TWI270333B - Organic electroluminescent display panel - Google Patents

Organic electroluminescent display panel Download PDF

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Publication number
TWI270333B
TWI270333B TW93140689A TW93140689A TWI270333B TW I270333 B TWI270333 B TW I270333B TW 93140689 A TW93140689 A TW 93140689A TW 93140689 A TW93140689 A TW 93140689A TW I270333 B TWI270333 B TW I270333B
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Taiwan
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organic electroluminescent
display panel
electroluminescent display
layer
substrate
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TW93140689A
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Chinese (zh)
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TW200517038A (en
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Hsien-Chang Lin
Chia-Hao Fan
Chun-Yi Hsu
Sin-Da Liao
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Ritdisplay Corp
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Abstract

An organic electroluminescent display panel comprises a substrate, at least one organic electroluminescent device and an encapsulation unit. The organic electroluminescent device sequentially comprises an optical modulation layer, a planarization layer, a first electrode, at least one organic functional layer and a second electrode over the substrate. The encapsulation unit is connected to the substrate for forming an airtight space where the organic electroluminescent device is disposed inside.

Description

1270333 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種有機電激發光顯示面板,特別關於 種具有阻隔水氣及/或氧氣知入結構之有機電激發光顯 不面板。 【先前技術】 近年來平面顯示器朝著1%亮度、平面化、輕薄以及省 能源的趨勢發展,有鑑於此,有機電激發光(〇EL)顯示 裝置成為目前光電產業中極欲發展的方向之一。有機電激 發光顯示裝置係利用有機官能性材料(organic functional materials)的自發光的特性來達到顯示效果,依照有機官 能性材料的分子量不同,可分為小分子有機電激發光顯示 裝置(small molecule OLED,SM-OLED)與高分子有機電 激發光顯示裝置(polymer light-emitting display,PLED ) 兩大類。 有機電激發光顯示裝置係由有機電激發光元件所構 成’為達全彩化之目的,目前有機電激發光顯示裝置主要 使用之全彩化技術可分為三種··第一種係採用R、G、B :原色為各自獨立之發光圖素的「三原色發光層法」,第 厂種係利用藍色材料配合紅、綠有機螢光體或白光配合 a、綠、藍有機營光體來產生各種顏色的「色變換結構 去」’第三種是以白色發光層搭配彩色濾光片的「彩色濾 光片法」;以色變換結構法的技術為例說明,如圖1所示, 1270333 全彩之有機電激發光顯示面板1係包含一有機電激發光元 件10、一平坦層1卜一色轉換層12以及一玻璃基板13 ; 色轉換層12係設置於玻璃基板13上,平坦層11係設置 於色轉換層12上,有機電激發光元件10係設置於平坦層 11上。其中,色轉換層12係具有複數個濾光片與複數個 色轉換膜,平坦層11則是為了平坦化色轉換層,而有機 電激發光元件10係具有一第一電極101、一有機官能層 102以及一第二電極103依序設置於平坦層11上,其作用 原理係當對電極施以電流時,使電洞和電子在有機官能層 102内再結合(recombination)而產生激子,使有機官能層 102依照其材料之特性例如白光材料而可產生一白光,再 藉由色轉換層12將有機電激發光元件10發射之白光轉換 成構成全彩所需的三原色光一藍光、綠光以及紅光。 由於有機電激發光元件10對於水氣及/或氧氣非常敏 感,為確保有機電激發光元件10的使用壽命,如圖1所 示,有機電激發光顯示面板1的製程尚包含一封裝製程, 以一封裝體14藉由一紫外光硬化膠15黏合於平坦層11 之上,形成一密閉空間,來保護有機電激發光元件10免 於水氣及/或氧氣之侵入;然而,就習知之結構來說,由於 平坦層11仍有部分裸露於密閉空間外,因而提供了水氣 及/或氧氣侵入之管道,因而會有破壞有機電激發光元件 10之隱憂。 爰因於此,如何提供一種有效隔離水氣及/或氧氣侵入 之有機電激發光顯示面板實為當前平面顯示器的重要課 1270333 題之一。 【發明内容】 有鑑於上述課題,本發明之目的為提供一種具有版隔 水氣及/或氧氣侵入結構之有機電激發光顯 示面板。 為達上述目的,依據本發明之一種有機電激發光顯示 面板包含-基板、至少_有機電激發光元件以及_封裳單 兀、。,其中’有機電激發光元件係依序包含一光學調變層、 二平坦層、一第一電極、至少一有機官能層與一第二電極 $又置於基板上;封裝單元係連結基板形成一密閉空間,有 機電激發光元件係位於密閉空間内。 一為達上述目的,依據本發明之另一種有機電激發光顯 不:板包含-基板、至少_有機電激發光元件、至少一阻 礙單70以及—封裝單元。其中,有機電激發光元件係依序 ^-光學調變層、一平坦層、一第一電極、至少一有機 SI層與—第二電極設置於基板上;阻礙單元係設置於基 板=上*封裝單元係覆蓋阻礙單元且與基板相連結以形成 您閉二間,有機電激發光元件係位於密閉空間内。 一為達上述目的,依據本發明之再一種有機電激發光顯 :面板包含-基板、至少一有機電激發光元件以及一封裝 單元。其中,有機電激發光元件係依序包含一光學調變 層平坦層、一第一電極、至少一有機官能層與一第二 電極认置於基板上,封裝單元係連結基板以形成—密閉空 間,使有機電激發光元件位於密閉空間内,且封裝單元之 1270333 至少一部分係與平坦層之側邊連結。 