TWI577055B - Wavelength converting film and manufacturing method thereof - Google Patents

Wavelength converting film and manufacturing method thereof Download PDF

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TWI577055B
TWI577055B TW104114838A TW104114838A TWI577055B TW I577055 B TWI577055 B TW I577055B TW 104114838 A TW104114838 A TW 104114838A TW 104114838 A TW104114838 A TW 104114838A TW I577055 B TWI577055 B TW I577055B
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wavelength conversion
conversion layer
layer
film
fabricating
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TW104114838A
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TW201620160A (en
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李允立
蘇柏仁
麥軒偉
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錼創科技股份有限公司
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Description

波長轉換膜及其製作方法 Wavelength conversion film and manufacturing method thereof

本發明是有關於一種波長轉換結構,且特別是有關於一種波長轉換膜及其製作方法。 The present invention relates to a wavelength conversion structure, and more particularly to a wavelength conversion film and a method of fabricating the same.

習知的發光二極體晶片的封裝方法,通常是透過點膠的方式使封裝膠體(如AB膠)直接密封發光二極體晶片,其中封裝膠體中亦會填加螢光顆粒來改變發光二極體晶片的出光顏色。然而,上述的點膠方式無法一次完成多個發光二極體晶片的封裝體,造成製作時間和製作成本的花費。 The conventional method for packaging a light-emitting diode chip is generally to directly seal a light-emitting diode chip by means of dispensing, such as an AB glue, wherein the packaged colloid is also filled with fluorescent particles to change the light-emitting diode. The color of the exit of the polar body wafer. However, the above-described dispensing method cannot complete the package of a plurality of light-emitting diode wafers at one time, resulting in production time and manufacturing cost.

此外,封裝膠體的固含量低,在未進行固化前,封裝膠體內的螢光顆粒也容易受到重力影響,而產生沉澱現象,造成封裝膠體內的螢光顆粒分布不均,如此一來,將使得封裝後的發光二極體封裝體產生出光及色溫不均的現象。 In addition, the solid content of the encapsulant is low, and the fluorescent particles in the encapsulant are also susceptible to gravity before the curing, and the precipitation phenomenon occurs, resulting in uneven distribution of the fluorescent particles in the encapsulant, so that The packaged LED package produces a phenomenon of uneven light and color temperature.

本發明提供一種波長轉換膜及其製作方法,其可以改善習知螢光顆粒於封裝膠體內的沉降問題,且有較佳的發光二極體元件製作效率。 The invention provides a wavelength conversion film and a manufacturing method thereof, which can improve the settlement problem of the conventional fluorescent particles in the encapsulant, and has better manufacturing efficiency of the LED component.

本發明提供一種波長轉換膜的製作方法,其包括以下步驟。提供一離型膜。進行至少一塗佈製程,以於離型膜上形成至少一波長轉換層,其中至少一波長轉換層與離型膜的一第一接觸面具有一第一粗糙度。形成一黏著層於最遠離離型膜的波長轉換層的一表面上,其中黏著層與波長轉換層的一第二接觸面具有一第二粗糙度,且第二粗糙度大於第一粗糙度。 The present invention provides a method of fabricating a wavelength conversion film comprising the following steps. A release film is provided. Performing at least one coating process to form at least one wavelength conversion layer on the release film, wherein at least one of the wavelength conversion layer and a first contact mask of the release film has a first roughness. Forming an adhesive layer on a surface of the wavelength conversion layer farthest from the release film, wherein the second contact mask of the adhesive layer and the wavelength conversion layer has a second roughness, and the second roughness is greater than the first roughness.

在本發明的一實施例中,上述至少一波長轉換層的厚度為黏著層的厚度的1~3倍。 In an embodiment of the invention, the thickness of the at least one wavelength conversion layer is 1 to 3 times the thickness of the adhesive layer.

在本發明的一實施例中,上述至少一波長轉換層包括一波長轉換物質以及一膠體,且至少一波長轉換層以100%的組成成分總百分比計算,波長轉換物質的重量百分比為60%~95%。 In an embodiment of the invention, the at least one wavelength conversion layer comprises a wavelength conversion substance and a colloid, and the at least one wavelength conversion layer is calculated by a total percentage of 100% of the composition, and the weight percentage of the wavelength conversion substance is 60%~ 95%.

在本發明的一實施例中,上述每一波長轉換層的厚度介於波長轉換物質的平均粒徑之1.2~3倍。 In an embodiment of the invention, the thickness of each of the wavelength conversion layers is between 1.2 and 3 times the average particle diameter of the wavelength converting substance.

在本發明的一實施例中,上述於形成黏著層之後,更包括:進行一脫膜製程,以分離離型膜與至少一波長轉換層。 In an embodiment of the invention, after the forming the adhesive layer, the method further comprises: performing a stripping process to separate the release film and the at least one wavelength conversion layer.

在本發明的一實施例中,上述的黏著層內摻雜有多個擴散粒子、反射粒子、散射粒子或上述至少其中之二。 In an embodiment of the invention, the adhesive layer is doped with a plurality of diffusion particles, reflective particles, scattering particles or at least two of the above.

在本發明的一實施例中,上述的至少一波長轉換層包括 一第一波長轉換層與一第二波長轉換層。第一波長轉換層配置於離型膜與第二波長轉換層之間。 In an embodiment of the invention, the at least one wavelength conversion layer includes a first wavelength conversion layer and a second wavelength conversion layer. The first wavelength conversion layer is disposed between the release film and the second wavelength conversion layer.

在本發明的一實施例中,上述的第一波長轉換層的放射主波峰波長小於第二波長轉換層的放射主波峰波長。 In an embodiment of the invention, the radiation main peak wavelength of the first wavelength conversion layer is smaller than the radiation main peak wavelength of the second wavelength conversion layer.

在本發明的一實施例中,上述的第二波長轉換層的波形半高寬小於第一波長轉換層的波形半高寬。 In an embodiment of the invention, the waveform half-height width of the second wavelength conversion layer is smaller than the waveform half-width of the first wavelength conversion layer.

在本發明的一實施例中,上述的第一波長轉換層的厚度大於第二波長轉換層的厚度。 In an embodiment of the invention, the thickness of the first wavelength conversion layer is greater than the thickness of the second wavelength conversion layer.

在本發明的一實施例中,上述的至少一塗佈製程為一旋轉塗佈製程。 In an embodiment of the invention, the at least one coating process is a spin coating process.

在本發明的一實施例中,上述的至少一波長轉換層包括一波長轉換物質以及一膠體,其中波長轉換物質分散於膠體內。至少一波長轉換層具有一第一區域以及一第二區域。第一區域內的波長轉換物質濃度大於第二區域內的波長轉換物質濃度,且第二區域環繞第一區域。 In an embodiment of the invention, the at least one wavelength conversion layer comprises a wavelength converting substance and a colloid, wherein the wavelength converting substance is dispersed in the colloid. The at least one wavelength conversion layer has a first area and a second area. The concentration of the wavelength converting substance in the first region is greater than the concentration of the wavelength converting substance in the second region, and the second region surrounds the first region.

