TWI524549B - A photoelectronic element and the manufacturing method thereof - Google Patents

A photoelectronic element and the manufacturing method thereof Download PDF

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TWI524549B
TWI524549B TW102119091A TW102119091A TWI524549B TW I524549 B TWI524549 B TW I524549B TW 102119091 A TW102119091 A TW 102119091A TW 102119091 A TW102119091 A TW 102119091A TW I524549 B TWI524549 B TW I524549B
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layer
substrate
conductive
insulating substrate
region
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TW102119091A
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TW201342655A (en
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姚久琳
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晶元光電股份有限公司
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Description

光電元件及其製造方法 Photoelectric element and method of manufacturing same

本發明係關於一光電元件,尤其關於一種具有複合基板的光電元件。 The present invention relates to a photovoltaic element, and more particularly to a photovoltaic element having a composite substrate.

光電元件包含許多種類,例如發光二極體(Light-emitting Diode;LED)、太陽能電池(Solar Cell)和光電二極體(Photo diode)等。以LED為例,LED係一種固態半導體元件,其至少包含一p-n接面(p-n junction),此p-n接面係形成於p型與n型半導體層之間。當於p-n接面上施加一定程度之偏壓時,p型半導體層中之電洞與n型半導體層中之電子會結合而釋放出光。此光產生之區域一般又稱為發光區(light-emitting region)。 Photoelectric elements include many types, such as light-emitting diodes (LEDs), solar cells (Solar cells), and photodiodes (Photo diodes). Taking an LED as an example, the LED is a solid-state semiconductor device including at least a p-n junction formed between the p-type and n-type semiconductor layers. When a certain degree of bias is applied to the p-n junction, the holes in the p-type semiconductor layer combine with the electrons in the n-type semiconductor layer to emit light. This region of light generation is also commonly referred to as the light-emitting region.

LED的主要特徵在於尺寸小、發光效率高、壽命長、反應快速、可靠度高和色度良好,目前已經廣泛使用在電器、汽車、招牌和交通號誌上。隨著全彩LED的問世,LED已逐漸取代傳統的照明設備,如螢光燈和白熱燈泡。 The main features of LEDs are small size, high luminous efficiency, long life, fast response, high reliability and good chromaticity. They have been widely used in electrical appliances, automobiles, signboards and traffic signs. With the advent of full-color LEDs, LEDs have gradually replaced traditional lighting devices such as fluorescent lights and incandescent light bulbs.

上述光電元件可進一步地以基板經由焊塊或膠材與一基座連接,以形成一發光裝置或一吸光裝置。此外,基座更具有至少 一電路,可經由一導電結構,例如金屬線,電連接發光裝置或吸光裝置之電極。 The above-mentioned photovoltaic element may be further connected to a substrate via a solder bump or a glue material to form a light-emitting device or a light-absorbing device. In addition, the pedestal has at least A circuit electrically connecting the electrodes of the light emitting device or the light absorbing device via a conductive structure, such as a metal wire.

依據本發明之第一實施例,一種光電元件,包含一電絕緣基板;一導電基板,包含一部分位於該電絕緣基板之中;一半導體疊層;以及一黏結層,位於該電絕緣基板及該半導體層之間。 According to a first embodiment of the present invention, a photovoltaic element includes an electrically insulating substrate; a conductive substrate including a portion of the electrically insulating substrate; a semiconductor laminate; and a bonding layer on the electrically insulating substrate and the Between the semiconductor layers.

10、20、30、40、50‧‧‧複合基板 10, 20, 30, 40, 50‧‧‧ composite substrate

101‧‧‧空腔 101‧‧‧ cavity

102、202、302、402、502‧‧‧電絕緣基板 102, 202, 302, 402, 502‧‧‧Electrically insulated substrates

103‧‧‧第一反射層 103‧‧‧First reflective layer

104、204、304、404、504‧‧‧中介層 104, 204, 304, 404, 504‧‧‧Intermediary

105‧‧‧吸附層 105‧‧‧Adsorption layer

106、206、306、406、506‧‧‧導電基板 106, 206, 306, 406, 506‧‧‧ conductive substrate

107、207、307、407‧‧‧接觸表面 107, 207, 307, 407‧‧‧ contact surfaces

12、22、32、42、52‧‧‧黏結層 12, 22, 32, 42, 52‧‧ ‧ adhesive layer

122、222、322、422、522‧‧‧導電區 122, 222, 322, 422, 522‧‧‧ conductive areas

124、224、324、424、524‧‧‧電絕緣區 124, 224, 324, 424, 524‧‧ Electrically insulating areas

126‧‧‧導電區之上表面 126‧‧‧Top surface of conductive area

13、23、53‧‧‧電流阻擋層 13, 23, 53‧‧‧ current barrier

132‧‧‧電流阻擋層之上表面 132‧‧‧The upper surface of the current blocking layer

14、24、34、44、54‧‧‧第一電流擴散層 14, 24, 34, 44, 54‧‧‧ first current diffusion layer

15、25、35、45、55‧‧‧第二電流擴散層 15, 25, 35, 45, 55‧‧‧second current diffusion layer

152‧‧‧第二電流擴散層之下表面 152‧‧‧Under the surface of the second current diffusion layer

16、26、36、46、56‧‧‧第一半導體疊層 16, 26, 36, 46, 56‧‧‧ first semiconductor stack

162、262、362、462、562‧‧‧第一半導體層 162, 262, 362, 462, 562‧‧‧ first semiconductor layer

164、264、364、464、564‧‧‧第一活性層 164, 264, 364, 464, 564‧‧‧ first active layer

166、266、366、466、566‧‧‧第二半導體層 166, 266, 366, 466, 566‧‧‧ second semiconductor layer

17、27、37、47、57‧‧‧第一電極 17, 27, 37, 47, 57‧‧‧ first electrode

172‧‧‧第一電極之下表面 172‧‧‧The lower surface of the first electrode

21、31、51‧‧‧窗戶層 21, 31, 51‧‧ ‧ window layer

368、568‧‧‧高能隙區 368, 568‧‧‧ high energy gap area

43‧‧‧第二反射層 43‧‧‧Second reflective layer

48‧‧‧第三電流擴散層 48‧‧‧ Third current diffusion layer

49‧‧‧第二半導體疊層 49‧‧‧Second semiconductor stack

58‧‧‧第二電極 58‧‧‧second electrode

59‧‧‧通孔 59‧‧‧through hole

6‧‧‧光源產生裝置 6‧‧‧Light source generating device

61‧‧‧光源 61‧‧‧Light source

62‧‧‧電源供應系統 62‧‧‧Power supply system

63‧‧‧控制元件 63‧‧‧Control elements

7‧‧‧背光模組 7‧‧‧Backlight module

71‧‧‧光學元件 71‧‧‧Optical components

圖式用以促進對本發明之理解,係本說明書之一部分。圖式之實施例配合實施方式之說明以解釋本發明之原理。 The drawings are intended to facilitate an understanding of the invention and are part of the specification. The embodiments of the drawings are described in conjunction with the embodiments to explain the principles of the invention.

