TWI457513B - Tape-wrapped multilayer tubing and methods making the same - Google Patents

Tape-wrapped multilayer tubing and methods making the same Download PDF

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TWI457513B
TWI457513B TW096103430A TW96103430A TWI457513B TW I457513 B TWI457513 B TW I457513B TW 096103430 A TW096103430 A TW 096103430A TW 96103430 A TW96103430 A TW 96103430A TW I457513 B TWI457513 B TW I457513B
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diffusion barrier
tubular member
layer
inner tubular
sealing
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TW096103430A
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TW200732578A (en
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e werner Douglas
Firouzi Ali
Munch Mark
Cichocki Zbigniew
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Cooligy Inc
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Description

封帶包覆多層管件及其製法Sealing tape coated multi-layer pipe fitting and preparation method thereof 【相關申請案】[related application]

申請案申請在此併入參考2006年1月30日提出申請之共未決美國臨時專利申請案第60/763,566號之35U.S.C119(c)段,標題為”封帶包覆多層管件及其製法”下之優先權。</ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; The priority under its method of production.

本發明係有關避免流體擴散損失之流體傳輸系統。明確地說,本發明係有關用於流體冷卻系統之封帶包覆多層管件及其製法。The present invention is directed to a fluid delivery system that avoids loss of fluid diffusion. In particular, the present invention relates to a tape-wrapped multilayer tube for use in a fluid cooling system and a method of making same.

存在著許多需管件傳輸系統中之點間之流體的流體傳輸系統類型。無論損失是因水汽傳輸或混合物流體組成損失所致,流體擴散於該系統,特別是封閉系統中是個問題。例如,若三組成形成一流體混合物,而各組成具有不同擴散速率或可透率,則這些組成密度比率會因已知管件中之高擴散率而隨時間變換。There are many types of fluid transfer systems that require fluid between points in a pipe transport system. Whether the loss is due to water vapor transport or loss of composition of the mixture fluid, the diffusion of fluid into the system, particularly in closed systems, is a problem. For example, if the three components form a fluid mixture and the compositions have different diffusion rates or permeable rates, then these composition density ratios will change over time due to the high diffusivity in known tubing.

電子冷卻系統領域中會產生此問題另一例。此領域內需冷卻半導體晶片。當此需要上升時,傳統設計面臨明顯挑戰。再者,新式高效能處理器具有非常高散熱要求。然而,包含裝載風扇散熱器及熱管之傳統冷卻方法具有若干限制。裝載風扇散熱器通常不會將空氣移動快的足以冷卻新式處理器,或不足以從固定電子元件之殼罩移出熱空氣。同樣地,熱管係被限制散熱量,及可從熱源移動熱之距離。因此,使用熱管或裝載風扇散熱器之傳統冷卻技術,並不足以冷卻如高效能處理器之新式電子元件。Another example of this problem arises in the field of electronic cooling systems. There is a need to cool semiconductor wafers in this area. When this need rises, traditional designs face significant challenges. Furthermore, the new high-performance processors have very high heat dissipation requirements. However, conventional cooling methods involving loading fan heat sinks and heat pipes have several limitations. Loading a fan heat sink typically does not move the air fast enough to cool the new processor or to remove hot air from the housing of the fixed electronic component. Similarly, the heat pipe is limited in heat dissipation and the distance from which heat can be moved from the heat source. Therefore, conventional cooling techniques using heat pipes or load fan heat sinks are not sufficient to cool new electronic components such as high performance processors.

使用液體冷卻劑之系統可有效冷卻產生明顯熱之半導體晶片。該液體冷卻系統需使用管件來傳輸流體。在此併入參考之美國專利號7,000,684及美國臨時專利申請案第60/788,545號中,標題為”多晶片冷卻”係進一步說明該冷卻系統例。該系統中,流體係流經管件來消散半導體所產生的熱。A system using a liquid coolant can effectively cool a semiconductor wafer that produces significant heat. The liquid cooling system requires the use of tubing to transport fluid. In the U.S. Patent No. 7,000,684, the disclosure of which is incorporated herein by reference in its entirety in its entirety in the entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all all In this system, the flow system flows through the tube to dissipate the heat generated by the semiconductor.

這些系統中,水汽密度梯度係跨越管件邊界存在。冷卻情況下,因為管件令一側具有低密度,所以該被加熱冷卻劑係經由管件壁消散。擴散在此梯度下繼續被驅動,直到內管件兩側建立實質均衡,水汽密度梯度實質為零為止。In these systems, the water vapor density gradient exists across the boundary of the pipe. In the case of cooling, the heated coolant is dissipated via the wall of the tube because the tube has a low density on one side. The diffusion continues to be driven under this gradient until a substantial equilibrium is established on both sides of the inner tube, and the water vapor density gradient is substantially zero.

液體冷卻系統中之水汽擴散是個問題,且若允許該系統乾涸,則可能具有災難性。使用輻射器之液體冷卻系統中,流體損失會導致熱效能逐漸損失。再者,汲取流體之液體冷卻系統中,流體實質損失最終會導致過熱。Water vapor diffusion in liquid cooling systems is a problem and can be catastrophic if the system is allowed to dry up. In a liquid cooling system using a radiator, fluid loss can result in a gradual loss of thermal efficiency. Moreover, in a liquid cooling system that draws fluid, substantial loss of fluid eventually leads to overheating.

水汽損失問題之一解係使用已知具有低水汽傳輸率之管件。該管件之一例係為金屬管件。該管件使用因其堅硬特性,金屬費用及組裝困難而有設計上的挑戰。再者,該系統中之任何金屬混合均會導致管件,唧筒或輻射器的腐蝕及堵塞。One of the problems of water vapor loss is to use tubes that are known to have low water vapor transmission rates. One example of the tube is a metal tube. The pipe fittings have design challenges due to their hard properties, metal cost and assembly difficulties. Furthermore, any metal mixing in the system can cause corrosion and blockage of the tube, barrel or radiator.

所需為具有高度彈性及非常低水汽傳輸率之管件。It is required to be a pipe with high elasticity and very low water vapor transmission rate.

本發明實施例係有關可結合屏障高擴散彈性及低水汽傳輸率之一混合多層管件建構。因此,本發明目的係提供一種有彈性且具有有效水汽擴散屏障之封帶包覆多層管件,及一種以連續及線內(in-line)處理來製造該管件之方法。Embodiments of the present invention relate to the construction of a hybrid multi-layer pipe that can combine one of the barrier high diffusion elasticity and the low water vapor transmission rate. Accordingly, it is an object of the present invention to provide a tape-wrapped multilayer tubular member that is resilient and has an effective moisture diffusion barrier, and a method of making the tubular member in a continuous and in-line process.

多層封帶包覆管件係被配置有效阻礙水汽擴散且以連續線內處理來製造。多層封帶包覆管件可具有三個不同層:一內管件層,一擴散屏障層及一外包殼層。該內管件層係與液體及水汽接觸。通常經由管件擴散之水汽係被該擴散屏障層阻礙。該擴散屏障層係為包含具有非常低水汽擴散率,位於熱塑膠層間之一擴散屏障薄膜之一層板。該擴散屏障層係繞著該內管件被包覆一或更多次。該外包殼層係為可被連結至被包覆該內管件之該擴散屏障層上之一聚合包殼。The multi-layer tape-wrapped tube is configured to effectively impede moisture diffusion and is manufactured by continuous in-line processing. The multi-layer tape-wrapping tubular member can have three different layers: an inner tube layer, a diffusion barrier layer, and an outer shell layer. The inner tube layer is in contact with liquid and moisture. The water vapor system that is typically diffused through the tube is obstructed by the diffusion barrier layer. The diffusion barrier layer is a laminate comprising a diffusion barrier film located between the layers of the thermoplastic layer having a very low water vapor diffusivity. The diffusion barrier layer is wrapped one or more times around the inner tubular member. The outer envelope is a polymeric envelope that can be joined to the diffusion barrier layer that is coated with the inner tubular member.

本發明另一特徵係為一種有效以線內及連續處理來製造多層封帶包覆管件之方法。內管件及擴散屏障封帶首先被引導至包覆裝置。該包覆裝置可以擴散屏障封帶包覆管件且創造線縫。密封,擴散封帶包覆內管件接著被引導至外包殼突出於該管件上之一突出物。Another feature of the invention is a method of making a multi-layer tape-wrapped tubular member effective in-line and continuous processing. The inner tubular member and the diffusion barrier seal are first directed to the cladding device. The cladding device can diffuse the barrier seal to cover the tubular member and create a seam. The seal, the diffusion bandage inner tube is then directed to the outer casing to protrude from one of the protrusions on the tube.

以下說明中,許多細節係針對解釋做說明。然而,熟練技術人士將明瞭不需使用這些特定細節即可實施本發明。In the following description, many details are explained for explanation. However, the skilled artisan will understand that the invention may be practiced without these specific details.

第1A至1C圖藉由描繪使用一般聚合物管件之冷卻系統中之液體如何因水汽擴散而損失。第1A圖顯示時間(t)=0時被填充水汽110若干原始量之一聚合物管件100。水汽110於該系統中係為100%原始水汽。Figures 1A through 1C depict how liquid in a cooling system using a typical polymer tube is lost due to moisture diffusion. Figure 1A shows a polymer tube 100 that is filled with some of the original amounts of water vapor 110 at time (t) = 0. The water vapor 110 is 100% raw water vapor in the system.

