TWI365106B - Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions - Google Patents

Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions

Info

Publication number
TWI365106B
TWI365106B TW096126173A TW96126173A TWI365106B TW I365106 B TWI365106 B TW I365106B TW 096126173 A TW096126173 A TW 096126173A TW 96126173 A TW96126173 A TW 96126173A TW I365106 B TWI365106 B TW I365106B
Authority
TW
Taiwan
Prior art keywords
emm
making
molecular sieve
sieve composition
hydrocarbon conversions
Prior art date
Application number
TW096126173A
Other languages
English (en)
Other versions
TW200819199A (en
Inventor
Wieslaw J Roth
Thomas Yorke
Michael C Kerby
Simon Christopher Weston
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of TW200819199A publication Critical patent/TW200819199A/zh
Application granted granted Critical
Publication of TWI365106B publication Critical patent/TWI365106B/zh

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20Organic compounds not containing metal atoms
    • C10G29/205Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68Aromatisation of hydrocarbon oil fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/08Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW096126173A 2006-07-28 2007-07-18 Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions TWI365106B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83400106P 2006-07-28 2006-07-28
US83403006P 2006-07-28 2006-07-28
US92620407P 2007-04-25 2007-04-25

Publications (2)

Publication Number Publication Date
TW200819199A TW200819199A (en) 2008-05-01
TWI365106B true TWI365106B (en) 2012-06-01

Family

ID=38578580

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096126173A TWI365106B (en) 2006-07-28 2007-07-18 Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions

Country Status (6)

Country Link
EP (1) EP2051804B1 (zh)
JP (1) JP5211049B2 (zh)
KR (1) KR101120880B1 (zh)
BR (1) BRPI0714609B1 (zh)
TW (1) TWI365106B (zh)
WO (1) WO2008013639A1 (zh)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7910785B2 (en) * 2006-07-28 2011-03-22 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion process using EMM-10 family molecular sieve
CN102216215B (zh) * 2008-07-28 2014-03-26 埃克森美孚化学专利公司 使用emm-12制备烷基芳族化合物的方法
US8212096B2 (en) * 2008-07-28 2012-07-03 Exxonmobil Chemical Patents Inc. Hydroalkylation of aromatic compounds using EMM-13
KR101273039B1 (ko) * 2008-07-28 2013-06-10 엑손모빌 케미칼 패턴츠 인코포레이티드 신규한 분자체 조성물 emm-12, 이의 제조 방법 및 이를 사용하는 공정
US8704023B2 (en) 2008-07-28 2014-04-22 Exxonmobil Chemical Patents Inc. Molecular sieve composition EMM-13, a method of making and a process of using the same
KR101147008B1 (ko) * 2009-06-22 2012-05-22 한국과학기술원 단일 단위 결정 격자 한 개 또는 10개 이하가 연결되어 규칙적이거나 불규칙적이게 배열된, 다중 또는 단일 판상구조의 제올라이트 및 유사 제올라이트 물질
US9144792B2 (en) 2013-10-23 2015-09-29 Exxonmobil Chemical Patents Inc. Hydroalkylating process
JP7267537B2 (ja) 2017-11-28 2023-05-02 国立研究開発法人産業技術総合研究所 Mww型ゼオライト及びその製造方法、並びにクラッキング触媒
CN111099635B (zh) * 2018-10-25 2021-08-03 中国石油化工股份有限公司 Scm-19金属磷铝酸盐及其制备方法
CN114195166A (zh) * 2020-09-02 2022-03-18 中国科学院大连化学物理研究所 一种mww分子筛的离子交换方法