本發明提供一波長轉換膜的製作方法,用於搭載至少一發光晶圓。波長轉換膜的製作方法包括以下製程步驟。提供一離型膜。進行至少一塗佈製程,以於離型膜上形成至少一波長轉換層,其中至少一波長轉換層與離型膜的一第一接觸面具有一第一粗糙度。形成一黏著層於最遠離離型膜的波長轉換層的一表面上,其中黏著層與該波長轉換層的一第二接觸面具有一第二粗糙度,且第二粗糙度大於第一粗糙度,而黏著層連接於至少一發光 晶圓。 The invention provides a method for fabricating a wavelength conversion film for mounting at least one luminescent wafer. The method of fabricating the wavelength conversion film includes the following process steps. A release film is provided. Performing at least one coating process to form at least one wavelength conversion layer on the release film, wherein at least one of the wavelength conversion layer and a first contact mask of the release film has a first roughness. Forming an adhesive layer on a surface of the wavelength conversion layer farthest from the release film, wherein the adhesion layer and a second contact mask of the wavelength conversion layer have a second roughness, and the second roughness is greater than the first roughness And the adhesive layer is connected to at least one of the light Wafer.

本發明提供一波長轉換膜,用於搭載一發光晶圓。波長轉換膜包括一波長轉換層以及一黏著層。波長轉換層具有彼此相對的一第一表面與一第二表面,其中第一表面具有一第一粗糙度。黏著層連接波長轉換層的第二表面,且配置於波長轉換層與發光晶圓之間,其中黏著層與波長轉換層的一接觸面具有一第二粗糙度,且第二粗糙度大於第一粗糙度。 The present invention provides a wavelength conversion film for mounting a light-emitting wafer. The wavelength conversion film includes a wavelength conversion layer and an adhesive layer. The wavelength conversion layer has a first surface and a second surface opposite to each other, wherein the first surface has a first roughness. The adhesive layer is connected to the second surface of the wavelength conversion layer, and is disposed between the wavelength conversion layer and the light emitting wafer, wherein a contact mask of the adhesive layer and the wavelength conversion layer has a second roughness, and the second roughness is greater than the first Roughness.

在本發明的一實施例中,上述波長轉換層的硬度範圍為蕭氏硬度(Shore Durometer hardness)30D至90D。 In an embodiment of the invention, the hardness of the wavelength conversion layer ranges from Shore Dometer hardness 30D to 90D.

基於上述,由於本發明的波長轉換膜的製作方法是在離型膜上透過塗佈製程來形成波長轉換層,且於最遠離離型膜的波長轉換層的表面上形成黏著層。因此,相較於習知透過點膠的方式來形成發光二極體封裝體而言,本發明的波長轉換膜的製作方法除了具有製程容易,後續應用於發光晶圓上能一次大量製作發光元件,因而適於量產的優勢之外,亦可避免習知螢光顆粒於封裝膠體內的沉降問題而具有較佳的產品可靠度。此外,此波長轉換膜的製作方法所形成的波長轉換層也可具有較薄的厚度,可以較節省波長轉換層的成本。 Based on the above, since the wavelength conversion film of the present invention is produced by a coating process on a release film to form a wavelength conversion layer, and an adhesion layer is formed on the surface of the wavelength conversion layer farthest from the release film. Therefore, compared with the conventional method of forming a light-emitting diode package by means of dispensing, the method for fabricating the wavelength conversion film of the present invention has a process which is easy to process, and can be subsequently applied to a light-emitting wafer to mass-produce a light-emitting element at a time. Therefore, in addition to the advantages of mass production, it is also possible to avoid the problem of settlement of the conventional fluorescent particles in the encapsulant and have better product reliability. In addition, the wavelength conversion layer formed by the method for fabricating the wavelength conversion film can also have a thin thickness, which can save the cost of the wavelength conversion layer.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。 The above described features and advantages of the invention will be apparent from the following description.

100、100’、100a、100b、100c、100d、100e、100f、100g、100h‧‧‧波長轉換膜 100, 100', 100a, 100b, 100c, 100d, 100e, 100f, 100g, 100h‧ ‧ wavelength conversion film

110‧‧‧離型膜 110‧‧‧ release film

121‧‧‧膠體 121‧‧‧colloid

122、122c、122d、122e、122f、124、124c、124d、124e、126、126c‧‧‧波長轉換層 122, 122c, 122d, 122e, 122f, 124, 124c, 124d, 124e, 126, 126c‧‧‧ wavelength conversion layer

123‧‧‧波長轉換物質 123‧‧‧ wavelength conversion substances

130、130a‧‧‧黏著層 130, 130a‧‧‧ adhesive layer

132‧‧‧擴散粒子 132‧‧‧Diffusion particles

142、144‧‧‧黏著層 142, 144‧‧‧ adhesive layer

F1‧‧‧波長轉換物質 F1‧‧‧wavelength converting substance

F2‧‧‧膠體 F2‧‧‧ colloid

R1‧‧‧第一區域 R1‧‧‧ first area

R2‧‧‧第二區域 R2‧‧‧ second area

S‧‧‧表面 S‧‧‧ surface

S1‧‧‧第一接觸面 S1‧‧‧ first contact surface

S2‧‧‧第二接觸面 S2‧‧‧Second contact surface

W、W’‧‧‧發光晶圓 W, W’‧‧‧ luminescent wafer

圖1A至圖1C繪示為本發明的一實施例的一種波長轉換膜的製作方法的局部步驟的剖面示意圖。 1A-1C are schematic cross-sectional views showing a partial step of a method for fabricating a wavelength conversion film according to an embodiment of the invention.

圖1D繪示為本發明的一實施例的一種波長轉換膜的剖面示意圖。 FIG. 1D is a schematic cross-sectional view of a wavelength conversion film according to an embodiment of the invention.

圖2繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 2 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖3繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 3 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖4繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 4 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖5繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 FIG. 5 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖6繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 6 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖7繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。 FIG. 7 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention.

圖8(a)繪示為本發明的一實施例的一種波長轉換膜用於搭載一發光晶圓的剖面示意圖。 FIG. 8(a) is a cross-sectional view showing a wavelength conversion film for mounting a light-emitting wafer according to an embodiment of the invention.

圖8(b)繪示為本發明的一實施例的一種波長轉換膜用於搭載一發光晶圓的俯視示意圖。 FIG. 8(b) is a top plan view showing a wavelength conversion film for mounting a light-emitting wafer according to an embodiment of the invention.

圖8(c)繪示為本發明的另一實施例的一種波長轉換膜用於搭載多個發光晶圓的俯視示意圖。 FIG. 8(c) is a top plan view showing a wavelength conversion film for mounting a plurality of light-emitting wafers according to another embodiment of the present invention.

