TWI400198B - 殺生物劑及裝置 - Google Patents
殺生物劑及裝置 Download PDFInfo
- Publication number
- TWI400198B TWI400198B TW094101192A TW94101192A TWI400198B TW I400198 B TWI400198 B TW I400198B TW 094101192 A TW094101192 A TW 094101192A TW 94101192 A TW94101192 A TW 94101192A TW I400198 B TWI400198 B TW I400198B
- Authority
- TW
- Taiwan
- Prior art keywords
- biocide
- medium
- group
- hypochlorite
- variations
- Prior art date
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- 230000003115 biocidal effect Effects 0.000 title claims description 416
- 239000003139 biocide Substances 0.000 title claims description 411
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 368
- -1 alkaline earth metal hypochlorite Chemical class 0.000 claims description 159
- 239000007800 oxidant agent Substances 0.000 claims description 144
- 239000000460 chlorine Substances 0.000 claims description 142
- 238000002156 mixing Methods 0.000 claims description 131
- 229910052801 chlorine Inorganic materials 0.000 claims description 117
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 116
- 150000003839 salts Chemical class 0.000 claims description 100
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 97
- 238000000034 method Methods 0.000 claims description 93
- 239000000243 solution Substances 0.000 claims description 80
- 230000001590 oxidative effect Effects 0.000 claims description 74
- 239000000203 mixture Substances 0.000 claims description 55
- 244000005700 microbiome Species 0.000 claims description 54
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 52
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 46
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 34
- 239000003085 diluting agent Substances 0.000 claims description 31
- 239000007864 aqueous solution Substances 0.000 claims description 29
- 230000015572 biosynthetic process Effects 0.000 claims description 28
- 229920002472 Starch Polymers 0.000 claims description 20
- 235000019698 starch Nutrition 0.000 claims description 20
- 239000008107 starch Substances 0.000 claims description 19
- 239000002351 wastewater Substances 0.000 claims description 19
- 238000010790 dilution Methods 0.000 claims description 16
- 239000012895 dilution Substances 0.000 claims description 16
- 238000011065 in-situ storage Methods 0.000 claims description 13
- 239000000725 suspension Substances 0.000 claims description 13
- 239000011833 salt mixture Substances 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 239000010802 sludge Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 239000003621 irrigation water Substances 0.000 claims description 9
- 239000002689 soil Substances 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 6
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 5
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 claims description 5
- YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 claims description 5
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 claims description 5
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical group ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims description 4
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 4
- 230000033116 oxidation-reduction process Effects 0.000 claims description 3
- UWMJRBYGKZOPCC-UHFFFAOYSA-N 1-chloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)NC1=O UWMJRBYGKZOPCC-UHFFFAOYSA-N 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims 4
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims 2
- 239000002609 medium Substances 0.000 description 222
- 125000000217 alkyl group Chemical group 0.000 description 104
- 238000012360 testing method Methods 0.000 description 101
- 230000000813 microbial effect Effects 0.000 description 78
- 125000000753 cycloalkyl group Chemical group 0.000 description 60
- 125000003118 aryl group Chemical group 0.000 description 55
- 229910052757 nitrogen Inorganic materials 0.000 description 48
- 125000004433 nitrogen atom Chemical group N* 0.000 description 47
- 125000003342 alkenyl group Chemical group 0.000 description 41
- 125000000392 cycloalkenyl group Chemical group 0.000 description 41
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 description 40
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 40
- 230000009467 reduction Effects 0.000 description 39
- 125000000304 alkynyl group Chemical group 0.000 description 36
- 229910052739 hydrogen Inorganic materials 0.000 description 34
- 229910052736 halogen Inorganic materials 0.000 description 33
- 150000002367 halogens Chemical class 0.000 description 33
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 31
- 125000000623 heterocyclic group Chemical group 0.000 description 31
- 229910052799 carbon Inorganic materials 0.000 description 29
