TWI547983B - Semiconductor device and method of fabricating the same - Google Patents

Semiconductor device and method of fabricating the same Download PDF

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TWI547983B
TWI547983B TW104117067A TW104117067A TWI547983B TW I547983 B TWI547983 B TW I547983B TW 104117067 A TW104117067 A TW 104117067A TW 104117067 A TW104117067 A TW 104117067A TW I547983 B TWI547983 B TW I547983B
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layer
fin structures
dielectric
comb
substrate
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TW104117067A
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TW201642330A (en
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林烙躍
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旺宏電子股份有限公司
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半導體元件及其製造方法Semiconductor component and method of manufacturing same

本發明是有關於一種半導體元件及其製造方法。The present invention relates to a semiconductor device and a method of fabricating the same.

隨著半導體元件的積體化,為了達到高密度以及高效能的目標,在製造半導體元件時,傾向形成向上堆疊的結構,以更有效利用晶圓面積。因此,小尺寸元件中經常出現高深寬比(high aspect ratio)的半導體結構或開口。With the integration of semiconductor elements, in order to achieve high density and high performance, when manufacturing semiconductor elements, it tends to form an upward stacked structure to more effectively utilize the wafer area. Therefore, high aspect ratio semiconductor structures or openings often occur in small size components.

在製造上述元件時,為了形成具有高深寬比(high aspect ratio)的溝渠,通常會採用非常高的蝕刻選擇比進行圖案化製程。然而,在使用非常高的蝕刻選擇比的情況下,會有位於溝渠的側壁的材料層無法完全被移除的問題。一旦溝渠的側壁殘留有材料層且上述材料層為導體時,則會在半導體元件之間產生不當的導通,進而使元件的電性表現劣化。因此,如何在具有高深寬比的溝渠的半導體結構中,以溝渠的側壁不殘留材料層的方式,進行材料層(導體層)的圖案化,為當前所需研究的課題。In the fabrication of the above components, in order to form trenches having a high aspect ratio, a very high etching selectivity is typically employed for the patterning process. However, in the case of using a very high etching selectivity ratio, there is a problem that the material layer on the sidewall of the trench cannot be completely removed. When a material layer remains on the sidewall of the trench and the material layer is a conductor, improper conduction occurs between the semiconductor elements, and the electrical performance of the device is deteriorated. Therefore, how to pattern a material layer (conductor layer) in a semiconductor structure having a trench having a high aspect ratio without leaving a material layer on the sidewall of the trench is a subject of current research.

本發明提供一種半導體元件的製造方法,其可在具有高深寬比的溝渠的半導體結構進行材料層(導體層)的圖案化時,使得溝渠的側壁不殘留材料層或減少材料層殘留。The present invention provides a method of fabricating a semiconductor device in which a material layer (conductor layer) is patterned in a semiconductor structure having a trench having a high aspect ratio so that a sidewall of the trench does not leave a material layer or a material layer remains.

本發明提供一種半導體元件的製造方法。上述半導體元件的製造方法包括以下步驟。在基底上形成多個鰭狀結構,相鄰的上述鰭狀結構之間具有開口。形成導體材料層,以覆蓋上述鰭狀結構並填滿上述開口。圖案化上述導體材料層以及上述鰭狀結構,以形成網狀結構。上述網狀結構具有在第一方向延伸的多個第一條狀物與在第二方向延伸的多個第二條狀物。上述第一條狀物與上述第二條狀物交叉,且上述網狀結構具有多個孔洞。上述第一條狀物位於上述基底上且位於與上述鰭狀結構對應的位置。上述第二條狀物位於上述基底上且上述第二條狀物中的上述導體材料層橫跨上述鰭狀結構。上述孔洞位於上述開口中,且上述孔洞的周圍環繞有上述第一條狀物與上述第二條狀物,並且上述孔洞延伸至較上述鰭狀結構的底部更靠近上述基底的位置。The present invention provides a method of manufacturing a semiconductor device. The above method of manufacturing a semiconductor element includes the following steps. A plurality of fin structures are formed on the substrate, and openings between the adjacent fin structures are provided. A layer of conductive material is formed to cover the fin structure and fill the opening. The conductor material layer and the fin structure are patterned to form a mesh structure. The mesh structure has a plurality of first strips extending in a first direction and a plurality of second strips extending in a second direction. The first strip intersects the second strip, and the mesh structure has a plurality of holes. The first strip is located on the substrate and is located at a position corresponding to the fin structure. The second strip is located on the substrate and the conductive material layer of the second strip spans the fin structure. The hole is located in the opening, and the first strip and the second strip are surrounded by the hole, and the hole extends to a position closer to the base than the bottom of the fin structure.

在本發明的一實施例中,圖案化上述導體材料層以及上述鰭狀結構的步驟包括進行非選擇性蝕刻製程。In an embodiment of the invention, the step of patterning the conductive material layer and the fin structure includes performing a non-selective etching process.

在本發明的一實施例中,將上述導體材料層以及上述鰭狀結構之間的蝕刻選擇比控制為0.7至1.3,以進行上述非選擇性蝕刻製程。In an embodiment of the invention, the etching selectivity ratio between the conductor material layer and the fin structure is controlled to be 0.7 to 1.3 to perform the non-selective etching process.

在本發明的一實施例中,形成上述鰭狀結構的步驟包括以下步驟。在上述基底上形成堆疊層。上述堆疊層包括交互堆疊的至少一導體層以及至少一介電層。形成電荷儲存層,以覆蓋位於上述開口的底部的上述基底以及上述堆疊層的表面。In an embodiment of the invention, the step of forming the fin structure includes the following steps. A stacked layer is formed on the above substrate. The stacked layer includes at least one conductor layer and at least one dielectric layer that are alternately stacked. A charge storage layer is formed to cover the above-mentioned substrate at the bottom of the above opening and the surface of the above stacked layer.

在本發明的一實施例中,上述半導體元件的製造方法,更包括以下步驟。形成多個介電柱,以至少填滿上述孔洞。圖案化上述第一條狀物中的上述導體材料層以及上述介電柱,以使經圖案化的上述導體材料層形成多個梳狀結構。每一梳狀結構包括:多個梳部以及連接部。上述梳部插入於相鄰的上述鰭狀結構之間的上述開口中且與相鄰的上述鰭狀結構的側壁接觸。上述連接部在上述第二方向延伸,位於上述鰭狀結構上且連接上述梳部。In an embodiment of the invention, the method of manufacturing the semiconductor device further includes the following steps. A plurality of dielectric posts are formed to fill at least the holes. The conductor material layer and the dielectric post in the first strip are patterned such that the patterned conductor material layer forms a plurality of comb structures. Each comb structure includes a plurality of comb portions and a connecting portion. The comb portion is inserted into the opening between the adjacent fin structures and is in contact with a side wall of the adjacent fin structure. The connecting portion extends in the second direction and is located on the fin structure and connected to the comb portion.

在本發明的一實施例中,形成上述介電柱以及圖案化上述第一條狀物中的上述導體材料層以及上述介電柱的步驟包括以下步驟。形成介電材料層,以覆蓋上述網狀結構並填滿上述孔洞。圖案化上述介電材料層以及上述第一條狀物中的上述導體材料層,以形成上述梳狀結構、多個頂蓋層以及上述介電柱。每一梳狀結構包括上述梳部以及上述連接部。每一頂蓋層位於上述連接部上且沿著上述第二方向延伸。In an embodiment of the invention, the step of forming the dielectric post and patterning the conductive material layer and the dielectric post in the first strip includes the following steps. A layer of dielectric material is formed to cover the mesh structure and fill the holes. The dielectric material layer and the conductive material layer in the first strip are patterned to form the comb structure, the plurality of cap layers, and the dielectric post. Each of the comb structures includes the above comb portion and the above connecting portion. Each of the cap layers is located on the connecting portion and extends along the second direction.

