TWI329667B - - Google Patents

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TWI329667B
TWI329667B TW95112863A TW95112863A TWI329667B TW I329667 B TWI329667 B TW I329667B TW 95112863 A TW95112863 A TW 95112863A TW 95112863 A TW95112863 A TW 95112863A TW I329667 B TWI329667 B TW I329667B
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Taiwan
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powder
shell
dense
ball
water
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TW95112863A
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Chinese (zh)
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TW200738849A (en
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Jongshin Huang
Chong Yi Chou
Shang Cheng Huang
Chun Hsiang Huang
Ting Jung Chen
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Univ Nat Cheng Kung
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九、發明說明: 【發明所屬之技術領域】 之質球心部份及緻密質球殼部分 ,介_粒’尤指—種顆粒球形度佳、顆 ,球表層無大小不-且不規則分佈開口孔洞、高強度、保 肥、無g、歸、多孔性等功能之具多 部及 緻费質球殼部分之高強度保水無g栽培介質顆粒、。 【先前技術】 纽(a)-⑴圖,係目前國内銷售栽培介質與本發明 之外觀比較圖;其中第—(a)圖為唐山石、第一⑻ =石、第—(C)圖為蛭石、第—⑷圖為日本石、第 祖in為發泡練石、及第一⑴圖為新型介質;並可依材 無機栽培介質顆粒分為二類,第一類為低強度高保水 1’ ΐ虫至石、珍珠石、曰本石或唐山石,該類介質 造或—般泥土經加熱後製得,但其製程中並未經 庚至丁圓球造粒且燒結溫度低,故顆粒成品大多呈現球形 粒表層具眾多大小不—且分佈不均之開口孔洞,以及 足和離散性過大等缺點;第二類為高強度低保水力 妹:。質?、ί ’如發泡煉石’其雖經造粒機適當造粒且經雜燒 =比二八k結溫度遠超過黏土礦物熔融溫度,致使顆粒固體部 二為玻璃相,使保水力低,且因採高溫發泡燒結,難以 粒内部孔洞之大小及分佈,而呈現球形不佳、顆粒表層 缺點不一且分佈不均開口孔洞,以及顆粒強度離散性過大等 二灣第195632專利公告號揭示一種無土栽培介質之製 ’ ^可由廢棄物中提供之聚丙烯纖維(p〇丨y Acryi〇nitrie 1 er又稱奥隆QflGn)去構成無土栽培介質,及在台灣第 1329667 ==告種二造培養土,雖由曰本柳杉或 土,然,此依據上成人造培養 保水力特性。 產°σ”,、法知·到良好強度及 可燒區每^產生大4絲物,可概分為高溫 =:椰=:、===方: 產品價值;無害於環境,但 水廠污;泥:,泥、海水於泥、淨 【===二生產成本高且產品價格低,故 資^^^^日趨細,各晴各自纽的廢棄物進行 貝^匕再=用已、g遍受到國内外產官 ϊ傳㈣、直娜二二 ΐ旦掩埋方式已逐漸式微,因此開發可 害於環境且高附加價值之廢棄物再利用技 县比ίΐίΓ栽1介質齡縣水佩雜,對許多植物生 ίΐΐ. 口 Λ刖國内市售之無機栽培介質顆粒大多由 國外進且j貝格叩貝,使其應用性大幅受限。 =明的發明人有鑑於習知栽培介質顆粒尚有缺失,乃 可利用有機廢棄物高溫可失燒和無機廢棄 物问狐不可&失的機特性,根細粒力學理論分析結果,開 6 ί,強度、高保水保氣、球形度佳、 期能為台灣的=^使狀無機栽培介_球顆粒, 新局。、I、 >、.辰業、景觀工程和土木生態工程開創 【發明内容】 咖衡峨培介質 ⑷娜㈣球心部分及緻密質球 (b) 驟’係控管上述選擇多孔質球心部分及 (c) 、’雄質球威部分原料之顆粒大小; (d) 步驟,係將上述製備之多孔質球心粉 體以適2混合比例完成球心造粒; (e) ,適#方式將上述製備之緻 在貝坺设粉體包晨壓密上述造粒之球心;Nine, invention description: [Technical field of invention] The core part of the mass and the part of the dense spherical shell, the medium granules, especially the granules of the granules, the sphericity of the particles, the size of the spherical surface is not--and irregularly distributed High-strength water-retaining non-g cultivation medium particles with multiple openings and high-strength spherical shell parts with open pores, high strength, fertilizer retention, no g, return, and porosity. [Prior Art] New (a)-(1) map, which is a comparison chart of the domestically-produced cultivation medium and the present invention; wherein - (a) is Tangshan stone, first (8) = stone, and - (C) For the meteorite, the first (4) is the Japanese stone, the first ancestor is the foaming stone, and the first (1) picture is the new medium; and the inorganic culture medium particles according to the material are divided into two categories, the first type is low intensity and high. Baoshui 1' locust to stone, pearl stone, sputum stone or Tangshan stone, this kind of medium or general soil is obtained by heating, but the process is not granulated by G- to Ding sphere and the sintering temperature is low. Therefore, most of the finished particles of the spherical particles have many defects such as open pores with uneven size and uneven distribution, and the disadvantages of excessive foot and discreteness; the second type is high-intensity and low-water-protection sisters. Quality?, ί 'such as foaming stone', although it is properly granulated by the granulator and is miscellaneous = more than the temperature of the two-k k junction is far beyond the melting temperature of the clay mineral, so that the solid part of the granule is the glass phase, so that the water retention Low, and due to high temperature foaming and sintering, it is difficult to size and distribute the internal pores of the particles, and the spherical shape is poor, the surface layer defects are not uniform, the uneven distribution of open pores, and the dispersion of particle strength are too large, etc., etc. No. Reveals a system for soilless culture medium ' ^ can be made from waste polypropylene fiber (p〇丨y Acryi〇nitrie 1 er, also known as Olong QflGn) to form a soilless culture medium, and in Taiwan 1329667 == It is said that the cultivation soil is cultivated, although it is made of sassafras cedar or soil, however, this is based on the artificial culture and water retention characteristics. Production °σ",, the law knows that the good strength and the combustible area produce a large 4 filaments, can be divided into high temperature =: coconut =:, = = = square: product value; harmless to the environment, but the water plant Sludge; mud: mud, sea water in the mud, net [=== two production costs are high and the product price is low, so the capital ^^^^ is getting finer, and the wastes of each clearing are carried out. g has been rumored by domestic and foreign officials (4), and the way of burying the Naina 22nd has gradually declined. Therefore, the development of environmentally-friendly and high-value-added waste recycling technology is better than that of the county. It is produced for many plants. Most of the inorganic culture medium particles that are commercially available in the mouth are imported from abroad and jbergel mussels are greatly limited in their applicability. The granules are still missing, but the organic waste can be decomposed by high temperature and the inorganic waste can not be used. The machine characteristics of the roots and fines are theoretically analyzed. The results are 6 ί, strength, high water retention, and sphericity. Jia, period can be Taiwan's = ^ 状状无机栽培介_球粒,新局., I, >, Chenye, landscape Cheng and civil engineering pioneering [invention content] Ca Heng 峨 culture medium (4) Na (four) spherical part and dense ball (b) ' ' control tube selected above porous core part and (c), 'male ball part The particle size of the raw material; (d) the step of granulating the porous spherical powder prepared above in a suitable mixing ratio; (e), suitable for the above-mentioned preparation, the powder is set in the shellfish Baochen compacts the above-mentioned granulated ball core;

Cf) tin、虹砂職^生料财及組成比 步驟’係以接近緻密殼層可燒結性粉末最 ^.、-被燒、,°溫度進行上述乾燥後之燒結。 行燒結後介質可更包括:依需求而去選擇進行或不進 驟: n",、囷栽培介質顆粒之方法,該方法包括下列步 (a) fiff:係選擇多孔質球心部分及緻密質球殼部 刀原料,其中該多孔質球心部份係藉由可燒結 1329667Cf) tin, rainbow sand, raw materials, and composition ratio. The step is to close to the dense shell sinterable powder, the most dry, and then sintered at the same temperature. The sintered medium may further include: selecting or not proceeding according to requirements: n", a method for cultivating medium particles, the method comprising the following steps: (a) fiff: selecting a porous core portion and a dense mass Spherical shell knife material, wherein the porous core portion is sintered by 1329667