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 29
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 28
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 28
- 125000001072 heteroaryl group Chemical group 0.000 description 28
- 229910052760 oxygen Inorganic materials 0.000 description 28
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 28
- 150000003141 primary amines Chemical class 0.000 description 27
- 125000000129 anionic group Chemical group 0.000 description 21
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 21
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 19
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 19
- 150000003512 tertiary amines Chemical class 0.000 description 19
- 230000002596 correlated effect Effects 0.000 description 18
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 17
- 125000004122 cyclic group Chemical group 0.000 description 17
- 239000002253 acid Substances 0.000 description 16
- 239000002585 base Substances 0.000 description 16
- 150000003335 secondary amines Chemical class 0.000 description 16
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 15
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 15
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 125000005842 heteroatom Chemical group 0.000 description 14
- 239000003574 free electron Substances 0.000 description 13
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 12
- 125000000565 sulfonamide group Chemical group 0.000 description 12
- 229910019093 NaOCl Inorganic materials 0.000 description 11
- 125000004151 quinonyl group Chemical group 0.000 description 11
- 230000002407 ATP formation Effects 0.000 description 10
- 102000016938 Catalase Human genes 0.000 description 10
- 108010053835 Catalase Proteins 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 10
- 230000000875 corresponding effect Effects 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- ZDZGIEOXEZDPPG-UHFFFAOYSA-N azane;ethyl carbamate Chemical compound N.CCOC(N)=O ZDZGIEOXEZDPPG-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229940124530 sulfonamide Drugs 0.000 description 9
- 150000003456 sulfonamides Chemical class 0.000 description 9
- 108091006112 ATPases Proteins 0.000 description 8
- 102000057290 Adenosine Triphosphatases Human genes 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 150000004060 quinone imines Chemical class 0.000 description 8
- QDWYPRSFEZRKDK-UHFFFAOYSA-M sodium;sulfamate Chemical compound [Na+].NS([O-])(=O)=O QDWYPRSFEZRKDK-UHFFFAOYSA-M 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 7
- DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 7
- 150000002466 imines Chemical class 0.000 description 7
- 125000006649 (C2-C20) alkynyl group Chemical group 0.000 description 6
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 6
- 239000004475 Arginine Substances 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 6
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 6
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 6
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 6
- 239000004472 Lysine Substances 0.000 description 6
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 6
- 229940100389 Sulfonylurea Drugs 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000001099 ammonium carbonate Substances 0.000 description 6
- 235000012501 ammonium carbonate Nutrition 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 6
- 235000011130 ammonium sulphate Nutrition 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 6
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 6
- CVSVTCORWBXHQV-UHFFFAOYSA-N creatine Chemical compound NC(=[NH2+])N(C)CC([O-])=O CVSVTCORWBXHQV-UHFFFAOYSA-N 0.000 description 6
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 5
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 5
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 229910052794 bromium Inorganic materials 0.000 description 5
- 125000001309 chloro group Chemical group Cl* 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 239000004220 glutamic acid Substances 0.000 description 5
- 235000013922 glutamic acid Nutrition 0.000 description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 5
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- YIROYDNZEPTFOL-UHFFFAOYSA-N 5,5-Dimethylhydantoin Chemical compound CC1(C)NC(=O)NC1=O YIROYDNZEPTFOL-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 4
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 3
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 description 3
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical compound C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229910001513 alkali metal bromide Inorganic materials 0.000 description 3
- 229910001616 alkaline earth metal bromide Inorganic materials 0.000 description 3
- 239000001166 ammonium sulphate Substances 0.000 description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000001332 colony forming effect Effects 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 229960003624 creatine Drugs 0.000 description 3
- 239000006046 creatine Substances 0.000 description 3
- 229940109239 creatinine Drugs 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229960002317 succinimide Drugs 0.000 description 3
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 2
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241001148470 aerobic bacillus Species 0.000 description 2
- 150000003842 bromide salts Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
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- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- 241000220479 Acacia Species 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
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- 239000002028 Biomass Substances 0.000 description 1
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- 101100294106 Caenorhabditis elegans nhr-3 gene Proteins 0.000 description 1
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- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 1
- ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 description 1
- 235000010643 Leucaena leucocephala Nutrition 0.000 description 1
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000002355 alkine group Chemical group 0.000 description 1
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910001622 calcium bromide Inorganic materials 0.000 description 1
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- BTUYOSMJKPGOSS-UHFFFAOYSA-N chlorocarbamic acid Chemical compound OC(=O)NCl BTUYOSMJKPGOSS-UHFFFAOYSA-N 0.000 description 1
- OGQPUOLFKIMRMF-UHFFFAOYSA-N chlorosulfamic acid Chemical compound OS(=O)(=O)NCl OGQPUOLFKIMRMF-UHFFFAOYSA-N 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 description 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002458 infectious effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- AOLZTIVILVSYPO-UHFFFAOYSA-N methyl n-methyl-n-(1-methylbenzimidazol-2-yl)carbamate Chemical compound C1=CC=C2N(C)C(N(C)C(=O)OC)=NC2=C1 AOLZTIVILVSYPO-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000003419 tautomerization reaction Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/685—Devices for dosing the additives
- C02F1/686—Devices for dosing liquid additives
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/04—Oxidation reduction potential [ORP]
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53685104P | 2004-01-14 | 2004-01-14 | |
| US53685304P | 2004-01-14 | 2004-01-14 | |
| US53685204P | 2004-01-14 | 2004-01-14 | |
| US53681104P | 2004-01-14 | 2004-01-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200540123A TW200540123A (en) | 2005-12-16 |
| TWI400198B true TWI400198B (zh) | 2013-07-01 |
Family
ID=34799814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094101192A TWI400198B (zh) | 2004-01-14 | 2005-01-14 | 殺生物劑及裝置 |
Country Status (15)
| Country | Link |
|---|---|
| US (7) | US8632794B2 (enExample) |
| EP (1) | EP1711057B1 (enExample) |
| JP (1) | JP4705044B2 (enExample) |
| CN (1) | CN101151219B (enExample) |
| AU (1) | AU2005204492B2 (enExample) |
| CA (1) | CA2553323C (enExample) |
| DK (1) | DK1711057T3 (enExample) |
| ES (1) | ES2609682T3 (enExample) |
| HU (1) | HUE031510T2 (enExample) |
| NZ (1) | NZ548967A (enExample) |
| PL (1) | PL1711057T3 (enExample) |
| PT (1) | PT1711057T (enExample) |
| SI (1) | SI1711057T1 (enExample) |
| TW (1) | TWI400198B (enExample) |
| WO (1) | WO2005067380A2 (enExample) |
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| US7052614B2 (en) * | 2001-08-06 | 2006-05-30 | A.Y. Laboratories Ltd. | Control of development of biofilms in industrial process water |
| SI1711057T1 (sl) | 2004-01-14 | 2017-01-31 | A.Y. Laboratories Ltd | Biocidi |
| US20090311164A1 (en) * | 2006-12-29 | 2009-12-17 | Amit Gupta | Method for producing a stable oxidizing biocide |
| US20090242484A1 (en) * | 2008-04-01 | 2009-10-01 | Ana-Mariana Urmenyi | Environmentally friendly hybrid microbiological control technologies for cooling towers |
| CA2725204C (en) * | 2008-05-23 | 2016-04-19 | Kemira Oyj | Chemistry for effective microbe control with reduced gas phase corrosiveness in pulp & paper processing systems |
| CN101658183B (zh) * | 2008-08-29 | 2013-07-31 | 杜志刚 | 一种用于建筑内墙的除霉防霉剂 |
| EP2480719A1 (en) | 2009-09-22 | 2012-08-01 | SONOCO Development Inc. | Paperboard containing a biocide and method for making the same |
| CN103339317B (zh) * | 2011-01-24 | 2016-01-20 | 隆萨公司 | 使用氧化剂在还原条件下进行微生物控制的方法 |
| JP5835967B2 (ja) * | 2011-06-29 | 2015-12-24 | 伯東株式会社 | スライム剥離剤およびスライム剥離方法 |
