TWI610790B - Method for manufacturing microstructure transfer film and product thereof - Google Patents
Method for manufacturing microstructure transfer film and product thereof Download PDFInfo
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Description
本發明係有關一種微結構轉移膜之製造方法及其製品,尤指其製法可大幅縮減製程降低成本節省空間,而製品應用上基材層撕離後又能保持平整以供回收再利用者。 The invention relates to a method for manufacturing a microstructure transfer film and a product thereof, in particular to a method for greatly reducing the process, reducing the cost and saving space, and the substrate layer can be kept flat for recycling after the product is applied.
按,微結構膜,即表面具有雷射全像微結構紋路的蒸鍍薄膜,如貓眼、透鏡、全息、浮影等,其可利用光線干涉產生七彩顏色,圖案明顯色彩斑斕亮麗,虹光效果佳又兼具有防偽效果,被廣泛地應用在各種優質的精品包裝上使用。 According to the micro-structured film, that is, the vapor-deposited film with the laser-like holographic pattern on the surface, such as cat's eye, lens, hologram, floating shadow, etc., it can use the light interference to produce colorful colors, the pattern is obviously colorful and the rainbow effect It has anti-counterfeiting effect and is widely used in various high-quality boutique packaging.
常見的微結構膜可與纸張覆合後,再應用到高檔酒類的包裝盒上,但卻無法用於香煙包裝盒上,主要是礙於相關法律規定,香煙包裝盒上的微結構膜必須使用轉移紙,亦即要先做成轉移膜再轉移至紙張上。 The common microstructure film can be applied to the packaging of high-grade wine after it is covered with paper, but it cannot be used on the cigarette packaging box. The main reason is that the microstructure film on the cigarette packaging box must be Use transfer paper, that is, first transfer film and transfer to paper.
請參照第6圖所示,係傳統微結構轉移膜90的生產示意圖。製造時,先備好一卷基材層910,生產前端經由滾筒R1及儲料盤R2上的塗佈頭R3,在基材層910的一面塗佈上一可硬化樹脂轉移層920,即紫外線可硬化膠(UV膠),中間經過支持輪R4到達另邊的滾輪組R5,再使基材層910上的可硬化樹脂轉移 層920(UV膠)滾過一微結構版輪R6,同時用間隔設在對側的紫外線照射單元R7進行照射定形固化,讓可硬化樹脂轉移層920上形成一微結構面930,如第7圖所示,再於微結構面930上蒸鍍一金屬反射層940,並在金屬反射層940再設一熱熔膠層951,以方便後續轉移到紙盒4或紙張表面上應用。 Please refer to FIG. 6 for a schematic diagram of the production of the conventional microstructure transfer film 90. At the time of manufacture, a roll of the substrate layer 910 is prepared, and the front end of the substrate layer 910 is coated with a hardenable resin transfer layer 920, that is, ultraviolet rays, through the coating head R3 on the roll R1 and the stocker R2. The hardenable glue (UV glue) passes through the support wheel R4 to the other roller group R5, and then the hardenable resin on the substrate layer 910 is transferred. The layer 920 (UV glue) is rolled over a microstructured plate wheel R6, and is irradiated and shaped by the ultraviolet irradiation unit R7 disposed on the opposite side to form a microstructured surface 930 on the hardenable resin transfer layer 920, such as the seventh layer. As shown, a metal reflective layer 940 is deposited on the microstructured surface 930, and a hot melt adhesive layer 951 is placed over the metal reflective layer 940 to facilitate subsequent transfer to the carton 4 or paper surface.
惟可硬化樹脂轉移層920之UV膠材料成本相當昂貴,現約每公斤人民幣60元~100元,致使製造成本大幅增加。而且,當傳統微結構轉移膜90轉移至紙張上應用時,該基材層910一旦被撕離後,即會瞬間產生扭曲變皺,無法成卷回收再利用造成浪費,為其主要缺點。 However, the cost of the UV adhesive material of the hardened resin transfer layer 920 is quite expensive, and is now about RMB 60 to 100 per kilogram, resulting in a substantial increase in manufacturing costs. Moreover, when the conventional microstructure transfer film 90 is transferred to a paper application, once the base material layer 910 is torn off, the wrinkles and wrinkles are instantaneously generated, and the waste cannot be recovered by recycling and recycling, which is a major disadvantage.