承上所述,因依據本發明之有機電激發光顯示面板係 將包含光學調變層以及平坦層之有機電激發光元件設置 於由封裝單元與基板相連結所形成的密閉空間内,且封裝 單元之至少一部分亦可與平坦層之侧邊連結,因此能有效 斷絕外界或基板端水氣及/或氧氣進入侵害有機官能性材 料之管道,又,本發明之有機電激發光顯示面板更具有至 少一阻礙單元設置於基板上,且由封裝單元所覆蓋,可用 以阻隔水氣及/或氧氣經由封裝單元進入元件,進而更加強 杜絕水氣及/或氧氣侵害有機電激發光元件之可能性,以提 高有機電激發光顯示面板之使用壽命。 【實施方式】 以下將參照相關圖式,說明依據本發明較佳實施例之 有機電激發光顯示面板,其中相同的元件將以相同的參照 符號加以說明。 第一實施例 請參照圖2所示,依據本發明第一實施例之有機電激 發光顯示面板2包含一基板20、至少一有機電激發光元件 21以及一封裝單元22。 有機電激發光元件21係設置於基板20上,其係依序 包含一光學調變層211、一平坦層212、一第一電極213、 至少一有機官能層214與一第二電極215。 封裝單元22係與基板20相連結以形成一密閉空間 1270333 23 ’有機電激發光元件21則係位於密閉空間23内。其中, 封裝單元22係可藉由一蓋板221搭配一黏著劑222,或以 一保護層(Passivation Layer)封装於有機電激發光顯示面 板2之基板20上;蓋板221係可為一蓋體型式(如圖2所 示)或為一平板型式。 承上所述,在本實施例中,基板2〇係可選自剛性基 板、柔性基板、玻璃基板、塑膠基板及矽基板至少其中之 一’且基板之材質係選自聚曱基丙稀曱酯、塑膠、高分子、 玻璃及矽至少其中之一。 有機電激發光元件21之光學調變層211係可依據實 際需要選自色轉換層、濾光層、光學多層膜及半鏡面層至 少其中之一;平坦層212係為平坦化光學調變層211,以 利第一電極213設置於其上,平坦層212 —般係為透明或 半透明,且材質包含例如壓克力等之聚合物構成。 第一電極213通常為陽極,其材質係可為導電之金屬 乳化物’導電之金屬氧化物係選自姻锡氧化物、銘辞氧化 物、銦鋅氧化物及編錫氧化物至少其中之一,例如係用:賤 鍍(sputtering)或離子電鍍(ion plating)等方式形成於平坦層 212之上。 θ 有機官能層214通常包含一電洞注入層、一電洞傳遞 層、一發光層、一電洞阻擋層、一電子傳遞層、一電子注 入層及其組合(圖中未顯示),有機官能層214係可利用蒸 鑛(evaporation)、旋轉塗佈(spin coating)、噴墨印刷(inkjet printing)、移轉(transfer)或印刷(printing)等方式形成於第 1270333 一電極213上。此外,有檢〜 藍光、綠光、紅光、白光:能層214所發射的光線可為 H 具他的單色光或單色組合之彩 第二電極215通常作為 質,導電材質係選自銘^陰f,其材質係可為導電材 金及其合金至少其中之-,2、銦、錫、猛、銅、銀、 . 、 再中含鎂之合金可為鎂銀合 辦鎂銦。金鎂錫合金、鐵銻合金祕碲合金,利 錄或離子⑽等方法形成於有機官能層214上。 此外,第電極213與第二電極215之材質與作為陰 %極之應用,係可依據實際f求而加以互換。 在本實加例中,如圖3所示,有機電激發光顯示面 2之有機電激發光元件21更包含至少一阻隔層216,設置 ^平坦層212與第一電極213之間,阻隔層川係用以陡 =平坦層212或基板20之成分轉移至有機官能層214,而 影響元件之使財命。阻隔層216係為透明或半透明,其 材質係選自金屬氧化物、金屬、氧切(si〇x)、氣化石夕 ⑸〜、氮氧化列Si〇xNy)及聚合物至少其中之—,且阻隔 層216至少其中之-之材質係可與第—電極213之材質相 同,其中,金屬氧化物係選自銦锡氧化物、紹辞氧化物、 銦鋅氧化物及鑛錫氧化物至少其中之―,金屬則係可選自 鋁、飼、鎮、銦、錫、猛、銅、銀、金及其合金至少其中 之-。阻隔層216係可包含一第—阻隔層217與一第二阪 隔層218(如圖4所示),第二阻隔層218可設置於第一阻隔 層217之上,第一阻隔層217之材質可選自上述之金屬氣 11 1270333 务或金屬’而第二阻隔層218之材質可選自氧化石夕、氮 '氮氧切及聚合物至少其中之—。 i 一實施存生 如圖 S把一 _ 所示,依據本發明第二實施例之有機電激發光 員示面板3包含一基板30、至少一有機電激發光元件31、 至夕阻礙單元33以及一封裝單元32。 勺人有機電激發光元件31係設置於基板30上,其係依序 一光學調變層311、一平坦層312、一第一電極313、 至夕一有機官能層314與一第二電極315。在本實施例中, ^機電激發光元件31係如第_實施例所述更可包含至少 如阻隔層316設置於平坦層312與第一電極313之間,且 一圖5所示,阻隔層316可包含一第一阻隔層$ η與一第 二随隔層318。 /且礙單元33係設置於基板30之上;封裝單元32係 3蓋阻礙單疋33且與基板30相連結以形成一密閉空間 4,有機電激發光元件3丨係位於密閉空間%内。其中, ,裂單元32亦如第一實施例所述,可藉由一蓋板321搭 •己一黏著劑322 ’或以—保護層封裝於基板3〇上。 ,如圖5所tf ’在本實施例中’有機電激發光顯示面板 係具有二阻礙單元33設置於基板3Q之上且圍繞有機電 ,發光元件31,阻礙衫33之材f係由包含聚合物例如 光限或壓克力等材質來構成。 承上所述,在本實施例中,基板3〇、有機電激發光元 件31之光學調變層311、平坦層312、阻隔層316、第一 12 1270333 電極313、有機官能層314及第二電極315與封裝單元& 之結構、材質、性質與設置方式係對應第一實施例相同之 元件所述,故在此不再贅述。 請再參照圖6所示,依據本發明第三實施例之有機電 激發光顯示面板4包含一基板40、至少一有機電激發光元 件41以及一封裝單元42。 70 有機電激發光元件41係設置於基板40上,且係依序 包含一光學調變層411、一平坦層412、一第一電極、 至少一有機官能層414與一第二電極415。此外,有機電 激發光元件41更包含至少一阻隔層416設置於平垣層4以 與第一電極413之間,如上所述,在本實施例中,阻隔層 4ΐό可包含一第一阻隔層417與一第二阻隔層418。辑 封裝單元42係與基板4〇相連結以形成一密閉空間 43,有機電激發光元件41係位於密閉空間43内,且封孽 早兀42之至少一部分係與平坦層412之侧邊相連結(如^ 6所示)。如上所述,封裝單元42可藉由一蓋板42ι與二 黏著劑422,或以一保護層連結於基板4〇上。 、 在本實施例中,基板4〇、有機電激發光元件4 學調變層411、平坦層412'阻隔層416、第一電極 有機官能層4Η*第二電極415與封裝單元42之3、 材質、性質與設置方式係對應第一實施例相同之元件所 述,故亦不在此贅述。 件所 綜上所述’依據本發明較佳實施例之有機電激發光 13 1270333 示面板係將包含光學調變層與平坦; 件設置於由封裝單元與基板相連結戶;形:激發光元 内,由於本實施例之有機電激發光顯示面=閉空間 於封裝單元外之平坦層結構圖案化以形=將習知裸蜀 内,另外,平坦層之側邊係可與封裝單元於雄、閉空間 連結,因此可有效阻隔水氣及/ κι少-部分和 性材料之管道,此外,本發害有機官能 可包含至少-阻礙單元的結構’並示面板更 以更加-層阻隔水氣及/或氧氣經早續覆蓋,用 障’進而達到有效降低水氣/氧氣侵入機早:進入之屏 可能性,並提高有機電激發光顯示面件之 土广上所述僅為舉例性,而非為限制性者。::: 本發明之精神與料’㈣其進行:㈣未脫離 應包含於後附之中請專利範圍中。4私改或變更,均 圖 圖式簡單說明】 圖1為一顯示習知之有機電激發光 顯示面板的示意 圖2為一顯示依據本發明第一 顯示面板的示意圖; 有機電激發; 圖3為一顯示依據本發明第一 顯示面板更包含阻隔層的示4圖;1有機電激發; 圖4為一顯示依據本發明第一 顯示面板之阻隔層包含第-阻隔層與第::有隔:電: 1270333 圖, 圖5為一顯示依據本發明第二實施例之有機電激發光 顯示面板的示意圖;以及 圖6為一顯示依據本發明第三實施例之有機電激發光 顯示面板的示意圖。 