壓力裝置51《參照圖1》,以該孔153為介質,控制第6艙室320的氣體壓力。 第4艙室300係藉由轉錄支持體21、第2滑動器150、第2轉錄維持體122、和第2轉錄材料123所做成的。製造設備1,裝備了第2薄膜支持體115可附著和分離(attaching and detaching)結合裝置20的第2薄膜支持體運送機制230;第2薄膜支持體運送機制230包含第2薄膜支持體移動材料231;第2薄膜支持體115連接第2薄膜支持體移動材料231。13 and 14 show cross-sectional views of the bonding device 20 including the second film support 115. The coupling device 20, instead of the film support 15 of FIGS. 11 and 12, has a second film support 115; the coupling device 20, which is equipped with a second film support 115 and a second slider 150 with respect to the transcription support 21, has Bearings that slide these in the direction of gravity G; the coupling device 20 has a second film support 115 and a second transcription material 123, and a second film holder 116, and the second film holder 116 is a connector, which is attached to the first 2 The film support 115 and the second slider 150 are maintained there; the second slider 150 has a hole 151 therethrough. The second transcription maintaining body 122, using the hole 151 as a medium, is controlled to a negative pressure in the pressure device 50, and is adsorbed at the second slider 150; the coupling device 20 including the second film support 115 has a second film support The sixth compartment 320 made of the body 115, the second slider 150, the second transcription maintaining body 122, and the second transcription material 123; the second film maintaining body 116 is disposed in the sixth compartment 320. The second membrane support 115 has a hole 153, for example, the first pressure device 51 (see FIG. 1) included in the pressure device 50, and uses the hole 153 as a medium to control the gas pressure of the sixth chamber 320. The fourth compartment 300 is created by the transcription support 21, the second slider 150, the second transcription maintenance body 122, and the second transcription material 123. Manufacturing facility 1, equipped with a second film support transport mechanism 230 equipped with a second film support 115 attaching and detaching coupling device 20; the second film support transport mechanism 230 contains a second film support moving material 231; The second film support 115 is connected to the second film support moving material 231.

圖13顯示第2薄膜支持體115定位(setting)在轉錄支持體21的第1狀態。該第1狀態係圖12所示之與轉錄材料23結合的薄膜14的狀態;圖14顯示靠著上下機制140,轉錄支持體21向天側方向上升,薄膜14和第2轉錄材料123連接的第2狀態;藉由未圖示的照相機,監測薄膜14和第2轉錄材料123之間的距離,控制上下機制140;監測薄膜14和第2轉錄材料123之間的距離達到預定值以後,以第2薄膜支持體115所具有之孔153為介質,控制第6艙室320的氣體壓力從負壓力轉為正壓力,薄膜14被轉錄到第2轉錄材料123。 氣體壓力計120靠著監測第5艙室310內的氣體壓力,間接掌握轉錄狀態,控制第6艙室320或上下機制140;又,調整第6艙室320內的氣體壓力的供應口《第2薄膜支持體115所具有之孔153》連接於壓力裝置50;壓力裝置50,當轉錄支持體21向天側方向上升時,調整第6艙室320內的氣體壓力。再者,第4艙室300內的氣體壓力,可以和第6艙室320內的氣體壓力連動而相關聯,舉例來說,控制第6艙室320內的氣體壓力從負壓力或大氣壓轉為正壓力,薄膜14就轉錄於第2轉錄材料123;此時,第4艙室300內的氣體壓力控制為負壓力,然後,藉由這些作業,可以預期轉錄品質和轉錄速度的提高。還有,第4艙室300內的氣體壓力、和第6艙室320內的氣體壓力,也可以控制為只有負壓力、負壓力和大氣壓、負壓力和正壓力、大氣壓和正壓力、或只有正壓力;轉錄時的第4艙室300內的氣體壓力和第6艙室320內的氣體壓力的差壓氣體壓力是重要的。 第2轉錄材料123,較理想的是:薄膜狀(film)或窄帶狀(tape)的支持體《基材》上,相對於支持體,在垂直方向配置碳奈米管或石墨烯(graphene)的具纖維結構體的可以吸附和剝離的轉錄材料。第2轉錄材料123,不使用黏著劑,靠著原子或分子間做工的凡得瓦爾力(Van der Waals force)將薄膜14吸附,因此,第2轉錄材料123可以防止薄膜14的污染;具有導電性的第2轉錄材料123防止薄膜14的靜電放電損壞(electrostatic discharge damage),因此,第2轉錄材料123可以提高薄膜14的品質;轉錄材料23可以再使用,因此,第2轉錄材料123對削減成本有用。因為作成第2轉錄材料123的吸附力比轉錄材料23的吸附力大的設計值,從薄膜14的轉錄材料23到第2轉錄材料123的轉錄可以容易地實現。 再說,薄膜狀(film)或窄帶狀(tape)的支持體《基材》上,具有微級(microlevel)的吸盤功能,可以吸附和剝離,因此選擇能再使用的第2轉錄材料123也是可以的。第2轉錄材料123也可以取代產品基板《藍寶石(sapphire);矽(silicone;Si)、氮化鎵(gallium nitride;GaN)、碳化矽(silicon carbide;SiC)或砷化鎵(gallium arsenide;GaAs)等》。FIG. 13 shows the first state where the second thin film support 115 is set on the transcription support 21. This first state is the state of the film 14 combined with the transcription material 23 shown in FIG. 12; FIG. 14 shows that the transcription support 21 rises toward the sky side by the up-down mechanism 140, and the film 14 and the second transcription material 123 are connected. The second state; monitor the distance between the film 14 and the second transcription material 123 by a camera (not shown) to control the up and down mechanism 140; after the distance between the film 14 and the second transcription material 123 reaches a predetermined value, to The hole 153 of the second film support 115 is a medium, and the gas pressure of the sixth chamber 320 is controlled from negative pressure to positive pressure, and the film 14 is transcribed to the second transcription material 123. The gas pressure gauge 120 monitors the gas pressure in the fifth compartment 310 by indirectly grasping the transcription status, and controls the sixth compartment 320 or the up-down mechanism 140; The hole 153 of the body 115 is connected to the pressure device 50; the pressure device 50 adjusts the gas pressure in the sixth compartment 320 when the transcription support 21 rises to the sky side. Furthermore, the gas pressure in the fourth compartment 300 can be linked to the gas pressure in the sixth compartment 320, for example, to control the gas pressure in the sixth compartment 320 from negative pressure or atmospheric pressure to positive pressure, The film 14 is transcribed on the second transcription material 123; at this time, the gas pressure in the fourth compartment 300 is controlled to a negative pressure, and then, through these operations, the improvement in transcription quality and transcription speed can be expected. In addition, the gas pressure in the fourth compartment 300 and the gas pressure in the sixth compartment 320 can also be controlled to only negative pressure, negative pressure and atmospheric pressure, negative pressure and positive pressure, atmospheric pressure and positive pressure, or only positive pressure; transcription The differential gas pressure between the gas pressure in the fourth compartment 300 and the gas pressure in the sixth compartment 320 at that time is important. The second transcription material 123 is preferably a film or narrow tape support "substrate", and a carbon nanotube or graphene is arranged in a vertical direction relative to the support ) Transcription material with fiber structure that can be adsorbed and peeled off. The second transcription material 123 does not use an adhesive, and absorbs the thin film 14 by the Van der Waals force of work between atoms or molecules. Therefore, the second transcription material 123 can prevent the contamination of the thin film 14; it has conductivity The second transcription material 123 prevents electrostatic discharge damage of the film 14, so the second transcription material 123 can improve the quality of the film 14; the transcription material 23 can be reused, so the second transcription material 123 is reduced The cost is useful. Since the design value of the adsorption force of the second transcription material 123 is larger than that of the transcription material 23, transcription from the transcription material 23 of the film 14 to the second transcription material 123 can be easily realized. Furthermore, the film or narrow tape support "substrate" has a microlevel sucker function and can be adsorbed and peeled off, so the second transcription material 123 that can be reused is also selected Yes. The second transcription material 123 can also replace the product substrate sapphire; silicon (Si), gallium nitride (GaN), silicon carbide (SiC) or gallium arsenide (GaAs) )Wait".

