TWI345526B - Fabrication method and coating solution of anti-uv and antiglare film - Google Patents

Description

1.345526 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to the production of an optical film, and more particularly to a method for producing an ultraviolet-resistant anti-glare film and a coating liquid therefor. [Prior Art] The flat fluid 33⁄4 II Τ ϋ has been widely used in various modern electronic products such as personal computers, notebook computers, digital cameras, mobile phones, personalization assistants (PDAs) and LCD TVs. The development of LCD panel product technology, in addition to high contrast, wide viewing angle, high brightness, thinness, large size, also to the surface of additional functions such as anti-glare, anti-glare, anti-reflection, anti-pollution and other directions. Among them, anti-glare films are widely used in liquid crystal displays such as notebook computers and computer screens because of their obvious effects and low cost. The conventional anti-glare film achieves an anti-glare effect by adding antiglare particles, but the anti-glare particles have a problem of sedimentation and difficulty in dispersion in the coating liquid, which makes the coating liquid difficult to store, and thus is coated. The cloth system needs to have good stability, otherwise it is difficult to obtain a uniformly dispersed anti-glare film, and the anti-glare film made by using the anti-glare particles has poor wear resistance under high anti-glare property. In addition, it is disclosed in the Japanese Patent No. 2006-088643 and the Japanese Patent No. 7008066B2 that the coating liquid is dispersed on the roller, and the coating liquid is applied to the substrate while the coating liquid is formed on the surface of the coating film by the embossing roller. The microstructure "achieves anti-glare or anti-reflection effect, and forms an anti-glare film from the back/day of the board with uv light." Although this method can solve the disadvantages of anti-glare particle sedimentation and non-dispersion, the adhesion of the anti-glare film formed by it is not good, and the friction of the surface is not good, and the surface roughness is uneven. The microstructure is not easy to form. In addition, since the anti-glare film needs to effectively block the ultraviolet light emitted by the cold cathode tube and prevent the external ultraviolet light from damaging the polarizing film in the application of the liquid crystal display, the anti-glare film needs to have an ultraviolet wavelength with a blocking wavelength of deg. The function of light, and the method of manufacturing (4) anti-_ to cause (four) difficult to attach and incomplete hardening and other issues. Therefore, the industry is in urgent need of a method for manufacturing an anti-glare film, which can be improved.

Traditional anti-glare bribery, poor resistance to Nail and incomplete hardening, and at the same time, anti-glare has the disadvantage of anti-glare and (4) good traditional anti-glare film. SUMMARY OF THE INVENTION In view of the above, an object of the present invention is to provide an anti-ultraviolet anti-glare (four) manufacturing method without anti-glare particles and a coating liquid thereof, which can achieve the effects of improving adhesion and abrasion resistance, and can avoid hardening. The complete problem, at the same time, makes the anti-glare film both UV-resistant. In order to achieve the above object, the present invention provides a method for producing an anti-ultraviolet anti-glare film, which comprises applying a hard coating liquid coating onto a surface of a substrate, wherein the hard ore coating liquid is applied to a light-initiating agent, The absorption peak is in the range of 35〇~4〇〇'm(four)' the first solvent has invaded the substrate; the first solvent in the hard coating layer is volatilized to form a hard layer; and the hard (four) table is made by using the wheel (4) When the convex structure is closed, the external light source is irradiated by the lower surface of the substrate to form an anti-ultraviolet anti-glare film.

At the time of VI this '" month also provides a UV anti-glare coating solution 'including 1 external light curing type (10) monomer; light initiator, its absorption wave 0659-A21954TWF (N2); M06016; KELLY 6 The 1345526 peak is at 350 40 〇 nm, and the first solvent is aggressive against the substrate of the ultraviolet anti-glare film. _ In order to make the above and other objects, features, and advantages of the present invention more obvious - the preferred embodiment is described in the following paragraphs, and the details of the invention are as follows: [Embodiment]