元件符號說明: 1 有機電激發光顯示面板 10 有機電激發光元件 101 第一電極 102 有機官能層 103 第二電極 11 平坦層 12 色轉換層 13 基板 14 封裝體 15 紫外光硬化膠 2 有機電激發光顯示面板 20 基板 21 有機電激發光元件 211 光學調變層 212 平坦層 213 第一電極 214 有機官能層 15 1270333 215 第二電極 216 阻隔層 217 第一阻隔層 218 第二阻隔層 22 封裝單元 221 蓋板 222 黏著劑 23 密閉空間 3 有機電激發光顯示面板 30 基板 31 有機電激發光元件 311 光學調變層 312 平坦層 313 第一電極 314 有機官能層 315 第二電極 316 阻隔層 317 第一阻隔層 318 第二阻隔層 32 封裝單元 321 蓋板 322 黏著劑 33 阻礙單元 34 密閉空間 1270333 j 4 有機電激發光顯示面板 40 基板 41 有機電激發光元件 411 光學調變層 412 平坦層 413 第一電極 414 有機官能層 ‘ 415 第二電極 416阻隔層 * 417 第一阻隔層 418 第二阻隔層 42 封裝單元 421蓋板 422黏著劑 43 密閉空間 171270333 IX. Description of the Invention: [Technical Field] The present invention relates to an organic electroluminescence display panel, and more particularly to an organic electroluminescence display panel having a moisture barrier and/or oxygen-incorporating structure. [Prior Art] In recent years, flat panel displays have been trending toward 1% brightness, flatness, thinness, and energy saving. In view of this, organic electroluminescent (〇EL) display devices have become the most desirable direction in the optoelectronic industry. One. The organic electroluminescent display device utilizes the self-luminous properties of organic functional materials to achieve a display effect, and can be classified into a small molecule organic electroluminescent display device according to the molecular weight of the organic functional material (small molecule). OLED, SM-OLED) and polymer light-emitting display (PLED) are two major categories. The organic electroluminescence display device is composed of organic electroluminescence elements, which is the purpose of full colorization. At present, the full colorization technology mainly used in organic electroluminescence display devices can be divided into three types. , G, B: The primary colors are the "three primary color luminescent layer method" of the independent illuminating elements. The first plant uses blue materials with red, green organic phosphors or white light to match a, green and blue organic luminescent bodies. The "color conversion structure" of the various colors is generated. The third type is the "color filter method" in which the white light-emitting layer is matched with the color filter. The technique of the color conversion structure method is taken as an example, as shown in FIG. The 1270333 full-color organic electroluminescent display panel 1 comprises an organic electroluminescent device 10, a flat layer 1 color conversion layer 12 and a glass substrate 13; the color conversion layer 12 is disposed on the glass substrate 13, a flat layer 11 is provided on the color conversion layer 12, and the organic electroluminescence element 10 is provided on the flat layer 11. The color conversion layer 12 has a plurality of filters and a plurality of color conversion films, and the flat layer 11 is for flattening the color conversion layer, and the organic electroluminescent device 10 has a first electrode 101 and an organic function. The layer 102 and a second electrode 103 are sequentially disposed on the flat layer 11. The principle of operation is that when a current is applied to the electrodes, the holes and electrons are recombined in the organic functional layer 102 to generate excitons. The organic functional layer 102 can generate a white light according to the characteristics of