TWI569811B - Lips make up - Google Patents
Lips make up Download PDFInfo
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- TWI569811B TWI569811B TW101128664A TW101128664A TWI569811B TW I569811 B TWI569811 B TW I569811B TW 101128664 A TW101128664 A TW 101128664A TW 101128664 A TW101128664 A TW 101128664A TW I569811 B TWI569811 B TW I569811B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Description
本發明係關於一種口唇化妝料。 The present invention relates to a lip cosmetic.
口唇化妝料有口紅、護唇霜(lip cream)、唇蜜(gloss)等,作為其形狀,目前使用有棒狀型(固體狀)、直接填充於金屬器皿或樹脂器皿等中之固體注入型、填充於管或瓶中之液狀型(非固體狀)等。 The lip cosmetic has a lipstick, a lip cream, a gloss, and the like. As a shape thereof, a solid injection type in which a rod-shaped type (solid type) is directly filled in a metalware or a resin vessel is used. A liquid type (non-solid) filled in a tube or a bottle.
該等中,棒狀等之固體狀口紅雖然呈色良好,但於光澤度方面較差。又,以唇蜜為代表之非固體狀者雖然光澤度非常高,但於呈色、黏膩感、水潤度、水潤度之持續方面並不充分。 Among these, a solid lipstick such as a rod has a good color, but is inferior in gloss. In addition, although the non-solid state represented by lip gloss is very high in glossiness, it is not sufficient in terms of coloration, stickiness, hydration, and hydration.
因此,業界研究一種光澤度及呈色良好、使用感良好且水潤度性能較高之口唇化妝料。 Therefore, the industry has studied a lip cosmetic which has good gloss and good color rendering, good feeling of use, and high hydration performance.
例如,提出有以特定比例含有高黏度油分與特定之半固體油分的非固體口唇化妝料(專利文獻1)。該非固體口唇化妝料無黏膩感、塗抹時之光澤度及透明感優異,但於呈色或水潤度、水潤度之持續方面較差。 For example, a non-solid lip cosmetic containing a high-viscosity oil component and a specific semi-solid oil component in a specific ratio has been proposed (Patent Document 1). The non-solid lip cosmetic has no stickiness, is excellent in gloss and transparency when applied, but is inferior in coloring or hydration and hydration.
又,亦研究出含有特定之蠟、糊精脂肪酸酯、油溶性樹脂及板狀粉體的糊狀口唇化妝料(專利文獻2),或含有熔點不同之2種烴、水合性油及糊精脂肪酸酯之油性化妝料(專利文獻3)等。然而,該等化妝料雖然使用感良好,但由於使用膠化劑,而存在水潤度或水潤度之持續性降低的問題。 Further, a paste-like lip cosmetic containing a specific wax, a dextrin fatty acid ester, an oil-soluble resin, and a plate-like powder has been studied (Patent Document 2), or two kinds of hydrocarbons, hydrating oils, and pastes having different melting points have been studied. An oily cosmetic of a fine fatty acid ester (Patent Document 3) or the like. However, although these cosmetics have a good feeling of use, there is a problem in that the hydration degree or the hydration degree is lowered due to the use of a gelling agent.
[專利文獻1]日本專利特開2007-277189號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2007-277189
[專利文獻2]日本專利特開2002-193749號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2002-193749
[專利文獻3]日本專利特開2007-262033號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2007-262033
本發明係提供一種口唇化妝料,其含有以下之成分(a)及(b):(a)至少包含(a1)25℃下之針入度為5~20之烴系蠟、(a2)25℃下之針入度超過20且為110以下之烴系蠟的蠟,且該成分(a)於全部化妝料中為1~9質量%;(b)於25℃下為液狀或糊狀之油劑;且成分(a1)與成分(a2)之質量比例(a1)/(a2)=1/17~80/1,成分(a1)及成分(a2)之總和與成分(b)的質量比例((a1)+(a2))/(b)=0.02~0.12,成分(b)於25℃下之黏度為500~10000 mPa.s,30℃下之化妝料利用10 mmΦ治具獲得之針入硬度為0.5~9 N。 The present invention provides a lip cosmetic comprising the following components (a) and (b): (a) at least (a1) a hydrocarbon wax having a penetration of 5 to 20 at 25 ° C, (a2) 25 a wax of a hydrocarbon wax having a penetration degree exceeding 20 and 110 or less at ° C, and the component (a) is 1 to 9% by mass in all the cosmetic materials; (b) liquid or paste at 25 ° C Oil agent; and the mass ratio of component (a1) to component (a2) (a1)/(a2)=1/17~80/1, the sum of component (a1) and component (a2) and component (b) Mass ratio ((a1)+(a2))/(b)=0.02~0.12, component (b) has a viscosity of 500~10000 mPa at 25 °C. s, the cosmetic at 30 ° C using a 10 mmΦ fixture to achieve a needle hardness of 0.5 ~ 9 N.
本發明係關於一種不會損壞妝面之光澤度,呈色及使用感良好,水潤度之性能較高,並且該水潤度可持續的口唇化妝料。 The present invention relates to a lip cosmetic which does not damage the gloss of a makeup surface, has a good color and a good feeling of use, has a high water hydration property, and has a water hydration degree.
本發明者等人發現,使用包含針入度不同之2種烴系蠟的蠟,且組合具有特定黏度之油劑而獲得特定針入硬度的口唇化妝料可解決上述課題。 The inventors of the present invention have found that the use of a wax comprising two kinds of hydrocarbon waxes having different penetration degrees and a combination of an oil agent having a specific viscosity to obtain a specific needle hardness can solve the above problems.
本發明之口唇化妝料之呈色良好、妝面之光澤度優異、 不發黏、水潤度性能較高並且該水潤度性能可持續。 The lip cosmetic of the present invention has good color rendering and excellent gloss on the makeup surface. It is non-tacky, has high hydration properties and is sustainable in hydration properties.
本發明中所使用之成分(a)之蠟係於25℃下為固體之油性成分,其至少包含(a1)25℃下之針入度為5~20之烴系蠟、(a2)25℃下之針入度超過20且為110以下之烴系蠟。 The wax of the component (a) used in the present invention is a solid oily component at 25 ° C, and at least (a1) a hydrocarbon wax having a penetration degree of 5 to 20 at 25 ° C, (a2) 25 ° C A hydrocarbon wax having a penetration degree of more than 20 and 110 or less.