本發明又提供一種半導體元件。上述半導體元件包括基底、多個鰭狀結構、多個梳狀結構以及多個介電柱。上述鰭狀結構位於上述基底上,且在第一方向延伸。相鄰的上述鰭狀結構之間具有開口。上述梳狀結構包括導體材料,且每一梳狀結構包括多個梳部以及連接部。上述梳部插入於相鄰的上述鰭狀結構之間的上述開口中且與相鄰的上述鰭狀結構的側壁接觸。上述連接部在第二方向延伸,位於上述鰭狀結構上且連接上述梳部。上述介電柱插入於相鄰的上述鰭狀結構之間的上述開口中且與相鄰的上述鰭狀結構的側壁以及上述梳部接觸,且延伸至較上述鰭狀結構的底部更靠近上述基底的位置。The invention further provides a semiconductor component. The above semiconductor element includes a substrate, a plurality of fin structures, a plurality of comb structures, and a plurality of dielectric posts. The fin structure is located on the substrate and extends in the first direction. An adjacent opening between the fin structures is provided. The comb structure includes a conductor material, and each of the comb structures includes a plurality of combs and a joint. The comb portion is inserted into the opening between the adjacent fin structures and is in contact with a side wall of the adjacent fin structure. The connecting portion extends in the second direction and is located on the fin structure and connected to the comb portion. The dielectric post is inserted into the opening between the adjacent fin structures and is in contact with the sidewall of the adjacent fin structure and the comb portion, and extends closer to the base than the bottom of the fin structure position.

在本發明的一實施例中,上述鰭狀結構包括堆疊層以及電荷儲存層。上述堆疊層包括交互堆疊的至少導體層以及至少介電層。上述電荷儲存層覆蓋位於上述開口的底部的上述基底以及上述堆疊層的表面。In an embodiment of the invention, the fin structure includes a stacked layer and a charge storage layer. The stacked layer includes at least a conductor layer and at least a dielectric layer that are alternately stacked. The charge storage layer covers the substrate at the bottom of the opening and the surface of the stacked layer.

在本發明的一實施例中,每一介電柱分別具有不同的高度。In an embodiment of the invention, each dielectric post has a different height.

在本發明的一實施例中,每一介電柱的高度大於每一鰭狀結構的高度。In an embodiment of the invention, the height of each dielectric post is greater than the height of each fin structure.

基於上述,本發明藉由同時圖案化鰭狀結構以及材料層(導體層)並形成網狀結構,可在具有高深寬比的溝渠的半導體結構中,以溝渠的側壁不殘留材料層的方式,進行材料層(導體層)的圖案化。這樣的方法可以有效防止所形成的半導體元件之間產生不當的導通,進而改善元件的電性表現。Based on the above, the present invention can simultaneously pattern the fin structure and the material layer (conductor layer) and form a network structure, and in the semiconductor structure of the trench having a high aspect ratio, the sidewall of the trench does not have a material layer remaining. Patterning of the material layer (conductor layer) is performed. Such a method can effectively prevent improper conduction between the formed semiconductor elements, thereby improving the electrical performance of the elements.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the invention will be apparent from the following description.

圖1A至圖1F為依照本發明的一實施例所繪示的半導體元件的製造方法的立體圖。圖2A至圖2F為沿圖1A至圖1F之A-A’線所繪示的半導體元件的製造方法的剖面示意圖。圖3A至圖3F為沿圖1A至圖1F之B-B’線所繪示的半導體元件的製造方法的剖面示意圖。圖4A至圖4F為沿圖1A至圖1F之C-C’線所繪示的半導體元件的製造方法的剖面示意圖。1A-1F are perspective views of a method of fabricating a semiconductor device in accordance with an embodiment of the invention. 2A to 2F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line A-A' of Figs. 1A to 1F. 3A to 3F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line B-B' of Figs. 1A to 1F. 4A to 4F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line C-C' of Figs. 1A to 1F.

請同時參照圖1A、圖2A、圖3A以及圖4A,首先提供基底10。基底10可包括半導體材料、絕緣體材料、導體材料或上述材料的任意組合。基底10的材質例如是選自於由Si、Ge、SiGe、GaP、GaAs、SiC、SiGeC、InAs與InP所組成的群組中的至少一種物質所構成的材質或任何適合用於本發明製程的物理結構。基底10包括單層結構或多層結構。此外,也可使用絕緣層上矽(silicon on insulator,SOI)基底10。基底10例如是矽或矽化鍺。Referring to FIG. 1A, FIG. 2A, FIG. 3A, and FIG. 4A simultaneously, the substrate 10 is first provided. Substrate 10 can comprise a semiconductor material, an insulator material, a conductor material, or any combination of the foregoing. The material of the substrate 10 is, for example, a material selected from at least one selected from the group consisting of Si, Ge, SiGe, GaP, GaAs, SiC, SiGeC, InAs, and InP, or any suitable material for use in the process of the present invention. Physical structure. The substrate 10 includes a single layer structure or a multilayer structure. In addition, a silicon on insulator (SOI) substrate 10 can also be used. The substrate 10 is, for example, tantalum or niobium.

請再同時參照圖1A、圖2A、圖3A以及圖4A,在基底10上形成介電層12。介電層12包括氧化物、氮化物、氮氧化物或是介電常數小於4的低介電常數材料。在一實施例中,介電層12例如是底氧化層(bottom oxide layer,BOX)。介電層12的厚度例如是介於1000Å至5000Å之間。介電層12的形成方法例如是熱氧化法或化學氣相沈積法。Referring to FIG. 1A, FIG. 2A, FIG. 3A, and FIG. 4A simultaneously, a dielectric layer 12 is formed on the substrate 10. The dielectric layer 12 includes an oxide, a nitride, an oxynitride or a low dielectric constant material having a dielectric constant of less than 4. In an embodiment, the dielectric layer 12 is, for example, a bottom oxide layer (BOX). The thickness of the dielectric layer 12 is, for example, between 1000 Å and 5000 Å. The method of forming the dielectric layer 12 is, for example, a thermal oxidation method or a chemical vapor deposition method.

請再同時參照圖1A、圖2A、圖3A以及圖4A,接著在介電層12上形成堆疊層16。堆疊層16包括交互堆疊的多層導體層16a以及多層介電層16b。導體層16a的材料包括未摻雜的半導體或是經摻雜的半導體,例如是多晶矽或是摻雜的多晶矽。每一導體層16a的厚度例如是介於100Å至500Å之間。每一介電層16b的厚度例如是介於200Å至600Å之間。介電層16b的材料可與介電層12的材料相同或相異。介電層16b的材料可以包括氧化物、氮化物、氮氧化物或是介電常數小於4的低介電常數材料。導體層16a以及介電層16b的形成方法例如是熱氧化法或化學氣相沈積法。Referring again to FIGS. 1A, 2A, 3A, and 4A, a stacked layer 16 is then formed over the dielectric layer 12. The stacked layer 16 includes a plurality of electrically conductive layers 16a and a plurality of dielectric layers 16b that are alternately stacked. The material of the conductor layer 16a includes an undoped semiconductor or a doped semiconductor such as polysilicon or doped polysilicon. The thickness of each conductor layer 16a is, for example, between 100 Å and 500 Å. The thickness of each dielectric layer 16b is, for example, between 200 Å and 600 Å. The material of the dielectric layer 16b may be the same as or different from the material of the dielectric layer 12. The material of the dielectric layer 16b may include an oxide, a nitride, an oxynitride or a low dielectric constant material having a dielectric constant of less than 4. The method of forming the conductor layer 16a and the dielectric layer 16b is, for example, a thermal oxidation method or a chemical vapor deposition method.

