CN103717195B - Lip cosmetic - Google Patents
Lip cosmetic Download PDFInfo
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- CN103717195B CN103717195B CN201280037373.5A CN201280037373A CN103717195B CN 103717195 B CN103717195 B CN 103717195B CN 201280037373 A CN201280037373 A CN 201280037373A CN 103717195 B CN103717195 B CN 103717195B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
A kind of lip cosmetic, the lip cosmetic contains following composition（a）With（b）：（a）Wax, comprises at least（a1）Needle penetration at 25 DEG C be 5~20 hydrocarbon wax and（a2）Needle penetration at 25 DEG C more than 20 and for less than 110 hydrocarbon wax, its content is 1~9 mass % in cosmetics entirety；（b）It is liquid or the finish of paste, composition at 25 DEG C（a1）And composition（a2）Mass ratio be（a1）/（a2）=1/17~80/1, composition（a1）And composition（a2）Summation and composition（b）Mass ratio be（（a1）+（a2））/（b）=0.02~0.12, composition（b）Viscosity at 25 DEG C is 500~10000mPas, and the pin of 10mm φ fixtures used for cosmetic enters hardness for 0.5~9N at 30 DEG C.
Description
Technical field
The present invention relates to lip cosmetic.
Background technology
Lip cosmetic has lipstick, lipstick, lip gloss（lip gloss）Deng using bar-shaped type as its shape（Solid
Shape）, directly the solid that is filled in metal stamper or resin dish etc. pour into type, the liquid type being filled in pipe or bottle
（Non-solid shape）Deng.
Wherein, its color development of the solid-like lipstick of bar-shaped grade is good, but is wanting in gloss.In addition, with lip gloss as representative
Non-solid its gloss of shape lip cosmetic it is very high, but at color development, tackiness, wetability, the aspect such as continuation of wetting
Not enough.
Therefore, gloss has been inquired into and color development is good, use feeling is good, and wettability lip cosmetic high.
For example, proposing there is the non-solid lip for containing high viscosity oil and specific semisolid oil with specific ratio
Cosmetic（Patent document 1）.Although the non-solid lip cosmetic is not tacky, the gloss and transparent feel during coating are excellent, hair
Color, wetability, the continuation of wetting are wanting in.
In addition, also having inquired into the paste lip containing specific wax, dextrin fatty acid ester, oil-soluble resin and tabular powder
Cosmetics（Patent document 2）, or the oil-based cosmetic containing 2 kinds of different hydrocarbon of fusing point, water-retaining property oil and dextrin fatty acid ester
Product（Patent document 3）Deng.However, in these cosmetics, although use feeling is good, but due to having used gelling agent, therefore,
There are wetability, the problem of the continuation reduction of wetting.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2007-277189 publications
Patent document 2：Japanese Unexamined Patent Publication 2002-193749 publications
Patent document 3：Japanese Unexamined Patent Publication 2007-262033 publications
The content of the invention
The present invention provides a kind of lip cosmetic, and the lip cosmetic contains following composition（a）With（b）：
（a）Wax, comprises at least（a1）Needle penetration at 25 DEG C be 5~20 hydrocarbon wax and（a2）Needle penetration at 25 DEG C surpasses
Cross 20 and for less than 110 hydrocarbon wax, its content in cosmetics entirety be 1~9 mass %；
（b）It is the finish of liquid or paste at 25 DEG C,
Composition（a1）And composition（a2）Mass ratio be（a1）/（a2）=1/17~80/1,
Composition（a1）And composition（a2）Summation and composition（b）Mass ratio be（（a1）+（a2））/（b）=0.02~
0.12,
Composition（b）Viscosity at 25 DEG C is 500~10000mPas,
The pin of 10mm φ fixtures used for cosmetic enters hardness for 0.5~9N at 30 DEG C.
Specific embodiment
Gloss, color development and use feeling the present invention relates to not damage after the completion of smearing is good, and wettability is high, and
The lasting lip cosmetic of its wetness sensation.
Present inventors found that：Using comprising 2 kinds of different waxes of hydrocarbon wax of needle penetration, the oil of particular viscosity is combined into
Agent, and form specific pin and enter the lip cosmetic of hardness and solve above-mentioned technical problem.
Lip cosmetic color development of the invention is good, and the excellent gloss after the completion of smearing, not tacky, wettability
Height, and its wettability is lasting.
The composition used in the present invention（a）Wax be at 25 DEG C be the oil components of solid, comprise at least（a1）At 25 DEG C
Needle penetration be 5~20 hydrocarbon wax and（a2）Needle penetration at 25 DEG C more than 20 and for less than 110 hydrocarbon wax.