此處,針入度係測定規定之針(針之質量為2.5±0.02 g,針保持治具之質量為47.5±0.02 g,砝碼之質量為50±0.05 g)在保持為25±0.1℃之蠟之試樣中5秒鐘所插入之長度,以將該插入距離(mm)乘以10倍所得之值作為針入度,其係依據JIS K-2235-5.4(1991年)而測定之值。 Here, the penetration degree is determined by the specified needle (the mass of the needle is 2.5 ± 0.02 g, the mass of the needle holding fixture is 47.5 ± 0.02 g, and the mass of the weight is 50 ± 0.05 g) is maintained at 25 ± 0.1 ° C. The length of the wax sample inserted for 5 seconds, and the value obtained by multiplying the insertion distance (mm) by 10 times is taken as the penetration degree, which is determined according to JIS K-2235-5.4 (1991). value.
作為(a1)25℃下之針入度為5~20之烴系蠟,例如可列舉:地石蠟(ozokerite)、地蠟(ceresine)等礦物系蠟;石蠟、石蠟脂等石油系蠟;費托蠟(Fischer-Tropsch wax)、聚乙烯蠟等合成烴。 Examples of the hydrocarbon wax having a penetration degree of 5 to 20 at 25 ° C (a1) include mineral waxes such as ozokerite and ceresine; petroleum waxes such as paraffin wax and paraffin wax; Synthetic hydrocarbons such as Fischer-Tropsch wax and polyethylene wax.
該等蠟可使用市售品,例如,作為地蠟可列舉:CERESIN#810、CERESIN B(以上,NIKKO RICA公司);作為石蠟,可列舉:Paraffin wax 125、140、150、155、HNP-3、HNP-9、HNP-10、HNP-11、HNP-12、HNP-51、SP-0135、SP-0140、SP-0145、SP-0160、SP-0165、SP-3035、SP-3040(以上由日本精蠟公司製造);作為費托蠟,可列舉:FT-0070、FT-100、FT-105、FT-115、FT-0165、FT-5165、FNP-0115(以上由日本精蠟公司製造);作為聚乙烯蠟,可列舉:PERFORMALENE PL POLYETHYLENE、PERFORMA LENE 400、PERFORMA LENE 500、PERFORMA LENE 655(以上由NEW PHASE TECHNOLOGIES公司製造)等。(a1)之25℃ 下之針入度更佳為6~18。 Commercially available products can be used as the waxes, for example, CERESIN #810 and CERESIN B (above, NIKKO RICA); and paraffin waxes include Paraffin wax 125, 140, 150, 155, and HNP-3. , HNP-9, HNP-10, HNP-11, HNP-12, HNP-51, SP-0135, SP-0140, SP-0145, SP-0160, SP-0165, SP-3035, SP-3040 (above Made by Japan Fine Wax Co., Ltd.); as Fischer-Tropsch wax, FT-0070, FT-100, FT-105, FT-115, FT-0165, FT-5165, FNP-0115 (above by Japan Fine Wax Company) Manufactured as a polyethylene wax, PERFORMALENE PL POLYETHYLENE, PERFORMA LENE 400, PERFORMA LENE 500, PERFORMA LENE 655 (above, manufactured by NEW PHASE TECHNOLOGIES Co., Ltd.), and the like. 25°C of (a1) The penetration degree is preferably 6 to 18.
又,作為(a2)25℃下之針入度超過20且為110以下之烴系蠟,可列舉微晶蠟、石蠟等,較佳為微晶蠟。 Further, the (a2) hydrocarbon-based wax having a penetration of more than 20 and not more than 110 at 25 ° C may, for example, be a microcrystalline wax or a paraffin wax, and is preferably a microcrystalline wax.
該等蠟可使用市售品,例如,作為微晶蠟可列舉:Multiwax W-445、Multiwax W-835(以上由SONNEBORN公司製造),Hi-Mic-1045、Hi-Mic-1070、Hi-Mic-1080、Hi-Mic-1090、Hi-Mic-2045、Hi-Mic-2065、Hi-Mic-2095(以上由日本精蠟公司製造),精製微晶蠟(NIKKO RICA公司)、155°微晶石蠟(日本石油公司)等。(a2)之25℃下之針入度更佳為25~80。 Commercially available products can be used as the waxes. For example, as the microcrystalline wax, Multiwax W-445, Multiwax W-835 (manufactured by SONNEBORN Co., Ltd.), Hi-Mic-1045, Hi-Mic-1070, Hi-Mic can be cited. -1080, Hi-Mic-1090, Hi-Mic-2045, Hi-Mic-2065, Hi-Mic-2095 (above manufactured by Nippon Seiko Co., Ltd.), refined microcrystalline wax (NIKKO RICA), 155° microcrystal Paraffin (Nippon Oil Corporation) and so on. (a2) The penetration at 25 ° C is preferably 25 to 80.
作為成分(a)之蠟,(a1)之烴系蠟之針入度較佳為6~18,且(a2)之烴系蠟之針入度較佳為25~80。又,(a1)較佳為地蠟、石蠟,(a2)較佳為微晶蠟。 As the wax of the component (a), the degree of penetration of the hydrocarbon wax of (a1) is preferably from 6 to 18, and the penetration of the hydrocarbon wax of (a2) is preferably from 25 to 80. Further, (a1) is preferably a ceresin or a paraffin wax, and (a2) is preferably a microcrystalline wax.
於本發明中,(a1)與(a2)之質量比例(a1)/(a2)=1/17~80/1,為獲得更高之水潤度性能(或鎖水性較高之塗膜),較佳為1/8~70/1,更佳為2/7~25/1。 In the present invention, the mass ratio of (a1) to (a2) (a1) / (a2) = 1 / 17 ~ 80/1, in order to obtain a higher water wettability performance (or a coating film having a higher water lock ratio) ), preferably 1/8 to 70/1, more preferably 2/7 to 25/1.