請再同時參照圖1A、圖2A、圖3A以及圖4A,繼而形成電荷儲存層18,以覆蓋堆疊層16的表面以及介電層12的表面,而形成多個鰭狀結構14。電荷儲存層18的材料包括氧化物、氮化物或其組合。具體而言,電荷儲存層18的材料包括氮化矽、氧化矽或其組合。電荷儲存層18可以是單層或多層。在一實施例中,電荷儲存層18例如是單層的氮化矽層。在另一實施例中,電荷儲存層18例如是由氧化層/氮化層/氧化層(Oxide-Nitride-Oxide,ONO)所構成的複合層。電荷儲存層18的厚度例如是介於100Å至300Å之間。電荷儲存層18的形成方法例如是化學氣相沈積法或是熱氧化法。Referring to FIG. 1A, FIG. 2A, FIG. 3A and FIG. 4A simultaneously, a charge storage layer 18 is formed to cover the surface of the stacked layer 16 and the surface of the dielectric layer 12 to form a plurality of fin structures 14. The material of the charge storage layer 18 includes an oxide, a nitride, or a combination thereof. Specifically, the material of the charge storage layer 18 includes tantalum nitride, tantalum oxide, or a combination thereof. The charge storage layer 18 can be a single layer or multiple layers. In an embodiment, the charge storage layer 18 is, for example, a single layer of tantalum nitride layer. In another embodiment, the charge storage layer 18 is, for example, a composite layer composed of an Oxide-Nitride-Oxide (ONO) layer. The thickness of the charge storage layer 18 is, for example, between 100 Å and 300 Å. The method of forming the charge storage layer 18 is, for example, a chemical vapor deposition method or a thermal oxidation method.

請再同時參照圖1A、圖2A、圖3A以及圖4A,相鄰的鰭狀結構14之間具有開口T。開口T可以是任意長度、寬度、形狀的開口。開口T的剖面可為任意形狀,例如是V型、U型、菱形或其組合,但本發明不以此為限。Referring to FIG. 1A, FIG. 2A, FIG. 3A, and FIG. 4A simultaneously, the adjacent fin structures 14 have openings T therebetween. The opening T can be an opening of any length, width, shape. The cross section of the opening T may be any shape, for example, a V shape, a U shape, a diamond shape or a combination thereof, but the invention is not limited thereto.

請再同時參照圖1A、圖2A、圖3A以及圖4A,在一實施例中,每一鰭狀結構14可以選擇性地更包括第一硬罩幕層20。第一硬罩幕層20例如是位於堆疊層16與電荷儲存層18之間,但本發明不以此為限。第一硬罩幕層20可為單層或多層。第一硬罩幕層20的材料例如是氧化矽、氮化矽或其他具有高楊氏模數(Young’s modulus)的材料。第一硬罩幕層20的厚度例如是介於100Å至1000Å之間。第一硬罩幕層20的形成方法例如是化學氣相沉積法。Referring to FIG. 1A, FIG. 2A, FIG. 3A and FIG. 4A simultaneously, in an embodiment, each of the fin structures 14 may optionally further include a first hard mask layer 20. The first hard mask layer 20 is, for example, located between the stacked layer 16 and the charge storage layer 18, but the invention is not limited thereto. The first hard mask layer 20 can be a single layer or multiple layers. The material of the first hard mask layer 20 is, for example, tantalum oxide, tantalum nitride or other material having a high Young's modulus. The thickness of the first hard mask layer 20 is, for example, between 100 Å and 1000 Å. The method of forming the first hard mask layer 20 is, for example, a chemical vapor deposition method.

請參照圖1A、1B、圖2B、圖3B以及圖4B,形成導體材料層22,以覆蓋覆蓋鰭狀結構14的電荷儲存層18以及介電層12的表面,並填滿開口T。導體材料層22包括未摻雜的半導體或是經摻雜的半導體,例如是多晶矽或是摻雜的多晶矽。導體材料層22在鰭狀結構14的頂部上的厚度例如是介於500Å至1500Å之間。導體材料層22的形成方法例如是化學氣相沈積法。Referring to FIGS. 1A, 1B, 2B, 3B, and 4B, a conductive material layer 22 is formed to cover the surface of the charge storage layer 18 and the dielectric layer 12 covering the fin structure 14, and fill the opening T. The conductor material layer 22 comprises an undoped semiconductor or a doped semiconductor, such as a polysilicon or a doped polysilicon. The thickness of the layer of conductor material 22 on top of the fin structure 14 is, for example, between 500 Å and 1500 Å. The method of forming the conductor material layer 22 is, for example, a chemical vapor deposition method.

請同時參照圖1C、圖2C、圖3C以及圖4C,繼而在導體材料層22上形成罩幕結構24。罩幕結構24例如是依序包括第一先進圖案化薄膜(advanced patterning film, APF)24a、介電抗反射層(dielectric anti-reflective coating film, DARC)24b、第二先進圖案化薄膜24c、含矽硬罩幕底部抗反射層24d(silicon-containing hard-mask bottom anti-reflection coating,SHB)以及圖案化的光阻層24e。第一先進圖案化薄膜24a的材料例如是非晶碳。介電抗反射層24b的材料例如是氮氧化矽。第二先進圖案化薄膜24c的材料例如是非晶碳。含矽硬罩幕底部抗反射層24d的材料例如是有機矽高分子聚合物(organosilicon polymer)、聚矽烷(polysilane)或其組合。圖案化的光阻層24e的材料例如是正型光阻、負型光阻或其組合。第一先進圖案化薄膜24a的厚度例如是介於4000Å至15000Å之間。介電抗反射層24b的厚度例如是介於300Å至2000Å之間。第二先進圖案化薄膜24c的厚度例如是介於500Å至4000Å之間。含矽硬罩幕底部抗反射層24d的厚度例如是介於200Å至1000Å之間。圖案化的光阻層24e的厚度例如是介於200Å至3000Å之間。第一先進圖案化薄膜24a、介電抗反射層24b、第二先進圖案化薄膜24c以及含矽硬罩幕底部抗反射層24d的形成方法例如是化學氣相沉積法。圖案化的光阻層24e的形成方法例如是旋轉塗佈法搭配微影製程。在一實施例中,在形成罩幕結構24之前亦可對導體材料層22進行平坦化製程,以利於後續的圖案化製程。Referring to FIG. 1C, FIG. 2C, FIG. 3C, and FIG. 4C simultaneously, a mask structure 24 is formed on the conductor material layer 22. The mask structure 24 includes, for example, a first advanced patterning film (APF) 24a, a dielectric anti-reflective coating film (DARC) 24b, a second advanced patterned film 24c, and the like. A silicon-containing hard-mask bottom anti-reflection coating (SHB) and a patterned photoresist layer 24e are provided. The material of the first advanced patterned film 24a is, for example, amorphous carbon. The material of the dielectric anti-reflection layer 24b is, for example, bismuth oxynitride. The material of the second advanced patterned film 24c is, for example, amorphous carbon. The material of the anti-reflective layer 24d containing the hard mask bottom is, for example, an organosilicon polymer, a polysilane or a combination thereof. The material of the patterned photoresist layer 24e is, for example, a positive photoresist, a negative photoresist, or a combination thereof. The thickness of the first advanced patterned film 24a is, for example, between 4,000 Å and 15,000 Å. The thickness of the dielectric anti-reflection layer 24b is, for example, between 300 Å and 2000 Å. The thickness of the second advanced patterned film 24c is, for example, between 500 Å and 4,000 Å. The thickness of the anti-reflective layer 24d at the bottom of the ruthenium-containing hard mask is, for example, between 200 Å and 1000 Å. The thickness of the patterned photoresist layer 24e is, for example, between 200 Å and 3,000 Å. The first advanced patterned film 24a, the dielectric anti-reflective layer 24b, the second advanced patterned film 24c, and the ruthenium-containing hard mask bottom anti-reflective layer 24d are formed, for example, by chemical vapor deposition. The method of forming the patterned photoresist layer 24e is, for example, a spin coating method in combination with a lithography process. In an embodiment, the planarization process of the conductive material layer 22 may be performed prior to forming the mask structure 24 to facilitate subsequent patterning processes.

