TWI378995B - - Google Patents

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Publication number
TWI378995B
TWI378995B TW093102544A TW93102544A TWI378995B TW I378995 B TWI378995 B TW I378995B TW 093102544 A TW093102544 A TW 093102544A TW 93102544 A TW93102544 A TW 93102544A TW I378995 B TWI378995 B TW I378995B
Authority
TW
Taiwan
Prior art keywords
carbon atoms
hydrocarbon group
represented
general formula
independently
Prior art date
Application number
TW093102544A
Other languages
Chinese (zh)
Other versions
TW200508384A (en
Inventor
Nobuaki Shimizu
Original Assignee
Idemitsu Kosan Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2003028641A external-priority patent/JP4981240B2/en
Priority claimed from JP2003028642A external-priority patent/JP4981241B2/en
Application filed by Idemitsu Kosan Co filed Critical Idemitsu Kosan Co
Publication of TW200508384A publication Critical patent/TW200508384A/en
Application granted granted Critical
Publication of TWI378995B publication Critical patent/TWI378995B/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2406—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides
    • C10L1/2418—Organic compounds containing sulfur, selenium and/or tellurium mercaptans; hydrocarbon sulfides containing a carboxylic substituted; derivatives thereof, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/20—Thiols; Sulfides; Polysulfides
    • C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M135/26—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Description

1378995 第093102544號 民國102年1月is日訂正 二硫化合物做爲主成分， R^OOC-A1-Sx-A2-COOR2...... (I) (式中，R1及R2分別獨立爲碳數1〜30個的烴基，A1及A2分 別獨立爲以CR3R4所示之基，R3及R4分別獨立爲碳數 1〜20個的烴基，X爲表示2) 且，前述一般式（I)中之X爲3以上之多硫化合物含量，基 於與該二硫化合物之合計量，爲10質量％以下。 6·—種燃料油用添加劑，其特徵爲以一般式（II)和/或 一般式（III)所示之氫硫基鏈烷羧酸酯予以氧化偶合所得之 二硫化合物做爲主成分，1378995 No. 093102544, January 1st, the Republic of China, the revised disulfide compound as the main component, R^OOC-A1-Sx-A2-COOR2... (I) (wherein, R1 and R2 are independent a hydrocarbon group having 1 to 30 carbon atoms, A1 and A2 are each independently a group represented by CR3R4, and R3 and R4 are each independently a hydrocarbon group having 1 to 20 carbon atoms, and X is represented by 2), and the above general formula (I) The content of the polysulfide compound in which X is 3 or more is 10% by mass or less based on the total amount of the disulfide compound. An additive for a fuel oil, characterized in that a disulfide compound obtained by oxidative coupling of a hydrogenthioalkylalkanecarboxylate represented by the general formula (II) and/or the general formula (III) is used as a main component.

RiOOC-A^SH......(II) (式中，R1爲碳數1~30個的烴基，A1以CR3R4所示之基’ R3及R4分別獨立爲氫或碳數1〜20個的烴基） R2OOC-A2-SH...... (Ill) (式中，R2爲碳數1~30個的烴基，A2爲以CR3R4所示之基 ，R3及R4分別獨立爲氫或碳數卜20個的烴基）° 7.—種燃料油用添加劑’其特徵爲以—般式（IV)所示 之二硫化合物做爲主成分， Ι37β995 '-第093102544號 民國102年1月.访日訂正 R'00C-A3-Sx-a4-C00R2...... (IV) r (式中，R1及R2分別獨立爲碳數卜30個的烴基，A3及A4分 別獨立爲以CR5R6-CR7R8所示之基，r5~R8分別獨立爲氫 或碳數1〜20個的烴基，X爲表示2) 且，.前述一般式（IV)中之x爲3以上之多硫化合物含量， φ基於與該二硫化合物之合計量，爲1 〇質量％以下。 8·—種燃料用添加劑，其特徵爲一般式（V)和/或一般 式（VI)所示之氫硫基鏈烷羧酸酯予以氧化偶合所得之二硫 化合物做爲主成分， R'〇OC-A3-SH...... (V) (式中，R1爲碳數1~30個的烴基，A3爲以CR5R6-CR7R8所 #示之基，R5〜R8分別獨立爲氫或碳數1~20個的烴基） R2OOC-A4-SH......(VI) (式中，R2爲碳數1〜30個的烴基，A4爲以CR5R6-CR7R8所 示之基，R5〜R8分別獨立爲氫或碳數1〜20個的烴基）。 9.—種潤滑油組成物，其特徵爲含有（A)潤滑油基油 、和（B)如申請專利範圍第1項〜第4項中任一項記載之潤滑 油用添加劑。 -4 - 1378995 第〇931〇2544鷗 民國1〇2年1月18日訂正 10. 如申請專利範圍第9項之潤滑油組成物，其中， (B)成分之含量爲〇.〇1~50質量％。 11. —種燃料油組成物，其特徵爲含有（X)燃料油、和 (Y)如申請專利範圍第5項~第8項中任一項記載之燃料油用 添加劑。. 12. 如申請專利範圍第π項之燃料油組成物，其中， (Y)成分之含量爲0_01〜1000質量ppm。RiOOC-A^SH (II) (wherein R1 is a hydrocarbon group having 1 to 30 carbon atoms, and A1 is a group represented by CR3R4. R3 and R4 are each independently hydrogen or a carbon number of 1 to 20 Hydrocarbyl) R2OOC-A2-SH (Ill) (wherein R2 is a hydrocarbon group having 1 to 30 carbon atoms, A2 is a group represented by CR3R4, and R3 and R4 are each independently hydrogen or Carbon number of 20 hydrocarbons) ° 7. An additive for fuel oils, characterized by a disulfide compound represented by the general formula (IV) as a main component, Ι37β995 '- No. 093102544, January 102, Republic of China Visiting the date revised R'00C-A3-Sx-a4-C00R2... (IV) r (wherein R1 and R2 are each independently 30 carbon atoms, and A3 and A4 are independently The group represented by CR5R6-CR7R8, r5 to R8 are each independently hydrogen or a hydrocarbon group having 1 to 20 carbon atoms, X is a representation 2), and x in the above general formula (IV) is a polysulfide compound having 3 or more. Φ is 1% by mass or less based on the total amount of the disulfide compound. 8. A fuel additive characterized by a disulfide compound obtained by oxidative coupling of a hydrogenthioalkylalkanecarboxylate represented by the general formula (V) and/or the general formula (VI) as a main component, R' 〇OC-A3-SH... (V) (wherein R1 is a hydrocarbon group having 1 to 30 carbon atoms, A3 is a group represented by CR5R6-CR7R8#, and R5 to R8 are each independently hydrogen or a hydrocarbon group having 1 to 20 carbon atoms) R2OOC-A4-SH (VI) (wherein R2 is a hydrocarbon group having 1 to 30 carbon atoms, and A4 is a group represented by CR5R6-CR7R8, R5 ~R8 is independently hydrogen or a hydrocarbon group having 1 to 20 carbon atoms). A lubricant composition comprising (A) a lubricating base oil, and (B) an additive for lubricating oil according to any one of claims 1 to 4. -4 - 1378995 〇 〇 〇 544 544 544 544 544 544 544 544 544 544 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 如 如 如 如quality%. A fuel oil composition comprising (X) a fuel oil, and (Y) an additive for a fuel oil according to any one of claims 5 to 8. 12. The fuel oil composition of claim π, wherein the content of the (Y) component is from 0_01 to 1000 ppm by mass.