A schematic diagram of a manufacturing process of the anti-ultraviolet anti-glare film of the present invention is as shown in Fig. 1. The substrate 3 is unwound through the unwinder 1, and the hard coat layer is applied to the substrate 3 by the coating head 5. On the upper surface 301, the substrate advances in the direction of the arrow A. Before reaching the embossing roller 9, the solvent in the hard money layer coating liquid 7 is gradually volatilized, and the viscosity of the hard plating coating liquid is also increased. When the hard coating liquid reaches the embossing roller, since the surface of the dust roller has a concave-convex structure, the hard coating liquid contacts the embossing roller to form a concave-convex structure on the surface of the coating liquid to achieve anti-glare. While the clear coating liquid is in contact with the embossing roller, the ultraviolet light source is moved from the surface of the substrate 3, and the ultraviolet light is transmitted through the substrate 3 to harden the hard layer to form a demolding process, thereby forming the present invention. The anti-ultraviolet anti-glare film 12, and the anti-ultraviolet anti-glare film are then wound up by a winder 丨3. Because of at least the winter in the hard coating solution of the present invention... ν 3 has a light-initiating agent that absorbs the peak at 350 to 400 nm, so when the 厣Longtian/earthing roller forms a concave-convex structure in hard plating At the same time 'Using an ultraviolet light source from the back surface of the substrate ^ can make the concave and convex structure on the hard clock layer to be quickly hardened and molded, and the anti-preparation and external anti-glare film manufacturing method does not have a peak in the hard ore coating liquid. 350~400nm photoinitiator, so the absorption and external light source from 0659-A21954TWF(N2); M06016; KELLY 7 1345526 anti-UV substrate backside irradiation, hard coating wave is not easy to harden, after the pressure roller The uneven structure formed will not be candidized over time and is not easily formed. In addition, in the manufacturing process of the anti-ultraviolet anti-glare film of the present invention, the embossing roller forms a concave-convex structure on the hard-coating coating liquid and the ultraviolet light source is simultaneously formed from the back surface of the substrate, thereby being more advantageous for the hard-plated sputum. Hardening molding of the uneven structure. Another schematic diagram of the manufacturing process of the anti-ultraviolet anti-glare film of the present invention is as shown in Fig. 2, which differs from the first one in that the hard ore layer coating liquid 7 passes through the drying device 15 before it reaches the pressure roller 9 . 'For example, the tank is used to volatilize the solvent in the hard coating layer coating liquid 7, and then contact with the squeezing roller 9 to form a concave-convex structure on the surface of the hard coating layer coating liquid 7 to achieve the purpose of anti-glare. The substrate may be a transparent material having an ultraviolet shielding function, and the wavelength of the transmitted light is between 370 and 420 nm, and the light having a wavelength of less than 370 nm is completely shielded. The material of the substrate is, for example, triacetyl cellulose (TAC), polyacrylate, polycarbonate, polyethylene or polyethylene terephthalate. , referred to as PET), etc., which is better by TAC. The hard coating liquid of the present invention may include an ultraviolet light curing resin monomer, an ultraviolet light curing resin oligomer, a photoinitiator, and a solvent, wherein the ultraviolet light curing resin monomer and the ultraviolet light curing resin oligomer Or the combination of the foregoing has a total weight of 100 parts by weight, a solvent of 5 to 75 parts by weight, and a photoinitiator of 1 to 10 parts by weight. The photoinitiator comprises at least one photoinitiator having an absorption peak of 350 to 0659-A21954TWF (N2); M06016; KELLY 8 1345526 400 nm, and the solvent contains at least one of the substrates which are aggressive to the substrate. Solvent. The method for producing the ultraviolet anti-glare film of the present invention comprises applying a hard solvent to the substrate by applying a strong solvent which is erosive to the substrate in the hard coating layer coating solution, and The adhesion of the substrate is preferred. The ultraviolet curable resin monomer may be iS0butyl acrylate, 2-ethylhexyl acrylate, ι, 6-hexadiol dipropionate (l, 6-hexanediol diacrylate), tripropylene glycol diacrylate, trimethylolpropane triacrylate, dipentaerythritol pentaacrylate, pentaerythritol tripropyl Pentaerythritol triacrylate, dipentaerythritol hexaacrylate or diethylene glycol dimethacrylate. The ultraviolet curable resin oligomer may be a urethane (meth) acrylate oligomer, a polyester methacrylate oligomer, or a polyester methacrylate oligomer. An epoxy (meth) acrylate oligomer or the like. The main component in the photoinitiator is a photoinitiator having an absorption peak at 350 to 400 nm, such as diphenyl (2,4,6-trimercaptobenzoic acid)-phosphine oxide (diphenyl (2, 4, 6-trimethylbenzoyl)-phosphine oxide), phenyl bis (2,4,6-trimethylbenzoy) phosphine oxide, bis(5-2, 4-cyclopentadien-1-yl)-bis[2,6-bisfluoro-3-(lH-npyrrol-1-yl)phenyl]titanium (bis(eta 0659-A21954T WF(N2); M06016; KELLY 9 1345526 5-2,4-cyclopentadien-l-yl)-bis[2,6-difluoro-3-(lh-pyrrol-lyl)phenyl]titanium), 2-isopropylthioxanthone (2-isopropyl thioxanthone), Ν, Ν, Ν·, Ν'-tetraethyl-4,4'-diaminobenzophenone (N,N,N',N'-Tetraethyl-4,4'-diaminobenzophenone ), Michler ethylketone or a combination of the foregoing. The ultraviolet light source 11 used in combination may be of the Η type, the D type, the V type or the Q type, and among them, the Η type and the D type are preferable. In addition, the photoinitiator may also contain a photoinitiator having an absorption peak between 200 and 350 nm, such as benzophenone or 1-hydroxy-cyclohexyl-phenyl-ketone (1-hydroxy). -cyclohexyl-phenyl-ketone), 2-hydroxy-2-methyl-l-phenyl-l-propanone or bismuth benzoate _ (methylbenzoylformate) and the like. The strong solvent which is aggressive to the substrate is, for example, methyl ethyl ketone (MEK), decyl isobutyl ketone (oxime), ethyl acetate (EAC) or butyl acetate (BAC). In addition, a weak solvent which is not aggressive to the substrate may be contained in the solvent, such as iso-propyl alcohol (IPA), toluene, methanol, ethanol, cyclohexanone. (cyclohexanone) or propylene glycol monoethylether acetate. Further, the hard bell layer coating liquid of the present invention may also contain an ultraviolet light absorbing agent such as a benzotriazole, benzophenone or salicylic acid compound. The anti-ultraviolet anti-glare film of the present invention is produced by a method in which a hard coating solution contains a strong solvent which is erosive to a substrate, thereby increasing adhesion.