the material, such as a white light material, and convert the white light emitted by the organic electroluminescent device 10 into the three primary colors required for the full color by the color conversion layer 12, a blue light, a green light. And red light. Since the organic electroluminescent device 10 is very sensitive to moisture and/or oxygen, to ensure the service life of the organic electroluminescent device 10, as shown in FIG. 1, the process of the organic electroluminescent display panel 1 further includes a packaging process. A package 14 is adhered to the flat layer 11 by an ultraviolet curing adhesive 15 to form a sealed space to protect the organic electroluminescent device 10 from moisture and/or oxygen; however, it is known. In terms of structure, since the flat layer 11 is still partially exposed outside the sealed space, a pipe in which moisture and/or oxygen intrude is provided, and there is a concern that the organic electroluminescent element 10 is destroyed. Because of this, how to provide an organic electroluminescent display panel that effectively isolates moisture and/or oxygen intrusion is one of the important lessons of the current flat panel display 1270333. SUMMARY OF THE INVENTION In view of the above problems, an object of the present invention is to provide an organic electroluminescence display panel having a barrier water vapor and/or oxygen intrusion structure. To achieve the above object, an organic electroluminescent display panel according to the present invention comprises a substrate, at least an organic electroluminescence element, and a slab. The organic electroluminescent device comprises an optical modulation layer, a second planar layer, a first electrode, at least one organic functional layer and a second electrode on the substrate, and the package unit is formed on the substrate. In a confined space, the organic electroluminescent element is located in a confined space. In order to achieve the above object, another organic electroluminescent light according to the present invention is shown: the board comprises a substrate, at least an organic electroluminescent element, at least one blocking unit 70, and a package unit. The organic electroluminescent device is sequentially disposed on the substrate, and the second electrode, the first electrode, the at least one organic SI layer, and the second electrode are disposed on the substrate; the blocking unit is disposed on the substrate=up* The encapsulating unit covers the obstruction unit and is connected to the substrate to form a closed space, and the organic electroluminescent element is located in the sealed space. In order to achieve the above object, a further organic electroluminescent device according to the present invention comprises: a substrate comprising a substrate, at least one organic electroluminescent device, and a package unit. The organic electroluminescent device comprises an optical modulation layer flat layer, a first electrode, at least one organic functional layer and a second electrode disposed on the substrate, and the encapsulating unit is connected to the substrate to form a sealed space. The organic electroluminescent device is placed in the sealed space, and at least a portion of the encapsulating unit 1270333 is coupled to the side of the planar layer. As described above, the organic electroluminescent