TWI649458B - Plating apparatus - Google Patents

Plating apparatus Download PDF

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TWI649458B
TWI649458B TW106140621A TW106140621A TWI649458B TW I649458 B TWI649458 B TW I649458B TW 106140621 A TW106140621 A TW 106140621A TW 106140621 A TW106140621 A TW 106140621A TW I649458 B TWI649458 B TW I649458B
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anode
electroplating apparatus
plate
carrier
dimensional
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TW106140621A
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TW201925544A (en
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呂春福
周雅靜
顏銘翬
謝宏元
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財團法人工業技術研究院
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Abstract

電鍍設備包括電解槽及立體式陽極組。立體式陽極組配置在電解槽內且包括第一陽極及第二陽極。第一陽極沿第一方向延伸。第二陽極沿第一方向延伸,其中第一陽極與第二陽極沿第二方向排列且彼此間隔,其中第一方向與第二方向實質上垂直。The electroplating apparatus includes an electrolysis cell and a stereo anode group. The three-dimensional anode group is disposed in the electrolytic cell and includes a first anode and a second anode. The first anode extends in the first direction. The second anode extends in the first direction, wherein the first anode and the second anode are aligned in the second direction and spaced apart from each other, wherein the first direction is substantially perpendicular to the second direction.

Description

電鍍設備Plating equipment

本發明是有關於一種電鍍設備,且特別是有關於一種具有立體式陽極組的電鍍設備。This invention relates to an electroplating apparatus, and more particularly to an electroplating apparatus having a three-dimensional anode set.

傳統電鍍因為邊緣化現象,被鍍物邊緣(特別是轉角處)的膜厚比其它部位(如中間部位)的膜厚還厚,如此導致鍍膜厚度不均。因此,提出一種可獲得均勻電鍍膜厚的技術是本領域業者努力目標之一。Conventional electroplating is thicker than the film thickness of other parts (such as the middle part) due to the edge phenomenon, which results in uneven coating thickness. Therefore, it has been proposed that a technique for obtaining a uniform plating film thickness is one of the efforts of those skilled in the art.

因此,本發明提出一種電鍍設備,可改善前述習知問題。Accordingly, the present invention provides an electroplating apparatus that can ameliorate the aforementioned conventional problems.

根據本發明之一實施例,提出一種電鍍設備。電鍍設備包括一電解槽及一立體式陽極組。立體式陽極組配置在電解槽內且包括一第一陽極及一第二陽極。第一陽極沿一第一方向延伸。第二陽極沿第一方向延伸,其中第一陽極與第二陽極沿一第二方向排列且彼此間隔,其中第一方向與第二方向實質上垂直。According to an embodiment of the invention, an electroplating apparatus is proposed. The electroplating apparatus includes an electrolysis cell and a stereo anode group. The three-dimensional anode group is disposed in the electrolytic tank and includes a first anode and a second anode. The first anode extends in a first direction. The second anode extends in the first direction, wherein the first anode and the second anode are aligned in a second direction and spaced apart from each other, wherein the first direction is substantially perpendicular to the second direction.

為了對本發明之上述及其他方面有更佳的瞭解,下文特舉實施例,並配合所附圖式詳細說明如下:In order to better understand the above and other aspects of the present invention, the following detailed description of the embodiments and the accompanying drawings

請參照第1A~1C圖,第1A圖繪示依照本發明一實施例之電鍍設備100的示意圖,第1B圖繪示往視角V1觀看到的第1A圖之立體式陽極組120的視圖,而第1C圖繪示往視角V1觀看到的第1A圖之第一陽極121的結構示意圖。Please refer to FIGS. 1A-1C. FIG. 1A is a schematic view of a plating apparatus 100 according to an embodiment of the present invention, and FIG. 1B is a view of a three-dimensional anode group 120 of FIG. 1A viewed from a viewing angle V1. FIG. 1C is a schematic view showing the structure of the first anode 121 of FIG. 1A viewed from the viewing angle V1.

電鍍設備100包括電解槽105、電源供應器106、過濾器110、幫浦115、立體式陽極組120、立體式載板130、支撐架140、搖槳150、驅動機構155、驅動器160及均流板170。The electroplating apparatus 100 includes an electrolysis tank 105, a power supply 106, a filter 110, a pump 115, a stereo anode group 120, a three-dimensional carrier 130, a support frame 140, a rocker 150, a drive mechanism 155, a driver 160, and a current sharing Plate 170.

電解槽105用以容置立體式陽極組120、立體式載板130、支撐架140、搖槳150及均流板170。立體式載板130、立體式陽極組120與被鍍物W1(所在處為被鍍物放置區)沿第二方向X依序排列,其中第二方向X例如是電鍍方向或電場方向。被鍍物W1例如是導體,如金屬板。電源供應器106的負極電性連接於被鍍物W1,電源供應器106的電極電性連接於立體式陽極組120,以提供電流訊號給立體式陽極組120,且使立體式陽極組120與被鍍物W1之間產生電場,讓立體式陽極組120的材料電鍍在被鍍物W1上。The electrolytic cell 105 is used for accommodating the three-dimensional anode group 120, the three-dimensional carrier 130, the support frame 140, the rocker 150 and the flow equalization plate 170. The three-dimensional carrier plate 130, the three-dimensional anode group 120 and the object to be plated W1 (where the object placement area is placed) are sequentially arranged in the second direction X, wherein the second direction X is, for example, a plating direction or an electric field direction. The object to be plated W1 is, for example, a conductor such as a metal plate. The negative electrode of the power supply 106 is electrically connected to the object to be plated W1, and the electrode of the power supply 106 is electrically connected to the stereo anode group 120 to provide a current signal to the stereo anode group 120, and the stereo anode group 120 is An electric field is generated between the objects to be plated W1, and the material of the three-dimensional anode group 120 is plated on the object to be plated W1.

電解槽105內有電鍍液L1。電解槽105包括底板1051,底板1051具有開口1051a。電鍍液L1在幫浦115的驅動下從電解槽105的開口1051a進入電解槽105並通過均流板170及立體式陽極組120與被鍍物W1之間的空間,然後經由電解槽105的上部回流至幫浦115。電鍍液L1在進入電解槽105前會先流經過濾器110的過濾,可移除電鍍液L1的雜質及/或顆粒(若有的話)。The electrolytic bath 105 has a plating solution L1 therein. The electrolytic cell 105 includes a bottom plate 1051 having an opening 1051a. The plating solution L1 enters the electrolytic cell 105 from the opening 1051a of the electrolytic cell 105 by the pump 115 and passes through the space between the flow equalizing plate 170 and the three-dimensional anode group 120 and the object to be plated W1, and then passes through the upper portion of the electrolytic cell 105. Return to the pump 115. The plating solution L1 will first pass through the filter of the filter 110 before entering the electrolytic cell 105, and the impurities and/or particles (if any) of the plating solution L1 can be removed.

立體式陽極組120包括第一陽極121、第二陽極122及第三陽極123。在另一實施例中,立體式陽極組120的陽極數量可超過三個或少於二個。第一陽極121、第二陽極122及第三陽極123沿第一方向Y延伸。第一陽極121、第二陽極122與第三陽極123沿第二方向X排列且彼此間隔,其中第一方向Y與第二方向X實質上垂直。由於此些陽極與被鍍物W1的距離不同,因此被鍍物W1的各局部與此些陽極的距離而定,被鍍物W1的各局部的鍍膜厚度會有不同。換言之,藉由此些陽極與被鍍物W1的距離設計,可獲得被鍍物W1之特定區域的所欲鍍膜厚度,或讓形成在被鍍物W1上的整層鍍膜的膜厚均勻。The three-dimensional anode group 120 includes a first anode 121, a second anode 122, and a third anode 123. In another embodiment, the number of anodes of the three-dimensional anode assembly 120 can exceed three or less than two. The first anode 121, the second anode 122, and the third anode 123 extend in the first direction Y. The first anode 121, the second anode 122, and the third anode 123 are arranged in the second direction X and spaced apart from each other, wherein the first direction Y is substantially perpendicular to the second direction X. Since the distance between the anode and the object to be plated W1 is different, the thickness of each part of the object to be plated W1 differs from the distance of the anodes, and the thickness of each part of the object to be plated W1 differs. In other words, by designing the distance between the anode and the object to be plated W1, the desired coating thickness of the specific region of the object to be plated W1 can be obtained, or the film thickness of the entire layer of the plating film formed on the object to be plated W1 can be made uniform.