0659-A21954TWF(N2); M06016; KELLY 1345526 effect. In addition, the hard coating coating liquid contains at least a photoinitiator having an absorption peak at 350 to Yang nm. Therefore, the uneven structure of the surface of the anti-ultraviolet anti-glare film formed can be hardened completely and formed as described above. The invention utilizes the hard clock and red formula and the S branching, and the purpose of adhesion and abrasion resistance of the anti-UV 4 glare film.

And in the right anti-ultraviolet anti-glare film, the anti-ultraviolet function can be provided by a substrate having an anti-ultraviolet function, or by adding an ultraviolet light absorber to the laminating solution to achieve the function of resisting ultraviolet rays. Further, the anti-glare function is provided by the uneven structure on the surface of the hard-plated layer, and the ten-point average roughness Rz of the standing structure is about 0.5 to 5 mm, which can be determined by the size of the patterned structure on the embossing roller. Compared with the (4) ultraviolet anti-glare film of the present invention, the hard coating layer of the present invention has better adhesion to the substrate, and can be tested by a hundred-square test without peeling off. Further, the abrasion resistance of the ultraviolet anti-glare film of the present invention can be increased to about 5 times or more as conventional. [Example 1] 90 parts by weight of ultraviolet curable resin B-500SF (manufactured by Shin-Nakamura Chemical Co., Ltd.) was mixed with 10 parts by weight of ultraviolet light-curable resin monomer diethylene glycol dimethacrylate to form resin A. Further, 20 parts by weight of a strong solvent MEK was mixed with 3 parts by weight of a photoinitiator 2-isopropylthioxanthone', and then 80 parts by weight of the resin a was added to form a hard coating liquid. The hard coating solution was applied to a TAC transparent substrate (manufactured by LOFO Co., Ltd.) having a thickness of 80/zm, and the ultraviolet ray was manufactured by the manufacturing process of Fig. 1.