Here, needle penetration is the pin for determining regulation（The quality of pin is 2.5 ± 0.02g, the quality of needle lock for 47.5 ±
0.02g, the quality of counterweight is 50 ± 0.05g）Being held in the length that pin enters on the sample of 25 ± 0.1 DEG C of wax in 5 seconds,
The pin is entered into distance（The value of 10 times mm), as needle penetration, is according to JIS K-2235-5.4（1991）The value of measure.
As（a1）Needle penetration at 25 DEG C is 5~20 hydrocarbon wax, for example, can enumerate ceresine（ozokerite）, it is white
Ceresine（ceresin）Deng mineral substance wax；The petroleum-type wax of paraffin, vaseline etc.；Fischer-tropsch wax（Fischer-Tropsch wax）、
The synthesis hydrocarbon of Tissuemat E etc..
These waxes can use commercially available product, such as, as ceresin, can enumerate Ceresin#810, Ceresin B（With
Upper is Nikko Rica Co. manufactures）；As paraffin, can enumerate ParaffinWax125,140,150,155, HNP-3,9,
10、11、12、51、SP-0135、0140、0145、0160、0165、3035、3040（Above for Jing La companies of Japan manufacture）；Make
It is fischer-tropsch wax, FT-0070,100,105,115,0165,5165, FNP-0115 can be enumerated（It is above Japan's essence wax company system
Make）；As Tissuemat E, PERFORMALENEPL POLYETHYLENE, PERFORMALENE400,500,655 can be enumerated
（Manufactured by NEWPHASE TECHNOLOGIES companies above）Deng.（a1）Needle penetration at 25 DEG C is more preferably 6~
18。
In addition, conduct（a2）Needle penetration at 25 DEG C more than 20 and for less than 110 hydrocarbon wax, crystallite can be enumerated
Wax, paraffin etc., preferably microwax.
These waxes can use commercially available product, for example, can enumerate MultiwaxW-445, W-835 as microwax（Above by
SONNEBORN companies manufacture）、Hi-Mic-1045、1070、1080、1090、2045、2065、2095（It is public by Japanese essence wax above
Department's manufacture）, refined microwax（Nikko Rica Co.）、155°Microwax（Japan National Oil Corp）Deng.（a2）At 25 DEG C
Needle penetration be more preferably 25~80.
As composition（a）Wax,（a1）The needle penetration of hydrocarbon wax be preferably 6~18, and（a2）Hydrocarbon wax pin
In-degree is preferably 25~80.In addition,（a1）Preferably ceresin, paraffin,（a2）Preferably microwax.
In the present invention,（a1）With（a2）Mass ratio be（a1）/（a2）=1/17~80/1, it is higher in order to obtain
Wettability（Or the obstructive film of high-moisture）, preferably 1/8~70/1, more preferably 2/7~25/1.
In the present invention, composition（a）Wax total amount all composition in add up to 1~9 mass %.Further, from lip
From the viewpoint of the color development or stability of portion's cosmetics, preferably more than 2 mass %, more preferably more than 3 mass %, on
Limit is preferably below 8.5 mass %, more preferably below 8 mass %.Additionally, it is preferred that be 2~8.5 mass %, more preferably
3~8 mass %.
Further, preferably（a1）It is 0.1~7 mass %,（a2）It is 0.1~4 mass %.
Composition（a）Wax can contain in the range of effect of the invention not damaging（a1）With（a2）Wax in addition.Make
For（a1）With（a2）Wax in addition, for example, can enumerate Brazil wax, candelila wax, rice bran wax, haze tallow（wood wax）Deng
Plant wax；The animality wax of beeswax, spermaceti etc.；The synthetic wax of Tissuemat E, silicone wax etc.；Aliphatic acid, higher alcohol and it
Derivative.These（a1）With（a2）Wax in addition, from from the viewpoint of use feeling and wettability, preferably in whole waxes
It is below 5 mass %, more preferably below 3 mass %.
The composition used in the present invention（b）Finish be finish at 25 DEG C for liquid or paste, only mixing this
A little compositions（b）Whole finishes when, viscosity of these mixtures at 25 DEG C be 500~10000mPas.From use feeling
Or from the viewpoint of stability, composition（b）Lower viscosity limit of the mixture at 25 DEG C be preferably more than 700mPas, enter one
Step is preferably more than 1000mPas, and the upper limit is preferably below 8000mPas, more preferably below 7000mPas.