於本發明中,成分(a)之蠟之合計量於全部成分中以合計值計為1~9質量%。進而,就口唇化妝料之呈色或穩定性之方面而言,較佳為2質量%以上,更佳為3質量%以上,且上限較佳為8.5質量%以下,更佳為8質量%以下。又,較佳為2~8.5質量%,更佳為3~8質量%。 In the present invention, the total amount of the wax of the component (a) is from 1 to 9% by mass based on the total of the total components. Furthermore, it is preferably 2% by mass or more, more preferably 3% by mass or more, and the upper limit is preferably 8.5% by mass or less, and more preferably 8% by mass or less, from the viewpoint of color development or stability of the lip cosmetic. . Further, it is preferably 2 to 8.5% by mass, more preferably 3 to 8% by mass.
進而,較佳為(a1)為0.1~7質量%,(a2)為0.1~4質量%。 Further, it is preferable that (a1) is 0.1 to 7 mass%, and (a2) is 0.1 to 4 mass%.
成分(a)之蠟可於不損害本發明之效果之範圍內含有(a1)及(a2)以外之蠟。作為(a1)及(a2)以外之蠟,例如可列舉: 巴西棕櫚蠟、堪地里拉蠟、米糠蠟、木蠟等植物系蠟;蜂蠟、鯨蠟等動物性蠟;聚乙烯蠟、聚矽氧蠟等合成蠟;脂肪酸、高級醇及該等之衍生物。就使用感或水潤度性能之觀點而言,該等(a1)及(a2)以外之蠟較佳為於全部蠟中為5質量%以下,更佳為3質量%以下。 The wax of the component (a) may contain a wax other than (a1) and (a2) within a range not impairing the effects of the present invention. Examples of the wax other than (a1) and (a2) include, for example: Plant waxes such as carnauba wax, candid wax, rice bran wax, wood wax; animal wax such as beeswax and cetyl wax; synthetic waxes such as polyethylene wax and polyxanthene wax; fatty acids, higher alcohols and derivatives thereof . The wax other than the above (a1) and (a2) is preferably 5% by mass or less, and more preferably 3% by mass or less, based on the total sensation or the hydration performance.
本發明中所使用之成分(b)之油劑係於25℃下為液狀或糊狀之油劑,僅將該等成分(b)之全部油劑混合時,該等混合物於25℃下之黏度為500~10000 mPa.s。就使用感或穩定性之方面而言,成分(b)之混合物於25℃下之黏度的下限較佳為700 mPa.s以上,更佳為1000 mPa.s以上,且上限較佳為8000 mPa.s以下,更佳為7000 mPa.s以下。 The oil agent of the component (b) used in the present invention is a liquid or paste oil at 25 ° C, and only when the entire oil of the components (b) is mixed, the mixture is at 25 ° C The viscosity is 500~10000 mPa. s. The lower limit of the viscosity of the mixture of the component (b) at 25 ° C is preferably 700 mPa in terms of the feeling of use or stability. Above s, more preferably 1000 mPa. Above s, and the upper limit is preferably 8000 mPa. Below s, more preferably 7000 mPa. s below.
再者,黏度測定係使用B型黏度計(東機產業公司:TVB-10),於25℃之條件下,於將轉子No.4設定為轉速6 rpm之條件下,以旋轉時間1分鐘而進行測定。 In addition, the viscosity measurement was performed using a B-type viscometer (Tokyo Industry Co., Ltd.: TVB-10) under the condition of 25 ° C, and the rotor No. 4 was set to a rotation speed of 6 rpm, and the rotation time was 1 minute. The measurement was carried out.
成分(b)之於25℃下為液狀或糊狀之油劑可將通常之化妝料中所使用者使用1種或組合2種以上而使用。成分(b)較佳為組合2種以上而使用,且較佳為至少包含1種以上糊狀油劑。 In the case of the component (b), the oil may be used in the form of a liquid or a paste in the form of a conventional cosmetic, and one or a combination of two or more of them may be used. The component (b) is preferably used in combination of two or more kinds, and preferably contains at least one type of a paste oil agent.
此處,所謂液狀或糊狀油劑,係指於25℃下具有流動性之油劑,其中,糊狀油劑係於室溫~60℃左右具有熔點之油劑。 Here, the liquid or paste oil agent refers to an oil agent having fluidity at 25 ° C, wherein the paste oil agent is an oil agent having a melting point at room temperature to about 60 ° C.
具體而言,可列舉:凡士林、角鯊烷、液體石蠟、液體異構石蠟、聚丁烯、氫化聚異丁烯、氫化聚癸烯等烴油;異壬酸異十三烷基酯、異硬脂酸異丙酯、新戊二醇二癸酸 酯、二異硬脂酸甘油酯、三異硬脂酸甘油酯、蘋果酸二異硬脂基酯、荷荷芭油、辛基十二烷醇、N-月桂醯-L-麩胺酸二(植物甾醇/2-辛基十二烷基)酯等酯油;二甲基聚矽氧烷、苯基甲基聚矽氧烷等聚矽氧油;羊毛脂、二聚酸酯、二聚醇衍生物、膽固醇脂肪酸酯、植物甾醇脂肪酸酯、聚甘油脂肪酸酯、季戊四醇脂肪酸酯等。 Specific examples thereof include hydrocarbon oils such as petrolatum, squalane, liquid paraffin, liquid isomerized paraffin, polybutene, hydrogenated polyisobutylene, and hydrogenated polydecene; isotridecyl isononanoate and isostearyl Isopropyl acrylate, neopentyl glycol dicaprate Ester, glyceryl diisostearate, glyceryl triisostearate, diisostearyl malate, jojoba oil, octyldodecanol, N-laurel-L-glutamic acid Ester oils such as (phytosterol/2-octyldodecyl) ester; polyoxyxylene oils such as dimethyl polyoxane and phenylmethyl polyoxyalkylene; lanolin, dimer acid ester, dimerization Alcohol derivatives, cholesterol fatty acid esters, phytosterol fatty acid esters, polyglycerin fatty acid esters, pentaerythritol fatty acid esters, and the like.
