TWI505484B - Solar cell and module comprising the same - Google Patents

Solar cell and module comprising the same Download PDF

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TWI505484B
TWI505484B TW102119342A TW102119342A TWI505484B TW I505484 B TWI505484 B TW I505484B TW 102119342 A TW102119342 A TW 102119342A TW 102119342 A TW102119342 A TW 102119342A TW I505484 B TWI505484 B TW I505484B
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solar cell
electrode
openings
conductive
plate
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TW102119342A
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TW201445751A (en
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Chun Wen Lai
hao wei Liu
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Motech Ind Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Description

太陽能電池及其模組Solar cell and its module

本發明是有關於一種太陽能電池及其模組,特別是指一種矽晶太陽能電池及其模組。The invention relates to a solar cell and a module thereof, in particular to a twin solar cell and a module thereof.

參閱圖1、2(為便於說明,將圖2太陽能電池的背面朝上繪製),傳統的矽晶太陽能電池主要包含:一具有相反的一受光的正面811與一背光的背面812的基板81、一位於該正面811的正面電極82、數個位於該背面812的匯流電極83,以及一位於該背面812且連接該數個匯流電極83的背面電極84。一般而言,傳統電池中鋁材質的背面電極84用於焊接的效果不佳,通常會使用銀鋁混合之材質的匯流電極83來與焊帶導線(ribbon)作焊接。Referring to Figures 1 and 2 (for the sake of convenience, the back side of the solar cell of Figure 2 is drawn upwards), the conventional twinned solar cell mainly comprises: a substrate 81 having an opposite light-receiving front surface 811 and a back surface 812 of a backlight, A front surface electrode 82 on the front surface 811, a plurality of bus electrodes 83 on the back surface 812, and a back surface electrode 84 on the back surface 812 and connecting the plurality of bus electrodes 83. In general, the aluminum back electrode 84 of the conventional battery is not effective for soldering, and the bus electrode 83 of a silver-aluminum mixed material is usually used for soldering to the ribbon.

參閱圖3、4(為便於說明,將圖4太陽能電池的背面朝上繪製),為了提升電池效能,目前有一種改良結構的太陽能電池,包含:一具有一受光的正面911與一背光的背面912的基板91、一位於該正面911的正面電極92、數個位於該背面912的局部背表面電場(Local Back Surface Field,簡稱LBSF)98與數個鋁矽合金結構93、一位於該背面912上的鈍化層94、數個位於該鈍化層94上的 線狀開孔95、一背面電極96,以及數個連接該背面電極96的電極組97。Referring to Figures 3 and 4 (for convenience of illustration, the back side of the solar cell of Figure 4 is drawn upwards), in order to improve battery performance, there is currently a solar cell of improved structure comprising: a front surface 911 having a light receiving surface and a back surface of a backlight a substrate 91 of 912, a front electrode 92 on the front surface 911, a plurality of local back surface fields (LBSF) 98 on the back surface 912, and a plurality of aluminum-bismuth alloy structures 93, one on the back surface 912 a passivation layer 94 thereon, and a plurality of passivation layers 94 A linear opening 95, a back electrode 96, and a plurality of electrode groups 97 connecting the back electrode 96.

其中,該背面電極96包括數個可分別經由該數個線狀開孔95而接觸該數個鋁矽合金結構93的第一導電部961,以及一覆蓋在該鈍化層94表面並連接該數個第一導電部961的第二導電部962。該數個電極組97為間隔排列,每一電極組97包括數個彼此間隔的電極部971。The back electrode 96 includes a plurality of first conductive portions 961 that can contact the plurality of aluminum-bismuth alloy structures 93 via the plurality of linear openings 95, and a surface of the passivation layer 94 is attached and connected The second conductive portion 962 of the first conductive portion 961. The plurality of electrode groups 97 are arranged at intervals, and each electrode group 97 includes a plurality of electrode portions 971 spaced apart from each other.

藉由該鈍化層94修補、降低該基板91的表面缺陷,進而降低載子在該基板91的背面912處的複合速率,以提升電池的轉換效率。而該數個局部背表面電場98與鋁矽合金結構93分別對應該數個線狀開孔95地位於該背面912處,局部背表面電場98的摻雜濃度大於該基板91的摻雜濃度,可幫助提升載子收集效率及光電轉換效率。The surface of the substrate 91 is repaired and reduced by the passivation layer 94, thereby reducing the recombination rate of the carrier at the back surface 912 of the substrate 91 to improve the conversion efficiency of the battery. The plurality of partial back surface electric fields 98 and the aluminum-bismuth alloy structure 93 respectively correspond to the plurality of linear openings 95 at the back surface 912, and the doping concentration of the partial back surface electric field 98 is greater than the doping concentration of the substrate 91. It can help improve carrier collection efficiency and photoelectric conversion efficiency.