圖1A至圖1C繪示為本發明的一實施例的一種波長轉換膜的製作方法的局部步驟的剖面示意圖。請先參考圖1A,提供一離型膜110,其中離型膜110的材料可以是一透明材料,例如是環氧樹脂、聚乙烯對苯二甲酸酯、矽膠、聚氨酯、聚丙烯或二氧化矽。 1A-1C are schematic cross-sectional views showing a partial step of a method for fabricating a wavelength conversion film according to an embodiment of the invention. Referring first to FIG. 1A, a release film 110 is provided, wherein the material of the release film 110 may be a transparent material such as epoxy resin, polyethylene terephthalate, silicone, polyurethane, polypropylene or dioxide. Hey.

接著,請參考圖1B,進行至少一塗佈製程,以於離型膜110上形成至少一波長轉換層,其中至少一波長轉換層與離型膜110的一第一接觸面S1具有一第一粗糙度。此處的塗佈製程例如是刮刀塗佈製程、精密刀塗佈製程、推料塗佈製程、線棒塗佈製程、網印塗佈製程、旋轉塗佈製程或凹印塗佈製程,將一波長轉換物質F1與一膠體F2混合後得到一波長轉換膠體(未繪示),將波長轉換膠體置於離型膜110上,再以塗佈製程使波長轉換膠體形成一均勻的波長轉換層。此時,波長轉換層覆蓋離型膜110。其中,塗佈製程較佳為刮刀塗佈製程或精密刀塗佈製程,可具有較簡易實施的優點。 Next, referring to FIG. 1B, at least one coating process is performed to form at least one wavelength conversion layer on the release film 110, wherein at least one of the wavelength conversion layer and a first contact surface S1 of the release film 110 has a first Roughness. The coating process here is, for example, a doctor blade coating process, a precision knife coating process, a push coating process, a wire bar coating process, a screen printing process, a spin coating process or a gravure coating process, The wavelength conversion substance F1 is mixed with a colloid F2 to obtain a wavelength conversion colloid (not shown). The wavelength conversion colloid is placed on the release film 110, and the wavelength conversion colloid is formed into a uniform wavelength conversion layer by a coating process. At this time, the wavelength conversion layer covers the release film 110. Among them, the coating process is preferably a doctor blade coating process or a precision knife coating process, which has the advantages of simple implementation.

詳細來說,在本實施例中,例如是進行三次的塗佈製程,而形成依序堆疊的三層波長轉換層122、124、126,但並不以此為限,其中波長轉換層122配置於波長轉換層124與離型膜110之間。每一波長轉換層122(或124、126)包括一波長轉換物質F1以及一膠體F2,波長轉換層122(或124、126)以100%的組成成分總百分比計算,波長轉換物質F1的重量百分比為60%~95%,其中 較高濃度的波長轉換物質F1的配比,可提高波長轉換層122(或124、126)中的膠體F2的固含量,進而可降低膠體F2的流動性,藉此較容易將膠體F2定量地配置於離型膜110上,以便控制每一波長轉換層122(或124、126)的厚度。較佳的,波長轉換層122(或124、126)的厚度介於波長轉換物質F1的平均粒徑之1.2~3倍,可使得完成後的波長轉換膜100具有較薄的厚度,亦可使波長轉換時產生的熱不易蓄積於波長轉換層122(或124、126)內。再者,波長轉換層122(或124、126)的硬度範圍為蕭氏硬度(Shore Durometer Hardness)30D至90D,相較習知大多皆為蕭氏硬度A(Shore A)的封裝材料,本發明的波長轉換膜100可具有較佳的耐裂性和信賴性。在本實施例中,所形成的波長轉換層122、124、126的延伸方向與離型層110的延伸方向相同。也就是說,所形成的波長轉換層122、124、126具體化為平面結構。較佳地,每一波長轉換層122(或124、126)的厚度介於15微米至80微米之間,更佳地,每一波長轉換層122(或124、126)的厚度小於60微米,此處,波長轉換層122、124、126的厚度繪示為相同,但於其他實施例中,波長轉換層122、124、126的厚度亦可不同,於此並不加以限制。 In detail, in this embodiment, for example, the coating process is performed three times, and the three layers of wavelength conversion layers 122, 124, and 126 are sequentially stacked, but not limited thereto, wherein the wavelength conversion layer 122 is configured. Between the wavelength conversion layer 124 and the release film 110. Each wavelength conversion layer 122 (or 124, 126) includes a wavelength converting substance F1 and a colloid F2. The wavelength converting layer 122 (or 124, 126) is calculated as a total percentage of 100% of the composition, and the weight percentage of the wavelength converting substance F1. 60% to 95%, of which The ratio of the higher concentration of the wavelength converting substance F1 can increase the solid content of the colloid F2 in the wavelength conversion layer 122 (or 124, 126), thereby reducing the fluidity of the colloid F2, thereby making it easier to quantitatively colloid F2 It is disposed on the release film 110 to control the thickness of each of the wavelength conversion layers 122 (or 124, 126). Preferably, the thickness of the wavelength conversion layer 122 (or 124, 126) is 1.2 to 3 times the average particle diameter of the wavelength converting substance F1, so that the wavelength conversion film 100 after completion has a thin thickness, and The heat generated at the time of wavelength conversion is less likely to accumulate in the wavelength conversion layer 122 (or 124, 126). Moreover, the hardness range of the wavelength conversion layer 122 (or 124, 126) is Shore Durometer Hardness 30D to 90D, compared to the packaging material which is mostly known as Shore A, the present invention. The wavelength conversion film 100 can have better crack resistance and reliability. In the present embodiment, the extending direction of the formed wavelength conversion layers 122, 124, 126 is the same as the extending direction of the release layer 110. That is, the formed wavelength conversion layers 122, 124, 126 are embodied as planar structures. Preferably, each wavelength conversion layer 122 (or 124, 126) has a thickness between 15 microns and 80 microns, and more preferably each wavelength conversion layer 122 (or 124, 126) has a thickness less than 60 microns. The thickness of the wavelength conversion layers 122, 124, and 126 are the same, but in other embodiments, the thickness of the wavelength conversion layers 122, 124, and 126 may be different, and are not limited herein.