第1B圖呈現時間(t)=0後若干稍後時間t=△t時之相同聚合物管件100。時間t=△t處,因為管內較管外具有更高密度,所以若干水汽係經由聚合物管件壁擴散。擴散微粒120係逸出系統。當此發生時,聚合物管件100中之水汽量130係小於水汽110原始量。第1C圖描繪時間t=tc r i t i c a l 時之相同聚合物管件100。時間t=t c r i t i c a l 處,幾乎所有聚合物管件100中之水汽均經由管件壁擴散。該管件以水汽密度140等於外部密度做結束。Figure 1B presents the same polymer tube 100 at a later time t = Δt after time (t) = 0. At time t = Δt, since the inside of the tube has a higher density than the outside of the tube, some water vapor is diffused through the wall of the polymer tube. The diffusion particles 120 are escaping systems. When this occurs, the amount of water vapor 130 in the polymeric tubular member 100 is less than the original amount of water vapor 110. Figure 1C depicts the same polymer tube 100 at time t = t c r i t i c a l . At time t = t c r i t i c a l , almost all of the water vapor in the polymer tube 100 is diffused through the wall of the tube. The tube ends with a water vapor density 140 equal to the external density.

第2A至2C圖藉由描繪如何使用擴散屏障針對冷卻系統中之可擴散管件水汽擴散問題達成預期解來促進理解本發明。第2A至2C圖描繪聚合物管件200以實質密封點210被包覆於擴散屏障層220內之一系統。本發明之一實施例中,此擴散屏障層220係為第4圖所示之多層封帶層板。第2A圖描繪時間(t)=0時之聚合物管件200。第2A圖中,聚合物管件200係被填充水汽230若干原始量,而擴散屏障包覆區域240係為空的。水汽230於該系統中係為100%原始水汽。2A-2C facilitates an understanding of the present invention by delineating how to use the diffusion barrier to achieve an expected solution to the water vapor diffusion problem of the diffusible tubular in the cooling system. 2A-2C depict one system in which polymeric tubing 200 is encapsulated within diffusion barrier layer 220 at a substantial sealing point 210. In one embodiment of the invention, the diffusion barrier layer 220 is a multilayer tape laminate as shown in FIG. Figure 2A depicts the polymer tube 200 at time (t) = 0. In Figure 2A, the polymeric tubular member 200 is filled with a plurality of original amounts of water vapor 230, and the diffusion barrier cladding region 240 is empty. The water vapor 230 is 100% raw water vapor in the system.

第2B圖呈現時間(t)=0後若干稍後時間t=△t時之相同聚合物管件200。時間t=△t處,因為管內較管外具有更高密度,所以若干水汽係經由聚合物管件壁擴散。擴散微粒250係逸出系統。當此發生時,聚合物管件200中之水汽量260係小於水汽230原始量。相當地,因為擴散屏障層具有非常低水汽轉移率,並可捕捉塑膠管件200及擴散屏障層220間之水汽,所以擴散屏障包覆區域240中之水汽量係增加。Figure 2B presents the same polymer tube 200 at a later time t = Δt after time (t) = 0. At time t = Δt, since the inside of the tube has a higher density than the outside of the tube, some water vapor is diffused through the wall of the polymer tube. The diffusion particles 250 are escaping systems. When this occurs, the amount of water vapor 260 in the polymeric tubular member 200 is less than the original amount of water vapor 230. Quite, since the diffusion barrier layer has a very low water vapor transfer rate and can capture moisture between the plastic tube member 200 and the diffusion barrier layer 220, the amount of water vapor in the diffusion barrier coating region 240 increases.

第2C圖描繪時間(t)=te q u i l i b r i u m 時之相同聚合物管件200。時間T=te q u i l i b r i u m 時,擴散微粒250所需量擴散進入擴散屏障包覆區域240等於聚合物管件200中之水汽量270。時間t=te q u i l i b r i u m 時,擴散屏障包覆區域240及聚合物管件200內部間之水汽密度梯度實質為零且達成均衡。Figure 2C depicts the same polymer tube 200 at time (t) = t e q u i l i b r i u m . When the time T = t e q u i l i b r i u m , the required amount of diffusion particles 250 diffuses into the diffusion barrier cladding region 240 equal to the amount of water vapor 270 in the polymer tubular member 200. When the time t=t e q u i l i b r i u m , the water vapor density gradient between the diffusion barrier cladding region 240 and the interior of the polymer tube 200 is substantially zero and equilibrium is achieved.

第3圖描繪本發明多層封帶包覆管件之一實施例。區域310係為液體流動於液體冷卻系統之一空穴。內管件層320係為與經由區域310轉移之流體接觸之一彈性管件。內管件320較佳實質為圓柱形,然而亦可設想其他配置。內管件層320若干較佳特性係包含但不限制以下:優越彈性,紐結阻力,遲鈍,突出處理期間之熱機械及尺寸穩定性,及無漏洩連結之連接器耦合例。視應用而定,許多等級管件係為內管層潛在候選者,包含但不限制為:(1)如聚烯烴,修正聚烯烴,氟塑料,聚醯胺,聚酯及乙烯基樹脂之熱塑膠,(2)以烯烴,聚丁二烯,聚酯,苯乙烯及乙烯基化學元素為基礎之熱塑彈性體,及(3)如醋酸,聚異丁烯(簡稱PIB),三元乙丙膠(EPDM),NBR,SBR及鉑加工或過氧化物加工矽樹脂橡膠。再者,可強化管件來改善熱機械及紐結阻力特性。Figure 3 depicts an embodiment of a multi-layer tape-wrapped tubular member of the present invention. Region 310 is a liquid flowing into one of the liquid cooling systems. The inner tubular member layer 320 is one of the elastic tubular members in contact with the fluid transferred via the region 310. The inner tubular member 320 is preferably substantially cylindrical in shape, although other configurations are contemplated. Some of the preferred characteristics of the inner tubular member layer 320 include, but are not limited to, the following: superior elasticity, kink resistance, retardation, thermomechanical and dimensional stability during the protrusion process, and connector coupling examples without leaky connections. Depending on the application, many grades are potential candidates for the inner tube layer, including but not limited to: (1) thermoplastics such as polyolefins, modified polyolefins, fluoroplastics, polyamides, polyesters and vinyls. (2) Thermoplastic elastomers based on olefins, polybutadiene, polyester, styrene and vinyl chemical elements, and (3) such as acetic acid, polyisobutylene (PIB), EPDM ( EPDM), NBR, SBR and platinum processing or peroxide processing of ruthenium resin. Furthermore, the tube can be reinforced to improve thermomechanical and kink resistance characteristics.

擴散屏障封帶層板或層330可提供一包覆來限制水汽擴散。一實施例中,擴散屏障屏障封帶層板或層330係被包覆於內管件層320並接著藉由熱及壓力蜜封。較佳實施例中,擴散屏障層或層330具有彈性且可針對可靠,一致及可製造包覆具有必要穿刺,撕及拉力,且可針對低水汽傳輸速率特性創造連續擴散屏障。The diffusion barrier sealing layer or layer 330 can provide a coating to limit moisture diffusion. In one embodiment, the diffusion barrier barrier banding layer or layer 330 is wrapped over the inner tube layer 320 and then honey sealed by heat and pressure. In a preferred embodiment, the diffusion barrier layer or layer 330 is resilient and can have the necessary puncture, tear and pull for reliable, consistent and manufacturable cladding, and can create a continuous diffusion barrier for low moisture transport rate characteristics.

本發明設想各種屏障封帶層板配置。例如,第4A圖描繪本發明之一實施例之單擴散屏障封帶板層400,其中該層不被等比例繪圖。此實施例中,單擴散屏障層400係為一多層封帶層板,包含一擴散屏障材料410,熱塑膠膜片層430,440及一黏著層420。擴散屏障膜片410係對水汽傳輸具有高阻力。若干實施例中,擴散屏障膜片410係為鋁箔。其他實施例中,擴散屏障膜片410係為如尼龍之聚醯胺。擴散屏障膜片410亦可為透明聚合物,如Alcar,AlliedSignal所製造之聚三氟氯乙烯(PCTFE),DuPont所生產之Saran(聚偏二氯乙烯)或Tedlar(聚氟乙烯),或其他適當材料。本發明若干實施例中,擴散屏障膜片410係介於熱塑膠膜片層430,440之間。這些熱塑膠膜片層430,440可當作黏著劑,其可於施加適當壓力及熱時做熱密封。較佳實施例中,這些熱塑膠膜片層430,400係為具有低溶化溫度(攝氏~120度)之低密度聚乙烯。其他實施例中,外熱塑膠膜片層430,440係來自修正聚乙烯家族。The present invention contemplates various barrier banding laminate configurations. For example, Figure 4A depicts a single diffusion barrier sealing sheet layer 400 in accordance with one embodiment of the present invention, wherein the layers are not drawn to scale. In this embodiment, the single diffusion barrier layer 400 is a multi-layer tape sealing layer comprising a diffusion barrier material 410, a thermoplastic film layer 430, 440 and an adhesive layer 420. The diffusion barrier membrane 410 has high resistance to moisture transport. In some embodiments, the diffusion barrier film 410 is an aluminum foil. In other embodiments, the diffusion barrier membrane 410 is a polyamine such as nylon. The diffusion barrier membrane 410 can also be a transparent polymer such as Alcar, Polychlorotrifluoroethylene (PCTFE) manufactured by AlliedSignal, Saran (polyvinylidene chloride) or Tedlar (polyvinyl fluoride) manufactured by DuPont, or the like. Appropriate materials. In some embodiments of the invention, the diffusion barrier film 410 is interposed between the thermoplastic film layers 430, 440. These thermoplastic film layers 430, 440 act as an adhesive which can be heat sealed when appropriate pressure and heat are applied. In a preferred embodiment, the thermoplastic film layers 430, 400 are low density polyethylene having a low melting temperature (120 degrees Celsius). In other embodiments, the outer thermoplastic plastic film layers 430, 440 are from the modified polyethylene family.

若干實施例中,熱塑膠膜片層430係經由黏著層420被黏著連結至擴散屏障膜片410。若干實施例中,此連結係使用較不溶解黏著層壓技術來達成。若干實施例中,熱塑膠膜片層440係使用塑性壓力突出敷設處理,藉由突出熱塑膠膜片層於板層邊界450處之擴散屏障膜片410上來連接至擴散屏障膜片410。若干實施例中,包含多層擴散屏障材料之擴散屏障膜片410係介於兩熱塑膠層430,440之間。In some embodiments, the thermoplastic film layer 430 is adhesively bonded to the diffusion barrier film 410 via the adhesive layer 420. In some embodiments, this bonding is achieved using a less soluble adhesive lamination technique. In some embodiments, the thermoplastic film layer 440 is joined to the diffusion barrier film 410 by a plastic pressure relief coating process by projecting a layer of thermoplastic film on the diffusion barrier film 410 at the ply boundary 450. In some embodiments, a diffusion barrier film 410 comprising a plurality of diffusion barrier materials is interposed between two thermoplastic layers 430, 440.

熱塑膠層430,440可提供優於已知技術之大優點。適當熱及壓力處理時,因層430及440彼此連結之減輕,所以使用熱塑膠層於擴散屏障兩側係可促使連續及線內處理來包覆內管件。The thermoplastic layers 430, 440 provide significant advantages over known techniques. During proper heat and pressure treatment, the layers 430 and 440 are reduced in connection with each other, so the use of a thermoplastic layer on both sides of the diffusion barrier promotes continuous and in-line processing to cover the inner tubular member.

第4B圖可提供較佳屏障封帶板層配置例。第4B圖可描繪具有一附加層425之一擴散屏障板層。單擴散屏障層400係為一多層封帶層板,包含一擴散屏障材料410,熱塑膠膜片層430,440及一黏著層420。附加層425係為如尼龍之聚醯胺。包含聚醯胺於擴散屏障封帶板層中係可大為改善屏障膜片之撕力。此撕力改善可提供一非預期結果,其可被改善水汽擴散之預期結果混合。該撕力改善給予管件較佳彎曲特性。該撕力改善可促使管件被用於以較正常為高而維持擴散屏障完整性之膨脹比率與倒鉤連結之倒鉤上。Figure 4B provides an example of a preferred barrier tape layer configuration. FIG. 4B depicts a diffusion barrier slab having an additional layer 425. The single diffusion barrier layer 400 is a multi-layer sealing layer comprising a diffusion barrier material 410, a thermoplastic film layer 430, 440 and an adhesive layer 420. The additional layer 425 is a polyamine such as nylon. The inclusion of polyamine in the diffusion barrier sealing sheet layer can greatly improve the tearing force of the barrier film. This tear improvement can provide an unexpected result that can be mixed by the desired result of improved water vapor diffusion. This tearing improvement imparts better bending characteristics to the tubular member. This tearing improvement can cause the tube to be used to maintain the stability of the diffusion barrier at a higher ratio than normal to the barb-joined barbs.

本發明若干實施例使用一個以上擴散屏障層400。以降低彈性及更複雜建構作為懲罰,多擴散屏障層將可提供穿刺,撕,拉力及較佳水汽傳輸特性且將實質消除單錯誤密封效應。Several embodiments of the invention use more than one diffusion barrier layer 400. With reduced flexibility and more complex construction as a penalty, the multi-diffusion barrier layer will provide puncture, tear, pull and better moisture transport characteristics and will substantially eliminate the single false seal effect.

回去參考第3圖,多層封帶包覆管件若干實施例係包含可提供實質密封管件保護及整合。包殼層340厚度亦可修正擴散屏障封帶板層包覆管件300之紐結特性。修改包殼層340厚度係改變紐結阻礙管件內之流體流動前之管件彎曲多寡。較佳實施例中,外層340係為一聚合物包殼。該包殼層亦具有用於全多層管件化合物較佳燃燒能力特性之燃燒遲緩組成。Referring back to Figure 3, several embodiments of the multi-layer tape-wrapped tubular member include the protection and integration of a substantially sealed tubular member. The thickness of the cladding layer 340 can also modify the kink characteristics of the diffusion barrier sealing sheet layer cladding tube 300. Modifying the thickness of the cladding layer 340 changes the amount of bending of the tube before the knot interferes with fluid flow within the tube. In the preferred embodiment, outer layer 340 is a polymer cladding. The cladding layer also has a combustion retardant composition for better combustion capability characteristics of the full multilayer tube compound.

若干實施例中,係使用連續線內壓力突出處理施加包殼層340。替代實施例中,係使用管件突出處理或半壓力突出處理。再另一實施例中,使用熱收縮處理,且經由熱收縮管件施加包殼層340。這些施加包殼層340之替代方式具有顯著製造優點,但因使用附加熱及壓力而均有助於最小化擴散屏障層330中錯誤密封的機率。較佳實施例中,來自壓力突出步驟之附加熱及壓力進一步熱密封熱塑膠膜片層430,440(第4圖)至擴散屏障材料,並進一步連結擴散屏障封帶層板330至內管320。In several embodiments, the cladding layer 340 is applied using a continuous in-line pressure relief process. In an alternative embodiment, a tube projection process or a semi-pressure protrusion process is used. In still another embodiment, a heat shrink process is used and the cladding layer 340 is applied via a heat shrink tubing. These alternative ways of applying the cladding layer 340 have significant manufacturing advantages, but all contribute to minimizing the chance of erroneous sealing in the diffusion barrier layer 330 due to the use of additional heat and pressure. In a preferred embodiment, the additional heat and pressure from the pressure projecting step further thermally seals the thermoplastic film layers 430, 440 (Fig. 4) to the diffusion barrier material and further joins the diffusion barrier sealing sheet 330 to the inner tube 320. .

處理,組裝及鉗緊期間,包殼層340亦可保護底下擴散屏障層330不受刺穿或撕力。若干實施例中,擴散屏障封帶層板330及包殼層340之間係包含或包殼層340中倒鉤強化層(無圖示)來改善外包殼層之紐結阻力。其他實施例中,多包殼層(無圖示)係被用來進一步保護內層。若干實施例中,該包殼厚度範圍從一(1)微米至二分之一(0.5)英吋。The cladding layer 340 also protects the underlying diffusion barrier layer 330 from puncture or tearing during handling, assembly, and clamping. In some embodiments, the barrier barrier encapsulation layer 330 and the cladding layer 340 comprise or include a barb reinforcement layer (not shown) in the cladding layer 340 to improve the kink resistance of the outer envelope layer. In other embodiments, a multi-cladding layer (not shown) is used to further protect the inner layer. In some embodiments, the cladding thickness ranges from one (1) micron to one-half (0.5) inch.

第5圖為依據本發明若干實施例之製造封帶包覆多層管件之一方法流程圖。於步驟555,係形成內管件及擴散屏障封帶層板。一實施例中,內管件係藉由管件突出處理形成,但亦可設想其他形成內管件之方法。一實施例中,屏障封帶層板係以壓力突出處理藉以施加兩熱塑膠層於擴散屏障材料上來形成。亦可使用半壓力突出處理施加熱塑膠。若干實施例中,黏著劑係被配置於該擴散屏障材料及該熱塑膠之間當作黏著層。Figure 5 is a flow diagram of a method of making a tape wrapped multi-layered tubular member in accordance with several embodiments of the present invention. In step 555, an inner tubular member and a diffusion barrier sealing laminate are formed. In one embodiment, the inner tubular member is formed by a tubular projecting process, but other methods of forming the inner tubular member are also contemplated. In one embodiment, the barrier banding layer is formed by pressure protrusion treatment to apply two layers of thermoplastic material to the diffusion barrier material. It is also possible to apply a hot plastic using a semi-pressure protrusion treatment. In some embodiments, an adhesive is disposed between the diffusion barrier material and the thermoplastic as an adhesive layer.

如突出處理,鉗緊或製成層板之其他處理同樣可被用來建造本發明之層。雖然這些特定例被給定解釋本發明之層如何被建造,但熟練技術人士可輕易理解可使用任何其他適當處理。Other treatments such as prominence, clamping or lamination may also be used to construct the layers of the present invention. While these specific examples are given to explain how the layers of the present invention are constructed, those skilled in the art will readily appreciate that any other suitable processing may be utilized.

接著,於步驟560,材料係被饋送至一包覆器。尚未被包覆之內管件係被饋送至第一包覆器。若干實施例中,先前被包覆及密封之管件係被饋送至連續包覆器或第一包覆器下游的包覆器。若干實施例中,該包覆器係為如以下第6圖解釋之香煙包覆型包覆器。其他實施例中,係以包覆器執行旗幟包覆(如第7A,7B及7C圖所示),螺旋包覆(如第8圖所示),或任何其他適當包覆。Next, at step 560, the material is fed to a wrapper. The inner tube that has not been coated is fed to the first wrapper. In several embodiments, the previously wrapped and sealed tubular member is fed to a continuous coater or a wrapper downstream of the first cladding. In some embodiments, the wrapper is a cigarette wrap-around wrapper as explained in Figure 6 below. In other embodiments, the flag wrap is performed with a wrapper (as shown in Figures 7A, 7B, and 7C), spiral coated (as shown in Figure 8), or any other suitable wrap.