本發明中,在成分(b)之於25℃下為液狀或糊狀之全部油劑中,液狀油較佳為40質量%以上、95質量%以下。 In the present invention, the liquid oil is preferably 40% by mass or more and 95% by mass or less based on the total oil of the component (b) which is liquid or paste at 25 °C.
又,於成分(b)之油劑中包含平均分子量1200以上之烴油時,就無黏膩感、光澤度及水潤度、以及其持續性之方面而言較佳。關於平均分子量1200以上之烴油之含量,於成分(b)中之上限較佳為60質量%以下,更佳為50質量%以下,且下限較佳為10質量%以上,更佳為20質量%以上,進而更佳為30質量%以上,進而更佳為40質量%以上。 Further, when the hydrocarbon oil having an average molecular weight of 1200 or more is contained in the oil agent of the component (b), it is preferable in terms of no stickiness, glossiness, hydration degree, and sustainability. The upper limit of the component (b) is preferably 60% by mass or less, more preferably 50% by mass or less, and the lower limit is preferably 10% by mass or more, more preferably 20% by mass, based on the content of the hydrocarbon oil having an average molecular weight of 1200 or more. % or more, more preferably 30% by mass or more, and still more preferably 40% by mass or more.
又,就穩定性及保養效果之觀點而言,25℃下之黏度為100 mPa.s以下之聚矽氧油之含量較佳為於成分(b)中為3質量%以下,更佳為2質量%以下。 Moreover, in terms of stability and maintenance effect, the viscosity at 25 ° C is 100 mPa. The content of the polyoxygenated oil of s or less is preferably 3% by mass or less, and more preferably 2% by mass or less based on the component (b).
再者,聚矽氧油之黏度係利用振動式黏度計(A&D公司:SV型黏度計SV-10 VIBRO VISCOMETER)測定。 Furthermore, the viscosity of the polyoxygenated oil was measured using a vibrating viscometer (A&D: SV type viscometer SV-10 VIBRO VISCOMETER).
就妝面之光澤度優異,且無黏膩感,不損害使用感之方面而言,成分(b)之油劑於全部化妝料中之下限較佳為30質量%以上,更佳為40質量%以上,進而較佳為50質量%以上,進而更佳為60質量%以上,且上限較佳為95質量%以下,更佳為90質量%以下。 The lower limit of the gloss of the makeup surface and the non-sticky feeling, and the damage of the use of the component (b) is preferably 30% by mass or more, more preferably 40% by mass. % or more is more preferably 50% by mass or more, still more preferably 60% by mass or more, and the upper limit is preferably 95% by mass or less, and more preferably 90% by mass or less.
於本發明中,成分(a1)及成分(a2)之總和與成分(b)的質量比例((a1)+(a2))/(b)=0.02~0.12,就水分阻隔性優異、妝面之光澤度優異、不發黏、水潤度性能可持續之方面而言,下限較佳為0.04以上,且上限較佳為0.1以下,更佳為0.09以下。又,((a1)+(a2))/(b)較佳為0.02~0.1,更佳為0.04~0.09。 In the present invention, the ratio of the sum of the component (a1) and the component (a2) to the mass ratio of the component (b) ((a1)+(a2))/(b)=0.02 to 0.12 is excellent in moisture barrier property and makeup surface. The lower limit is preferably 0.04 or more, and the upper limit is preferably 0.1 or less, more preferably 0.09 or less, in terms of excellent glossiness, no stickiness, and hydration performance. Further, ((a1)+(a2))/(b) is preferably 0.02 to 0.1, more preferably 0.04 to 0.09.
本發明之口唇化妝料中,自蠟之結晶化不會受到阻礙,使穩定性及水潤度可持續之方面考慮,親油性膠化劑之含量較佳為於全部化妝料中為2質量%以下,更佳為1質量%以下,更佳為實質上不調配。 In the lip cosmetic of the present invention, the crystallization of the wax is not hindered, and the stability and the hydration degree are considered to be sustainable, and the content of the lipophilic gelling agent is preferably 2% by mass in all the cosmetic materials. Hereinafter, it is more preferably 1% by mass or less, and more preferably substantially not formulated.
作為此種親油性膠化劑,例如可列舉:棕櫚酸糊精、硬脂酸糊精、椰子油脂肪酸糊精等糊精脂肪酸酯;蔗糖脂肪酸酯、12-羥基硬脂酸等。 Examples of such lipophilic gelling agents include dextrin fatty acid esters such as palmitic acid dextrin, stearic acid dextrin, and coconut oil fatty acid dextrin; sucrose fatty acid esters and 12-hydroxystearic acid.
本發明之口唇化妝料可進而含有(c)粉體。作為該粉體,只要為通常之化妝料中所使用者則並無限制,可使用體質顏料、著色顏料、珠光顏料等。 The lip cosmetic of the present invention may further contain (c) a powder. The powder is not particularly limited as long as it is a user of a usual cosmetic, and an extender pigment, a coloring pigment, a pearl pigment, or the like can be used.
作為體質顏料,例如可列舉:矽酸、矽酸酐、矽酸鎂、滑石、絹雲母、雲母、高嶺土、黏土、膨土、氧氯化鉍、氧化鋯、氧化鎂、氧化鋁、硫酸鈣、硫酸鋇、硫酸鎂、碳酸鈣、碳酸鎂等無機顏料及該等之複合粉體。 Examples of the extender pigment include citric acid, phthalic anhydride, magnesium citrate, talc, sericite, mica, kaolin, clay, bentonite, yttrium oxychloride, zirconia, magnesia, alumina, calcium sulfate, and sulfuric acid. Inorganic pigments such as barium, magnesium sulfate, calcium carbonate, and magnesium carbonate, and composite powders thereof.
作為著色顏料,例如可列舉:氧化鈦、氧化鋅、氧化鐵黃、鐵丹、氧化鐵黑、鐵藍、群青、氧化鉻、氫氧化鉻等金屬氧化物;錳紫(manganese violet)、鈦酸鈷等金屬錯合物;以及碳黑等無機顏料,焦油系色素、色澱顏料等有機顏料,洋紅等天然色素等。 Examples of the coloring pigment include metal oxides such as titanium oxide, zinc oxide, iron oxide yellow, iron oxide, iron oxide black, iron blue, ultramarine blue, chromium oxide, and chromium hydroxide; manganese violet and titanic acid. A metal complex such as cobalt; an inorganic pigment such as carbon black; an organic pigment such as a tar pigment or a lake pigment; or a natural pigment such as magenta.