圖15~圖19揭示本發明製造設備《圖2~圖14》處理薄膜的第1~第5的狀態。圖15係成長用基板13和薄膜14被裝載(loading)於圖2的剝離裝置10的狀態;薄膜14具有A面和、在A面相對側的對應成長用基板13的面的B面,舉例來說,A面表示P型層(P-type layer)、B面表示N型層(N-type layer);舉例來說,第1化合物半導體InP基板《成長用基板》上,順序形成來自第2化合物半導體InAsxP1-x《x=0.05、0.10、0.15、0.20、0.25、0.30》的複數的組分梯度層(composition gradient layer)《複數的薄膜》的情形時,A面表示第1層《最後層;x=0.30;InAs0.30P0.70》、B面表示第2層《x=0.05;InAs0.05P0.95》;舉例來說,在藍寶石成長用基板上,使氮化鎵、氮化鋁、氮化銦(InN;Indium Nitride)、和這些的混晶,以最適當的構造,順序層積成長的III-V族氮化物類的半導體(III-V nitride semiconductor)磊晶晶圓(epitaxial wafer)中,A面表示氮化鋁鎵(AlGaN;aluminium gallium nitride)層、中間層為氮化鎵(gallium nitride)層、B面為氮化鋁鎵層。15 to 19 disclose the first to fifth states in which the manufacturing equipment of the present invention "FIGS. 2 to 14" processes the thin film. 15 is a state in which the growth substrate 13 and the film 14 are loaded on the peeling device 10 of FIG. 2; the film 14 has an A surface and a B surface on the opposite side of the A surface corresponding to the surface of the growth substrate 13, for example For example, the A surface represents a P-type layer (P-type layer), and the B surface represents an N-type layer (N-type layer); for example, on the first compound semiconductor InP substrate "Growth Substrate", the 2 In the case of compound semiconductor InAsxP1-x "x = 0.05, 0.10, 0.15, 0.20, 0.25, 0.30", a complex composition gradient layer "complex thin film", the A side represents the first layer "Last Layer; x = 0.30; InAs0.30P0.70 ", the B-side represents the second layer" x = 0.05; InAs0.05P0.95 "; for example, on a sapphire growth substrate, gallium nitride , Indium Nitride (InN; Indium Nitride), and these mixed crystals, with the most appropriate structure, sequentially stacked and grown III-V nitride semiconductor (III-V nitride semiconductor) epitaxial wafer (epitaxial wafer), the A side represents the aluminum gallium nitride (AlGaN; aluminum gallium nitride) layer, medium Gallium nitride layer (gallium nitride) layer, B is an aluminum gallium nitride layer surface.

圖16係在剝離裝置10中,薄膜14維持在薄膜維持體16的狀態;A面和B面,相對於圖15是反轉過來的。圖17係在結合裝置20中,薄膜14被轉錄到轉錄材料23的狀態;A面和B面,相對於圖15是正轉過來的。圖18係在結合裝置20中,薄膜14被轉錄到第2轉錄材料123的狀態;A面和B面,相對於圖15是反轉過來的。圖19係薄膜14被轉錄到產品基板160的狀態;A面和B面,相對於圖15是正轉過來的。依照電子設備裡搭載的半導體設備要求的包含薄膜14的裝置設計(device)構造基準《例如圖19;第1裝置設計構造基準》,可以適當選擇A面和B面。又,可以實現圖16或圖18到圖19的裝置設計構造;當在第1裝置設計構造基準的相反的第2裝置設計構造基準之時,從圖17開始,與圖19的A面和B面相反的裝置設計構造就可以實現。FIG. 16 shows the state in which the film 14 is maintained in the film maintenance body 16 in the peeling device 10; the A surface and the B surface are reversed with respect to FIG. 15. FIG. 17 shows the state in which the film 14 is transcribed into the transcription material 23 in the bonding device 20; the A side and the B side are turned forward with respect to FIG. 15. FIG. 18 shows the state in which the film 14 is transcribed into the second transcription material 123 in the bonding device 20; the A side and the B side are reversed with respect to FIG. 15. FIG. 19 shows the state in which the thin film 14 is transcribed onto the product substrate 160; the A side and the B side are turned forward relative to FIG. 15. The plane A and the plane B can be appropriately selected in accordance with the device design structure standard (for example, FIG. 19; the first device design structure standard) including the thin film 14 required by the semiconductor device mounted in the electronic device. In addition, the device design structure of FIG. 16 or FIGS. 18 to 19 can be realized; when the second device design structure standard is opposite to the first device design structure standard, starting from FIG. 17, it is the same as A and B of FIG. 19. The opposite design and construction of the device can be achieved.