接著,於步驟565,包覆器包覆內管周圍之層擴散屏障封帶層板。可替代是,包覆器包覆已被包覆內管件周圍之附加層擴散屏障封帶層板。包覆器係以實質管件長度向下留下重疊擴散屏障封帶層板線縫來包覆內管件。Next, in step 565, the wrapper coats the layer diffusion barrier seal laminate around the inner tube. Alternatively, the wrapper coats an additional layer of diffusion barrier seal laminate that has been wrapped around the inner tubular member. The wrapper encloses the inner tubular member with a layer of overlapping diffusion barrier seal plys down the length of the substantial tubular member.

於步驟570,被包覆管件係被饋送至第一密封劑。於步驟575,被包覆管件線縫係被密封,其中密封劑係施加熱及壓力至該線縫。較佳是,密封劑施加足夠熱及壓力來熔化擴散屏障封帶層板熱塑膠,並將該線縫黏著一起。使用約攝氏120度熱溫度係充分超過軟化點且足以黏著該線縫。At step 570, the coated tubular member is fed to the first sealant. At step 575, the coated tubular seam is sealed wherein the sealant applies heat and pressure to the seam. Preferably, the sealant applies sufficient heat and pressure to melt the diffusion barrier seal ply thermoplastic and adhere the seam together. The use of a temperature of about 120 degrees Celsius is sufficient to exceed the softening point and is sufficient to adhere to the seam.

本發明若干實施例中,僅線縫黏著層被密封一起,而擴散屏障封帶層板不被黏著至內管件。當內管件為矽樹脂時,該實施例較佳。矽樹脂並不連結至擴散屏障封帶層板之內層,所以當管件彎曲時,其可滑動於擴散屏障封帶層板內。該滑動可有效地縮減撕裂擴散屏障封帶層板。其他實施例中,密封劑係施加足夠熱及壓力來黏著該線縫及該內管至該擴散屏障封帶。若干實施例中,第一密封劑下游之附加密封劑可供給附加熱及壓力來進一步黏著該內管至該擴散屏障封帶,並將該線縫黏著一起。In several embodiments of the invention, only the seam adhesive layers are sealed together, and the diffusion barrier seal laminate is not adhered to the inner tubular members. This embodiment is preferred when the inner tubular member is a resin. The resin is not bonded to the inner layer of the diffusion barrier sealing laminate, so that when the tubular is bent, it can slide within the diffusion barrier sealing laminate. This sliding effectively reduces the tear diffusion barrier seal laminate. In other embodiments, the sealant applies sufficient heat and pressure to adhere the seam and the inner tube to the diffusion barrier seal. In some embodiments, an additional sealant downstream of the first sealant can supply additional heat and pressure to further adhere the inner tube to the diffusion barrier seal and adhere the seam together.

若干實施例中,被包覆管件係被饋送至步驟580處之前一者下游之附加包覆器及密封劑。若干實施例中,這些包覆器及密封劑可創造管件周圍不同配置及不同軸位置中之線縫。其他實施例中,於步驟580,管件僅經由一包覆器及一密封劑饋送。In some embodiments, the coated tubular member is fed to an additional wrapper and sealant downstream of one of the previous steps at step 580. In some embodiments, these wrappers and sealants create seams in different configurations around the tube and in different axial positions. In other embodiments, at step 580, the tube is fed only through a wrapper and a sealant.

若干實施例中,包殼層係於步驟590被施加至該被包覆及密封管件。可替代是,該管件並不具有一包殼層。若干實施例中,該包殼層係使用壓力突出處理施加。其他實施例中,該包殼層係使用半壓力突出處理施加。若干實施例中,被用來施加包殼層至該被包覆管件之處理,係可進一步黏著內管件至擴散屏障封帶,並將線縫黏著一起。In some embodiments, a cladding layer is applied to the coated and sealed tubular member in step 590. Alternatively, the tube does not have a cladding layer. In several embodiments, the cladding layer is applied using a pressure relief treatment. In other embodiments, the cladding layer is applied using a semi-pressure protrusion treatment. In several embodiments, the treatment used to apply the cladding layer to the coated tubular member further adheres the inner tubular member to the diffusion barrier seal and adheres the seams together.

本發明若干實施例中,熱收縮處理係被用來施加包殼至封帶包覆管件。依據此實施例,內管件首先以連續及線內處理被包覆及密封一次或多次,接著以熱收縮包殼分別包殼。In several embodiments of the invention, heat shrink processing is used to apply the cladding to the tape-wrapped tubular member. According to this embodiment, the inner tubular members are first coated and sealed one or more times in a continuous and in-line process, and then individually wrapped in a heat shrinkable cladding.

第6至9圖分別說明環繞內管件包覆擴散屏障封帶層板之各種方法。在此揭示這些特定包覆方法,然而,亦可設想其他包覆類型。Figures 6 through 9 illustrate various methods of encasing the diffusion barrier sealing laminate surrounding the inner tubular member, respectively. These specific coating methods are disclosed herein, however, other types of coatings are also contemplated.

第6圖說明本發明一實施例俗稱”香煙包覆”之包覆法。此實施例中,內管件600係被饋送至包覆器610及擴散屏障封帶層板620。如以上解釋及第5圖中,內管件600可選擇性在此處理之前及同時突出。同樣地,擴散屏障封帶層板可在此處理上游,之前及同時製造。當內管件被引導通過包覆器610時,擴散屏障封帶層板620係經由可環繞內管件600摺疊擴散屏障封帶620之裝置630饋送。摺疊後,擴散屏障封帶層板重疊區域640係重疊擴散屏障封帶層板620另一部份。擴散屏障封帶層板重疊比例範圍較佳從百分之十至百分之二十五,然而,亦可設想其他重疊比例。擴散屏障封帶層板620之重疊部分,係具有可被一起熱密封之熱塑膠表面(如第4圖所示430及440)。具有擴散屏障封帶層板重疊區域640之擴散屏障封帶層板包覆內管件650係被饋送至熱密封劑660。熱密封劑660可提供適當熱及壓力至擴散屏障封帶層板重疊區域640,及至與內管件接觸以密封擴散屏障封帶層板包覆內管件650之熱塑膠材料。Fig. 6 is a view showing a coating method commonly known as "cigarette coating" according to an embodiment of the present invention. In this embodiment, the inner tubular member 600 is fed to the wrapper 610 and the diffusion barrier seal ply 620. As explained above and in Figure 5, the inner tubular member 600 can be selectively protruded prior to and at the same time as this treatment. Likewise, the diffusion barrier sealing laminate can be processed upstream, before and at the same time. When the inner tubular member is guided through the wrapper 610, the diffusion barrier sealing strip 620 is fed via a device 630 that can fold the diffusing barrier seal 620 around the inner tubular member 600. After folding, the diffusion barrier seal laminate overlap region 640 overlaps another portion of the diffusion barrier seal laminate 620. The diffusion barrier sealing layer overlap ratio preferably ranges from ten to twenty-five percent, however, other overlapping ratios are also contemplated. The overlapping portions of the diffusion barrier sealing ply 620 have a thermoplastic surface that can be heat sealed together (as shown in Figures 4 and 440). A diffusion barrier encapsulation laminate inner tube 650 having a diffusion barrier enveloping laminate overlap region 640 is fed to a heat sealant 660. The heat sealant 660 can provide suitable heat and pressure to the diffusion barrier seal laminate overlap region 640 and to the thermoplastic material in contact with the inner tubular member to seal the diffusion barrier seal laminate from the inner tubular member 650.

本發明一實施例中,包覆及密封處理係於包殼之前被重複,提供一個或更多擴散屏障封帶層板附加層(無圖示)。一實施例中,一個或更多擴散屏障封帶層板係使用相同包覆方法,但可替代地使用不同方法包覆。當相同包覆方法被用來包覆具有多層擴散屏障封帶層板620之內管件600時,較佳偏置線縫來提供擴散屏障封帶層板重疊區域640間之更大距離。In one embodiment of the invention, the cladding and sealing process is repeated prior to encapsulation to provide one or more additional layers of diffusion barrier encapsulation laminate (not shown). In one embodiment, one or more of the diffusion barrier banding sheets use the same coating method, but may alternatively be coated using different methods. When the same coating method is used to coat the inner tubular member 600 having the multi-layer diffusion barrier sealing ply 620, the slits are preferably offset to provide a greater distance between the diffusion barrier enveloping laminate overlapping regions 640.

一實施例中,以至少一層擴散屏障封帶層板620包覆及以熱密封劑660密封之內管件600係被引導至突出物680,並施加外包殼層690。各種方法均可被用來施加外包殼層690,包含但不限於連續線內壓力突出,管件突出或半壓力突出。In one embodiment, the inner tubular member 600, which is covered with at least one layer of the diffusion barrier sealing strip 620 and sealed with a heat sealant 660, is directed to the protrusions 680 and the outer shell layer 690 is applied. Various methods can be used to apply the outer shell 690, including but not limited to continuous in-line pressure protrusions, tubular protrusions or semi-pressure protrusions.