第1A-1G圖係依據本發明之第一實施例之製造流程剖面圖。 1A-1G is a cross-sectional view of a manufacturing process in accordance with a first embodiment of the present invention.

第2A圖係依據本發明之第二實施例之剖面圖。 Fig. 2A is a cross-sectional view showing a second embodiment of the present invention.

第2B圖係依據本發明之第三實施例之剖面圖。 Fig. 2B is a cross-sectional view showing a third embodiment of the present invention.

第3圖係依據本發明之第四實施例之剖面圖。 Figure 3 is a cross-sectional view showing a fourth embodiment of the present invention.

第4圖係依據本發明之第五實施例之剖面圖。 Figure 4 is a cross-sectional view showing a fifth embodiment of the present invention.

第5A圖係依據本發明之第六實施例之剖面圖。 Fig. 5A is a cross-sectional view showing a sixth embodiment of the present invention.

第5B圖係依據本發明之第七實施例之剖面圖。 Fig. 5B is a cross-sectional view showing a seventh embodiment of the present invention.

第5C圖係依據本發明之第八實施例之剖面圖。 Figure 5C is a cross-sectional view showing an eighth embodiment of the present invention.

第6圖係為示意圖,顯示利用本發明實施例所組成之一光源產生裝置之示意圖。 Figure 6 is a schematic view showing a schematic diagram of a light source generating apparatus constructed using an embodiment of the present invention.

第7圖係為示意圖,顯示利用本發明實施例所組成之一 背光模組之示意圖。 Figure 7 is a schematic diagram showing one of the embodiments of the present invention. A schematic diagram of a backlight module.

本發明之實施例會被詳細地描述,並且繪製於圖式中,相同或類似的部分會以相同或相似的號碼在各圖式以及說明出現。 The embodiments of the present invention are described in detail, and in the drawings, the same or similar

第1A-1G圖係第一實施例之製造流程剖面圖,其中第1A-1C圖係如第1G圖所示之一光電元件所包含之複合基板10之製造流程剖面圖。如第1C圖所示,複合基板10具有一電絕緣基板102、一導電基板106與一中介層104形成於電絕緣基板102與導電基板106之間。如第1A圖所示,提供具有一空腔101之電絕緣基板102,空腔101形成於電絕緣基板102之中,係移除部分電絕緣基板102而由其裸露之內壁環繞形成之一空間。形成空腔101之方法包含蝕刻或雷射剝除法。如第1B圖所示,一中介層104形成於電絕緣基板102之下及空腔101與電絕緣基板102之間,中介層104包含一吸附層105位於電絕緣基板102之下以及空腔101與電絕緣基板102之間,以及一第一反射層103位於電絕緣基板102與吸附層105之間。如第1C圖所示,導電基板106形成於中介層104之下以形成複合基板10,其中導電基板106之一部分位於空腔101之中。接著,如第1D-1E圖所示,一黏結層12形成於複合基板10之上,其中黏結層12包含一導電區122,位於導電基板106之上,可與導電基板106形成電連接;以及一電絕緣區124位於電絕緣基板102之上,環繞且鄰接於導電區122,可與電絕緣基板102直接接觸,鄰接係指與導電區122之側邊直接接觸。一第一電流擴散層14形成於黏結層12之上。如第1F-1G圖所示,一第一半導體疊層16形成於第一電流擴散層14之上,其中第一半導體疊層16包含一第一半導體層162,位 於第一電流擴散層14之上;一第一活性層164位於第一半導體層162之上;以及一第二半導體層166位於發光層164之上。一電流阻擋層13形成於第一半導體疊層16之上,其中電流阻擋層13位於導電區122所在位置向上延伸之處;一第二電流擴散層15形成於第一半導體疊層16與電流阻擋層13之上,且覆蓋電流阻擋層13;以及一第一電極17形成於第二電流擴散層15之上,其中第一電極17位於導電區122所在位置向上延伸之處,導電區122之上表面126之面積較佳地係不大於第一電極17之下表面172之面積。 1A-1G is a cross-sectional view showing a manufacturing process of the first embodiment, wherein the first A-1C is a cross-sectional view showing a manufacturing process of the composite substrate 10 included in the photovoltaic element shown in Fig. 1G. As shown in FIG. 1C, the composite substrate 10 has an electrically insulating substrate 102, a conductive substrate 106 and an interposer 104 formed between the electrically insulating substrate 102 and the electrically conductive substrate 106. As shown in FIG. 1A, an electrically insulating substrate 102 having a cavity 101 is formed. The cavity 101 is formed in the electrically insulating substrate 102, and a portion of the electrically insulating substrate 102 is removed to form a space surrounded by its exposed inner wall. . The method of forming the cavity 101 includes etching or laser stripping. As shown in FIG. 1B, an interposer 104 is formed under the electrically insulating substrate 102 and between the cavity 101 and the electrically insulating substrate 102. The interposer 104 includes an adsorption layer 105 under the electrically insulating substrate 102 and the cavity 101. Between the electrically insulating substrate 102 and a first reflective layer 103 is disposed between the electrically insulating substrate 102 and the adsorption layer 105. As shown in FIG. 1C, a conductive substrate 106 is formed under the interposer 104 to form a composite substrate 10 in which one portion of the conductive substrate 106 is located in the cavity 101. Next, as shown in FIG. 1D-1E, a bonding layer 12 is formed on the composite substrate 10, wherein the bonding layer 12 includes a conductive region 122 on the conductive substrate 106 to form an electrical connection with the conductive substrate 106; An electrically insulating region 124 is disposed over the electrically insulating substrate 102, surrounding and adjacent to the electrically conductive region 122, and is in direct contact with the electrically insulating substrate 102. The adjacent fingers are in direct contact with the sides of the electrically conductive region 122. A first current spreading layer 14 is formed over the bonding layer 12. As shown in FIG. 1F-1G, a first semiconductor stack 16 is formed over the first current spreading layer 14, wherein the first semiconductor stack 16 includes a first semiconductor layer 162. Above the first current diffusion layer 14; a first active layer 164 is over the first semiconductor layer 162; and a second semiconductor layer 166 is over the luminescent layer 164. A current blocking layer 13 is formed over the first semiconductor stack 16, wherein the current blocking layer 13 is located at a position where the conductive region 122 is located upward; a second current spreading layer 15 is formed on the first semiconductor stack 16 and current blocking Above the layer 13, and covering the current blocking layer 13; and a first electrode 17 is formed on the second current diffusion layer 15, wherein the first electrode 17 is located at a position where the conductive region 122 is located upward, above the conductive region 122 The area of surface 126 is preferably no greater than the area of lower surface 172 of first electrode 17.