請同時參照圖1C、圖1D、圖2D、圖3D以及圖4D,以罩幕結構24做為罩幕,進行非選擇性蝕刻製程,圖案化導體材料層22並移除部分的電荷儲存層18以及介電層12,以形成網狀結構26。所謂的非選擇性蝕刻製程是指對導體材料層22、電荷儲存層18以及介電層12以實質上相等的蝕刻速率進行蝕刻。在一實施例中,導體材料層22對於電荷儲存層18以及導體材料層22對於介電層12的蝕刻選擇比例如是0.7至1.3。雖然以上列舉了蝕刻選擇比的範圍,但本發明並不限於此。只要能夠確保用於形成隔離結構的開口的的側壁上的導體材料層22能夠完全被移除,則可以任意調整為所需的蝕刻選擇比。非選擇性蝕刻製程例如是乾式蝕刻法。乾式蝕刻法可以是濺鍍蝕刻、反應性離子蝕刻等。在一實施例中,非選擇性蝕刻製程中使用的氣體例如是NF 3、HBr、CH 4、N 2、He、Ar、SF 6、CH 2F 2及CH 3F。 Referring to FIG. 1C, FIG. 1D, FIG. 2D, FIG. 3D and FIG. 4D, the mask structure 24 is used as a mask to perform a non-selective etching process, patterning the conductive material layer 22 and removing a portion of the charge storage layer 18 The dielectric layer 12 is also formed to form the mesh structure 26. By non-selective etching process is meant etching the conductor material layer 22, the charge storage layer 18, and the dielectric layer 12 at substantially equal etch rates. In one embodiment, the etch selectivity ratio of the conductor material layer 22 to the charge storage layer 18 and the conductor material layer 22 to the dielectric layer 12 is, for example, 0.7 to 1.3. Although the range of the etching selection ratio is enumerated above, the present invention is not limited thereto. As long as it can be ensured that the conductor material layer 22 on the side wall of the opening for forming the isolation structure can be completely removed, it can be arbitrarily adjusted to a desired etching selectivity ratio. The non-selective etching process is, for example, a dry etching method. The dry etching method may be sputtering etching, reactive ion etching, or the like. In one embodiment, the gases used in the non-selective etching process are, for example, NF 3 , HBr, CH 4 , N 2 , He, Ar, SF 6 , CH 2 F 2 , and CH 3 F.

請再同時參照圖1D、圖2D、圖3D以及圖4D,之後移除罩幕結構24,裸露出網狀結構26。網狀結構26具有交叉的多個第一條狀物26a與多個第二條狀物26b。更具體地說,第一條狀物26a在第一方向D1延伸,且位於與鰭狀結構14對應的位置。亦即每一第一條狀物26a包括鰭狀結構14以及位於鰭狀結構14上的第一條狀導體層25a。第二條狀物26b在第二方向D2延伸,且位於基底10上,並且第二條狀物26b中的第二條狀導體層25b橫跨鰭狀結構14。亦即每一第二條狀物26b包括鰭狀結構14的一部分以及橫跨鰭狀結構14的第二條狀導體層25b。第一條狀導體層25a與第二條狀導體層25b由圖1C、圖2C、圖3C以及圖4C中的導體材料層22圖案化而得。第一條狀導體層25a與第二條狀導體層25b彼此交叉,構成網狀層25。Referring again to FIGS. 1D, 2D, 3D, and 4D, the mask structure 24 is removed and the mesh structure 26 is exposed. The mesh structure 26 has a plurality of first strips 26a and a plurality of second strips 26b that intersect. More specifically, the first strip 26a extends in the first direction D1 and is located at a position corresponding to the fin structure 14. That is, each of the first strips 26a includes a fin structure 14 and a first strip conductor layer 25a on the fin structure 14. The second strip 26b extends in the second direction D2 and is located on the substrate 10, and the second strip conductor layer 25b in the second strip 26b spans the fin structure 14. That is, each second strip 26b includes a portion of the fin structure 14 and a second strip conductor layer 25b that spans the fin structure 14. The first strip conductor layer 25a and the second strip conductor layer 25b are patterned by the conductor material layer 22 in FIGS. 1C, 2C, 3C, and 4C. The first strip conductor layer 25a and the second strip conductor layer 25b cross each other to form the mesh layer 25.

換言之,網狀結構26具有多個孔洞P。孔洞P的周圍環繞有第一條狀物26a與第二條狀物26b。孔洞P位於相鄰的兩個鰭狀結構14之間的開口T(請同時參照圖1A以及圖1D)中。而且孔洞P延伸至電荷儲存層18下方的介電層12中,亦即孔洞P的底部至比鰭狀結構14的底部更靠近基底10。移除罩幕結構24的方法例如是乾式蝕刻法。乾式蝕刻法可以是濺鍍蝕刻或反應性離子蝕刻等。In other words, the mesh structure 26 has a plurality of holes P. The circumference of the hole P is surrounded by a first strip 26a and a second strip 26b. The hole P is located in the opening T between the adjacent two fin structures 14 (please refer to FIG. 1A and FIG. 1D simultaneously). Moreover, the hole P extends into the dielectric layer 12 below the charge storage layer 18, that is, the bottom of the hole P to be closer to the substrate 10 than the bottom of the fin structure 14. The method of removing the mask structure 24 is, for example, a dry etching method. The dry etching method may be sputtering etching, reactive ion etching, or the like.

由於網狀結構26是藉由進行非選擇性蝕刻製程來形成,因此可有效避免或減少導體材料層22殘留在用於形成隔離結構的開口的側壁上,進而防止所形成的半導體元件之間產生不當的導通。另外,由於導體材料層22圖案化成網狀層25,因而可在兩個方向上賦予足夠的支撐力,進而避免圖案倒塌的情況。Since the mesh structure 26 is formed by performing a non-selective etching process, the conductive material layer 22 can be effectively prevented or reduced from remaining on the sidewalls of the openings for forming the isolation structure, thereby preventing the formation of the formed semiconductor elements. Improper conduction. In addition, since the conductor material layer 22 is patterned into the mesh layer 25, sufficient supporting force can be imparted in both directions, thereby preventing the pattern from collapsing.