第7A至7C圖說明使用旗幟包覆時之本發明封帶包覆多層管件。此包覆方法使用旗幟包覆器(無圖示)環繞內管件710包覆擴散屏障封帶層板720。旗幟包覆內管件之旗幟730隨後被摺疊於包覆管件上且被密封。若干實施例中,被向下摺疊於該被包覆管件上之旗幟長度範圍係從約一(1)微米至二十(20)微米。密封摺疊旗幟狹條730長度係為被包覆管件長度。一實施例中,包覆及密封處理係於包殼之前被重複,提供一個或更多擴散屏障封帶層板附加層(無圖示)。一實施例中,該一個或更多擴散屏障封帶層板附加層係使用相同包覆方法,但可替代地使用不同方法包覆。第7C圖說明施加外包殼層750後之密封旗幟包覆內管件740。Figures 7A through 7C illustrate the closure of a multi-layer tube of the present invention when coated with a flag. This coating method encloses the diffusion barrier seal laminate 720 around the inner tubular member 710 using a banner wrapper (not shown). The flag 730 of the flag wrapped inner tube is then folded over the cladding tube and sealed. In some embodiments, the length of the flag folded down onto the coated tubular member ranges from about one (1) micron to twenty (20) micrometers. The length of the sealed folded banner strip 730 is the length of the wrapped tubular member. In one embodiment, the cladding and sealing process is repeated prior to encapsulation to provide one or more additional layers of diffusion barrier encapsulation laminate (not shown). In one embodiment, the one or more diffusion barrier banding laminate additional layers use the same coating method, but may alternatively be coated using different methods. Figure 7C illustrates a sealed flag wrapped inner tubular member 740 after application of the outer shell 750.

執行旗幟包覆之本發明其他實施例中,該旗幟係於被包覆之後被裁修。第7D,7E及7F圖說明依據本發明此實施例之旗幟包覆管件。如第7D圖所示,擴散屏障封帶層板720係環繞內管件710做包覆。旗幟包覆內管件之垂直延伸旗幟730隨後被裁修做為部份連續,線內處理。第7E圖說明被裁修後之旗幟包覆管件。如圖示,小殘端760維持及輕微從內管件710延伸出。第7C圖說明施加外包殼層750後之密封旗幟包覆內管件740。In other embodiments of the invention in which the flag wrap is performed, the flag is trimmed after being wrapped. Figures 7D, 7E and 7F illustrate a flag cladding tube member in accordance with this embodiment of the present invention. As shown in FIG. 7D, the diffusion barrier sealing layer 720 is wrapped around the inner tubular member 710. The vertically extending banner 730 of the flag-wrapped inner tubular member is then trimmed as a partial continuous, in-line process. Figure 7E illustrates the flagged tube fitting after being trimmed. As shown, the small stump 760 is maintained and slightly extended from the inner tubular member 710. Figure 7C illustrates a sealed flag wrapped inner tubular member 740 after application of the outer shell 750.

第8圖說明使用螺旋包覆時之本發明封帶包覆多層管件。此包覆方法使用螺旋包覆器(無圖示)環繞內管件810包覆擴散屏障封帶層板820。螺旋包覆器以連續重疊螺旋方式環繞內管件810長度包覆擴散屏障封帶層板820。螺旋包覆擴散屏障封帶層板可形成一重疊區域830。螺旋包覆擴散屏障封帶層板之重疊比率範圍較佳係從百分之二十五至五十五,然而,亦可設想任何其他重疊比率。螺旋包覆擴散屏障封帶層板被密封之後,係施加外包殼層840。Figure 8 illustrates the closure of a multi-layer tube of the present invention when a spiral coating is used. This coating method encloses the diffusion barrier sealing ply 820 around the inner tubular member 810 using a spiral wrapper (not shown). The spiral wrapper encloses the diffusion barrier seal ply 820 around the length of the inner tubular member 810 in a continuous overlapping spiral. The spiral coated diffusion barrier sealing laminate can form an overlap region 830. The overlap ratio of the spiral coated diffusion barrier sealing laminate is preferably from 25 to 55 percent, however, any other overlapping ratio is also contemplated. After the spiral coated diffusion barrier sealing ply is sealed, an outer casing 840 is applied.

本發明若干實施例中,包覆及密封處理係於包殼之前被重複,提供一個或更多擴散屏障封帶層板附加層(無圖示)。該附加包覆及密封可以連續線內處理做施加。可替代是,該附加包覆及密封可藉由如纏繞封帶包覆管件,接著藉由即使相同機器之包覆及密封機器再饋送先前包覆管件而依序發生。若干實施例中,一個或更多擴散屏障封帶層板附加層係使用相同包覆方法做包覆。可替代是,該擴散屏障封帶層板附加層可使用不同方法做包覆。若干實施例中,擴散屏障封帶層板第一層係使用順時針螺旋包覆處理做包覆,而擴散屏障封帶層板附加層可使用逆時針或順時針包覆處理做包覆。同時,若干實施例中,包覆附加層所形成之線縫係被放置於內管件不同軸位置上。In several embodiments of the invention, the coating and sealing process is repeated prior to encapsulation to provide one or more additional layers of diffusion barrier encapsulation laminate (not shown). The additional coating and sealing can be applied in a continuous line for application. Alternatively, the additional covering and sealing can be sequentially performed by, for example, wrapping the tubular member with a wrap, and then sequentially feeding the previously coated tubular member even if the same machine is coated and sealed. In several embodiments, one or more of the diffusion barrier banding layer additional layers are coated using the same coating method. Alternatively, the diffusion barrier banding layer additional layer can be coated using different methods. In some embodiments, the first layer of the diffusion barrier sealing layer is coated with a clockwise spiral coating process, and the additional layer of the diffusion barrier sealing layer can be coated with a counterclockwise or clockwise coating process. At the same time, in some embodiments, the seams formed by the additional layers are placed at different axial positions of the inner tubular members.

本發明說明包含細節之特定實施例型式來促進理解本發明建構及操作原理。該特定實施例及細節參考並不預期限制其附帶申請專利範圍。熟練技術人士將明瞭只要不背離本發明精神及範圍,均可修改被選擇做說明的實施例。明確地說,熟練技術人士將明瞭本發明裝置及方法可以若干不同方式來實施且具有若干不同面貌。The present invention is described in terms of specific embodiments of the invention in order to facilitate the understanding of the invention. This particular embodiment and details are not intended to limit the scope of the accompanying claims. It will be apparent to those skilled in the art that the embodiments that are selected for the description can be modified without departing from the spirit and scope of the invention. In particular, the skilled artisan will appreciate that the devices and methods of the present invention can be implemented in a number of different ways and have a number of different aspects.

100、200...聚合物管件100, 200. . . Polymer pipe fittings

110、230...水汽110, 230. . . Water vapor

120、250...擴散微粒120, 250. . . Diffusion particle

130、260、270...水汽量130, 260, 270. . . Water vapor

140...水汽密度140. . . Water vapor density

210...實質密封點210. . . Substantial sealing point

220...擴散屏障層220. . . Diffusion barrier

240...擴散屏障包覆區域240. . . Diffusion barrier cladding area

300...管件300. . . Pipe fittings

310...區域310. . . region

320...內管件層320. . . Inner tube layer

330...擴散屏障封帶層板或層330. . . Diffusion barrier sealing layer or layer

340...包殼層340. . . Shell layer

400...單擴散屏障封帶板層400. . . Single diffusion barrier sealing layer

410...擴散屏障膜片410. . . Diffusion barrier diaphragm

420...黏著層420. . . Adhesive layer

425...附加層425. . . Additional layer

430、440...熱塑膠膜片層430, 440. . . Hot plastic film layer

450...板層邊界450. . . Laminate boundary

600、650、710、740、810...內管件600, 650, 710, 740, 810. . . Inner pipe fitting

610...包覆器610. . . Wrapper

620、720、820...擴散屏障封帶層板620, 720, 820. . . Diffusion barrier sealing layer

630...裝置630. . . Device

640...擴散屏障封帶層板重疊區域640. . . Diffusion barrier sealing layer overlap area

660...熱密封劑660. . . Heat sealant

680...突出物680. . . obstructive

690、750、840...外包殼層690, 750, 840. . . Outer shell

730...旗幟730. . . banner

760...小殘端760. . . Small stump

830...重疊區域830. . . Overlapping area

本發明最新特徵係被說明於附帶申請專利範圍中。然而,為了解釋本發明若干實施例係被說明於以下圖示中。The most recent features of the present invention are described in the appended claims. However, several embodiments of the invention have been described in the following figures.

第1A圖說明時間t=0開始發生於無附加擴散屏障之塑膠管件中之擴散處理。Figure 1A illustrates the diffusion process that begins at time t = 0 in a plastic tube without an additional diffusion barrier.

第1B圖說明時間t=△t開始發生於無附加擴散屏障之塑膠管件中之擴散處理。Figure 1B illustrates the diffusion process in which the time t = Δt begins to occur in a plastic pipe without an additional diffusion barrier.

第1C圖說明時間t=tc r i t i c a l 開始發生於無附加擴散屏障之塑膠管件中之擴散處理。Figure 1C illustrates the time t = t c r i t i c a l The diffusion process that begins in a plastic tube without an additional diffusion barrier.

第2A圖說明時間t=0開始發生於有附加擴散屏障之擴散處理。Figure 2A illustrates that time t = 0 begins to occur in a diffusion process with an additional diffusion barrier.

第2B圖說明時間t=△t開始發生於有附加擴散屏障之擴散處理。Figure 2B illustrates that time t = Δt begins to occur in the diffusion process with an additional diffusion barrier.