(b)(b)

溫可燒失材料與黏結劑所構成之混合物,該 質球殼部份係藉由可燒結粉與黏結劑所構成; ΖΠί包括天然礦物粉末、無機廢棄物及其混 二物’無機廢棄物如於泥、軟湖泥、石材污泥 棄陶究煉鐵廠爐渣、焚化爐絲等;高溫 ^ 料係指包括農財機廢棄物、畜牧有機廢棄物、g 市有機廢棄物或Jlf廢棄物等;黏結舰可為水、 有機、無機性黏合劑組成物,其係水、壓克型樹脂、 胺基樹脂、三聚氰銨樹脂、水泥、石膏、高嶺土及 粘土之組成之族群中;並且,球心與球殼部份可 結性粉與黏結劑,可為相同或不同材料所構成; 球心造粒成形:其目的係提供由上述原料(可燒結 性粉:高溫可燒失材料與減劑)製造之高強G 水無菌栽培介質顆粒球心圓球部分,其中造粒方法^ 包括鑄型法及包裏法;鑄型法係將粉體原料與膠結 ,混合漿體,澆灌至圓球模具固化後脫膜;包裏法 ,由粉體小顆粒配合膠結液以浸泡、濕裏或喷粉乾 裏等方式’逐層包裏至指定顆粒大小; 、 球殼包裏壓密:其目的係完成高強度保水無菌栽培 介質顆粒緻密球殼部分,其中包裏壓密方法可係以 上^球心造粒步驟製造之球心圓球部分,以浸泡、 濕畏或噴粉乾晨等方式,分層分次將緻密質球殼部 份原料(可燒結粉與黏結劑)包裏於顆粒表層,並 以壓密方式使各球殼層達指定緻密狀態,反覆上述 動作至指定包裏厚度為止;上述壓密方式可包括逐 次以施氣壓、施液壓、施油壓和滾動方式。「生粒 多孔質球心半徑與整體圓球半徑比在〇〜〇 99間 ^心〜極薄空心球殼);且,「生粒」規格可限於球 形度大於0. 7,表面殼層最大開口孔洞平均直徑小於 8 2mm,表面殼層開口孔洞面積之總合與表面殼層總面 積比小於0. 2’緻密質球殼部份的孔隙率為3〇%0以>; (d) 乾燥:其目的係將球殼包裏壓密步驟中得到之產物 乾燥,乾燥時間及溫度依生料材質和組成比例而 異;以70〜150°C乾燥,乾燥時間介於〇 5〜48小時為 最適範圍; ’ (e) 高溫燒結:其目的可提高介質顆粒之顆粒強度,係 將上述步驟得出之介質顆粒進行高溫燒結;其中燒 結溫度以接近緻密殼層可燒結性粉末最緻密^堯結溫 度進行燒結,且燒結溫度愈接近最緻密燒結溫度, 孔隙率愈小,顆粒強度愈高;高溫燒結溫度介於1 至 2000°C ; ' (f) w質成伤調整.其目的係為不同需求而進行或不進 行高強度保水無菌栽培介質顆粒高溫燒結後之介質 成份調整’包括酸驗性調整和肥料調整。 、 還有,^發明之另一目的係提供根據本發明之製造方法所 生的一種高強度保水無菌栽培介質顆粒,該介質顆粒包括 礼質球心部份及緻密質球殼部分。 顆教本提供—種高強度保水無菌栽培介質 ^該;I質顆粒包括多孔質球心部份及緻密質球殼部分其 殼部保氣功能’_球 顆叔本之另—目的係提供—種高強度保水無賊培介質 该介質顆粒包括多孔質球心部份及緻密質球殼部分,1 盥ΐϋϊ心部份係藉由包括可燒結性粉或高溫可燒失材& ifΐ成,緻密質球殼部份係藉由包括可燒結性粉與 勒J,可Aj:且成且上述球心與球殼部份之可燒結粉與黏結 Η 了為相同或不同材料所組成。 1329667 八所H ’本發明之另一目的係提供一種高強度保水益菌栽谇 介質齡包括多孔質球心部份及緻密質球“ 材料轉丨1 球心部份係藉由包括可燒結性粉或高溫可燒失 黏m副荨所組成,緻密質球殼部份 轉所域;其巾,關溫观錄 祕其Ιΐΐ機廢棄物更包括:農業有機廢棄物、畜牧有機廢 ίϊ物或工業廢棄物等;該可燒結性粉= 機性黏合劑組成物’並且該有機、無機性黏合劑 銨=:::選擇i水严型樹脂、胺基樹脂、三聚氰 钕树舳水泥、石貧、高嶺土或粘土。 介質it’,ΐϊίΐί 一目的係提供一種高強度保水無菌栽培 二貝顆拉該讀顆粒具備酿球做佳、雜球表層無大小 =且ί規則分佈開口孔洞、高強度、保水保氣、保肥、無菌、 1、夕,性等功能。具有價格便宜、i害環境且可大量使用 ί石技读顆粒可廣泛應用於農業栽垃介質、景觀石、過 濾石、透氧材料、保水材料、營建材料、土壤改良等範嘴。 本發明之另一目的係提供一種高強度保水盔菌择 Ζ =介質顆粒規格為·· _。0至_°C高溫燒結,i形ί —’顆粒表面殼層最大開口孔洞平均直徑小於2mm,緻 下’且不大桃 ΐ ΐ Γ附的孔隙率為G·⑼至99%(即近似 心之顆㈣")’多孔f球‘時徑與整 體顆,球之核比在。至99之間,栽培介質ph值為4至ι〇。 本發明之又一目的係提供一種製造高強度保水無 法’其中該方法係利用有機廢棄物高溫可失燒^ 無機廢棄物純不可敎的㈣舰,絲據讎力學理論, 10 1329667 而製造出高強度、高保水保氣、球形度佳、價格便宜、無害環 境且可大量使用之高強度保水無菌栽培介質顆粒。 為使熟悉該項技藝人士瞭解本發明之目的、特徵及功效, 茲藉由下述具體實施例,並配合所附之圖式,對本發明詳加說 明,說明如後: 【實施方式】 配合習知陶瓷材料於不同溫度下之收縮與孔隙度,如第二圖所 示’其係為陶瓷材料之典型的收縮與孔隙度曲線圖;並根據本發 明依立力學理論分析測得之實驗數據’而得到較佳實施例之表 現^第三(a)-(c)圖與第四(a) —(c)圖,分別說明於E=1〇〇GPa、 ν=0· 25、p=-iGPa狀態條件下在不同厚度中空球殼受「均佈壓應 $」户輿「集中均佈壓應力」作用下之應力分佈圖;依此,達^ ^^例目的’係提供具備多孔質球心與緻密質球殼之高強度保水 ,函栽培介質顆粒,其剖面圖請參閱第五(a) - (f)圖所示, Ϊ曰^本發明較佳實施例中緻密殼層與多孔質球心混合示意圖;盆 3第i(a)圖說明緻密殼層與多孔質球心係採用相同陶究粉末^ (?)圖說明緻密殼層與多孔質球心係採用不同陶究粉末、 圖說明緻密殼層係由兩種以上陶瓷粉末組成、第五(d) 二;球心最大含氣量示意(似空心球殼)、第五(e)圖說 f二々ίί心最小含氣量示意(實心圓球)、及第五(f)圖說明 Ξ方t l卜層包裹有色枯土 ;以下配合圖示對本創作的較佳實施 步的說明後當更能明瞭。惟本發明不受以下實施例 南丨田t«發明之一種製造向強度保水無菌栽培介質顆粒之方法,可 與木屑體積比1:5,1:3,1:1與1:Q(實心),並以純 土ϋ &結劑’以圓球造粒機製造直徑7刪圓球球心,並採黏 〃7做為緻密殼層之可燒結性粉和黏結劑,利用滾圓機包裹 1329667 滾壓製做1mm、3mm和5mm緻密球殼’分別量測9〇〇v、]〇 〇 巧,_溫度下,介_歡恤^視= =哲、表層最大開口孔洞大小、與筒壓強度,用以 早保水性、保氣性與顆粒強度。其中該高強度 栽介質顆粒具備多孔質球心與緻密質球殼,包括下 燒失:球"部㈣11料燒馳、高溫可 燒失材枓與黏結劑所構成混合物,緻密 ^ 一:…機廢棄物及其混合無機廢棄物如於泥、軟湖泥、石 St ίΐϊ竞煉鐵廠爐渣、焚化爐底潰等;高溫可燒失材 =工物 =黏結?m可為水 '有機 '無i 石音;克型樹月曰、胺基樹脂、三聚氰錢樹脂、水泥、 ίΪ嶺及點土之組成之族群中;並且’球心鱼球崎邻份 可燒、Μ生粉與黏結劑,可為相同或不同材料所構成;Λ -可步驟:其目的係控制上述原料(可燒結性粉、高 與黏結劑)粉末顆粒大小,包括但不限定於,以 阽進仃大顆粒原料夹碎、配合粉碎機'打碎機戋磨粉機得 /外,输f球_絲度 可限於2咖内,若可燒結性粉末屬非 末的取大粒徑可限於〇·5咖内; 1玎貝杨 於造粒成形步驟:其目的係提供由上述原料(可燒社性 可燒失材料與黏結劑)製造之高強度保水無菌介 ίΓίϋ球部分,其中造粒方法包括但不限於鑄 具固化後脫膜;包裏法::土:合漿體澆灌至圓球模 裏或喷粉it 3 粉體小顆粒配合朦結液以浸泡、濕 逐層包裏至指定顆粒大小,· "又匕祕密步驟:其目的係完成高強度保水域裁培介 12 1329667a mixture of a material that can be burned and a binder, the shell portion of which is composed of a sinterable powder and a binder; ΖΠί includes a natural mineral powder, an inorganic waste, and a mixture thereof, such as inorganic waste. In the mud, soft lake mud, stone sludge abandoned ceramics iron slag, incinerator wire, etc.; high temperature ^ material refers to agricultural waste, livestock organic waste, g municipal organic waste or Jlf waste, etc. The bonding ship may be a composition of water, an organic or inorganic binder, which is a group consisting of water, acrylic resin, amine resin, melamine resin, cement, gypsum, kaolin and clay; The spherical core and the spherical shell part of the knottable powder and the binder may be composed of the same or different materials; the spherical core granulation forming: the purpose is to provide the above raw materials (sinterable powder: high temperature combustible material and reduction) Manufactured high-strength G water aseptic cultivation medium granules spherical sphere part, wherein the granulation method ^ includes a casting method and a bag method; the casting method is to mix the powder raw material with the cement, mix the slurry, and water to the ball Release the film after curing the mold; The method consists of mixing small particles of powder with cementing liquid in a manner of soaking, damp or powder drying, etc. to layer the layer to the specified particle size; and compacting in the spherical shell: the purpose is to complete the high-strength water-preserving aseptic cultivation medium. The dense spherical shell portion of the particle, wherein the bag compacting method can be the spherical ball portion manufactured by the above-mentioned ball centrifugation step, and the dense ball is layered and divided by means of soaking, dampness or powder drying. The shell part of the raw material (sinterable powder and binder) is wrapped in the surface layer of the particle, and the spherical shell layer is compacted in a specified density state, and the above action is repeated until the thickness of the specified bag; the above compacting method may include successively Apply air pressure, hydraulic pressure, oil pressure and rolling method. "The ratio of the radius of the spherical core to the radius of the whole sphere is between 〇~〇99^心~very thin hollow sphere shell; and the size of the "granules" may be limited to a sphericity greater than 0.7. The average diameter of the open pores is less than 82 mm, and the ratio of the total open area of the surface shell to the total surface area of the surface shell is less than 0.2. The porosity of the dense spherical shell portion is 3〇%0 to >; Drying: The purpose is to dry the product obtained in the compacting step of the spherical shell. The drying time and temperature vary according to the raw material and composition ratio; dry at 70~150 °C, and the drying time is between 〜5~48 hours. It is the optimum range; ' (e) High-temperature sintering: its purpose is to increase the particle strength of the medium particles, and the medium particles obtained by the above steps are sintered at a high temperature; wherein the sintering temperature is close to the dense shell layer sinterable powder is the most compact. The junction temperature is sintered, and the sintering temperature is closer to the most dense sintering temperature. The smaller the porosity, the higher the particle strength; the high temperature sintering temperature is between 1 and 2000 °C; '(f) w quality damage adjustment. The purpose is High or strong with different needs Sterile growing media water retention after adjustment of the composition of the particulate media, high temperature sintering 'comprises an acid and fertilizers adjusted experimental adjustment. Further, another object of the invention is to provide a high-strength water-retaining sterile cultivation medium particle produced by the manufacturing method of the present invention, the medium particle comprising a core portion and a dense spherical shell portion. A teaching book provides a kind of high-strength water-preserving aseptic cultivation medium ^; the I-type particles include a porous spherical core portion and a dense spherical shell portion of the shell portion of the gas-holding function '_球球叔本的-- the purpose is provided - High-strength water-retaining thief-free medium The medium particle includes a porous core portion and a dense spherical shell portion, and the first core portion is densely formed by including a sinterable powder or a high-temperature burnt-loss material. The spherical shell portion is composed of a sinterable powder and a squeezing powder, and the sinterable powder and the squeezing powder of the spherical core and the spherical shell portion are composed of the same or different materials. 1329667 Eight H's another object of the present invention is to provide a high-strength water-retaining bacteria carrier medium age including a porous core portion and a dense ball "material transfer 1 core portion by including sinterability Powder or high temperature can be burned and lost, and the dense spherical shell is transferred to the field; its towel, Guan Wenguan recorded its waste, including: agricultural organic waste, animal husbandry, organic waste or industrial waste. The sinterable powder = organic binder composition' and the organic and inorganic binder ammonium =::: select i water-saturated resin, amine-based resin, melamine eucalyptus cement, stone poor , kaolin or clay. Medium it', ΐϊίΐί A purpose is to provide a high-strength water-proof sterile cultivation of two shells. The reading particles have good stuffing balls, no surface of the ball, no size = and ί regular distribution of open pores, high strength, water retention Gas-proof, fertilizer-preserving, aseptic, 1, eve, sex and other functions. It has low price, i harm environment and can be used in large quantities. ί石技读颗粒 can be widely used in agricultural planting media, landscape stone, filter stone, oxygen permeable material. Water-retaining materials, Construction of materials, soil improvement, etc. Another object of the present invention is to provide a high-strength water-proof Helmets 介质 介质 = medium particle size is · · _. 0 to _ ° C high temperature sintering, i-shaped ί - 'granular surface shell The maximum diameter of the largest open pores of the layer is less than 2mm, resulting in a porosity of G·(9) to 99% (ie, approximate to the heart (4) ") 'porous f sphere' and the overall size, the ball The nuclear ratio is between 99 and 99, and the cultivation medium has a pH of 4 to ι 〇. Another object of the present invention is to provide a high-strength water retention method, wherein the method utilizes organic waste at a high temperature and can be burned. The purely indispensable (four) ship, according to the theory of mechanical mechanics, 10 1329667, produces high-strength, water-preserving aseptic cultivation medium particles with high strength, high water retention, good sphericity, low price, environmentally sound and can be used in large quantities. The present invention will be described in detail by the following specific embodiments and with the accompanying drawings, and the following description is given by the following specific embodiments. Ceramic material The shrinkage and porosity at different temperatures, as shown in the second figure, which is a typical shrinkage and porosity curve of the ceramic material; and according to the experimental data of the theoretical analysis of the invention according to the invention The performance of the preferred embodiment ^3(a)-(c) and fourth (a)-(c) are respectively illustrated in the states of E=1〇〇GPa, ν=0·25, p=-iGPa Under the condition, the stress distribution map of the hollow spherical shells with different thicknesses under the action of “uniform pressure on the load” is “concentrated and evenly compressive stress”; accordingly, the purpose of the method is to provide a porous core with The high-strength water-retaining of the dense spherical shell, the medium of the culture medium, the cross-sectional view of which is shown in the fifth (a) - (f), in the preferred embodiment of the present invention, the dense shell and the porous core Mixing diagram; the i-th (a) diagram of pot 3 shows that the dense shell layer and the porous sphere core system use the same ceramic powder ^ (?) diagram to illustrate that the dense shell layer and the porous sphere core system use different ceramic powder, the figure shows the dense The shell layer is composed of two or more kinds of ceramic powders, and the fifth (d) two; the maximum gas content of the spherical center is indicated (like a hollow spherical shell), (e) The diagram shows that the minimum gas content of the f 々 ί ί 示意 ( (solid sphere) and the fifth (f) diagram illustrate the tunning of the square tl layer of colored soil; the following description of the preferred implementation steps of the creation Later, it will be more clear. However, the present invention is not subject to the following embodiment of the method of manufacturing a water-repellent aseptic cultivation medium granule of Nantutian t« invention, which can be compared with the volume ratio of wood chips 1:5, 1:3, 1:1 and 1:Q (solid) And using a pure soil amp & knotting agent to make a diameter 7 ball ball core with a ball granulator, and use the viscous 〃 7 as a compact shell sinterable powder and binder, wrapped with a rounding machine 1329667 roll Pressed to make 1mm, 3mm and 5mm dense spherical shells 'measured 9〇〇v, respectively】, 〇〇 ,, _ temperature, 介 _ ^ ^ ^ = = 哲, surface maximum opening hole size, and tube compression strength, with Early water retention, gas retention and particle strength. The high-strength planting medium particles have a porous spherical core and a dense spherical shell, including a lower burning loss: a ball " part (four) 11 material burning, a mixture of high temperature burnt material and a binder, dense ^ 1:... Machine waste and its mixed inorganic wastes such as mud, soft lake mud, stone St ΐϊ ΐϊ 铁 铁 、 、 、 、 、 、 、 、 、 、 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; No i stone sound; gram-type tree scorpion, amine-based resin, melamine resin, cement, Ϊ Ϊ 岭 and the soil of the composition of the group; and 'ball heart fish saki neighbors can burn, twin powder and The binder may be composed of the same or different materials; Λ - the step of: the purpose is to control the particle size of the above raw materials (sinterable powder, high and binder), including but not limited to, into the large particles The raw material is crushed, and the pulverizer is used in the 'breaking machine 戋 grinding machine. The output f ball _ the degree can be limited to 2 coffee. If the sinterable powder is non-end, the large particle size can be limited to 〇·5 coffee. 1; 玎 杨 于 in the granulation forming step: its purpose is to provide the above raw materials (can be burned High-strength water-preserving and sterilizing parts made of materials and binders, wherein the granulation method includes but is not limited to the removal of the film after solidification of the casting tool; the bag method:: soil: the slurry is poured into the ball mold or dusted It 3 powder small particles with sputum sputum to soak, wet layer by layer to the specified particle size, · " 匕 secret steps: its purpose is to complete high-strength water-protection cleavage 12 1329667

質顆粒緻密球殼部分,其中包裏壓密方法可係以上述球心造粒 步驟製造之球心圓球部分,以浸泡、濕裏或噴粉乾裏等方式, 分層分次將緻密質球殼部份原料(可燒結粉與黏結劑)包^於 顆粒表層,並以壓密方式使各球殼層達指定緻密狀態,反覆上 述動作至指定包裏厚度為止;上述壓密方式可包括但不限定於 逐次以施氣壓、施液壓、施油壓和滾動方式。「生粒」多孔質球 =半徑與整體圓球半徑比在〇〜〇.卯間(即實心〜極薄空心球 殼);且,「生粒」規格可限於球形度大於〇 7,表面殼層最大 開口孔洞平均直徑小於2腦,表面殼層開口孔洞面積之&合與 =二殼層總面積比小於〇· 2,緻密質球殼部份的孔隙率g “ 乾燥步驟 外.八a的係將球忒包裏壓密步驟中得到之產物乾 燦L乾燥時間及溫度依生料材質和組成比例而異;以7〇〜1 乾燥,乾燥時間介於〇. 5〜48小時為最適範圍; 兩溫燒結:其目的係提高高強度保水無菌栽培介質顆#立之顆 =度’將上述步驟得出之介質顆粒進行高 近緻密殼層可燒結性粉末最緻密燒結溫度進g燒结了 古1二溫度愈接近最緻密燒結溫度,孔隙率愈小,a dense spherical shell portion, wherein the bag compacting method may be a spherical core portion manufactured by the above-mentioned centripetal granulation step, in a manner of soaking, wet or dry powdering, stratifying and dividing the dense mass The spherical shell material (sinterable powder and binder) is coated on the surface layer of the particle, and the spherical shell layer is brought into a specified dense state in a compact manner, and the above action is repeated until the thickness of the specified bag; the above compacting method may include However, it is not limited to the application of air pressure, hydraulic pressure, oil pressure and rolling method. "Porous" porous sphere = radius to the radius of the whole sphere is between 〇~〇.卯(ie solid ~ very thin hollow spherical shell); and, "granule" specification can be limited to sphericity greater than 〇7, surface shell The average diameter of the largest open pores of the layer is less than 2 brains, the area of the open pores of the surface shell is & the ratio of the total area of the second shell is less than 〇·2, and the porosity of the dense spherical shell part is “outside the drying step. 8a The drying time and temperature of the product obtained in the compacting step of the ball bag are different depending on the material and composition ratio of the raw material; drying is performed at 7〇~1, and the drying time is between 〇. 5~48 hours is optimum. Scope; two-temperature sintering: the purpose is to improve the high-strength water-preserving aseptic cultivation medium particles #立之粒=度' The medium particles obtained by the above steps are subjected to the highest density of the high-nense dense shell sinterable powder. The temperature of the ancient 12 is closer to the most dense sintering temperature, and the porosity is smaller.

尚;高溫燒結溫度介於6〇〇至2〇〇〇。〇為最適範圍; 又。 強卢整!^驟:其目的係為不同需求而進行或不進行高 燒轉讀粒份調整,包括 利用圓球造粒機製造直徑7二球球心並 密殼層之可燒結性粉和黏結劑,_滾 做為, 緻密殼層材料之賴,經⑽叱燒 =麵上述Still; high temperature sintering temperature is between 6 〇〇 and 2 〇〇〇. 〇 is the optimal range; Strong Lu! ^: The purpose is to carry out high-heat transfer and grain adjustment for different needs, including the use of a ball granulator to make a sinterable powder and bond of a diameter of 7 two-ball core and a dense shell. Agent, _ roll as, the shell material of the dense shell, after (10) 叱 = = face above

Iff之纖縣 13 其中第六⑷與⑻ 之顆粒的外觀與内部結構之n sc黏土球殼 。。燒結後之顆粒外觀與:部^:、(c)與(d)圖說明以1_ 篇二實: 栽㈣心與緻㈣球狀轉度保水無菌 倾,並且該多孔質球心能達到最大含氣 ί殼包,料選擇、粉體製備、球心造粒成形、 “又〇表堙在乾爍、向溫燒結,其中: 土、| I;»原料^^擇夕孔質球心部份係藉由可燒結粉、高溫可燒类;M· ϋΐ結ΐ所構成混合物’緻密質球殼部份係藉由可燒結粉與 啟劑所構成’可燒結性粉包括但不限於天録物粉末、益^ ;;物及其混合物,無機廢棄物如於泥、軟湖泥ί5』 廢棄陶銳鐵廠爐渣、焚化爐底料;高 括農業有機廢棄物、畜敕右嬙麻鲞:曰包 麻奎μ 有機廢棄物、城市有機廢棄物或工業 3物^黏結劑係可為水、有機、無機性黏 3、壓克型樹脂、胺基樹脂、三聚氰_脂、水泥成 枯土之組成之族群中;並且,球心與球殼部份可^结 性叙與黏結劑,可為相同或不同材料所構成; 。 失材目的係控制上述原料(可燒結性粉、高溫可燒 材枓/、黏、、,。劑)粉末顆粒大小,包括但不限定於,以 =亍大顆粒原料夾碎、配合粉碎機、打碎機或磨粉機得到可_ ί 此1,為控管球殼緻密程度’所得原料粉體最大ί 大粒徑可限於〇.5咖内; 負々末的取 球心造粒成形:其目的係提供由上述原料(可燒結性粉、高 1329667 紐以財财錢栽培介質顆粒 鑄型法係將;粒方法包括但不限於禱型法及包裏法; =等》?法=體小顆粒配娜液以浸=裏= 物乾長τ方1逐層包裏至指定顆粒大小,· 粒緻密求3,係完成高強度保水無菌栽培介質顆 製二U包裏壓密方ΐ可係以上述球心造粒步驟 。圓求邛为,以浸泡、濕晨或喷粉乾裏等方式,八展 U將,密質球殼部份原料(可燒結粉與黏結 ^ 使各球殼層達指定緻密狀態, 以;^ ίΐ厚度為止;上述壓密方式可包括但不限定於逐次 -、把液壓、施油壓和滚動方式。「生粒」多孔質球心半 ^與「整^球半徑比在㈣·(即實〜極」 洞平始二」丨規格可限於球做大於G. 7,表硫層最大開口孔 ϋ^Γ、ΐη2ΐΓ ’表面殼層開口孔洞面積之總合與表面殼 層〜面積比小於〇·2,緻密質球殼部份的孔隙率為以下. 乾焊球殼包裏壓密步驟中得到之產物乾燥, ^時〒及溫度依生料材質和組成比例而異;卩?〇1Iff's Fixian 13 where the sixth (4) and (8) particles have the appearance and internal structure of the n sc clay sphere shell. . The appearance of the granules after sintering is as follows: Parts::, (c) and (d) are illustrated in the first paragraph: (4) The heart and the (4) spherical rotation ensure that the water is aseptically inclined, and the porous core can reach the maximum Gas 壳 shell package, material selection, powder preparation, spherical granulation forming, “also 〇 堙 堙 干 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 向 向 向 向 向 向 向The sinterable powder consists of a sinterable powder, a high-temperature flammable type, and a mixture of M and yttrium. The compacted spherical shell portion is composed of a sinterable powder and an initiator. The sinterable powder includes but is not limited to a natural record. Powder, Yi^;; and their mixture, inorganic waste such as mud, soft lake mud ί5』 abandoned Tao Rui iron plant slag, incinerator bottom material; high agricultural agricultural waste, livestock right 嫱 paralysis: 曰Bao Makui μ organic waste, urban organic waste or industrial 3 materials ^ bonding agent can be water, organic, inorganic adhesive 3, acrylic resin, amine resin, melamine - grease, cement into dry soil In the group of the composition; and the spherical core and the spherical shell portion can be combined with the bonding agent, which can be composed of the same or different materials; Control the powder size of the above-mentioned raw materials (sinterable powder, high-temperature combustible material 、 /, viscosity, agent), including but not limited to, crushed with 亍 large particle raw materials, with a crusher, broken Machine or mill can get _ ί ί, to control the tightness of the spherical shell, 'the maximum size of the raw material powder can be limited to 〇.5 coffee; 々 的 的 的 : : : : : : : : It is provided by the above-mentioned raw materials (sinterable powder, high 1329667 New Zealand for the cultivation of medium particles casting method; grain method including but not limited to prayer method and bag method; = etc.) method = small particles With the immersion = 里 = dry long τ side 1 layer by layer to the specified particle size, · granules to find 3, is to complete high-strength water retention aseptic cultivation medium granules in the two U bag in the compacted square can be The above-mentioned ball core granulation step. For the purpose of immersion, wet morning or spray dry, etc., eight exhibitions of U, dense spherical shell parts of raw materials (sinterable powder and bonding ^ make each spherical shell layer Specify the dense state, to the thickness of the ^^ ;; the above-mentioned compaction method may include but is not limited to successive-- hydraulic pressure, The oil pressure and the rolling method. The "grain" porous core half and the "the whole sphere radius ratio in (4) · (that is, the real ~ pole) hole flat two" 丨 specifications can be limited to the ball to do more than G. 7, The maximum open pores of the surface sulfur layer ϋ^Γ, ΐη2ΐΓ 'the total open area of the surface shell layer and the surface shell layer ~ area ratio is less than 〇 · 2, the porosity of the dense spherical shell part is below. Dry solder ball shell package The product obtained in the compacting step is dry, and the temperature and temperature vary depending on the raw material and composition ratio; 卩?〇1

燥,乾燥時間介於〇. 5〜48小時為最適範圍; L 縣:其目的係提高高強度保水無菌栽培介質顆粒之 度,將上述步驟得出之介質顆粒進行高溫燒結; 皿度以接近緻密殼層可燒結性粉末最贿燒結溫度 二i燒Ϊ溫度愈接近最緻密燒結溫度,孔隙率愈小,顆粒i X愈同,咼溫燒結溫度介於600至2〇〇〇。〇為最適範圍; ^質成份調整:其目的係為不同需求而進行或不進行 J保水無_培介_粒高溫燒結後之介㈣份調整,包J 不限於酸驗性調整和肥料調整; - 其中’於此實施例並以較佳方式表示:多孔質球 係以木屑與膠水為粉體原料,利用圓球造粒機製造直徑6聰& 15 刺用二二ΐίΐ水做為緻密殼層之可燒結性粉和黏結劑, /1ιηιη上述緻密殼層材料之球殼,經1000 水佯ϊ植栽2 為具緻密殼層與多孔f球心之高強度保 (tsu,tt’並且該多孔質球心能達到最大含氣量 ^ ^ :第七(a) _ (d)圖所示,係本發明第二實 =L夕)大含氣量情形(似中空球殼)示意圖;其中第 明以木屑與膠水做球心,包裹—黏土球 “結後之顆粒㈦與⑷圖說明以_ 篇三實施例 栽培球=密質球殼之高強度保水無菌 料辦:纽質球心部份储由可燒結粉、高溫 冓成ΐ合物,緻密質球殼部份係藉由可曉結粉 其混合物,無機廢棄物如職、軟湖泥、石泥: ,棄陶£煉鐵廠爐渣、焚化爐底渣等;高溫可 勺 工業 其 ϋίί機廢棄物、畜牧有機廢棄物、城市有機廢棄‘或广 tiUif系可為水、有機、無機性黏合劑組成物, 含爲X ^克垔树知、胺基樹脂、三聚氰銨樹脂、水泥、石膏、 ΰιίίΐ之組ί之族群中;並且,球心與球殼部份可燒結 生畚與黏結劑,可為相同或不同材料所構成; 燒生備:其目的係控制上述原料(可燒結性粉、高溫可 結劑)粉末顆粒大小,包括但不限定於,以夾碎 tun ’,控管球殼緻密程度’所得原料粉體最大 了限於2麵内,若可燒結性粉末屬非可塑性材質,粉末的 16 1329667 最大粒徑可限於0.5mm内; 高溫^^1;目的係提供由上述顧(可燒結性粉、 栽培介質顆 法;f型法係將粉體原料與膠結液:合漿體 等》f係由粉體小顆粒配合膠結液以』 或喷1气方式’逐層包裏至指定顆粒大小; ^设包_密:其目的係完成高強度 ==,其中包裏壓密方法可係以上 球心®球部分’以浸泡、濕裏或喷粉乾裏等方式,分= 二份原料(可燒結粉與黏結劑)包裏於顆^ Ιίίί"if?上述壓密方式可包括但不限定於逐次 以轭氧壓、施液壓、施油壓和滾動方式。「生粒」多孔 ,與「整體圓球半徑比在㈣卵間(即實心〜極薄空心球殼); 汩巫ϋ立?規格可限於球形度大於〇.7,表面殼層最大開口孔 =句直徑小於2麵’表面殼層開口孔洞面積之總合與表面殼 層w面積α比小於〇. 2,緻密質球殼部份的孔隙率為3〇%以下; α乾燥:其目的係將球殼包裏壓密步驟中得到之產物乾燥, $燥時間及溫度依生料材質和組成比例而異;以7〇〜15〇。(:乾 燥,乾燥時間介於〇. 5〜48小時為最適範圍; 向a〇L燒結.其目的係提高高強度保水無菌栽培介質顆粒之 $粒強度,將上述步驟得出之介質顆粒進行高溫燒結;其中燒 結溫度以接近緻密殼層可燒結性粉末最緻密燒結溫度i行燒 結,且燒結溫度愈接近最緻密燒結溫度,孔隙率愈小,顆粒強 度愈高;高溫燒結溫度介於600至2000°C為最適^圍; 介質成份調整:其目的係為不同需求而進行或不進行高強 度保水無菌栽培介質顆粒高溫燒結後之介質成份調整,包括但 不限於酸鹼性調整和肥料調整; 1329667 其中,於此實施例並以較佳方式表示:如第八(a)〜Drying, drying time is between 〇. 5~48 hours is the optimum range; L County: The purpose is to improve the degree of high-strength water-preserving aseptic cultivation medium particles, and the medium particles obtained by the above steps are sintered at a high temperature; The shell sinterable powder is the most brittle sintering temperature. The temperature is the closest to the most compact sintering temperature. The smaller the porosity, the more the particle i X is, and the sintering temperature is between 600 and 2 〇〇〇. 〇 is the optimum range; ^Quality composition adjustment: its purpose is to carry out different waters for different needs or not. _ _ _ granules after high temperature sintering (four) adjustment, package J is not limited to acidity adjustment and fertilizer adjustment; - wherein 'in this embodiment and in a preferred manner: the porous ball system uses wood chips and glue as a powder material, and uses a ball granulator to make a diameter of 6 Cong & 15 puncture with two or two ΐ ΐ ΐ water as a dense shell Layer of sinterable powder and binder, /1ιηιη The shell of the above-mentioned dense shell material, planted by 1000 leeches 2 is a high-strength protection with a dense shell and a porous f-ball (tsu, tt' and The porous core can reach the maximum gas content ^ ^ : The seventh (a) _ (d) figure is a schematic diagram of the second gas content of the present invention (like a hollow spherical shell); Using wood chips and glue to make the center of the ball, the package-clay ball "The particles after the knot (seven) and (4) illustrate the _ three examples of cultivation of the ball = dense ball shell of high-strength water-proof sterile material: New core part of the storage From the sinterable powder, the high temperature enthalpy into a chelate, the dense spherical shell part is made up of a mixture of the powder Inorganic waste, such as occupation, soft lake mud, stone mud: abandoning pottery, iron slag, incinerator bottom slag, etc.; high temperature can be used in the industry, ίί machine waste, livestock organic waste, urban organic waste 'or widely tiUif can be a composition of water, organic and inorganic binders, and is contained in the group of X ^ grams of eucalyptus, amine resin, melamine resin, cement, gypsum, ΰιίίΐ; The sinter can be sintered with the spherical shell and can be made of the same or different materials. The raw material is controlled to control the particle size of the above raw materials (sinterable powder, high temperature binder), including but not The raw material powder obtained by crushing tun ', and controlling the density of the spherical shell is limited to two sides. If the sinterable powder is non-plastic material, the maximum particle size of the powder 16 1329667 can be limited to 0.5 mm; High temperature ^^1; The purpose is to provide the above-mentioned Gu (sinterable powder, cultivation medium particle method; f-type system to powder raw material and cementing liquid: slurry, etc.) f series from powder small particles with cementing solution 』 or spray 1 gas way 'layer by layer to the finger Particle size; ^ Set package _ dense: its purpose is to complete high strength ==, where the bag compaction method can be used above the ball core® ball part to soak, wet or dry powder, etc., divided into two parts The raw material (sinterable powder and binder) is contained in the package ^ ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί Compared with the "integral sphere radius" between (four) eggs (that is, solid ~ very thin hollow spherical shell); 汩 ϋ ? ?? Specifications can be limited to sphericity greater than 〇.7, the largest open pores of the surface shell = sentence diameter less than 2 sides The ratio of the open pore area of the surface shell to the surface shell w area α ratio is less than 〇. 2, the porosity of the dense spherical shell portion is less than 3〇%; α dry: the purpose is to compact the spherical shell The product obtained in the step is dried, and the drying time and temperature vary depending on the raw material and composition ratio; 7〇~15〇. (: drying, drying time is between 〇. 5~48 hours is the optimum range; sintering to a〇L. The purpose is to increase the grain strength of the high-strength water-preserving aseptic cultivation medium particles, and the medium particles obtained by the above steps are subjected to high temperature. Sintering; wherein the sintering temperature is sintered near the densest sintering temperature of the dense shell sinterable powder, and the sintering temperature is closer to the most dense sintering temperature, the smaller the porosity, the higher the particle strength; the high temperature sintering temperature is between 600 and 2000 °C is the optimum fit; medium composition adjustment: its purpose is to adjust the medium composition after high-temperature sintering of high-strength water-preserving aseptic cultivation medium particles for different needs, including but not limited to acid-alkaline adjustment and fertilizer adjustment; 1329667 Wherein, this embodiment is represented in a preferred manner: as the eighth (a)~

圖所不,係分別說明在8〇〇t、90(rc、1〇〇(rc、與n〇〇t溫产 時^發明第三實施例黏土圓球顆粒燒結紅掠色系之景觀用皿石x ,夕孔質球心部份係以黏土為粉體原料,並以純水做為 ' ° 利用圓球造粒機製造直徑7mm實心黏土圓球球心,I 之可燒結性粉和黏結劑’利用滾圓機 lnim上述緻密殼層材料之球殼,經800°c、900它、1000 結後,分別呈現橙紅色、紅色與椋色等光亮色3 Γ、ί1”景觀用石。所得製品係為具緻密殼層與多孔質 球心之向強度保水保氣植栽介質材料。 、 描曰㈣財因重覆滾壓動作兼具拋光個,而得大幅 °且在本實施财,不= 至色各自不同,表面無須額外添釉料。 第四實施你丨 菌栽備多孔f來讀緻㈣球殼之高強度保水| 粒成升Γ ,=括f料選擇、粉體製備、球心造 又匕晨壓捃、乾燥、高溫燒結,其中: 材料與黏、ίί所部份係藉由可燒結粉、高溫可燒失 機料物及f 燒粉包括但雜於天_物粉末、益 “ίϋ、此合物,無機廢棄物如於泥、軟湖泥、石材料: 括ϊ章秘驗、焚化爐底轉;高溫可燒失材料传Ρ包 高嶺土成=旨、三聚氣鋪脂、水泥、石膏: 1329667 粕體製備.其目的係控制上述原料(可燒社、古田 ,失材料與黏結劑)粉末顆粒大小,包括但不限定於, 粒原”夾?、,粉碎機、打碎機或磨粉機得到ΐ ^一!·叙末,此外’為控官球殼緻密程度,所得原料粉體 粒徑可限於2mm内’若可燒結性躲屬非可齡㈣ 最大粒徑可限於〇. 5mm内; ' …球心造粒成形:其目的係提供由上述原料(可燒結性粉、 冋:可燒失材料與黏結劑)製造之高強度保水無菌栽培介質 粒球心圓球部分’其中造粒方法包括但不限於鑄型法 法;鑄型法係將粉體原料與膠結液混合漿體,澆灌至 1 固化後脫膜;包裏法係由粉體小顆粒配合膠結液以浸泡、、恳g 或喷粉乾裏等方式,逐層包裏至指定顆粒大小; …In the figure, it is explained that in the case of 8〇〇t, 90(rc, 1〇〇(rc, and n〇〇t), the third embodiment of the clay ball sinter sintered red smudged landscape dish was invented. Stone x, the core part of the core hole is made of clay as the powder material, and pure water is used as '°. The diameter of the 7mm solid clay ball core is made by the ball granulator, and the sinterable powder and bonding of I The agent 'utilizes the spherical shell of the above-mentioned dense shell material by the spheronizing machine lnim, and after 800 ° C, 900 it, 1000 knots, respectively, it presents orange, red, red and ochre bright colors 3 Γ, ί1" landscape stone. The system is a water-tight and gas-proof planting medium material with a tight shell and a porous core. The crucible (four) financial re-rolling action has both polishing and a large degree, and in this implementation, not = The color is different, the surface does not need to add additional glaze. The fourth implementation of your sputum bacteria planted porous f to read (four) the high strength of the spherical shell water retention | grain into the Γ, = including f material selection, powder preparation, ball core Made in the morning, dry, high-temperature sintering, in which: the material and the sticky, ίί part are made by sinterable powder, high temperature can be burnt The material and the f-burning powder include but are mixed with the _ powder, the benefit, the compound, the inorganic waste such as mud, soft lake mud, stone material: the seal of the scorpion, the bottom of the incinerator; The calcinable material is transferred to the kaolin clay, the triad gas, the cement, and the gypsum: 1329667. The purpose of the preparation is to control the powder size of the above raw materials (Coke, Gutian, lost material and binder). Including but not limited to, the granules are clamped, the pulverizer, the shredder or the mill is obtained ΐ ^一!· 末, and in addition, the density of the obtained raw material powder can be limited to Within 2mm, if the sinterability is non-ageable (4), the maximum particle size can be limited to 〇. 5mm; '...spherical granulation: the purpose is to provide the above raw materials (sinterable powder, sputum: burnt-loss material) The high-strength water-preserving aseptic cultivation medium granule core ball portion manufactured by the binder is composed of, but not limited to, the casting method; the casting method is to mix the powder material and the cement liquid into the slurry, and watering it to 1 Release film after curing; the bag method is made by mixing small particles of powder with cement solution to soak , 恳g or dry powder, etc., layer by layer to the specified particle size; ...

球殼包裏壓密:其目的係完成高強度保水無菌栽培介 =緻密球殼部分,其中包裏壓密方法可係以上述球心造粒步驟 製造之球心圓球部分,以浸泡、濕裏或喷粉乾裏等方式,分声 分次將緻密質球殼部份原料(可燒結粉與黏結劑)包裏於顆& 表層,並以壓密方式使各球殼層達指定緻密狀態,反覆上述動 作至指定包裏厚度為止;上述壓密方式可包括但不限定於逐次 以施氣壓、施液壓、施油壓和滾動方式。「生粒」多孔質球心 徑與整體圓球半徑比在〇〜0.99間(即實心〜極薄空心球殼); 且,「生粒」規格可限於球形度大於〇·7,表面殼層最大開""口孔 洞平均直徑小於2mm,表面殼層開口孔洞面積之總合與表面殼 層總面積比小於0.2,緻密質球殼部份的孔隙率為3〇%以下;AX 。乾燥:其目的係將球殼包裏壓密步驟中得到之產°物乾燥, 乾燥時間及溫度依生料材質和組成比例而異;以7〇〜15〇<>c乾 燥’乾燥時間介於〇. 5〜48小時為最適範圍; i 向溫燒結.其目的係提局南強度保水無菌栽培介質顆粒之 顆粒強度,將上述步驟得出之介質顆粒進行高溫燒結;、其中燒 結溫度以接近緻密殼層可燒結性粉末最緻密燒結^度^行燒 19 丄J/ =燒;,強 介質成份調整♦•其目的係為不同為取適範圍;The ball-shell bag is compacted: the purpose is to complete the high-strength water-retaining aseptic cultivation medium=compact ball shell part, wherein the bag inner compacting method can be the ball core ball part manufactured by the above-mentioned ball core granulation step to soak and wet In the way of dry powder or dry powder, the parts of the dense spherical shell (sinterable powder and binder) are placed on the surface of the pellets in a sounding manner, and the shells are densely specified in a compact manner. The state repeats the above action until the thickness of the specified bag; the above-mentioned compaction mode may include, but is not limited to, successively applying air pressure, hydraulic pressure, oil pressure and rolling mode. The ratio of the radius of the porous sphere to the sphere of the whole sphere is between 〇 and 0.99 (that is, the solid to the extremely thin hollow sphere); and the specification of the "granule" can be limited to a sphericity greater than 〇·7, the surface shell The maximum opening "" mouth hole diameter is less than 2mm, the total surface area of the surface shell and the total area ratio of the surface shell layer is less than 0.2, and the porosity of the dense spherical shell portion is less than 3〇%; AX. Drying: The purpose is to dry the product obtained in the compacting step of the spherical shell. The drying time and temperature vary according to the raw material and composition ratio; drying time of 7〇~15〇<>c Between 5 and 48 hours is the optimum range; i is to the temperature sintering. The purpose is to improve the particle strength of the medium strength water-preserving aseptic cultivation medium particles, and the medium particles obtained by the above steps are sintered at a high temperature; wherein the sintering temperature is Close to the dense shell sinterable powder, the most compact sintering ^ ^ ^ burning 19 丄 J / = burning;, strong medium composition adjustment ♦ • its purpose is to take the appropriate range;

縣舰駿賴纽_心之植石栽 2i實:=四實施例中,由於製程中於最後表層添加有 度保水保:系之具敏密殼層與多孔質球心之高強 力ϊίίίί/ ^㈣提高職抗㈣度,降低強 伴皮粗>* 、s σ景觀性之製造方法,成功製造出高強度、高 機栽=質==繼宜、細境且可大量使用之無 旦©土發日〖之無機栽培介質顆粒除具保水保氣功能,對植物生 顯著助益,同時’本發财可顧於廢棄物處理及資源 iH·栽培ΐ質、景觀石、過據石、透氣材料、保水材料、 ^建^料與土壤改良。該®球顆粒可廣泛應用於農業栽培介 ^: 石、過濾石、透氣材料、保水材料、營建材料、土壤 己又等範疇。此外,本發明之產品可大幅採用國内廢棄物如木 20County Ship Chun Lai Xin _ heart plant stone plant 2i real: = four examples, because the process in the final surface layer added a degree of water protection: the system with a sensitive shell and porous core of high strength          (4) Improve the occupational resistance (four) degree, reduce the manufacturing method of strong skin with thick >*, s σ landscape, and successfully produce high-strength, high-planting=quality==continuous, fine-grained and can be used in large quantities. In addition to the water-holding and gas-holding function of the inorganic cultivation medium granules of the soil-issuing day, it has a significant benefit to the plant, and at the same time, 'this wealth can be considered for waste treatment and resources iH·cultivation enamel, landscape stone, stone, ventilation Materials, water retention materials, construction materials and soil improvement. The ® ball particles can be widely used in agricultural cultivation: stone, filter stone, gas permeable material, water retention material, construction materials, soil and so on. In addition, the product of the present invention can greatly utilize domestic waste such as wood 20

屑、稻殼、水庫淤泥和湖底淤泥等做為造粒原料,可將國内廢 棄物資源化再利用為高附加價值產品。 X 雖然本發明已以較佳實施例揭露如上,然其並非用以限定 本發8月,任何熟悉此項技藝者,在不脫離本發明之精神和範圍 内,當可做些許更動與潤飾,所作更動與潤飾仍屬於本發明後 附之申請專利範圍之内。 >【圖式簡單說明】 \ _ (f)圖’係目前國内銷售栽培介質與本發明栽培介 之外觀比較圖;其中第—(a)圖為唐山石、第—⑹圖為珍 、第一(C)圖為蛭石、第一(d)圖為日本石、第一(e) ,為發泡煉石、及第一(f)圖為新型介質; ’係,知技陶竟材料之典型的收縮與孔隙度曲線圖; 你人圖,說明於 E=100GPa、v=0. 25、P=_lGPa 狀態 “下在不同厚度巾空球殼受「均健應力」户作訂之應力分 Ύψ圓, ^ (a) - (c)圖,說明於E=1〇〇Gpa、ν=〇·四、『跳狀態 二、Z在不同厚度中空球殼受「針均佈壓應力」^作用下之應 力分佈圖; 千i 2 .U本發明較佳實施例中緻㉟殼層與多孔質 ί採:同、SS粉i 5圖說明緻密殼層與多孔質球心 係採用不同ΐ ί ) ®說明緻密殼層與多孔質球心 、(d)圖說明多孔質球心最大含氣量示意(似空 固圖說明多孔質球心最小含氣量示意(實心圓 球二之高強;伴)★圖位係本發明第一實施例具緻密殼層與多孔質 球妒之顆卜迤;木屑體積比1:5之球心材,包裹lmm黏土 球设之顆粒的外硯與内部結構、及第六(C)與⑷圖說明以 1329667 1000°C燒結後之顆粒外觀與内部結構; 第七(a) _ (d)圖,」係本發明第二實施例多孔質心人 量情,(似中空球^^意圖;其中第七(a)與(b)圖說明二木 屑與膠水做球心,〇裹1麵黏土球殼之顆粒外觀與内部妙 1七jc)與(d)圖說明以l〇〇〇°c燒結後之顆粒外觀與内部社 第八(a) - (d)圖’係分別說明在800°C、900°c、 11 oo°c溫度時,本發明第三實施例黏土圓球顆粒燒結紅卢與 景觀用石示意圖。 、休巴糸之 【主要元件符號說明】As a granulation raw material, scraps, rice husks, reservoir silt and mud at the bottom of the lake can recycle domestic wastes into high value-added products. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention. Any one skilled in the art can make some changes and refinements without departing from the spirit and scope of the present invention. Modifications and retouchings are still within the scope of the patent application appended hereto. >[Simplified illustration] \ _ (f) Figure ' is a comparison of the current domestic sales of cultivation medium and the cultivation of the present invention; wherein - (a) is Tangshan stone, the first - (6) picture is Jane, The first (C) picture is meteorite, the first (d) picture is Japanese stone, the first (e), the foaming stone, and the first (f) picture is a new medium; 'system, knowledge technology pottery The typical shrinkage and porosity curve of the material; your figure shows that in the state of E=100GPa, v=0. 25, P=_lGPa, the air ball shells of different thicknesses are subject to the “uniform stress”. Stress distribution circle, ^ (a) - (c) diagram, showing that E = 1 Gpa, ν = 〇 · four, "jumping state two, Z in the hollow shell of different thickness is subject to "needle uniform compressive stress" ^ Stress distribution diagram under the action; 千i 2 .U in the preferred embodiment of the invention, the 35 shell layer and the porous material: the same, the SS powder i 5 diagram shows that the dense shell layer and the porous spherical core system are different. ί ) ® indicates the dense shell and the porous core, and (d) shows the maximum gas content of the porous core. (The empty solid map indicates the minimum gas content of the porous core (the solid ball is high; accompanied) The figure is a dip of a dense shell layer and a porous sphere of the first embodiment of the present invention; a spherical core material having a wood pulp volume ratio of 1:5, an outer crucible and an internal structure of a particle coated with a lmm clay sphere, and a sixth (C) and (4) illustrate the appearance and internal structure of the particles after sintering at 1329667 1000 ° C; and the seventh (a) _ (d) diagram, which is a porous core of the second embodiment of the present invention, The ball ^^ intends; wherein the seventh (a) and (b) diagrams illustrate two sawdust and glue as the center of the ball, the surface of the spheroidal shell of the clay shell is wrapped and the inside of the shell is shown in the figure 1(c) and (d) The appearance of the particles after sintering and the eighth (a) - (d) diagram of the internal body illustrate the clay of the third embodiment of the present invention at temperatures of 800 ° C, 900 ° C, and 11 oo ° C, respectively. Schematic diagram of the spherical red sulphide and the stone used for the landscape.

22twenty two

Claims (1)

1329667 十、申請專利範圍: 1、一種尚強度保水無菌栽培介質顆粒之製造方法,該介質顆粒之 特徵在於§彡顆粒具有多孔質球心部分及緻密球殼部分,其中,多 ^質球〜部77主要提供栽培介質保水保氣功*,緻密質球殼部份 提供雜強度與控制水分魏,該方法係至少包括下列步驟: 2原料選擇步驟,係.、部分及贿質球殼部分之 原料,1329667 X. Patent application scope: 1. A method for manufacturing a sterile strength water-preserving aseptic cultivation medium particle, wherein the medium particle is characterized in that the 彡 particle has a porous spherical core portion and a dense spherical shell portion, wherein the multi-mass ball portion is 77 mainly provides the cultivation medium water retention and gas retention function*, and the dense spherical shell portion provides the impurity strength and the control moisture. The method includes at least the following steps: 2 the raw material selection step, the part, the part and the raw material of the brittle ball shell part, 娜職赠及緻密質球 係紅賴叙纽賊讀體以適當 將上絲備之雜質球殼 以乾^步驟,係依上述步驟產出之生料材質及組成比例以進行 倾,仙接近緻㈣層最緻結溫度進行上述 第1項所述之方法,其中更包括高溫燒結後 3、 ===;=方法’其中,該介質成份調整 4、 如申請專利範圍第1項所述之 之原料係包括可燒結性粉其巾,纽料心部份 5、 如申請專利範圍第i項所述之皿ο失^料祕f劑所/且成。 之屌粗仫今紅去’其中,緻密質球殼部份 6、 :=?:ί、ί=ϊ結劑所纽成。 Λ Τ η月寻利辄圍第4或5項所沭夕+、J_ ^ _ 失材料係由有機廢棄物巾取得。、’ /、+ ’如溫可燒 、如申請糊範㈣6項所述之轉,射,該有機廢棄物係 23 1329667 包括農業有機廢棄物、畜牧有機廢棄物、城市有機廢棄物咬 工業有機廢棄物。 ~ 如申請專利範圍第4或5項所述之方法,其中,該可燒結性 粉係包括天然礦物粉末、無機廢棄物或其混合物。 m 如申請專利範圍第4或5項所述之方法,其中,該黏結劑係 可為水或有機、無機性黏合劑組成物。 如申請專利範圍第9項所述之方法,其中,該有機、無機性 黏合劑組成物包括:水、壓克型樹脂、胺基樹脂、三聚^銨 脂、水泥、石膏、高嶺土或粘土。 如申請專利範圍第4或5項所述之方法,其中,該粉體製 控制可燒結性粉之最大粒徑小於2mm。 如申請專利範圍第11項所述之方法,其中,該粉體製備 非可塑性之該可燒結性粉的最大粒徑小於〇 5mm。圍第1項所述之方法,其中,該乾燥溫度介於 侧之方法,其中,麵時間介於 ϊ!請圍第1項所述之方法,其中,該球心造粒方法=具脫合漿體,洗灌至圓 =1包裏於顆粒表層’並_密方式使各球殼層達指j 17、 如申凊專利範圍第16項所琉 施氣壓、施液壓、施油方法’其中該壓密方式係可如 18、 如申請專利範圍第丨項所万式。 介於600至2000^間❶ 法,其中,該咼溫燒結溫度 8、 9、 10 11 12 13 14 15 16 24Na's job and the compact ball are the red lyrics of the New Zealand thief, to properly prepare the raw material of the shell, and the raw materials and composition ratios produced by the above steps are used to pour. (4) The maximum junction temperature is the method described in the above item 1, which further comprises after high temperature sintering 3, ===; = method 'where the medium composition is adjusted 4, as described in claim 1 The raw material includes a sinterable powder and a towel thereof, and the core portion 5, as described in the patent application scope item i. After the rough red to go, 'the dense spherical shell part 6, :=?: ί, ί = ϊ 所 所 。 。. Λ Τ η月寻利辄围4 or 5 items + 、+, J_ ^ _ Lost materials are obtained from organic waste towels. , ' /, + ' such as Wen Ke Shao, such as the application of paste (4) 6 said transfer, the organic waste system 23 1329667 including agricultural organic waste, animal husbandry organic waste, urban organic waste bite industry organic waste Things. The method of claim 4, wherein the sinterable powder comprises natural mineral powder, inorganic waste or a mixture thereof. The method of claim 4, wherein the binder is water or an organic or inorganic binder composition. The method of claim 9, wherein the organic or inorganic binder composition comprises: water, a gram-type resin, an amine-based resin, a trimeric ammonium ester, cement, gypsum, kaolin or clay. The method of claim 4, wherein the powder system controls the sinterable powder to have a maximum particle size of less than 2 mm. The method of claim 11, wherein the powder has a non-plasticity, and the sinterable powder has a maximum particle diameter of less than 〇 5 mm. The method of claim 1, wherein the drying temperature is on the side, wherein the surface time is between ϊ! Please refer to the method according to the item 1, wherein the core granulation method = detachment Slurry, wash into the circle = 1 bag in the surface of the particle 'and _ dense way to make each shell layer up to j 17, as applied in the scope of the application of the 16th article of the scope of the application of pressure, hydraulic, oil application method The compacting method can be as in the case of 18, as in the scope of the patent application. Between 600 and 2000 ❶, wherein the enthalpy sintering temperature is 8, 9, 10 11 12 13 14 15 16 24
TW095112863A 2006-04-11 2006-04-11 High strength water-preserving aseptic particles of culture media and manufacturing method thereof TW200738849A (en)

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