圖20係圖2和圖3揭示的剝離裝置10的變形實例。圖20揭示的剝離裝置10A,其基板維持體12和薄膜維持體16,相對於圖3,係天地倒轉;再進而,薄膜維持體16以孔25為介質,吸附第3轉錄材料124維持在該處;薄膜14被轉錄至第3轉錄材料124;換句話說,薄膜14以被吸附的第3轉錄材料124為介質,間接地維持在薄膜維持體16上。相對地,圖3的薄膜維持體16,直接地吸引多孔金屬墊100、和碳奈米墊101、以及薄膜14三者而維持在該處。 圖20揭示的剝離裝置10A,薄膜14從成長用基板13剝離、轉錄到第3轉錄材料124之時,係利用重力;第1艙室200控制為大氣壓時,該重力能更有效地作用。第3轉錄材料124也可以取代產品基板《藍寶石(sapphire);矽(silicone;Si)、氮化鎵(gallium nitride;GaN)、碳化矽(silicon carbide;SiC)或砷化鎵(gallium arsenide;GaAs)等》。對應圖20揭示的剝離裝置10A,圖1揭示的結合裝置20也是天地反轉;又,圖20揭示的剝離裝置10A,係說明非加熱時的狀態的圖示。FIG. 20 is a modified example of the peeling device 10 disclosed in FIGS. 2 and 3. In the peeling device 10A disclosed in FIG. 20, the substrate holder 12 and the film holder 16 are inverted relative to FIG. 3; furthermore, the film holder 16 uses the hole 25 as a medium, and the third transcription material 124 is adsorbed and maintained at this position. The film 14 is transcribed to the third transcription material 124; in other words, the film 14 uses the adsorbed third transcription material 124 as a medium, and is indirectly maintained on the film maintenance body 16. On the other hand, the thin film support body 16 of FIG. 3 directly attracts the porous metal pad 100, the carbon nano pad 101, and the thin film 14 to be maintained there. In the peeling device 10A disclosed in FIG. 20, when the film 14 is peeled from the growth substrate 13 and transcribed to the third transcription material 124, gravity is used; when the first compartment 200 is controlled to atmospheric pressure, the gravity can act more effectively. The third transcription material 124 can also replace the product substrate "sapphire"; silicon (Si), gallium nitride (GaN), silicon carbide (SiC) or gallium arsenide (GaAs) )Wait". Corresponding to the peeling device 10A disclosed in FIG. 20, the bonding device 20 disclosed in FIG. 1 is also reversed; and the peeling device 10A disclosed in FIG. 20 is a diagram illustrating a state when it is not heated.

圖20揭示的剝離裝置10A的基板維持體12,相對於圖3的基板維持體12具有加熱器90,係以第1金屬112和第2金屬113所構成、具有雙金屬(bimetal)。第1金屬112和第2金屬113對於溫度具有互相不同的膨脹係數(expansion coefficient);雙金屬也可以取代圖3的基板維持體12,其他則與前述相同。The substrate holding body 12 of the peeling device 10A disclosed in FIG. 20 has a heater 90 relative to the substrate holding body 12 of FIG. 3, is composed of a first metal 112 and a second metal 113, and has a bimetal. The first metal 112 and the second metal 113 have mutually different expansion coefficients with respect to temperature; the bimetal can also replace the substrate holder 12 of FIG. 3, and the other is the same as described above.

圖21係說明圖20的加熱時的剝離裝置10A的狀態。基板維持體12和成長用基板13,藉由第1金屬112和第2金屬113所構成的雙金屬,被加熱至200℃以下,慢慢地彎曲;其結果,成長用基板13的周圍邊緣開始開裂,產生縫隙Z2;縫隙Z2意味薄膜14從成長用基板13的剝離;其他則與前述相同。FIG. 21 illustrates the state of the peeling device 10A during heating in FIG. 20. The substrate holding body 12 and the growth substrate 13 are heated by a bimetal composed of the first metal 112 and the second metal 113 to below 200 ° C and slowly bend; as a result, the peripheral edge of the growth substrate 13 begins Cracking generates a gap Z2; the gap Z2 means the peeling of the thin film 14 from the growth substrate 13; the others are the same as described above.

圖22~圖25揭示本發明之製造設備《圖20和圖21》處理薄膜的第6~第9的狀態。圖22係成長用基板13和薄膜14被裝載(loading)於圖20的剝離裝置10A上的狀態,與圖15相同,薄膜14具有A面和B面。圖23係在剝離裝置10A,薄膜14被轉錄至第3轉錄材料124的狀態,A面和B面,相對於圖22,係反轉的。圖24係薄膜14和第3轉錄材料124從剝離裝置10A《製造設備1》卸載(unloading)的狀態。圖25係第3轉錄材料124的背面研磨後的狀態,第3轉錄材料124研磨後,其中的一部分變成產品基板160。電子設備裡搭載的半導體設備要求的包含薄膜14的裝置設計(device)構造基準,就可用於前述第2裝置設計構造基準《與圖19的A面和B面相反的裝置設計構造》之時。22 to 25 disclose the sixth to ninth states of the thin film processing apparatus of the present invention "FIG. 20 and FIG. 21" to process the thin film. FIG. 22 shows a state in which the growth substrate 13 and the film 14 are loaded on the peeling device 10A of FIG. 20. As in FIG. 15, the film 14 has an A surface and a B surface. FIG. 23 shows the state where the film 14 is transcribed to the third transcription material 124 in the peeling device 10A, and the A surface and the B surface are reversed with respect to FIG. 22. FIG. 24 shows a state where the film 14 and the third transcription material 124 are unloaded from the peeling device 10A "manufacturing equipment 1". FIG. 25 shows a state where the back surface of the third transcription material 124 is polished. After the third transcription material 124 is polished, a part of it becomes the product substrate 160. The device design structure criterion including the thin film 14 required by the semiconductor device mounted on the electronic device can be used when the second device design structure criterion "device design structure opposite to the planes A and B of FIG. 19".

圖26~圖28揭示本發明之製造設備《圖20的薄膜維持體16設置於上下反轉的結合裝置20的狀態》處理薄膜的第10~第12的狀態。圖26顯示從圖23的狀態移動到結合裝置20後的狀態;與圖23相同,薄膜14具有A面和B面。圖27係在結合裝置20中,薄膜14被轉錄至第4轉錄材料125的狀態,且薄膜14和第4轉錄材料125從結合裝置20《製造設備1》卸載下來的狀態;A面和B面,相對於圖26,係反轉的。圖28係第4轉錄材料125的背面研磨後的狀態,第4轉錄材料125研磨後,其中的一部分變成產品基板160。電子設備裡搭載的半導體設備要求的包含薄膜14的裝置設計(device)構造基準,就可用於前述第1裝置設計構造基準《圖19的A面和B面的裝置設計構造》之時。FIGS. 26 to 28 disclose the tenth to twelfth states of the processing apparatus of the present invention, “the state in which the film holding body 16 of FIG. 20 is provided in the bonding device 20 reversed upside down”. FIG. 26 shows the state after moving from the state of FIG. 23 to the bonding device 20; as in FIG. 23, the film 14 has an A surface and a B surface. FIG. 27 shows the state in which the film 14 is transcribed to the fourth transcription material 125 in the bonding device 20, and the film 14 and the fourth transcription material 125 are unloaded from the bonding device 20 "Manufacturing Equipment 1"; side A and side B , Relative to Fig. 26, is reversed. FIG. 28 shows a state where the back surface of the fourth transcription material 125 is polished. After the fourth transcription material 125 is polished, a part of it becomes the product substrate 160. The device design structure criterion including the thin film 14 required by the semiconductor device mounted in the electronic device can be used when the first device design structure criterion "device design structure of the A and B surfaces in FIG. 19" is mentioned above.