In addition, the measure of viscosity is to use Brookfield viscometer（Dong Ji industry companies：TVB-10）Under conditions of 25 DEG C, will
Condition of the No.4 rotors with rotating speed as 6rpm rotates what is determined within 1 minute.
As composition（b）Be the finish of liquid or paste at 25 DEG C, it is possible to use a kind is applied in combination 2 kinds
More than for the finish in common cosmetics.Composition（b）Two or more is used preferred compositions, preferably at least contains more than a kind
Paste finish.
Here, liquid or paste finish refer to the finish with mobility at 25 DEG C, wherein, paste finish is in room
Temperature~60 DEG C nearby with fusing point finish.
Specifically, vaseline, saualane, atoleine, liquid isoparaffin, polybutene, hydrogenation can be enumerated poly- different
The hydrocarbon ils of butylene, Nexbase 2004 etc.；Different n-nonanoic acid isotridecyl ester, isopropyl isostearate, neopentyl glycol dicaprate, two
Glyceryl isostearate, three glyceryl isostearates, the iso stearyl ester of malic acid two, jojoba oil, octyldodecanol, the N- months
Osmanthus acyl group-Pidolidone two（Phytosterol/2- octyldodecyls）The ester oil of ester etc.；Dimethyl polysiloxane, phenyl methyl
The silicone oil of polysiloxanes etc.；Lanolin, dimeric dibasic acid ester, dimer diol（dimer diol）Derivative, cholesterol fatty acid ester,
Phytosterin fatty acid ester, polyglyceryl fatty acid ester, pentaerythritol fatty ester etc..
In the present invention, in composition（b）At 25 DEG C for the whole finish of liquid or paste in, unthickened fuel is preferably
More than 40 mass % and below 95 mass %.
In addition, in composition（b）Finish in, the viewpoint of the continuation of never tacky, gloss and wetability and wetting goes out
Hair, preferably comprises the hydrocarbon ils that mean molecule quantity is more than 1200.Mean molecule quantity is the content of more than 1200 hydrocarbon ils in composition
（b）The middle upper limit is preferably below 60 mass %, more preferably below 50 mass %, and lower limit is preferably more than 10 mass %, enters one
Step is preferably more than 20 mass %, more preferably more than 30 mass %, is still more preferably more than 40 mass %.
In addition, from from the viewpoint of stability and nursing efficacy, the viscosity at 25 DEG C is the silicone oil of below 100mPas
Content preferably in composition（b）In be below 3 mass %, more preferably below 2 mass %.
In addition, the viscosity of silicone oil is to use vibrating type viscometer（A&D Company,Limited：SV type viscosimeters SV-
10VIBRO VISCOMETER）The viscosity of measure.
Excellent gloss from after the completion of smearing and not tacky, does not damage from the viewpoint of use feeling, composition（b）Oil
Agent is preferably more than 30 mass % in cosmetics entirety lower limit, more preferably more than 40 mass %, more preferably 50 matter
Amount more than %, be still more preferably more than 60 mass %, the upper limit is preferably below 95 mass %, more preferably 90 mass % with
Under.
In the present invention, composition（a1）And composition（a2）Summation and composition（b）Mass ratio be（（a1）+（a2））/
（b）=0.02~0.12, from moisture it is obstructive it is excellent, smear after the completion of excellent gloss, the lasting sight of not tacky, wettability
Point sets out, and lower limit is preferably more than 0.04, and the upper limit is preferably less than 0.1, more preferably less than 0.09.In addition（（a1）+
（a2））/（b）Preferably 0.02~0.1, more preferably 0.04~0.09.
Lip cosmetic of the invention can continue due to the crystallization, stability or the wetability that do not hinder wax, thus,
The content of lipophile gelling agent is preferably below 2 mass %, more preferably below 1 mass % in cosmetics entirety, more
Preferably actually mismatch.
As such lipophile gelling agent, for example, can enumerate dextrin palmitate, dextrin stearate, dextrin cocounut oil
The dextrin fatty acid ester of fatty acid ester etc.；Sucrose fatty ester, 12- hydroxy stearic acids etc..
Lip cosmetic of the invention can further contain（c）Powder.As described powder, as long as common
What is used in cosmetics does not just limit, it is possible to use extender pigment, coloring pigment, pearlescent pigment etc..