電絕緣基板102用以支撐位於其上之半導體結構,其材料可為能隙較高之電絕緣材料,例如藍寶石(Sapphire)、鑽石(Diamond)、玻璃(Glass)、石英(Quartz)、壓克力(Acryl)、氧化鋅(ZnO)或氮化鋁(AlN)。第一反射層103可為具有高反射率之材料,例如銅(Cu)、鋁(Al)、銦(In)、錫(Sn)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、鎳(Ni)、鉻(Cr)、鎘(Cd)、鈷(Co)、錳(Mn)、銻(Sb)、鉍(Bi)、鎵(Ga)、鉈(Tl)、砷(As)、硒(Se)、碲(Te)、釙(Po)、銥(Ir)、錸(Re)、銠(Rh)、鋨(Os)、鎢(W)、鋰(Li)、鈉(Na)、鉀(K)、鈹(Be)、鎂(Mg)、鈣(Ca)、鍶(Sr)、鋇(Ba)、鋯(Zr)、鉬(Mo)、鑭(La)、銅-錫(Cu-Sn)、銅-鋅(Cu-Zn)、銅-鎘(Cu-Cd)、錫-鉛-銻(Sn-Pb-Sb)、錫-鉛-鋅(Sn-Pb-Zn)、鎳-錫(Ni-Sn)、鎳-鈷(Ni-Co)或金合金(Au alloy)等,以反射外來或第一活性層164產生之光線。吸附層105可用以協助電鍍材料的附著力及沉積,可為具有導電性之材料,例如銅(Cu)、鋁(Al)、銦(In)、錫(Sn)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、鎳(Ni)、鉻(Cr)、鎘(Cd)、鈷(Co)、錳(Mn)、銻(Sb)、鉍(Bi)、鎵(Ga)、鉈(Tl)、砷(As)、硒(Se)、碲(Te)、釙(Po)、銥(Ir)、錸(Re)、銠(Rh)、鋨(Os)、鎢(W)、鋰(Ii)、 鈉(Na)、鉀(K)、鈹(Be)、鎂(Mg)、鈣(Ca)、鍶(Sr)、鋇(Ba)、鋯(Zr)、鉬(Mo)、鑭(La)、銅-錫(Cu-Sn)、銅-鋅(Cu-Zn)、銅-鎘(Cu-Cd)、錫-鉛-銻(Sn-Pb-Sb)、錫-鉛-鋅(Sn-Pb-Zn)、鎳-錫(Ni-Sn)、鎳-鈷(Ni-Co)或金合金(Au alloy)等。導電基板106可支撐電絕緣基板102與其上之半導體結構,以及幫助導熱或導電,材料包含銅(Cu)、鋁(Al)、銦(In)、錫(Sn)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、鎳(Ni)、鉻(Cr)、鎘(Cd)、鈷(Co)、錳(Mn)、銻(Sb)、鉍(Bi)、鎵(Ga)、鉈(Tl)、砷(As)、硒(Se)、碲(Te)、釙(Po)、銥(Ir)、錸(Re)、銠(Rh)、鋨(Os)、鎢(W)、鋰(Li)、鈉(Na)、鉀(K)、鈹(Be)、鎂(Mg)、鈣(Ca)、鍶(Sr)、鋇(Ba)、鋯(Zr)、鉬(Mo)、鑭(La)、銅-錫(Cu-Sn)、銅-鋅(Cu-Zn)、銅-鎘(Cu-Cd)、錫-鉛-銻(Sn-Pb-Sb)、錫-鉛-鋅(Sn-Pb-Zn)、鎳-錫(Ni-Sn)、鎳-鈷(Ni-Co)、金合金(Au alloy)、錫化金(AuSn)、銀化銦(InAg)、金化銦(InAu)、鈹化金(AuBe)、鍺化金(AuGe)、鋅化金(AuZn)、錫化鉛(PbSn)或銦化鈀(PdIn)。導電基板106的形成方法包括電鍍法。此外,複合基板10之材料也可包括銅(Cu)、鋁(Al)、金屬、複合材料、金屬基複合材料(Metal Matrix Composite;MMC)、陶瓷基複合材料(Ceramic Matrix Composite;CMC)、矽(Si)、磷化碘(IP)、硒化鋅(ZnSe)、氮化鋁(AlN)、砷化鎵(GaAs)、碳化矽(SiC)、磷化鎵(GaP)、磷砷化鎵(GaAsP)、硒化鋅(ZnSe)、氧化鋅(ZnO)、磷化銦(InP)、鎵酸鋰(LiGaO2)或鋁酸鋰(LiAlO2)。 The electrically insulating substrate 102 is used to support the semiconductor structure located thereon, and the material thereof can be an electrically insulating material with a high energy gap, such as Sapphire, Diamond, Glass, Quartz, and Acrylic. Acryl, zinc oxide (ZnO) or aluminum nitride (AlN). The first reflective layer 103 may be a material having high reflectivity, such as copper (Cu), aluminum (Al), indium (In), tin (Sn), gold (Au), platinum (Pt), zinc (Zn), Silver (Ag), titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), nickel (Ni), chromium (Cr), cadmium (Cd), cobalt (Co), manganese (Mn),锑(Sb), bismuth (Bi), gallium (Ga), strontium (Tl), arsenic (As), selenium (Se), strontium (Te), strontium (Po), strontium (Ir), strontium (Re), Rh (Rh), bismuth (Os), tungsten (W), lithium (Li), sodium (Na), potassium (K), bismuth (Be), magnesium (Mg), calcium (Ca), strontium (Sr), Ba (Ba), Zr (Zr), Mo (Mo), La (La), Cu-Sn, Cu-Zn, Cu-Cd, Tin-Lead -锑(Sn-Pb-Sb), tin-lead-zinc (Sn-Pb-Zn), nickel-tin (Ni-Sn), nickel-cobalt (Ni-Co) or gold alloy (Au alloy), etc. The light generated by the foreign or first active layer 164 is reflected. The adsorption layer 105 can be used to assist the adhesion and deposition of the plating material, and can be a conductive material such as copper (Cu), aluminum (Al), indium (In), tin (Sn), gold (Au), platinum ( Pt), zinc (Zn), silver (Ag), titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), nickel (Ni), chromium (Cr), cadmium (Cd), cobalt ( Co), manganese (Mn), strontium (Sb), bismuth (Bi), gallium (Ga), strontium (Tl), arsenic (As), selenium (Se), strontium (Te), strontium (Po), strontium (Po) Ir), 铼 (Re), 铑 (Rh), 锇 (Os), tungsten (W), lithium (Ii), Sodium (Na), potassium (K), strontium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), zirconium (Zr), molybdenum (Mo), lanthanum (La), Cu-Sn, Cu-Zn, Cu-Cd, Sn-Pb-Sb, Tin-Pb-Sb, Sn-Pb- Zn), nickel-tin (Ni-Sn), nickel-cobalt (Ni-Co) or gold alloy (Au alloy). The conductive substrate 106 can support the electrically insulating substrate 102 and the semiconductor structure thereon, and help to conduct heat or conduct. The material comprises copper (Cu), aluminum (Al), indium (In), tin (Sn), gold (Au), platinum ( Pt), zinc (Zn), silver (Ag), titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), nickel (Ni), chromium (Cr), cadmium (Cd), cobalt ( Co), manganese (Mn), strontium (Sb), bismuth (Bi), gallium (Ga), strontium (Tl), arsenic (As), selenium (Se), strontium (Te), strontium (Po), strontium (Po) Ir), ruthenium (Re), rhodium (Rh), osmium (Os), tungsten (W), lithium (Li), sodium (Na), potassium (K), bismuth (Be), magnesium (Mg), calcium ( Ca), strontium (Sr), barium (Ba), zirconium (Zr), molybdenum (Mo), lanthanum (La), copper-tin (Cu-Sn), copper-zinc (Cu-Zn), copper-cadmium ( Cu-Cd), tin-lead-bismuth (Sn-Pb-Sb), tin-lead-zinc (Sn-Pb-Zn), nickel-tin (Ni-Sn), nickel-cobalt (Ni-Co), gold Alloy, AuSn, InAg, InAu, AuBe, AuGe, AuZn, Tin Lead (PbSn) or indium palladium (PdIn). The method of forming the conductive substrate 106 includes an electroplating method. In addition, the material of the composite substrate 10 may also include copper (Cu), aluminum (Al), metal, composite materials, metal matrix composite (MMC), ceramic matrix composite (CMC), and germanium. (Si), phosphine oxide (IP), zinc selenide (ZnSe), aluminum nitride (AlN), gallium arsenide (GaAs), tantalum carbide (SiC), gallium phosphide (GaP), gallium arsenide ( GaAsP), zinc selenide (ZnSe), zinc oxide (ZnO), indium phosphide (InP), lithium gallate (LiGaO2) or lithium aluminate (LiAlO2).