為解決前述習知微結構轉移膜的生產製造物料成本過高及其產品應用上的缺點,本發明之主要目的,在提供一種微結構轉移膜之製造方法及其製品,其步驟包括:a.將不相容之兩種熱塑性聚合物原料經雙層共擠壓押出,由T形模頭擠出形成一雙層擠出物,一邊形成一基材層,另一邊依附一轉移層;b.經由一背壓輪與一表面設有微結構的版輪,使雙層擠出物擠壓成膜,並在該轉移層上形成一微結構面,以及;c.在微結構面上蒸鍍形成一金屬反射層,以製成微結構轉移膜; 較佳之實施,其中該步驟a.係將兩種不相容之熱塑性聚合物原料分別放進兩台押出機中,經熔融押出及分流器分流後形成兩層從一T形模頭擠出來,該b步驟之後,先經由一冷卻輪及一捲收輪,以冷卻捲收形成一複層半成品;再執行c步驟以鋁蒸鍍方式將金屬反射層形成於該微結構面上側;而本發明的製品一種微結構轉移膜,主要包括:一基材層、一轉移層、一微結構面、及一金屬反射層,其中該基材層及該轉移層為兩種不相容熱塑性聚合物,由雙層共擠壓押出所構成,該微結構面係以背壓輪與表面設有微結構的版輪擠壓而形成於轉移層上,以及;該金屬反射層係以蒸鍍形成在微結構面上。 In order to solve the disadvantages of the above-mentioned conventional microstructure transfer film production material cost and its application, the main object of the present invention is to provide a method for manufacturing a microstructure transfer film and a product thereof, the steps of which include: a. The incompatible two kinds of thermoplastic polymer raw materials are co-extruded by two layers, and are extruded from a T-die to form a double-layered extrudate, forming a substrate layer on one side and a transfer layer on the other side; b. Passing a back pressure roller and a plate with a microstructure on the surface to extrude the two-layer extrudate into a film, and forming a microstructured surface on the transfer layer; and c. evaporating on the microstructured surface Forming a metal reflective layer to form a microstructure transfer film; Preferably, in the step a. two incompatible thermoplastic polymer raw materials are placed in two extruders, and the two layers are formed by a melt extrusion and a splitter to be extruded from a T-die. After the step b, a multi-layer semi-finished product is formed by cooling and winding through a cooling wheel and a reeling wheel; and a metal reflective layer is formed on the surface of the microstructured surface by aluminum vapor deposition in a step c; A microstructure transfer film comprising: a substrate layer, a transfer layer, a microstructured surface, and a metal reflective layer, wherein the substrate layer and the transfer layer are two incompatible thermoplastic polymers, The double-layer co-extrusion extrusion is formed on the transfer layer by pressing the back pressure roller and the plate wheel having the microstructure on the surface, and the metal reflective layer is formed by evaporation. Structural surface.
藉此,使微結構轉移膜製造上更為簡單快速,可大幅降低成本縮減製程節省空間,應用上基材層撕離後又能保持平整以供回收再利用。 Thereby, the microstructure transfer film is made simpler and faster, and the cost reduction process can be greatly reduced, and the space can be kept flat for the recycling and reuse after the substrate layer is peeled off.
11‧‧‧押出機 11‧‧‧Exporting machine
12‧‧‧押出機 12‧‧‧Exporting machine
13‧‧‧T形模頭 13‧‧‧T-die
14‧‧‧背壓輪 14‧‧‧Back pressure wheel
15‧‧‧版輪 15‧‧‧ edition round
151‧‧‧微結構 151‧‧‧Microstructure
16‧‧‧冷卻輪 16‧‧‧Cooling wheel
17‧‧‧捲收輪 17‧‧‧Retraction round
20‧‧‧微結構轉移膜 20‧‧‧Microstructure Transfer Film
21‧‧‧基材層 21‧‧‧Substrate layer
210‧‧‧熱塑性聚合物 210‧‧‧ thermoplastic polymer
22‧‧‧轉移層 22‧‧‧Transfer layer
220‧‧‧熱塑性聚合物 220‧‧‧ thermoplastic polymer
23‧‧‧微結構面 23‧‧‧Microstructured surface
24‧‧‧金屬反射層 24‧‧‧Metal reflector
31‧‧‧熱熔膠層 31‧‧‧ hot melt adhesive layer
4‧‧‧紙盒 4‧‧‧carton
90‧‧‧微結構轉移膜 90‧‧‧Microstructure transfer film
910‧‧‧基材層 910‧‧‧Substrate layer
920‧‧‧轉移層 920‧‧‧Transfer layer
930‧‧‧微結構面 930‧‧‧Microstructured surface
940‧‧‧金屬反射層 940‧‧‧Metal reflector
951‧‧‧熱熔膠層 951‧‧‧hot melt adhesive layer
R1‧‧‧滾筒 R1‧‧‧Roller
R2‧‧‧儲料盤 R2‧‧‧ storage tray
R3‧‧‧塗佈頭 R3‧‧‧ coating head
R4‧‧‧支持輪 R4‧‧‧ support wheel
R5‧‧‧滾輪組 R5‧‧‧Roller set
R6‧‧‧微結構版輪 R6‧‧‧Microstructure wheel
R7‧‧‧紫外線照射單元 R7‧‧‧UV irradiation unit
S101、S102、S103‧‧‧步驟 S101, S102, S103‧‧‧ steps
第1圖為本發明微結構轉移膜製造方法之流程圖。 1 is a flow chart of a method for manufacturing a microstructure transfer film of the present invention.