As extender pigment, for example, can enumerate silicic acid, silicic acid anhydride, magnesium silicate, talcum, sericite, mica, kaolinite
Soil, clay, bentonite, bismoclite, zirconium oxide, magnesia, aluminum oxide, calcium sulfate, barium sulfate, magnesium sulfate, calcium carbonate, carbonic acid
The inorganic pigment of magnesium etc. and their composite granule.
As coloring pigment, for example, can enumerate titanium oxide, zinc oxide, yellow iron oxide, iron oxide red, black oxidation
The metal complex of metal oxide, manganese violet, the cobalt titanate of iron, Prussian blue, ultramarine, chromium oxide, chromium hydroxide etc. etc., enters one
Step can enumerate the natural pigment of organic pigment, the famille rose of inorganic pigment, tar class pigment, the mordant pigment of carbon black etc. etc. etc.
Deng.
As pearlescent pigment, it is possible to use with titanium oxide, iron oxide, silica, Prussian blue, chromium oxide, famille rose, have
The colouring agent of machine pigment etc. has coated pearlescent pigment behind the surface of mica, synthesis phlogopite, glass etc. etc..
These powders can also carry out each of water-proofing treatment, waterproof and anti-oiling treatment etc. using the method by commonly using
Plant the powder of surface treatment.
Composition（c）Powder can using a kind or two or more, all composition lower limits be preferably 0.01 mass % with
On, more preferably more than 0.1 mass %, the upper limit is preferably below 20 mass %, more preferably below 10 mass %.Separately
Outward, 0.01~20 mass %, further preferably 0.1~10 mass % are preferably contained in all compositions.
Lip cosmetic of the invention can be not being damaged in the range of effect of the invention containing in common cosmetics
The composition for using, such as surfactant, lower alcohol, polyalcohol, macromolecular compound, ultra-violet absorber, antioxidant, perfume (or spice)
Material, anti-fouling agent, NMF, water etc..
The pin of the fixture of the 10mm φ that lip cosmetic of the invention applies some make up at 30 DEG C enters hardness for 0.5~9N,
Preferably 0.8~6N.If within this range, being easily filled in tubular container or dipping multi container during fabrication
（dipping vessel）In, in addition, being for the user that liquid drippage, the hardness being easily coated with are less likely to occur.
" pin enters hardness " in the present invention refers to the rheometer that will be manufactured using motionless industrial group, in 30 DEG C of lower clamps
A diameter of 2mm is with the speed of table（table speed）Be the speed of 2mm/s, fixture pin enter to depth be 2mm when maximum
It is scaled the numerical value on per unit area.
Lip cosmetic of the invention can be manufactured by usual way, be obtained as the cosmetics of non-solid shape
Arrive.Lipstick, lipstick, lip gloss, lip line etc. can be made.
Although here, non-solid shape in bulk, be the low shape of the shape-retaining ability of the degree that can not be molded in mould etc.
State, the state not used in the feeding container as bar-shaped.Lip cosmetic of the invention is preferably filled and holds in tubulose
In device, dipping multi container etc..
For above-mentioned implementation method, the present invention further discloses following composition.
<1>A kind of lip cosmetic, wherein, contain following composition（a）With（b）：
（a）Wax, comprises at least（a1）Needle penetration at 25 DEG C be 5~20 hydrocarbon wax and（a2）Needle penetration at 25 DEG C surpasses
Cross 20 and for less than 110 hydrocarbon wax, its content in cosmetics entirety be 1~9 mass %；
（b）It is the finish of liquid or paste at 25 DEG C,
Composition（a1）And composition（a2）Mass ratio be（a1）/（a2）=1/17~80/1,
Composition（a1）And composition（a2）Summation and composition（b）Mass ratio be（（a1）+（a2））/（b）=0.02~
0.12,
Composition（b）Viscosity at 25 DEG C is 500~10000mPas,
The pin of 10mm φ fixtures used for cosmetic enters hardness for 0.5~9N at 30 DEG C.
<2>As described above<1>Described lip cosmetic, wherein,（a1）Needle penetration of the hydrocarbon wax at 25 DEG C for 6~
18。
<3>As described above<1>Or<2>Described lip cosmetic, wherein,（a2）Needle penetration of the hydrocarbon wax at 25 DEG C be
25~80.
<4>As described above<1>~<3>Any one of lip cosmetic, wherein,（a1）With（a2）Mass ratio be
（a1）/（a2）=1/8~70/1, preferably 2/7~25/1.
<5>As described above<1>~<4>Any one of lip cosmetic, wherein, composition（a）Content in cosmetics
It is 2~8.5 mass %, preferably 3~8 mass % in entirety.