作為珠光顏料,可使用利用氧化鈦、氧化鐵、氧化矽、鐵藍、氧化鉻、洋紅、有機顏料等著色劑將雲母、合成金雲母、玻璃等之表面被覆而成者等。 As the pearl pigment, those obtained by coating the surface of mica, synthetic phlogopite, glass, or the like with a coloring agent such as titanium oxide, iron oxide, cerium oxide, iron blue, chromium oxide, magenta, or an organic pigment can be used.
該等粉體亦可使用藉由通常之方法實施斥水處理、斥水/斥油化處理等各種表面處理而成者。 These powders can also be obtained by various surface treatments such as water repellent treatment, water repellent/oil repellent treatment by a usual method.
成分(c)之粉體可使用1種或2種以上,於全部成分中之下限較佳為0.01質量%以上,更佳為0.1質量%以上,且上限較佳為20質量%以下,更佳為10質量%以下。又,較佳為於全部成分中含有0.01~20質量%,更佳為含有0.1~10質量%。 The powder of the component (c) may be used alone or in combination of two or more. The lower limit of all the components is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and the upper limit is preferably 20% by mass or less, more preferably It is 10% by mass or less. Further, it is preferably contained in an amount of from 0.01 to 20% by mass, more preferably from 0.1 to 10% by mass, based on the total of the components.
本發明之口唇化妝料可於不損害本發明之效果之範圍內,含有通常之化妝料中所使用之成分,例如:界面活性劑、低級醇、多元醇、高分子化合物、紫外線吸收劑、抗氧化劑、香料、防污劑、保濕劑、水等。 The lip cosmetic of the present invention may contain components used in usual cosmetics, such as surfactants, lower alcohols, polyols, polymer compounds, ultraviolet absorbers, and anti-drugs, within the range not impairing the effects of the present invention. Oxidizing agents, perfumes, antifouling agents, moisturizers, water, etc.
本發明之口唇化妝料於30℃下之化妝料利用10 mmΦ治具獲得之針入硬度為0.5~9 N,較佳為0.8~6 N。只要在該範圍內,則製造時容易填充至管容器或蘸塗式容器(dipping container)中,又,對於使用者而言,係不會產生滴液且容易塗抹之硬度。 The cosmetic material of the present invention has a needle penetration hardness of 0.5 to 9 N, preferably 0.8 to 6 N, obtained by using a 10 mm Φ fixture at 30 ° C. When it is within this range, it is easy to be filled into a tube container or a dipping container at the time of manufacture, and the user does not have a hardness which is dripping and easy to apply.
於本發明中,所謂「針入硬度」係以如下方式所得者:使用不動工業公司(FUDO kougyou,Inc.)製造之流變計,於30℃下,於治具之直徑為2 mm且工作台速度(table speed)為2 mm/s之條件下,將治具插入至深度2 mm為止,將此時之最大值換算至每單位面積。 In the present invention, the "needle-in hardness" is obtained by using a rheometer manufactured by FUDO kougyou, Inc. at a temperature of 30 ° C and working at a diameter of 2 mm. When the table speed is 2 mm/s, insert the jig to a depth of 2 mm and convert the maximum value to the unit area.
本發明之口唇化妝料可藉由通常之方法製造,以非固體 狀之形式而獲得。本發明之口唇化妝料可製成口紅、護唇霜、唇蜜、唇線筆等。 The lip cosmetic of the present invention can be manufactured by a usual method to be non-solid Obtained in the form of a shape. The lip cosmetic of the present invention can be made into a lipstick, a lip balm, a lip gloss, a lip liner, and the like.
此處,所謂非固體狀,係指雖呈現為塊狀,但為保型性低至利用模具等無法成型之程度的狀態,無法如棒狀般於旋出式容器中使用者。本發明之口唇化妝料較佳為填充於管容器、蘸塗式容器等中。 Here, the term "non-solid" refers to a state in which the shape retaining property is as low as that which cannot be molded by a mold or the like, and the user cannot be in a spin-out type container as a rod. The lip cosmetic of the present invention is preferably filled in a tube container, a sputum-coated container or the like.
以下,本發明關於上述實施形態進而揭示以下組合物。 Hereinafter, the present invention further discloses the following composition in the above embodiment.
<1>一種口唇化妝料,其含有以下之成分(a)及(b):(a)至少包含(a1)25℃下之針入度為5~20之烴系蠟、(a2)25℃下之針入度超過20且為110以下之烴系蠟的蠟,且該成分(a)於全部化妝料中為1~9質量%;(b)於25℃下為液狀或糊狀之油劑;且成分(a1)與成分(a2)之質量比例(a1)/(a2)=1/17~80/1,成分(a1)及成分(a2)之總和與成分(b)的質量比例((a1)+(a2))/(b)=0.02~0.12,成分(b)於25℃下之黏度為500~10000 mPa.s,30℃下之化妝料利用10 mm治具獲得之針入硬度為0.5~9 N。 <1> A lip cosmetic comprising the following components (a) and (b): (a) at least (a1) a hydrocarbon wax having a penetration of 5 to 20 at 25 ° C, (a2) 25 ° C a wax of a hydrocarbon wax having a penetration degree of more than 20 and 110 or less, and the component (a) is 1 to 9% by mass in all the cosmetic materials; (b) is liquid or paste at 25 ° C. Oil agent; and mass ratio of component (a1) to component (a2) (a1)/(a2)=1/17~80/1, sum of component (a1) and component (a2) and mass of component (b) The ratio ((a1)+(a2))/(b)=0.02~0.12, the viscosity of the component (b) at 25 °C is 500~10000 mPa. s, 10 ° C of cosmetics using 10 mm The penetration hardness of the fixture is 0.5~9 N.
<2>如上述<1>之口唇化妝料,其中(a1)之烴系蠟於25℃下之針入度為6~18。 <2> The lip cosmetic of the above <1>, wherein the hydrocarbon wax of (a1) has a penetration of 6 to 18 at 25 °C.