0659-A21954TWF(N2); M06016; KELLY 1345526 anti-glare film, wherein the solvent drying time in the hard coating liquid solution is about 5 seconds before reaching the embossing roller, and then irradiated by a mercury-type lamp, the ultraviolet dose thereof The anti-ultraviolet anti-glare film of Example 1 was completed at about 500 to 600 mJ/cm2. The anti-ultraviolet anti-glare film of Example 1 was subjected to Adhesion, hardness, anti-scratch, Total transmittance, and haze in the following test manners. Test, the results are shown in Table 1. Adhesion test: Using a hundred-square test, the surface of the anti-ultraviolet anti-glare film of 1 cm2 was divided into 100 parts of the same area, and the tape was peeled off with a tape of 3M of 600, and the film was peeled off. If there is no peeling at all, it means good adhesion; if peeling occurs, it means poor adhesion. Pencil hardness test: Tested with a hardness tester Model 291 (labeled Erichsen Testing Equipment) with a load of 5 (8) grams. The pencil hardness is expressed in 3H, 4H, 5H, etc. The higher the number, the higher the pencil hardness. Abrasion resistance test: 10 times of rubbing with steel wool 0000, the diameter of the rubbing area was 2.5 cm, and the maximum load was observed without scratching. The higher the load, the better the friction. Transmittance and haze test: The light transmittance and haze of the anti-UV anti-glare film were tested with an optical test machine Haze meter NDH2000 (label Nippon Denshoku). [Example 2] 90 parts by weight of ultraviolet light curing resin 0659-A21954TWF (N2); M06016; KELLY 12 1345526 B, 500SF (manufactured by Shin-Nakamura Chemical Co., Ltd.) and 10 parts by weight of ultraviolet light curing resin monomer diethylene Glycol dimethacrylate is mixed into resin A. Separately, 20 parts by weight of the strong solvent MEK is mixed with 5 parts by weight of the photoinitiator 2-isopropyl thioxanthone and 5 parts by weight of the photoinitiator diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide, and then added to 80. In the part by weight of the resin A, a hard bond layer coating liquid was formed. The hard coating solution of Example 2 was formed into the anti-ultraviolet anti-glare film in the same manner as in the production method of Example 1, and the adhesion, hardness, abrasion resistance, transmittance, and haze were respectively tested by the above-mentioned test methods. The result is shown in the table - [Comparative Example 1] 90 parts by weight of ultraviolet curable resin B-500SF (manufactured by Shin_Nakamura Chemical Co., Ltd.) was mixed with 10 parts by weight of the ultraviolet curable resin monomer diethylene glycol dimethacrylate. Hard clock layer coating. The hard coating liquid of Comparative Example 1 was formed into an anti-ultraviolet anti-glare film in the same manner as in the production method of Example 1, and the adhesion, hardness, abrasion resistance, transmittance, and haze were respectively tested by the above-mentioned test methods. The results are shown in Table 1. Since the anti-ultraviolet anti-glare film of Comparative Example 1 could not be completely cured, its adhesion was inferior. [Comparative Example 2] 1 part by weight of a UV-curable resin monomer diethylene glycol dimethacrylate and 5 parts by weight of a photoinitiator

0659-A21954TWF(N2); M06016; KELLY 1345526 diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide mixed, and then added 90 parts by weight of ultraviolet light curing resin B-500SF (manufactured by Shin-Nakamura Chemical Co., Ltd.) to form a hard Coating solution. The hard ore layer coating liquid of Comparative Example 2 was formed into an anti-ultraviolet anti-glare film in the same manner as in the production method of Example 1, and the adhesion, hardness, abrasion resistance, penetration rate, and haze test were respectively tested by the aforementioned test methods. The results are shown in Table 1. Although the anti-ultraviolet anti-glare film of Comparative Example 2 was hard to be completely cured, a part of the anti-ultraviolet anti-glare film adhered to the embossing roller, so that the adhesion was poor. [Comparative Example 3] 90 parts by weight of ultraviolet curable resin B-500SF (manufactured by Shin-Nakamura Chemical Co., Ltd.) was mixed with 10 parts by weight of the ultraviolet curable resin monomer diethylene glycol dimethacrylate to form a resin A. 50 parts by weight of Resin A was mixed with 50 parts by weight of a strong solvent MEK and 4.5 parts by weight of anti-glare particles 〇K607 (produced by Degussa Co., Ltd.) to form a hard money layer coating liquid. The hard coating solution was applied to a TAC substrate (manufactured by LOFO Co., Ltd.) having a thickness of 80 μm using a wire bar (specification No. RDS No. 6), and baked in an oven at 70 ° C for 3 minutes, followed by a mercury-type lamp (dose). It is irradiated and hardened to 500 to 600 mJ/cm 2 to form an anti-ultraviolet anti-glare film. The anti-ultraviolet anti-glare film of Comparative Example 3 was tested for adhesion, hardness, abrasion resistance, transmittance, and haze in the same manner as described above, and the results are shown in Table 1.