<6>As described above<1>~<5>Any one of lip cosmetic, wherein,（a1）It is selected from mineral substance wax, stone
Wax in oils wax and synthesis hydrocarbon, preferably ceresin, paraffin.
<7>As described above<1>~<6>Any one of lip cosmetic, wherein,（a2）It is selected from microwax and paraffin
In wax, preferably microwax.
<8>As described above<1>~<7>Any one of lip cosmetic, wherein,（a1）Content in cosmetics entirety
In be 0.1~7 mass %,（a2）Content in cosmetics entirety be 0.1~4 mass %.
<9>As described above<1>~<8>Any one of lip cosmetic, wherein, composition（b）Mixture at 25 DEG C
Under lower viscosity limit be more than 700mPas, preferably more than 1000mPas, the upper limit be below 8000mPas, preferably
Below 7000mPas.
<10>As described above<1>~<9>Any one of lip cosmetic, wherein, composition（b）Content in cosmetics
Overall lower limit be more than 30 mass %, more preferably preferably more than 40 mass %, more than 50 mass %, more preferably
More than 60 mass %, the upper limit is below 95 mass %, preferably below 90 mass %.
<11>As described above<1>~<10>Any one of lip cosmetic, wherein, composition（b）Whole finishes in
Unthickened fuel is more than 40 mass % and below 95 mass %.
<12>As described above<1>~<11>Any one of lip cosmetic, wherein, composition（b）In, mean molecule quantity
For the upper content limit of more than 1200 hydrocarbon ils is below 60 mass %, preferably below 50 mass %, lower limit is more than 10 mass %,
Preferably more than 20 mass %, more preferably more than 30 mass %, more preferably more than 40 mass %.
<13>As described above<1>~<12>Any one of lip cosmetic, wherein, composition（b）In, it is viscous at 25 DEG C
The content for spending the silicone oil for below 100mPas is below 3 mass %, preferably below 2 mass %.
<14>As described above<1>~<13>Any one of lip cosmetic, wherein, composition（a1）And composition（a2）'s
Summation and composition（b）Mass ratio（（a1）+（a2））/（b）It is more than 0.04 and less than 0.1, preferably less than 0.09.
<15>As described above<1>~<14>Any one of lip cosmetic, wherein, lipophile gelling agent is in cosmetics
It is below 2 mass %, preferably below 1 mass % in entirety.
<16>As described above<1>~<15>Any one of lip cosmetic, wherein, further contain（c）Powder.
<17>As described above<1>~<16>Any one of lip cosmetic, wherein, composition（c）Content in whole
Composition lower limit is more than 0.01 mass %, and preferably more than 0.1 mass %, the upper limit is below 20 mass %, preferably 10 mass %
Below.
<18>As described above<1>~<17>Any one of lip cosmetic, wherein, the 10mm used for cosmetic at 30 DEG C
The pin of φ fixtures enters hardness for 0.8~6N.
<19>As described above<1>~<18>Any one of lip cosmetic, wherein, be filled in tubular container or
In dipping multi container.
Embodiment 1~13 and comparative example 1~5
By method as shown below, the lip cosmetic of composition shown in manufacture Tables 1 and 2（Lipstick）.
For the lip cosmetic for obtaining, measure pin enters hardness and moisture is obstructive, in addition, evaluation stability, color development
Excellent, gloss, whether there is tacky, nursing efficacy sense and whether there is dry sensation.Result is shown in Tables 1 and 2 in the lump.
（Manufacture method）
By base raw material（Except color material）Heated at 90 DEG C and melt and equably mix.Next, being added to color
Material raw material is allowed to be uniformly dispersed in a heated state in dispersion machine, after deaeration, is injected into dipping multi container, obtains mouth
It is red.
（Evaluation method）
（1）Pin enters hardness：
Determination sample is that block is heated into 90 DEG C, is injected into the certain aluminum sample pond of diameter, is cooled down at 20 DEG C
Solidification, the sample that placement is obtained for 2 hours at 30 DEG C.The rheometer manufactured using motionless industrial group to the sample, at 30 DEG C
The lower fixture with a diameter of 10mm φ is measured.The speed of table for 2mm/s speed lower clamp pin enter to depth be 2mm when
Maximum.
（2）Moisture is obstructive：
To glass system sample bottle（Opening portion 1.5cm φ）The water of middle loading 10cc, filter paper is coated by sample（Japan's filter paper
Company, membrane filter, aperture is 0.2 μm）One side on make 25 μm of thickness, cover opening portion with it.Determining will
The weight decrement of its sample bottle when being stood 12 hours under conditions of 30 DEG C, 30%RH（Moisture decrement）.Applied with no
Weight decrement in the case that the filter paper of cloth sample is covered compares, and it is obstructive to try to achieve moisture by following formula.