因此圖3、4的電池相較於圖1、2的傳統電池具有更高的轉換效率。而圖3、4的電池之通過各個鋁矽合金結構93處的載子可經由該背面電極96與該數個電極部971傳導至外部,其中,因為大部分的線狀開孔95與該數個電極部971的位置有局部重疊對應,因此對應於這些部位的鋁矽合金結構93處的載子要傳導到電極部971的路徑較短(如圖4的箭頭A),傳導能力佳。但實際上該電池結構仍有缺失,因為該數個電極部971與該數個線狀開孔95的配置關係未經過特殊設計,往往會有一些線狀開孔95未與電極部971的位置重疊,例如圖3所示的第一個線狀開孔95與最一個線狀開孔95皆未與電極部971的位置對應,造 成對應於該第一個線狀開孔95與該最後一個線狀開孔95的該兩個合金結構93未與電極部971接觸,使得載子經鋁矽合金結構93傳導後,仍必須經過外部的第一導電部961和第二導電部962才能傳遞到電極部971,如此載子的傳導路徑將會增加(如圖4的箭頭B),影響電池之電性效果;以及,又因背面電極96的材質是鋁與一些混合物組合而成,其電阻較該鋁矽合金結構93高出許多,故而若電的傳導需經過背面電極96上的第一導電部961和第二導電部962時,容易造成電流損耗,導致電流收集效率不佳以及光電轉換效率降低。Therefore, the batteries of Figures 3 and 4 have higher conversion efficiencies than the conventional batteries of Figures 1 and 2. The carriers of the batteries of FIGS. 3 and 4 passing through the respective aluminum-bismuth alloy structures 93 can be conducted to the outside through the back electrode 96 and the plurality of electrode portions 971, wherein most of the linear openings 95 and the number are Since the positions of the electrode portions 971 are partially overlapped, the path of the carriers at the aluminum-bismuth alloy structure 93 corresponding to these portions to be conducted to the electrode portion 971 is short (as indicated by an arrow A in Fig. 4), and the conductivity is good. However, in fact, the battery structure is still missing, because the arrangement relationship between the plurality of electrode portions 971 and the plurality of linear openings 95 is not specially designed, and there are often some positions of the linear openings 95 and the electrode portion 971. The overlapping, for example, the first linear opening 95 and the most linear opening 95 shown in FIG. 3 do not correspond to the position of the electrode portion 971. The two alloy structures 93 corresponding to the first linear opening 95 and the last linear opening 95 are not in contact with the electrode portion 971, so that the carrier must pass through the aluminum-bismuth alloy structure 93. The outer first conductive portion 961 and the second conductive portion 962 can be transmitted to the electrode portion 971, so that the conduction path of the carrier will increase (as shown by the arrow B in FIG. 4), affecting the electrical effect of the battery; The material of the electrode 96 is a combination of aluminum and some mixtures, and its electrical resistance is much higher than that of the aluminum-bismuth alloy structure 93. Therefore, if the electrical conduction needs to pass through the first conductive portion 961 and the second conductive portion 962 on the back surface electrode 96, It is easy to cause current loss, resulting in poor current collection efficiency and reduced photoelectric conversion efficiency.

因此,本發明之目的,即在提供一種能提升載子傳導能力,並可增加電流收集效率及光電轉換效率的太陽能電池及其模組。Accordingly, it is an object of the present invention to provide a solar cell and a module thereof which can enhance carrier conduction capability and increase current collection efficiency and photoelectric conversion efficiency.

於是,本發明太陽能電池,包含:一基板、一射極層、一正面電極、一鈍化層、數個第一線狀開孔、數個第一導電部、數個合金結構,及數個電極部。Therefore, the solar cell of the present invention comprises: a substrate, an emitter layer, a front electrode, a passivation layer, a plurality of first linear openings, a plurality of first conductive portions, a plurality of alloy structures, and a plurality of electrodes unit.

該基板包括一受光的正面及一相對於該正面的背面。該射極層配置於該正面處。該正面電極配置於該正面處並接觸該射極層。該鈍化層配置於該背面處。該數個第一線狀開孔位於該鈍化層上,該數個第一線狀開孔沿一第一方向延伸並且沿一第二方向間隔排列。該數個第一導電部分別位於該數個第一線狀開孔並沿該第一方向延伸。該數個合金結構形成於該背面並分別對應該數個第一線狀 開孔而沿該第一方向延伸,其中各該合金結構位於各該第一導電部與該基板之間,並接觸各該第一導電部。該數個電極部配置於該鈍化層上並沿該第二方向間隔排列,其中每一個合金結構與該數個電極部中的至少一個電極部接觸。The substrate includes a light-receiving front side and a back side opposite the front side. The emitter layer is disposed at the front side. The front electrode is disposed at the front surface and contacts the emitter layer. The passivation layer is disposed at the back surface. The plurality of first linear openings are located on the passivation layer, and the plurality of first linear openings extend in a first direction and are spaced apart in a second direction. The plurality of first conductive portions are respectively located in the plurality of first linear openings and extend in the first direction. The plurality of alloy structures are formed on the back surface and respectively correspond to a plurality of first lines Opening and extending along the first direction, wherein each of the alloy structures is located between each of the first conductive portions and the substrate, and contacts each of the first conductive portions. The plurality of electrode portions are disposed on the passivation layer and spaced apart along the second direction, wherein each of the alloy structures is in contact with at least one of the plurality of electrode portions.

本發明還提供另一種太陽能電池,主要是改變電極部的結構。該另一種太陽能電池包含一配置於該鈍化層上並沿該第二方向延伸的電極部,該電極部的兩端分別靠近該基板的兩個相對的側邊,且該電極部與該數個合金結構中的每一個合金結構接觸。The present invention also provides another solar cell, which mainly changes the structure of the electrode portion. The other solar cell includes an electrode portion disposed on the passivation layer and extending along the second direction, the two ends of the electrode portion are respectively adjacent to two opposite sides of the substrate, and the electrode portion and the plurality of electrodes Each alloy structure in the alloy structure is in contact.

本發明太陽能電池模組,包含:相對設置的一第一板材與一第二板材、至少一個如上述的任一種且排列於該第一板材與該第二板材之間的太陽能電池,及一位於該第一板材與該第二板材之間並接觸該太陽能電池的封裝材。The solar cell module of the present invention comprises: a first plate and a second plate disposed oppositely, at least one solar cell arranged in any one of the above and arranged between the first plate and the second plate, and a The first plate and the second plate are in contact with the packaging material of the solar cell.

本發明之功效:藉由使每一個合金結構皆與電極部接觸,可形成完善的導電網路,以縮短載子傳導的路徑長度,進而能降低電流損耗,提升電流收集效率與光電轉換效率。The effect of the invention: by making each alloy structure contact with the electrode portion, a perfect conductive network can be formed to shorten the path length of the carrier conduction, thereby reducing current loss, improving current collection efficiency and photoelectric conversion efficiency.