第2圖為本發明微結構轉移膜製造方法之生產示意圖。 Fig. 2 is a schematic view showing the production of the microstructure transfer film of the present invention.
第3圖為本發明微結構轉移膜製品之剖面圖。 Figure 3 is a cross-sectional view of a microstructure transfer film article of the present invention.
第4圖為本發明微結構轉移膜製品之應用示意圖。 Figure 4 is a schematic view showing the application of the microstructure transfer film product of the present invention.
第5圖為本發明微結構轉移膜製品之應用剖面圖。 Figure 5 is a cross-sectional view showing the application of the microstructure transfer film article of the present invention.
第6圖為習知微結構轉移膜製造方法之生產示意圖。 Figure 6 is a schematic view showing the production of a conventional microstructure transfer film manufacturing method.
第7圖為習知微結構轉移膜製品之應用剖面圖。 Figure 7 is a cross-sectional view showing the application of a conventional microstructure transfer film product.
為使 貴審查委員能進一步瞭解本發明方法之組成、特徵及其達到之功效,茲附以圖式及較佳具體實施例之詳細說明如后。請參照第1~3圖所示,本發明微結構轉移膜20之製造方法,主要步驟包括:步驟S101 a.將不相容之兩種熱塑性聚合物210、220原料經雙層共擠壓押出,由T形模頭13擠出形成一雙層擠出物,一邊形成一基材層21,另一邊依附一轉移層22;步驟S102 b.經由一背壓輪14與一表面設有微結構151的版輪15,使雙層擠出物擠壓成膜,並在該轉移層22上形成一微結構面23,以及;步驟S103 c.在微結構面23上蒸鍍形成一金屬反射層24,以製成微結構轉移膜20;更具體而言,如第2圖所示,其中實施時步驟a.可將二種不相容之熱塑性聚合物210、220原料分別放進兩台押出機11、12中,經熔融押出及分流器分流後形成兩層從T形模頭13擠出來,使其遇版輪15而冷卻,因背壓輪14之擠壓而成膜,使一邊形成一基材層21,另一邊依附一轉移層22;且在轉移層22上形成微結構面23,該b步驟之後可先經由一冷卻輪16及一捲收 輪17,以冷卻捲收形成一複層半成品,但實際製造上並不以此為限,當然也可採用其他的冷卻或捲收方式來達成。再執行c步驟;再透過蒸鍍機(圖未示出)於轉移層22的微結構面23上蒸鍍該金屬反射層24,通常為一鋁金屬薄膜,即如第3圖所示,形成一微結構轉移模20。 In order to provide a further understanding of the composition, features, and effects of the methods of the present invention, the detailed description of the drawings and the preferred embodiments are set forth below. Referring to Figures 1-3, the method for manufacturing the microstructure transfer film 20 of the present invention comprises the following steps: Step S101 a. Extrusion of two incompatible thermoplastic polymers 210 and 220 by double-layer coextrusion Extrusion from the T-die 13 to form a two-layer extrudate, forming a substrate layer 21 while the other side is attached to a transfer layer 22; Step S102 b. Providing a microstructure through a back pressure wheel 14 and a surface a plate wheel 15 of 151, extruding the two-layer extrudate into a film, and forming a microstructured surface 23 on the transfer layer 22; and step S103 c. depositing a metal reflective layer on the microstructured surface 23 24, to make the microstructure transfer film 20; more specifically, as shown in Figure 2, wherein the steps a. can be carried out two kinds of incompatible thermoplastic polymer 210, 220 raw materials into two In the machines 11, 12, two layers are formed by the melt extrusion and the splitter are extruded from the T-die 13 to be cooled by the plate wheel 15, and the film is formed by the extrusion of the back pressure wheel 14, so that one side is formed. a substrate layer 21, the other side is attached to a transfer layer 22; and a microstructured surface 23 is formed on the transfer layer 22, and the b step may be followed by Cooling wheel 16 and a roll The wheel 17 is formed by cooling and winding to form a multi-layer semi-finished product, but the actual manufacturing is not limited thereto, and of course, other cooling or winding methods can be used. Step c is further performed; and the metal reflective layer 24 is deposited on the microstructured surface 23 of the transfer layer 22 through an evaporation machine (not shown), usually an aluminum metal film, as shown in FIG. A microstructure transfer mold 20.