Moisture is obstructive（%）=（1- [the moisture in the case of moisture decrement when being coated with sample/without coated sample
Decrement]）×100
（3）Stability：
Will be implanted into radius for 1.5cm, highly for 6cm cylindric transparent vessel in lipstick 5.5cm high, at 50 DEG C
It is lower to preserve 2 weeks, its outward appearance is visually observed, judge whether finish separates according to following standard.
○：With preliminary phase than essentially unchangedization.
△：Finish is separated to the position of 1cm or so from above.
×：Finish is significantly separated.
（4）Color development it is excellent：
After specially evaluating group members to just coating on lip each lip cosmetic by 10 and after 3 hours
The Optimality of color development carries out sensory evaluation.Represented with the number for being evaluated as good evaluation group member.
（5）Gloss：
After specially evaluating group members to just coating on lip each lip cosmetic by 10 and after 3 hours
Gloss carries out sensory evaluation.Represented with the number for being evaluated as good evaluation group member.
（6）Whether there is tacky：
After specially evaluating group members to just coating on lip each lip cosmetic by 10 and after 3 hours
It is the presence or absence of tackiness to carry out sensory evaluation.Represented with the number for being evaluated as good evaluation group member.
（7）Nursing efficacy sense：
After specially evaluating group members to just coating on lip each lip cosmetic by 10 and after 3 hours
Nursing efficacy sense carries out sensory evaluation.Represented with the number for being evaluated as good evaluation group member.
（8）Whether there is dry sensation：
After specially evaluating group members to just coating on lip each lip cosmetic by 10 and after 3 hours
Whetheing there is dry sensation carries out sensory evaluation.Represented with the number for being evaluated as good evaluation group member.
*1：Ceresin#810（Nikko Rica Co. are manufactured）Needle penetration 7
*2：HNP-9（Japanese Jing La companies manufacture）Needle penetration 7
*3：SP3040（Japanese Jing La companies manufacture）Needle penetration 14
*4：Multiwax W-445（SONNEBORN, INC. company manufacture）Needle penetration 34
*5：Refined candelila wax is superfine（CERARICA NODA Co., Ltd. manufactures）Needle penetration 1
*6：PERFORMALENE PL POLYETHYLENE（NEW PHASETECHNOLOGIES companies manufacture）Needle penetration
0.5
*7：PARLEAM46（Nof Corp. manufactures）Mean molecule quantity 2700
*8：PARLEAM24（Nof Corp. manufactures）Mean molecule quantity 1350
*9：PARLEAM18（Nof Corp. manufactures）Mean molecule quantity 1000
*10：SALACOS DP-418N（Qing OilliO companies manufacture）
*11：MORESCO WHITE P500（Nof Corp. manufactures）
*12：RISOCAST ODSHS（KOKYU ALCOHOL KOGYO CO.,LTD.）
*13：Plandool-G（Japan refine company manufacture）
*14：Cosmol168M（Qing OilliO companies manufacture）
*15：SALACOS FH（Qing OilliO companies manufacture）
*16：Eldew PS-304（AJINOMOTO CO., INC. manufactures）
*17：SH556FLUID（Dow Corning Toray Co., Ltd. manufactures）
*18：Rheopearl KL2（Chiba Zhi Fen companies manufacture）
Embodiment 14~26 and comparative example 6~10
The lip cosmetic of composition shown in 3~table of table 5 is manufactured in the same manner as embodiment 1~13（Lipstick）, determine pin and enter firmly
Degree and moisture are obstructive, in addition, evaluating stability, the excellent of color development, gloss, whetheing there is tacky, nursing efficacy sense and whether there is
Dry sensation.Result is shown in 3~table of table 5 in the lump.