0659-A21954TWF(N2); M06016; KELLY 1345526 The test results of the anti-ultraviolet anti-glare films of the above examples and comparative examples are listed in Table 1 below: Table 1 Test Results of Examples and Comparative Examples Example 1 Example 2 Comparison Example 1 Comparative Example 2 Comparative Example 3 Adhesiveness Good difference Good pencil hardness 3H 3H __ _ - 3H Wear resistant tree (g) >1880 > 1880 One <400 Haze (%) 48.32 47.5 _ 47.67 Wear Permeability (%) 90.65 90.81 _ _ 91.15 It can be seen from the hardness and abrasion resistance test results of Table 1 that the hard coating layer of Examples 1 and 2 containing a strong solvent MEK and a photoinitiator having an absorption peak at 350 to 400 nm is known. The coating liquid, the adhesion and abrasion resistance of the anti-ultraviolet anti-glare film prepared by the coating liquid were significantly improved compared with the comparative examples 1 and 2 without the strong solvent MEK. In addition, in Examples 1 and 2, compared with Comparative Example 3 in which anti-glare particles were added, the abrasion resistance was also improved from less than 400 g to more than 1880 g, indicating that the anti-ultraviolet anti-glare film of the present invention was produced and The hard-plated coating liquid can obtain a UV-resistant anti-glare film having better adhesion and sharpness, and is equivalent to an anti-glare film to which anti-glare particles are added in terms of pencil hardness, penetration, and haze. Although the present invention has been disclosed in its preferred embodiments, it is not intended to limit the invention, and the invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application attached. 0659-A21954TWF(N2); M06016; KELLY 15 1345526 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows a manufacturing process of an anti-ultraviolet anti-glare film according to a preferred embodiment of the present invention. Fig. 2 is a view showing the manufacturing process of the anti-ultraviolet anti-glare film according to another preferred embodiment of the present invention. [Main component symbol description] 1~ unwinding machine; 3~ substrate; 5~ coating head; 7~ hard coating liquid; 9~ embossing roller; Π~ ultraviolet light source; 12~ anti-UV anti-glare film; ~ Winding machine; 15 ~ drying device; A ~ substrate advancing direction; 301 ~ substrate upper surface; 302 ~ substrate lower surface. 0659-A21954TWF(N2); M06016; KELLY 16

Claims (1)