最後,請參考圖1C,形成一黏著層130於最遠離離型膜110的波長轉換層126的一表面S上,其中黏著層130與波長轉換層126的一第二接觸面S2具有一第二粗糙度,且第二粗糙度大於第一粗糙度。此處,黏著層130的厚度例如是介於5微米至35微 米之間,較佳的,黏著層130的厚度小於20微米。其中,黏著層130覆蓋波長轉換層126的表面S,換言之,本實施例的波長轉換層122、124、126是位於離型膜110與黏著層130之間。至此,已完成波長轉換膜100的製作。需說明的是,離型膜110設置的目的在於保護波長轉換層122的表面且讓波長轉換層122可形成一平面結構,黏著層130設置的目的在於使波長轉換膜100可整面貼附於發光晶圓(未繪示)上,來增加波長轉換膜100的應用。特別的是,黏著層130可利用形成波長轉換層122、124、126的塗佈製程而形成,使得每一波長轉換層122、124、126的厚度與黏著層130的厚度約略相同。較佳的,每一波長轉換層122、124、126的厚度為黏著層130的厚度的1~3倍,可使得波長轉換膜100具有更均勻的厚度和較小的體積。 Finally, referring to FIG. 1C, an adhesive layer 130 is formed on a surface S of the wavelength conversion layer 126 farthest from the release film 110, wherein the adhesion layer 130 and a second contact surface S2 of the wavelength conversion layer 126 have a second surface. Roughness, and the second roughness is greater than the first roughness. Here, the thickness of the adhesive layer 130 is, for example, 5 micrometers to 35 micrometers. Preferably, the thickness of the adhesive layer 130 is less than 20 microns. The adhesive layer 130 covers the surface S of the wavelength conversion layer 126. In other words, the wavelength conversion layers 122, 124, and 126 of the present embodiment are located between the release film 110 and the adhesive layer 130. So far, the fabrication of the wavelength conversion film 100 has been completed. It should be noted that the release film 110 is disposed to protect the surface of the wavelength conversion layer 122 and allows the wavelength conversion layer 122 to form a planar structure. The adhesive layer 130 is disposed to allow the wavelength conversion film 100 to be attached to the entire surface. The luminescent wafer (not shown) is used to increase the application of the wavelength conversion film 100. In particular, the adhesion layer 130 may be formed using a coating process that forms the wavelength conversion layers 122, 124, 126 such that the thickness of each of the wavelength conversion layers 122, 124, 126 is approximately the same as the thickness of the adhesion layer 130. Preferably, each of the wavelength conversion layers 122, 124, 126 has a thickness of 1 to 3 times the thickness of the adhesive layer 130, so that the wavelength conversion film 100 has a more uniform thickness and a small volume.

由於本實施例的波長轉換膜100的製作是在離型膜110上透過塗佈製程來形成波長轉換層122、124、126,且於最遠離離型膜110的波長轉換層126的表面S上形成黏著層130。因此,相較於習知透過點膠的方式來形成密封發光二極體的封裝膠體而言,本實施例的波長轉換膜100的製作方法除了具有製作容易且適於量產的優勢之外,亦可避免習知螢光顆粒於封裝膠體內的沉降問題而具有較佳的產品可靠度。再者,於後續的應用上可直接將此波長轉換膜100透過其黏著層130而貼附於發光晶圓(未繪示)上,一次完成多個發光元件(未繪示)的製作,可具有較佳的使用便利性。此外,此波長轉換膜100的製作方法所形成的波 長轉換層122、124、126具體化為平面結構,因而使得波長轉換膜100可具有較薄的厚度,於發光元件(未繪示)上將具有較小的體積,且可以較節省波長轉換膜的成本。 Since the wavelength conversion film 100 of the present embodiment is formed by performing a coating process on the release film 110 to form the wavelength conversion layers 122, 124, 126, and on the surface S of the wavelength conversion layer 126 farthest from the release film 110. An adhesive layer 130 is formed. Therefore, the method for fabricating the wavelength conversion film 100 of the present embodiment has the advantages of being easy to manufacture and suitable for mass production, as compared with the conventional method of forming a sealing colloid for sealing a light-emitting diode by means of dispensing. It is also possible to avoid the problem of settlement of the conventional fluorescent particles in the encapsulant and have better product reliability. Furthermore, in the subsequent application, the wavelength conversion film 100 can be directly attached to the light-emitting wafer (not shown) through the adhesive layer 130, and the plurality of light-emitting elements (not shown) can be fabricated at one time. It has better ease of use. In addition, the wave formed by the method of fabricating the wavelength conversion film 100 The long conversion layer 122, 124, 126 is embodied as a planar structure, so that the wavelength conversion film 100 can have a thinner thickness, will have a smaller volume on a light-emitting element (not shown), and can save a wavelength conversion film. the cost of.

再者,本實施例的波長轉換層122、124、126具有薄形(波長轉換物質F1的平均粒徑的1.2~3倍)、高濃度(波長轉換物質F1的重量百分比為60%~95%)以及高硬度(蕭氏硬度30D~90D)的優勢,可使得本實施例的波長轉換膜100同時達成輕薄化及保護其黏貼之元件(如發光元件,未繪示)的功效。此外,由於本實施例的離型膜110很平滑,當塗佈製程於離型膜110上形成波長轉換層122時,波長轉換層122中的膠體F2會填滿波長轉換物質F1和離型膜110之間的空隙,故波長轉換層122和離型膜110的第一接觸面S1的粗糙度很低。而,波長轉換層126中的波長轉換物質F1的顆粒大(如介於15~30微米)且濃度很高,所以波長轉換層126的表面S的粗糙度比較高且與黏著層130之間的黏附力也較大。故,波長轉換層126與黏著層130的第二接觸面S2的第二粗糙度大於波長轉換層122與離型膜110的第一接觸面S1的第一粗糙度。由於第二粗糙度大於第一粗糙度,透過黏著層130黏貼於後續應用的發光晶圓(未繪示)上時,可使光線易於從黏著層130進入波長轉換層122、124、126,而使光線能充分於波長轉換層122、124、126進行波長轉換後再出光。 Furthermore, the wavelength conversion layers 122, 124, and 126 of the present embodiment have a thin shape (1.2 to 3 times the average particle diameter of the wavelength conversion substance F1) and a high concentration (the weight percentage of the wavelength conversion substance F1 is 60% to 95%). And the high hardness (Shore hardness 30D~90D), the wavelength conversion film 100 of the present embodiment can simultaneously achieve the effect of thinning and protecting the components (such as light-emitting elements, not shown) which are adhered thereto. In addition, since the release film 110 of the present embodiment is very smooth, when the coating process forms the wavelength conversion layer 122 on the release film 110, the colloid F2 in the wavelength conversion layer 122 is filled with the wavelength conversion substance F1 and the release film. The gap between the 110s is such that the roughness of the wavelength conversion layer 122 and the first contact surface S1 of the release film 110 is low. On the other hand, the wavelength conversion substance F1 in the wavelength conversion layer 126 has a large particle (for example, between 15 and 30 micrometers) and a high concentration, so that the surface S of the wavelength conversion layer 126 has a relatively high roughness and is between the adhesion layer 130 and the adhesion layer 130. Adhesion is also large. Therefore, the second roughness of the second contact surface S2 of the wavelength conversion layer 126 and the adhesive layer 130 is greater than the first roughness of the first contact surface S1 of the wavelength conversion layer 122 and the release film 110. Since the second roughness is greater than the first roughness, when the adhesive layer 130 is adhered to the subsequent application of the luminescent wafer (not shown), the light can be easily entered from the adhesive layer 130 into the wavelength conversion layer 122, 124, 126. The light can be sufficiently wavelength-transformed by the wavelength conversion layers 122, 124, and 126 to emit light.