*19：Hi-Mic-1080（Japanese Jing La companies manufacture）Needle penetration 10
*20：Multiwax W-835（SONNEBORN, INC company manufacture）Needle penetration 75
[table 3]
Claims (25)
1. a kind of lip cosmetic, wherein,
Contain following composition (a), (b) and (c)：
(a) wax, comprising 25 DEG C of the hydrocarbon wax and (a2) that the needle penetration at 25 DEG C of (a1) is 5~20 at needle penetration is more than 20 and is
Less than 110 hydrocarbon wax, its content is 1~9 mass % in cosmetics entirety；
It is liquid or the finish of paste, more than 60 mass % and below 95 mass % at 25 DEG C of (b),
(c) powder, 0.1~10 mass %,
The mass ratio of composition (a1) and composition (a2) is (a1)/(a2)=1/17~80/1,
The summation of composition (a1) and composition (a2) is ((a1)+(a2))/(b)=0.02~0.12 with the mass ratio of composition (b),
Viscosity of the composition (b) at 25 DEG C is 500~10000mPas,
The pin of 10mm φ fixtures used for cosmetic enters hardness for 0.5~5.0N at 30 DEG C,
The needle penetration is to determine the pin of regulation in 5 seconds being held in the length that pin enters on the sample of 25 ± 0.1 DEG C of wax,
The pin is entered the value apart from 10 times of mm as needle penetration, is the value determined according to the JIS K-2235-5.4 of 1991, the pin
Quality be 2.5 ± 0.02g, the quality of needle lock is 47.5 ± 0.02g, and the quality of counterweight is 50 ± 0.05g,
It refers to the rheometer that will be manufactured using motionless industrial group that pin enters hardness, in 30 DEG C of a diameter of 2mm of lower clamp working
Platform speed is the speed of 2mm/s, fixture pin enter to depth be 2mm when maximum be scaled numerical value on per unit area.
2. lip cosmetic as claimed in claim 1, wherein,
The content of composition (b) is 60~90 mass % in cosmetics entirety.
3. lip cosmetic as claimed in claim 1 or 2, wherein,
Viscosity of the mixture of composition (b) at 25 DEG C is 700~8000mPas.
4. lip cosmetic as claimed in claim 1 or 2, wherein,
Viscosity of the mixture of composition (b) at 25 DEG C is 1000~7000mPas.
5. lip cosmetic as claimed in claim 1 or 2, wherein,
In whole finishes of composition (b), unthickened fuel is 40~95 mass %.
6. lip cosmetic as claimed in claim 1 or 2, wherein,
In composition (b), mean molecule quantity is that the content of more than 1200 hydrocarbon ils is 10~60 mass %.
7. lip cosmetic as claimed in claim 1 or 2, wherein,
In composition (b), mean molecule quantity is that the content of more than 1200 hydrocarbon ils is 20~60 mass %.
8. lip cosmetic as claimed in claim 1 or 2, wherein,
In composition (b), mean molecule quantity is that the content of more than 1200 hydrocarbon ils is 30~50 mass %.
9. lip cosmetic as claimed in claim 1 or 2, wherein,
In composition (b), mean molecule quantity is that the content of more than 1200 hydrocarbon ils is 40~50 mass %.
10. lip cosmetic as claimed in claim 1 or 2, wherein,
(a1) content is 0.1~7 mass % in cosmetics entirety, and the content of (a2) is 0.1~4 matter in cosmetics entirety
Amount %.
11. lip cosmetics as claimed in claim 1 or 2, wherein,
(a1) needle penetration at 25 DEG C is 6~18.
12. lip cosmetics as claimed in claim 1 or 2, wherein,
(a2) needle penetration at 25 DEG C is 25~80.
13. lip cosmetics as claimed in claim 1 or 2, wherein,
(a1) and (a2) mass ratio be (a1)/(a2)=1/8~70/1.
14. lip cosmetics as claimed in claim 1 or 2, wherein,
The summation of composition (a1) and composition (a2) is ((a1)+(a2))/(b)=0.02~0.1 with the mass ratio of composition (b).
15. lip cosmetics as claimed in claim 1 or 2, wherein,
The summation of composition (a1) and composition (a2) is ((a1)+(a2))/(b)=0.04~0.09 with the mass ratio of composition (b).
16. lip cosmetics as claimed in claim 1 or 2, wherein,
(a1) it is selected from the wax in mineral substance wax, pertroleum wax and synthesis hydrocarbon.
17. lip cosmetics as claimed in claim 1 or 2, wherein,
(a2) it is selected from the wax in microwax and paraffin.
18. lip cosmetics as claimed in claim 1 or 2, wherein,
The content of composition (a) is 2~8.5 mass % in cosmetics entirety.
19. lip cosmetics as claimed in claim 1 or 2, wherein,
In composition (b), the viscosity at 25 DEG C is that the content of the silicone oil of below 100mPas is below 3 mass %.
20. lip cosmetics as claimed in claim 1 or 2, wherein,
The content of lipophile gelling agent is below 2 mass % in cosmetics entirety.