圖29~圖31揭示製造設備的控制方法及步驟(step)。圖29係製造設備的宏觀視角(macroscopic perspective )的控制方法;圖30係剝離裝置的宏觀視角的控制方法;圖31係結合裝置的宏觀視角的控制方法。29 to 31 disclose the control method and steps of the manufacturing equipment. Fig. 29 is a method of controlling the macroscopic perspective of the manufacturing equipment; Fig. 30 is a method of controlling the macroscopic perspective of the peeling device; and Fig. 31 is a method of controlling the macroscopic perspective of the device.

於圖29中,步驟S100係在剝離裝置中設置薄膜支持體;步驟S200係成長用基板的薄膜剝離的處置;步驟S300係在結合裝置中設置維持已剝離薄膜的薄膜支持體;步驟S400係薄膜轉錄至轉錄材料的結合處置。In FIG. 29, step S100 is to provide a film support in the peeling device; step S200 is to process the film peeling of the growth substrate; step S300 is to set the film support to maintain the peeled film in the bonding device; step S400 is the film Transcription to the combined disposal of transcribed material.

圖30的處置係對應步驟S200。於圖30中,步驟S210係成長用基板和薄膜裝載於剝離裝置,與圖20相關連,將第3轉錄材料124設置在薄膜維持體16處;步驟S220揭示第1~第3艙室的個別的氣體壓力的控制;步驟S221係施加第2和第3艙室的個別的氣體壓力,包括含真空的負壓力、大氣壓、和比大氣壓更大的正壓力;步驟S225係施加氣體壓力於第1艙室,包括負壓力、大氣壓、和比大氣壓更大的正壓力;步驟S230係施加氣體(gas)於第1艙室。再者,步驟S220和步驟S230的順序沒有差別;步驟S240係施加熱於基板維持體,使基板維持體變形。The treatment system of FIG. 30 corresponds to step S200. In FIG. 30, step S210 is that the growth substrate and the film are loaded on the peeling device, and related to FIG. 20, the third transcription material 124 is provided at the film holding body 16; step S220 reveals the individual compartments of the first to third compartments Control of gas pressure; step S221 applies individual gas pressures in the second and third compartments, including vacuum-containing negative pressure, atmospheric pressure, and positive pressure greater than atmospheric pressure; step S225 applies gas pressure to the first compartment, It includes negative pressure, atmospheric pressure, and positive pressure greater than atmospheric pressure; step S230 applies gas to the first compartment. Furthermore, there is no difference in the order of step S220 and step S230; step S240 applies heat to the substrate holder to deform the substrate holder.

圖31的處置係對應步驟S400。於圖31中,步驟S410係維持已剝離薄膜的薄膜支持體藉由薄膜支持體運送機制(carry mechanism)30,設置於結合裝置。步驟S420揭示在個別控制結合裝置形成的複數的艙室的氣體壓力和氣體壓力計、以及上下機制之時,薄膜轉錄至轉錄材料23的第1結合處置,該結合處置的進行,係控制上下機制,施加氣體壓力《真空、正氣體壓力》於第3艙室220內。步驟S430中,藉由第2薄膜支持體運送機制230,第2薄膜支持體115取代薄膜支持體15,設置於結合裝置20,藉此,第2轉錄維持體122被吸附在第2滑動器150處。步驟S440揭示在個別控制結合裝置形成的複數的艙室的氣體壓力和氣體壓力計、以及上下機制之時,轉錄至轉錄材料23的薄膜更進一步被轉錄至第2轉錄材料123的第2結合處置,該結合處置的進行,係控制上下機制,施加氣體壓力《正氣體壓力》於第6艙室320內。步驟S450和步驟S460,對應圖18和圖19,轉錄至第2轉錄材料123的薄膜,被轉錄至產品基板。再者,個別對應電子設備裡搭載的半導體設備要求的包含薄膜14的裝置設計(device)構造基準《第1和第2裝置設計構造基準》,就可以將前述之圖15~圖19、圖22~圖25、和圖26~圖28的變形在個別的步驟裡反映或併入。The treatment system of FIG. 31 corresponds to step S400. In FIG. 31, step S410 is that the film support that maintains the peeled film is provided to the bonding device by a film support transport mechanism (carry mechanism) 30. Step S420 reveals that when individually controlling the gas pressure and the gas pressure gauge of the plurality of chambers formed by the bonding device, and the up-down mechanism, the film is transcribed to the first bonding process of the transcription material 23, and this bonding process is performed by controlling the up-down mechanism, Apply the gas pressure "vacuum, positive gas pressure" in the third compartment 220. In step S430, the second film support 115 replaces the film support 15 by the second film support transport mechanism 230, and is installed in the coupling device 20, whereby the second transcription support 122 is attracted to the second slider 150 Office. Step S440 reveals that the film transcribed to the transcription material 23 is further transcribed to the second binding treatment of the second transcription material 123 when individually controlling the gas pressure and the gas pressure gauge of the plural chambers formed by the combining device, and the up-down mechanism. The process of the combined treatment is controlled by the up and down mechanism, and the gas pressure "positive gas pressure" is applied in the sixth compartment 320. Steps S450 and S460 correspond to FIGS. 18 and 19, and the film transcribed to the second transcription material 123 is transcribed to the product substrate. In addition, the device design structure standard (first and second device design structure standard) including the thin film 14 corresponding to the requirements of the semiconductor device mounted on the electronic device can be compared with the aforementioned FIGS. 15 to 19, 22 The variations of FIGS. 25 and 26 to 28 are reflected or incorporated in individual steps.

以上就本發明之實施型態加以說明,但本發明並非侷限於前述之實施型態,只要未脫離本發明主旨的範圍的其他各種型態,都可以實施。舉例來說,壓力裝置50,可以設置個別對應含有結合裝置20的複數個艙室的複數個的壓力裝置;又舉例來說,已揭示的負數構造的基板維持體、基板支持體、薄膜維持體、薄膜支持體、轉錄維持體、和轉錄支持體、等,雖然本說明書中未記明或未明示,但仍可以適當組合起來。本發明之技術範圍,並未侷限於前述複數個實施例或其組合,涵括專利申請範圍所記載事項及其同等物(equivalent)或變形物。The embodiments of the present invention have been described above, but the present invention is not limited to the aforementioned embodiments, and other various types can be implemented as long as they do not deviate from the scope of the present invention. For example, the pressure device 50 may be provided with a plurality of pressure devices corresponding to the plurality of compartments including the bonding device 20; and for example, the disclosed negative structure substrate support, substrate support, thin film support, The thin film support, the transcription maintenance body, the transcription support, and the like, although not specified or explicitly stated in this specification, may be combined as appropriate. The technical scope of the present invention is not limited to the foregoing plural embodiments or combinations thereof, and includes the items described in the scope of the patent application and their equivalents or variants.