如第1A圖所示,第一陽極121、第二陽極122及第三陽極123可透過數條導線電性連接於電源供應器106。電源供應器106可提供不同或相同電流給第一陽極121、第二陽極122及第三陽極123。例如,電鍍設備100更包括第一可變電阻1061、第二可變電阻1062及第三可變電阻1063,其中第一可變電阻1061耦接第一陽極121與電源供應器106,第二可變電阻1062耦接第二陽極122與電源供應器106,而第三可變電阻1063耦接第三陽極123與電源供應器106。電源供應器106或另一控制器可控制第一可變電阻1061、第二可變電阻1062及第三可變電阻1063的電阻值,以提供不同或相同電流給第一陽極121、第二陽極122及第三陽極123。As shown in FIG. 1A, the first anode 121, the second anode 122, and the third anode 123 are electrically connected to the power supply 106 through a plurality of wires. The power supply 106 can provide different or the same current to the first anode 121, the second anode 122, and the third anode 123. For example, the electroplating apparatus 100 further includes a first variable resistor 1061, a second variable resistor 1062, and a third variable resistor 1063, wherein the first variable resistor 1061 is coupled to the first anode 121 and the power supply 106, and the second The variable resistor 1062 is coupled to the second anode 122 and the power supply 106, and the third variable resistor 1063 is coupled to the third anode 123 and the power supply 106. The power supply 106 or another controller may control the resistance values of the first variable resistor 1061, the second variable resistor 1062, and the third variable resistor 1063 to provide different or the same current to the first anode 121 and the second anode. 122 and a third anode 123.

如第1A圖所示,在本實施例的此些陽極中,第一陽極121相距被鍍物W1的距離最近。第一陽極121的位置大致對應被鍍物W1的中間區域R1。如此,相較於習知被鍍物的鍍膜厚度,本實施例的被鍍物W1的中間區域R1的形成膜厚較厚。在此些陽極中,第三陽極123相距被鍍物W1的距離最遠。第三陽極123的位置大致對應被鍍物W1的邊緣區域R3,因此相較於習知被鍍物的鍍膜厚度,本實施例的被鍍物W1的邊緣區域R3的形成膜厚較薄。如此,相較於習知被鍍物的鍍膜厚度,本發明實施例之被鍍物W1的中間區域R1與邊緣區域R3的形成膜厚的差異縮小。As shown in Fig. 1A, in the anodes of the present embodiment, the first anode 121 is closest to the object to be plated W1. The position of the first anode 121 substantially corresponds to the intermediate portion R1 of the object to be plated W1. Thus, the intermediate portion R1 of the object to be plated W1 of the present embodiment has a thick film thickness as compared with the thickness of the plating material of the conventional object to be plated. Among the anodes, the third anode 123 is farthest from the object to be plated W1. The position of the third anode 123 substantially corresponds to the edge region R3 of the object to be plated W1. Therefore, the film thickness of the edge region R3 of the object to be plated W1 of the present embodiment is thinner than that of the conventional plated article. Thus, the difference in film thickness between the intermediate portion R1 and the edge region R3 of the object to be plated W1 of the embodiment of the present invention is reduced as compared with the thickness of the coating of the conventional object to be plated.

如第1C圖所示,第一陽極121包括網目結構1211及數個可溶性陽極顆粒1212,此些可溶性陽極顆粒1212填充於網目結構1211的數個網目1211a內。此些可溶性陽極顆粒1212的正離子在電鍍過程中會與電鍍液L1的電子結合成化合物,然後析出在被鍍物W1的表面上,而形成鍍膜。因此,在電鍍過程中,可溶性陽極顆粒1212會逐漸消耗。在一實施例中,可溶性陽極顆粒1212可以是銅、鎳或其它被鍍物W1所需的金屬。網目結構1211例如是鈦金屬製成,其不會消耗。此外,第二陽極122及第三陽極123具有類似第一陽極121的結構,於此不再贅述。此外,一個網目1211a內可填入一個或數個可溶性陽極顆粒1212,而可溶性陽極顆粒1212的形狀不受圖式所限,其可以是圓形、橢圓形、圓餅形或不規則形狀。As shown in FIG. 1C, the first anode 121 includes a mesh structure 1211 and a plurality of soluble anode particles 1212, and the soluble anode particles 1212 are filled in a plurality of meshes 1211a of the mesh structure 1211. The positive ions of the soluble anode particles 1212 are combined with the electrons of the plating solution L1 to form a compound in the electroplating process, and then precipitated on the surface of the object to be plated W1 to form a plating film. Therefore, the soluble anode particles 1212 are gradually consumed during the electroplating process. In one embodiment, the soluble anode particles 1212 can be copper, nickel, or other metals required for the substrate W1. The mesh structure 1211 is, for example, made of titanium metal, which is not consumed. In addition, the second anode 122 and the third anode 123 have a structure similar to that of the first anode 121, and details are not described herein again. In addition, one mesh 1211a may be filled with one or several soluble anode particles 1212, and the shape of the soluble anode particles 1212 is not limited by the drawings, and may be circular, elliptical, pie-shaped or irregular.

此外,第一陽極121、第二陽極122及第三陽極123的網目結構的網目內徑可不同,使第一陽極121、第二陽極122及第三陽極123具有不同的表面粗糙度,以控制電鍍液L1流經第一陽極121、第二陽極122及第三陽極123的流速,進而控制形成在被鍍物W1上的鍍膜厚度。例如,第一陽極121的網目結構的網目內徑小於第二陽極122的網目結構的網目內徑,使第二陽極122的粗糙度大於第一陽極121的粗糙度,如此電鍍液L1流經第二陽極122的流速小於流經第一陽極121的流速,對應地被鍍物W1的鍍膜厚度也會不同。In addition, the mesh diameters of the mesh structures of the first anode 121, the second anode 122, and the third anode 123 may be different, so that the first anode 121, the second anode 122, and the third anode 123 have different surface roughnesses to control The plating solution L1 flows through the flow rates of the first anode 121, the second anode 122, and the third anode 123, thereby controlling the thickness of the plating film formed on the object to be plated W1. For example, the mesh inner diameter of the mesh structure of the first anode 121 is smaller than the mesh inner diameter of the mesh structure of the second anode 122, so that the roughness of the second anode 122 is greater than the roughness of the first anode 121, so that the plating solution L1 flows through the first The flow rate of the two anodes 122 is smaller than the flow rate of the first anode 121, and the thickness of the coating of the object to be plated W1 is also different.

如第1A及1B圖所示,第一陽極121、第二陽極122與第三陽極123沿第二方向X的投影係不互相重疊。如此,可避免此些陽極的正離子往被鍍物W1的移動路徑過度彼此干擾。在另一實施例中,第一陽極121、第二陽極122與第三陽極123沿第二方向X的投影可部分重疊。As shown in FIGS. 1A and 1B, the projections of the first anode 121, the second anode 122, and the third anode 123 in the second direction X do not overlap each other. In this way, it is possible to prevent the positive ions of the anodes from excessively interfering with each other toward the moving path of the object to be plated W1. In another embodiment, the projections of the first anode 121, the second anode 122, and the third anode 123 in the second direction X may partially overlap.

此外,如第1A及1B圖所示,第一陽極121、第二陽極122與第三陽極123之一者為環形陽極。例如,第二陽極122及第三陽極123為環形電極,而第一陽極121為一從外側面往內連續延伸而無貫孔的電極。詳言之,如第1B圖所示,從視角V1觀看到的第一陽極121並無任何貫穿部,而第二陽極122環繞出第一貫穿部122a,以允許第一陽極121從第一貫穿部122a露出,而第三陽極123環繞出第二貫穿部123a,以允許第一陽極121及第二陽極122從第二貫穿部123a露出。Further, as shown in FIGS. 1A and 1B, one of the first anode 121, the second anode 122, and the third anode 123 is a ring-shaped anode. For example, the second anode 122 and the third anode 123 are ring electrodes, and the first anode 121 is an electrode extending continuously from the outer side surface without a through hole. In detail, as shown in FIG. 1B, the first anode 121 viewed from the viewing angle V1 does not have any penetration portion, and the second anode 122 surrounds the first penetration portion 122a to allow the first anode 121 to pass through from the first. The portion 122a is exposed, and the third anode 123 surrounds the second through portion 123a to allow the first anode 121 and the second anode 122 to be exposed from the second through portion 123a.

如第1A圖所示,立體式載板130配置在支撐架140且上用以承載立體式陽極組120。立體式載板130包括第一載件131、第二載件132及第三載件133。第一載件131承載第一陽極121且沿第二方向X可平移地連接於支撐架140。第二載件132承載第二陽極122且沿第二方向X可平移地連接於支撐架140。第三載件133承載第三陽極123且沿第二方向X可平移地連接於支撐架140。由於第一載件131、第二載件132及第三載件133可平移地連接於支撐架140,因此能調整第一陽極121、第二陽極122及第三陽極123各自相對被鍍物W1的距離。As shown in FIG. 1A, the three-dimensional carrier 130 is disposed on the support frame 140 and is configured to carry the three-dimensional anode assembly 120. The three-dimensional carrier 130 includes a first carrier 131, a second carrier 132, and a third carrier 133. The first carrier 131 carries the first anode 121 and is translationally coupled to the support frame 140 in a second direction X. The second carrier 132 carries the second anode 122 and is translationally coupled to the support frame 140 in a second direction X. The third carrier 133 carries a third anode 123 and is translationally coupled to the support frame 140 in a second direction X. Since the first carrier 131, the second carrier 132, and the third carrier 133 are translationally coupled to the support frame 140, the first anode 121, the second anode 122, and the third anode 123 can be adjusted relative to the object to be plated W1. the distance.

請參照第2A及2B圖,第2A圖繪示往視角V1觀看到的第1A圖之立體式載板130的示意圖,而第2B圖繪示第1A圖的區域2B’的放大圖。Referring to FIGS. 2A and 2B, FIG. 2A is a schematic view showing a three-dimensional carrier 130 of FIG. 1A viewed from a viewing angle V1, and FIG. 2B is an enlarged view of a region 2B' of FIG. 1A.

如第2B圖所示,支撐架140包括至少一第一支架滑動部141。第一載件131包括至少一第一載件滑動部1311。第一支架滑動部141及第一載板滑動部1311皆沿第二方向X延伸,其中第一支架滑動部141與第一載件滑動部1311可相對滑動地連接。如此,第一載件131可相對支撐架140沿第二方向X相對移動,進而調整第一陽極121與被鍍物W1的相對距離。當第一載件131與支撐架140的相對位置決定後,可透過固定元件107固定在第一支架滑動部141的固定孔141a與第一載件滑動部1311的數個固定孔1311a之一者,以暫時性固定支撐架140與第一載件131的相對位置。如第2B圖所示,第一載件滑動部1311的固定孔1311a的數量為多個,以提供多段行程調整功能。As shown in FIG. 2B, the support frame 140 includes at least one first bracket sliding portion 141. The first carrier 131 includes at least one first carrier sliding portion 1311. The first bracket sliding portion 141 and the first carrier sliding portion 1311 both extend in the second direction X, wherein the first bracket sliding portion 141 is slidably coupled to the first carrier sliding portion 1311. In this way, the first carrier 131 can be relatively moved relative to the support frame 140 in the second direction X, thereby adjusting the relative distance between the first anode 121 and the object to be plated W1. After the relative position of the first carrier 131 and the support frame 140 is determined, the fixing hole 107 can be fixed to the fixing hole 141a of the first bracket sliding portion 141 and the plurality of fixing holes 1311a of the first carrier sliding portion 1311. The position of the support frame 140 and the first carrier 131 is temporarily fixed. As shown in FIG. 2B, the number of the fixing holes 1311a of the first carrier sliding portion 1311 is plural to provide a multi-step stroke adjustment function.

如第2B圖所示,固定元件107例如是具有螺紋的元件,而第一載件滑動部1311的固定孔1311a為螺孔。或者,固定元件107可以卡合方式(如緊配)暫時性固定於固定孔141a及固定孔1311a,在此設計下,固定元件107可不具螺紋,而固定孔1311a可不為螺孔。As shown in FIG. 2B, the fixing member 107 is, for example, a threaded member, and the fixing hole 1311a of the first carrier sliding portion 1311 is a screw hole. Alternatively, the fixing member 107 may be temporarily fixed to the fixing hole 141a and the fixing hole 1311a in a snapping manner (for example, a tight fit). In this design, the fixing member 107 may not be threaded, and the fixing hole 1311a may not be a screw hole.

此外,如第2A及2B圖所示,連接第一載件131的第一載件滑動部1311的數量可以是四個,其配置在第一陽極121的二個對角處,如第2A圖所示的第一支架滑動部141的配置區域A1~A4 (繪製成圓形虛線)。然,本發明實施例不限制第一載件滑動部1311的數量及/或配置位置。In addition, as shown in FIGS. 2A and 2B, the number of the first carrier sliding portions 1311 connecting the first carrier members 131 may be four, which are disposed at two opposite corners of the first anode 121, as shown in FIG. 2A. The arrangement areas A1 to A4 of the first holder sliding portion 141 are shown (drawn as circular dashed lines). However, the embodiment of the present invention does not limit the number and/or arrangement position of the first carrier sliding portion 1311.

相似地,第二支撐架140更包括第二支架滑動部(未標示)及第三支架滑動部(未標示),而第二載件132及第三載件133分別包括至少一第二載件滑動部(未標示)及至少一第三載件滑動部(未標示)。第二支架滑動部與第二載件滑動部的連接關係類似前述第一支架滑動部141與第一載件滑動部1311的連接關係。第三支架滑動部與第三載件滑動部的連接關係類似前述第一支架滑動部141與第一載件滑動部1311的連接關係。此外,連接第二載件132的第二載件滑動部的數量可以是四個,如第2A圖所示第二載件132的四個圓形虛線。然,本發明實施例不限制第二載件滑動部的數量及/或配置位置。連接第三載件133的第三載件滑動部的數量可以是四個,如第2A圖所示第三載件133的四個圓形虛線。然,本發明實施例不限制第三載件滑動部的數量及/或配置位置。Similarly, the second support frame 140 further includes a second bracket sliding portion (not labeled) and a third bracket sliding portion (not labeled), and the second carrier member 132 and the third carrier member 133 respectively include at least one second carrier member a sliding portion (not shown) and at least a third carrier sliding portion (not shown). The connection relationship between the second bracket sliding portion and the second carrier sliding portion is similar to the connection relationship between the first bracket sliding portion 141 and the first carrier sliding portion 1311. The connection relationship between the third bracket sliding portion and the third carrier sliding portion is similar to the connection relationship between the first bracket sliding portion 141 and the first carrier sliding portion 1311. Further, the number of second carrier sliding portions connecting the second carrier 132 may be four, as shown in FIG. 2A, four circular dashed lines of the second carrier 132. However, embodiments of the present invention do not limit the number and/or arrangement of the second carrier sliding portions. The number of the third carrier sliding portions that connect the third carrier member 133 may be four, as shown by the second circular 133 of the third carrier member 133 shown in FIG. 2A. However, embodiments of the present invention do not limit the number and/or arrangement of the third carrier sliding portions.

請參照第3圖,其繪示第1A圖之立體式載板130及立體式陽極組120的另一種姿態圖。由圖可知,以第一陽極121來說,藉由第一載件滑動部1311與第一支架滑動部141的相對位置調整,可調整各配置區域A1~A4 (繪示於第2B圖)相對支撐架140的距離。藉由相似的調整方式,第二陽極122及/或第三陽極123相對被鍍物W1可調整成不同的傾斜姿態,如第3圖所示。在另一實施例中,第一陽極121、第二陽極122與第三陽極123之至少一者相對被鍍物W1可調整成傾斜的姿態,而其它者相對被鍍物W1可調整成平行的姿態。本發明實施例不限定第一陽極121、第二陽極122及/或第三陽極123的姿態,其可視所設計的被鍍物W1的鍍膜厚度分布而定。Referring to FIG. 3, another attitude diagram of the three-dimensional carrier 130 and the three-dimensional anode assembly 120 of FIG. 1A is shown. As can be seen from the figure, in the first anode 121, by adjusting the relative positions of the first carrier sliding portion 1311 and the first holder sliding portion 141, the respective arrangement areas A1 to A4 (shown in FIG. 2B) can be adjusted. The distance of the support frame 140. By similar adjustment, the second anode 122 and/or the third anode 123 can be adjusted to different inclined postures with respect to the object to be plated W1, as shown in FIG. In another embodiment, at least one of the first anode 121, the second anode 122, and the third anode 123 can be adjusted to an inclined posture with respect to the object to be plated W1, and the others can be adjusted to be parallel with respect to the object to be plated W1. attitude. The embodiment of the present invention does not limit the posture of the first anode 121, the second anode 122, and/or the third anode 123, which may depend on the designed coating thickness distribution of the object to be plated W1.

請參照第4圖,其繪示往第二方向X觀看到的第1A圖之搖槳150的示意圖。搖槳150與立體式陽極組120 (繪示於第1A圖)沿第二方向X排列。驅動器160用以驅動搖槳150沿第一方向Y與第三方向Z至少一者運動,其中第三方向Z與第一方向Y實質上垂直。由於搖槳150沿第一方向Y與第三方向Z至少一者運動,可擾動電鍍液L1,以調節離子反應效率,提供被鍍物W1表面足夠的正離子,或移除氣泡等副產物 。此外,驅動器160例如是馬達,其可透過驅動機構155驅動搖槳150沿第一方向Y與第三方向Z至少一者運動。此處的驅動機構155例如是齒條齒輪組、蘇格蘭軛或其它合適的機構。Please refer to FIG. 4, which shows a schematic diagram of the rocker 150 of FIG. 1A viewed in the second direction X. The paddle 150 and the three-dimensional anode group 120 (shown in FIG. 1A) are arranged in the second direction X. The driver 160 is configured to drive the rocker 150 to move in at least one of the first direction Y and the third direction Z, wherein the third direction Z is substantially perpendicular to the first direction Y. Since the paddle 150 moves at least one of the first direction Y and the third direction Z, the plating solution L1 can be disturbed to adjust the ion reaction efficiency, provide sufficient positive ions on the surface of the object to be plated W1, or remove by-products such as bubbles. Further, the driver 160 is, for example, a motor that can drive the rocker 150 to move in at least one of the first direction Y and the third direction Z through the drive mechanism 155. The drive mechanism 155 herein is, for example, a rack and pinion set, a scotch yoke or other suitable mechanism.