1‧‧‧第一板材1‧‧‧ first plate

36‧‧‧第一導電部36‧‧‧First Conductive Department

2‧‧‧第二板材2‧‧‧Second plate

37‧‧‧連接導電部37‧‧‧Connecting the conductive part

3‧‧‧太陽能電池3‧‧‧Solar battery

380‧‧‧電極組380‧‧‧electrode group

30‧‧‧局部背表面電場30‧‧‧Local back surface electric field

38‧‧‧電極部38‧‧‧Electrode

31‧‧‧基板31‧‧‧Substrate

39‧‧‧第二導電部39‧‧‧Second Conductive Department

311‧‧‧正面311‧‧‧ positive

4‧‧‧封裝材4‧‧‧Package

312‧‧‧背面312‧‧‧ back

51‧‧‧第一方向51‧‧‧First direction

313‧‧‧射極層313‧‧ ‧ emitter layer

52‧‧‧第二方向52‧‧‧second direction

314‧‧‧側邊314‧‧‧ side

61‧‧‧銜接開孔61‧‧‧Connecting the opening

32‧‧‧正面電極32‧‧‧ front electrode

62‧‧‧第三導電部62‧‧‧ Third Conductive Department

33‧‧‧鈍化層33‧‧‧ Passivation layer

71‧‧‧第二線狀開孔71‧‧‧Second linear opening

34‧‧‧合金結構34‧‧‧ alloy structure

72‧‧‧第四導電部72‧‧‧4th Conductive Department

35‧‧‧第一線狀開孔35‧‧‧First linear opening

8‧‧‧焊帶導線8‧‧‧welding tape

本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:圖1是一種已知太陽能電池的背面示意圖;圖2是沿圖1之A-A線所取的剖視圖; 圖3是另一種已知太陽能電池的背面示意圖;圖4是圖3的太陽能電池的局部立體剖視圖;圖5是本發明太陽能電池模組之一第一較佳實施例的局部剖視示意圖;圖6是該第一較佳實施例的一太陽能電池的背面示意圖;圖7是沿圖6之B-B線所取的剖視圖;圖8是沿圖6之C-C線所取的剖視圖;圖9是該第一較佳實施例的該太陽能電池之背面朝上的局部立體剖視圖,圖中的箭頭示意載子傳導方向;圖10是本發明太陽能電池模組之一第二較佳實施例的一太陽能電池的背面示意圖;圖11是本發明太陽能電池模組之一第三較佳實施例的一太陽能電池的背面示意圖;圖12是本發明太陽能電池模組之一第四較佳實施例的一太陽能電池的背面示意圖;及圖13是本發明太陽能電池模組之一第五較佳實施例的一太陽能電池的背面示意圖。Other features and effects of the present invention will be apparent from the following description of the drawings. FIG. 1 is a schematic view of a rear view of a known solar cell; FIG. 2 is a cross-sectional view taken along line A-A of FIG. 3 is a schematic side view of another known solar cell; FIG. 4 is a partial perspective cross-sectional view of the solar cell of FIG. 3; FIG. 5 is a partial cross-sectional view showing a first preferred embodiment of the solar cell module of the present invention; 6 is a rear view of a solar cell of the first preferred embodiment; FIG. 7 is a cross-sectional view taken along line BB of FIG. 6; FIG. 8 is a cross-sectional view taken along line CC of FIG. A top perspective view of a back side of the solar cell of a preferred embodiment, the arrows in the figure indicate the direction of carrier conduction; and FIG. 10 is a solar cell of a second preferred embodiment of the solar cell module of the present invention. FIG. 11 is a schematic rear view of a solar cell according to a third preferred embodiment of the solar cell module of the present invention; FIG. 12 is a solar cell of a fourth preferred embodiment of the solar cell module of the present invention. FIG. 13 is a schematic rear view of a solar cell according to a fifth preferred embodiment of the solar cell module of the present invention.

在本發明被詳細描述之前,應當注意在以下的說明內容中,類似的元件是以相同的編號來表示。Before the present invention is described in detail, it should be noted that in the following description, similar elements are denoted by the same reference numerals.

參閱圖5、6,本發明太陽能電池模組之第一較佳實施例包含:相對設置的一第一板材1與一第二板材2、數個陣列式排列於該第一板材1與該第二板材2間的太 陽能電池3,及至少一位於該第一板材1及該第二板材2間,並接觸該數個太陽能電池3的封裝材4。其中,該模組可以包含至少一太陽能電池3即可,不以數個太陽能電池3為絕對之必要。Referring to FIGS. 5 and 6, a first preferred embodiment of the solar cell module of the present invention comprises: a first plate 1 and a second plate 2 disposed opposite to each other, and a plurality of arrays arranged on the first plate 1 and the first Two plates 2 The solar cell 3, and at least one encapsulant 4 located between the first plate 1 and the second plate 2 and contacting the plurality of solar cells 3. The module may include at least one solar cell 3, and it is absolutely unnecessary to use a plurality of solar cells 3.

該第一板材1與該第二板材2在實施上沒有特殊限制,可以使用玻璃或塑膠板材,而且位於電池受光面的一側的板材必須為可透光。若為雙面受光之太陽能電池時,則該第一板材1與該第二板材2皆必須可透光。該封裝材4的材質例如可透光的乙烯醋酸乙烯共聚物(EVA),或其他可用於太陽能電池模組封裝的相關材料。The first plate 1 and the second plate 2 are not particularly limited in implementation, and a glass or plastic plate may be used, and the plate on one side of the light receiving surface of the battery must be permeable to light. In the case of a double-sided light-receiving solar cell, both the first plate 1 and the second plate 2 must be transparent. The material of the encapsulant 4 is, for example, a light transmissive ethylene vinyl acetate copolymer (EVA), or other related materials that can be used for solar cell module packaging.

該數個太陽能電池3透過焊帶導線(ribbon)8電連接。該數個太陽能電池3的結構都相同,以下僅以其中一個為例進行說明。但在一模組中的數個電池的結構不以相同為絕對之必要。The plurality of solar cells 3 are electrically connected through a ribbon strip 8. The structures of the plurality of solar cells 3 are the same, and only one of them will be described below as an example. However, the structure of several batteries in a module is not absolutely necessary.