1‧‧‧製造設備1‧‧‧ Manufacturing equipment

10、10A‧‧‧剝離裝置10. 10A‧‧‧ Stripping device

11‧‧‧基板支持體11‧‧‧Substrate support

12‧‧‧基板維持體12‧‧‧ substrate holder

13‧‧‧成長用基板13‧‧‧ Growth substrate

14‧‧‧薄膜(磊晶膜)14‧‧‧ Thin film (epitaxial film)

15、15A、15B、15C、15D‧‧‧薄膜支持體15, 15A, 15B, 15C, 15D ‧‧‧ film support

16‧‧‧薄膜維持體16‧‧‧Thin film support

17‧‧‧(彈性應變)變形部17‧‧‧ (elastic strain) deformation part

18、18A‧‧‧剪切部門18、18A‧‧‧Shearing department

19、19A‧‧‧(彈性應變)變形部的範圍19、19A‧‧‧ (elastic strain) deformation range

20‧‧‧結合裝置20‧‧‧Combination device

21‧‧‧轉錄支持體21‧‧‧ transcription support

22‧‧‧轉錄維持體22‧‧‧Transcription maintainer

23‧‧‧轉錄材料23‧‧‧ Transcribed material

24、25、151、153‧‧‧孔24, 25, 151, 153‧‧‧ hole

30‧‧‧薄膜支持體運送機制30‧‧‧ film support delivery mechanism

31‧‧‧薄膜支持體移動材料31‧‧‧moving material for thin film support

40‧‧‧機箱(chassis)40‧‧‧chassis

50‧‧‧壓力裝置50‧‧‧Pressure device

51‧‧‧第1壓力裝置51‧‧‧First pressure device

52‧‧‧第2壓力裝置52‧‧‧The second pressure device

60‧‧‧第1密封料60‧‧‧The first sealant

61‧‧‧第2密封料61‧‧‧Second sealant

62‧‧‧第3密封料62‧‧‧The third sealant

70、71、72‧‧‧連接器70, 71, 72 ‧‧‧ connectors

80‧‧‧聲頻發射測定器80‧‧‧Audio emission tester

81‧‧‧超音波探傷器81‧‧‧Ultrasonic flaw detector

90‧‧‧加熱器90‧‧‧heater

91‧‧‧紅外線局部加熱器91‧‧‧Infrared local heater

100‧‧‧多孔金屬墊100‧‧‧Porous metal pad

101‧‧‧碳奈米墊101‧‧‧Carbon Nano Mat

110‧‧‧彈簧110‧‧‧Spring

112‧‧‧第1金屬112‧‧‧First metal

113‧‧‧第2金屬113‧‧‧Second metal

115‧‧‧第2薄膜支持體115‧‧‧Second film support

116‧‧‧第2薄膜維持體116‧‧‧Second film maintenance body

120‧‧‧氣體壓力計120‧‧‧Gas pressure gauge

122‧‧‧第2轉錄維持體122‧‧‧ 2nd transcription maintainer

123‧‧‧第2轉錄材料123‧‧‧ 2nd transcription material

124‧‧‧第3轉錄材料124‧‧‧ Third transcription material

125‧‧‧第4轉錄材料125‧‧‧ 4th transcription material

130‧‧‧第1滑動器130‧‧‧1st slider

131‧‧‧軸承131‧‧‧bearing

140‧‧‧上下機制140‧‧‧Up and down mechanism

150‧‧‧第2滑動器150‧‧‧ 2nd slider

160‧‧‧產品基板160‧‧‧Product substrate

170‧‧‧照相機170‧‧‧Camera

200‧‧‧第1艙室200‧‧‧ First cabin

210‧‧‧第2艙室210‧‧‧ 2nd cabin

220‧‧‧第3艙室220‧‧‧ third cabin

230‧‧‧第2薄膜支持體運送機制230‧‧‧ 2nd film support delivery mechanism

231‧‧‧第2薄膜支持體移動材料231‧‧‧The second film support moving material

300‧‧‧第4艙室300‧‧‧ fourth cabin

310‧‧‧第5艙室310‧‧‧ fifth cabin

320‧‧‧第6艙室320‧‧‧ 6th cabin

Z1、Z2、Z3‧‧‧縫隙Z1, Z2, Z3 ‧‧‧ gap

【圖1】係實現本發明的製造設備的一個實施例《剖面圖》。 【圖2】係本發明的製造設備所包含的剝離裝置《第1例》。 【圖3】係圖2的一部分的非加熱時的放大圖。 【圖4】係圖3的熱供應(application of heat)時的放大圖。 【圖5】係圖2的薄膜支持體《第1例》的放大圖。 【圖6】係圖5的頂視圖(top view)《第1例》。 【圖7】係圖6的薄膜支持體的變形例。 【圖8】係圖2的薄膜支持體《第2例》的放大圖。 【圖9】係圖2的薄膜支持體《第3例》的放大圖。 【圖10】係圖2的薄膜支持體《第4例》的放大圖。 【圖11】係本發明的製造設備所包含的結合裝置(conjugation device)《第1例:第1狀態時》。 【圖12】係本發明的製造設備所包含的結合裝置(conjugation device)《第1例:第2狀態時》。 【圖13】係本發明的製造設備所包含的結合裝置(conjugation device)《第2例:第1狀態時》。 【圖14】係本發明的製造設備所包含的結合裝置(conjugation device)《第2例:第2狀態時》。 【圖15】係本發明的製造設備處理的薄膜《第1狀態時》。 【圖16】係本發明的製造設備處理的薄膜《第2狀態時》。 【圖17】係本發明的製造設備處理的薄膜《第3狀態時》。 【圖18】係本發明的製造設備處理的薄膜《第4狀態時》。 【圖19】係本發明的製造設備處理的薄膜《第5狀態時》。 【圖20】係本發明的製造設備所包含的剝離裝置《第2例》。 【圖21】係圖20的熱供應(application of heat)時的放大圖。 【圖22】係本發明的製造設備處理的薄膜《第6狀態時》。 【圖23】係本發明的製造設備處理的薄膜《第7狀態時》。 【圖24】係本發明的製造設備處理的薄膜《第8狀態時》。 【圖25】係本發明的製造設備處理的薄膜《第9狀態時》。 【圖26】係本發明的製造設備處理的薄膜《第10狀態時》。 【圖27】係本發明的製造設備處理的薄膜《第11狀態時》。 【圖28】係本發明的製造設備處理的薄膜《第12狀態時》。 【圖29】係本發明的製造設備的控制技術。 【圖30】係本發明的剝離裝置的控制技術。 【圖31】係本發明的結合裝置的控制技術。[Fig. 1] An embodiment of the manufacturing equipment for realizing the present invention, "Sectional View". [Fig. 2] This is the first example of the peeling device included in the manufacturing equipment of the present invention. [Fig. 3] An enlarged view of a part of Fig. 2 during non-heating. [Fig. 4] An enlarged view of the application of heat in Fig. 3. [Fig. 5] An enlarged view of the thin film support "first example" of Fig. 2. [Figure 6] The first view of the top view of FIG. 5 (top view). Fig. 7 is a modification of the film support of Fig. 6. [Fig. 8] An enlarged view of the thin film support "second example" of Fig. 2. [Fig. 9] An enlarged view of the thin film support "third example" of Fig. 2. [Fig. 10] An enlarged view of the "4th example" of the film support of Fig. 2. [Fig. 11] This is a conjugation device (first example: in the first state) included in the manufacturing equipment of the present invention. [Fig. 12] This is a conjugation device "first example: in the second state" included in the manufacturing equipment of the present invention. [Fig. 13] This is a conjugation device included in the manufacturing equipment of the present invention (the second example: in the first state). [Fig. 14] This is a conjugation device (second example: in the second state) included in the manufacturing equipment of the present invention. [Fig. 15] A film "at the first state" processed by the manufacturing equipment of the present invention. [Fig. 16] A film "at the second state" processed by the manufacturing equipment of the present invention. [FIG. 17] A film "at the third state" processed by the manufacturing equipment of the present invention. [Fig. 18] This is the film "at the fourth state" processed by the manufacturing equipment of the present invention. [FIG. 19] A film "at the fifth state" processed by the manufacturing equipment of the present invention. [Fig. 20] This is the second example of the peeling device included in the manufacturing equipment of the present invention. [Fig. 21] An enlarged view of the application of heat in Fig. 20. [FIG. 22] A film "at the sixth state" processed by the manufacturing equipment of the present invention. [FIG. 23] It is the film "at the 7th state" processed by the manufacturing equipment of this invention. [Fig. 24] The film "at the eighth state" processed by the manufacturing equipment of the present invention. [FIG. 25] It is the film "at the 9th state" processed by the manufacturing equipment of this invention. [Fig. 26] The film "at the tenth state" processed by the manufacturing equipment of the present invention. [FIG. 27] It is the film "at the 11th state" processed by the manufacturing equipment of this invention. [FIG. 28] It is the film "at the 12th state" processed by the manufacturing equipment of this invention. [FIG. 29] It is the control technique of the manufacturing equipment of this invention. Fig. 30 is a control technique of the peeling device of the present invention. [Fig. 31] It is the control technology of the coupling device of the present invention.