如第4圖所示,搖槳150包括連接件151及至少一擾動槳152。連接件151沿第三方向Z延伸。擾動槳152連接於連接件151且沿第一方向Y延伸。前述驅動機構155連接於連接件151,以帶動擾動槳152沿第一方向Y與第三方向Z至少一者運動。As shown in FIG. 4, the rocker 150 includes a connector 151 and at least one agitating paddle 152. The connector 151 extends in the third direction Z. The disturbance paddle 152 is coupled to the connector 151 and extends in the first direction Y. The driving mechanism 155 is connected to the connecting member 151 to drive the disturbing paddle 152 to move in at least one of the first direction Y and the third direction Z.

如第4圖所示,各擾動槳152具有至少一導電區152C。導電區152C可吸引電力線,提高導電區152C周圍的電流密度,可增加被鍍物W1中對應導電區152C的區域的鍍膜厚度。換言之,透過此些擾動槳152的數個導電區152C的圖案設計,可獲致被鍍物W1的不同區域的不同鍍膜厚度。此外,本發明實施例不限定各擾動槳152的導電區152C的數量、尺寸及/或位置。另外,以製程來說,搖槳150可以是導電架,如金屬導電架,其外表面可以塗佈一層絕緣層,但露出一部分,其中露出的外表面部分即定義為導電區152C。在另一實施例中,整個搖槳150可以是絕緣搖槳,或者整個導電架的外表面塗佈一層絕緣層而不露出任何導電區。As shown in FIG. 4, each of the disturbing paddles 152 has at least one conductive region 152C. The conductive region 152C can attract the power line, increase the current density around the conductive region 152C, and increase the coating thickness of the region of the corresponding conductive region 152C in the substrate W1. In other words, through the pattern design of the plurality of conductive regions 152C of the disturbing paddles 152, different coating thicknesses of different regions of the object to be plated W1 can be obtained. Moreover, embodiments of the present invention do not limit the number, size, and/or location of conductive regions 152C of each of the disturbing paddles 152. In addition, in terms of process, the paddle 150 may be a conductive frame, such as a metal conductive frame, the outer surface of which may be coated with an insulating layer, but a portion is exposed, wherein the exposed outer surface portion is defined as a conductive region 152C. In another embodiment, the entire paddle 150 can be an insulated paddle or the outer surface of the entire conductive frame can be coated with an insulating layer without exposing any conductive regions.

請參照第5圖,其繪示第4圖之擾動槳152沿方向5-5’的剖視圖。擾動槳152包括第一板片1521及第二板片1522。第一板片1521具有第一端1521a與第二端1521b。第一板片1521相距立體式陽極組120(未繪示於第5圖)的距離H1自第一板片1521的第二端1521b往第一端1521a的方向漸短。即,第一板片1521相距被鍍物W1的距離H2自第一板片1521的第一端1521a往第二端1521b的方向漸短。如此,當擾動槳152往-Z方向移動時,電鍍液L1相對往+Z方向移動,使電鍍液L1從較大空間的距離H2被擠壓至較小空間的距離H2,以達到擾動電鍍液L1的效果,進而提高離子交換效率,以提供被鍍物W1表面足夠的正離子。Referring to Figure 5, there is shown a cross-sectional view of the disturbing paddle 152 of Figure 4 in the direction 5-5'. The disturbance paddle 152 includes a first plate 1521 and a second plate 1522. The first plate 1521 has a first end 1521a and a second end 1521b. The distance H1 of the first plate 1521 from the three-dimensional anode group 120 (not shown in FIG. 5) is gradually shorter from the second end 1521b of the first plate 1521 toward the first end 1521a. That is, the distance H2 of the first plate piece 1521 from the object to be plated W1 is gradually shortened from the first end 1521a of the first plate piece 1521 toward the second end 1521b. Thus, when the disturbing paddle 152 moves in the -Z direction, the plating solution L1 moves relative to the +Z direction, so that the plating solution L1 is squeezed from the larger space distance H2 to a smaller space distance H2 to achieve the disturbing plating solution. The effect of L1, in turn, increases the ion exchange efficiency to provide sufficient positive ions on the surface of the object to be plated W1.

此外,如第5圖所示,第一板片1521比第二板片1522遠離立體式陽極組120,即第一板片1521比第二板片1522靠近被鍍物W1。第二板片1522具有第三端1522a與第四端1522b,第一板片1521的第一端1521a與第二板片1522的第三端1522a連接。第二板片1522相距立體式陽極組120的距離H3自第二板片1522的第四端1522b往第三端1522a漸長,即第二板片1522相距被鍍物W1的距離H4自第二板片1522的第三端1522a往第四端1522b漸短。如此,第一板片1521與第二板片1522連接成例如是V字型,V字型的空間(即第一板片1521與第二板片1522之間的空間)內可容納電鍍液L1。Further, as shown in FIG. 5, the first plate piece 1521 is away from the three-dimensional anode group 120 than the second plate piece 1522, that is, the first plate piece 1521 is closer to the object to be plated W1 than the second plate piece 1522. The second plate 1522 has a third end 1522a and a fourth end 1522b, and the first end 1521a of the first plate 1521 is coupled to the third end 1522a of the second plate 1522. The distance H3 of the second plate 1522 from the three-dimensional anode group 120 is gradually longer from the fourth end 1522b of the second plate 1522 to the third end 1522a, that is, the distance H4 of the second plate 1522 from the object W1 is from the second The third end 1522a of the plate 1522 is tapered toward the fourth end 1522b. Thus, the first plate 1521 and the second plate 1522 are connected to form, for example, a V-shape, and the V-shaped space (ie, the space between the first plate 1521 and the second plate 1522) can accommodate the plating solution L1. .

此外,第一板片1521具有貫孔1521r。如此,當擾動槳152往+Z方向移動時,第一板片1521與第二板片1522之間的電鍍液L1被迫從貫孔1521r擠出,以擾動第一板片1521與被鍍物W1之間的電鍍液L1,進而提高離子交換效率,以提供被鍍物W1表面足夠的正離子。Further, the first plate 1521 has a through hole 1521r. Thus, when the disturbing paddle 152 moves in the +Z direction, the plating solution L1 between the first plate 1521 and the second plate 1522 is forced to be extruded from the through hole 1521r to disturb the first plate 1521 and the object to be plated. The plating solution L1 between W1 further increases the ion exchange efficiency to provide sufficient positive ions on the surface of the object to be plated W1.

此外,在另一實施例中,擾動槳152可以具有實心剖面,如多邊形、圓形或橢圓形等,其中多邊形例如是菱形、矩形等。在其它實施例中,搖槳150可改以後述的均流板170或170’取代,以提供均流效果。在另一實施例中,第4圖之搖槳150的擾動槳152可具有類似或同於後述蜂巢孔(如170a、270a1及/或270a2)的蜂巢結構,以提供均流效果。Further, in another embodiment, the disturbing paddle 152 may have a solid cross section, such as a polygon, a circle, or an ellipse, etc., wherein the polygon is, for example, a diamond, a rectangle, or the like. In other embodiments, the paddle 150 may be replaced with a current equalizing plate 170 or 170' to provide a current sharing effect. In another embodiment, the perturbation paddle 152 of the paddle 150 of FIG. 4 can have a honeycomb structure similar or identical to the honeycomb holes (such as 170a, 270a1, and/or 270a2) described below to provide a current sharing effect.

如第1A及6A及6B圖所示,第6A圖繪示第1A圖之均流板170的俯視圖,而第6B圖繪示另一實施例之均流板270的俯視圖。如第1A圖所示,均流板170配置在立體式陽極組120的下方。例如,電解槽105的底板1051具有一開口1051a。均流板170位於電解槽105的開口1051a與立體式陽極組120之間,例如,開口1051a與立體式陽極組120沿第一方向Y排列。如第6A圖所示,均流板170具有數個蜂巢孔170a,可擾動通過的電鍍液L1,以提高離子交換效率。As shown in FIGS. 1A and 6A and 6B, FIG. 6A is a plan view of the current equalizing plate 170 of FIG. 1A, and FIG. 6B is a plan view of the current sharing plate 270 of another embodiment. As shown in FIG. 1A, the current equalizing plate 170 is disposed below the three-dimensional anode group 120. For example, the bottom plate 1051 of the electrolytic cell 105 has an opening 1051a. The current equalizing plate 170 is located between the opening 1051a of the electrolytic cell 105 and the three-dimensional anode group 120. For example, the opening 1051a and the three-dimensional anode group 120 are arranged in the first direction Y. As shown in Fig. 6A, the flow equalizing plate 170 has a plurality of honeycomb holes 170a for disturbing the passing plating solution L1 to improve ion exchange efficiency.