21. lip cosmetics as claimed in claim 1 or 2, wherein,
The content of lipophile gelling agent is below 1 mass % in cosmetics entirety.
22. lip cosmetics as claimed in claim 1 or 2, wherein,
Actually mismatch lipophile gelling agent.
23. lip cosmetics as claimed in claim 1 or 2, wherein,
The pin with 10mm φ fixtures of cosmetics enters hardness for 0.8~5.0N at 30 DEG C.
24. lip cosmetics as claimed in claim 1 or 2, wherein,
The lip cosmetic is filled in tubular container or dipping multi container.
Lip cosmetic any one of 25. claims 1~24 is used to coat the use of the non-treatment purpose on lip
On the way.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-172689 | 2011-08-08 | ||
| JP2011172689 | 2011-08-08 | ||
| PCT/JP2012/069844 WO2013021943A1 (en) | 2011-08-08 | 2012-08-03 | Lip cosmetic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103717195A CN103717195A (en) | 2014-04-09 |
| CN103717195B true CN103717195B (en) | 2017-05-31 |
Family
ID=47668451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280037373.5A Active CN103717195B (en) | 2011-08-08 | 2012-08-03 | Lip cosmetic |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6000013B2 (en) |
| KR (1) | KR101938908B1 (en) |
| CN (1) | CN103717195B (en) |
| MY (1) | MY180589A (en) |
| TW (1) | TWI569811B (en) |
| WO (1) | WO2013021943A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6553838B2 (en) * | 2013-08-29 | 2019-07-31 | 紀伊産業株式会社 | Stick cosmetic |
| JP6244202B2 (en) * | 2013-12-27 | 2017-12-06 | 花王株式会社 | Lip cosmetics |
| CN105434199B (en) * | 2015-12-28 | 2018-06-19 | 佛山市雅丽诗化妆品股份有限公司 | A kind of production technology of double-colored greasepaint |
| CN106137795B (en) * | 2016-08-15 | 2020-04-17 | 广州澳希亚实业有限公司 | Composition for inhibiting sweating of lip balm and repairing lip injury |
| JP6796620B2 (en) * | 2018-06-26 | 2020-12-09 | 紀伊産業株式会社 | Makeup method |
| JP7340951B2 (en) * | 2019-04-25 | 2023-09-08 | 花王株式会社 | oil-based cosmetics |
| JP7541326B2 (en) | 2020-05-08 | 2024-08-28 | 株式会社トキワ | Water-based cosmetics |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10192050A (en) * | 1996-12-27 | 1998-07-28 | Kao Corp | Pen type lip cosmetic |
| JP3610469B2 (en) * | 1997-06-05 | 2005-01-12 | 株式会社コーセー | Oily solid cosmetics |
| JP2005247776A (en) | 2004-03-05 | 2005-09-15 | Kao Corp | Liquid lip cosmetic |
| JP4786399B2 (en) | 2006-04-10 | 2011-10-05 | 株式会社 資生堂 | Non-solid lip cosmetic |
| US7989002B2 (en) * | 2006-12-20 | 2011-08-02 | Avon Products, Inc | High gloss gel-based lipstick |
| JP5322198B2 (en) * | 2007-09-25 | 2013-10-23 | 株式会社 資生堂 | Cosmetics for lips |
| JP5356710B2 (en) * | 2008-03-27 | 2013-12-04 | 株式会社コーセー | Oily cosmetics |
| JP5651307B2 (en) * | 2009-08-06 | 2015-01-07 | 花王株式会社 | Oily cosmetics |
-
2012
- 2012-08-03 JP JP2012172779A patent/JP6000013B2/en active Active
- 2012-08-03 CN CN201280037373.5A patent/CN103717195B/en active Active
- 2012-08-03 MY MYPI2013004297A patent/MY180589A/en unknown
- 2012-08-03 WO PCT/JP2012/069844 patent/WO2013021943A1/en active Application Filing
- 2012-08-03 KR KR1020137032855A patent/KR101938908B1/en active IP Right Grant
- 2012-08-08 TW TW101128664A patent/TWI569811B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140047613A (en) | 2014-04-22 |
| MY180589A (en) | 2020-12-03 |
| WO2013021943A1 (en) | 2013-02-14 |
| JP2013053141A (en) | 2013-03-21 |
| JP6000013B2 (en) | 2016-09-28 |
| CN103717195A (en) | 2014-04-09 |
| KR101938908B1 (en) | 2019-01-15 |
| TW201311278A (en) | 2013-03-16 |
| TWI569811B (en) | 2017-02-11 |
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