參閱圖6、7、8、9,該太陽能電池3包含:一基板31、一正面電極32、一鈍化層33、數個鋁矽之合金結構34、數個第一線狀開孔35、數個第一導電部36、一個連接導電部37,及數個電極組380。Referring to FIGS. 6, 7, 8, and 9, the solar cell 3 includes a substrate 31, a front electrode 32, a passivation layer 33, a plurality of aluminum alloy structures 34, a plurality of first linear openings 35, and a plurality of The first conductive portion 36, one connecting conductive portion 37, and a plurality of electrode groups 380.

該基板31包括一受光的正面311,及一相對於該正面311的背面312,該基板31例如但不限於矽基板,且該正面311處配置一射極層313,該射極層313與該基板31的導電性相反,其中一個為p型半導體,另一個為n型半導體。此外,該基板31的正面311還可配置一圖未示出的抗反射層,可提升電池的入光量。The substrate 31 includes a light-receiving front surface 311 and a back surface 312 opposite to the front surface 311. The substrate 31 is, for example but not limited to, a germanium substrate, and the front surface 311 is provided with an emitter layer 313. The conductivity of the substrate 31 is reversed, one of which is a p-type semiconductor and the other is an n-type semiconductor. In addition, the front surface 311 of the substrate 31 can also be provided with an anti-reflection layer not shown, which can increase the amount of light entering the battery.

該正面電極32配置於該正面311處並接觸該射極層313,該正面電極32與該數個第一導電部36、該連接導電部37及該數個電極組380配合輸出該電池的電能。The front surface electrode 32 is disposed on the front surface 311 and contacts the emitter layer 313. The front surface electrode 32 cooperates with the plurality of first conductive portions 36, the connecting conductive portion 37 and the plurality of electrode groups 380 to output electrical energy of the battery. .

該鈍化層33配置於該基板31的背面312處,用於鈍化與修補該背面312,從而降低載子表面複合速率(Surface Recombination Velocity,簡稱SRV)。該鈍化層33的材質例如氧化物、氮化物、氧化物與氮化物之組合,或其他可用於鈍化、修補該基板31表面的介電材料。The passivation layer 33 is disposed on the back surface 312 of the substrate 31 for passivating and repairing the back surface 312, thereby reducing the Surface Recombination Velocity (SRV). The material of the passivation layer 33 is, for example, an oxide, a nitride, a combination of an oxide and a nitride, or other dielectric material that can be used to passivate and repair the surface of the substrate 31.

該數個合金結構34位於該基板31的背面312處,且分別對應該數個第一線狀開孔35的位置,並且皆沿一第一方向51延伸。且每一該合金結構34與該基板31內部間具有一與該基板31的導電性相同的局部背表面電場(LBSF)30,局部背表面電場30的摻雜濃度大於該基板31的摻雜濃度,藉由局部背表面電場30的電場作用阻擋電子朝該背面312的方向移動,使電子被收集於該射極層313,以提升載子收集效率及轉換效率。又,該合金結構34於實施上是指鋁矽合金結構,其中矽含量約佔12.6%,而局部背表面電場30中的鋁含量約為1%和99%的矽,此僅是舉例但不以此為限。The plurality of alloy structures 34 are located at the back surface 312 of the substrate 31 and respectively correspond to the positions of the plurality of first linear openings 35 and extend along a first direction 51. And each of the alloy structure 34 and the interior of the substrate 31 has a partial back surface electric field (LBSF) 30 having the same conductivity as the substrate 31, and the doping concentration of the partial back surface electric field 30 is greater than the doping concentration of the substrate 31. The electric field of the partial back surface electric field 30 blocks the movement of electrons toward the back surface 312, so that electrons are collected in the emitter layer 313 to improve carrier collection efficiency and conversion efficiency. Moreover, the alloy structure 34 is referred to as an aluminum-bismuth alloy structure in which the germanium content is about 12.6%, and the aluminum content in the partial back surface electric field 30 is about 1% and 99%, which is only an example but not This is limited to this.

該數個第一線狀開孔35相間隔地位於該鈍化層33上,該數個第一線狀開孔35沿該第一方向51延伸並且沿一垂直該第一方向51的第二方向52間隔排列。在實施時,也可以於任兩第一線狀開孔35之間設置其他開孔以將第一線狀開孔35相連。The plurality of first linear openings 35 are spaced apart from each other on the passivation layer 33. The plurality of first linear openings 35 extend along the first direction 51 and along a second direction perpendicular to the first direction 51. 52 intervals. In practice, other openings may be provided between any two of the first linear openings 35 to connect the first linear openings 35.

該數個第一導電部36分別位於該數個第一線狀開孔35並沿該第一方向51延伸,且接觸該基板31的該背面312的該數個合金結構34。每一第一導電部36局部填入與其相對應的該第一線狀開孔35中,且局部露出於第一線狀開孔35外。該連接導電部37位於該鈍化層33的表面上並連接該數個第一導電部36以及該數個電極部38。該數個第一導電部36與該連接導電部37的材料例如但不限於鋁,於實施上,為相同材質的包含鋁的混合物。The plurality of first conductive portions 36 are respectively located in the first linear opening 35 and extend along the first direction 51 and contact the plurality of alloy structures 34 of the back surface 312 of the substrate 31 . Each of the first conductive portions 36 is partially filled in the first linear opening 35 corresponding thereto and partially exposed outside the first linear opening 35. The connection conductive portion 37 is located on the surface of the passivation layer 33 and connects the plurality of first conductive portions 36 and the plurality of electrode portions 38. The material of the plurality of first conductive portions 36 and the connecting conductive portion 37 is, for example but not limited to, aluminum, and is a mixture of aluminum of the same material.