如第6B圖所示,另一實施例之均流板270具有數個蜂巢孔270a。蜂巢孔270a的壁厚t1與第6A圖的蜂巢孔170a的壁厚不同。且,第6B的蜂巢孔270a的內徑d1也可與第6A圖的蜂巢孔170a的內徑不同。比較第6A及6B圖,第6B圖的蜂巢孔270a的壁厚t1大於第6A圖的蜂巢孔170a的壁厚,使蜂巢孔270a的內徑d1大於蜂巢孔170a的內徑。綜上可知,本發明實施例之均流板的蜂巢孔可具有不同壁厚及/或內徑,以改變通過此些蜂巢孔的電鍍液L1的流速,進而可控制形成在被鍍物W1上的鍍膜厚度。As shown in Fig. 6B, the flow equalization plate 270 of another embodiment has a plurality of honeycomb holes 270a. The wall thickness t1 of the honeycomb hole 270a is different from the wall thickness of the honeycomb hole 170a of Fig. 6A. Further, the inner diameter d1 of the honeycomb hole 270a of the sixth embodiment may be different from the inner diameter of the honeycomb hole 170a of the sixth embodiment. Comparing Figs. 6A and 6B, the wall thickness t1 of the honeycomb hole 270a of Fig. 6B is larger than the wall thickness of the honeycomb hole 170a of Fig. 6A, so that the inner diameter d1 of the honeycomb hole 270a is larger than the inner diameter of the honeycomb hole 170a. In summary, the honeycomb holes of the current sharing plate of the embodiment of the present invention may have different wall thicknesses and/or inner diameters to change the flow rate of the plating solution L1 passing through the honeycomb holes, thereby being controlled to be formed on the object to be plated W1. Coating thickness.

請參照第7圖,其繪示依照本發明另一實施例之均流板170’的示意圖。均流板170’具有數個第一蜂巢孔170a1及數個第二蜂巢孔170a2,其中第一蜂巢孔170a1的分布密度與第二蜂巢孔170a2的分布密度相異。如圖所示,第一蜂巢孔170a1的分布密度大於第二蜂巢孔170a2的分布密度。透過蜂巢孔分布密度的差異,可讓通過均流板170’不同區域的電鍍液L1具有不同的流速,以控制形成在被鍍物W1上的鍍膜厚度。此外,第一蜂巢孔170a1的內徑與第二蜂巢孔170a2的內徑可相異,以達到類似的效果。由上可知,本發明實施例的均流板的數個蜂巢孔在不同區域可以有不同密度及/或不同內徑,使通過此些蜂巢孔的電鍍液L1的流速不同,以控制形成在被鍍物W1上的鍍膜厚度。Referring to Figure 7, a schematic view of a current sharing plate 170' in accordance with another embodiment of the present invention is shown. The flow plate 170' has a plurality of first honeycomb holes 170a1 and a plurality of second honeycomb holes 170a2, wherein the distribution density of the first honeycomb holes 170a1 is different from the distribution density of the second honeycomb holes 170a2. As shown, the distribution density of the first honeycomb apertures 170a1 is greater than the distribution density of the second honeycomb apertures 170a2. The difference in distribution density of the honeycomb holes allows the plating solution L1 passing through different regions of the flow equalizing plate 170' to have different flow rates to control the thickness of the plating film formed on the object to be plated W1. Further, the inner diameter of the first honeycomb hole 170a1 and the inner diameter of the second honeycomb hole 170a2 may be different to achieve a similar effect. It can be seen from the above that the plurality of honeycomb holes of the current sharing plate of the embodiment of the present invention may have different densities and/or different inner diameters in different regions, so that the flow rate of the plating solution L1 passing through the honeycomb holes is different to control the formation of the honeycomb layer. The thickness of the coating on the plating material W1.

請參照第8A及8B圖,第8A圖繪示依照本發明另一實施例之立體式載板230、支撐架240及立體式陽極組120的示意圖,而第8B圖繪示往視角V1觀看到的第8A圖之立體式陽極組120的示意圖。Please refer to FIGS. 8A and 8B. FIG. 8A is a schematic diagram of a three-dimensional carrier 230, a support frame 240 and a three-dimensional anode assembly 120 according to another embodiment of the present invention, and FIG. 8B is viewed from a viewing angle V1. A schematic view of a three-dimensional anode assembly 120 of Figure 8A.

立體式載板230包括第一載件231、第二載件232及第三載件233。在本實施例中,第一載件231、第二載件232及第三載件233可沿第一方向Y及/或第三方向Z相對支撐架240移動,以調整第一陽極121、第二陽極122及第三陽極123相對被鍍物W1的位置,以控制形成在被鍍物W1上的鍍膜厚度。The three-dimensional carrier 230 includes a first carrier 231, a second carrier 232, and a third carrier 233. In this embodiment, the first carrier 231, the second carrier 232, and the third carrier 233 are movable relative to the support frame 240 along the first direction Y and/or the third direction Z to adjust the first anode 121, the first The positions of the two anodes 122 and the third anodes 123 with respect to the object to be plated W1 are controlled to control the thickness of the plating film formed on the object to be plated W1.

請參照第9圖,其繪示依照本發明另一實施例之立體式載板330、支撐架340及立體式陽極組120的示意圖。Please refer to FIG. 9 , which illustrates a schematic view of a three-dimensional carrier 330 , a support frame 340 , and a three-dimensional anode assembly 120 according to another embodiment of the present invention.

立體式載板330包括第一連接凸緣331、第二連接凸緣332、第三連接凸緣333、第四連接凸緣334、第四連接凸緣334、第一連接桿335、第二連接桿336、第五連接凸緣337、第六連接凸緣338及至少一固定元件339。第一連接凸緣331及第三連接凸緣333分別連接於(如固定於)第一陽極121的相對二側。第二連接凸緣332及第四連接凸緣334分別連接於第二陽極122的相對二側。第一連接桿335連接於支撐架340且穿過第一連接凸緣331及第二連接凸緣332,以串接第一陽極121與第二陽極122。第二連接桿336連接於支撐架340且穿過第三連接凸緣333及第四連接凸緣334,以串接第一陽極121與第二陽極122。由於第一連接桿335及第二連接桿336分別串接立體式陽極組120的相對二側,使立體式陽極組120的此些陽極的相對位置關係更加穩定。在另一實施例中,若無必要,可省略第一連接桿335與第二連接桿336之一者。The three-dimensional carrier 330 includes a first connecting flange 331, a second connecting flange 332, a third connecting flange 333, a fourth connecting flange 334, a fourth connecting flange 334, a first connecting rod 335, and a second connection. The rod 336, the fifth connecting flange 337, the sixth connecting flange 338 and at least one fixing element 339. The first connecting flange 331 and the third connecting flange 333 are respectively connected (eg, fixed) to opposite sides of the first anode 121. The second connecting flange 332 and the fourth connecting flange 334 are respectively connected to opposite sides of the second anode 122. The first connecting rod 335 is connected to the support frame 340 and passes through the first connecting flange 331 and the second connecting flange 332 to connect the first anode 121 and the second anode 122 in series. The second connecting rod 336 is connected to the support frame 340 and passes through the third connecting flange 333 and the fourth connecting flange 334 to serially connect the first anode 121 and the second anode 122. Since the first connecting rod 335 and the second connecting rod 336 are respectively connected to opposite sides of the three-dimensional anode group 120, the relative positional relationship of the anodes of the three-dimensional anode group 120 is more stable. In another embodiment, one of the first connecting rod 335 and the second connecting rod 336 may be omitted if not necessary.

此外,第五連接凸緣337及第六連接凸緣338分別連接第三陽極123的相對二側。第一連接桿335及第二連接桿336可分別穿過第五連接凸緣337及第六連接凸緣338,以串接第一陽極121、第二陽極122與第三陽極133。In addition, the fifth connecting flange 337 and the sixth connecting flange 338 are respectively connected to opposite sides of the third anode 123. The first connecting rod 335 and the second connecting rod 336 can pass through the fifth connecting flange 337 and the sixth connecting flange 338, respectively, to connect the first anode 121, the second anode 122 and the third anode 133 in series.

如第9圖所示,第一連接桿335具有數個固定孔335a,而第一連接凸緣331具有固定孔331a。藉由調整第一連接桿335與第一連接凸緣331的相對位置,可讓第一連接凸緣331的固定孔331a與第一連接桿335的其中一固定孔335a在位置上相對應。當第一連接桿335與第一連接凸緣331的相對位置決定後,固定元件339可穿過相對應之固定孔331a與固定孔335a,以固定第一陽極121與第一連接桿335的相對位置。As shown in Fig. 9, the first connecting rod 335 has a plurality of fixing holes 335a, and the first connecting flange 331 has a fixing hole 331a. By adjusting the relative position of the first connecting rod 335 and the first connecting flange 331, the fixing hole 331a of the first connecting flange 331 can be correspondingly positioned with one of the fixing holes 335a of the first connecting rod 335. When the relative position of the first connecting rod 335 and the first connecting flange 331 is determined, the fixing member 339 can pass through the corresponding fixing hole 331a and the fixing hole 335a to fix the relative relationship between the first anode 121 and the first connecting rod 335. position.