Claims (47)

一種電子器件的製造設備,其中裝備有:含有維持得到磊晶膜的薄膜的成長用基板的基板維持體、和支持前述基板維持體的基板支持體、和維持從成長用基板剝離的前述薄膜的薄膜維持體、和支持前述薄膜維持體的薄膜支持體、和由前述基板支持體與前述薄膜維持體構成的第1艙室、和由前述基板維持體與前述基板支持體構成的第2艙室、和由前述薄膜維持體與前述薄膜支持體構成的第3艙室的剝離裝置;以及施加個別對應前述第1、第2和第3艙室的第1、第2和第3氣體壓力的壓力裝置。An electronic device manufacturing facility comprising: a substrate holder including a growth substrate for maintaining a thin film obtained with an epitaxial film, a substrate support for supporting the substrate holder, and a substrate for maintaining the thin film peeled from the growth substrate A film holder, a film support that supports the film holder, a first compartment composed of the substrate support and the film holder, and a second compartment composed of the substrate support and the substrate support, and A peeling device for the third compartment constituted by the film maintenance body and the film support; and a pressure device for applying the first, second, and third gas pressures corresponding to the first, second, and third compartments, respectively. 如申請專利範圍第1項所述之製造設備,其中前述第1和第3氣體壓力的氣體壓力差施加於前述薄膜為其特徵者。The manufacturing equipment described in item 1 of the scope of the patent application, wherein the gas pressure difference between the first and third gas pressures is applied to the thin film as a feature. 如申請專利範圍第1項所述之製造設備,其中前述薄膜支持體具有因前述第1氣體壓力產生彈性應變的變形部門為其特徵者。The manufacturing equipment according to item 1 of the scope of the patent application, wherein the film support has a deformation section that generates elastic strain due to the first gas pressure as a feature. 如申請專利範圍第3項所述之製造設備,前述變形部門具有在前述薄膜支持體的厚方向有溝槽的剪切部門為其特徵者。As in the manufacturing equipment described in item 3 of the patent application scope, the deformation section is characterized by a shear section having grooves in the thickness direction of the film support. 如申請專利範圍第3項所述之製造設備,其中前述變形部門的厚度,比前述變形部門的外周緣的厚度較薄為其特徵者。The manufacturing equipment as described in item 3 of the scope of the patent application, wherein the thickness of the deformation section is thinner than the thickness of the outer periphery of the deformation section. 如申請專利範圍第3項所述之製造設備,其中前述薄膜維持體係安裝在前述變形部門為其特徵者。The manufacturing equipment described in item 3 of the scope of the patent application, in which the film maintenance system is installed in the deformation department as its characteristic. 如申請專利範圍第2項所述之製造設備,其中前述第1氣體壓力和前述第2氣體壓力的壓力差、及前述第1氣體壓力和前述第3氣體壓力的壓力差,將大氣壓當作1氣體壓力時,係1.3氣體壓力至3.0氣體壓力為其特徵者。The manufacturing equipment according to item 2 of the patent application scope, wherein the pressure difference between the first gas pressure and the second gas pressure, and the pressure difference between the first gas pressure and the third gas pressure, and the atmospheric pressure is regarded as 1 In the case of gas pressure, it is characterized by 1.3 gas pressure to 3.0 gas pressure. 如申請專利範圍第2項所述之製造設備,其中前述第2和第3氣體壓力係比大氣壓低的負壓力,前述第1氣體壓力係比大氣壓高的正壓力為其特徵者。The manufacturing equipment according to item 2 of the scope of the patent application, wherein the second and third gas pressures are negative pressures lower than atmospheric pressure, and the first gas pressure is positive pressures higher than atmospheric pressure. 如申請專利範圍第2項所述之製造設備,其中前述第1艙室,被供給乾燥空氣氣體或氮氣氣體為其特徵者。The manufacturing equipment as described in item 2 of the scope of patent application, wherein the first compartment is characterized by being supplied with dry air gas or nitrogen gas. 如申請專利範圍第2項所述之製造設備,其中前述第1艙室,被供給至少比前述成長用基板或前述薄膜的波耳半徑還小的波耳半徑的原子或分子的氣體為其特徵者。The manufacturing equipment according to item 2 of the patent application scope, wherein the first chamber is supplied with gas having atoms or molecules having a Bohr radius at least smaller than the Bohr radius of the growth substrate or the film . 如申請專利範圍第2項所述之製造設備,其中前述第1艙室,被供給至少氫氣氣體、或氦氣氣體為其特徵者。The manufacturing equipment according to item 2 of the scope of the patent application, wherein the first compartment is characterized by being supplied with at least hydrogen gas or helium gas. 如申請專利範圍第9項至第11項之任一項所述之製造設備,其中前述半導體設備或前述第1艙室,更進一步裝備支撐物(support)為其特徵者。The manufacturing equipment according to any one of the items 9 to 11 of the patent application range, wherein the semiconductor device or the first compartment is further equipped with a support as a feature. 如申請專利範圍第2項至第9項之任一項所述之製造設備,其中前述基板維持體,更進一步包含加熱部門為其特徵者。The manufacturing equipment according to any one of claims 2 to 9 of the patent application, wherein the substrate maintenance body further includes a heating department as a feature. 如申請專利範圍第13項所述之製造設備,其中前述加熱部門係雙金屬為其特徵者。The manufacturing equipment as described in item 13 of the scope of patent application, wherein the heating department is characterized by bimetal. 如申請專利範圍第1項所述之製造設備,其中前述剝離裝置,更進一步,在前述薄膜支持體和前述基板支持體之間,包含維持前述第1氣體壓力的第1密封材料。The manufacturing facility according to item 1 of the patent application scope, wherein the peeling device further includes a first sealing material that maintains the first gas pressure between the film support and the substrate support. 如申請專利範圍第15項所述之製造設備,其中前述薄膜支持體,藉由前述第1密封材料,與前述基板支持體可以附著和分離(attaching and detaching)為其特徵者。The manufacturing equipment as described in item 15 of the patent application range, wherein the film support is characterized by attaching and detaching from the substrate support by the first sealing material. 如申請專利範圍第1項至第11項、第15項和第16項之任一項所述之製造設備,其中前述剝離裝置,更進一步,在前述薄膜支持體和前述薄膜維持體之間,包含維持前述第3氣體壓力的第2密封材料。