1345526; No. 96104585 Revision date: 100.3.3 X. Patent application scope: Amendment 修正 March 3, 011, revised replacement stomach A method for producing an anti-ultraviolet anti-glare film, comprising: providing a substrate, wherein the substrate has a wavelength of light that is at a wavelength of ～420 nm; and coating a hard ore coating on the surface of the substrate The hard-bonding layer coating liquid comprises at least one ultraviolet curing resin monomer, a photoinitiator having an absorption peak at 350 to 400 nm', and the first solvent has an invading property on the substrate. And an ultraviolet light absorber; volatilizing the first solvent in the hard coating solution to form a hard clock layer; and using an embossing roller to form the surface of the hard coating layer into a concave-convex structure while The lower surface of the substrate is irradiated to form the anti-ultraviolet anti-glare film. 2. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the material of the substrate comprises a transparent material having an ultraviolet shielding function, and light having a wavelength of 370 nm or less is shielded. 3. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the substrate comprises triacetyl cellulose, polyacrylate, polycarbonate, polyethylene (polyacrylate) Polyethylene) or polyethylene terephthalate. 4. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the photoinitiator comprises diphenyl(2,4,6-trimercaptobenzoyl)-phosphine oxide ( Diphenyl(2,4,6-trimethylbenzoyl)-phosphine 1345526 j Revision No. 96104585: 100.3.3 Amendment to this year, March 3, rev. replacement page oxide), phenyl di(2,4,6-tridecyl) Phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide, bis(5-2,4-cyclopentadien-1-yl)-bis[2,6-difluoro· 3-(1Η-ηpyrrol-1-yl)phenyl]titanium (bis(eta 5-2,4-cyclopentadien-l-yl)-bis[2,6-difluoro-3-(lh-pyrrol-ly l) phenyl]titanium), 2-isopropyl thioxanthone, N,N,N',N'-tetraethyl-4,4'-diaminobenzophenone (N, N, N', N'-Tetraethyl-4, 4'-diaminobenzophenone) or a combination of the foregoing. 5. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the first solvent comprises methyl ethyl ketone (MEK), mercaptoisobutyl ketone (MIBK), ethyl acetate (EAC) or Barium acetate (BAC). 6. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the hard-coating solution further comprises an ultraviolet-curable resin oligomer. The method for producing an anti-ultraviolet anti-glare film according to claim 6, wherein the ultraviolet-curable resin monomer and the ultraviolet-curable resin oligomer have a total weight of 100 parts by weight. One solvent is 5 to 75 parts by weight, and the photoinitiator is 1 to 10 parts by weight. 8. The method of producing an anti-ultraviolet anti-glare film according to claim 1, wherein the hard-coating solution further comprises a second solvent which is non-invasive to the substrate. 9. The method for producing an anti-ultraviolet anti-glare film according to claim 8, wherein the second solvent comprises isopropanol (iso-propyl alcoho IPA), toluene (toluene), methanol (methanol). , ethanol (ethanol), ring 18 1345526 Revision No. 96104585: 100.3.3 Amend this year, the moon fly date correction replacement cyclohexanone or propylene glycol acetyl ether ethyl acetate (pr0pyiene glycol monoethylether acetate) ° • 10. The method for producing an anti-ultraviolet anti-glare film according to claim 1, wherein the ultraviolet light absorber is selected from the group consisting of benzotriazole, benz0phenone, and salicylate. At least one compound of the group consisting of salicylic acid compounds. 11. The method for making an anti-ultraviolet anti-glare film according to claim 1, further comprising volatilizing the first solvent with a drying device. 12. A coating liquid for anti-ultraviolet anti-glare film, comprising: an ultraviolet curing resin monomer; a photoinitiator having an absorption peak at 350 to 400 nm; a first solvent 'the first solvent The substrate of the ultraviolet anti-glare film is aggressive; and an ultraviolet light absorber. The coating liquid of the anti-ultraviolet anti-glare film according to claim 12, wherein the photoinitiator comprises diphenyl (2,4,6-trimercaptobenzoyl)-phosphine oxide (diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide), phenyl bis (2,4,6-trimethylbenzoyl) phosphine oxide , bis(5-2,4-cyclopentadien-1-yl)-bis[2,6-bisfluoro.3-(1Η-ηpyrrolidyl)phenyl]titanium (bis(eta 5-) 254-cyclopentadien-l-yl)-bis[2,6-difluoro-3-(lh-pyrrol-lyl)phenyl]titanium), 2-isopropyi thioxanthone, anthraquinone, Ν,Ν',Ν'-tetraethyl-4,4'-diaminobenzophenone 19 1345526 Revision No. 96104585: 100.3.3 Call for the month 3»Day correction replacement page Amendment L___ (N, N, N ', N'-Tetraethyl-4, 4'-diaminobenzophenone) or a combination of the foregoing. 14. The coating liquid for anti-ultraviolet anti-glare film according to the scope of claim π, wherein the first solvent comprises methyl ethyl ketone (MEK), mercaptoisobutyl ketone (MIBK), ethyl acetate (EAC) or Butyl acetate (BAC). 15. The coating liquid of the anti-ultraviolet anti-glare film as described in the scope of claim π further includes an ultraviolet curing resin oligomer. 16. The coating liquid for an anti-ultraviolet anti-glare film according to claim 15 wherein the total weight of the ultraviolet-curable resin monomer and the ultraviolet-curable resin oligomer is 100 parts by weight, One solvent is 5 to 75 parts by weight, and the photoinitiator is 1 to 10 parts by weight. 17. The coating liquid for anti-ultraviolet anti-glare film as described in the scope of claim π further includes a second solvent which is non-invasive to the substrate of the anti-ultraviolet anti-glare film. 18. The coating liquid for anti-ultraviolet anti-glare film according to the scope of claim π, wherein the second solvent comprises iso-propyl alcohol (IPA), toluene, methanol The propylene glycol monoethylether acetate coating solution according to claim 12, wherein the ultraviolet ray is propylene glycol monoethyl ether acetate. The light absorbing agent is selected from at least one compound selected from the group consisting of benzotriazole, benzophenone, and salicylic acid. 20