<3>如上述<1>或<2>之口唇化妝料,其中(a2)之烴系蠟於25℃下之針入度為25~80。 <3> The lip cosmetic of the above <1> or <2>, wherein the hydrocarbon wax of (a2) has a penetration of 25 to 80 at 25 °C.
<4>如上述<1>至<3>中任一項之口唇化妝料,其中(a1)與(a2)之質量比例(a1)/(a2)=1/8~70/1,較佳為2/7~25/1。 <4> The lip cosmetic according to any one of the above <1> to <3>, wherein a mass ratio of (a1) to (a2) (a1)/(a2) = 1/8 to 70/1, preferably It is 2/7~25/1.
<5>如上述<1>至<4>中任一項之口唇化妝料,其中成分(a) 之含量於全部化妝料中為2~8.5質量%,較佳為3~8質量%。 <5> A lip cosmetic according to any one of <1> to <4> above, wherein the component (a) The content is 2 to 8.5% by mass, preferably 3 to 8% by mass, based on the total amount of the cosmetic.
<6>如上述<1>至<5>中任一項之口唇化妝料,其中(a1)為選自礦物系蠟、石油系蠟及合成烴中者,且較佳為地蠟、石蠟。 The lip cosmetic according to any one of the above-mentioned items, wherein (a1) is selected from the group consisting of a mineral wax, a petroleum wax, and a synthetic hydrocarbon, and is preferably a ceresin or a paraffin wax.
<7>如上述<1>至<6>中任一項之口唇化妝料,其中(a2)為選自微晶蠟及石蠟中者,且較佳為微晶蠟。 The lip cosmetic of any one of <1> to <6>, wherein (a2) is selected from the group consisting of microcrystalline wax and paraffin wax, and is preferably a microcrystalline wax.
<8>如上述<1>至<7>中任一項之口唇化妝料,其中(a1)之含量於全部化妝料中為0.1~7質量%,(a2)之含量於全部化妝料中為0.1~4質量%。 <8> The lip cosmetic according to any one of the above <1> to <7> wherein the content of (a1) is 0.1 to 7% by mass in all the cosmetic materials, and the content of (a2) is in all the cosmetic materials. 0.1 to 4% by mass.
<9>如上述<1>至<8>中任一項之口唇化妝料,其中成分(b)之混合物於25℃下之黏度之下限為700 mPa.s以上,較佳為1000 mPa.s以上,且上限為8000 mPa.s以下,較佳為7000 mPa.s以下。 <9> The lip cosmetic according to any one of <1> to <8> wherein the lower limit of the viscosity of the mixture of the component (b) at 25 ° C is 700 mPa. Above s, preferably 1000 mPa. Above s, and the upper limit is 8000 mPa. Below s, preferably 7000 mPa. s below.
<10>如上述<1>至<9>中任一項之口唇化妝料,其中成分(b)之含量於全部化妝料中之下限為30質量%以上,較佳為40質量%以上,更佳為50質量%以上,進而更佳為60質量%以上,且上限為95質量%以下,較佳為90質量%以下。 In the lip cosmetic according to any one of the above-mentioned items, the content of the component (b) is 30% by mass or more, preferably 40% by mass or more, more preferably 40% by mass or more. The content is preferably 50% by mass or more, more preferably 60% by mass or more, and the upper limit is 95% by mass or less, preferably 90% by mass or less.
<11>如上述<1>至<10>中任一項之口唇化妝料,其中於成分(b)之全部油劑中,液狀油為40質量%以上、95質量%以下。 The lip cosmetic of any one of the above-mentioned <1> to <10>, wherein the liquid oil is 40% by mass or more and 95% by mass or less of the total oil of the component (b).
<12>如上述<1>至<11>中任一項之口唇化妝料,其中成分(b)中,平均分子量1200以上之烴油之含量之上限為60質量%以下,較佳為50質量%以下,且下限為10質量%以上,較佳為20質量%以上,更佳為30質量%以上,進而更佳為40 質量%以上。 The lip cosmetic of any one of the above-mentioned <1> to <11>, wherein the upper limit of the content of the hydrocarbon oil having an average molecular weight of 1200 or more in the component (b) is 60% by mass or less, preferably 50% by mass. % or less, and the lower limit is 10% by mass or more, preferably 20% by mass or more, more preferably 30% by mass or more, and still more preferably 40% by mass. More than % by mass.
<13>如上述<1>至<12>中任一項之口唇化妝料,其中成分(b)中,25℃下之黏度為100mPa.s以下之聚矽氧油之含量為3質量%以下,較佳為2質量%以下。 <13> The lip cosmetic according to any one of the above <1> to <12> wherein, in the component (b), the viscosity at 25 ° C is 100 mPa. The content of the polyoxygenated oil below s is 3% by mass or less, preferably 2% by mass or less.
<14>如上述<1>至<13>中任一項之口唇化妝料,其中成分(a1)及成分(a2)之總和與成分(b)的質量比例((a1)+(a2))/(b)為0.04以上0.1以下,較佳為0.09以下。 <14> The lip cosmetic according to any one of the above <1> to <13> wherein the sum of the component (a1) and the component (a2) and the mass ratio of the component (b) ((a1)+(a2)) /(b) is 0.04 or more and 0.1 or less, preferably 0.09 or less.
<15>如上述<1>至<14>中任一項之口唇化妝料,其中親油性膠化劑於全部化妝料中為2質量%以下,較佳為1質量%以下。 The lip-part cosmetic of any one of the above-mentioned <1> to <14>, wherein the lipophilic gelling agent is 2% by mass or less, preferably 1% by mass or less, based on the total amount of the cosmetic.
<16>如上述<1>至<15>中任一項之口唇化妝料,其進而含有(c)粉體。 The lip cosmetic of any one of the above-mentioned <1> to <15> which further contains (c) powder.
<17>如上述<1>至<16>中任一項之口唇化妝料,其中成分(c)之含量於全部成分中之下限為0.01質量%以上,較佳為0.1質量%以上,且上限為20質量%以下,較佳為10質量%以下。 The lip cosmetic of any one of the above-mentioned <1> to <16>, wherein the content of the component (c) is 0.01% by mass or more, preferably 0.1% by mass or more, and the upper limit of all components. It is 20% by mass or less, preferably 10% by mass or less.