請再同時參照圖1C與1D、圖2D、圖3D以及圖4D,相鄰的兩個孔洞P在第一方向D1上的間距例如是介於200Å至400Å之間。相鄰的兩個孔洞P在第二方向D2上的間距例如是介於200Å至400Å之間。孔洞P的面積例如是介於5000nm 2至10000nm 2之間。孔洞P的形狀例如是圓形、方形、菱形或其組合。雖然以上列舉了孔洞P的形狀、面積以及間距等,但本發明並不限於此。只要能夠確保用於形成隔離結構的開口(亦即孔洞P)的側壁上的導體材料層22能夠完全被移除,則孔洞P可以具有任意的形狀、面積以及間距。 Referring to FIGS. 1C and 1D, FIG. 2D, FIG. 3D, and FIG. 4D simultaneously, the distance between the adjacent two holes P in the first direction D1 is, for example, between 200 Å and 400 Å. The spacing of the adjacent two holes P in the second direction D2 is, for example, between 200 Å and 400 Å. P, for example, area of the void is between 5000nm 2 to 10000nm 2. The shape of the hole P is, for example, a circle, a square, a diamond, or a combination thereof. Although the shape, the area, the pitch, and the like of the hole P are listed above, the present invention is not limited thereto. The hole P may have any shape, area, and pitch as long as it can be ensured that the conductor material layer 22 on the side wall of the opening for forming the isolation structure (i.e., the hole P) can be completely removed.

請再同時參照圖1C與1D、圖2D、圖3D以及圖4D,在一實施例中,每一第一條狀物26a的側壁較每一第二條狀物26b的側壁傾斜。更具體地說,每一第一條狀物26a的第一夾角A1可以小於每一第二條狀物26b的第二夾角A2。第一夾角A1為位於孔洞P的底部的第一條狀物26a的側壁與基底10的表面之間的夾角。第二夾角A2為位於孔洞P的底部的第二條狀物26b的側壁與基底10的表面之間的夾角。Referring again to FIGS. 1C and 1D, FIG. 2D, FIG. 3D, and FIG. 4D, in one embodiment, the sidewall of each first strip 26a is inclined from the sidewall of each second strip 26b. More specifically, the first angle A1 of each of the first strips 26a may be smaller than the second angle A2 of each of the second strips 26b. The first angle A1 is an angle between the side wall of the first strip 26a at the bottom of the hole P and the surface of the substrate 10. The second angle A2 is the angle between the side wall of the second strip 26b at the bottom of the hole P and the surface of the substrate 10.

請再同時參照圖1D、圖2D、圖3D以及圖4D,在進行蝕刻的過程中,由於負載效應(loading effect)的緣故,而使得蝕刻的程度不均,造成所形成的網狀結構26的多個孔洞P的側壁的高度H3可能不完全相同,但因為在後續的製程中填入孔洞P的是介電材料,因此即使每一孔洞P的高度H3不同,亦不會影響到元件整體的電性表現。在一實施例中,網狀結構26的多個孔洞P的側壁的高度H3均不同。在又一實施例中,網狀結構26的每一孔洞P的側壁的高度H3大於第一條狀物26a的高度H。舉例來說,網狀結構26的每一孔洞P的側壁的高度H3超出第一條狀物26a的高度H的30%以上,或者是40%以上。在一實施例中,孔洞P的側壁的高度H3例如是介於7000Å至12000Å之間。網狀結構26的每一孔洞P的側壁的高度H3超出第一條狀物26a的高度H 1000Å至5000Å。藉由將網狀結構26的每一孔洞P的側壁的高度H3設為超出第一條狀物26a的高度H的30%以上,可更加確保用於形成隔離結構的開口的側壁上的導體材料層22能夠完全被移除。Referring to FIG. 1D, FIG. 2D, FIG. 3D, and FIG. 4D simultaneously, during the etching process, the degree of etching is uneven due to the loading effect, resulting in the formed mesh structure 26. The height H3 of the side walls of the plurality of holes P may not be completely the same, but since the holes P are filled with a dielectric material in a subsequent process, even if the height H3 of each hole P is different, the entire component is not affected. Electrical performance. In an embodiment, the heights H3 of the sidewalls of the plurality of holes P of the mesh structure 26 are different. In yet another embodiment, the height H3 of the sidewall of each of the holes P of the mesh structure 26 is greater than the height H of the first strip 26a. For example, the height H3 of the side wall of each hole P of the mesh structure 26 exceeds 30% or more of the height H of the first strip 26a, or is 40% or more. In an embodiment, the height H3 of the side wall of the hole P is, for example, between 7000 Å and 12000 Å. The height H3 of the side wall of each hole P of the mesh structure 26 exceeds the height H 1000 Å to 5000 Å of the first strip 26a. By setting the height H3 of the side wall of each hole P of the mesh structure 26 to be more than 30% of the height H of the first strip 26a, the conductor material on the side wall of the opening for forming the isolation structure can be more ensured. Layer 22 can be completely removed.

請同時參照圖1E、圖2E、圖3E以及圖4E,繼而形成覆蓋網狀結構26並填滿孔洞P的介電材料層28a。介電材料層28a的材料包括氧化物、氮化物、氮氧化物或是介電常數小於4的低介電常數材料。介電材料層28a在網狀結構26上的厚度例如是介於200Å至1000Å之間。介電材料層28a的形成方法例如是化學氣相沉積法。Referring to FIG. 1E, FIG. 2E, FIG. 3E, and FIG. 4E simultaneously, a dielectric material layer 28a covering the mesh structure 26 and filling the holes P is formed. The material of the dielectric material layer 28a includes an oxide, a nitride, an oxynitride or a low dielectric constant material having a dielectric constant of less than 4. The thickness of the dielectric material layer 28a on the mesh structure 26 is, for example, between 200 Å and 1000 Å. The method of forming the dielectric material layer 28a is, for example, a chemical vapor deposition method.

請同時參照圖1D、圖1E與圖1F、圖2F、圖3F以及圖4F,進行圖案化製程,例如是微影與蝕刻製程,以圖案化介電材料層28a以及網狀結構26,進而形成多個梳狀結構30以及介電柱28。更具體地說,藉由上述圖案化製程,留下位於第二條狀物26b表面上的頂蓋層28b以及位於孔洞P之中的介電柱28。頂蓋層28b位於連接部30b上且沿著第二方向D2延伸。此外,藉由上述圖案化製程,網狀結構26的第一條狀物26a被部分移除,留下梳狀結構30。每一梳狀結構30包括多個梳部30a以及連接部30b。每一梳部30a插入於相鄰的兩個鰭狀結構14之間的開口T中且與相鄰的鰭狀結構14中的電荷儲存層18的側壁接觸(請參照圖1A以及圖1F)。連接部30b連接梳部30a,且在第二方向D2延伸。在一實施例中,連接部30b在第一方向D1上的長度例如是介於400Å至600Å之間。在一實施例中,連接部30b之間的間距例如是介於200Å至400Å之間。在一實施例中,連接部30b在第一方向D1的長度W1小於每一介電柱28在第一方向D1的長度W2。Referring to FIG. 1D, FIG. 1E and FIG. 1F, FIG. 2F, FIG. 3F and FIG. 4F, a patterning process, such as a lithography and etching process, is performed to pattern the dielectric material layer 28a and the mesh structure 26, thereby forming A plurality of comb structures 30 and dielectric posts 28. More specifically, by the above-described patterning process, the cap layer 28b on the surface of the second strip 26b and the dielectric post 28 located in the hole P are left. The top cover layer 28b is located on the connecting portion 30b and extends along the second direction D2. Moreover, by the patterning process described above, the first strip 26a of the mesh structure 26 is partially removed leaving the comb structure 30. Each of the comb structures 30 includes a plurality of comb portions 30a and a connecting portion 30b. Each comb portion 30a is inserted into the opening T between the adjacent two fin structures 14 and is in contact with the sidewall of the charge storage layer 18 in the adjacent fin structure 14 (please refer to FIGS. 1A and 1F). The connecting portion 30b connects the comb portion 30a and extends in the second direction D2. In an embodiment, the length of the connecting portion 30b in the first direction D1 is, for example, between 400 Å and 600 Å. In an embodiment, the spacing between the connecting portions 30b is, for example, between 200 Å and 400 Å. In an embodiment, the length W1 of the connecting portion 30b in the first direction D1 is smaller than the length W2 of each dielectric post 28 in the first direction D1.

此外,在進行上述圖案化製程時,在形成頂蓋層28b以及梳狀結構30之後,可以進行過度蝕刻,以移除位於頂蓋層28b之間的鰭狀結構14的一部分。因此,相鄰的兩個梳狀結構30之間的每一鰭狀結構14的高度(第一高度H1)會低於每一梳狀結構30之下的每一鰭狀結構14的高度(第二高度H2)。在一實施例中,第一高度H1比第二高度H2小500Å至1000Å。由於負載效應的緣故,相鄰的兩個梳狀結構30之間的導體材料有可能發生移除不完全的情況,但藉由進行過度蝕刻並移除位於頂蓋層28b之間的鰭狀結構14的一部分,可以確保在進行上述圖案化製程之後,相鄰的兩個梳狀結構30之間不會因為導體材料的殘留而互相導通。Further, during the above-described patterning process, after the cap layer 28b and the comb structure 30 are formed, over-etching may be performed to remove a portion of the fin structure 14 between the cap layers 28b. Therefore, the height (first height H1) of each fin structure 14 between adjacent two comb structures 30 may be lower than the height of each fin structure 14 below each comb structure 30 (the Two heights H2). In an embodiment, the first height H1 is less than 500 Å to 1000 Å less than the second height H2. Due to the load effect, the conductor material between the adjacent two comb structures 30 may be incompletely removed, but by over etching and removing the fin structure between the cap layers 28b. A part of 14 can ensure that after the above-mentioned patterning process, the adjacent two comb-like structures 30 are not electrically connected to each other due to the residual of the conductor material.

請同時參照圖1F、圖2F、圖3F以及圖4F,本發明的半導體元件包括基底10、介電層12、多個鰭狀結構14、多個梳狀結構30以及多個介電柱28。介電層12位於基底10上。多個鰭狀結構14位於介電層12上,且在第一方向D1延伸。鰭狀結構14包括堆疊層16以及電荷儲存層18。堆疊層16包括交互堆疊的多個導體層16a以及多個介電層16b。相鄰的鰭狀結構14之間具有開口T。電荷儲存層18覆蓋在堆疊層16的表面以及介電層12上。1F, 2F, 3F, and 4F, the semiconductor device of the present invention includes a substrate 10, a dielectric layer 12, a plurality of fin structures 14, a plurality of comb structures 30, and a plurality of dielectric posts 28. The dielectric layer 12 is on the substrate 10. A plurality of fin structures 14 are located on the dielectric layer 12 and extend in the first direction D1. The fin structure 14 includes a stacked layer 16 and a charge storage layer 18. The stacked layer 16 includes a plurality of conductor layers 16a and a plurality of dielectric layers 16b that are alternately stacked. There are openings T between adjacent fin structures 14. A charge storage layer 18 overlies the surface of the stacked layer 16 and the dielectric layer 12.

請同時參照圖1F、圖2F、圖3F以及圖4F,梳狀結構30可以是導體材料。每一梳狀結構30包括多個梳部30a以及連接部30b。多個梳部30a插入於相鄰的兩個鰭狀結構14之間的開口T中且與相鄰的鰭狀結構14中的電荷儲存層18的側壁接觸。連接部30b在第二方向D2延伸,位於電荷儲存層18上且與梳部30a連接。Referring to FIG. 1F, FIG. 2F, FIG. 3F, and FIG. 4F simultaneously, the comb structure 30 may be a conductor material. Each of the comb structures 30 includes a plurality of comb portions 30a and a connecting portion 30b. A plurality of comb portions 30a are inserted into the opening T between the adjacent two fin structures 14 and are in contact with the sidewalls of the charge storage layer 18 in the adjacent fin structures 14. The connecting portion 30b extends in the second direction D2 and is located on the charge storage layer 18 and connected to the comb portion 30a.

多個介電柱28插入於相鄰的兩個鰭狀結構14之間的開口T中且與相鄰的鰭狀結構14的側壁以及梳狀結構30的梳部30a接觸,且延伸至較鰭狀結構14更靠近基底10的位置(亦即介電柱28延伸至電荷儲存層18下方的介電層12中)。多個介電柱28的高度H3可以不完全相同。在一實施例中,多個介電柱28的高度H3均不同。在另一實施例中,每一介電柱28的高度H3大於鰭狀結構14的高度H1。舉例來說,每一介電柱28的高度H3超出鰭狀結構14的高度H1的30%以上,或者是40%以上。A plurality of dielectric posts 28 are inserted into the opening T between the adjacent two fin structures 14 and are in contact with the sidewalls of the adjacent fin structures 14 and the comb portions 30a of the comb structure 30, and extend to the fins Structure 14 is closer to the location of substrate 10 (i.e., dielectric post 28 extends into dielectric layer 12 below charge storage layer 18). The height H3 of the plurality of dielectric posts 28 may not be identical. In an embodiment, the heights H3 of the plurality of dielectric posts 28 are different. In another embodiment, the height H3 of each dielectric post 28 is greater than the height H1 of the fin structure 14. For example, the height H3 of each dielectric post 28 exceeds 30% or more of the height H1 of the fin structure 14, or is 40% or more.

在一實施例中,每一鰭狀結構14的側壁可以較每一梳部30a的側壁傾斜。更具體地說,每一鰭狀結構14(亦即電荷儲存層18)的第一夾角A1小於每一梳部30a的第二夾角A2。第一夾角A1為每一鰭狀結構14的側壁與基底10的表面之間的夾角,第二夾角A2為每一梳部30a的側壁與基底10的表面之間的夾角。每一連接部30b在第一方向D1的長度W1可與每一介電柱28在第一方向D1的長度W2不同。在一實施例中,每一連接部30b在第一方向D1的長度W1小於每一介電柱28在第一方向D1的長度W2。In an embodiment, the sidewalls of each fin structure 14 may be inclined relative to the sidewalls of each comb portion 30a. More specifically, the first angle A1 of each of the fin structures 14 (i.e., the charge storage layer 18) is smaller than the second angle A2 of each of the comb portions 30a. The first angle A1 is the angle between the side wall of each fin structure 14 and the surface of the substrate 10, and the second angle A2 is the angle between the side wall of each comb portion 30a and the surface of the substrate 10. The length W1 of each of the connecting portions 30b in the first direction D1 may be different from the length W2 of each of the dielectric posts 28 in the first direction D1. In an embodiment, the length W1 of each of the connecting portions 30b in the first direction D1 is smaller than the length W2 of each of the dielectric posts 28 in the first direction D1.

請再同時參照圖1F、圖2F、圖3F以及圖4F,每一鰭狀結構14在第一方向D1的高度可以不同。在一實施例中,每一鰭狀結構14的一部分的第一高度H1低於每一鰭狀結構14的另一部分的第二高度H2。第一高度H1為位於相鄰的兩個梳狀結構30之間的每一鰭狀結構14的高度。第二高度H2為位於每一梳狀結構30之下的每一鰭狀結構14的高度。Referring to FIG. 1F, FIG. 2F, FIG. 3F and FIG. 4F simultaneously, the height of each fin structure 14 in the first direction D1 may be different. In an embodiment, the first height H1 of a portion of each fin structure 14 is lower than the second height H2 of another portion of each fin structure 14. The first height H1 is the height of each fin structure 14 between the adjacent two comb structures 30. The second height H2 is the height of each fin structure 14 located below each comb structure 30.

請再同時參照圖1F、圖2F、圖3F以及圖4F,本發明的半導體元件可以更包括多個頂蓋層28b。多個頂蓋層28b位於梳狀結構30的連接部30b上,且沿著第二方向D2延伸。Referring again to FIGS. 1F, 2F, 3F, and 4F, the semiconductor device of the present invention may further include a plurality of cap layers 28b. A plurality of cap layers 28b are located on the connecting portion 30b of the comb structure 30 and extend along the second direction D2.

綜上所述,本發明實施例藉由進行非選擇性蝕刻製程並形成網狀結構,可有效去除殘留在溝渠的側壁的材料層,進而防止所形成的半導體元件之間產生不當的導通。另外,由於導體材料層圖案化成網狀,因而可在兩個方向上賦予足夠的支撐力,進而避免圖案倒塌的情況。In summary, in the embodiment of the present invention, by performing a non-selective etching process and forming a mesh structure, the material layer remaining on the sidewall of the trench can be effectively removed, thereby preventing improper conduction between the formed semiconductor elements. In addition, since the conductor material layer is patterned into a mesh shape, sufficient supporting force can be imparted in both directions, thereby preventing the pattern from collapsing.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.

10‧‧‧基底
12、16b‧‧‧介電層
14‧‧‧鰭狀結構
16‧‧‧堆疊層
16a‧‧‧導體層
18‧‧‧電荷儲存層
20‧‧‧第一硬罩幕層
22‧‧‧導體材料層
24‧‧‧罩幕結構
24a‧‧‧第一先進圖案化薄膜
24b‧‧‧介電抗反射層
24c‧‧‧第二先進圖案化薄膜
24d‧‧‧含矽硬罩幕底部抗反射層
24e‧‧‧圖案化的光阻層
25‧‧‧網狀層
25a‧‧‧第一條狀導體層
25b‧‧‧第二條狀導體層
26‧‧‧網狀結構
26a‧‧‧第一條狀物
26b‧‧‧第二條狀物
28‧‧‧介電柱
28a‧‧‧介電材料層
30‧‧‧梳狀結構
30a‧‧‧梳部
30b‧‧‧連接部
28b‧‧‧頂蓋層
A1‧‧‧第一夾角
A2‧‧‧第二夾角
D1‧‧‧第一方向
D2‧‧‧第二方向
H、H3‧‧‧高度
H1‧‧‧第一高度
H2‧‧‧第二高度
P‧‧‧孔洞
T‧‧‧開口
W1、W2‧‧‧長度
10‧‧‧Base
12, 16b‧‧‧ dielectric layer
14‧‧‧Fin structure
16‧‧‧Stacking
16a‧‧‧Conductor layer
18‧‧‧Charge storage layer
20‧‧‧First hard mask layer
22‧‧‧Conductor layer
24‧‧‧ Cover structure
24a‧‧‧First advanced patterned film
24b‧‧‧Dielectric anti-reflection layer
24c‧‧‧Second advanced patterned film
24d‧‧‧Anti-reflective layer at the bottom of the hard mask
24e‧‧‧ patterned photoresist layer
25‧‧‧ mesh layer
25a‧‧‧First strip conductor layer
25b‧‧‧Second strip conductor layer
26‧‧‧Mesh structure
26a‧‧‧first article
26b‧‧‧Second article
28‧‧‧ dielectric column
28a‧‧‧ dielectric material layer
30‧‧‧Comb structure
30a‧‧‧Comb
30b‧‧‧Connecting Department
28b‧‧‧Top cover
A1‧‧‧ first angle
A2‧‧‧second angle
D1‧‧‧ first direction
D2‧‧‧ second direction
H, H3‧‧‧ height
H1‧‧‧ first height
H2‧‧‧second height
P‧‧‧ Hole
T‧‧‧ openings
W1, W2‧‧‧ length

圖1A至圖1F為依照本發明的一實施例所繪示的半導體元件的製造方法的立體圖。 圖2A至圖2F為沿圖1A至圖1F之A-A’線所繪示的半導體元件的製造方法的剖面示意圖。 圖3A至圖3F為沿圖1A至圖1F之B-B’線所繪示的半導體元件的製造方法的剖面示意圖。 圖4A至圖4F為沿圖1A至圖1F之C-C’線所繪示的半導體元件的製造方法的剖面示意圖。1A-1F are perspective views of a method of fabricating a semiconductor device in accordance with an embodiment of the invention. 2A to 2F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line A-A' of Figs. 1A to 1F. 3A to 3F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line B-B' of Figs. 1A to 1F. 4A to 4F are schematic cross-sectional views showing a method of manufacturing a semiconductor device taken along line C-C' of Figs. 1A to 1F.

10‧‧‧基底 10‧‧‧Base

12、16b‧‧‧介電層 12, 16b‧‧‧ dielectric layer

14‧‧‧鰭狀結構 14‧‧‧Fin structure

16‧‧‧堆疊層 16‧‧‧Stacking

16a‧‧‧導體層 16a‧‧‧Conductor layer

18‧‧‧電荷儲存層 18‧‧‧Charge storage layer

20‧‧‧第一硬罩幕層 20‧‧‧First hard mask layer

28‧‧‧介電柱 28‧‧‧ dielectric column

28b‧‧‧頂蓋層 28b‧‧‧Top cover

30‧‧‧梳狀結構 30‧‧‧Comb structure

30a‧‧‧梳部 30a‧‧‧Comb

30b‧‧‧連接部 30b‧‧‧Connecting Department

A1‧‧‧第一夾角 A1‧‧‧ first angle

D1‧‧‧第一方向 D1‧‧‧ first direction

D2‧‧‧第二方向 D2‧‧‧ second direction

H3‧‧‧高度 H3‧‧‧ Height

H1‧‧‧第一高度 H1‧‧‧ first height

H2‧‧‧第二高度 H2‧‧‧second height

W1、W2‧‧‧長度 W1, W2‧‧‧ length

Claims (10)