display panel according to the present invention is configured to dispose an organic electroluminescent device including an optical modulation layer and a planar layer in a sealed space formed by a package unit and a substrate, and packaged. At least a part of the unit can also be connected to the side of the flat layer, so that the external or substrate end moisture and/or oxygen can be effectively cut into the pipeline invading the organic functional material, and the organic electroluminescent display panel of the present invention further has At least one blocking unit is disposed on the substrate and covered by the packaging unit, and can be used to block moisture and/or oxygen from entering the component through the packaging unit, thereby further enhancing the possibility of preventing moisture and/or oxygen from invading the organic electroluminescent component. To improve the service life of the organic electroluminescent display panel. [Embodiment] Hereinafter, an organic electroluminescent display panel according to a preferred embodiment of the present invention will be described with reference to the accompanying drawings, wherein the same elements will be described with the same reference numerals. First Embodiment Referring to FIG. 2, an organic electroluminescent display panel 2 according to a first embodiment of the present invention includes a substrate 20, at least one organic electroluminescent element 21, and a package unit 22. The organic electroluminescent device 21 is disposed on the substrate 20, and includes an optical modulation layer 211, a flat layer 212, a first electrode 213, at least one organic functional layer 214 and a second electrode 215. The package unit 22 is coupled to the substrate 20 to form a sealed space. 1270333 23 ' The organic electroluminescent element 21 is located in the sealed space 23. The package unit 22 can be packaged on the substrate 20 of the organic electroluminescent display panel 2 by using a cover 221 with an adhesive 222 or a protective layer. The cover 221 can be a cover. The body type (as shown in Figure 2) or a flat type. As described above, in the embodiment, the substrate 2 can be selected from at least one of a rigid substrate, a flexible substrate, a glass substrate, a plastic substrate, and a germanium substrate, and the material of the substrate is selected from the group consisting of polyacrylonitrile. At least one of ester, plastic, polymer, glass and enamel. The optical modulation layer 211 of the organic electroluminescent device 21 can be selected from at least one of a color conversion layer, a filter layer, an optical multilayer film, and a semi-specular layer according to actual needs; the flat layer 212 is a planarized optical modulation layer. 211, the first electrode 213 is disposed thereon, and the flat layer 212 is generally transparent or translucent, and the material is composed of a polymer such as acryl. The first electrode 213 is usually an anode, and the material thereof is a conductive metal emulsion. The conductive metal oxide is selected from at least one of a tin oxide, an indium oxide, an indium zinc oxide, and a tin oxide. For example, it is formed on the flat layer 212 by means of sputtering or ion plating. The θ organic functional layer 214 generally comprises a hole injection layer, a hole transfer layer, a light-emitting