在此必須說明的是,下述實施例沿用前述實施例的元件標號與部分內容,其中採用相同的標號來表示相同或近似的元 件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,下述實施例不再重複贅述。 It should be noted that the following embodiments follow the component numbers and parts of the foregoing embodiments, wherein the same reference numerals are used to denote the same or similar elements. And the description of the same technical content is omitted. For the description of the omitted portions, reference may be made to the foregoing embodiments, and the following embodiments are not repeated.

圖1D繪示為本發明的一實施例的一種波長轉換膜的剖面示意圖。本實施例的波長轉換膜100’與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例於形成黏著層130之後,更包括:進行一脫膜製程,以分離離型膜110與波長轉換層122、124、126,而形成沒有離型膜110的波長轉換膜100’。 FIG. 1D is a schematic cross-sectional view of a wavelength conversion film according to an embodiment of the invention. The wavelength conversion film 100' of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference between the two is that after the adhesive layer 130 is formed, the method further includes: performing a stripping process to separate The release film 110 and the wavelength conversion layers 122, 124, and 126 form a wavelength conversion film 100' having no release film 110.

圖2繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請同時參考圖1C與圖2,本實施例的波長轉換膜100a與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例的波長轉換膜100a的黏著層130a內摻雜有多個擴散粒子132。當後續將波長轉換膜100a黏貼於發光晶圓(未繪示)上時,可使得發光元件(未繪示)所產生的光線產生散射的效果,有助於提高整體產品的發光效率。特別說明的是,除了擴散粒子之外,黏著層130a內亦可摻雜有反射粒子(未繪示)、散射粒子(未繪示)或上述至少其中之二,可讓發光元件所產生的光線產生散射、反射及擴散的效果,此仍屬於本發明所欲保護之範圍。 2 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 1C and FIG. 2 simultaneously, the wavelength conversion film 100a of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference is that the adhesion layer 130a of the wavelength conversion film 100a of the present embodiment is A plurality of diffusion particles 132 are doped. When the wavelength conversion film 100a is subsequently adhered to the light-emitting wafer (not shown), the light generated by the light-emitting element (not shown) can be scattered to help improve the luminous efficiency of the overall product. In particular, in addition to the diffusing particles, the adhesive layer 130a may be doped with reflective particles (not shown), scattering particles (not shown), or at least two of the above, which allow the light generated by the light-emitting element. The effect of scattering, reflection and diffusion is still within the scope of the invention to be protected.

圖3繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請同時參考圖1C與圖3,本實施例的波長轉換膜100b與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例的波長轉換膜100b於製作時,於任兩次塗佈製程之間,更包括形成一黏著層於前一次塗佈製程所形成的波長轉換層上。也 就是說,黏著層142是形成於波長轉換層122之後,且形成於波長轉換層124之前。而,黏著層144是形成於波長轉換層124之後,且形成於波長轉換層126之前。此處,形成黏著層142、144的目的在於增加波長轉換層122與波長轉換層124之間以及波長轉換層124與波長轉換層126之間的附著力,並調整其表面張力,且讓波長轉換層122、124、126間經黏著層142的堆疊後具有表面平坦化的效果,使表面粗糙度小於5微米。當然,亦可於黏著層142、144內摻雜擴散粒子(未繪示)、反射粒子(未繪示)、散射粒子(未繪示)或上述至少其中之二,而使後續波長轉換膜100b黏著於發光元件(未繪示)上時,可讓發光元件所產生的光線產生散射、反射及擴散的效果,此仍屬於本發明所欲保護之範圍。 3 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 1C and FIG. 3 simultaneously, the wavelength conversion film 100b of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference between the two is that the wavelength conversion film 100b of the present embodiment is Between any two coating processes, an adhesive layer is formed on the wavelength conversion layer formed by the previous coating process. and also That is, the adhesive layer 142 is formed after the wavelength conversion layer 122 and before the wavelength conversion layer 124. The adhesive layer 144 is formed after the wavelength conversion layer 124 and before the wavelength conversion layer 126. Here, the purpose of forming the adhesive layers 142, 144 is to increase the adhesion between the wavelength conversion layer 122 and the wavelength conversion layer 124 and between the wavelength conversion layer 124 and the wavelength conversion layer 126, and adjust the surface tension thereof, and allow wavelength conversion. The stacking of the layers 122, 124, 126 via the adhesive layer 142 has the effect of planarizing the surface to a surface roughness of less than 5 microns. Of course, the adhesion layer 142, 144 may be doped with diffusion particles (not shown), reflective particles (not shown), scattering particles (not shown) or at least two of the above, so that the subsequent wavelength conversion film 100b When it is adhered to a light-emitting element (not shown), the light generated by the light-emitting element can be scattered, reflected and diffused, which is still within the scope of the present invention.

圖4繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請參考圖4與圖1C,本實施例的波長轉換膜100c與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:第一波長轉換層122c的放射主波峰波長小於第二波長轉換層124c的放射主波峰波長。舉例來說,波長轉換層124c的放射主波峰波長可大於波長轉換層122c的放射主波峰波長,而波長轉換層126c的放射主波峰波長可大於波長轉換層124c的放射主波峰波長。此種排列可使得經具有較長的放射主波峰波長的波長轉換層126c轉換後的光,不會被具有較短的放射主波峰波長的波長轉換層124c、122c所吸收,以此類推。更具體來說,波長轉換層126c可為一紅色波長轉換層,而波長轉換層124c可為一黃色波長轉換 層,且波長轉換層122c可為一綠色波長轉換層。 4 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 4 and FIG. 1C, the wavelength conversion film 100c of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference is that the first wavelength conversion layer 122c has a radiation main peak wavelength smaller than the second wavelength. The main peak wavelength of the radiation of the wavelength conversion layer 124c. For example, the emission main peak wavelength of the wavelength conversion layer 124c may be greater than the emission main peak wavelength of the wavelength conversion layer 122c, and the emission main peak wavelength of the wavelength conversion layer 126c may be greater than the emission main peak wavelength of the wavelength conversion layer 124c. Such an arrangement allows light converted by the wavelength conversion layer 126c having a longer main wavelength of the radiation to be absorbed by the wavelength conversion layers 124c, 122c having a shorter main wavelength of the radiation, and so on. More specifically, the wavelength conversion layer 126c can be a red wavelength conversion layer, and the wavelength conversion layer 124c can be a yellow wavelength conversion. The layer, and the wavelength conversion layer 122c can be a green wavelength conversion layer.