該數個電極組380配置於該鈍化層33上,且該數個電極組380彼此間沿該第一方向51間隔排列。每一電極組380包括數個沿該第二方向52間隔排列的電極部38,電極部38的材料例如但不限於銀,於實施上,為包含銀的混合物。每一電極組380中的該數個電極部38中的至少一電極部38,接觸該數個合金結構34中的至少一個合金結構34,較佳地為每一電極部38接觸至少一個合金結構34。而且每一個合金結構34與該數個電極部38中的至少一個電極部38接觸。具體而言,本實施例的每一電極組380中的該數個電極部38與該數個合金結構34為一對一的接觸關係,各該合金結構34位於每一電極組380的各該第一導電部38與該基板31之間。The plurality of electrode groups 380 are disposed on the passivation layer 33, and the plurality of electrode groups 380 are spaced apart from each other along the first direction 51. Each electrode set 380 includes a plurality of electrode portions 38 spaced apart along the second direction 52. The material of the electrode portion 38 is, for example, but not limited to, silver, and in practice, is a mixture comprising silver. At least one of the plurality of electrode portions 38 in each electrode group 380 contacts at least one of the plurality of alloy structures 34, preferably each electrode portion 38 contacts at least one alloy structure 34. Further, each of the alloy structures 34 is in contact with at least one of the plurality of electrode portions 38. Specifically, the plurality of electrode portions 38 in each electrode group 380 of the embodiment are in a one-to-one contact relationship with the plurality of alloy structures 34, and each of the alloy structures 34 is located in each of the electrode groups 380. The first conductive portion 38 is between the substrate 31 and the substrate 31.

需要說明的是,本發明之電極組380的數量也可以為一個。此外,本實施例的每一該電極部38與該基板31的該背面312之間設有一第二導電部39,該第二導電部39位於該數個第一線狀開孔35中的一個內,其中電流自 合金結構34傳至第二導電部39後,再直接傳導到該數個電極部38。第二導電部39的材料可以為銀或/及鋁的混合物,可以利用一次網印作業同時形成第二導電部39與電極部38(此時第二導電部39與電極部38之間無分界),此時該電極部38與第二導電部39的材質例如為銀與鋁的混合物(其中銀的比例遠高於鋁,故俗稱背銀漿),之後再對位網印該數個第一導電部36與該連接導電部37,此時該第一導電部36與連接導電部37的材質例如為鋁的混合物。故而,若前述之第二導電部39使用鋁時,可以利用一次網印作業先同時形成第二導電部39、第一導電部36與連接導電部37,之後再網印形成該數個電極部38;當然,此時所網印的第二導電部39可透過網版乳劑層厚度之調控等方式使其厚度較第一導電部36與連接導電部37薄上許多,從而使之後網印的電極部38的高度與第一導電部36及連接導電部37的高度不致產生過大之落差。此外,於實施上,通常採用先網印第二導電部39與電極部38即俗稱之背銀,後網印第一導電部36與連接導電部37之順序來製作背面電極即俗稱之背鋁,其中,背銀的周圍通常會被背鋁所覆蓋而有重疊之現象,亦即兩者會有所接觸。It should be noted that the number of the electrode groups 380 of the present invention may also be one. In addition, a second conductive portion 39 is disposed between each of the electrode portions 38 of the embodiment and the back surface 312 of the substrate 31. The second conductive portion 39 is located in one of the plurality of first linear openings 35. Inside, where current is self After the alloy structure 34 is transferred to the second conductive portion 39, it is directly conducted to the plurality of electrode portions 38. The material of the second conductive portion 39 may be a mixture of silver or/and aluminum, and the second conductive portion 39 and the electrode portion 38 may be simultaneously formed by one screen printing operation (in this case, there is no boundary between the second conductive portion 39 and the electrode portion 38). At this time, the material of the electrode portion 38 and the second conductive portion 39 is, for example, a mixture of silver and aluminum (wherein the ratio of silver is much higher than that of aluminum, so commonly referred to as back silver paste), and then the number of screens is printed on the alignment screen. A conductive portion 36 and the connecting conductive portion 37, wherein the material of the first conductive portion 36 and the connecting conductive portion 37 is, for example, a mixture of aluminum. Therefore, when the second conductive portion 39 is made of aluminum, the second conductive portion 39, the first conductive portion 36, and the connecting conductive portion 37 can be simultaneously formed by a single screen printing operation, and then the plurality of electrode portions are formed by screen printing. 38; Of course, the second conductive portion 39 printed on the screen can be thinner than the first conductive portion 36 and the connecting conductive portion 37 by adjusting the thickness of the screen emulsion layer, thereby making the screen printed later. The height of the electrode portion 38 does not cause an excessive difference between the heights of the first conductive portion 36 and the connection conductive portion 37. In addition, in practice, the second conductive portion 39 and the electrode portion 38, which are commonly referred to as back silver, and the first printed portion 36 and the connecting conductive portion 37 are sequentially screen printed to form a back electrode, which is commonly referred to as a back aluminum. Among them, the surrounding silver is usually covered by the back aluminum and overlaps, that is, the two will have contact.

另外,本發明不以設置第二導電部39為必要,當未設置第二導電部39時,該鈍化層33之對應該數個電極部38的部位可以不需要形成孔洞,此時該數個電極部38位於該鈍化層33的表面上,此時,電流的傳導即可於合金結構34傳遞至上述之背鋁與背銀之重疊處,並進一步 直接傳遞到上述的電極部38。In addition, in the present invention, it is not necessary to provide the second conductive portion 39. When the second conductive portion 39 is not provided, the portion of the passivation layer 33 corresponding to the plurality of electrode portions 38 may not need to form a hole. The electrode portion 38 is located on the surface of the passivation layer 33. At this time, the conduction of current can be transmitted to the overlap of the back aluminum and the back silver in the alloy structure 34, and further Directly transferred to the electrode portion 38 described above.