<18>如上述<1>至<17>中任一項之口唇化妝料,其於30℃下之化妝料利用10mmΦ治具獲得之針入硬度為0.8~6N。 <18> The lip cosmetic according to any one of the above <1> to <17>, wherein the cosmetic at 30 ° C has a penetration hardness of 0.8 to 6 N using a 10 mm Φ fixture.
<19>如上述<1>至<18>中任一項之口唇化妝料,其係填充於管容器或蘸塗式容器中。 <19> The lip cosmetic according to any one of the above <1> to <18> which is filled in a tube container or a sputum-coated container.
藉由以下所示之方法,製造表1及表2所示之組成之口唇化妝料(口紅)。 A lip cosmetic (lipstick) of the composition shown in Tables 1 and 2 was produced by the method shown below.
測定所獲得之口唇化妝料的針入硬度及水分阻隔性, 又,對穩定性、呈色之良好程度、光澤度、無黏膩感、保養效果感及無乾燥感進行評價。將結果一併示於表1及表2。 The penetration hardness and moisture barrier property of the obtained lip cosmetic were measured. Further, the stability, coloring degree, glossiness, non-stickiness, maintenance effect, and no dry feeling were evaluated. The results are shown together in Tables 1 and 2.
將基劑原料(有色材料除外)於90℃下加熱熔解且混合均勻。其次,向其中添加有色材料原料,於加熱狀態下利用分散器均勻地分散,消泡後,注入至蘸塗式容器中獲得口紅。 The base material (except the colored material) was heated and melted at 90 ° C and mixed well. Next, a raw material of a colored material was added thereto, and it was uniformly dispersed by a disperser in a heated state, and after defoaming, it was poured into a sputum-coated container to obtain a lipstick.
測定樣品係將上述口紅整體加熱至90℃,注入至鋁製槽中,於20℃下冷卻固化,於30℃下放置2小時所得者。使用不動工業公司製造之流變計,於30℃下利用直徑10 mmΦ之治具對該樣品進行測定。該針入硬度係於工作台速度為2 mm/s之條件下,將治具插入至深度2 mm時之最大值。 In the measurement sample, the entire lipstick was heated to 90 ° C, poured into an aluminum bath, cooled and solidified at 20 ° C, and left at 30 ° C for 2 hours. The sample was measured at 30 ° C using a rheometer of 10 mm Φ using a rheometer manufactured by Immobilisation Industries. The penetration hardness is at a table speed of 2 mm/s and the fixture is inserted to a maximum of 2 mm depth.
於玻璃製試劑瓶(開口部1.5 cmΦ)中裝入水10 cc,將樣品以厚度成為25 μm之方式塗佈於濾紙(東洋濾紙公司,薄膜過濾器,微孔直徑0.2 μm)之單面,以此覆蓋開口部。測定將其於30℃、30% RH之條件下靜置12小時之時的試劑瓶之重量減少(水分減少量)。與以未塗佈有樣品之濾紙覆蓋之情形的重量減少加以比較,利用下式求出水分阻隔性。 10 cc of water was placed in a glass reagent bottle (opening 1.5 cmφ), and the sample was applied to a single side of a filter paper (Toyo Filter Co., Ltd., membrane filter, micropore diameter 0.2 μm) so as to have a thickness of 25 μm. This covers the opening. The weight of the reagent bottle (water reduction amount) at the time of standing at 30 ° C and 30% RH for 12 hours was measured. The water barrier property was determined by the following formula in comparison with the weight reduction in the case where the filter paper was not coated with the sample.
水分阻隔性(%)=(1-[塗佈有樣品時之水分減少量/未塗佈有樣品之情形之水分減少量])×100 Moisture barrier property (%) = (1 - [the amount of water reduction when a sample is applied / the amount of water reduction in the case where a sample is not coated]) × 100
將於半徑1.5 cm、高度6 cm之圓筒狀透明容器中注入至5.5 cm之高度的口紅於50℃下保存2週,目視觀察其外觀,按照以下基準判斷油劑是否分離。 The lipstick which was poured to a height of 5.5 cm in a cylindrical transparent container having a radius of 1.5 cm and a height of 6 cm was stored at 50 ° C for 2 weeks, and the appearance was visually observed, and whether the oil was separated was judged according to the following criteria.
○:與初期相比幾乎無變化。 ○: There is almost no change from the initial stage.
△:自上表面至約1 cm之位置為止分離為油劑。 △: Separated as an oil agent from the upper surface to a position of about 1 cm.
×:油劑顯著分離。 ×: The oil agent was significantly separated.
由10名專業官能檢查員,對將各口唇化妝料剛塗抹於唇上後、及3小時後的呈色之良好程度進行官能評價。以評價為良好之官能檢查員之人數進行表示。 The panel of 10 professional inspectors performed a sensory evaluation on the degree of coloration immediately after application of each lip cosmetic to the lips and after 3 hours. Expressed by the number of functional inspectors who were evaluated as good.
由10名專業官能檢查員,對將各口唇化妝料剛塗抹於唇上後、及3小時後之光澤度進行官能評價。以評價為良好之官能檢查員之人數進行表示。 The sensitivity of each of the lip cosmetic materials immediately after application to the lips and the gloss after 3 hours was evaluated by 10 professional inspectors. Expressed by the number of functional inspectors who were evaluated as good.
由專業官能檢查員10名,對將各口唇化妝料剛塗抹於唇上後、及3小時後之無黏膩感進行官能評價。以評價為良好之官能檢查員之人數進行表示。 Ten members of the professional inspector were functionally evaluated for the non-sticky feeling after applying the respective lip cosmetics to the lips and after 3 hours. Expressed by the number of functional inspectors who were evaluated as good.
由專業官能檢查員10名,對將各口唇化妝料剛塗抹於唇上後、及3小時後之保養效果感進行官能評價。以評價為良好之官能檢查員之人數進行表示。 Ten of the professional inspectors were subjected to sensory evaluation after applying the respective lip cosmetics to the lips and after 3 hours. Expressed by the number of functional inspectors who were evaluated as good.