導電區122為可導電及接合之材料,例如銦(In)、錫(Sn)、鋁(Al)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、銅(Cu)、鎳(Ni)、錫化金(AuSn)、銀化銦(InAg)、金化銦(InAu)、鈹化金(AuBe)、鍺化金(AuGe)、鋅化金(AuZn)、錫化鉛(PbSn)或銦化鈀(PdIn),用以傳導電流 以及接合複合基板10與位於其上之半導體結構。電絕緣區124為能隙較高之可電絕緣及接合之材料,例如介電材料、Su8、苯并環丁烯(BCB)、過氟環丁烷(PFCB)、環氧樹脂(Epoxy)、丙烯酸樹脂(Acrylic Resin)、環烯烴聚合物(COC)、聚甲基丙烯酸甲酯(PMMA)、聚對苯二甲酸乙二酯(PET)、聚碳酸酯(PC)、聚醚醯亞胺(Polyetherimide)、氟碳聚合物(Fluorocarbon Polymer)、矽膠(Silicone)、玻璃(Glass)、氧化鋁(Al2O3)、氧化矽(SiO2)、氧化鈦(TiO2)、氮化矽(SiNx)、旋塗玻璃(SOG)、四乙基矽烷(Tetraethyl orthosilane;TEOS)或其他有機黏結材料,用以改變電流路徑以及接合複合基板10與位於其上之半導體結構。第一電流擴散層14與第二電流擴散層15可為具有低側向電阻之材料,使電流較易側向擴散,包括氧化銦錫(ITO)、氧化銦(InO)、氧化錫(SnO)、氧化鎘錫(CTO)、氧化銻錫(ATO)、氧化鋅鋁(AZO)、氧化鋅錫(ZTO)、氧化鋅(ZnO)、砷鎵化鋁(AlGaAs)、氮化鎵(GaN)、磷化鎵(GaP)、砷化鎵(GaAs)、磷化鎵砷(GaAsP)、銦(In)、錫(Sn)、鋁(Al)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、銅(Cu)、鎳(Ni)、銀化銦(InAg)、金化銦(InAu)、鈹化金(AuBe)、鍺化金(AuGe)、鋅化金(AuZn)、錫化鉛(PbSn)、銦化鈀(PdIn)或錫化金(AuSn),其結構可為單層或疊層結構。第一半導體疊層16之第一活性層164能吸收或產生光線,第一半導體層162與第二半導體層166的電性相異,材料包括一種或一種以上之物質選自鎵(Ga)、鋁(Al)、銦(In)、砷(As)、磷(P)、氮(N)、鋅(Zn)、鎘(Cd),硒(Se)、銻(Sb)、鎘(Cd)、鍗(Te)、汞(Hg)、硫(S)、氫(H)、鎂(Mg)、錫(Sn)、硼(B)、鉛(Pb)、碳(C)與矽(Si)所構成之群組。第二半導體層166可選擇性地包含一粗糙之上表面,位於第二電流擴散層15之下。電流阻擋層13可為高電 阻材料,例如介電材料、Su8、苯并環丁烯(BCB)、過氟環丁烷(PFCB)、環氧樹脂(Epoxy)、丙烯酸樹脂(Acrylic Resin)、環烯烴聚合物(COC)、聚甲基丙烯酸甲酯(PMMA)、聚對苯二甲酸乙二酯(PET)、聚碳酸酯(PC)、聚醚醯亞胺(Polyetherimide)、氟碳聚合物(Fluorocarbon Polymer)、矽膠(Silicone)、玻璃(Glass)、氧化鋁(Al2O3)、氧化矽(SiO2)、氧化鈦(TiO2)、氮化矽(SiNx)、旋塗玻璃(SOG)、四乙基矽烷(Tetraethyl Orthosilane;TEOS)或其他有機材料等,以改變光電元件之電流路徑。第一電極17可為金屬材料,例如銅(Cu)、鋁(Al)、銦(In)、錫(Sn)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、鎳(Ni)、鉻(Cr)、鎘(Cd)、鈷(Co)、錳(Mn)、銻(Sb)、鉍(Bi)、鎵(Ga)、鉈(Tl)、砷(As)、硒(Se)、碲(Te)、釙(Po)、銥(Ir)、錸(Re)、銠(Rh)、鋨(Os)、鎢(W)、鋰(Li)、鈉(Na)、鉀(K)、鈹(Be)、鎂(Mg)、鈣(Ca)、鍶(Sr)、鋇(Ba)、鋯(Zr)、鉬(Mo)、鑭(La)、銅-錫(Cu-Sn)、銅-鋅(Cu-Zn)、銅-鎘(Cu-Cd)、錫-鉛-銻(Sn-Pb-Sb)、錫-鉛-鋅(Sn-Pb-Zn)、鎳-錫(Ni-Sn)、鎳-鈷(Ni-Co)或金合金(Au alloy)等,以接受外來的電壓。 The conductive region 122 is a material capable of conducting and bonding, such as indium (In), tin (Sn), aluminum (Al), gold (Au), platinum (Pt), zinc (Zn), silver (Ag), titanium (Ti) ), lead (Pb), palladium (Pd), germanium (Ge), copper (Cu), nickel (Ni), gold (AuSn), indium (InAg), indium (InAu), antimony AuBe, AuGe, AuZn, PbSn or PdIn to conduct current And bonding the composite substrate 10 to the semiconductor structure thereon. The electrically insulating region 124 is a material having high energy gap and can be electrically insulated and bonded, such as a dielectric material, Su8, benzocyclobutene (BCB), perfluorocyclobutane (PFCB), epoxy resin (Epoxy), Acrylic Resin, cycloolefin polymer (COC), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate (PC), polyether quinone ( Polyetherimide), Fluorocarbon Polymer, Silicone, Glass, Al2O3, SiO2, TiO2, SiNx, Spin-on Glass (SOG), Tetraethyl orthosilane (TEOS) or other organic bonding material to modify the current path and bond the composite substrate 10 to the semiconductor structure thereon. The first current diffusion layer 14 and the second current diffusion layer 15 may be materials having a low lateral resistance, which facilitate current lateral diffusion, including indium tin oxide (ITO), indium oxide (InO), and tin oxide (SnO). , cadmium tin oxide (CTO), antimony tin oxide (ATO), zinc aluminum oxide (AZO), zinc tin oxide (ZTO), zinc oxide (ZnO), aluminum gallium arsenide (AlGaAs), gallium nitride (GaN), Gallium phosphide (GaP), gallium arsenide (GaAs), gallium arsenide (GaAsP), indium (In), tin (Sn), aluminum (Al), gold (Au), platinum (Pt), zinc (Zn ), silver (Ag), titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), copper (Cu), nickel (Ni), indium (InAg), indium (InAu) , AuBe, AuGe, AuZn, PbSn, PdIn or AuSn, the structure can be single layer or Laminated structure. The first active layer 164 of the first semiconductor stack 16 can absorb or generate light, and the first semiconductor layer 162 and the second semiconductor layer 166 are electrically different, and the material includes one or more substances selected from the group consisting of gallium (Ga), Aluminum (Al), indium (In), arsenic (As), phosphorus (P), nitrogen (N), zinc (Zn), cadmium (Cd), selenium (Se), antimony (Sb), cadmium (Cd),鍗(Te), mercury (Hg), sulfur (S), hydrogen (H), magnesium (Mg), tin (Sn), boron (B), lead (Pb), carbon (C) and bismuth (Si) The group that makes up. The second semiconductor layer 166 may optionally include a rough upper surface under the second current diffusion layer 15. The current blocking layer 13 can be high power Resistive materials, such as dielectric materials, Su8, benzocyclobutene (BCB), perfluorocyclobutane (PFCB), epoxy resin (Epoxy), acrylic resin (Acrylic Resin), cycloolefin polymer (COC), Polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate (PC), polyetherimide, fluorocarbon polymer, silicone (Silicone) ), Glass, Al2O3, SiO2, TiO2, SiNx, SOG, Tetraethyl Orthosilane (TEOS) or Other organic materials, etc., to change the current path of the photovoltaic element. The first electrode 17 may be a metal material such as copper (Cu), aluminum (Al), indium (In), tin (Sn), gold (Au), platinum (Pt), zinc (Zn), silver (Ag), Titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), nickel (Ni), chromium (Cr), cadmium (Cd), cobalt (Co), manganese (Mn), antimony (Sb),铋 (Bi), gallium (Ga), strontium (Tl), arsenic (As), selenium (Se), strontium (Te), strontium (Po), strontium (Ir), strontium (Re), argon (Rh), Os, tungsten (W), lithium (Li), sodium (Na), potassium (K), beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), Zirconium (Zr), molybdenum (Mo), lanthanum (La), copper-tin (Cu-Sn), copper-zinc (Cu-Zn), copper-cadmium (Cu-Cd), tin-lead-bismuth (Sn- Pb-Sb), tin-lead-zinc (Sn-Pb-Zn), nickel-tin (Ni-Sn), nickel-cobalt (Ni-Co) or Au alloy, etc., to accept an external voltage.