當然,於其他實施例中,波長轉換層122c、124c、126c的放射主波峰波長也可以是朝遠離離型膜110的方向漸減。舉例來說,波長轉換層122c的放射主波峰波長大於波長轉換層124c的放射主波峰波長,而波長轉換層124c的放射主波峰波長大於波長轉換層126c的放射主波峰波長。使用者可依據所欲使用的發光晶圓的種類,自行搭配波長轉換層122c、124c、126c的排列順序。 Of course, in other embodiments, the main wavelength of the radiation of the wavelength conversion layers 122c, 124c, and 126c may also decrease toward the direction away from the release film 110. For example, the radiation main peak wavelength of the wavelength conversion layer 122c is larger than the radiation main peak wavelength of the wavelength conversion layer 124c, and the radiation main peak wavelength of the wavelength conversion layer 124c is larger than the emission main peak wavelength of the wavelength conversion layer 126c. The user can match the order of the wavelength conversion layers 122c, 124c, and 126c according to the type of the light-emitting wafer to be used.

需說明的是,此處波長轉換膜100、100’、100a、100b是以具有三層波長轉換層122、124、126為例說明,但於其他未繪示的實施例中,波長轉換膜亦可僅具有一層的波長轉換層;或者是,二層的波長轉換層;或者是大於三層的波長轉換層,此仍屬於本發明所欲保護的範圍。 It should be noted that the wavelength conversion films 100, 100', 100a, and 100b are exemplified by having three layers of wavelength conversion layers 122, 124, and 126. However, in other embodiments not shown, the wavelength conversion film is also used. It may have only one layer of the wavelength conversion layer; or, a two-layer wavelength conversion layer; or a wavelength conversion layer of more than three layers, which is still within the scope of the present invention.

圖5繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請同時參考圖5與圖1C,本實施例的波長轉換膜100d與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例的波長轉換層只有兩層,第一波長轉換層122d與第二波長轉換層124d,且波長轉換層122d、124d的厚度不同。較佳地,這些波長轉換層122d、124d的厚度朝遠離離型膜110的方向漸減。也就是說,第一波長轉換層122d的厚度大於第二波長轉換層124d的厚度。舉例來說,當波長轉換層124d為紅色波長轉換層,而波長轉換層122d為綠色波長轉換層,因此波長轉換層124d的厚度可為波長轉換層122d的厚度的0.2倍至0.4倍,可減少成本較高 的紅色螢光粉用量,可有效降低整體波長轉換膜100d的製作成本。 FIG. 5 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 5 and FIG. 1C simultaneously, the wavelength conversion film 100d of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference is that the wavelength conversion layer of the embodiment has only two layers, the first The wavelength conversion layer 122d and the second wavelength conversion layer 124d have different thicknesses of the wavelength conversion layers 122d and 124d. Preferably, the thickness of these wavelength conversion layers 122d, 124d is gradually decreased toward the direction away from the release film 110. That is, the thickness of the first wavelength conversion layer 122d is greater than the thickness of the second wavelength conversion layer 124d. For example, when the wavelength conversion layer 124d is a red wavelength conversion layer and the wavelength conversion layer 122d is a green wavelength conversion layer, the thickness of the wavelength conversion layer 124d may be 0.2 to 0.4 times the thickness of the wavelength conversion layer 122d, which may be reduced. higher cost The amount of red fluorescent powder can effectively reduce the manufacturing cost of the entire wavelength conversion film 100d.

圖6繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請同時參考圖6與圖1C,本實施例的波長轉換膜100e與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例的波長轉換層只有兩層,第一波長轉換層122e與第二波長轉換層124e,且波長轉換層122e、124e的波形半高寬不同。較佳地,第二波長轉換層124e的波形半高寬小於第一波長轉換層122e的波形半高寬,可避免波長轉換單元層122e的放射光波長涵蓋到波長轉換層124e的吸收波段,因此可提供較寬頻譜的演色性表現。更具體來說,波長轉換層124e可為一紅色波長轉換層,而波長轉換層122e可為一綠色波長轉換層,紅色波長轉換層的波形半高寬小於綠色波長轉換層的波形半高寬。 6 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 6 and FIG. 1C simultaneously, the wavelength conversion film 100e of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference is that the wavelength conversion layer of the embodiment has only two layers, the first The wavelength conversion layer 122e and the second wavelength conversion layer 124e have different half-widths of the waveforms of the wavelength conversion layers 122e and 124e. Preferably, the full width at half maximum of the second wavelength conversion layer 124e is smaller than the full width at half maximum of the first wavelength conversion layer 122e, so that the wavelength of the emitted light of the wavelength conversion unit layer 122e is prevented from covering the absorption band of the wavelength conversion layer 124e. Provides a wide spectrum of color rendering performance. More specifically, the wavelength conversion layer 124e may be a red wavelength conversion layer, and the wavelength conversion layer 122e may be a green wavelength conversion layer, and the waveform half width of the red wavelength conversion layer is smaller than the waveform half height width of the green wavelength conversion layer.

圖7繪示為本發明的另一實施例的一種波長轉換膜的剖面示意圖。請同時參考圖7與圖1C,本實施例的波長轉換膜100f與圖1C中的波長轉換膜100相似,惟二者主要差異之處在於:本實施例的波長轉換層122f只有一層,其中波長轉換層122f包括一膠體121以及一波長轉換物質123。詳細來說,波長轉換物質123分散於膠體121內,且波長轉換層122f具有第一區域R1以及第二區域R2,其中第一區域R1內的波長轉換物質123濃度大於第二區域R2內的波長轉換物質123密度,且第二區域R2環繞第一區域R1。 FIG. 7 is a cross-sectional view showing a wavelength conversion film according to another embodiment of the present invention. Referring to FIG. 7 and FIG. 1C simultaneously, the wavelength conversion film 100f of the present embodiment is similar to the wavelength conversion film 100 of FIG. 1C, but the main difference is that the wavelength conversion layer 122f of the embodiment has only one layer, wherein the wavelength The conversion layer 122f includes a colloid 121 and a wavelength converting substance 123. In detail, the wavelength converting substance 123 is dispersed in the colloid 121, and the wavelength converting layer 122f has the first region R1 and the second region R2, wherein the concentration of the wavelength converting substance 123 in the first region R1 is greater than the wavelength in the second region R2 The substance 123 is converted in density, and the second region R2 surrounds the first region R1.

在製程上,本實施例的波長轉換膜100f的製作方法與圖 1A至圖1C的波長轉換膜100的製作方法相同,差異之處僅在於:本實施例的塗佈製程實質上為旋轉塗佈製程。更具體來說,本實施例藉由旋轉塗佈製程的方式,利用離心力與膠體121的黏性搭配,來產生具有不同波長轉換物質123濃度的第一區域R1與第二區域R2。在後續的波長轉換膜100f的應用中,可搭配正向發光的發光晶圓(未繪示),來提高產品的出光與色溫均勻度。 In the process, the method and the diagram of the wavelength conversion film 100f of the embodiment The wavelength conversion film 100 of 1A to 1C is produced in the same manner, except that the coating process of the present embodiment is substantially a spin coating process. More specifically, in the present embodiment, the first region R1 and the second region R2 having different wavelength conversion substance 123 concentrations are generated by a centrifugal coating process using a centrifugal force and a viscosity of the colloid 121. In the application of the subsequent wavelength conversion film 100f, a forward-emitting light-emitting wafer (not shown) can be used to improve the light-emitting and color temperature uniformity of the product.