第2C圖說明時間t=tc r i t i c a l 開始發生於有附加擴散屏障之擴散處理。Figure 2C illustrates that the time t = t c r i t i c a l begins to occur in the diffusion process with an additional diffusion barrier.

第3圖說明本發明若干實施例之多層管件基本配置。Figure 3 illustrates the basic configuration of a multilayer tubular member in accordance with several embodiments of the present invention.

第4A圖說明本發明若干實施例之擴散屏障封帶層之一可能建構。Figure 4A illustrates the possible construction of one of the diffusion barrier sealing layers of several embodiments of the present invention.

第4B圖說明本發明若干實施例之擴散屏障封帶層之另一可能建構。Figure 4B illustrates another possible construction of a diffusion barrier encapsulation layer in accordance with several embodiments of the present invention.

第5圖係為本發明若干實施例之製造多層管件基本步驟流程圖。Figure 5 is a flow diagram of the basic steps in the manufacture of a multilayer tubular member in accordance with several embodiments of the present invention.

第6圖說明製造具有保護性包殼之香煙包覆多層擴散屏障封帶包覆管件之裝置。Figure 6 illustrates an apparatus for making a multi-layer diffusion barrier seal wrap tube having a protective envelope.

第7A圖係為旗幟被摺疊之前無外包殼之旗幟包覆管件透視圖。Figure 7A is a perspective view of the flagged tube fitting without the outer envelope before the flag is folded.

第7B圖係為旗幟被摺疊之前無外包殼之旗幟包覆管件一末端圖。Figure 7B is an end view of the flag-clad tube without the outer envelope before the flag is folded.

第7C圖係為旗幟被摺疊及包殼之後之旗幟包覆管件透視圖。Figure 7C is a perspective view of the flag-wrapped tube after the flag has been folded and enveloped.

第7D圖係為旗幟被摺疊之前無外包殼之旗幟包覆管件透視圖。The 7D image is a perspective view of the flagged tube fitting without the outer envelope before the flag is folded.

第7E圖係為旗幟被摺疊之前無外包殼之旗幟包覆管件一末端圖。Figure 7E is an end view of the flag-wrapped tube without the outer envelope before the flag is folded.

第7F圖係為旗幟被摺疊及包殼之後之旗幟包覆管件透視圖。Figure 7F is a perspective view of the flag-wrapped tube after the flag is folded and enveloped.

第8圖係為具有保護性包殼之螺旋包覆多層管件。Figure 8 is a spirally wrapped multi-layered tubular member having a protective cladding.

300...管件300. . . Pipe fittings

310...區域310. . . region

320...內管件層320. . . Inner tube layer

330...擴散屏障封帶層板或層330. . . Diffusion barrier sealing layer or layer

340...包殼層340. . . Shell layer

Claims (50)