如第1G圖所示,第一電極17與電流阻擋層13皆位於導電區122之上方,較佳為導電區122所在位置向上延伸之處。其中電流阻擋層13之上表面132面積較佳地係不小於第一電極17之下表面172或導電區122之上表面126之面積,且不大於第二電流擴散層15之下表面152之面積。導電基板106包含一與導電區122直接接觸之接觸表面107,其中接觸表面107、電流阻擋層13、導電區122與第一電極17可具有相同或相異圖案之圖案化結構。導電區122可為一單一導電區,例如黏結層12中唯一以導電材料形成之一塊區域,位於第一電極17所在位置之向下延伸之處或下方, 並與接觸表面107直接接觸。 As shown in FIG. 1G, the first electrode 17 and the current blocking layer 13 are both located above the conductive region 122, preferably where the conductive region 122 extends upward. The area of the upper surface 132 of the current blocking layer 13 is preferably not less than the area of the lower surface 172 of the first electrode 17 or the upper surface 126 of the conductive region 122, and is not larger than the area of the lower surface 152 of the second current diffusion layer 15. . The conductive substrate 106 includes a contact surface 107 in direct contact with the conductive region 122, wherein the contact surface 107, the current blocking layer 13, the conductive region 122, and the first electrode 17 may have a patterned structure of the same or different patterns. The conductive region 122 can be a single conductive region, for example, the only region of the adhesive layer 12 formed of a conductive material, located at or below the position where the first electrode 17 is located, And in direct contact with the contact surface 107.

由於導電基板106為熱導率高之材料,可增加光電元件的熱傳導速率,提升光電元件的可靠度與發光效率。此外,藉由導電區122與導電基板106的電連接,使得光電元件的電流可以垂直導通;再配合能隙較高的電絕緣區124與電絕緣基板102,可避免吸光。電流阻擋層13位於第一電極17所在位置向下延伸之處或下方,使電流流向沒有電流阻擋層13覆蓋的區域,避免第一半導體疊層16位於第一電極17下方的區域產生光線,降低第一電極17吸光的機率。 Since the conductive substrate 106 is a material having high thermal conductivity, the thermal conduction rate of the photovoltaic element can be increased, and the reliability and luminous efficiency of the photovoltaic element can be improved. In addition, the electrical connection between the conductive region 122 and the conductive substrate 106 allows the current of the photovoltaic element to be vertically turned on; and the electrically insulating region 124 having a higher energy gap and the electrically insulating substrate 102 are combined to avoid light absorption. The current blocking layer 13 is located at or below the position where the first electrode 17 is located downward, so that current flows to a region not covered by the current blocking layer 13, and the first semiconductor layer 16 is prevented from being lighted in a region below the first electrode 17, reducing The probability of the first electrode 17 absorbing light.