圖8(a)至8(c)繪示為本發明的一波長轉換膜搭載於發光晶圓的示意圖。為了方便說明起見,圖8(a)繪示為剖面示意圖,而圖8(b)及圖8(c)繪示為俯視示意圖。請先同時參考圖8(a)與圖8(b),本實施例的波長轉換膜100g的製作方法同上述圖1A至圖1C的波長轉換膜100的製作步驟,差異之處在於:本實施例的波長轉換膜100g用於搭載至少一發光晶圓W(圖8(a)中僅示意地繪示一個發光晶圓)。詳細來說,本實施例的黏著層130連接於發光晶圓W,且黏著層130配置於波長轉換層126與發光晶圓W之間,其中本實施例的波長轉換膜100g的尺寸(如表面積)大於發光晶圓W的尺寸(如表面積)。因此,波長轉換膜100g透過波黏著層130而黏貼於發光晶圓W上,此方式沒有元件對準的問題,可具有較佳的製程效率。此外,後續進行脫膜製程,分離離型膜110和波長轉換層122時,也不會因波長轉換層的位移而影響元件的色溫表現。特別的是,本實施例的波長轉換膜100g的尺寸(如表面積)可大於多個發光晶圓W的尺寸(如表面積)。如圖8(c)所示,因此可使波長轉換膜100h同時黏貼於多個發光晶圓W’上,具有較佳的使用便利性以及組裝容易,可具有更佳的製程效率。 8(a) to 8(c) are schematic views showing a wavelength conversion film of the present invention mounted on a light-emitting wafer. For convenience of explanation, FIG. 8( a ) is a schematic cross-sectional view, and FIGS. 8( b ) and 8 ( c ) are schematic plan views. Referring to FIG. 8(a) and FIG. 8(b), the manufacturing method of the wavelength conversion film 100g of the present embodiment is the same as the manufacturing process of the wavelength conversion film 100 of the above-mentioned FIG. 1A to FIG. 1C, and the difference lies in: The wavelength conversion film 100g is used to mount at least one light-emitting wafer W (only one light-emitting wafer is schematically shown in FIG. 8(a)). In detail, the adhesive layer 130 of the present embodiment is connected to the light-emitting wafer W, and the adhesive layer 130 is disposed between the wavelength conversion layer 126 and the light-emitting wafer W, wherein the size (such as the surface area of the wavelength conversion film 100g of the embodiment) ) is larger than the size (such as surface area) of the light-emitting wafer W. Therefore, the wavelength conversion film 100g is adhered to the light-emitting wafer W through the wave adhesion layer 130. This method has no problem of component alignment and can have better process efficiency. Further, when the release film process is subsequently performed and the release film 110 and the wavelength conversion layer 122 are separated, the color temperature performance of the element is not affected by the displacement of the wavelength conversion layer. In particular, the size (e.g., surface area) of the wavelength conversion film 100g of the present embodiment may be larger than the size (e.g., surface area) of the plurality of light-emitting wafers W. As shown in Fig. 8(c), the wavelength conversion film 100h can be simultaneously adhered to the plurality of light-emitting wafers W', which has better usability and ease of assembly, and can have better process efficiency.

值得一提的是,上述實施例中的波長轉換膜100g、100h的尺寸(如表面積)實質上略大於發光晶圓W、W’的尺寸(如表面積)。因此,波長轉換膜100g、100h無須裁切即可直接透過黏著層130而貼附於發光晶圓W、W’,可具有較佳的使用便利性以及組裝容易的優勢。 It is to be noted that the size (e.g., surface area) of the wavelength conversion films 100g, 100h in the above embodiments is substantially larger than the size (e.g., surface area) of the light-emitting wafers W, W'. Therefore, the wavelength conversion films 100g and 100h can be attached directly to the light-emitting wafers W and W' directly through the adhesive layer 130 without cutting, and can have advantages such as better usability and ease of assembly.

基於上述,由於本發明的波長轉換膜的製作方法是在離型膜上透過塗佈製程來形成波長轉換層,且於最遠離離型膜的波長轉換層的表面上形成黏著層。因此,相較於習知透過點膠的方式來形成發光二極體封裝體而言,本發明的波長轉換膜的製作方法除了具有製作容易且適於量產的優勢之外,亦可避免習知螢光顆粒於封裝膠體內的沉降問題而具有較佳的產品可靠度。再者,此波長轉換膜的製作方法所形成的波長轉換層也可具有較薄的厚度。此外,於後續的應用中,可直接將此波長轉換膜透過其黏著層而貼附於發光晶圓上,可具有較佳的使用便利性。 Based on the above, since the wavelength conversion film of the present invention is produced by a coating process on a release film to form a wavelength conversion layer, and an adhesion layer is formed on the surface of the wavelength conversion layer farthest from the release film. Therefore, the method for fabricating the wavelength conversion film of the present invention can be avoided in addition to the advantages of being easy to manufacture and suitable for mass production, as compared with the conventional method of forming a light-emitting diode package by dispensing. Knowing the problem of sedimentation of the fluorescent particles in the encapsulant has better product reliability. Furthermore, the wavelength conversion layer formed by the method of fabricating the wavelength conversion film may have a relatively thin thickness. In addition, in the subsequent application, the wavelength conversion film can be directly attached to the luminescent wafer through the adhesive layer, which can have better usability.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.