layer, a hole barrier layer, an electron transport layer, an electron injection layer and a combination thereof (not shown), and an organic function. The layer 214 can be formed on the first electrode 213 of the 1270333 by means of evaporation, spin coating, inkjet printing, transfer, or printing. In addition, there are detected ~ blue light, green light, red light, white light: the light emitted by the energy layer 214 can be H. The color of the monochromatic light or the combination of the monochrome second electrode 215 is generally used as a quality, and the conductive material is selected from Ming ^ Yin f, its material can be at least one of the conductive gold and its alloy -, 2, indium, tin, fierce, copper, silver, and magnesium alloy can be magnesium and silver combined with magnesium indium. A gold-magnesium-tin alloy, a stellite alloy, an alloy or the like (10) is formed on the organic functional layer 214. Further, the materials of the first electrode 213 and the second electrode 215 and the application as the negative electrode can be interchanged according to the actual f. In the present embodiment, as shown in FIG. 3, the organic electroluminescent device 21 of the organic electroluminescent display surface 2 further includes at least one barrier layer 216 disposed between the planarization layer 212 and the first electrode 213, and a barrier layer. The Chuan system uses the composition of the steep = flat layer 212 or the substrate 20 to transfer to the organic functional layer 214, which affects the life of the component. The barrier layer 216 is transparent or translucent, and is made of a metal oxide, a metal, an oxygen cut (si〇x), a gasification stone (5)~, an oxynitride (Si?xNy), and at least a polymer thereof. The material of at least one of the barrier layers 216 may be the same as the material of the first electrode 213, wherein the metal oxide is selected from the group consisting of indium tin oxide, bismuth oxide, indium zinc oxide, and tin oxide. The metal may be selected from at least one of aluminum, feed, town, indium, tin, fierce, copper, silver, gold and alloys thereof. The barrier layer 216 can include a first barrier layer 217 and a second barrier layer 218 (shown in FIG. 4). The second barrier layer 218 can be disposed on the first barrier layer 217, and the first barrier layer 217 The material may be selected from the above-mentioned metal gas 11 1270333 or metal' and the material of the second barrier layer 218 may be selected from the group consisting of oxidized stone oxide, nitrogen oxynitride and at least one of the polymers. The organic electroluminescence indicator panel 3 according to the second embodiment of the present invention includes a substrate 30, at least one organic electroluminescent element 31, and an obstruction unit 33, as shown in FIG. A package unit 32. The scooping organic electroluminescent device 31 is disposed on the substrate 30, which is an optical modulation layer 311, a flat layer 312, a first electrode 313, an organic functional layer 314 and a second electrode 315. . In this embodiment, the electromechanical excitation light element 31 may further include at least the barrier layer 316 disposed between the flat layer 312 and the first electrode 313 as shown in the embodiment, and a barrier layer as shown in FIG. 316 can include a first barrier layer $η and a second spacer layer 318. And the blocking unit 33 is disposed on the substrate 30; the encapsulating unit 32 is a cover obstructing the single turn 33 and is coupled to the substrate 30 to form a sealed space 4, and the organic electroluminescent element 3 is located in the sealed space %. The splitting unit 32 is also encapsulated on the substrate 3 by a cover 321 or an adhesive layer as described in the first embodiment. As shown in FIG. 5, tf 'in the present embodiment, the organic electroluminescence display panel has two barrier units 33 disposed on the substrate 3Q and surrounding the organic light, and the light-emitting element 31 blocks the material of the shirt 33 from being aggregated. The material is composed of a material such as a light limit or an acryl. As described above, in the embodiment, the substrate 3, the optical modulation layer 311 of the organic electroluminescent device 31, the flat layer 312, the barrier layer 316, the first 12 1270333 electrode 313, the organic functional layer 314, and the second The structure, material, properties and arrangement of the electrode 315 and the package unit & are the same as those of the first embodiment, and therefore will not be described again. Referring to FIG. 6, the organic electroluminescent display panel 4 according to the third embodiment of the present invention comprises a substrate 40, at least one organic electroluminescent element 41, and a package unit 42. The organic electroluminescent element 41 is disposed on the substrate 40 and includes an optical modulation layer 411, a flat layer 412, a first electrode, at least one organic functional layer 414 and a second electrode 415. In addition, the organic electroluminescent device 41 further includes at least one barrier layer 416 disposed between the planar layer 4 and the first electrode 413. As described above, in the embodiment, the barrier layer 4A may include a first barrier layer 417. And a second barrier layer 418. The package unit 42 is coupled to the substrate 4 to form a sealed space 43. The organic electroluminescent element 41 is located in the sealed space 43 and at least a portion of the sealing layer 42 is coupled to the side of the flat layer 412. (as shown in ^6). As described above, the package unit 42 can be attached to the substrate 4 by a cover 42ι and a second adhesive 422, or with a protective layer. In this embodiment, the substrate 4, the organic electroluminescent device 4, the modulating layer 411, the flat layer 412' barrier layer 416, the first electrode organic functional layer 4 Η * the second electrode 415 and the package unit 42 The materials, properties, and arrangement are the same as those of the first embodiment, and therefore will not be described here. According to the preferred embodiment of the present invention, the organic electroluminescent light 13 1270333 panel will comprise an optical modulation layer and a flat; the device is disposed between the package unit and the substrate; shape: excitation light element In the embodiment, the organic electroluminescent display surface of the embodiment has a flat layer structure outside the package unit, and the pattern is formed in the shape of the blank. In addition, the side layer of the flat layer can be combined with the package unit. The closed space is connected, so that the water vapor and/or the