The manufacturing equipment as described in any one of the first to eleventh, fifteenth and sixteenth items of the patent application scope, wherein the peeling device is further between the film support and the film support, Including the second sealing material that maintains the third gas pressure. 如申請專利範圍第17項所述之製造設備,其中前述薄膜維持體,藉由前述第2密封材料,與前述薄膜支持體可以附著和分離為其特徵者。The manufacturing equipment according to item 17 of the scope of the patent application, wherein the film holding body is characterized by being able to be attached and detached from the film support by the second sealing material. 如申請專利範圍第1項至第11項、第15項和第16項之任一項所述之製造設備,其中前述剝離裝置,更進一步,在前述基板支持體和前述基板維持體之間,包含維持前述第2氣體壓力的第3密封材料。The manufacturing equipment according to any one of the first to eleventh, fifteenth and sixteenth items of the patent application scope, wherein the peeling device is further between the substrate support and the substrate holder, It includes a third sealing material that maintains the second gas pressure. 如申請專利範圍第19項所述之製造設備,其中前述基板維持體,藉由前述第3密封材料,與前述基板支持體可以附著和分離為其特徵者。The manufacturing equipment as described in item 19 of the patent application range, wherein the substrate holding body is attached to and detachable from the substrate support by the third sealing material, and is characterized as such. 如申請專利範圍第1項至第11項、第15項和第16項之任一項所述之製造設備,其中前述薄膜維持體,具有貫通前述薄膜範圍關聯的每特定單位面積的前述薄膜維持體的複數的第1孔,更進一步,前述薄膜和前述薄膜維持體之間,包含具有比前述複數的第1孔數目更多的每特定單位面積的複數的第2貫通孔的多孔金屬墊為其特徵者。The manufacturing equipment according to any one of the first to eleventh, fifteenth and fifteenth items of the patent application range, wherein the thin film maintenance body has the thin film maintenance per specific unit area associated with the thin film range The plurality of first holes of the body, and further, the porous metal pad having a plurality of second through holes per specific unit area between the thin film and the thin film maintenance body is larger than the number of the first holes of the complex is Its characteristics. 如申請專利範圍第21項所述之製造設備,其中前述薄膜維持體,更進一步,前述薄膜和前述多孔金屬墊之間,包含具有比前述複數的第2孔數目更多的每特定單位面積的複數的第3貫通孔的碳奈米墊為其特徵者。The manufacturing equipment as described in item 21 of the scope of the patent application, wherein the film maintenance body, and further, between the film and the porous metal pad, a more specific unit area per unit area than that of the plurality of second holes Carbon nanomats with multiple third through-holes are characteristic. 如申請專利範圍第1項至第11項之任一項所述之製造設備,其中前述基板維持體,以重力方向為基準,係配置在前述薄膜維持體的上側為其特徵者。The manufacturing equipment according to any one of claims 1 to 11, wherein the substrate holder is characterized by being placed on the upper side of the film holder based on the direction of gravity. 如申請專利範圍第1項至第11項之任一項所述之製造設備,其中前述薄膜維持體,以第3轉錄材料為介質,維持前述薄膜為其特徵者。The manufacturing equipment according to any one of claims 1 to 11 of the patent application range, wherein the film maintenance body uses the third transcription material as a medium and maintains the film as its characteristic. 如申請專利範圍第24項所述之製造設備,其中前述第3轉錄材料係產品基板為其特徵者。The manufacturing equipment as described in item 24 of the patent application, wherein the third transcription material is a product substrate whose characteristics are. 如申請專利範圍第1項所述之製造設備,其中前述製造設備更進一步包含結合裝置,前述結合裝置,與前述薄膜支持體可以附著和分離,包含支持轉錄材料的轉錄支持體,而維持在前述薄膜維持體的前述薄膜轉錄至轉錄材料為其特徵者。The manufacturing equipment as described in item 1 of the scope of the patent application, wherein the manufacturing equipment further includes a binding device that can be attached to and detached from the film support, and includes a transcription support that supports transcription materials, while maintaining the above It is characteristic that the aforementioned thin film of the thin film support body is transcribed to a transcription material. 如申請專利範圍第26項所述之製造設備,其中前述薄膜支持體和前述轉錄支持體的至少一者,係活動式可以變更相互間的距離為其特徵者。The manufacturing equipment as described in item 26 of the patent application scope, wherein at least one of the thin film support and the transcription support is a movable type whose characteristics can be changed by changing the distance between them. 如申請專利範圍第27項所述之製造設備,其中前述結合裝置,更進一步,在前述薄膜支持體和前述轉錄支持體之間,包含第1滑動器或軸承為其特徵者。The manufacturing equipment according to item 27 of the patent application scope, wherein the coupling device further includes a first slider or a bearing as a feature between the film support and the transcription support. 如申請專利範圍第27項所述之製造設備,其中前述薄膜支持體和前述轉錄支持體的另一者,係活動式可以變更相互間的距離為其特徵者。The manufacturing equipment as described in item 27 of the patent application scope, wherein the other of the film support and the transcription support is a movable type that can change the distance between each other as its characteristic. 如申請專利範圍第29項所述之製造設備,其中前述結合裝置,更進一步,包含使前述轉錄支持體活動的上下機制為其特徵者。The manufacturing equipment as described in item 29 of the scope of the patent application, wherein the above-mentioned coupling device further includes a feature that enables the up-down mechanism of the transcription support to move. 如申請專利範圍第26項至第30項之任一項所述之製造設備,其中施加於前述第3艙室的第3氣體壓力,係比大氣壓高的正氣體壓力為其特徵者。The manufacturing equipment as described in any one of patent application items 26 to 30, wherein the third gas pressure applied to the third compartment is characterized by a positive gas pressure higher than atmospheric pressure. 如申請專利範圍第26項至第30項之任一項所述之製造設備,其中前述結合裝置,包含:前述薄膜支持體和前述轉錄支持體所形成的第4艙室、和前述轉錄材料和前述轉錄支持體所形成的第5艙室、和測定前述第5艙室的氣體壓力的氣體壓力計為其特徵者。