此外,第一連接桿335與第二連接凸緣332的連接關係同於第一連接桿335與第一連接凸緣331的連接關係,於此不再贅述。第一連接桿335與第五連接凸緣337的連接關係同於第一連接桿335與第一連接凸緣331的連接關係,於此不再贅述。另,第二連接桿336具有類似或相似於第一連接桿335的結構。第二連接桿336與第三連接凸緣333、第四連接凸緣334及第六連接凸緣338的連接關係同於第一連接桿335與第一連接凸緣331的連接關係,於此也不再贅述。In addition, the connection relationship between the first connecting rod 335 and the second connecting flange 332 is the same as the connecting relationship between the first connecting rod 335 and the first connecting flange 331 , and details are not described herein again. The connection relationship between the first connecting rod 335 and the fifth connecting flange 337 is the same as the connecting relationship between the first connecting rod 335 and the first connecting flange 331, and details are not described herein. In addition, the second connecting rod 336 has a structure similar or similar to that of the first connecting rod 335. The connection relationship between the second connecting rod 336 and the third connecting flange 333, the fourth connecting flange 334 and the sixth connecting flange 338 is the same as the connecting relationship between the first connecting rod 335 and the first connecting flange 331. No longer.

請參照第10圖,其繪示依照本發明另一實施例之電鍍設備400的示意圖。電鍍設備400包括電解槽105、電源供應器106、過濾器110、幫浦115、立體式陽極組120、立體式載板130、支撐架140、搖槳150、驅動機構155及驅動器160。本發明實施例之電鍍設備400具有與電鍍設備100類似或相同特徵,不同處在於電鍍液L1的流動方向,以及立體式陽極組120及立體式載板130與被鍍物W1的高低位置不同。Referring to FIG. 10, a schematic diagram of a plating apparatus 400 in accordance with another embodiment of the present invention is shown. The electroplating apparatus 400 includes an electrolysis cell 105, a power supply 106, a filter 110, a pump 115, a stereo anode group 120, a stereoscopic carrier 130, a support frame 140, a paddle 150, a drive mechanism 155, and a driver 160. The electroplating apparatus 400 of the embodiment of the present invention has similar or identical features to the electroplating apparatus 100, except that the flow direction of the plating solution L1 is different, and the three-dimensional anode set 120 and the three-dimensional carrier 130 are different from the height of the object to be plated W1.

如第10圖所示,支撐架140的底部140b及立體式陽極組120的底部120b與電解槽105的底板1051之間具有一距離,以提供電鍍液L1一下流路通道。此外,被鍍物W1的頂部W11低於立體式陽極組120的頂部120u,以提供電鍍液L1一上流路通道。此外,電解槽105更包括側板1052,其中側板1052具有開口1052a。如此,電鍍液L1從開口1052a側向地進入電解槽105內,依序經由下流路通道及上流路通道後,流出電解槽105。由於電鍍液L1經過立體式陽極組120的底部120b,因此可擾動立體式陽極組120的底部120b與底板1051之間的電鍍液,使電鍍液充分循環,以提升離子交換效率。As shown in Fig. 10, the bottom portion 140b of the support frame 140 and the bottom portion 120b of the three-dimensional anode group 120 have a distance from the bottom plate 1051 of the electrolytic cell 105 to provide a flow path for the plating solution L1. Further, the top portion W11 of the object to be plated W1 is lower than the top portion 120u of the three-dimensional anode group 120 to provide a plating liquid channel L1 to an upper flow path. In addition, the electrolytic cell 105 further includes a side plate 1052, wherein the side plate 1052 has an opening 1052a. In this manner, the plating solution L1 enters the electrolytic cell 105 laterally from the opening 1052a, and then flows out of the electrolytic cell 105 through the lower flow path and the upper flow path. Since the plating solution L1 passes through the bottom portion 120b of the three-dimensional anode group 120, the plating solution between the bottom portion 120b of the three-dimensional anode group 120 and the bottom plate 1051 can be disturbed to sufficiently circulate the plating solution to enhance the ion exchange efficiency.

請參照第11圖,其繪示依照本發明另一實施例之第一陽極121’的示意圖。第一陽極121’具有第一表面121s1及第二表面121s2,其中第一陽極121’以第一表面121s1配置在第一載件131上。第二表面121s2相對第一表面121s1傾斜,使第二表面121s2的各點與被鍍物W1的相對距離不同,以控制形成在被鍍物W1上的鍍膜厚度。第一表面121s1例如是平面、曲面或其組合。第一表面121s1可具有中間區域相對邊緣區域突出的輪廓,使第一表面121s1的中間區域相距被鍍物W1的距離小於邊緣區域相距被鍍物W1的距離。或者,第一表面121s1可具有中間區域相對邊緣區域凹陷的輪廓,使第一表面121s1的中間區域相距被鍍物W1的距離大於邊緣區域相距被鍍物W1的距離。此外,第一表面121s1的幾何型態可視被鍍物W1的鍍膜設計而定,本發明實施例不限制第一表面121s1的幾何型態。此外,第二陽極121及第三陽極123可具有類似或同於第一陽極121’的表面特徵,於此不再贅述。Referring to Figure 11, there is shown a schematic view of a first anode 121' in accordance with another embodiment of the present invention. The first anode 121' has a first surface 121s1 and a second surface 121s2, wherein the first anode 121' is disposed on the first carrier 131 with the first surface 121s1. The second surface 121s2 is inclined with respect to the first surface 121s1 such that the relative distance between each point of the second surface 121s2 and the object to be plated W1 is different to control the thickness of the plating film formed on the object to be plated W1. The first surface 121s1 is, for example, a plane, a curved surface, or a combination thereof. The first surface 121s1 may have a contour in which the intermediate portion protrudes from the edge region such that the intermediate portion of the first surface 121s1 is spaced apart from the object to be plated W1 by a distance smaller than the distance of the edge region from the object to be plated W1. Alternatively, the first surface 121s1 may have a contour in which the intermediate portion is recessed with respect to the edge region such that the intermediate portion of the first surface 121s1 is spaced apart from the object to be plated W1 by a distance greater than the distance of the edge region from the object to be plated W1. In addition, the geometry of the first surface 121s1 may depend on the coating design of the substrate W1, and the embodiment of the present invention does not limit the geometry of the first surface 121s1. In addition, the second anode 121 and the third anode 123 may have surface features similar to or the same as those of the first anode 121', and will not be described herein.

綜上可知,本發明實施例之電鍍設備包括立體式陽極組。立體式陽極組包括數個陽極,此些陽極與被鍍物之間的距離不同,因此可使被鍍物上的鍍膜厚度均勻化,或獲得所欲的鍍膜厚度設計。在一實施例中,立體式陽極組的各陽極相對被鍍物的相對距離及/或角度係可調整。在另一實施例中,立體式陽極組的陽極具有一表面,此表面的數點與被鍍物W1的相對距離可不同,其中此表面例如是平面、曲面或其組合。在其它實施例中,透過電鍍液的入口可設在電解槽的側板,使電鍍液流經立體式陽極組的底部及被鍍物的頂部,使電鍍液充分循環,提升離子交換效率。In summary, the electroplating apparatus of the embodiment of the present invention includes a three-dimensional anode group. The three-dimensional anode group includes a plurality of anodes, and the distance between the anodes and the object to be plated is different, so that the thickness of the plating film on the object to be plated can be made uniform, or the desired coating thickness can be obtained. In one embodiment, the relative distance and/or angle of the anodes of the three-dimensional anode assembly relative to the substrate can be adjusted. In another embodiment, the anode of the three-dimensional anode set has a surface, the number of points of which may be different from the relative distance of the object to be plated W1, wherein the surface is, for example, a plane, a curved surface or a combination thereof. In other embodiments, the inlet through the plating solution may be disposed on the side plate of the electrolytic cell, so that the plating solution flows through the bottom of the three-dimensional anode group and the top of the object to be plated, so that the plating solution is fully circulated, and the ion exchange efficiency is improved.

綜上所述,雖然本發明已以實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。In conclusion, the present invention has been disclosed in the above embodiments, but it is not intended to limit the present invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.