一種半導體元件的製造方法,包括: 在一基底上形成多個鰭狀結構,相鄰的該些鰭狀結構之間具有一開口; 形成一導體材料層,以覆蓋該些鰭狀結構並填滿該開口;以及 圖案化該導體材料層以及該些鰭狀結構,以形成一網狀結構,該網狀結構具有在一第一方向延伸的多個第一條狀物與在一第二方向延伸的多個第二條狀物,該些第一條狀物與該些第二條狀物交叉,且該網狀結構具有多個孔洞,其中 該些第一條狀物位於該基底上且位於與該些鰭狀結構對應的位置,該些第二條狀物位於該基底上且該些第二條狀物中的該導體材料層橫跨該些鰭狀結構, 該些孔洞位於該開口中,且該些孔洞的周圍環繞有該些第一條狀物與該些第二條狀物,並且該些孔洞延伸至較該些鰭狀結構的底部更靠近該基底的位置。A method of fabricating a semiconductor device, comprising: forming a plurality of fin structures on a substrate, an adjacent opening between the fin structures; forming a layer of conductive material to cover the fin structures and filling The opening; and patterning the layer of conductor material and the fin structures to form a mesh structure having a plurality of first strips extending in a first direction and extending in a second direction a plurality of second strips, the first strips intersecting the second strips, and the mesh structure has a plurality of holes, wherein the first strips are located on the substrate and are located Positioning corresponding to the fin structures, the second strips are located on the substrate and the layer of the conductor material in the second strips spans the fin structures, the holes being located in the openings And the first strip and the second strip are surrounded by the holes, and the holes extend to a position closer to the base than the bottoms of the fin structures. 如申請專利範圍第1項所述的半導體元件的製造方法,其中圖案化該導體材料層以及該些鰭狀結構的步驟包括進行一非選擇性蝕刻製程。The method of fabricating a semiconductor device according to claim 1, wherein the step of patterning the conductor material layer and the fin structures comprises performing a non-selective etching process. 如申請專利範圍第2項所述的半導體元件的製造方法,其中將該導體材料層以及該些鰭狀結構之間的蝕刻選擇比控制為0.7至1.3,以進行該非選擇性蝕刻製程。The method of manufacturing a semiconductor device according to claim 2, wherein an etching selectivity ratio between the conductor material layer and the fin structures is controlled to be 0.7 to 1.3 to perform the non-selective etching process. 如申請專利範圍第1項所述的半導體元件的製造方法,其中形成該些鰭狀結構的步驟包括: 在該基底上形成一堆疊層,該堆疊層包括交互堆疊的至少一導體層以及至少一介電層;以及 形成一電荷儲存層,以覆蓋位於該開口的底部的該基底以及該堆疊層的表面。The method of fabricating a semiconductor device according to claim 1, wherein the forming the fin structures comprises: forming a stacked layer on the substrate, the stacked layer comprising at least one conductor layer and at least one stacked alternately a dielectric layer; and a charge storage layer is formed to cover the substrate at the bottom of the opening and the surface of the stacked layer. 如申請專利範圍第1項所述的半導體元件的製造方法,更包括: 形成多個介電柱,以至少填滿該些孔洞;以及 圖案化該些第一條狀物中的該導體材料層以及該些介電柱,以使經圖案化的該導體材料層形成多個梳狀結構,每一梳狀結構包括:     多個梳部,插入於相鄰的該些鰭狀結構之間的該開口中且與相鄰的該些鰭狀結構的側壁接觸;以及     一連接部,在該第二方向延伸,位於該些鰭狀結構上且連接該些梳部。The method of fabricating a semiconductor device according to claim 1, further comprising: forming a plurality of dielectric pillars to fill at least the holes; and patterning the conductor material layer in the first strips and The dielectric pillars are configured such that the patterned layer of the conductor material forms a plurality of comb structures, each comb structure comprising: a plurality of comb portions inserted in the openings between the adjacent fin structures And contacting adjacent sidewalls of the fin structures; and a connecting portion extending in the second direction on the fin structures and connecting the comb portions. 如申請專利範圍第5項所述的半導體元件的製造方法,其中形成該些介電柱以及圖案化該些第一條狀物中的該導體材料層以及該些介電柱的步驟包括: 形成一介電材料層,以覆蓋該網狀結構並填滿該些孔洞;以及 圖案化該介電材料層以及該些第一條狀物中的該導體材料層,以形成該些梳狀結構、多個頂蓋層以及該些介電柱,每一梳狀結構包括該些梳部以及該連接部,每一頂蓋層位於該連接部上且沿著該第二方向延伸。The method of manufacturing a semiconductor device according to claim 5, wherein the forming the dielectric pillars and patterning the conductive material layer and the dielectric pillars in the first strips comprises: forming a dielectric layer a layer of electrical material to cover the mesh structure and fill the holes; and patterning the layer of dielectric material and the layer of conductive material in the first strips to form the comb structures, a cap layer and the dielectric posts, each of the comb structures including the comb portions and the connecting portion, each cap layer being located on the connecting portion and extending along the second direction. 一種半導體元件,包括: 一基底; 多個鰭狀結構,位於該基底上,且在一第一方向延伸,相鄰的該些鰭狀結構之間具有一開口; 多個梳狀結構,該些梳狀結構包括導體材料,每一梳狀結構包括:     多個梳部,插入於相鄰的該些鰭狀結構之間的該開口中且與相鄰的該些鰭狀結構的側壁接觸;以及     一連接部,在一第二方向延伸,位於該些鰭狀結構上且連接該些梳部;以及 多個介電柱,插入於相鄰的該些鰭狀結構之間的該開口中且與相鄰的該些鰭狀結構的側壁以及該些梳部接觸,且延伸至較該些鰭狀結構的底部更靠近該基底的位置。A semiconductor device comprising: a substrate; a plurality of fin structures on the substrate and extending in a first direction, an adjacent opening between the fin structures; a plurality of comb structures, The comb structure includes a conductor material, each comb structure comprising: a plurality of comb portions inserted in the openings between adjacent fin structures and in contact with sidewalls of adjacent fin structures; a connecting portion extending in a second direction on the fin structures and connecting the comb portions; and a plurality of dielectric posts inserted in the opening between the adjacent fin structures and The sidewalls of the adjacent fin structures and the comb portions are in contact and extend to a position closer to the substrate than the bottom of the fin structures. 如申請專利範圍第7項所述的半導體元件,其中該些鰭狀結構包括一堆疊層以及一電荷儲存層,該堆疊層包括交互堆疊的至少一導體層以及至少一介電層,該電荷儲存層覆蓋位於該開口的底部的該基底以及該堆疊層的表面。The semiconductor device of claim 7, wherein the fin structures comprise a stacked layer and a charge storage layer, the stacked layer comprising at least one conductor layer and at least one dielectric layer alternately stacked, the charge storage A layer covers the substrate at the bottom of the opening and the surface of the stacked layer. 如申請專利範圍第7項所述的半導體元件,其中每一介電柱分別具有不同的高度。The semiconductor device of claim 7, wherein each of the dielectric posts has a different height. 如申請專利範圍第7項所述的半導體元件,其中每一介電柱的高度大於每一鰭狀結構的高度。The semiconductor component of claim 7, wherein the height of each dielectric post is greater than the height of each fin structure.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1967842A (en) * 2005-11-14 2007-05-23 三星电子株式会社 Fabrication of local damascene finfets using contact type nitride damascene mask
US20130015521A1 (en) * 2010-11-19 2013-01-17 Micron Technology, Inc. Cross-hair cell devices and methods for manufacturing the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1967842A (en) * 2005-11-14 2007-05-23 三星电子株式会社 Fabrication of local damascene finfets using contact type nitride damascene mask
US20130015521A1 (en) * 2010-11-19 2013-01-17 Micron Technology, Inc. Cross-hair cell devices and methods for manufacturing the same

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