一種實質密封管件,包含:一內管件,一擴散屏障材料,及至少兩熱塑膠材料層,其中一第一熱塑膠材料層係被施加至該擴散屏障材料的一第一側,而其中一第二熱塑膠材料層係被施加至該擴散屏障材料的一第二側,該第一熱塑膠材料層、該第二熱塑膠材料層及該擴散屏障材料係形成一擴散屏障封帶層板,而其中該擴散屏障封帶層板係與至該內管件外側耦合,而其中該擴散屏障封帶層板係實質該內管件全長地環繞該內管件的周圍,且其中該第一熱塑膠材料層及該第二熱塑膠材料層係被密封一起,而其中與該擴散屏障封帶層板耦合的該內管件係實質密封,其中該擴散屏障封帶層板非常完全地包圍該內管件周圍,及提供與該內管件長度平行的一擴散屏障封帶層板重疊狹條,且其中該擴散屏障封帶層板重疊狹條與擴散屏障封帶層板下方耦合,及繞著該內管件而密封該屏障封帶層板。 A substantially sealed tubular member comprising: an inner tubular member, a diffusion barrier material, and at least two layers of thermoplastic material, wherein a first layer of thermoplastic material is applied to a first side of the diffusion barrier material, and wherein the first a second layer of thermal plastic material is applied to a second side of the diffusion barrier material, the first layer of thermoplastic material, the layer of second thermoplastic material and the diffusion barrier material form a diffusion barrier sealing layer, and Wherein the diffusion barrier sealing layer is coupled to the outer side of the inner tubular member, and wherein the diffusion barrier sealing layer is substantially integral around the inner tubular member, and wherein the first thermoplastic material layer and The second layer of thermoplastic material is sealed together, and wherein the inner tube coupled to the diffusion barrier sealing layer is substantially sealed, wherein the diffusion barrier sealing sheet surrounds the inner tube very completely and provides a diffusion barrier sealing strip parallel to the inner tube length overlapping the strip, and wherein the diffusion barrier sealing strip overlapping strip is coupled below the diffusion barrier sealing layer and around the inner The barrier member is sealed with a sealing lamina. 如申請專利範圍第1項的實質密封管件,其中該內管件係由選自包含聚烯烴;經修飾的聚烯烴;氟塑料;聚醯胺;聚酯;乙烯基樹脂;以烯烴、聚丁二烯、聚酯、苯乙烯及乙烯基化學元素為基礎之熱塑彈性體;如丁基的彈性體;聚異丁烯(PIB);三元乙丙膠(EPDM);NBR;SBR及鉑加工或過氧化物加工矽樹脂橡膠之一組的材料製成。 The substantially sealed pipe member of claim 1, wherein the inner pipe member is selected from the group consisting of polyolefins; modified polyolefin; fluoroplastic; polyamine; polyester; vinyl resin; Thermoplastic elastomer based on olefin, polyester, styrene and vinyl chemical elements; elastomer such as butyl; polyisobutylene (PIB); EPDM; NBR; SBR and platinum processing or The oxide is processed from a group of materials of a resin rubber. 如申請專利範圍第1項的實質密封管件,其中該擴散屏障材料係為鋁箔。 The substantially sealed tubular member of claim 1, wherein the diffusion barrier material is an aluminum foil. 如申請專利範圍第1項的實質密封管件,其中該擴散屏障材料係為聚醯胺。 The substantially sealed tubular member of claim 1, wherein the diffusion barrier material is polyamine. 如申請專利範圍第1項的實質密封管件,其中當各熱塑膠材料層與該內管件接觸並以熱及壓力處理時係經配置以提供與該內管件的強密封。 The substantially sealed tubular member of claim 1, wherein each of the layers of thermoplastic material is configured to provide a strong seal with the inner tubular member when it is in contact with the inner tubular member and is treated with heat and pressure. 如申請專利範圍第1項的實質密封管件,其中該擴散屏障封帶層板並不密封至該內管件,其中該內管件可於該擴散屏障封帶層板內滑動。 The substantially sealed tubular member of claim 1, wherein the diffusion barrier sealing laminate is not sealed to the inner tubular member, wherein the inner tubular member is slidable within the diffusion barrier sealing laminate. 如申請專利範圍第1項的實質密封管件,其中該擴散屏障材料的多層係於該至少兩熱塑膠層之間分層。 The substantially sealed tubular member of claim 1, wherein the plurality of layers of the diffusion barrier material are layered between the at least two thermoplastic layers. 如申請專利範圍第1項的實質密封管件,其中一黏著劑係用以將一熱塑膠層連結至一擴散屏障材料層。 A substantially sealed tubular member of claim 1, wherein an adhesive is used to bond a layer of thermoplastic material to a layer of diffusion barrier material. 如申請專利範圍第1項的實質密封管件,其中該第一熱塑膠材料層及該第二熱塑膠材料層係使用一突出處理而直接突出於該擴散屏障材料上。 The substantially sealed tubular member of claim 1, wherein the first layer of thermoplastic material and the second layer of thermoplastic material directly protrude from the diffusion barrier material using a protrusion treatment. 如申請專利範圍第1項的實質密封管件,其中該第一熱塑膠材料層及該第二熱塑膠材料層係使用一層板處理而直接突出於該擴散屏障材料上。 The substantially sealed tube member of claim 1, wherein the first layer of thermoplastic material and the layer of the second layer of thermoplastic material directly adhere to the diffusion barrier material by using a layer of a sheet. 如申請專利範圍第1項的實質密封管件,其中該第一熱塑膠材料層及該第二熱塑膠材料層係使用一壓光處理被連結至該擴散屏障材料。 The substantially sealed tubular member of claim 1, wherein the first layer of thermoplastic material and the second layer of thermoplastic material are bonded to the diffusion barrier material using a calendering process. 如申請專利範圍第1項的實質密封管件,其中耦合至該 擴散屏障封帶層板之該熱塑膠層係為低密度聚乙烯。 The substantially sealed tubular member of claim 1, wherein the coupling is The thermoplastic layer of the diffusion barrier sealing laminate is a low density polyethylene. 如申請專利範圍第1項的實質密封管件,其中與該內管件長度平行的該擴散屏障封帶層板重疊狹條的一重疊比率範圍係該內管件周圍約百分之十至約百分之二十五。 The substantially sealed tubular member of claim 1, wherein an overlapping ratio of the diffusion barrier sealing strip overlapping strips parallel to the length of the inner tubular member is about 10% to about 10% around the inner tubular member twenty five. 如申請專利範圍第1項的實質密封管件,進一步包含一包殼層,其中該包殼層覆蓋該擴散屏障封帶層板。 The substantially sealed tubular member of claim 1, further comprising a cladding layer, wherein the cladding layer covers the diffusion barrier sealing laminate. 如申請專利範圍第14項的實質密封管件,其中該包殼層係為一聚合物。 The substantially sealed tubular member of claim 14, wherein the cladding layer is a polymer. 如申請專利範圍第14項的實質密封管件,其中該包殼層係使用一突出處理所施加。 The substantially sealed tubular member of claim 14, wherein the cladding layer is applied using a protrusion treatment. 如申請專利範圍第14項的實質密封管件,其中該包殼層係使用一熱收縮處理所施加。 The substantially sealed tubular member of claim 14, wherein the cladding layer is applied using a heat shrinking treatment. 如申請專利範圍第14項的實質密封管件,其中該包殼的一厚度範圍係從0.5微米至十五微米。 The substantially sealed tubular member of claim 14, wherein the cladding has a thickness ranging from 0.5 micrometers to fifteen micrometers. 一種經執行做為一線內及連續處理的實質密封管件製造方法,包含步驟為:提供一擴散屏障材料;施加一第一熱塑膠材料層至該擴散屏障材料的一側;施加一第二熱塑膠材料層至該擴散屏障材料的另一側;饋送一擴散屏障封帶層板至一第一包覆器裝置,饋送一內管件至該第一包覆器裝置,以該擴散屏障封帶層板包覆該內管件,其中形成一重疊擴散屏障封帶層板線縫,饋送該擴散屏障封帶層板包覆的內管件至一第一密封器裝 置;及密封該重疊擴散屏障封帶層板線縫。 A method for manufacturing a substantially sealed tubular member that is implemented as a one-line and continuous treatment, comprising the steps of: providing a diffusion barrier material; applying a first layer of thermoplastic material to one side of the diffusion barrier material; applying a second thermoplastic a material layer to the other side of the diffusion barrier material; feeding a diffusion barrier sealing laminate to a first cladding device, feeding an inner tubular member to the first cladding device, and the diffusion barrier sealing layer Coating the inner tubular member, wherein an overlapping diffusion barrier sealing layer seam is formed, and the inner tubular member covered by the diffusion barrier sealing layer is fed to a first sealing device And sealing the overlapping diffusion barrier sealing layer plate seam. 如申請專利範圍第19項的方法,其中該內管件係經由該第一包覆器裝置上游的一管件突出處理且於饋送該內管件至該第一包覆器裝置之前形成。 The method of claim 19, wherein the inner tubular member is protruded through a tubular member upstream of the first cladding device and formed prior to feeding the inner tubular member to the first cladding device. 如申請專利範圍第19項的方法,其中該擴散屏障封帶層板係從該第一包覆器裝置上游且於饋送該擴散屏障封帶層板至該第一包覆器裝置之前形成。 The method of claim 19, wherein the diffusion barrier sealing layer is formed upstream of the first cladding device and prior to feeding the diffusion barrier sealing laminate to the first cladding device. 如申請專利範圍第19項的方法,其中一黏著連結層係被用來連結該第一熱塑膠材料層及該第二熱塑膠材料層至該擴散屏障材料。 The method of claim 19, wherein an adhesive bonding layer is used to join the first thermoplastic material layer and the second thermoplastic material layer to the diffusion barrier material. 如申請專利範圍第19項的方法,其中各熱塑膠層係使用一壓力突出處理而突出於該擴散屏障材料上。 The method of claim 19, wherein each of the thermoplastic layers is protruded from the diffusion barrier material using a pressure protrusion treatment. 如申請專利範圍第19項的方法,其中該熱塑膠係為低密度聚乙烯。 The method of claim 19, wherein the thermoplastic is a low density polyethylene. 如申請專利範圍第19項的方法,其中該擴散屏障材料係為鋁箔。 The method of claim 19, wherein the diffusion barrier material is an aluminum foil. 如申請專利範圍第19項的方法,其中該擴散屏障材料係為聚醯胺。 The method of claim 19, wherein the diffusion barrier material is polyamine. 如申請專利範圍第19項的方法,其中擴散屏障材料的多層係於該熱塑膠層之間分層。 The method of claim 19, wherein the plurality of layers of the diffusion barrier material are layered between the layers of the thermoplastic layer. 如申請專利範圍第19項的方法,該密封包含:導引該擴散屏障封帶層板包覆的內管件至一對滾輪,其中加熱至少一滾輪,其中該被加熱的滾輪係經配置以提供熱 及壓力至進入的擴散屏障封帶層板包覆的內管件。 The method of claim 19, the sealing comprising: guiding the inner tubular member covered by the diffusion barrier sealing layer to a pair of rollers, wherein at least one roller is heated, wherein the heated roller is configured to provide heat And the inner tube member coated with the pressure to the incoming diffusion barrier sealing strip. 如申請專利範圍第19項的方法,其中被導引至該包覆器的該擴散屏障封帶層板係較該內管件周圍寬,其中該包覆器裝置係繞著該內管件包覆該擴散屏障封帶,使得與該內管件長度平行的一擴散屏障封帶層板重疊狹條形成該擴散屏障封帶層板線縫。 The method of claim 19, wherein the diffusion barrier sealing layer plate guided to the wrapper is wider than the inner tubular member, wherein the wrapper device wraps around the inner tubular member Diffusion barrier encapsulation such that a diffusion barrier enveloping laminate sheet parallel to the length of the inner tubular member overlaps the strip to form the diffusion barrier enveloping laminate seam. 如申請專利範圍第29項的方法,其中該擴散屏障材料狹條至少為一微米。 The method of claim 29, wherein the diffusion barrier material strip is at least one micron. 如申請專利範圍第19項的方法,其中被導引至該包覆器裝置的該擴散屏障封帶層板係較該內管件周圍寬,其中該包覆器裝置係繞著該內管件包覆該擴散屏障封帶,使得該擴散屏障封帶層板的一超出寬度於該內管件上的一點處得到滿足,並從此垂直延伸,形成從該內管件上該一點垂直延伸且彼此實質平行的一旗幟,其中該旗幟形成該擴散屏障封帶層板線縫。 The method of claim 19, wherein the diffusion barrier sealing layer plate guided to the wrapper device is wider than the inner tubular member, wherein the wrapper device is wrapped around the inner tubular member The diffusion barrier encapsulation is such that an extent of the diffusion barrier enveloping laminate that is beyond the width of the inner tubular member is satisfied and extends vertically therefrom to form a vertical extension from the point on the inner tubular member and substantially parallel to each other a flag, wherein the flag forms a seam of the diffusion barrier seal layer. 如申請專利範圍第31項的方法,其中該密封的垂直延伸旗幟係向下摺回至該內管件周圍的一側上。 