100、400‧‧‧電鍍設備100,400‧‧‧Electroplating equipment

105‧‧‧電解槽105‧‧‧electrolyzer

1051‧‧‧底板1051‧‧‧floor

1052‧‧‧側板1052‧‧‧ side panels

1051a、1052a‧‧‧開口1051a, 1052a‧‧‧ openings

106‧‧‧電源供應器106‧‧‧Power supply

1061‧‧‧第一可變電阻1061‧‧‧First variable resistor

1062‧‧‧第二可變電阻1062‧‧‧Second variable resistor

1063‧‧‧第三可變電阻1063‧‧‧ Third variable resistor

107、339‧‧‧固定元件107, 339‧‧‧Fixed components

110‧‧‧過濾器110‧‧‧Filter

115‧‧‧幫浦115‧‧‧ pump

120‧‧‧立體式陽極組120‧‧‧Three-dimensional anode group

120b、140b‧‧‧底部120b, 140b‧‧‧ bottom

120u、W11‧‧‧頂部120u, W11‧‧‧ top

121、121’‧‧‧第一陽極121, 121'‧‧‧ first anode

121s1‧‧‧第一表面121s1‧‧‧ first surface

121s2‧‧‧第二表面121s2‧‧‧ second surface

1211‧‧‧網目結構1211‧‧‧Mesh structure

1212‧‧‧可溶性陽極顆粒1212‧‧‧Soluble anode particles

1211a‧‧‧網目1211a‧‧‧Mesh

122‧‧‧第二陽極122‧‧‧Second anode

122a、123a‧‧‧貫穿部122a, 123a‧‧‧ penetration

123‧‧‧第三陽極123‧‧‧ Third anode

130、230、330‧‧‧立體式載板130, 230, 330‧‧‧ three-dimensional carrier

131、231‧‧‧第一載件131, 231‧‧‧ first carrier

132、232‧‧‧第二載件132, 232‧‧‧second carrier

133、233‧‧‧第三載件133, 233‧‧‧ third carrier

1311‧‧‧第一載件滑動部1311‧‧‧First carrier sliding part

140、240、340‧‧‧支撐架140, 240, 340‧‧‧ support frame

141‧‧‧第一支架滑動部141‧‧‧First bracket sliding part

141a、1311a、331a、335a‧‧‧固定孔141a, 1311a, 331a, 335a‧‧‧ fixing holes

150‧‧‧搖槳150‧‧‧Woist

151‧‧‧連接件151‧‧‧Connecting parts

152‧‧‧擾動槳152‧‧‧ disturbed paddle

1521‧‧‧第一板片1521‧‧‧ first board

1521a‧‧‧第一端1521a‧‧‧ first end

1521b‧‧‧第二端1521b‧‧‧second end

1521r‧‧‧貫孔1521r‧‧‧through hole

1522‧‧‧第二板片1522‧‧‧ second plate

1522a‧‧‧第三端1522a‧‧‧ third end

1522b‧‧‧第四端1522b‧‧‧ fourth end

152C‧‧‧導電區152C‧‧‧ conductive area

155‧‧‧驅動機構155‧‧‧ drive mechanism

160‧‧‧驅動器160‧‧‧ drive

170、170’、270‧‧‧均流板170, 170’, 270‧‧ ‧ flow boards

170a、270a‧‧‧蜂巢孔170a, 270a‧‧‧ honeycomb holes

170a1‧‧‧第一蜂巢孔170a1‧‧‧First Honeycomb Hole

170a2‧‧‧第二蜂巢孔170a2‧‧‧Second honeycomb hole

331‧‧‧第一連接凸緣331‧‧‧First connecting flange

332‧‧‧第二連接凸緣332‧‧‧Second connection flange

333‧‧‧第三連接凸緣333‧‧‧ Third connecting flange

334‧‧‧第四連接凸緣334‧‧‧fourth connection flange

335‧‧‧第一連接桿335‧‧‧first connecting rod

336‧‧‧第二連接桿336‧‧‧Second connecting rod

337‧‧‧第五連接凸緣337‧‧‧ fifth connecting flange

338‧‧‧第六連接凸緣338‧‧‧6th connection flange

d1‧‧‧內徑D1‧‧‧Down

H1、H2、H3、H4‧‧‧距離H1, H2, H3, H4‧‧‧ distance

L1‧‧‧電鍍液L1‧‧‧ plating solution

R1、R2、R3‧‧‧區域R1, R2, R3‧‧‧ areas

V1‧‧‧視角V1‧‧ Perspective

W1‧‧‧被鍍物W1‧‧‧ plating

X‧‧‧第二方向X‧‧‧second direction

t1‧‧‧壁厚T1‧‧‧ wall thickness

Y‧‧‧第一方向Y‧‧‧First direction

Z‧‧‧第三方向Z‧‧‧ third direction

第1A圖繪示依照本發明一實施例之電鍍設備的示意圖。 第1B圖繪示往視角V1觀看到的第1A圖之立體式陽極組的視圖。 第1C圖繪示往視角V1觀看到的第1A圖之第一陽極的結構示意圖。 第2A圖繪示往視角V1觀看到的第1A圖之立體式載板的示意圖。 第2B圖繪示第1A圖的區域2B’的放大圖。 第3圖繪示第1A圖之立體式載板及立體式陽極組的另一種姿態圖。 第4圖繪示往第二方向X觀看到的第1A圖之搖槳的示意圖。 第5圖繪示第4圖之擾動槳沿方向5-5’的剖視圖。 第6A圖繪示第1A圖之均流板的俯視圖。 第6B圖繪示另一實施例之均流板的俯視圖。 第7圖繪示依照本發明另一實施例之均流板的示意圖。 第8A圖繪示依照本發明另一實施例之立體式載板、支撐架及立體式陽極組的示意圖。 第8B圖繪示往視角V1觀看到的第8A圖之立體式陽極組的示意圖。 第9圖繪示依照本發明另一實施例之立體式載板、支撐架及立體式陽極組的示意圖。 第10圖繪示依照本發明另一實施例之電鍍設備的示意圖。 第11圖繪示依照本發明另一實施例之第一陽極的示意圖。FIG. 1A is a schematic view of an electroplating apparatus according to an embodiment of the invention. FIG. 1B is a view showing a three-dimensional anode group of FIG. 1A viewed from a viewing angle V1. FIG. 1C is a schematic view showing the structure of the first anode of FIG. 1A viewed from the viewing angle V1. FIG. 2A is a schematic diagram showing a three-dimensional carrier of FIG. 1A viewed from a viewing angle V1. Fig. 2B is an enlarged view of a region 2B' of Fig. 1A. Fig. 3 is a view showing another posture of the three-dimensional carrier and the three-dimensional anode assembly of Fig. 1A. FIG. 4 is a schematic view showing the paddle of FIG. 1A viewed in the second direction X. Fig. 5 is a cross-sectional view showing the disturbing paddle of Fig. 4 in the direction 5-5'. Fig. 6A is a plan view showing the current sharing plate of Fig. 1A. FIG. 6B is a top view of a current sharing plate of another embodiment. FIG. 7 is a schematic view showing a current sharing plate according to another embodiment of the present invention. FIG. 8A is a schematic view showing a three-dimensional carrier, a support frame and a three-dimensional anode assembly according to another embodiment of the invention. FIG. 8B is a schematic view showing a three-dimensional anode group of FIG. 8A viewed from a viewing angle V1. FIG. 9 is a schematic view showing a three-dimensional carrier, a support frame and a three-dimensional anode assembly according to another embodiment of the present invention. Figure 10 is a schematic view of an electroplating apparatus in accordance with another embodiment of the present invention. 11 is a schematic view showing a first anode according to another embodiment of the present invention.

Claims (20)