TW093102544A 2003-02-05 2004-02-04 Additives for lubricating oils and fuel oils, lubricating oil compositions, and fuel oil compositions TW200508384A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003028641A JP4981240B2 (en) 2003-02-05 2003-02-05 Additive for lubricating oil and fuel oil, and lubricating oil composition and fuel oil composition
JP2003028642A JP4981241B2 (en) 2003-02-05 2003-02-05 Additive for lubricating oil and fuel oil, and lubricating oil composition and fuel oil composition

Publications (2)

Publication Number Publication Date
TW200508384A TW200508384A (en) 2005-03-01
TWI378995B true TWI378995B (en) 2012-12-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
TW093102544A TW200508384A (en) 2003-02-05 2004-02-04 Additives for lubricating oils and fuel oils, lubricating oil compositions, and fuel oil compositions

Country Status (6)

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US (1) US20060148663A1 (en)
EP (1) EP1602709B1 (en)
KR (1) KR101083151B1 (en)
ES (1) ES2375127T3 (en)
TW (1) TW200508384A (en)
WO (1) WO2004069966A1 (en)

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JP4878742B2 (en) * 2004-08-04 2012-02-15 出光興産株式会社 Additive for lubricating oil and fuel oil, and lubricating oil composition and fuel oil composition
JP5175462B2 (en) * 2006-09-04 2013-04-03 出光興産株式会社 Lubricating oil composition for internal combustion engines
EP2067846B1 (en) * 2006-09-28 2012-03-21 Idemitsu Kosan Co., Ltd. Lubricating oil composition
WO2008050717A1 (en) * 2006-10-23 2008-05-02 Idemitsu Kosan Co., Ltd. Lubricating oil composition for internal combustion engine
JP5468728B2 (en) * 2007-05-29 2014-04-09 出光興産株式会社 Lubricating oil composition for internal combustion engines
WO2009104682A1 (en) * 2008-02-20 2009-08-27 出光興産株式会社 Lubricating oil composition for internal combustion engine
AT507280B1 (en) * 2008-08-27 2011-04-15 Blum Gmbh Julius FURNITURE FITTING WITH A DAMPER
JP2011084721A (en) * 2009-09-15 2011-04-28 Idemitsu Kosan Co Ltd Sliding mechanism
EP2508590A4 (en) * 2009-12-03 2013-07-24 Idemitsu Kosan Co Lubricating oil composition
CN101921635B (en) * 2010-09-30 2012-12-26 洛阳万山高新技术应用工程有限公司 High-oxygen-content active fuel and preparation method thereof
JP6678647B2 (en) * 2014-08-06 2020-04-08 ザ ルブリゾル コーポレイションＴｈｅ Ｌｕｂｒｉｚｏｌ Ｃｏｒｐｏｒａｔｉｏｎ Additive package for industrial gear lubricants with biodegradable sulfur components
JP7213694B2 (en) * 2018-01-12 2023-01-27 Ｅｎｅｏｓ株式会社 Sulfur-based compound, lubricating oil additive containing said sulfur-based compound, and lubricating oil composition containing said sulfur-based compound
JP6891358B1 (en) * 2019-07-26 2021-06-18 株式会社Adeka Lubricating oil additive and lubricating oil composition containing it
JP6891359B1 (en) * 2019-07-26 2021-06-18 株式会社Adeka Lubricating oil additive and lubricating oil composition containing it
US11905488B2 (en) * 2020-10-16 2024-02-20 Infineum International Limited Transmission fluid compositions for hybrid and electric vehicle applications

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Also Published As

Publication number Publication date
WO2004069966A1 (en) 2004-08-19
KR101083151B1 (en) 2011-11-11
ES2375127T3 (en) 2012-02-27
KR20050096180A (en) 2005-10-05
EP1602709A1 (en) 2005-12-07
TW200508384A (en) 2005-03-01
EP1602709B1 (en) 2011-12-28
US20060148663A1 (en) 2006-07-06
EP1602709A4 (en) 2009-04-01

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