| CN102402185B (zh) * | 2011-11-03 | 2013-06-12 | 北京林业大学 | 基于模糊控制的非充分灌溉控制方法 |
| US20130313474A1 (en) * | 2012-05-23 | 2013-11-28 | The Clorox Company | Alkali metal monochloro (alkali metal) sulfamate compositions |
| LT3357870T (lt) * | 2013-02-07 | 2022-08-25 | A.Y. Laboratories Ltd. | Biocido gamybos būdas ir aparatas |
| CN103636673A (zh) * | 2013-12-10 | 2014-03-19 | 山东农业大学 | 一种塑料管道疏通剂及其制备方法 |
| US10850999B2 (en) | 2015-04-24 | 2020-12-01 | Ecolab Usa Inc. | Submergible biocide reactor and method |
| US10793451B2 (en) | 2015-06-30 | 2020-10-06 | Bulk Chemical Services, LLC. | Method for treating water used in oil field applications to inhibit bacterial growth with methylammonium monomethyldithiocarbamate |
| EP3697213A4 (en) | 2017-10-18 | 2021-07-21 | Solenis Technologies, L.P. | COMPOSITIONS PRESENTING A SYNERGY IN THE FIGHT AGAINST BIOFILMS |
| CN111726988B (zh) | 2017-10-18 | 2022-10-14 | 索理思科技公司 | 在生物膜控制中表现出协同作用的组合物 |
| JP7064267B2 (ja) * | 2018-03-28 | 2022-05-10 | アクアス株式会社 | 薬液の添加方法 |
| HRP20230453T1 (hr) * | 2018-06-13 | 2023-09-01 | A.Y. Laboratories Ltd. | Sustav i metoda za praćenje proizvodne vode tretirane biocidom pomoću senzora za kisik |
| US12072279B2 (en) * | 2018-11-27 | 2024-08-27 | Kemira Oyj | Method for estimating the vapor phase corrosion load |
| US11812741B2 (en) | 2019-07-01 | 2023-11-14 | A.Y. Laboratories Ltd. | Method for producing a biocide |
| SG11202113128PA (en) | 2019-07-08 | 2021-12-30 | A Y Lab Ltd | Process for producing a solution of ammonium carbamate |
| EP4054338A4 (en) * | 2019-11-06 | 2023-12-06 | De Nora Holdings US, Inc. | CONTROLLED PRODUCTION OF AQUEOUS HALOGEN SOLUTIONS WITH VARIABLE COMPOSITIONS |
| BR112023004105A2 (pt) | 2020-09-04 | 2023-04-04 | Buckman Laboratories Int Inc | Método para otimização de dosagem para uma unidade de alimentação química e sistema para otimização de dosagem em uma unidade de alimentação química |
| JP7633701B2 (ja) * | 2022-11-02 | 2025-02-20 | 株式会社マツバラ | 消毒剤 |
| JP2024103040A (ja) * | 2023-01-20 | 2024-08-01 | 栗田工業株式会社 | 処理方法 |
| EP4477090A1 (en) | 2023-06-13 | 2024-12-18 | Solenis Technologies Cayman, L.P. | Method for controlling microbiological growth in sterilizer and pasteurizer applications using monochloramine |
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| US5976386A (en) * | 1994-10-03 | 1999-11-02 | A.Y. Laboratories Ltd. | Method and apparatus for treating liquids to inhibit growth of living organisms |
| US6471974B1 (en) * | 1999-06-29 | 2002-10-29 | S.C. Johnson & Son, Inc. | N-chlorosulfamate compositions having enhanced antimicrobial efficacy |
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-
2005
- 2005-01-12 SI SI200532121A patent/SI1711057T1/sl unknown
- 2005-01-12 PL PL05703082T patent/PL1711057T3/pl unknown
- 2005-01-12 US US10/586,349 patent/US8632794B2/en not_active Expired - Fee Related
- 2005-01-12 AU AU2005204492A patent/AU2005204492B2/en not_active Expired
- 2005-01-12 CA CA2553323A patent/CA2553323C/en not_active Expired - Lifetime
- 2005-01-12 NZ NZ548967A patent/NZ548967A/xx not_active IP Right Cessation
- 2005-01-12 ES ES05703082.7T patent/ES2609682T3/es not_active Expired - Lifetime
- 2005-01-12 PT PT57030827T patent/PT1711057T/pt unknown
- 2005-01-12 CN CN2005800081169A patent/CN101151219B/zh not_active Expired - Lifetime
- 2005-01-12 DK DK05703082.7T patent/DK1711057T3/en active
- 2005-01-12 JP JP2006548579A patent/JP4705044B2/ja not_active Expired - Lifetime
- 2005-01-12 EP EP05703082.7A patent/EP1711057B1/en not_active Expired - Lifetime
- 2005-01-12 WO PCT/IL2005/000039 patent/WO2005067380A2/en not_active Ceased
- 2005-01-12 HU HUE05703082A patent/HUE031510T2/en unknown
- 2005-01-14 TW TW094101192A patent/TWI400198B/zh not_active IP Right Cessation
- 2005-02-14 US US11/056,405 patent/US7837883B2/en active Active
-
2010
- 2010-03-25 US US12/731,917 patent/US8652496B2/en not_active Expired - Fee Related
- 2010-08-20 US US12/860,802 patent/US8211318B2/en not_active Expired - Lifetime
-
2013
- 2013-12-11 US US14/102,706 patent/US9179682B2/en not_active Expired - Lifetime
-
2014
- 2014-01-06 US US14/147,759 patent/US9468214B2/en not_active Expired - Fee Related
-
2015
- 2015-12-21 US US14/976,182 patent/US9713331B2/en not_active Expired - Fee Related
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| US3920832A (en) * | 1974-04-18 | 1975-11-18 | Sol J Barer | N-chloro carbamates as insecticides and fungicides |
| US5976386A (en) * | 1994-10-03 | 1999-11-02 | A.Y. Laboratories Ltd. | Method and apparatus for treating liquids to inhibit growth of living organisms |
| US6471974B1 (en) * | 1999-06-29 | 2002-10-29 | S.C. Johnson & Son, Inc. | N-chlorosulfamate compositions having enhanced antimicrobial efficacy |
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