綜上所述,由於本發明的該數個合金結構34皆與電極部38具有上下對應之關係,於實施上其為具有兩者直接接觸之設計,或是如上述未設置第二導電部39時,仍可具有電流傳遞效果之間接傳遞之導電效果。另言之,在本發明的合金結構34與電極部38的特殊配置關係之下,可形成完善的導電網路、縮短載子傳導的路徑長度,使該數個合金結構34的位置皆可與至少一個電極部38的位置對應到。如此一來,該基板31內所產生之載子於傳導時,就能經由合金結構34以較短的路徑傳導至與該合金結構34接觸的該電極部38,而不需要經由外部的第一導電部36與連接導電部37才能傳導給電極部38,進而能降低電流損耗(請參照本發明之先前技術之說明,因為第一導電部36與連接導電部37為鋁混合物之電極,其電阻較(鋁矽)合金結構34為高,有礙電流傳導),從而提升電池的電流收集效率與光電轉換效率。In summary, since the plurality of alloy structures 34 of the present invention have an upper and lower corresponding relationship with the electrode portion 38, it is designed to have direct contact with each other, or the second conductive portion 39 is not provided as described above. At the same time, the conduction effect of the current transfer effect can still be transmitted. In addition, under the special arrangement relationship between the alloy structure 34 and the electrode portion 38 of the present invention, a perfect conductive network can be formed, and the path length of the carrier conduction can be shortened, so that the positions of the plurality of alloy structures 34 can be The position of at least one electrode portion 38 corresponds to. In this way, the carrier generated in the substrate 31 can be conducted to the electrode portion 38 in contact with the alloy structure 34 via the alloy structure 34 during conduction without the need for the first through the external portion. The conductive portion 36 and the connecting conductive portion 37 can be conducted to the electrode portion 38, thereby reducing current loss (refer to the description of the prior art of the present invention, because the first conductive portion 36 and the connecting conductive portion 37 are electrodes of an aluminum mixture, and the resistance thereof Compared with the (aluminum bismuth) alloy structure 34, it is high, which hinders current conduction), thereby improving the current collecting efficiency and photoelectric conversion efficiency of the battery.

又或者該數個合金結構34分別與該數個第二導電部39直接接觸時,該數個合金結構34處的載子則可分別透過該數個第二導電部39傳導至該數個電極部38,並且當第二導電部39與電極部38皆使用銀漿網印形成時,每一組相對應的該第二導電部39與該電極部38可視為一整體,此時該數個合金結構34則相當於直接接觸該數個導電部38,可達到更直接、更好的載子傳導效果。When the plurality of alloy structures 34 are in direct contact with the plurality of second conductive portions 39, the carriers at the plurality of alloy structures 34 are respectively transmitted to the plurality of electrodes through the plurality of second conductive portions 39. When the second conductive portion 39 and the electrode portion 38 are formed by using a silver paste screen, each of the corresponding second conductive portions 39 and the electrode portion 38 can be regarded as a whole. The alloy structure 34 is equivalent to directly contacting the plurality of conductive portions 38 to achieve a more direct and better carrier conduction effect.

參閱圖10,本發明太陽能電池模組的第二較佳 實施例,與該第一較佳實施例不同的地方在於:本實施例的太陽能電池3的每一電極部38接觸兩個合金結構34,而且在實施上每一電極部38也可以接觸三個、四個或更多個合金結構34。Referring to FIG. 10, a second preferred embodiment of the solar cell module of the present invention The embodiment is different from the first preferred embodiment in that each electrode portion 38 of the solar cell 3 of the present embodiment contacts two alloy structures 34, and in practice, each electrode portion 38 can also contact three. Four or more alloy structures 34.

參閱圖11,本發明太陽能電池模組的第三較佳實施例,與該第一較佳實施例不同的地方在於:本實施例的太陽能電池3還包含數個位於該鈍化層上並且皆沿該第二方向52延伸的銜接開孔61,該數個銜接開孔61分別連接在該數個第一線狀開孔35中的任兩相鄰的第一線狀開孔35的同側至少一端之間,且該數個銜接開孔61彼此間不連接。每一該銜接開孔61上有一個與位於該任兩相鄰的第一線狀開孔35的該兩第一導電部36分別連接的第三導電部62,其中對應於第一導電部36與第三導電部62之基板背面處會形成鋁矽之合金結構34,亦即藉由第三導電部62連接該數個第一導電部36之設計於燒結後,可形成連續的鋁矽之合金結構34的導電網路,從而提升電流收集效率。於實施上,該數個銜接開孔61與對應的該數個第三導電部62通常位於靠近該基板31的相對兩側邊處。Referring to FIG. 11, a third preferred embodiment of the solar cell module of the present invention is different from the first preferred embodiment in that the solar cell 3 of the present embodiment further includes a plurality of cells located on the passivation layer. The second direction 52 extends into the opening 61, and the plurality of engaging openings 61 are respectively connected to the same side of any two adjacent first linear openings 35 of the plurality of first linear openings 35. Between one end, and the plurality of engaging openings 61 are not connected to each other. Each of the connecting openings 61 has a third conductive portion 62 connected to the two first conductive portions 36 of the two adjacent first linear openings 35, wherein the first conductive portion 36 corresponds to the first conductive portion 36. An aluminum alloy structure 34 is formed on the back surface of the substrate of the third conductive portion 62, that is, the plurality of first conductive portions 36 are connected by the third conductive portion 62 to form a continuous aluminum crucible. The conductive network of alloy structure 34 enhances current collection efficiency. In practice, the plurality of connection openings 61 and the corresponding plurality of third conductive portions 62 are generally located at opposite side edges of the substrate 31.

具體而言,該數個銜接開孔61可分為兩組,其中一組的該數個銜接開孔61分別連接在第n個及第n+1個第一線狀開孔35的一端之間,且n=1、3、5…等奇數;另一組的該數個銜接開孔61分別連接在第m個及第m+1個第一線狀開孔35的一端之間,m=2、4、6…等偶數。Specifically, the plurality of connection openings 61 can be divided into two groups, wherein the plurality of connection openings 61 of the group are respectively connected to one ends of the nth and n+1th first linear openings 35. And an odd number such as n=1, 3, 5, etc.; the plurality of connection openings 61 of the other group are respectively connected between one ends of the mth and m+1th first linear openings 35, m =2, 4, 6... and even numbers.

參閱圖12,本發明太陽能電池模組的第四較佳 實施例,與該第一較佳實施例不同的地方在於:本實施例的太陽能電池3還包含兩個位於該鈍化層並且皆沿該第二方向52延伸的第二線狀開孔71,該兩個第二線狀開孔71沿該第一方向51間隔排列並連接在該數個第一線狀開孔35的相反兩端。每一該第二線狀開孔71上有一個與位於該數個第一線狀開孔35的該數個第一導電部36連接的第四導電部72,其中於第四導電部72對應之基板背面處同樣具有鋁矽之合金結構34,透過如此之設計可形成全面連續的導電網路,從而提升電流收集效率。Referring to FIG. 12, a fourth preferred embodiment of the solar cell module of the present invention The embodiment is different from the first preferred embodiment in that the solar cell 3 of the present embodiment further includes two second linear openings 71 located in the passivation layer and extending along the second direction 52. Two second linear openings 71 are spaced apart along the first direction 51 and connected to opposite ends of the plurality of first linear openings 35. Each of the second linear openings 71 has a fourth conductive portion 72 connected to the plurality of first conductive portions 36 of the plurality of first linear openings 35, wherein the fourth conductive portion 72 corresponds to The back surface of the substrate also has an aluminum alloy structure 34, which is designed to form a fully continuous conductive network, thereby improving current collection efficiency.

參閱圖13,本發明太陽能電池模組的第五較佳實施例,與該第一較佳實施例不同的地方在於電極部38的設計。本實施例包含數個電極部38,該數個電極部38皆沿該第二方向52延伸並沿該第一方向51間隔排列。本實施例的每一電極部38為一體式的連續延伸的長條狀,而且每一電極部38的兩端分別靠近該基板31之沿該第二方向52間隔排列的兩個相對的側邊314。每一電極部38接觸每一合金結構34。當然,本實施例也可以只設置一個長條的電極部38,只要該電極部38可接觸所有的合金結構34就能達到本發明的目的。此外,本實施例在改良電極部38結構的情況下,同樣可以搭配該第三較佳實施例(圖11)的銜接開孔61與第三導電部62及其所對應之合金結構34的設計,或搭配該第四較佳實施例(圖12)的第二線狀開孔71與第四導電部72及其所對應之合金結構34的設計。此外,本實施例的該電極部38與該基板31之間設有數個第二導 電部(圖13未示,請參酌圖9),每一第二導電部分別位於每一第一線狀開孔35中。Referring to Figure 13, a fifth preferred embodiment of the solar cell module of the present invention differs from the first preferred embodiment in the design of the electrode portion 38. The embodiment includes a plurality of electrode portions 38 extending in the second direction 52 and spaced apart along the first direction 51. Each of the electrode portions 38 of the present embodiment is an integrated continuous extending strip shape, and two ends of each electrode portion 38 are respectively adjacent to two opposite sides of the substrate 31 which are arranged along the second direction 52. 314. Each electrode portion 38 contacts each alloy structure 34. Of course, this embodiment can also provide only one elongated electrode portion 38 as long as the electrode portion 38 can contact all of the alloy structures 34 to achieve the object of the present invention. In addition, in the case of improving the structure of the electrode portion 38, the embodiment can also be matched with the design of the engaging opening 61 and the third conductive portion 62 of the third preferred embodiment (FIG. 11) and the corresponding alloy structure 34 thereof. Or with the design of the second linear opening 71 and the fourth conductive portion 72 of the fourth preferred embodiment (FIG. 12) and the corresponding alloy structure 34 thereof. In addition, a plurality of second guides are disposed between the electrode portion 38 of the embodiment and the substrate 31. The electric parts (not shown in FIG. 13 , please refer to FIG. 9 ), each of the second conductive portions are respectively located in each of the first linear openings 35 .

綜上所述,本發明的精神主要是藉由電極部38連接各個合金結構34,以縮短載子傳導路徑,從而可提升電流收集效率與光電轉換效率。實施時該數個電極部38與合金結構34的形狀、連接關係等設計都不須限制,只要能形成上述的結構配置關係即為本發明之保護範圍。當然,於實施上,採用第一至四較佳實施例的該數個間隔的電極部38之方式亦可有效節省材料之成本。In summary, the spirit of the present invention mainly connects the respective alloy structures 34 by the electrode portions 38 to shorten the carrier conduction path, thereby improving current collection efficiency and photoelectric conversion efficiency. In the implementation, the design of the shape and connection relationship of the plurality of electrode portions 38 and the alloy structure 34 is not limited, and the above-described structural arrangement relationship is the protection scope of the present invention. Of course, in practice, the use of the plurality of spaced electrode portions 38 of the first to fourth preferred embodiments can also effectively save the cost of materials.

惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made by the patent application scope and patent specification content of the present invention, All remain within the scope of the invention patent.

3‧‧‧太陽能電池3‧‧‧Solar battery

37‧‧‧連接導電部37‧‧‧Connecting the conductive part

31‧‧‧基板31‧‧‧Substrate

380‧‧‧電極組380‧‧‧electrode group

34‧‧‧合金結構34‧‧‧ alloy structure

38‧‧‧電極部38‧‧‧Electrode

35‧‧‧第一線狀開孔35‧‧‧First linear opening

51‧‧‧第一方向51‧‧‧First direction

36‧‧‧第一導電部36‧‧‧First Conductive Department

52‧‧‧第二方向52‧‧‧second direction

Claims (11)

一種太陽能電池,包含:一基板,包括一受光的正面及一相對於該正面的背面;一射極層,配置於該正面處;一正面電極,配置於該正面處並接觸該射極層;一鈍化層,配置於該背面處;數個第一線狀開孔,位於該鈍化層上,該數個第一線狀開孔沿一第一方向延伸並且沿一第二方向間隔排列;數個第一導電部,分別位於該數個第一線狀開孔並沿該第一方向延伸;數個合金結構,形成於該背面並分別對應該數個第一線狀開孔而沿該第一方向延伸,其中各該合金結構位於各該第一導電部與該基板之間,並接觸各該第一導電部;及數個電極部,配置於該鈍化層上並沿該第二方向間隔排列,其中每一個合金結構與該數個電極部中的至少一個電極部接觸。A solar cell comprising: a substrate comprising a light-receiving front surface and a back surface opposite to the front surface; an emitter layer disposed at the front surface; a front electrode disposed at the front surface and contacting the emitter layer; a passivation layer disposed at the back surface; a plurality of first linear openings located on the passivation layer, the plurality of first linear openings extending along a first direction and spaced along a second direction; The first conductive portions are respectively located in the plurality of first linear openings and extend along the first direction; a plurality of alloy structures are formed on the back surface and respectively correspond to the plurality of first linear openings along the first a direction extending, wherein each of the alloy structures is located between each of the first conductive portions and the substrate, and contacts each of the first conductive portions; and a plurality of electrode portions disposed on the passivation layer and spaced along the second direction Arranged, wherein each of the alloy structures is in contact with at least one of the plurality of electrode portions. 如請求項1所述的太陽能電池,其中,每一電極部接觸該數個合金結構中的至少一個合金結構。The solar cell of claim 1, wherein each electrode portion contacts at least one of the plurality of alloy structures. 如請求項1所述的太陽能電池,其中,每一該電極部與該基板之間設有一第二導電部,該第二導電部位於該數個第一線狀開孔中的一個內。The solar cell of claim 1, wherein a second conductive portion is disposed between each of the electrode portions and the substrate, and the second conductive portion is located in one of the plurality of first linear openings. 如請求項1所述的太陽能電池,還包含數個位於該鈍化層上的銜接開孔,該數個銜接開孔分別連接在該數個第一線狀開孔中的任兩相鄰的第一線狀開孔的同側至少一端之間,每一該銜接開孔上有一個與位於該任兩相鄰的第一線狀開孔的該兩第一導電部分別連接的第三導電部。The solar cell of claim 1, further comprising a plurality of connection openings on the passivation layer, wherein the plurality of connection openings are respectively connected to any two adjacent ones of the plurality of first linear openings Between at least one end of the same side of the linear opening, each of the connecting openings has a third conductive portion respectively connected to the two first conductive portions of the two adjacent first linear openings . 如請求項1所述的太陽能電池,還包含一位於該鈍化層的表面上並連接該數個電極部以及該數個第一導電部的連接導電部。The solar cell of claim 1, further comprising a connecting conductive portion on the surface of the passivation layer and connecting the plurality of electrode portions and the plurality of first conductive portions. 一種太陽能電池模組,包含:相對設置的一第一板材與一第二板材;至少一個如請求項1至5中任一項所述的太陽能電池,排列於該第一板材與該第二板材之間;及一封裝材,位於該第一板材與該第二板材之間,並接觸該太陽能電池。A solar cell module comprising: a first plate and a second plate disposed oppositely; at least one solar cell according to any one of claims 1 to 5, arranged on the first plate and the second plate And a package material between the first plate and the second plate and contacting the solar cell. 一種太陽能電池,包含:一基板,包括一受光的正面及一相對於該正面的背面;一射極層,配置於該正面處;一正面電極,配置於該正面處並接觸該射極層;一鈍化層,配置於該背面處;數個第一線狀開孔,位於該鈍化層上,該數個第一線狀開孔沿一第一方向延伸並且沿一第二方向間隔排列; 數個第一導電部,分別位於該數個第一線狀開孔並沿該第一方向延伸;數個合金結構,形成於該背面並分別對應該數個第一線狀開孔而沿該第一方向延伸,其中各該合金結構位於各該第一導電部與該基板之間,並接觸各該第一導電部;及一電極部,配置於該鈍化層上並沿該第二方向延伸,其中該電極部的兩端分別靠近該基板的兩個相對的側邊,且該電極部與該數個合金結構中的每一個合金結構接觸。A solar cell comprising: a substrate comprising a light-receiving front surface and a back surface opposite to the front surface; an emitter layer disposed at the front surface; a front electrode disposed at the front surface and contacting the emitter layer; a passivation layer disposed at the back surface; a plurality of first linear openings located on the passivation layer, the plurality of first linear openings extending along a first direction and spaced apart along a second direction; a plurality of first conductive portions respectively located in the plurality of first linear openings and extending along the first direction; a plurality of alloy structures formed on the back surface and respectively corresponding to the plurality of first linear openings a first direction extending, wherein each of the alloy structures is located between each of the first conductive portions and the substrate, and contacts each of the first conductive portions; and an electrode portion disposed on the passivation layer and extending along the second direction The two ends of the electrode portion are respectively adjacent to two opposite sides of the substrate, and the electrode portion is in contact with each of the plurality of alloy structures. 如請求項7所述的太陽能電池,其中,該電極部與該基板之間設有數個第二導電部,每一第二導電部分別位於每一第一線狀開孔中。The solar cell of claim 7, wherein a plurality of second conductive portions are disposed between the electrode portion and the substrate, and each of the second conductive portions is located in each of the first linear openings. 如請求項7所述的太陽能電池,還包含數個位於該鈍化層上的銜接開孔,該數個銜接開孔分別連接在該數個第一線狀開孔中的任兩相鄰的第一線狀開孔的同側至少一端之間,每一該銜接開孔上有一個與位於該任兩相鄰的第一線狀開孔的該兩第一導電部分別連接的第三導電部。The solar cell of claim 7, further comprising a plurality of connection openings on the passivation layer, wherein the plurality of connection openings are respectively connected to any two adjacent ones of the plurality of first linear openings Between at least one end of the same side of the linear opening, each of the connecting openings has a third conductive portion respectively connected to the two first conductive portions of the two adjacent first linear openings . 如請求項7所述的太陽能電池,還包含一位於該鈍化層的表面上並連接該電極部以及該數個第一導電部的連接導電部。The solar cell of claim 7, further comprising a connecting conductive portion on the surface of the passivation layer and connecting the electrode portion and the plurality of first conductive portions. 一種太陽能電池模組,包含:相對設置的一第一板材與一第二板材; 至少一個如請求項7至10中任一項所述的太陽能電池,排列於該第一板材與該第二板材之間;及一封裝材,位於該第一板材與該第二板材之間,並接觸該太陽能電池。A solar cell module comprising: a first plate and a second plate disposed opposite each other; At least one solar cell according to any one of claims 7 to 10, arranged between the first plate and the second plate; and a package material between the first plate and the second plate, And contact the solar cell.
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