The method of claim 31, wherein the sealed vertically extending flag is folded back down to a side around the inner tubular member. 如申請專利範圍第32項的方法,其中向下摺回至該內管件周圍的該旗幟長度其介於1微米及20微米之間。 The method of claim 32, wherein the length of the flag folded back down to the inner tubular member is between 1 micrometer and 20 micrometers. 如申請專利範圍第32項的方法,其中該密封垂直延伸旗幟係被裁修為線內部分及連續處理。 The method of claim 32, wherein the sealed vertical extension banner is cut into an in-line portion and continuously processed. 如申請專利範圍第19項的方法,其中該包覆器裝置係以一螺旋方式以該擴散屏障封帶層板繞著該內管線周圍而包覆該內管件,其中該擴散屏障封帶層板在向下纏繞該內 管件長度時本身部分重疊,其中該重疊區域係形成該擴散屏障封帶層板線縫。 The method of claim 19, wherein the applicator device coats the inner tube member around the inner tube with the diffusion barrier sealing layer in a spiral manner, wherein the diffusion barrier sealing layer sheet Winding down inside The length of the tubular members themselves partially overlaps, wherein the overlapping regions form the diffusion barrier seal layer plate seam. 如申請專利範圍第35項的方法,其中該重疊區域的重疊百分比範圍為該擴散屏障封帶層板寬度約百分之十至約百分之五十五。 The method of claim 35, wherein the overlap percentage of the overlap region ranges from about ten percent to about fifty percent of the width of the diffusion barrier seal laminate. 如申請專利範圍第19項的方法,其中該第一密封器裝置可藉由施加熱及壓力至該擴散屏障封帶層板重疊來密封該擴散屏障封帶層板重疊。 The method of claim 19, wherein the first sealer device seals the diffusion barrier seal laminate overlap by applying heat and pressure to the diffusion barrier seal laminate overlap. 如申請專利範圍第19項的方法,進一步包含步驟為:導引至少一附加擴散屏障封帶板層至至少一附加包覆器裝置,其中各包覆器裝置之後跟著一附加密封器裝置;從該第一包覆器裝置將由該擴散屏障封帶層板至少包覆一次之內管件及藉由該第一密封器裝置至少密封一次導引至該至少一附加包覆器;以該至少一附加擴散屏障封帶板層包覆該至少一次包覆及密封的內管件,其中係形成一至少兩次包覆的內管件及一至少一附加擴散屏障封帶線縫;導引該至少兩次包覆的內管件至該至少一附加密封器;及密封該至少一附加擴散屏障封帶線縫。 The method of claim 19, further comprising the step of: guiding at least one additional diffusion barrier sealing strip layer to at least one additional wrapper device, wherein each wrapper device is followed by an additional sealer device; The first applicator device guides the inner tubular member covered by the diffusion barrier sealing layer at least once and at least once by the first sealing device to the at least one additional covering device; The diffusion barrier sealing strip layer covers the at least one coated and sealed inner tubular member, wherein at least two coated inner tubular members and at least one additional diffusion barrier sealing seam are formed; guiding the at least two packages Covering the inner tubular member to the at least one additional seal; and sealing the at least one additional diffusion barrier sealing seam. 如申請專利範圍第38項的方法,其中這些步驟係以一線內及連續方式執行。 The method of claim 38, wherein the steps are performed in a one-line and continuous manner. 如申請專利範圍第19項的方法,進一步包含:導引該擴散屏障封帶層板包覆及密封的內管件至一包殼裝置;及 包殼該擴散屏障封帶層板包覆及密封的內管件,其中該包殼發生於該線內及連續處理的最後步驟時。 The method of claim 19, further comprising: guiding the inner tubular member covered and sealed by the diffusion barrier sealing layer to a cladding device; The inner tubular member is coated and sealed by the diffusion barrier sealing layer, wherein the cladding occurs in the line and in the final step of continuous processing. 如申請專利範圍第40項的方法,其中包殼是藉由一壓力突出處理所完成。 The method of claim 40, wherein the cladding is completed by a pressure protrusion process. 如申請專利範圍第40項的方法,其中包殼是藉由一半壓力突出處理所完成。 The method of claim 40, wherein the cladding is completed by a half pressure protrusion process. 如申請專利範圍第40項的方法,其中該內管件及該擴散屏障板層係於包殼期間藉由熱施加而進一步連結在一起,而其中該擴散屏障層板之熱塑膠曝光側係藉由包殼而連結在一起。 The method of claim 40, wherein the inner tube member and the diffusion barrier layer are further joined together by heat application during the encapsulation, wherein the thermal plastic exposure side of the diffusion barrier layer is Encased and joined together. 如申請專利範圍第19項的方法,進一步包含:導引該擴散屏障封帶層板包覆及密封的內管件至一包殼裝置;及包殼該擴散屏障封帶層板包覆及密封的內管件,其中包殼是藉由一片段熱收縮處理所完成。 The method of claim 19, further comprising: guiding the inner tubular member covered and sealed by the diffusion barrier sealing layer to a cladding device; and encapsulating and diffusing the diffusion barrier sealing layer The inner tube member, wherein the cladding is completed by a heat shrinkage treatment of a segment. 一種實質密封管件,包含:一內管件,以及一擴散屏障封帶層板實質上密封地耦合至該內管件外側周圍實質上該內管件的全長,包含:一擴散屏障材料;一第一熱塑膠材料層被施加至該擴散屏障材料的一第一側;一第二熱塑膠材料層被施加至該擴散屏障材料的一第二側;以及該第一熱塑膠材料層及該第二熱塑膠材料層係被密 封一起;其中該擴散屏障封帶層板並不密封至該內管件,其中該內管件可於該擴散屏障封帶層板內滑動。 A substantially sealed tubular member comprising: an inner tubular member, and a diffusion barrier sealing strip substantially substantially sealingly coupled to the outer side of the inner tubular member substantially the entire length of the inner tubular member, comprising: a diffusion barrier material; a first thermoplastic a layer of material is applied to a first side of the diffusion barrier material; a second layer of thermoplastic material is applied to a second side of the diffusion barrier material; and the first layer of thermoplastic material and the second thermoplastic material Layer is dense The seal together; wherein the diffusion barrier sealing laminate is not sealed to the inner tubular member, wherein the inner tubular member is slidable within the diffusion barrier sealing laminate. 一種實質密封管件,包含:一內管件,以及一擴散屏障封帶層板實質上密封地耦合至該內管件外側周圍實質上該內管件的全長,包含:一擴散屏障材料;一第一熱塑膠材料層被施加至該擴散屏障材料的一第一側;一第二熱塑膠材料層被施加至該擴散屏障材料的一第二側;以及該第一熱塑膠材料層及該第二熱塑膠材料層係被密封一起;其中耦合於該擴散屏障封帶層板之該等熱塑膠層係為低密度聚乙烯。 A substantially sealed tubular member comprising: an inner tubular member, and a diffusion barrier sealing strip substantially substantially sealingly coupled to the outer side of the inner tubular member substantially the entire length of the inner tubular member, comprising: a diffusion barrier material; a first thermoplastic a layer of material is applied to a first side of the diffusion barrier material; a second layer of thermoplastic material is applied to a second side of the diffusion barrier material; and the first layer of thermoplastic material and the second thermoplastic material The layers are sealed together; wherein the thermoplastic layers coupled to the diffusion barrier sealing ply are low density polyethylene. 一種實質密封管件,包含:一內管件,以及一擴散屏障封帶層板實質上密封地耦合至該內管件外側周圍實質上該內管件的全長,包含:一擴散屏障材料;一第一熱塑膠材料層被施加至該擴散屏障材料的一第一側;一第二熱塑膠材料層被施加至該擴散屏障材料的一 第二側;以及該第一熱塑膠材料層及該第二熱塑膠材料層係被密封一起;其中該擴散屏障封帶層板係較該內管件周圍寬,其中該擴散屏障封帶層板的一超出寬度可於該內管件的一點處滿足,並由此垂直延伸,創造兩垂直延伸旗幟,而其中一密封存在於該垂直延伸旗幟之間。 A substantially sealed tubular member comprising: an inner tubular member, and a diffusion barrier sealing strip substantially substantially sealingly coupled to the outer side of the inner tubular member substantially the entire length of the inner tubular member, comprising: a diffusion barrier material; a first thermoplastic a layer of material is applied to a first side of the diffusion barrier material; a second layer of thermoplastic material is applied to the diffusion barrier material a second side; and the first layer of thermoplastic material and the second layer of thermoplastic material are sealed together; wherein the diffusion barrier sealing layer is wider than the circumference of the inner tube, wherein the diffusion barrier seals the laminate An excess width is satisfied at one point of the inner tubular member and thereby extends vertically to create two vertically extending flags, one of which is present between the vertically extending flags. 如申請專利範圍第47項的實質密封管件,其中該密封垂直延伸旗幟係向下摺回至該內管件周圍的一側上。 The substantially sealed tubular member of claim 47, wherein the sealed vertically extending flag is folded back down to a side around the inner tubular member. 如申請專利範圍第48項的實質密封管件,其中該旗幟的長度範圍介於1微米及20微米之間。 The substantially sealed tubular member of claim 48, wherein the flag has a length ranging between 1 micrometer and 20 micrometers. 一種實質密封管件,包含:一內管件,以及一擴散屏障封帶層板實質上密封地耦合至該內管件外側周圍實質上該內管件的全長,包含:一擴散屏障材料;一第一熱塑膠材料層被施加至該擴散屏障材料的一第一側;一第二熱塑膠材料層被施加至該擴散屏障材料的一第二側;以及該第一熱塑膠材料層及該第二熱塑膠材料層係被密封一起;其中該擴散屏障封帶層板係以一螺旋方式纏繞該內管件周圍,其中該擴散屏障封帶在向下纏繞該內管件長度時本身 部分重疊且被配置一重疊區域,其中該重疊屏障封帶層板係繞著該內管件而密封該屏障封帶層板,以及其中擴散屏障封帶層板的一附加層係繞著一次包覆內管件而反向纏繞。 A substantially sealed tubular member comprising: an inner tubular member, and a diffusion barrier sealing strip substantially substantially sealingly coupled to the outer side of the inner tubular member substantially the entire length of the inner tubular member, comprising: a diffusion barrier material; a first thermoplastic a layer of material is applied to a first side of the diffusion barrier material; a second layer of thermoplastic material is applied to a second side of the diffusion barrier material; and the first layer of thermoplastic material and the second thermoplastic material The layer is sealed together; wherein the diffusion barrier sealing layer is wound around the inner tubular member in a spiral manner, wherein the diffusion barrier sealing tape is wound downwardly around the length of the inner tubular member Partially overlapping and configured with an overlapping region, wherein the overlapping barrier sealing layer seals the barrier sealing laminate around the inner tubular member, and wherein an additional layer of the diffusion barrier sealing laminate is wrapped around the coating The inner tube is wound in the opposite direction.
TW096103430A 2006-01-30 2007-01-30 Tape-wrapped multilayer tubing and methods making the same TWI457513B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2600103A (en) * 1948-02-19 1952-06-10 Feck John Franz Means for absorbing ice pressure
US5362530A (en) * 1990-09-26 1994-11-08 The Yokohama Rubber Co., Ltd. Gas-and-oil impermeable hose construction
US6213156B1 (en) * 1998-12-16 2001-04-10 Tokai Rubber Industries, Ltd. Hose for refrigerant for an electrically driven compressor
US6237614B1 (en) * 1999-04-05 2001-05-29 Dale Retter Retractable vehicle wash system
US6988515B2 (en) * 2002-08-30 2006-01-24 The Yokohama Rubber Co., Ltd. Ultra-low permeation hose and method of manufacture

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2600103A (en) * 1948-02-19 1952-06-10 Feck John Franz Means for absorbing ice pressure
US5362530A (en) * 1990-09-26 1994-11-08 The Yokohama Rubber Co., Ltd. Gas-and-oil impermeable hose construction
US6213156B1 (en) * 1998-12-16 2001-04-10 Tokai Rubber Industries, Ltd. Hose for refrigerant for an electrically driven compressor
US6237614B1 (en) * 1999-04-05 2001-05-29 Dale Retter Retractable vehicle wash system
US6988515B2 (en) * 2002-08-30 2006-01-24 The Yokohama Rubber Co., Ltd. Ultra-low permeation hose and method of manufacture

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