藉此,使微結構轉移膜20製造上更為簡單快速,可大幅降低成本縮減製程節省空間。 Thereby, the microstructure transfer film 20 is made simpler and faster to manufacture, and the cost reduction process can be greatly reduced to save space.
如第3圖所示,依本發明方法所生產製成的微結構轉移膜20,主要包括:基材層21、轉移層22、微結構面23、及金屬反射層24,其中該基材層21及該轉移層22為兩種不相容熱塑性聚合物210、220,由雙層共擠壓押出所構成,該微結構面23係以背壓輪14與表面設有微結構151的版輪15擠壓而形成於轉移層22上,以及;該金屬反射層24係以蒸鍍形成在微結構面23上。 As shown in FIG. 3, the microstructure transfer film 20 produced by the method of the present invention mainly comprises: a substrate layer 21, a transfer layer 22, a microstructured surface 23, and a metal reflective layer 24, wherein the substrate layer 21 and the transfer layer 22 are two incompatible thermoplastic polymers 210, 220 which are formed by two-layer co-extrusion extrusion, the microstructured surface 23 being a counter wheel 14 and a plate with a microstructure 151 on its surface. 15 is formed by extrusion on the transfer layer 22, and the metal reflective layer 24 is formed on the microstructured surface 23 by evaporation.
組成之微結構轉移膜20,該轉移層22係位於該基材層21之上側,該微結構面23係以壓花方式形成於該轉移層22之上。該金屬反射層24係以蒸鍍方式形成於該微結構面23之上。其中,金屬反射層24之蒸鍍材料例如但不限於為鋁。 The microstructure transfer film 20 is composed of the transfer layer 22 on the upper side of the substrate layer 21, and the microstructure surface 23 is formed on the transfer layer 22 by embossing. The metal reflective layer 24 is formed on the microstructured surface 23 by vapor deposition. The vapor deposition material of the metal reflective layer 24 is, for example but not limited to, aluminum.
如第2圖所示,而該轉移層22所採用的熱塑性聚合物220,例如但不限於為聚乙烯、聚丙烯、聚乙烯之共聚物、聚丙烯之共聚物或含有聚乙烯、聚丙烯之混合物,其成本每公斤約人民幣10元~20元,相較於上述習知製品之UV膠轉移層每公 斤約人民幣60元~100元,確實可達到大幅降低該微結構轉移膜20之製造成本。 As shown in FIG. 2, the thermoplastic polymer 220 used in the transfer layer 22 is, for example but not limited to, a copolymer of polyethylene, polypropylene, polyethylene, a copolymer of polypropylene, or a polyethylene or polypropylene. The cost of the mixture is about RMB 10 to RMB 20 per kg, compared to the UV adhesive transfer layer of the above-mentioned conventional products. Approximately RMB 60 to 100 yuan, it is indeed possible to achieve a significant reduction in the manufacturing cost of the microstructure transfer film 20.
較佳實施,其中該含有聚乙烯、聚丙烯之混合物之含量例如但不限於為高於50%,且該含有聚乙烯、聚丙烯之混合物中進一步包括微量添加物,該微量添加物例如但不限於為滑劑或爽滑劑。 Preferably, the content of the mixture containing polyethylene and polypropylene is, for example but not limited to, more than 50%, and the mixture containing polyethylene and polypropylene further includes a trace additive, such as but not Limited to slip or slip agent.
譬如:其中若轉移層22為聚丙烯(PP),則基材層21可選用與聚丙烯(PP)不相容之熱塑性聚合物210,因而在成膜後轉移層22與基材層21間彼此不會相粘,僅呈暫時貼合狀態,只要施以適當外力即可令其快速分開。 For example, if the transfer layer 22 is polypropylene (PP), the base material layer 21 may be selected from a thermoplastic polymer 210 which is incompatible with polypropylene (PP), and thus between the transfer layer 22 and the substrate layer 21 after film formation. They are not sticky to each other, only in a temporary fit state, and they can be quickly separated by applying an appropriate external force.