一種電鍍設備,包括:一電解槽;以及一立體式陽極組,配置在該電解槽內,且包括:一第一陽極,沿一第一方向延伸;一第二陽極,沿該第一方向延伸,其中該第一陽極與該第二陽極沿一第二方向排列且彼此間隔,其中該第一方向與該第二方向實質上垂直;其中,該第一陽極與一被鍍物放置區的距離係相異於該第二陽極與該被鍍物放置區的距離。 An electroplating apparatus comprising: an electrolytic cell; and a three-dimensional anode set disposed in the electrolytic cell, and comprising: a first anode extending along a first direction; and a second anode extending along the first direction The first anode and the second anode are arranged in a second direction and spaced apart from each other, wherein the first direction is substantially perpendicular to the second direction; wherein a distance between the first anode and a substrate placement area It is different from the distance between the second anode and the object placement area. 如申請專利範圍第1項所述之電鍍設備,其中該第一陽極與該第二陽極沿該第二方向的投影係不互相重疊。 The electroplating apparatus of claim 1, wherein the projections of the first anode and the second anode in the second direction do not overlap each other. 如申請專利範圍第1項所述之電鍍設備,其中該第一陽極與該第二陽極之一者為環形陽極。 The electroplating apparatus of claim 1, wherein one of the first anode and the second anode is a toroidal anode. 如申請專利範圍第1項所述之電鍍設備,更包括:一支撐架;一第一載件,承載該第一陽極且沿該第二方向可平移地連接於該支撐架;以及一第二載件,承載該第二陽極且沿該第二方向可平移地連接於該支撐架。 The electroplating apparatus of claim 1, further comprising: a support frame; a first carrier member that carries the first anode and is translatably coupled to the support frame in the second direction; and a second A carrier carrying the second anode and being translatably coupled to the support frame in the second direction. 如申請專利範圍第4項所述之電鍍設備,其中該支撐架包括一第一支架滑動部及一第二支架滑動部,該第一載件包 括一第一載件滑動部,該第二載件包括一第二載件滑動部,該第一支架滑動部、該第二支架滑動部、該第一載件滑動部及該第二載件滑動部皆沿該第二方向延伸,其中該第一支架滑動部與該第一載件滑動部可滑動地連接,且該第二支架滑動部與該第二載件滑動部可滑動地連接。 The electroplating apparatus of claim 4, wherein the support frame comprises a first bracket sliding portion and a second bracket sliding portion, the first carrier package a first carrier sliding portion, the second carrier member includes a second carrier sliding portion, the first bracket sliding portion, the second bracket sliding portion, the first carrier sliding portion and the second carrier The sliding portion extends in the second direction, wherein the first bracket sliding portion is slidably coupled to the first carrier sliding portion, and the second bracket sliding portion is slidably coupled to the second carrier sliding portion. 如申請專利範圍第1項所述之電鍍設備,更包括:一支撐架;一第一連接凸緣,連接於該第一陽極;一第二連接凸緣,連接於該第二陽極;以及一第一連接桿,連接於該支撐架且穿過該第一連接凸緣及該第二連接凸緣,以連接該第一陽極與該第二陽極。 The electroplating apparatus according to claim 1, further comprising: a support frame; a first connecting flange connected to the first anode; a second connecting flange connected to the second anode; and a a first connecting rod is coupled to the support frame and passes through the first connecting flange and the second connecting flange to connect the first anode and the second anode. 如申請專利範圍第6項所述之電鍍設備,其中該第一連接凸緣連接於該第一陽極的一側,該第二連接凸緣連接於該第二陽極的一側,該電鍍設備更包括:一第三連接凸緣,連接於該第一陽極之相對另一側;一第四連接凸緣,連接於該第二陽極之相對另一側;以及一第二連接桿,連接於該支撐架且穿過該第三連接凸緣及該第四連接凸緣,以連接該第一陽極與該第二陽極。 The electroplating apparatus according to claim 6, wherein the first connecting flange is connected to one side of the first anode, and the second connecting flange is connected to one side of the second anode, and the electroplating apparatus is further The method includes: a third connecting flange connected to the opposite side of the first anode; a fourth connecting flange connected to the opposite side of the second anode; and a second connecting rod connected to the The support frame passes through the third connecting flange and the fourth connecting flange to connect the first anode and the second anode. 如申請專利範圍第1項所述之電鍍設備,更包括:一搖槳,與該立體式陽極組沿該第二方向排列;以及一驅動器,用以驅動該搖槳沿該第一方向與一第三方向至少一者運動,其中該第三方向與該第一方向實質上垂直。 The electroplating apparatus according to claim 1, further comprising: a paddle arranged in the second direction with the three-dimensional anode group; and a driver for driving the paddle along the first direction and a At least one of the third directions moves, wherein the third direction is substantially perpendicular to the first direction. 如申請專利範圍第1項所述之電鍍設備,更包括:一搖槳,與該立體式陽極組沿該第二方向排列,且包括:一連接件,沿該第三方向延伸;以及一擾動槳,連接於該連接件且沿該第一方向延伸,該擾動槳具有一導電區。 The electroplating apparatus of claim 1, further comprising: a paddle arranged in the second direction with the three-dimensional anode group, and comprising: a connecting member extending along the third direction; and a disturbance A paddle is coupled to the connector and extends along the first direction, the perturbation paddle having a conductive region. 如申請專利範圍第1項所述之電鍍設備,更包括:一搖槳,與該立體式陽極組沿該第二方向排列,且包括:一連接件,沿該第三方向延伸;以及一擾動槳,連接於該連接件且沿該第一方向延伸,該擾動槳包括一第一板片,該第一板片具有一第一端與一第二端,該第一板片相距該立體式陽極組的距離自該第一板片的該第二端的方向往該第一端漸短。 The electroplating apparatus of claim 1, further comprising: a paddle arranged in the second direction with the three-dimensional anode group, and comprising: a connecting member extending along the third direction; and a disturbance a paddle connected to the connecting member and extending along the first direction, the disturbing paddle comprising a first plate, the first plate having a first end and a second end, the first plate being spaced apart from the three-dimensional The distance of the anode group is gradually shorter from the direction of the second end of the first sheet toward the first end. 如申請專利範圍第10項所述之電鍍設備,其中該擾動槳更包括一第二板片,該第一板片比該第二板片遠離該立體式陽極組;該第二板片具有一第三端與一第四端,該第一板片的該第一端與該第二板片的該第三端連接,且該第二板片相距該立體式陽極組的距離自該第二板片的該第四端往該第三端的方向漸長。 The electroplating apparatus of claim 10, wherein the disturbing paddle further comprises a second plate, the first plate being away from the stereo anode group than the second plate; the second plate having a a third end and a fourth end, the first end of the first plate is connected to the third end of the second plate, and the distance between the second plate and the three-dimensional anode group is from the second The fourth end of the plate is gradually elongated toward the third end. 如申請專利範圍第10項所述之電鍍設備,其中該第一板片具有一貫孔。 The electroplating apparatus of claim 10, wherein the first sheet has a uniform aperture. 如申請專利範圍第1項所述之電鍍設備,更包括: 一均流板,配置在該立體式陽極組與該電解槽的一底板的一開口之間,且具有複數個蜂巢孔。 For example, the electroplating equipment mentioned in the scope of claim 1 includes: A current sharing plate is disposed between the three-dimensional anode group and an opening of a bottom plate of the electrolytic cell, and has a plurality of honeycomb holes. 如申請專利範圍第13項所述之電鍍設備,其中該些蜂巢孔在不同區域的密度相異。 The electroplating apparatus of claim 13, wherein the honeycomb holes have different densities in different regions. 如申請專利範圍第13項所述之電鍍設備,其中該些蜂巢孔在不同區域的內徑相異。 The electroplating apparatus of claim 13, wherein the honeycomb holes have different inner diameters in different regions. 如申請專利範圍第1項所述之電鍍設備,其中該第一陽極及該第二陽極各包括一網目結構,該第一陽極比該第二陽極靠近該被鍍物放置區,該第一陽極的該網目結構的網目內徑小於該第二陽極的該網目結構的網目內徑。 The electroplating apparatus of claim 1, wherein the first anode and the second anode each comprise a mesh structure, the first anode is closer to the object placement area than the second anode, the first anode The mesh inner diameter of the mesh structure is smaller than the mesh inner diameter of the mesh structure of the second anode. 如申請專利範圍第1項所述之電鍍設備,其中該電解槽包括一側板,該側板具有一允許讓電鍍液進入該電解槽內的開口,且該立體式陽極組的底部與該電解槽之底板之間具有一距離。 The electroplating apparatus of claim 1, wherein the electrolysis cell comprises a side plate having an opening allowing the plating solution to enter the electrolysis cell, and the bottom of the stereo anode group and the electrolysis cell There is a distance between the bottom plates. 如申請專利範圍第1項所述之電鍍設備,其中該第一陽極具有相對之一第一表面與一第二表面,該第二表面相對該第一表面傾斜。 The electroplating apparatus of claim 1, wherein the first anode has a first surface opposite to the second surface, the second surface being inclined relative to the first surface. 如申請專利範圍第4項所述之電鍍設備,其中該第一陽極具有相對之一第一表面與一第二表面,該第一陽極以該第一表面配置在該第一載件上,該第二表面的中間區域相距該被鍍物放置區的距離短於該第二表面的邊緣區域相距該被鍍物放置區的距離。 The electroplating apparatus of claim 4, wherein the first anode has a first surface and a second surface, and the first anode is disposed on the first carrier with the first surface, The intermediate portion of the second surface is spaced from the object placement region by a distance that is shorter than the edge region of the second surface from the substrate placement region. 如申請專利範圍第1項所述之電鍍設備,更包括:一搖槳,與該立體式陽極組沿該第二方向排列,且包括:一連接件,沿該第三方向延伸;以及一擾動槳,連接於該連接件且沿該第一方向延伸,該擾動槳具有至少一蜂巢孔。 The electroplating apparatus of claim 1, further comprising: a paddle arranged in the second direction with the three-dimensional anode group, and comprising: a connecting member extending along the third direction; and a disturbance A paddle is coupled to the connector and extends along the first direction, the perturbation paddle having at least one honeycomb aperture.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103261491A (en) * 2010-12-23 2013-08-21 通用电气-日立核能美国有限责任公司 Modular anode assemblies and methods of using the same for electrochemical reduction

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103261491A (en) * 2010-12-23 2013-08-21 通用电气-日立核能美国有限责任公司 Modular anode assemblies and methods of using the same for electrochemical reduction

Cited By (2)

* Cited by examiner, † Cited by third party
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CN115537902A (en) * 2022-10-19 2022-12-30 厦门海辰新材料科技有限公司 Titanium net assembly and electroplating equipment
CN115537902B (en) * 2022-10-19 2023-12-22 厦门海辰新材料科技有限公司 Titanium net assembly and electroplating equipment

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