第2A圖所示為一第二實施例之結構剖面圖,第二實施例與第一實施例相似,包含一複合基板20,其中複合基板20包含一電絕緣基板202、一中介層204與一導電基板206;一黏結層22,包含一導電區222與一電絕緣區224;一第一電流擴散層24;一第一半導體疊層26,包含一第一半導體層262、一第一活性層264與一第二半導體層266;一電流阻擋層23;一第二電流擴散層25;以及一第一電極27。第二實施例與第一實施例差異在於第二實施例更包含一窗戶層21,位於第一半導體疊層26與第一電流擴散層24之間。因為窗戶層21的折射率與第一半導體疊層26不同,可造成光線散射以提升光摘出效率。窗戶層21之材料包含氧化銦錫(ITO)、氧化銦(InO)、氧化錫(SnO)、氧化鎘錫(CTO)、氧化銻錫(ATO)、氧化鋅鋁(AZO)、氧化鋅錫(ZTO)、氧化鋅(ZnO)、砷化鋁鎵(AlGaAs)、氮化鎵(GaN)、磷化鎵(GaP)、砷化鎵(GaAs)或磷砷化鎵(GaAsP)。此外,窗戶層21可選擇性地包含一粗糙之下表面,位於窗戶層21與第一電流擴散層24之介面。第2B圖所示為一第三實施例之結構剖面圖,第三實施例與第二實施例相似,差異在 於電流阻擋層23位於第一電流擴散層24與窗戶層21之間,且被窗戶層21覆蓋。導電基板206包含一與導電區222直接接觸之接觸表面207,其中接觸表面207、電流阻擋層23、導電區222與第一電極27可具有相同或相異圖案之圖案化結構。 2A is a cross-sectional view showing a structure of a second embodiment. The second embodiment is similar to the first embodiment and includes a composite substrate 20. The composite substrate 20 includes an electrically insulating substrate 202, an interposer 204 and a The conductive substrate 206; a bonding layer 22, comprising a conductive region 222 and an electrically insulating region 224; a first current diffusion layer 24; a first semiconductor layer 26 comprising a first semiconductor layer 262, a first active layer 264 and a second semiconductor layer 266; a current blocking layer 23; a second current spreading layer 25; and a first electrode 27. The second embodiment differs from the first embodiment in that the second embodiment further comprises a window layer 21 between the first semiconductor stack 26 and the first current spreading layer 24. Because the refractive index of the window layer 21 is different from that of the first semiconductor stack 26, light scattering can be caused to enhance light extraction efficiency. The material of the window layer 21 comprises indium tin oxide (ITO), indium oxide (InO), tin oxide (SnO), cadmium tin oxide (CTO), antimony tin oxide (ATO), zinc aluminum oxide (AZO), zinc tin oxide ( ZTO), zinc oxide (ZnO), aluminum gallium arsenide (AlGaAs), gallium nitride (GaN), gallium phosphide (GaP), gallium arsenide (GaAs) or gallium arsenide (GaAsP). In addition, the window layer 21 can optionally include a rough lower surface located between the window layer 21 and the first current spreading layer 24. 2B is a cross-sectional view showing a structure of a third embodiment, and the third embodiment is similar to the second embodiment, and the difference is The current blocking layer 23 is located between the first current diffusion layer 24 and the window layer 21 and is covered by the window layer 21. The conductive substrate 206 includes a contact surface 207 in direct contact with the conductive region 222, wherein the contact surface 207, the current blocking layer 23, the conductive region 222, and the first electrode 27 may have patterned structures of the same or different patterns.

如第3圖所示,一第四實施例與第二實施例相似,包含一複合基板30,其中複合基板30包含一電絕緣基板302、一中介層304與一導電基板306;一黏結層32,包含一導電區322與一電絕緣區324;一第一電流擴散層34;一第一半導體疊層36,包含一第一半導體層362、一第一活性層364與一第二半導體層366;一第二電流擴散層35;以及一第一電極37。差異在於第四實施例中沒有電流阻擋層,而第一活性層364包含一高能隙區368,係一高電阻區域,可改變光電元件內的電流路徑。高能隙區368位於第一電極37所在位置之向下延伸之處或下方,使電流流向高能隙區368以外的區域,避免高能隙區368產生光線,以降低第一電極17吸光的機率。導電基板306包含一與導電區322直接接觸之接觸表面307,其中接觸表面307、導電區322、高能隙區368與第一電極37可具有相同或相異圖案的圖案化結構。 As shown in FIG. 3, a fourth embodiment is similar to the second embodiment, and includes a composite substrate 30. The composite substrate 30 includes an electrically insulating substrate 302, an interposer 304 and a conductive substrate 306, and a bonding layer 32. A conductive region 322 and an electrically insulating region 324; a first current diffusion layer 34; a first semiconductor layer 36 comprising a first semiconductor layer 362, a first active layer 364 and a second semiconductor layer 366 a second current spreading layer 35; and a first electrode 37. The difference is that there is no current blocking layer in the fourth embodiment, and the first active layer 364 includes a high energy gap region 368, which is a high resistance region, which can change the current path in the photovoltaic element. The high energy gap region 368 is located at or below the position where the first electrode 37 is located downward, so that current flows to a region other than the high energy gap region 368, and the high energy gap region 368 is prevented from generating light to reduce the probability of the first electrode 17 absorbing light. The conductive substrate 306 includes a contact surface 307 that is in direct contact with the conductive region 322, wherein the contact surface 307, the conductive region 322, the high energy gap region 368, and the first electrode 37 may have patterned structures of the same or different patterns.

高能隙區368的形成方法包含以雷射直接加熱第一活性層364的特定區域,於改變特定區域的組成後形成高能隙區368。或是以雷射加熱第二半導體層366,熱再傳導至第一活性層364的特定區域以改變其組成。高能隙區368位於第一電極37所在位置之向下延伸之處或下方。 The method of forming the high energy gap region 368 includes directly heating a specific region of the first active layer 364 with a laser, and forming a high energy gap region 368 after changing the composition of the specific region. Alternatively, the second semiconductor layer 366 is heated by laser, and heat is re-conducted to a specific region of the first active layer 364 to change its composition. The high energy gap region 368 is located at or below the downward extension of the location at which the first electrode 37 is located.

如第4圖所示,一第五實施例與第四實施例相似,包含一複合基板40,其中複合基板40包含一電絕緣基板402、一中介層404與一導 電基板406;一黏結層42,包含一導電區422與一電絕緣區424;一第一電流擴散層44;一第一半導體疊層46,包含一第一半導體層462、一第一活性層464與一第二半導體層466;一第二電流擴散層45;以及一第一電極47。差異在於第五實施例不具有高能隙區,但更包含一第二反射層43,位於複合基板40與黏結層42之間;一第二半導體疊層49,至少包含一第二活性層(未顯示),位於第二反射層43與黏結層42之間;以及一第三電流擴散層48,位於第二半導體疊層49與黏結層42之間。導電基板406包含一與第二反射層43直接接觸之接觸表面407,其中接觸表面407、導電區422與第一電極47可具有相同或相異圖案之圖案化結構。 As shown in FIG. 4, a fifth embodiment is similar to the fourth embodiment, and includes a composite substrate 40, wherein the composite substrate 40 includes an electrically insulating substrate 402, an interposer 404 and a guide. An electrical substrate 406; a bonding layer 42 comprising a conductive region 422 and an electrically insulating region 424; a first current spreading layer 44; a first semiconductor stack 46 comprising a first semiconductor layer 462, a first active layer 464 and a second semiconductor layer 466; a second current diffusion layer 45; and a first electrode 47. The difference is that the fifth embodiment does not have a high energy gap region, but further includes a second reflective layer 43 between the composite substrate 40 and the bonding layer 42. A second semiconductor laminate 49 includes at least a second active layer (not Displayed between the second reflective layer 43 and the bonding layer 42; and a third current spreading layer 48 between the second semiconductor stack 49 and the bonding layer 42. The conductive substrate 406 includes a contact surface 407 that is in direct contact with the second reflective layer 43, wherein the contact surface 407, the conductive region 422, and the first electrode 47 may have a patterned structure of the same or different patterns.