The manufacturing equipment according to any one of items 26 to 30 of the patent application range, wherein the combining device includes: a fourth compartment formed by the thin film support and the transcription support, and the transcription material and the foregoing The fifth compartment formed by the transcription support and the gas pressure gauge for measuring the gas pressure of the fifth compartment are characterized. 如申請專利範圍第26項至第30項之任一項所述之製造設備,其中前述轉錄材料係產品基板為其特徵者。The manufacturing equipment as described in any one of patent application items 26 to 30, wherein the transcription material is a product substrate whose characteristics are. 如申請專利範圍第26項所述之製造設備,其中前述結合裝置,與前述轉錄支持體可以附著和分離,包含支持第2轉錄材料的第2薄膜支持體,維持在前述轉錄材料之前述薄膜能更進一步轉錄至第2轉錄材料為其特徵者。The manufacturing equipment according to item 26 of the patent application scope, wherein the coupling device can be attached to and detached from the transcription support, includes a second film support that supports the second transcription material, and is maintained at the energy of the film of the transcription material Transcribed further to the second transcription material is its characteristic. 如申請專利範圍第34項所述之製造設備,其中前述第2薄膜支持體和前述轉錄支持體的至少一者,係活動式能變更相互間距離為其特徵者。The manufacturing equipment described in item 34 of the patent application scope, wherein at least one of the second film support and the transcription support is a movable type capable of changing the distance between them as a characteristic. 如申請專利範圍第35項所述之製造設備,其中前述結合裝置更進一步,在前述第2薄膜支持體和前述轉錄支持體之間,包含第2滑動器或軸承為其特徵者。The manufacturing equipment according to item 35 of the patent application scope, wherein the coupling device is further characterized by including a second slider or bearing as a feature between the second film support and the transcription support. 如申請專利範圍第35項所述之製造設備,其中前述第2薄膜支持體和前述轉錄支持體的另一者,係活動式能變更相互間距離為其特徵者。The manufacturing equipment as described in item 35 of the patent application scope, wherein the other of the second film support and the transcription support is a movable type that can change the distance between them as its characteristics. 如申請專利範圍第37項所述之製造設備,其中前述結合裝置更進一步,包含使前述轉錄支持體活動的上下機制為其特徵者。The manufacturing equipment as described in item 37 of the patent application scope, wherein the combining device further includes a feature that makes the up and down mechanism of the transcription support activity. 如申請專利範圍第34項所述之製造設備,其中前述結合裝置包含前述第2薄膜支持體和前述第2轉錄材料所形成的第6艙室為其特徵者。The manufacturing equipment as described in item 34 of the patent application range, wherein the bonding device includes the sixth compartment formed by the second film support and the second transcription material as a feature. 如申請專利範圍第39項所述之製造設備,其中前述壓力裝置,更進一步,施加比大氣壓高的正氣體壓力之第4氣體壓力於第6艙室為其特徵者。The manufacturing equipment as described in item 39 of the patent application range, wherein the pressure device is further characterized by a fourth gas pressure that applies a positive gas pressure higher than atmospheric pressure in the sixth chamber. 如申請專利範圍第39項所述之製造設備,其中前述結合裝置,更進一步,包含:在前述第2薄膜支持體和前述第2轉錄材料之間、且配置在前述第6艙室的第2薄膜維持體為其特徵者。The manufacturing equipment according to item 39 of the patent application scope, wherein the coupling device further includes: a second film disposed between the second film support and the second transcription material and disposed in the sixth compartment Maintain the body as its characteristic. 如申請專利範圍第35項所述之製造設備,其中前述結合裝置,更進一步,包含:維持前述第2轉錄材料、配置在前述第2薄膜支持體和前述第2轉錄材料之間的第2薄膜維持體為其特徵者。The manufacturing equipment according to item 35 of the patent application scope, wherein the bonding device further includes: maintaining the second transcription material, and a second film disposed between the second film support and the second transcription material Maintain the body as its characteristic. 如申請專利範圍第42項所述之製造設備,其中前述結合裝置,更進一步,包含:配置在前述第2薄膜支持體和前述第2薄膜維持體之間的第2滑動器為其特徵者。The manufacturing equipment according to item 42 of the patent application range, wherein the coupling device further includes: a second slider disposed between the second film support and the second film holder is a feature. 如申請專利範圍第43項所述之製造設備,其中前述第2滑動器,具有藉由前述壓力裝置供應的氣體壓力維持第2薄膜維持體的貫通孔為其特徵者。The manufacturing facility according to item 43 of the patent application range, wherein the second slider has a through hole for maintaining the second film maintaining body by the gas pressure supplied by the pressure device. 如申請專利範圍第34項至第44項之任一項所述之製造設備,其中前述第2轉錄材料係產品基板為其特徵者。The manufacturing equipment as described in any one of patent application items 34 to 44, wherein the second transcription material is a product substrate whose characteristics are. 如申請專利範圍第26項所述之製造設備,其中前述製造設備更進一步包含薄膜支持體運送機制,前述薄膜支持體運送機制,包含在前述剝離裝置和前述結合裝置之間,運送前述薄膜支持體的薄膜支持體移動材料為其特徵者。The manufacturing equipment according to item 26 of the patent application scope, wherein the manufacturing equipment further includes a film support transport mechanism, and the film support transport mechanism includes transporting the film support between the peeling device and the bonding device The moving material of the thin film support is its characteristic. 如申請專利範圍第34項所述之製造設備,其中前述製造設備更進一步包含第2薄膜支持體運送機制,前述第2薄膜支持體運送機制,包含在前述剝離裝置和其他裝置之間,運送前述第2薄膜支持體的第2薄膜支持體移動材料為其特徵者。The manufacturing equipment according to item 34 of the patent application scope, wherein the manufacturing equipment further includes a second film support transport mechanism, and the second film support transport mechanism is included between the peeling device and other devices to transport the foregoing The second thin film support moving material of the second thin film support is its characteristic.
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