由專業官能檢查員10名,對將各口唇化妝料剛塗抹於唇上後、及3小時後之無乾燥感進行官能評價。以評價為良好之官能檢查員之人數進行表示。 Ten members of the professional inspector were subjected to sensory evaluation immediately after applying the respective lip cosmetics to the lips and no dry feeling after 3 hours. Expressed by the number of functional inspectors who were evaluated as good.
*1:CERESIN#810(NIKKO RICA公司製造)針入度7 *1: CERESIN #810 (manufactured by NIKKO RICA) penetration 7
*2:HNP-9(日本精蠟公司製造)針入度7 *2: HNP-9 (made by Nippon Seiko Co., Ltd.) penetration 7
*3:SP3040(日本精蠟公司製造)針入度14 *3: SP3040 (made by Japan Fine Wax Company) penetration degree 14
*4:Multiwax W-445(SONNEBORN,INC.公司製造)針入度34 *4: Multiwax W-445 (manufactured by SONNEBORN, INC.) penetration 34
*5:特級精製堪地里拉蠟(CERARICA NODA公司製造)針入度1 *5: Premium refined candidella wax (manufactured by CERARICA NODA) penetration degree 1
*6:PERFORMALENE PL POLYETHYLENE(NEW PHASE TECHNOLOGIES公司製造)針入度0.5 *6: PERFORMALENE PL POLYETHYLENE (manufactured by NEW PHASE TECHNOLOGIES) penetration degree 0.5
*7:PARLEAM 46(日本油脂公司製造)平均分子量2700 *7: PARLEAM 46 (manufactured by Nippon Oil & Fats Co., Ltd.) average molecular weight 2700
*8:PARLEAM 24(日本油脂公司製造)平均分子量1350 *8: PARLEAM 24 (manufactured by Nippon Oil & Fats Co., Ltd.) average molecular weight 1350
*9:PARLEAM 18(日本油脂公司製造)平均分子量1000 *9: PARLEAM 18 (manufactured by Nippon Oil & Fats Co., Ltd.) average molecular weight of 1000
*10:SALACOS DP-418N(NISSHIN OILLIO公司製造) *10: SALACOS DP-418N (manufactured by NISSHIN OILLIO)
*11:MORESCO WHITE P500(日本油脂公司製造) *11: MORESCO WHITE P500 (manufactured by Nippon Oil & Fats Co., Ltd.)
*12:RISOCAST ODSHS(高級醇工業公司製造) *12: RISOCAST ODSHS (manufactured by Advanced Alcohol Industries)
*13:Plandool-G(日本精化公司製造) *13: Planool-G (manufactured by Nippon Seiki Co., Ltd.)
*14:COSMOL 168M(NISSHIN OILLIO公司製造) *14: COSMOL 168M (manufactured by NISSHIN OILLIO)
*15:SALACOS FH(NISSHIN OILLIO公司製造) *15: SALACOS FH (manufactured by NISSHIN OILLIO)
*16:ELDEW PS-304(味之素公司製造) *16: ELDEW PS-304 (manufactured by Ajinomoto Co., Ltd.)
*17:SH556 FLUID(DOW CORNING公司製造) *17: SH556 FLUID (manufactured by DOW CORNING)
*18:RHEOPEARL KL2(千葉製粉公司製造) *18: RHEOPEARL KL2 (manufactured by Chiba Powder Co., Ltd.)
以與實施例1~13相同之方式製造表3~表5所示之組成之口唇化妝料(口紅),測定針入硬度及水分阻隔性,又,對穩定性、呈色之良好程度、光澤度、無黏膩感、保養效果感及無乾燥感進行評價。將結果一併示於表3~表5。 The lip cosmetic (lipstick) of the composition shown in Tables 3 to 5 was produced in the same manner as in Examples 1 to 13, and the hardness and moisture barrier property of the needle were measured, and the degree of stability, coloration, and gloss were measured. Evaluation of degree, no stickiness, maintenance effect and no dry feeling. The results are shown together in Tables 3 to 5.
*19:Hi-Mic-1080(日本精蠟公司製造)針入度10 *19: Hi-Mic-1080 (made by Nippon Seiko Co., Ltd.) penetration 10
*20:Multiwax W-835(SONNEBORN,INC公司製造)針入度75 *20: Multiwax W-835 (manufactured by SONNEBORN, INC) penetration 75
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CN (1) | CN103717195B (en) |
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JP6553838B2 (en) * | 2013-08-29 | 2019-07-31 | 紀伊産業株式会社 | Stick cosmetic |
JP6244202B2 (en) * | 2013-12-27 | 2017-12-06 | 花王株式会社 | Lip cosmetics |
CN105434199B (en) * | 2015-12-28 | 2018-06-19 | 佛山市雅丽诗化妆品股份有限公司 | A kind of production technology of double-colored greasepaint |
CN106137795B (en) * | 2016-08-15 | 2020-04-17 | 广州澳希亚实业有限公司 | Composition for inhibiting sweating of lip balm and repairing lip injury |
JP6796620B2 (en) * | 2018-06-26 | 2020-12-09 | 紀伊産業株式会社 | Makeup method |
JP7340951B2 (en) * | 2019-04-25 | 2023-09-08 | 花王株式会社 | oil-based cosmetics |
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JPH10192050A (en) * | 1996-12-27 | 1998-07-28 | Kao Corp | Pen type lip cosmetic |
JP3610469B2 (en) * | 1997-06-05 | 2005-01-12 | 株式会社コーセー | Oily solid cosmetics |
JP2005247776A (en) | 2004-03-05 | 2005-09-15 | Kao Corp | Liquid lip cosmetic |
JP4786399B2 (en) | 2006-04-10 | 2011-10-05 | 株式会社 資生堂 | Non-solid lip cosmetic |
US7989002B2 (en) * | 2006-12-20 | 2011-08-02 | Avon Products, Inc | High gloss gel-based lipstick |
JP5356710B2 (en) * | 2008-03-27 | 2013-12-04 | 株式会社コーセー | Oily cosmetics |
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