較佳實施,當轉移層22為聚丙烯(PP)或聚乙烯(PE)時,基材層21可為聚丁烯對苯二甲酸酯(PBT)、聚甲醛樹酯(POM)、超交聯聚合物(HCPs)、聚乙烯對苯二甲酸酯(PET)、聚碳酸酯(PC)、及聚醯胺(PA、尼龍)等其中一種所構成。 Preferably, when the transfer layer 22 is polypropylene (PP) or polyethylene (PE), the substrate layer 21 may be polybutylene terephthalate (PBT), polyoxymethylene resin (POM), super It is composed of one of crosslinked polymers (HCPs), polyethylene terephthalate (PET), polycarbonate (PC), and polyamine (PA, nylon).
請參第2~5圖所示,本發明方法之製品微結構轉移模20,因其轉移層22與基材層21為不相容之兩種熱塑性聚合物210、220所製成,其彼此間不會相粘,僅呈暫時貼合狀態,只要施以適當外力即可令其快速分開。實際應用其金屬反射層24上設一熱熔膠層31,當轉移貼到紙盒4面上時,其基材層21撕離後,整個基材層21仍能保持平整以供回收再利用,是本發明最大的特色。所提供之微結構轉移模20製造方法及其製品確實具有進步性,能成功有效克服習知製法及其成品應用上的缺點。 Referring to Figures 2 to 5, the article microstructure transfer mold 20 of the method of the present invention is made of two thermoplastic polymers 210, 220 whose transfer layer 22 is incompatible with the substrate layer 21, and which are mutually It will not be sticky, only in a temporary fit, and it can be quickly separated by applying an appropriate external force. A hot melt adhesive layer 31 is disposed on the metal reflective layer 24 of the actual application. When the substrate layer 21 is peeled off, the entire substrate layer 21 can be kept flat for recycling and reuse. Is the biggest feature of the invention. The manufacturing method and the article for manufacturing the microstructure transfer die 20 are indeed advanced, and can successfully overcome the shortcomings of the conventional manufacturing method and its finished product application.
綜上所述,本發明新穎實用與習知技術相較又具有明顯的進步,同時也具可供產業利用性,完全符合專利要件,爰提出發明專利申請。惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍;故,凡依本發明申請專利範圍及創作說明書內容所作之等效變化與修飾,皆應仍屬本發明專利涵蓋之範圍內。 In summary, the novel utility of the present invention has significant progress compared with the prior art, and at the same time, it has industrial availability, fully conforms to the patent requirements, and proposes an invention patent application. The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto; therefore, the equivalent changes and modifications made by the scope of the patent application and the content of the present invention are all It should remain within the scope of this invention.
11‧‧‧押出機 11‧‧‧Exporting machine
12‧‧‧押出機 12‧‧‧Exporting machine
13‧‧‧T形模頭 13‧‧‧T-die
14‧‧‧背壓輪 14‧‧‧Back pressure wheel
15‧‧‧版輪 15‧‧‧ edition round
151‧‧‧微結構 151‧‧‧Microstructure
16‧‧‧冷卻輪 16‧‧‧Cooling wheel
17‧‧‧捲收輪 17‧‧‧Retraction round
20‧‧‧微結構轉移膜 20‧‧‧Microstructure Transfer Film
21‧‧‧基材層 21‧‧‧Substrate layer
210‧‧‧熱塑性聚合物 210‧‧‧ thermoplastic polymer
22‧‧‧轉移層 22‧‧‧Transfer layer
220‧‧‧熱塑性聚合物 220‧‧‧ thermoplastic polymer
23‧‧‧微結構面 23‧‧‧Microstructured surface
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TW105139183A TWI610790B (en) | 2016-11-29 | 2016-11-29 | Method for manufacturing microstructure transfer film and product thereof |
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TW105139183A TWI610790B (en) | 2016-11-29 | 2016-11-29 | Method for manufacturing microstructure transfer film and product thereof |
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TWI610790B true TWI610790B (en) | 2018-01-11 |
TW201819150A TW201819150A (en) | 2018-06-01 |
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Citations (1)
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TW201425025A (en) * | 2012-08-06 | 2014-07-01 | Teijin Ltd | Multilayer film, film for decorative molding, and molded body |
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Patent Citations (1)
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TW201425025A (en) * | 2012-08-06 | 2014-07-01 | Teijin Ltd | Multilayer film, film for decorative molding, and molded body |
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TW201819150A (en) | 2018-06-01 |
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