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6077A (en) 1849-01-30 Improved hinged claw-wrench
US498A (en) 1837-12-01 Improvement in mode of constructing saw-cylinders for cotton-gins
DE3117135A1 (de) 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
NZ218939A (en) * 1986-01-29 1989-11-28 Chevron Res Zeolite ssz-25; mole ratio of sio 2 or geo 2 to other framework oxides greater than 20 to 1
US4826667A (en) 1986-01-29 1989-05-02 Chevron Research Company Zeolite SSZ-25
US5013422A (en) 1986-07-29 1991-05-07 Mobil Oil Corp. Catalytic hydrocracking process
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US5019670A (en) 1986-07-29 1991-05-28 Mobil Oil Corporation Process for producing alkylaromatic lubricant fluids
US4962256A (en) 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing long chain alkyl aromatic compounds
US5019664A (en) 1988-10-06 1991-05-28 Mobil Oil Corp. Process for the conversion of paraffins to olefins and/or aromatics and low acidity zeolite catalyst therefor
US4983276A (en) 1988-10-06 1991-01-08 Mobil Oil Corp. Octane improvement in catalytic cracking and cracking catalyst composition therefor
US4954663A (en) 1988-10-06 1990-09-04 Mobil Oil Corp. Process for preparing long chain alkyl phenols
US4956514A (en) 1988-10-06 1990-09-11 Mobil Oil Corp. Process for converting olefins to higher hydrocarbons
DE3625693A1 (de) 1986-07-30 1988-02-11 Bayer Ag Verfahren zur umsetzung von aminen mit heterocyclischen reaktivkomponenten
US4721806A (en) 1986-10-06 1988-01-26 Uop Inc. Process for separating 2,4-toluene diisocyanate from isomers of toluene diisocyanate
US4721807A (en) 1986-10-06 1988-01-26 Uop Inc. Process for separating 2,6-toluene diisocyanate from isomers of toluene diisocyanate
IT1205681B (it) 1987-05-26 1989-03-31 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio e boro
US4986894A (en) 1988-10-06 1991-01-22 Mobil Oil Corp. Catalytic hydroisomerization process
US4962257A (en) 1988-10-06 1990-10-09 Mobil Oil Corp. Process for the catalytic disproportionation of toluene
US4982040A (en) 1988-10-06 1991-01-01 Mobil Oil Corp. Process for the catalytic disproportionation of methylnaphthalenes
US4962239A (en) 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing ethers
US5001283A (en) 1988-10-06 1991-03-19 Mobil Oil Corp. Process for preparing aromatic alkanols
US4973784A (en) 1988-10-06 1990-11-27 Mobil Oil Corp. Process for reducing the durene content of effluent resulting from the catalytic conversion of C1 -C4 oxygenates to gasoline
US4982033A (en) 1988-10-06 1991-01-01 Mobil Oil Corp. Process for converting light aliphatics to aromatics
US4992606A (en) 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5012033A (en) 1988-10-06 1991-04-30 Mobil Oil Corp. Isoparaffin-olefin alkylation process and catalyst composition thereof
US5001295A (en) 1988-10-06 1991-03-19 Mobil Oil Corp. Process for preparing dialkylnaphthalene
AU628056B2 (en) * 1988-11-28 1992-09-10 Mobil Oil Corporation Zeolite material
US4992611A (en) 1989-12-13 1991-02-12 Mobil Oil Corp. Direct conversion of C1 -C4 oxygenates to low aromatic distillate range hydrocarbons
US4962250A (en) 1990-01-24 1990-10-09 Mobile Oil Corp. Process for the conversion of paraffins to olefins and/or aromatics and non-acidic zeolite catalyst therefor
US4992615A (en) 1990-01-25 1991-02-12 Mobil Oil Corp. Isoparaffin-olefin alkylation process
US5000839A (en) 1990-02-14 1991-03-19 Mobil Oil Corp. Hydrocracking process for producing a high density jet fuel
US4968402A (en) 1990-02-14 1990-11-06 Mobil Oil Corp. Process for upgrading hydrocarbons
US5001296A (en) 1990-03-07 1991-03-19 Mobil Oil Corp. Catalytic hydrodealkylation of aromatics
US5019665A (en) 1990-04-18 1991-05-28 Mobil Oil Corp. Shape-selective process for concentrating diamondoid-containing hydrocarbon solvents
US5250277A (en) 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
DE69225311T2 (de) * 1991-01-11 1998-08-20 Mobil Oil Corp Schichtenförmige oxide sowie geschwollene und saeulenartige formen dieser materialien
KR930703069A (ko) * 1991-01-11 1993-11-29 에드워드 에이치. 밸런스 지주(支柱)가 있는 층구조의 옥사이드 재료를 제조하는 방법
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
ES2124154B1 (es) 1995-11-08 1999-12-01 Univ Politecnica De Valencia C Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa.
ES2105982B1 (es) 1995-11-23 1998-07-01 Consejo Superior Investigacion Zeolita itq-1
US6936744B1 (en) 2000-07-19 2005-08-30 Exxonmobil Chemical Patents, Inc. Alkylaromatics production
ES2246704B1 (es) * 2004-05-28 2007-06-16 Universidad Politecnica De Valencia Zeolita itq-30.
US7799316B2 (en) 2006-02-14 2010-09-21 Exxonmobil Chemical Patents Inc. Process for manufacturing MCM-22 family molecular sieves
US7846418B2 (en) 2006-02-14 2010-12-07 Exxonmobil Chemical Patents Inc. MCM-22 family molecular sieve composition

Also Published As

Publication number Publication date
EP2051804A1 (en) 2009-04-29
KR20090025285A (ko) 2009-03-10
BRPI0714609A2 (pt) 2013-02-05
TW200819199A (en) 2008-05-01
JP5211049B2 (ja) 2013-06-12
JP2009544566A (ja) 2009-12-17
KR101120880B1 (ko) 2012-02-27
WO2008013639A1 (en) 2008-01-31
BRPI0714609B1 (pt) 2016-11-08
EP2051804B1 (en) 2016-08-10

Similar Documents

Publication Publication Date Title
TWI365105B (en) Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions
ZA200810728B (en) A MCM-22 family molecular sieve composition, its method of making, and use for hydrocarbon conversions
TWI365106B (en) Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions
HRP20190408T1 (hr) Ariloazol-2-il-cijanoetilamino-spojevi, postupak njihove proizvodnje i postupak njihove uporabe
TWI365107B (en) A novel molecular sieve composition, a method of making and a process of using the same
ZA201009262B (en) A novel molecular sieve composition emm-13,a method of making and a process of using the same
ZA200906057B (en) Promoted carbride-based fischer-tropsch catalyst,method for its preparation and uses thereof
IL205073A (en) 2 bst antibodies, methods of making them, medicinal preparations containing them and their use
ZA200902255B (en) Synthesis, methods of using, and compositions of cycloalkylmethylamines
EP1972648A4 (en) AROMATIC POLYETHER, PROCESS FOR PRODUCING THE SAME, AND POLYMER COMPOSITION
EP2074258A4 (en) FIBER PLATES, THEIR MANUFACTURE AND USE
WO2008021135A8 (en) Syneretic composition, associated method and article
EP2065354A4 (en) REACTION APPROACH AND REACTION PROCEDURES
GB0601684D0 (en) Composition, process for preparation and method of use
ZA200810603B (en) Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
EP2048506A4 (en) MARKERS FOR POSTPRANDIAL HYPERGLYKEMIA, METHOD OF DETERMINING THEREOF AND USE THEREOF
GB0607562D0 (en) Method, composition and use
ZA200810099B (en) Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions
GB0607354D0 (en) Agent, Composition And Method
HU0600418D0 (en) Process for modification of carbon nanopipes, these modified carbon nanopipes and their application

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees