1274024 九、發明說明： * 【發明所屬之技術領域】 本發明是有關於一種氣調保鮮與微波 :;有可=波加熱過程中具有自動調 【先前技術】 體内之有機_貞、殿粉與脂肪的氧化雜率速f监疏果 ίϊί?ίίί外，十年前即有Λί 5ί改ίϊϊί 基礎上的進-步提高貯藏保鮮效果 ，亦不同，-般而言’葉菜類蔬果其表面積 = 需空氣量大，減成熟老化與黃變鱗 氣^ f严$球莖類蔬果則因只有外表皮 ίίίίίί苎感，所以於貯運環境溫度、氧Z與ί ϋ反辰度的变化需求不尚，一般大氣環境中 ’在盛裝以生鮮蔬果並且將貯^境 5^5ί?二，溫度’以及降低氧氣濃度為2至15%與 上’此對於蔬果需要遠距離儲運配銷之大ϊί 產此—_包鮮用包裝材料之開發有其重要ί 球各國無不大力投入研發特殊蔬果包裝材料；目前市場上 對於蔬果保鮮的應用方法可以分兩大類，其一供3以之 6 1274024 調上石供氧氣與二氧化碳使 果得以延長保鮮期與優良品^ 得該環境下之蔬 較高，另一種為被動式氣體調)控軟硬體控制系統成本 用與及該包裝材料本身具有新陳代謝與守吸作 間内環境之氧氣與二氧化碳隨著時軋率，而使蔬果包裝空 上述兩種延長生鮮蔬果保之軟^^包包壯^^的應用成本較低。 延長生鮮蔬果的保鮮期限，但均益s ; :雖可以提供 包裝材料同時具有延長保鮮的匕?如本發明所揭露之 約介於20至200000 cc/(dayfm2 · = ϋ萬包材之氧氣透過率 舆生⑸此包裝材“氣： 產生之大量高溫高壓熱蒸氣限制："°周即與承叉微波加熱所 鮮』2言;52=了 率丄使具有生 包褒下，直接微波加熱烹體 須於包裝材料上搓洞、打孔或預先打開命壯;^於工煮調理w無 、u藉由複合膜上—組多數微觀間隙結s進^: 過壓（over pressure)自動調節，避备白壯^巫订:’皿回反熱疾m ^ίί,ίίίϊίί^ 致大 成2紐膜，抛上有其複雜ϊϊϊίίί^ -调控所需之透氧率與透二氧化碳率不能—體適乳 1274024 所產生巧提供密閉式微波加熱環境下 ff透氣性薄膜蔬果包裝式日微波么熱烹調，具有 T-die押出與單或雙軸工’均勻混練後藉吹袋⑻晴)或 axial tenter)，製得====了 two difflensi_ iSf ^ 5 (A1203)，均勻摻混5古她古八夕"平以匕欽Uia^或乳化鋁 4, 466, 931 . 4, 777, 073J5 34ΐ 655 ； 該類材料雖具有特殊透氣性，5而言， 歸或聚丙稀，機ίί=ϊ3ίϊί之聚乙 ί^Ι ίίίίίϊ:【三】原料配方中常需加人其他添加劑如 ϊϊίΐίϊί中，也常造成不愉快的異味(unpleasant ， ίϊίίί有較弱機械強度與溶點偏低，無法應用於密閉式包裝 下^波加熱過程，此常會導致持續受熱過程中有過度延伸與 之虞0 、义 2二^塑膠^料摻混一低分子量成份，如礦油，製膜後可以藉特殊 淬取洗出該礦油成份，實務製程上塑膠原料與礦油均勻 混，後藉T-die或casting製膜後再經溶劑淬取洗出該成份， ‘付一透氡性薄膜材料，製造原理屬於一種利用不相容之材料混 巧後製成薄膜，再使用溶劑萃取方法將其中某一成份溶洗出，而 形成具有孔洞狀結構之薄膜，如美國專利號碼3, 378, 507、 3, 310, 505、3, 607, 793、3, 812, 224、4247498、4, 466, 931 和 5, 928, 582案所揭露之技術，一般而言，該類材料雖具有特殊透氣 性’可以達到氣體調控包裝環境(Modif ied Atmosphere Packaging， MAP)功能需求，同樣的當於密閉式包裝下之微波加熱應用條件， 8 1274024 溫高壓熱蒸氣量而會有爆破之虞，同樣的，是 的未洗淨的礦油成份與食品接觸問題，與持續高溫受 尤、下之材料過度延伸與爆裂現象，均必須被考慮。 t〉，f巧材ί，如美國專利號碼5, 865, 926案所揭露之技 ‘合接氣ί質之不織布或是纖維布。然、而這些方法1274024 IX. Description of the invention: * [Technical field to which the invention belongs] The present invention relates to a modified atmosphere and microwave: there is an automatic adjustment in the process of wave heating; [previous technique] organic 贞, temple powder in the body With the oxidative rate of fat, it is 疏 ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ 5 5 5 5 5 5 5 5 5 5 5 5 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础 基础Large amount of air, reduced mature aging and yellowing scales ^ f strict $ bulbs fruits and vegetables because only the outer skin ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί In the atmosphere, 'in the fresh food and fruit and will store 5^5ί? 2, the temperature' and reduce the oxygen concentration of 2 to 15% and the above. This is the need for long-distance storage and distribution of fruits and vegetables. _ The development of packaging materials for fresh packaging has its important importance. All countries in the world have invested heavily in the research and development of special packaging materials for fruits and vegetables. At present, the application methods for the preservation of fruits and vegetables in the market can be divided into two categories, one for 3 to 6 1274024. oxygen With carbon dioxide, the fruit can be extended for the fresh-keeping period and the good product is better than the vegetable in the environment, and the other is the passive gas tone. The control software and hardware control system costs and the packaging material itself has metabolism and retention. The oxygen and carbon dioxide of the environment will be rolled at the same time, and the application of the above two kinds of extended fresh fruits and vegetables will be low. Extending the shelf life of fresh fruits and vegetables, but the benefits are s; : Although the packaging materials can be provided and have the advantages of prolonging the preservation of fresh water, as disclosed in the present invention, the oxygen permeation of about 20 to 200,000 cc / (day fm 2 · = 10,000 vouchers) Rate of hygiene (5) This packaging material "gas: a large number of high-temperature and high-pressure heat steam generated: "° week is the same as the microwave heating of the fork" 2 words; 52 = the rate of 丄 具有 具有 具有 , ,, direct microwave heating The cooking body must be holed, perforated or pre-opened on the packaging material; ^ in the cooking and conditioning w no, u through the composite film - the majority of the microscopic gap junction s into the ^: over pressure (over pressure) automatic adjustment , avoid white sturdy ^ witch set: 'Dish back anti-heat disease m ^ ίί, ί ί ί ί ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ Milk 1274024 is produced in a closed microwave heating environment, ff breathable film, fruit and vegetable packaging, microwave, hot cooking, with T-die extrusion and single or double-axis workers 'evenly mixed after blowing bag (8) sunny) or axial tenter) , made ==== two difflensi_ iSf ^ 5 (A1203), evenly blended 5古古古八夕"平以匕钦 Uia^ or emulsified aluminum 4, 466, 931. 4, 777, 073J5 34ΐ 655; although the material has special gas permeability, 5, or polypropylene, machine Ίί=ϊ3ίϊί聚乙ί^Ι ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料 原料The closed-package heating process, which often leads to excessive extension during continuous heating, and blends with a low-molecular weight component such as mineral oil, which can be specially extracted after film formation. The mineral oil component is washed out, and the plastic raw material is evenly mixed with the mineral oil in the practical process. After the film is formed by T-die or casting, the solvent is used to extract the component, and the manufacturing principle belongs to a transparent film material. A film formed by mixing incompatible materials and then using a solvent extraction method to dissolve a certain component to form a film having a hole-like structure, such as U.S. Patent Nos. 3, 378, 507, 3, 310 , 505, 3, 607, 793 3, 812, 224, 4247498, 4, 466, 931 and 5, 928, 582, the technology disclosed in general, although the material has a special gas permeability 'can achieve gas-conditioning packaging environment (Modif ied Atmosphere Packaging, MAP) functional requirements, the same as the microwave heating application conditions under the closed packaging, 8 1274024 high temperature hot steam volume will have the blast, the same, is the unwashed mineral oil and food contact problems, Both excessive elongation and bursting of materials with continuous high temperatures must be considered. t>, f 巧材, ί, as disclosed in the US Patent No. 5, 865, 926, ‘the combination of non-woven fabric or fiber cloth. However, these methods
Hi述ίίί僅具ί氣調保鮮功能但無密閉式微波加熱自動調 。&產免微波加熱或其他烹煮物品時，因食 膨脹現象而導致的氣爆現象，大多利用 力械式政孔加工薄膜(microperforated film) 二= (-cro hole, aperturl 結構，具有巨觀孔洞之透氣性包裝材料，一 e)7 令孔洞，雖然可以進行密閉式微波加熱亨調，;' 受的包裝材料特性，結果均會變成-高ϋί性 f 誠上’則氣調保鮮所需之低透氧轉低 調控透氣率之另一外包裝材料進行 ；有=5„可 膜，如此過度包裝也將增加包裝製程 = 保鮮 ，機械沖孔包裝材料做為蔬果包裝3 一般 日T除了蔬果周圍之各種氣體濃度幾乎盘界又‘二此 乎相同外，包裝袋外若有小昆蟲盘菌體浪度幾 再者其巨觀之孔洞結構，當於j巧孔洞， overtime microwave cooking)時，物 〇 柄古^| 二'，、、過転（abuse 而有變乾變硬之虞。 物。°仍有因加熱過程失水過多 所述之透氣性材料與製造製程方法 s物品同時具有密閉式微波加埶盥氣早鲧 ^ ’但均不適 重要的是其製造成本很高。…、礼雜_包裝材料應用，更 1 ’亡發明人則一直針對食品微波加埶 作改善，其中，發明人於早期提出申 衣體或益體材料 卞刈扠ffi曱叫亚經核准之台灣發明專利 9 1274024 522123的公告號「包裝袋盥勢Α ΐϋίί食品微波加熱袋能透氣性複合膜 作使用之特性，同時更氣性材料之缺點 二之水份被大量保留及其含有之 J耋夸加熱過程中，食 ，時清洗與水資源浪費成本。要$ ^貫濺於微波爐内， 調壓功能包裳材料於微波加熱前處3资^此—可逆性自動 程中可自動調節包裝材料本身所能 '二，式結構；於加熱過 ΐ 一，力溫度相關之可逆性結構結構。 性微波加熱使用方式有極大不同點二、次。丨開一開口之單次破壞 【發明内容】 本發明的主要目的就是在提供一種 > 自動調壓包裝裝置用複合膜與！f保鮮與微波加熱 包裝金體或袋體，在盛裝以生鮮薪果“力以用在各式蔬果 裝置於平常儲運過程可以保持封合，該包裝 !裝，即可直接進行藉微波、^^|=’士3需打開 並直接置於微波爐中加ί即可自冷珠室取出， ϊ發作產品與技術應 是第^2722、微12^^12^取2灣發明專利其公告號各別 置及势短上，έ士人座唬，本發明之自動調節壓力包裝裝 輾了^種技術，例如特殊微觀間隙結構(15) U觀間隙結構(15)輾壓輪組，主要用來製備自動調。壓包裝裝置中 10 1274024 性調節壓力基材膜層，製程中，係藉輾壓該基材膜層並 f二ίϊ亡ΐ上形成複數個微觀間隙結構而成，另外 上氣壓力程度需求’於設計上，可藉控制該基材膜層 姑f、形狀、分佈密度、分佈位置、基材膜層厚度與基 3決定’輾壓製程中所需之加工設備可以採用 次？=2對=以 rt4iSSi-^ ί 處理i^deningtreatment)方法而得最後所需 Ϊ行i面φ進行化學電解綱成均勾尖凸結構後i =»;鍍巧”械㈣者t _門階，輕【'輪’猎輕麗加工製程使得結構上具有複數個料 際需求具有不同之分間隙結構區域也可以因實 =機 ϊ;ί:^不 ί;ί?彈Sitr基材腹層材料、加工“？=^舆 所:ί ί:: JJ2: H，)結構之基 材膜之重量沒有減損，不同於傳統f由機械 11 1274024 ϊίί 物或表面電暈放電(_na discharse)過程中有高- ，化垸除物，此冲孔加工與電暈放電加工均會導致 = 減少且產生賴結構之高親孔聽構。致裏基材重置 =外，本發明所選用的尖突輾壓機構上的突出物 、金字塔型、四方錐型、多面角錐形、⑵jjj盆 ，型式，經過輾壓加工製程之後，於輾壓加工後，一;八。 1，由於本身具有之粘彈性(viscoelasticit )ϋ刀其 ^之巨觀結構上，外觀之巨觀結構將大部分 =3度調節控制之壓光輪組加工，使該基材 =多數微觀間隙結構(15)之類平面(pseud0 plan)t j ，型、金字塔型、四方錐型、多面角錐形%==^ 篇超壓光輪組，可以使該易撕性基材外觀更平整，ϋ3ΐί 本發明者在之前提出申請的pCT國際申請案其申請声 ρ^/=04/_88所揭示該具有自動透氣調壓基^芦上多數 ί15) ’參第8-1圖、第8—2圖、第8-= ^圖ί由 亡!^縫(151) (upper seam portion)與其表面上具有一成斜賢鄰 矢員尺山气邊緣結構(丨53)，和一閉合之下隙缝(丨52) (1〇虹 PA n)組合而成之一類似紋裂結構（155) (craze structure)， ，、中之下細縫閉合結構為相鄰兩邊緣界面相互接觸人 -密閉式微觀_結構(15)，結構上於沿著厚 至下隙缝底面⑽逐漸變窄直至 構，§貫際夸用於蔬果包裝用微波袋之加熱過程中， ' ^ 缝結構於未受熱或微波加熱初始階段，微波袋 勒、 補續，該随結構(15)初 田u波加熱持績進行過程中，因受密閉内壓逐漸葶 =，__(15)而得以進行 ίΐίί的^ ’重要的是，當作用於該膜之兩侧面具有力 ，於微波加熱過程中因一壓力差產生與作用， 始膨服且沿科行_絲面方向上，受表祕力 12 1274024 伸拉伸，膜上之微觀間隙結構（15)也開始受沿膜表面上切應力作 用而變為微張且逐漸具有透氣調壓性，需要注意的是，該彳^觀^ 構上沿膜厚度方向上由外而内逐漸閉合之紋裂結構（155)於加埶 逐漸增壓過程中，藉由微波袋内部少量由内而外之熱墓奢' 类、“ 雲移以調節袋中之高溫内建壓力以防包裝材料之爆裂'了‘大部份 ，果中的水份仍可被保留下來，另外於微波加熱過程中内n 费今苎維持在高於一大氣壓之加壓烹煮狀態，結構上，此一ί張 調節高溫高壓熱蒸氣之能力與受内外瞬間壓力差大小作用導ϋ 層延j申拉伸量有正變比例關係，相反的，當作用於膜上之壓力差 f除後，例如於微波加熱終止時，因為受内外壓力差作用而變 ^氣調壓性結構之微觀間隙結構（15)又將逐漸回復為原來之密閉 ^結構，所以此一特殊具有受增壓差作用逐漸微開與移除壓差逐 織間隙結構為—可逆式設計，以微波爐加熱氣調 被波袋中之甜玉米為例，甜玉米中水份受微波加熱作用下， 微波袋内部產上一高溫熱蒸氣壓與並由其所伴生之壓力差 作用於膜上，袋内壓力高於袋外之一大氣壓，當此一壓力差 壓膜底侧面（⑷時，該底膜上關閉之微觀間隙 =μ二沿者平行膜的表面方向逐漸延伸拉大而漸張開，同 膜層之間隙結構（15)也開始擴大，此受壓力差（350)作用 ，，艾開結構得以用來調節微波加熱過程中微波袋内所產 發ί，因此可以避免氣漲爆裂，本 自動調節壓力（pressure regulating)之 (丨5)與—般藉機械冲孔膜之透氣雜(Pressure 是不同的，前者加熱烹調過程屬於加壓烹煮， i'ii2i2i(PFeSSUre cooker)般，後者則是採用於一般一大 ’是在^出—種密閉式蔬果氣調保鮮與微波加 置用複合膜，包括一基材膜層，該基材膜層上 θ一組複數個微觀間隙結構’微觀間隙結構的幾何 微觀間隙結構的平均尺寸大小介於G.1微米至3 間?構鄰邊緣則屬物理緊密接觸性(Physically ;另外—封合膜層，可以覆蓋於該具有 複數個舰_、結構區域之_侧，該封合膜層係藉另一黏著層連 13 1274024 =合与量材f! ’接著於總 、ί2ί有微5⑺構，此第二:Ai2Si cc/(day · m2 · atm · 25t^pf^透過率約介於20至200000 cc/(day · m2 · atm · 25Hp^ 佳建議值為介於40至100000 盒體上蓋膜或袋贿合膜㈣用在各式生鮮蔬果之包裝 具有氣調保鮮所需求規格f j組複數個微觀間隙結構 調控包裝盒體或袋體内所需:之于與透二氧化碳氣體率， 層&料用複合膜，其中黏著 貼合製程，連結封合膜或藉黏著液塗佈、乾燥與 膜層’使最後之複合膜層隙結構區域的基材 包裝盤具上蓋膜，同時使該包裝裝置之包裝袋或 密閉式氣調保鮮包裝材料，且‘二署，二般室溫或冷藏溫度下為 IV联層，因受來自包裝梦 、〜二〜π T动T负鄱者層之 高屢熱蒸氣得穿透該第、熱過程所產生之高溫 後對黏著層表面枯著特性逐漸=32^於碰觸高_蒸氣 膜層下方之具有第-，此時緊鄰該封合 動調節高溫熱蒸氣過壓功能，使雙J管之基材膜層具有自 本發明即是依上揭具同一 而避免氣爆之虞。 果包襄盒體或袋體用之複合膜材為mi與微波加熱用之蔬 辱品尚未具有之包裝功能加以伸而明^去各種創作 ΐϊΐ及於微波加熱過程中所產生閉式氣 2溫蒸氣作用使預定黏著介面黏熱療氣能適時藉 g形成-透氣通道並導引高溫高壓^1:3;!=交界 (pressure regulating area)之證一二?:周即堡力區域 域之基材騎糾界大_力， 高屢熱蒸氣得穿透該第-所產生之高溫 14 1274024 裝盒體lfiSii55iS2列ίϊί能J服傳統密閉包 之氧氣與二氧化果包褒盤體與袋體内 裝置上i行拆封而自冷藏裝置取出直接置於任何力^ ί調保包裝用透氣性材料，此-蔬果 免此特殊包穿材‘外奉物污染，除了可以大量避 ίΐϊίίίϊί 齡需求、尺寸 調^福的’提出一種透氣性氣調保鮮與微波加熱自動 面積利用輾壓製程產生以第-組複數個微觀 膜芦係^ t於雜觀聰結構區域上藉黏著層貼合-封合 壓i程於全構’再於ΐ體複合膜沿厚度方向利用二次輾 袋或======調壓=合膜應用於密閉式包裝 所需的平衡氧氣與:氧到 產以溫力力if呈或盤具上蓋膜内蔬果受熱 著層由“大1^與高壓蒸氣將促使緊鄰之黏 部高、、田二「亚逐漸降低其層間黏著力，同時複合膜受内 擠延??？使得微朗隙結構延伸間隙開。 阻力較小之古二f，讀錢間隙結構區域處也逐漸變成一 加過壓安全調節區域’可避免該封裝蔬果袋因 …^衣内w艾累積之内建高熱與高壓蒸氣（innerbuiid即 15 1274024 p^essu]：ized steam)所導致之瞬間氣爆危險現象。另外本發 透氣性封裝袋’其上之第—組自動讎微觀間隙結構具 Μίίϊ與關可逆性細功能，對於躲可於微減熟後直 ί ΐί 封存冷权’備為往後仙，再食贿只要擺置入 ^元、衣置内’如微波爐’直接再復熱，短時間加熱孰食後即可撕 開=裝袋膜後直接使用該食品，另外該微觀“亦可避免 小％蟲不必要的入侵。 ^ 實施方式】 可niiH第i圖係本發明的實驗實例之一，其為一種氣調保鮮 i ί 2調，用65pmpET/膠層/pet/膠層/cpp複合 元醇聚siPu膠系’應用於熱封包裝生鮮甜玉 熱封覆蓋於—可微波加熱聚丙稀盤具長寬高各 八H 6. °fm與厚度0.6mm，其盤内裝填三只重量 二内之冷藏溫度5。。，上蓋膜除四周熱封邊緣外， f i16.Gcm x ΐ4·5αη，此上蓋膜上具有兩組微觀 觀間隙結構分部於長與寬為l4.5cm X 5〇η面 ^^^^貫^尸/膠層/卿’最主要是用來調節微波加熱 於壓熱蒸氣之内建過壓以防氣爆現象，另一組 」ί 膠層/ΡΕΤ/膠層/CPP複合膜厚度方向之第 ίίίίΓ ff f區域面積上，該區域面積上平均透氧率(_) ^^m$ratm—25°C，透二氧化碳率(C02TR)為 143000 氧氣、，产氣區面積大小，使盤具内之含 率i 乂二艾，?辰度5周節至具有減緩甜玉米新陳代謝_吸速 5%與5:30%的濃度’於此氣體濃度下具有延 ^ 9^*羊J限，於本貫施例中使用盤具之透氧率（02TR)約 (SH獻^ 入i年；㈣ 16 1274024 深S撕之甜玉米粒有重量減少與玉米穗轴心有 ，二，以總厚度5_之勝/膠層/教封性 1 ϊί ί氣，鮮f微波加熱自動調節壓用上蓋^:膠ί X 6 otm盘//〇 β上ΐίί封覆蓋於一長寬高為18.0cmx 16.5cm 波加熱聚丙稀盤具，盤内裝殖二只重量 皿丨κ负双边矹囬檟為16· 〇cm χ 14· 5cm，上蓋 且 =結構’第-組微觀間隙結構位於熱封性、寬4 士 i二if25(over pressure)以防氣爆現象，另一組微 T 上但不重豐於第一組微觀間隙結構 率(02TR)為56000 cc/m2—day-atm-25 、、鳶声乂別9:1^里/ i具内之動態平衡氧氣濃度與二氧化碳 ίϊ二甜玉米外觀正f、無發霉與無異味， 微波爐微波強火加熱5分鐘後可食用。 福人膜i制if：調保鮮與微波加熱自動調壓包裝裝置用 1^1¾ ίΐ/情上述兩實驗所得設計喊，參第3圖、第 ^JMC-1100 y、，18 Gan X 16.5αη X 6.Gan(長/寬/高)厚度G.6mm盤聚，具有 券=2一d^^^25C之透氧率(02TR)，内裝填有重量約500公 玉米，在包裝盒⑴盤具熱封邊緣開口端藉敎 2=253膜層（2)後，對該基材膜層（2)在覆設貼^ 對：全面積覆蓋貼合至基材膜層⑵的製^工程 更東ίΐίi膜層（?)一侧（即對應第一組微觀間隙結構區域 抵菩居佈f产著層⑷（如第5si) ’該封合膜層(3)其 k斧iiiit弟4圖），並於貼合後整體複合膜沿厚度的方向上 再利用輾觀程’於預設條狀區間2公分、5公分、1G公分與全面 17 1274024Hi ί ί 仅 仅 ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί ί & When microwave-free heating or other cooking materials are produced, the gas explosion caused by the expansion of food is mostly made of microperforated film (= cro hole, aperturl structure, with giant view) Perforated air-permeable packaging material, one e) 7-hole, although it can be closed microwave heating, "the characteristics of the packaging materials, the results will become - high ϋ 性 f 诚 诚 ” ” Another low-oxygen to low-regulation air permeability of the outer packaging material; there = = 5 „ film, so over-packaging will also increase the packaging process = preservation, mechanical punching packaging materials as fruit and vegetable packaging 3 general day T except fruits and vegetables The concentration of various gases around it is almost the same as that of the second circle. If there is a small insect disk outside the package, the pore structure of the giant body is a large pore structure, when it is overtime microwave cooking, The object 〇 handle ancient ^| two ',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Micro It is not important to increase the cost of manufacturing.... Early introduction of the garment or prosthetic material 卞刈 fork ffi 亚 亚 亚 亚 核准 核准 台湾 台湾 台湾 台湾 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品 食品The disadvantages of the more gas-soluble materials are that the water is largely retained and contains J. The heating process, food, cleaning and water waste costs. To be splashed in the microwave oven, the pressure-regulating function Before the microwave heating, the 3 resources can be automatically adjusted in the reversible automatic process. The structure of the packaging material itself can be 'two, type structure; after heating, the reversible structure of the force temperature is related. The microwave heating method is extremely large. The difference between the second and the second. The single break of the opening is opened. [The present invention] The main object of the present invention is to provide a composite film for the automatic pressure regulating packaging device and the f-preservation and microwave The hot-packed gold body or bag body is used in the fresh-keeping salary. “It can be used in various kinds of fruit and vegetable devices to keep the seal during the normal storage and transportation process. The package! Pack it, you can directly borrow the microwave, ^^|=' Shishi 3 needs to be opened and placed directly in the microwave oven. It can be taken out from the cold bead room. The product and technology of the sputum attack should be the second 2, 2, 12, 12, and 12 Bay invention patents. Shortly, the gentleman seat 唬, the automatic adjustment pressure packaging of the present invention is equipped with a variety of techniques, such as a special micro-gap structure (15) U-view gap structure (15) rolling wheel set, mainly used to prepare automatic adjustment. In the press-packing device, 10 1274024 adjusts the pressure base film layer. In the process, the base film layer is formed by pressing the base film layer, and a plurality of micro-gap structures are formed on the dead scorpion, and the upper gas pressure degree requirement is In design, by controlling the substrate film layer, shape, distribution density, distribution position, thickness of the substrate film layer and the base 3, the processing equipment required in the press process can be used twice. =2 pairs = rt4iSSi-^ ί processing i^deningtreatment) method and finally the required i-face φ for chemical electrolysis, the uniformity of the hook-shaped convex structure i =»; plating Qiao (four) t _ doorstep, Light ['wheel' hunting light processing process makes the structure have a plurality of inter-material requirements with different gap structure areas can also be due to the actual machine; ί: ^不ί; ί? bomb Sitr substrate abdominal material, machining"? =^舆:: ί ί:: JJ2: H,) The weight of the base film of the structure is not degraded, unlike the conventional f by the mechanical 11 1274024 ϊ ίί or the surface corona discharge (_na discharse) process is high - In the case of the decontamination, both the punching process and the corona discharge process result in a decrease in the high-porosity of the structure. In the case of the base substrate reset = outside, the protrusions on the pointed pressing mechanism selected by the present invention, pyramid type, square pyramid type, multi-faceted pyramid shape, (2) jjj basin, type, after the rolling process, in the rolling After processing, one; eight. 1, due to its own viscoelastic (viscoelasticit) knives its giant structure, the appearance of the giant structure will be most = 3 degree adjustment control of the calender wheel set, so that the substrate = most micro-gap structure ( 15) such as plane (pseud0 plan) tj, type, pyramid type, square pyramid type, multi-faceted pyramid type %==^ The super-calendering wheel set can make the easy-to-tear substrate look flatter, ϋ3ΐί The application for the pCT international application has been applied for the sound ρ^/=04/_88, which has an automatic gas-permeable pressure-regulating base. ^Lan on the majority ί15) 'Paragraphs 8-1, 8-2, 8- = ^图ί由死! ^ seam (151) (upper seam portion) and its surface has a slanting sacred yoke yam mountain edge structure (丨53), and a closed lower gap (丨52) (1 〇虹PA n) is a combination of a similar cleavage structure (155) (craze structure), and a lower-sleeve closed structure in which the adjacent two edge interfaces contact each other in a human-closed microscopic structure (15). The structure is gradually narrowed along the bottom surface (10) of the thick to the lower seam until the structure, § is used in the heating process of the microwave bag for packaging fruits and vegetables, ' ^ The seam structure is in the initial stage of unheated or microwave heating, and the microwave bag is stretched and replenished. During the process of heating with the structure (15), the initial pressure is gradually 葶 =, __ (15) It is important to make ίΐίί ^ 'Important, as the force applied to the two sides of the film, due to a pressure difference in the microwave heating process, the initial expansion and the direction along the line _ silk surface, subject to the secret Force 12 1274024 Stretching, the micro-gap structure (15) on the film is also beginning to be micro-sheeted along the surface of the film, and gradually has gas permeability and pressure regulation. It should be noted that the structure is The cleavage structure (155) which is gradually closed from the outside in the thickness direction of the film is gradually pressurized in the process of twisting, and a small amount of heat inside the microwave bag is used to adjust the heat to the tomb. The high temperature built-in pressure in the bag prevents the bursting of the packaging material, and the water in the fruit can still be retained. In addition, during the microwave heating process, the temperature is maintained above one atmosphere. Pressurized cooking state, structurally, this one adjusts high temperature and high pressure hot steaming The capacity is proportional to the magnitude of the difference between the internal and external transient pressures. In contrast, the pressure difference f used on the membrane is divided, for example, when the microwave heating is terminated, because it is subjected to internal and external The micro-gap structure (15) of the pressure-regulating structure will gradually return to the original closed structure, so this special has the effect of the differential pressure to gradually open and remove the pressure difference. The structure is - reversible design, taking the microwave oven to heat the atmosphere, the sweet corn in the bag is taken as an example. In the sweet corn, the water is heated by the microwave, and the microwave bag is internally produced with a high temperature hot vapor pressure and associated with it. The pressure difference acts on the membrane, and the pressure in the bag is higher than the atmospheric pressure outside the bag. When the pressure difference is on the bottom side of the film ((4), the microscopic gap on the base film is closed = the surface direction of the parallel film of the two edges) Gradually extended and gradually opened, the gap structure (15) with the film layer also began to expand, which is affected by the pressure difference (350), and the Ai Kai structure can be used to adjust the hair produced in the microwave bag during microwave heating. So you can avoid gas Burst, the pressure regulating (丨5) is different from the gas permeability of the mechanical punching film (Pressure is different, the former heating process is pressurized cooking, i'ii2i2i (PFeSSUre cooker) The latter is used in the general one of the 'combined-type-closed type of vegetable and fruit modified atmosphere preservation and microwave addition composite film, including a substrate film layer, the substrate film layer θ a plurality of micro gaps The average size of the geometric micro-gap structure of the structure 'micro-gap structure is between G.1 micron and 3? The adjacent edge is physically close contact (Physically; another - sealing film layer, which can cover a plurality of Ship_, the side of the structural area, the sealing film layer is connected by another adhesive layer 13 1274024 = combined with the material f! 'Next to the total, ί2ί has a micro 5 (7) structure, this second: Ai2Si cc / (day · m2 · atm · 25t^pf^ Transmittance is about 20 to 200,000 cc / (day · m2 · atm · 25Hp ^ Good recommended value is between 40 and 100000 boxes on the cover film or bag bribe film (four) used in each The packaging of fresh fruits and vegetables has the requirements of the atmosphere preservation and preservation. The structure of the gap is controlled by the package body or the bag body: the composite film with the carbon dioxide gas rate, the layer & material, wherein the adhesive bonding process, the joint sealing film or the adhesive coating, drying and film layer 'Making the substrate packaging tray of the final composite film gap structure area with a cover film, and at the same time making the packaging device of the packaging device or the closed atmosphere fresh-keeping packaging material, and the second unit, at room temperature or at refrigerating temperature IV joint layer, due to the high temperature and heat vapor from the packaging dream, ~2~π T moving T negative layer, the high temperature generated by the first and hot processes penetrates the surface of the adhesive layer and the characteristics of the dead layer gradually = 32^ Having the first-thickness under the high-vapor film layer, and at this time, the high-temperature heat vapor overpressure function is adjusted in close proximity to the sealing, so that the base film layer of the double J tube has the same And avoid the blast of gas. The composite membrane material used for the box or the bag body is a packaging function that mi and microwave heating use have not yet had the packaging function to extend, and the various types of creation and the closed gas 2 warm steam generated in the microwave heating process. The role of the predetermined adhesive interface sticky heat treatment gas can be formed by timely g-ventilation channel and guide high temperature and high pressure ^1:3;! = pressure regulating area of the certificate one or two?: week, the base of the Fortune region Ride the big _ force, high heat steam to penetrate the first - generated high temperature 14 1274024 Packing box lfiSii55iS2 column ίϊί can J traditional sealed bag of oxygen and dioxide fruit package body and body device The upper row is unpacked and taken out from the refrigerating device and placed directly on any force. ί 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护 护^福's 'proposed a gas-permeable modified atmosphere preservation and microwave heating automatic area utilization 辗 compression process to produce a first-group of multiple micro-film reeds ^ t on the complex view area of the adhesive layer adhesion-sealing pressure i Process in the whole body Thickness direction using secondary sputum bag or ====== pressure regulation = film is applied to the balance of oxygen required for closed packaging: oxygen to produce a force force if or the plate is covered with a film inside the cover of the fruit by the heat layer The large 1^ and high-pressure vapor will promote the high adhesion in the immediate vicinity, and the second phase of the field will gradually reduce the adhesion between the layers. At the same time, the composite film will be stretched by the internal expansion, so that the micro-gap structure extends the gap. Second f, the reading money gap structure area is gradually becoming an over-pressure safety adjustment area 'can avoid the package of fruit and vegetable bags due to ... ^ inside the clothing accumulation of built-in high heat and high pressure steam (innerbuiid ie 15 1274024 p^essu] : ized steam) caused by the phenomenon of instantaneous gas explosion. In addition, the first part of the gas-permeable package bag's automatic 雠 micro-gap structure has Μ ϊ ϊ ϊ 关 关 关 关 关 关 关 关 关 关 关 关 可 可 可 可 可 可 可 可 可Ϊ́ί Sealing the cold right 'prepared for the future fairy, then put a bribe into the ^ yuan, clothing inside the 'such as the microwave oven' directly reheat, short-time heating after the foraging can be torn open = use the bag film directly Food, in addition to the micro" can also avoid small % Unnecessary intrusion. ^ Embodiments niH i diagram is one of the experimental examples of the present invention, which is a modified atmosphere, ί 2 adjustment, with 65pmpET / glue layer / pet / glue layer / cpp compound alcohol poly siPu glue system 'application In the heat-sealed package, the fresh sweet jade heat seal is covered by the microwave-heatable polypropylene disk with a length, a width, a height of eight H 6. °fm and a thickness of 0.6 mm, and the disk is filled with three refrigerating temperatures of five weights. . The upper cover film is surrounded by heat-sealed edges, f i16.Gcm x ΐ4·5αη, and the upper cover film has two sets of microscopic gap structure sections with a length and a width of l4.5cm X 5〇n surface ^^^^ ^The corpse/adhesive layer/Qing' is mainly used to adjust the built-in overpressure of microwave heating in the autoclave to prevent gas explosion. The other group is the thickness of the layer/ΡΕΤ/胶/CPP composite film. The area of the ί f area, the average oxygen permeability (_) ^ ^ m $ ratm - 25 ° C, the carbon dioxide permeability (C02TR) is 143000 oxygen, the area of the gas producing area, so that the inside of the plate The content rate i 乂二艾, 辰辰5 weeks to slow down the metabolism of sweet corn _ the rate of 5% and 5:30% of the concentration 'has the extension of this gas concentration ^ 9 ^ * sheep J limit, in this The oxygen permeability (02TR) of the disc used in the application example is about (SH is given to i years; (iv) 16 1274024. The deep S teared sweet corn kernels have a weight reduction and the corn cobs have a total thickness, and the total thickness is 5_ The victory / glue layer / teaching seal 1 ϊί ί gas, fresh f microwave heating automatic adjustment pressure with the top cover ^: glue ί X 6 otm disk / / 〇 β upper ΐ ί 封 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖 覆盖Heating polypropylene The plate is filled with two weights 丨 κ negative bilateral 矹 槚 16 〇 χ cm χ 14· 5cm, upper cover and = structure 'the first group micro-gap structure is located in heat sealability, width 4 士 i two if25 (over pressure) to prevent gas explosion, another group of micro T but not heavy in the first group of micro-gap structure ratio (02TR) is 56000 cc / m2 - day-atm-25, 鸢 乂 9: 1^里/i with dynamic equilibrium oxygen concentration and carbon dioxide ϊ ϊ 甜 sweet corn appearance is f, no mold and no odor, microwave oven microwave heat for 5 minutes after eating. The automatic pressure regulating packaging device is designed with 1^13⁄4 ΐ 情 情 上述 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , .6mm disc gathers, has the oxygen permeability (02TR) of the coupon = 2 a d ^ ^ ^ 25C, the inside is filled with a weight of about 500 male corn, in the box (1) the heat sealed edge open end of the tray borrows 2 = 253 film layer (2) After that, the base film layer (2) is covered with a full-surface cover to the base film layer (2) on the side of the substrate (?) (ie, corresponding to the first a set of microscopic The gap structure area is in contact with the diarrhea fabric (4) (such as the 5th) 'the sealing film layer (3) its k-axe iiiit brother 4 picture), and after the lamination, the overall composite film is reused in the thickness direction辗观程' in the preset strip interval 2 cm, 5 cm, 1G cm and comprehensive 17 1274024
If 3有複數倾觀間隙結構區域(22) ’提供所 5透率與透二氧化碳氣體率，藉此，提供甜玉米於5 ⑦53職(2)的包裝盒(1)其内狀冷藏食品在 溫、（ff，圖、第6-_)，當食品受熱產生高 =播=5究氕乳#透過基材膜層⑵所具設之第一組微觀間隙 透氣調壓’並使相鄰之枯著層⑷開始因受高溫 對包裝盒^内部的内建過熱高壓蒸氣⑸㈤贈 C|up hot pressurized steam)便會循著不受封合膜am神淨 處往外進行調節過壓，藉此&將受Ί 持包裝盒⑴㈣的高溫統⑸不mi 失，確保加熱之食品不致變乾硬之美味維持。 里 8其2中圖基材裳^(同2)Λ具^之微觀間隙結構(15)，（參第Η圖、第 閉： ,^ 糸$上隙缝(151)(卿er seam portion)與一 f二構Sfi))(十0wer seam p，rtion)組合而成之一類似紋 f二，（155) (craze structure)(如第7圖），其中之下隙絲ρ』 言結構為相㈣邊緣界面相互摘合在—起彡 隙結構(15)，結構上於沿著厚度方向具有由上 巧縫底面(14)變窄直至最後接觸閉合的結構，實際(口 $裝33=熱過程中’下隙缝結構於未受熱或微波ϋΐϋ 内含有食物之内部產生之蒸氣壓不夠大時，間卩二士 A 的#此時全部微波能轉化為熱能將全部被侷ΐ 加，烹調該食品’當於微波加熱持續過2中， 口文岔閉咼溫尚壓熱蒸氣内建壓力逐漸累積升高作 ，微觀間隙結構(15)，需要注意的是斤 裂結卞(155)於加熱逐漸增溫增壓過財，藉_節少 =、、， 之熱瘵氣的透過遷移率以調節盤中之高溫内部過壓，^ 口卜 中的水份將被保留下來，微波加熱過程中内部基氣壓;二二; 時此南溫與高壓熱統會使相鄰之歸層⑷触氣^ 18 1274024 第i—B圖)而逐漸將粘膠軟化及使原先層間 一進行調節部份過度内建高溫高壓蒸氣以避 ί騎自動調壓包裝裝置用複合膜亦可應用 業⑤㈣=¾圖;置用這複種4裝 成(严’並钱體(61& 口心^鏈Λ口合邊 ί離ί i产裝置人冷藏食品後能便利作密閉封合。 ϋ出，透ί基材膜層’在成型前為利用輾壓製程來 所具微觀間隙結構區域(63)寬幅來取決出：需 圍之封合膜層⑺’基於製造方便性考量，封合膜而 义膜屏覆蓋貼合至基材膜層的製造工程較方便“盾著封 如Ϊ11圖）’該封合膜層⑺其枯著層⑻為對 a復故在基材膜層之微觀間隙結構區域（63)表層面（如 ，並於貼合後整體複合膜沿厚度的方向上再利用輾壓製程， 微觀間隙結構區域(63)上或不同面積區域上形成第二组 微觀間隙結構區域(64)，以提供袋體(61)内所需求規 ^之透氧氟率與透二氧化碳氣體率，而與蔬果呼吸速率間達到一 個能$長保鮮之動態平衡氧氣和二氧化碳濃度。 氣密式食品微波包裝袋為了提供足夠之自動調壓功能以防止 士口$日^破裂’需藉由微觀間隙結構區域(63)設計上有足夠的透氣 j節=積，當基材膜層厚度為80 μιτι或小於80 μηι時，最少需要有 全包裝袋總面積之3%以上為微觀間隙結構區域（63)，當基材膜層 ^介於80 μηι與160 μιτι間時，所需要之具有微觀間隙結構區& Cbd)面積最少為全包裝袋總面積之狨以上。 對這，密閉覆設有基材膜層的包裝袋（6)其内部之冷凍、冷藏食品 行微波加熱時（參第Π圖），當食品受熱產生高溫、高壓的 療，，即會透過基材膜層所具設之微觀間隙結構區域（63)，並使 相鄰之粘著層（8)開始因受熱蒸氣（9)滲透而逐漸將粘膠軟化及使 19 1274024 黏著介面黏著強度減弱，而使得塗佈以粘著層 體(61)之基材膜層，使包裝袋⑹内部的高^過‘ 不^封合膜層⑺遮覆之微觀間隙結構區域⑽處 來避免，裝袋⑹發生爆破，同時確保包裝袋⑹内 ^的咼軋不致大1流失，維持加熱過程中之食品的美味。 警盒(1)開口端的基材膜層（2)、或包裝袋⑹的袋體 疋含有一種材料以上，係可選自壓克力（acrylic)、If 3 has a plurality of observing gap structure areas (22) 'providing a permeability of 5 and a carbon dioxide gas permeability rate, thereby providing sweet corn in a box of 5 753 jobs (2) (1) , (ff, Fig., 6-_), when the food is heated to produce high = broadcast = 5 氕 氕 milk # through the substrate film layer (2) set the first set of micro-gap venting pressure regulation and make the adjacent dry At the beginning of the layer (4), due to the high temperature, the built-in superheated high-pressure steam inside the package (5) (5) (C) will be adjusted to over-press the unsealed membrane. The high temperature system (5) of the box (1) (4) will not be lost, ensuring that the heated food does not become dry and delicious. In the middle of the 8th, the substrate of the substrate is the same as the microscopic gap structure (15) of the cookware ^, (refer to the first map, the first closed: , ^ 糸 $ upper slit (151) (clear er seam portion) and One f two structure Sfi)) (10 wer seam p, rtion) is a combination of one of the similar lines f, (155) (craze structure) (as shown in Figure 7), in which the lower layer ρ 』 』 (4) The edge interfaces are mutually picked up in the crevice structure (15), and the structure has a structure which is narrowed from the upper surface (14) of the upper seam to the final contact and closed in the thickness direction, and the actual (portion: 33) The middle 'lower slit structure is not enough when the vapor pressure generated inside the unheated or microwaved food contains enough food. At this time, all the microwave energy converted into heat energy will be added and cooked. When the microwave heating continues for 2 times, the pressure of the internal pressure of the hot and cold steam is gradually increased, and the micro-gap structure (15) needs to be noted that the crucible crucible (155) is gradually increased in heating. The temperature is supercharged, and the heat transfer rate is adjusted by the heat transfer rate to adjust the high temperature internal overpressure in the disk. Retained, the internal base air pressure during microwave heating; 22; this south temperature and high pressure heat system will make the adjacent layer (4) touch the gas ^ 18 1274024 i-B) and gradually soften the viscose and make the original The interlayer is adjusted to partially over-built high-temperature and high-pressure steam to avoid the use of the composite film for the automatic pressure regulating packaging device. It can also be applied to the industry 5 (4) = 3⁄4 map; the use of this multiple seed 4 is installed (strict 'and money body (61 & mouth The heart ^ chain Λ 合 ί ί ί 产 产 产 产 装置 人 人 人 人 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏 冷藏63) The width is determined by: the sealing film layer (7) is required to be based on the convenience of manufacturing, and the sealing film is covered by the film covering the substrate. The manufacturing process is convenient. The sealing layer (7) has a dry layer (8) which is a surface layer of the micro-gap structure region (63) of the base film layer (for example, and after lamination, the overall composite film is in the direction of thickness) Forming a second set of microscopic gaps on the micro-gap structure region (63) or on different area regions by using a crucible pressing process The structural region (64) is provided to provide the oxygen permeable rate and the carbon dioxide gas rate required in the bag body (61), and to achieve a dynamic balance of oxygen and carbon dioxide concentration between the vegetable and fruit respiration rates. The dense food microwave packaging bag in order to provide sufficient automatic pressure regulating function to prevent the crater's rupture's need to be adequately ventilated by the micro-gap structure area (63). When it is 80 μmτι or less than 80 μηι, at least 3% of the total area of the full-package bag is required to be the micro-gap structure region (63). When the substrate film layer is between 80 μηι and 160 μιτι, it is required The area of the micro-gap structure area & Cbd) is at least the total area of the entire package. In this case, when the packaged bag (6) in which the base film layer is sealed is covered, the frozen and chilled food inside is heated by microwaves (see the figure), and when the food is heated to generate high temperature and high pressure, it will pass through the base. The micro-gap structure region (63) of the material film layer, and the adjacent adhesive layer (8) begins to soften the viscose due to the penetration of the hot vapor (9) and weakens the adhesion strength of the adhesive layer of the 19 1274024 adhesive layer. Therefore, the base film layer coated with the adhesive layer body (61) is avoided, and the inside of the packaging bag (6) is prevented from being covered by the micro-gap structure region (10) which is covered by the sealing film layer (7). The blasting occurs, and at the same time, it is ensured that the rolling in the packaging bag (6) is not lost, and the food in the heating process is maintained. The base film layer (2) at the open end of the police box (1) or the bag body of the packaging bag (6) contains one or more materials, and may be selected from acrylic,
♦酉日頜（polyester)、聚乙浠(polyethylene，PE)、聚丙烯 (polypropylene，PP)、聚醯胺（p〇iyamide)、乙烯苯乙烯共聚合 物（ethylene-styrene copolymer, ES)、環狀烯共聚合物gyclo olefin)、聚對苯二甲酸二乙酯（p〇iyethyiene terephthalate， PET)、聚乙烯醇(p〇iyVinyi aic〇h〇i，pva)、乙烯乙酸乙酯’ (ethylene-vinyl acetate，EVA)、乙烯-乙烯醇共聚合物 (ethylene vinyl alcohol， EVOH) 、Surlyn™ (Dupont ionomer離 子高分子化合物之商標名）、聚乙二醇對萘二曱酸酯 (polyettiylene naphthalate，PEN)、聚醚酮（p〇iy ether ether ketone，PEEK)、聚碳酸酯（polycarbonate, PC)、聚讽 (polysulfone)、聚亞醯胺（polyimide，PI)、聚丙烯氰 (polyacrylonitrile, PAN)、苯乙烯丙烯氰共聚合物（styrene acrylonitrile，SAN)、聚胺酯（polyurethane，PU)、尼龍♦ Polyester, polyethylene, PE, polypropylene, p〇iyamide, ethylene-styrene copolymer (ES), ring Gyclo olefin), polyethylene terephthalate (PET), polyvinyl alcohol (p〇iyVinyi aic〇h〇i, pva), ethyl acetate ethyl acetate' (ethylene- Vinyl acetate, EVA), ethylene vinyl alcohol (EVOH), SurlynTM (trade name of Dupont ionomer), polyethylene terephthalate (polyettiylene naphthalate, PEN) ), polyether ketone (PEEK), polycarbonate (PC), polysulfone, polyimide (PI), polyacrylonitrile (PAN), Styrene acrylonitrile (SAN), polyurethane (PU), nylon
(nylon)、躐紙、高分子多層共押出延伸膜、合成紙(Synfhetic paper)、玻璃紙(glassine paper)、高分子材料彼覆之紙材、紙 等材料或由以上材料所組合之一族群。(nylon), crepe paper, polymer multilayer coextruded stretch film, synthetic paper, glass paper, polymer material, paper, paper, etc. or a group of the above materials.
應用在上述包裝盒（1)開口端基材膜層（2)或包裝袋（6)袋體(61) 其微觀間隙結構區域(21、63)覆設的封合膜層至少是由一種材料 組合而成，係可選自由浠烴聚合物(polyolefin)、聚乙烯(PE)、 聚丙烯(PP)、聚酯膜(polyester film)、聚對苯二甲酸二乙酯 (polyethylene terephthalate，PET)、聚苯乙烯、聚氯乙烯、聚 乙二醇對萘二甲酸酯（polyethylene naplrthalate，PEN)、聚_酬I (poly ether ether ketone, PEEK)、聚碳酸酯（polycarbonate， PC)、聚亞醢胺（polyimide，PI)、聚硕l(polysulfone)、聚丙烯氰 (polyacrylonitrile，PAN)、壓克力（acrylic)、聚乙烯聚丙烯共 聚合物、乙烯苯乙稀共聚合物（ethylene-styrene copolymer， 20 1274024 ES)、環狀烯共聚合物（cyclo olefin)、聚乙烯醇(polyvinyl alcohol，PVA)、乙烯乙酸乙酯（ethylene-vinyl acetate，EVA)、 乙烯-乙烯醇共聚合物(ethylene vinyl alcohol, EVOH)、聚二氯 乙烯(polyvinyl dichloride，PVDC)、苯乙烯丙烯氰共聚合物 (styrene acrylonitrile, SAN)、聚胺酯（p〇lyurethane，PU)、 尼龍(nylon)、聚醯胺(polyamide)、乙烯苯乙烯共聚合物 (ethylene-styrene copolymer，ES)、或Surlyn™ (Dupont ionomer 離'^高分子化合物之商標名）、合成紙、躐紙、聚乙烯不織布、聚 丙稀不織布、無機物添加塑膠膜、合成紙(Synthetic paper)，或 多層共押出延伸膜、多層複合膜等材料或由以上材料所组合之二 族群。 並對上述封合膜層亦可選自於由塑膠膜貼合或蒸鍍一金屬層與氧 化後之複合膜所組成之一族群，並該金屬層選自鋁或鋁合金： 應用在上述包裝盒(1)開口端基材膜層（2)或包裝袋（6)袋體(61) 貼合之封合膜層（3、7)—侧層面均勻塗佈之粘著層（4、9)材料， 可選自亞克力聚合物(polyacrylics)、聚g旨類(p〇lyester)、烯烴 聚合物(polyolefin)、聚乙烯(PE)、聚丙烯(pp)、環狀烯共聚合 物（cyclo olefin)、聚乙烯醇(polyvinyl aic〇h〇i，pva)、乙烯 乙酸乙酯（ethylene-vinyl acetate，EVA)、乙稀-乙稀醇共聚合 物（ethylene vinyl alcohol, EV0H)、聚烯烴衍生膠(pol/0、lefin derivative adhesive)、聚醯胺（p〇lyamide，nyi〇n)、聚胺酯 (polyurethane，PU)、聚苯乙烯丁二烯共聚合物，聚乙烯聚丙烯 共聚合物^乙烯苯乙烯共聚合物(ES)、環狀烯共聚合物(cycl〇 olefin)、單液型底膠(primer)、兩液型底膠(primer)、橡膠 (rubbers)、熱溶膠(hot melt elastomers)、碎膠(silicone elastomers)、離子高分子化合物（i〇nomer)、熱可塑性膠(廿 plastic rubber)、棕櫚蠟、石蠟、微晶粒蠟、峰蠟、‘米糠蠟等 ，然蠟材料(natural wax)、聚乙烯(PE)合成壤、氧化g丙烯(PP) 樣、5^乙氧樹脂(ΡΕ0)蝶、與其他石油製品、礦油品、聚烯炉類 (polyolefin)、蠟品之氧化物合成蠟等人工合^犧材料 wax or syn仕ietic wax)、脂肪酸（fatty acid)及其衍生物、以及 澱，$其含澱粉質之衍生物等材料等材料或由以上'材料所組合之 一族群。其中該黏著層可以是全部或部分區域黏著覆蓋至且有複 數個微觀間隙結構區域基材膜層。 21The sealing film layer applied to the above-mentioned packaging box (1) open end base film layer (2) or packaging bag (6) bag body (61) whose microscopic gap structure region (21, 63) is applied is at least one material Combined, optional free polyolefin, polyethylene (PE), polypropylene (PP), polyester film (polyester film), polyethylene terephthalate (PET) , polystyrene, polyvinyl chloride, polyethylene naphthalate (PEN), poly ether ether ketone (PEEK), polycarbonate (PC), poly Polyimide (PI), polysulfone, polyacrylonitrile (PAN), acrylic, polyethylene polypropylene copolymer, ethylene styrene copolymer (ethylene-styrene) Copolymer, 20 1274024 ES), cycloolefin, polyvinyl alcohol (PVA), ethylene-vinyl acetate (EVA), ethylene-vinyl alcohol copolymer (ethylene) Vinyl alcohol, EVOH), polyvinyl dichloride (PVD) C), styrene acrylonitrile (SAN), polyurethane (PU), nylon (nylon), polyamide, ethylene styrene copolymer (ethylene-styrene copolymer, ES), or SurlynTM (Dupont ionomer from '^ polymer compound brand name), synthetic paper, crepe paper, polyethylene non-woven fabric, polypropylene non-woven fabric, inorganic plastic film, synthetic paper (Synthetic paper), or multi-layer co-extruded A material such as a stretched film, a multilayer composite film, or a combination of the above materials. The sealing film layer may also be selected from a group consisting of a metal film laminated or vapor-deposited with a metal layer and an oxidized composite film, and the metal layer is selected from aluminum or aluminum alloy: Box (1) Open end substrate film layer (2) or packaging bag (6) Bag body (61) Laminated sealing film layer (3, 7) - Adhesive layer uniformly coated on the side layer (4, 9) Material selected from the group consisting of polyacrylics, p〇lyester, olefin, polyethylene (PE), polypropylene (pp), cyclic olefinic copolymer (cyclo Olefin, polyvinyl avinyl® (pva), ethylene-vinyl acetate (EVA), ethylene vinyl alcohol (EVOH), polyolefin-derived Glue (pol/0, lefin derivative adhesive), polyfluorene (p〇lyamide, nyi〇n), polyurethane (PU), polystyrene butadiene copolymer, polyethylene polypropylene copolymer, ethylene Styrene copolymer (ES), cyclic olefin, single-liquid primer, two-liquid primer, rubber (rubb) Ers), hot melt elastomers, silicone elastomers, ionic polymer compounds (i〇nomer), thermoplastic rubber, palm wax, paraffin wax, microcrystalline wax, peak wax, 'rice wax, etc., natural wax, polyethylene (PE) synthetic soil, oxidized g-propylene (PP)-like, 5^ ethoxy resin (ΡΕ0) butterfly, and other petroleum products, mineral oil, polyolefin Materials such as polyolefins, oxides, waxes, waxes, waxes, waxes, waxes, waxes, and derivatives, and fatty acids, derivatives, and lakes. Such materials or a group of groups combined by the above 'materials'. Wherein the adhesive layer may be a substrate film layer which is adhered to all or part of the region and has a plurality of micro-gap structure regions. twenty one