第二反射層43可為具有高反射率之材料,例如銅(Cu)、鋁(Al)、銦(In)、錫(Sn)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、鎳(Ni)、鉻(Cr)、鎘(Cd)、鈷(Co)、錳(Mn)、銻(Sb)、鉍(Bi)、鎵(Ga)、鉈(Tl)、砷(As)、硒(Se)、碲(Te)、釙(Po)、銥(Ir)、錸(Re)、銠(Rh)、鋨(Os)、鎢(W)、鋰(Li)、鈉(Na)、鉀(K)、鈹(Be)、鎂(Mg)、鈣(Ca)、鍶(Sr)、鋇(Ba)、鋯(Zr)、鉬(Mo)、鑭(La)、銅-錫(Cu-Sn)、銅-鋅(Cu-Zn)、銅-鎘(Cu-Cd)、錫-鉛-銻(Sn-Pb-Sb)、錫-鉛-鋅(Sn-Pb-Zn)、鎳-錫(Ni-Sn)、鎳-鈷(Ni-Co)或金合金(Au alloy)等,以反射第一活性層464或第二活性層所產生或外來之光線。第二半導體疊層49能產生或吸收光線,可選擇性地包含一粗糙之上表面,其材料包括一種或一種以上之物質選自鎵(Ga)、鋁(Al)、銦(In)、砷(As)、磷(P)、氮(N)、鋅(Zn)、鎘(Cd),硒(Se)、銻(Sb)、鎘(Cd)、鍗(Te)、汞(Hg)、硫(S)、氫(H)、鎂(Mg)、錫(Sn)、硼(B)、鉛(Pb)、碳(C)與矽(Si)所構成之群組。第三電流擴散層48可為具有低側向電阻之材料,使電流較易側向擴散,材 料包括氧化銦錫(ITO)、氧化銦(InO)、氧化錫(SnO)、氧化鎘錫(CTO)、氧化銻錫(ATO)、氧化鋅鋁(AZO)、氧化鋅錫(ZTO)、氧化鋅(ZnO)、砷鎵化鋁(AlGaAs)、氮化鎵(GaN)、磷化鎵(GaP)、砷化鎵(GaAs)、磷化砷鎵(GaAsP)、銦(In)、錫(Sn)、鋁(Al)、金(Au)、鉑(Pt)、鋅(Zn)、銀(Ag)、鈦(Ti)、鉛(Pb)、鈀(Pd)、鍺(Ge)、銅(Cu)、鎳(Ni)、銀化銦(InAg)、金化銦(InAu)、鈹化金(AuBe)、鍺化金(AuGe)、鋅化金(AuZn)、錫化鉛(PbSn)、銦化鈀(PdIn)或錫化金(AuSn),其結構可為單層或疊層結構。由於第一半導體疊層46與第二半導體疊層49也能吸收光線,可應用於光感測器或太陽能電池。 The second reflective layer 43 may be a material having high reflectivity, such as copper (Cu), aluminum (Al), indium (In), tin (Sn), gold (Au), platinum (Pt), zinc (Zn), Silver (Ag), titanium (Ti), lead (Pb), palladium (Pd), germanium (Ge), nickel (Ni), chromium (Cr), cadmium (Cd), cobalt (Co), manganese (Mn),锑(Sb), bismuth (Bi), gallium (Ga), strontium (Tl), arsenic (As), selenium (Se), strontium (Te), strontium (Po), strontium (Ir), strontium (Re), Rh (Rh), bismuth (Os), tungsten (W), lithium (Li), sodium (Na), potassium (K), bismuth (Be), magnesium (Mg), calcium (Ca), strontium (Sr), Ba (Ba), Zr (Zr), Mo (Mo), La (La), Cu-Sn, Cu-Zn, Cu-Cd, Tin-Lead -锑(Sn-Pb-Sb), tin-lead-zinc (Sn-Pb-Zn), nickel-tin (Ni-Sn), nickel-cobalt (Ni-Co) or gold alloy (Au alloy), etc. Reflecting light generated by the first active layer 464 or the second active layer or from the outside. The second semiconductor stack 49 can generate or absorb light, and optionally includes a rough upper surface, the material of which includes one or more substances selected from the group consisting of gallium (Ga), aluminum (Al), indium (In), and arsenic. (As), phosphorus (P), nitrogen (N), zinc (Zn), cadmium (Cd), selenium (Se), antimony (Sb), cadmium (Cd), antimony (Te), mercury (Hg), sulfur (S), hydrogen (H), magnesium (Mg), tin (Sn), boron (B), lead (Pb), carbon (C) and bismuth (Si). The third current diffusion layer 48 may be a material having a low lateral resistance, so that the current is more easily diffused laterally. Indium tin oxide (ITO), indium oxide (InO), tin oxide (SnO), cadmium tin oxide (CTO), antimony tin oxide (ATO), zinc aluminum oxide (AZO), zinc tin oxide (ZTO), oxidation Zinc (ZnO), AlGaAs, AlGaN, GaN, GaP, GaAs, GaAs, GaAs, Sn ) aluminum, Al, platinum, Pt, zinc, Zn, Zn, Pb, Pd, Pd ), nickel (Ni), indium (InAg), indium (InAu), gold (AuBe), gold (AuGe), gold (AuZn), lead (PbSn), indium Palladium (PdIn) or gold-plated gold (AuSn), which may have a single layer or a stacked structure. Since the first semiconductor stack 46 and the second semiconductor stack 49 can also absorb light, they can be applied to a photo sensor or a solar cell.

如第5A圖所示,一第六實施例與第二實施例相似,包含一複合基板50,其中複合基板50一電絕緣基板502、一中介層504與一導電基板506;一黏結層52,包含一導電區522與一電絕緣區524;一第一電流擴散層54;一窗戶層51;一第一半導體疊層56,包含一第一半導體層562、一第一活性層564與一第二半導體層566;一電流阻擋層53;一第二電流擴散層55;以及一第一電極57。差異在於第六實施例更包含一第二電極58位於第一半導體層562之上,經由一通孔59下向延伸連接至第一電流擴散層54,以及導電區522位與導電基板506形成電連接。第一電極57與第二電極58皆位於複合基板50之同一側,形成一水平式光電元件。此外,導電區522、電流阻擋層53與第一電極57具有相同或相異圖案的圖案化結構。如第5B圖所示,第七實施例與第六實施例相似,差異在於電流阻擋層53位於第一電流擴散層54與窗戶層51之間,且被窗戶層51覆蓋。如第5C圖所示,第八實施例與第六實施例相似,差異在於光電元件沒有電流阻擋層53,但第一活性層564更包括一高能隙區568位於第一電極57所在位置 之向下延伸之處或下方。導電區522、高能隙區568與第一電極57具有相同或相異圖案的圖案化結構。上述圖案化結構可為一連續圖案,例如一圓形具有至少一個突出部。 As shown in FIG. 5A, a sixth embodiment is similar to the second embodiment, and includes a composite substrate 50, wherein the composite substrate 50 is an electrically insulating substrate 502, an interposer 504 and a conductive substrate 506, and a bonding layer 52. The first semiconductor layer 56 includes a first semiconductor layer 562, a first active layer 564 and a first semiconductor layer 562. a semiconductor layer 566; a current blocking layer 53; a second current spreading layer 55; and a first electrode 57. The difference is that the sixth embodiment further includes a second electrode 58 disposed on the first semiconductor layer 562, connected to the first current diffusion layer 54 via a through hole 59, and the conductive region 522 is electrically connected to the conductive substrate 506. . The first electrode 57 and the second electrode 58 are located on the same side of the composite substrate 50 to form a horizontal photovoltaic element. In addition, the conductive region 522, the current blocking layer 53 and the first electrode 57 have a patterned structure of the same or different patterns. As shown in FIG. 5B, the seventh embodiment is similar to the sixth embodiment except that the current blocking layer 53 is located between the first current diffusion layer 54 and the window layer 51, and is covered by the window layer 51. As shown in FIG. 5C, the eighth embodiment is similar to the sixth embodiment except that the photovoltaic element has no current blocking layer 53, but the first active layer 564 further includes a high energy gap region 568 at the position of the first electrode 57. The downward extension or below. The conductive region 522, the high energy gap region 568 and the first electrode 57 have a patterned structure of the same or different patterns. The patterned structure may be a continuous pattern, such as a circle having at least one protrusion.