100‧‧‧波長轉換膜 100‧‧‧ wavelength conversion film

110‧‧‧離型膜 110‧‧‧ release film

122、124、126‧‧‧波長轉換層 122, 124, 126‧‧‧ wavelength conversion layer

S‧‧‧表面 S‧‧‧ surface

S1‧‧‧第一接觸面 S1‧‧‧ first contact surface

S2‧‧‧第二接觸面 S2‧‧‧Second contact surface

130‧‧‧黏著層 130‧‧‧Adhesive layer

Claims (14)

一種波長轉換膜的製作方法,包括:提供一離型膜;進行至少一塗佈製程,以於該離型膜上形成至少一波長轉換層,其中該至少一波長轉換層與該離型膜的一第一接觸面具有一第一粗糙度;形成一黏著層於最遠離該離型膜的該波長轉換層的一表面上,其中該黏著層與該波長轉換層的一第二接觸面具有一第二粗糙度,該第二粗糙度大於該第一粗糙度;以及進行一脫膜製程,以自該第一接觸面分離該離型膜與該至少一波長轉換層。 A method for fabricating a wavelength conversion film, comprising: providing a release film; performing at least one coating process to form at least one wavelength conversion layer on the release film, wherein the at least one wavelength conversion layer and the release film a first contact mask having a first roughness; forming an adhesive layer on a surface of the wavelength conversion layer farthest from the release film, wherein the adhesive layer and a second contact mask of the wavelength conversion layer have a second roughness, the second roughness being greater than the first roughness; and performing a stripping process to separate the release film from the at least one wavelength conversion layer from the first contact surface. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中每一該波長轉換層的厚度為該黏著層的厚度的1~3倍。 The method for fabricating a wavelength conversion film according to claim 1, wherein each of the wavelength conversion layers has a thickness of 1 to 3 times a thickness of the adhesion layer. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中該至少一波長轉換層包括一波長轉換物質以及一膠體,該至少一波長轉換層以100%的組成成分總百分比計算,該波長轉換物質的重量百分比為60%~95%。 The method for fabricating a wavelength conversion film according to claim 1, wherein the at least one wavelength conversion layer comprises a wavelength conversion substance and a colloid, and the at least one wavelength conversion layer is calculated by a total percentage of 100% of components. The weight percentage of the wavelength converting substance is 60% to 95%. 如申請專利範圍第3項所述的波長轉換膜的製作方法,其中該至少一波長轉換層的厚度介於該波長轉換物質的平均粒徑之1.2~3倍。 The method for fabricating a wavelength conversion film according to claim 3, wherein the thickness of the at least one wavelength conversion layer is between 1.2 and 3 times the average particle diameter of the wavelength conversion material. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中該黏著層內摻雜有多個擴散粒子、反射粒子、散射粒子或上述 至少其中之二。 The method for fabricating a wavelength conversion film according to claim 1, wherein the adhesive layer is doped with a plurality of diffusion particles, reflective particles, scattering particles or the above At least two of them. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中該至少一波長轉換層包括一第一波長轉換層與一第二波長轉換層,該第一波長轉換層配置於該離型膜與該第二波長轉換層之間。 The method for fabricating a wavelength conversion film according to claim 1, wherein the at least one wavelength conversion layer comprises a first wavelength conversion layer and a second wavelength conversion layer, wherein the first wavelength conversion layer is disposed in the release layer Between the film and the second wavelength conversion layer. 如申請專利範圍第6項所述的波長轉換膜的製作方法,其中該第一波長轉換層的放射主波峰波長小於該第二波長轉換層的放射主波峰波長。 The method for fabricating a wavelength conversion film according to claim 6, wherein a radiation main peak wavelength of the first wavelength conversion layer is smaller than a radiation main peak wavelength of the second wavelength conversion layer. 如申請專利範圍第6項所述的波長轉換膜的製作方法,其中該第二波長轉換層的波形半高寬小於該第一波長轉換層的波形半高寬。 The method for fabricating a wavelength conversion film according to claim 6, wherein the second half-wavelength conversion layer has a waveform half-width wider than a waveform half-width of the first wavelength conversion layer. 如申請專利範圍第6項所述的波長轉換膜的製作方法,其中該第一波長轉換層的厚度大於該第二波長轉換層的厚度。 The method for fabricating a wavelength conversion film according to claim 6, wherein the thickness of the first wavelength conversion layer is greater than the thickness of the second wavelength conversion layer. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中該至少一塗佈製程為一旋轉塗佈製程。 The method for fabricating a wavelength conversion film according to claim 1, wherein the at least one coating process is a spin coating process. 如申請專利範圍第10項所述的波長轉換膜的製作方法,其中該至少一波長轉換層包括一波長轉換物質以及一膠體,該波長轉換物質分散於該膠體內,且該至少一波長轉換層具有一第一區域以及一第二區域,該第一區域內的該波長轉換物質濃度大於該第二區域內的該波長轉換物質濃度,且該第二區域環繞該第一區域。 The method for fabricating a wavelength conversion film according to claim 10, wherein the at least one wavelength conversion layer comprises a wavelength conversion substance and a colloid, the wavelength conversion substance is dispersed in the gel body, and the at least one wavelength conversion layer There is a first region and a second region, the wavelength conversion substance concentration in the first region is greater than the wavelength conversion substance concentration in the second region, and the second region surrounds the first region. 一種波長轉換膜的製作方法,用於搭載至少一發光晶圓,該波長轉換膜的製作方法包括: 提供一離型膜;進行至少一塗佈製程,以於該離型膜上形成至少一波長轉換層,其中該至少一波長轉換層與該離型膜的一第一接觸面具有一第一粗糙度;形成一黏著層於最遠離該離型膜的該波長轉換層的一表面上,其中該黏著層與該波長轉換層的一第二接觸面具有一第二粗糙度,且該第二粗糙度大於該第一粗糙度,而該黏著層連接於該至少一發光晶圓;以及進行一脫膜製程,以自該第一接觸面分離該離型膜與該至少一波長轉換層。 A method for fabricating a wavelength conversion film for mounting at least one luminescent wafer, the method for fabricating the wavelength conversion film comprising: Providing a release film; performing at least one coating process to form at least one wavelength conversion layer on the release film, wherein the at least one wavelength conversion layer and the first contact mask of the release film have a first roughness Forming an adhesive layer on a surface of the wavelength conversion layer farthest from the release film, wherein the adhesion layer and a second contact mask of the wavelength conversion layer have a second roughness, and the second roughness The adhesion is greater than the first roughness, and the adhesive layer is coupled to the at least one luminescent wafer; and a stripping process is performed to separate the release film and the at least one wavelength conversion layer from the first contact surface. 一種波長轉換膜,用於搭載一發光晶圓,該波長轉換膜包括:一波長轉換層,具有彼此相對的一第一表面與一第二表面,其中該第一表面具有一第一粗糙度;以及一黏著層,連接該波長轉換層的該第二表面,且配置於該波長轉換層與該發光晶圓之間,其中該黏著層與該波長轉換層的一接觸面具有一第二粗糙度,且該第二粗糙度大於該第一粗糙度。 A wavelength conversion film for mounting a light-emitting wafer, the wavelength conversion film comprising: a wavelength conversion layer having a first surface and a second surface opposite to each other, wherein the first surface has a first roughness; And an adhesive layer connected to the second surface of the wavelength conversion layer, and disposed between the wavelength conversion layer and the light emitting wafer, wherein a contact mask of the adhesive layer and the wavelength conversion layer has a second roughness And the second roughness is greater than the first roughness. 如申請專利範圍第1項所述的波長轉換膜的製作方法,其中該至少一波長轉換層的硬度範圍為蕭氏硬度30D至90D。 The method for fabricating a wavelength conversion film according to claim 1, wherein the at least one wavelength conversion layer has a hardness ranging from 30 D to 90 D.
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