第6圖係繪示出一光源產生裝置示意圖,一光源產生裝置6包含切割本發明任一實施例中之一晶圓光電結構所產生之晶粒。光源產生裝置6可以是一照明裝置,例如路燈、車燈、或室內照明光源,也可以是交通號誌、或一平面顯示器中背光模組的一背光光源。光源產生裝置6包含前述光電元件組成之一光源61;一電源供應系統62以供應光源61一電流;以及一控制元件63,用以控制電源供應系統62。 Figure 6 is a schematic diagram showing a light source generating device. The light source generating device 6 includes a die which is formed by cutting a photovoltaic structure of a wafer in any of the embodiments of the present invention. The light source generating device 6 may be a lighting device, such as a street light, a car light, or an indoor lighting source, or may be a traffic signal or a backlight source of a backlight module in a flat display. The light source generating device 6 comprises a light source 61 of the aforementioned photovoltaic element; a power supply system 62 for supplying a current to the light source 61; and a control element 63 for controlling the power supply system 62.

第7圖係繪示出一背光模組剖面示意圖,一背光模組7包含前述實施例中的光源產生裝置6,以及一光學元件71。光學元件71可將由光源產生裝置6發出的光加以處理,以應用於平面顯示器,例如散射光源產生裝置6發出的光。 FIG. 7 is a cross-sectional view showing a backlight module. The backlight module 7 includes the light source generating device 6 of the foregoing embodiment, and an optical element 71. The optical element 71 can process the light emitted by the light source generating device 6 to be applied to a flat display such as the light emitted by the scattered light source generating device 6.

惟上述實施例僅為例示性說明本發明之原理及其功效,而非用於限制本發明。任何熟於此項技藝之人士均可在不違背本發明之技術原理及精神的情況下,對上述實施例進行修改及變化。因此本發明之權利保護範圍如後述之申請專利範圍所列。 The above-described embodiments are merely illustrative of the principles and effects of the invention and are not intended to limit the invention. Modifications and variations of the above-described embodiments can be made by those skilled in the art without departing from the spirit and scope of the invention. Therefore, the scope of the invention is as set forth in the appended claims.

10‧‧‧複合基板 10‧‧‧Composite substrate

102‧‧‧電絕緣基板 102‧‧‧Electrically insulating substrate

104‧‧‧中介層 104‧‧‧Intermediary

106‧‧‧導電基板 106‧‧‧Electrical substrate

107‧‧‧接觸表面 107‧‧‧Contact surface

12‧‧‧黏結層 12‧‧‧Bonded layer

122‧‧‧導電區 122‧‧‧Conducting area

124‧‧‧電絕緣區 124‧‧‧Electrical insulation zone

126‧‧‧導電區之上表面 126‧‧‧Top surface of conductive area

13‧‧‧電流阻擋層 13‧‧‧current barrier

132‧‧‧電流阻擋層之上表面 132‧‧‧The upper surface of the current blocking layer

14‧‧‧第一電流擴散層 14‧‧‧First current diffusion layer

15‧‧‧第二電流擴散層 15‧‧‧Second current diffusion layer

152‧‧‧第二電流擴散層之下表面 152‧‧‧Under the surface of the second current diffusion layer

16‧‧‧第一半導體疊層 16‧‧‧First semiconductor stack

162‧‧‧第一半導體層 162‧‧‧First semiconductor layer

164‧‧‧發光層 164‧‧‧Lighting layer

166‧‧‧第二半導體層 166‧‧‧second semiconductor layer

17‧‧‧第一電極 17‧‧‧First electrode

172‧‧‧第一電極之下表面 172‧‧‧The lower surface of the first electrode

Claims (10)

一種光電元件,包含:一絕緣基板,具有一表面;一導電基板,包含一部分位於該絕緣基板之中並與該表面共平面;一半導體疊層;以及一黏結層,位於該絕緣基板及該半導體層之間。 A photovoltaic element comprising: an insulating substrate having a surface; a conductive substrate comprising a portion disposed in the same and coplanar with the surface; a semiconductor stack; and a bonding layer on the insulating substrate and the semiconductor Between the layers. 如請求項1所述之光電元件,其中該絕緣基板包含一空腔,暴露出該導電基板。 The photovoltaic device of claim 1, wherein the insulating substrate comprises a cavity exposing the conductive substrate. 如請求項1所述之光電元件,更包含一中介層,位於該絕緣基板及該導電基板之間。 The photovoltaic device according to claim 1, further comprising an interposer between the insulating substrate and the conductive substrate. 如請求項3所述之光電元件,其中該中介層更包含一第一反射層位於該絕緣基板之下。 The photovoltaic device of claim 3, wherein the interposer further comprises a first reflective layer under the insulating substrate. 如請求項4所述之光電元件,更包含一第二反射層形成於該第一反射層之上,並且該第二反射層位於該半導體疊層及該絕緣基板之間。 The photovoltaic element according to claim 4, further comprising a second reflective layer formed on the first reflective layer, and the second reflective layer being located between the semiconductor laminate and the insulating substrate. 如請求項1所述之光電元件,更包含一吸附層,位於該絕緣基板與該導電基板之間。 The photovoltaic device according to claim 1, further comprising an adsorption layer between the insulating substrate and the conductive substrate. 如請求項1所述之光電元件,更包含一窗戶層位於該黏結層與該半導體疊層之間,且該窗戶層包含一粗糙之下表面。 The photovoltaic element of claim 1 further comprising a window layer between the bonding layer and the semiconductor laminate, and the window layer comprises a rough lower surface. 如請求項1所述之光電元件,其中該黏結層包含一導電區以及一電絕緣區。 The photovoltaic device of claim 1, wherein the bonding layer comprises a conductive region and an electrically insulating region. 如請求項8所述之光電元件,其中該導電區係對應該導電基板位於該絕緣基板中之該部分之位置。 The photovoltaic element of claim 8, wherein the conductive region corresponds to a location of the portion of the conductive substrate in the insulating substrate. 如請求項8所述之光電元件,其中該電絕緣區係對應該絕緣基 板之位置。 The photovoltaic element according to claim 8, wherein the electrically insulating region corresponds to an insulating substrate The location of the board.
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