κι-part and the material of the pipeline can be effectively blocked. In addition, the damaging organic function can include at least the structure of the obstruction unit and the panel is more layer-blocking moisture. And/or the oxygen is covered by the early use, and the barrier is used to effectively reduce the moisture/oxygen intrusion into the machine early: the possibility of entering the screen, and increasing the organic electroluminescence excitation light to show the surface of the surface is only an example, Not a restrictive one. ::: The spirit and material of the present invention' (4) It is carried out: (4) It is not included in the scope of the patent application. FIG. 1 is a schematic diagram showing a conventional organic electroluminescent display panel. FIG. 1 is a schematic view showing a first display panel according to the present invention; organic electric excitation; FIG. 3 is a schematic diagram FIG. 4 is a view showing a first display panel according to the present invention further including a barrier layer; FIG. 4 is a view showing that the barrier layer of the first display panel according to the present invention includes a first barrier layer and a:: 1270333, FIG. 5 is a schematic view showing an organic electroluminescent display panel according to a second embodiment of the present invention; and FIG. 6 is a schematic view showing an organic electroluminescent display panel according to a third embodiment of the present invention. Description of component symbols: 1 Organic electroluminescent display panel 10 Organic electroluminescent element 101 First electrode 102 Organic functional layer 103 Second electrode 11 Flat layer 12 Color conversion layer 13 Substrate 14 Package 15 Ultraviolet curing adhesive 2 Organic electric excitation Light display panel 20 substrate 21 organic electroluminescent element 211 optical modulation layer 212 flat layer 213 first electrode 214 organic functional layer 15 1270333 215 second electrode 216 barrier layer 217 first barrier layer 218 second barrier layer 22 encapsulation unit 221 Cover 222 Adhesive 23 Confined space 3 Organic electroluminescent display panel 30 Substrate 31 Organic electroluminescent element 311 Optical modulation layer 312 Flat layer 313 First electrode 314 Organic functional layer 315 Second electrode 316 Barrier layer 317 First barrier Layer 318 Second Barrier Layer 32 Package Unit 321 Cover Plate 322 Adhesive 33 Barrier Cell 34 Confined Space 1270333 j 4 Organic Electroluminescent Display Panel 40 Substrate 41 Organic Electroluminescent Element 411 Optical Modulation Layer 412 Flat Layer 413 First Electrode 414 organic functional layer '415 second electrode 416 barrier Layer * 417 First barrier layer 418 Second barrier layer 42 Package unit 421 Cover 422 Adhesive 43 Confined space 17

Claims (1)

1270333 十、申請專利範圍: 1、 一種有機電激發光顯示面板,包含: 一基板; 至少一有機電激發光元件,其係依序包含一光學調變 層、一平坦層、一第一電極、至少一有機官能層與 一第二電極設置於基板上;以及 一封裝單元,係連結基板形成一密閉空間,有機電激 發光元件係位於密閉空間内。 2、 如申請專利範圍第1項所述之有機電激發光顯示面板, 其中光學調變層係選自色轉換層、濾光層、光學多層膜 及半鏡面層至少其中之一。 3、 如申請專利範圍第1項所述之有機電激發光顯示面板, 其中平坦層係為透明或半透明。 4、 如申請專利範圍第3項所述之有機電激發光顯示面板, 其中平坦層係包含聚合物。 5、 如申請專利範圍第4項所述之有機電激發光顯示面板, 其中聚合物係為壓克力。 6、 如申請專利範圍第1項所述之有機電激發光顯示面板, 其中有機電激發光元件更包含: 18 1270333 至少一阻隔層,係設置於平坦層與第一電極之間。 7、 如申請專利範圍第6項所述之有機電激發光顯示面板, 其中阻隔層係包含一第一阻隔層與一第二阻隔層,第二 阻隔層係設置於第一阻隔層之上。 8、 如申請專利範圍第6項所述之有機電激發光顯示面板, 其中阻隔層係為透明或半透明。 9、 如申請專利範圍第8項所述之有機電激發光顯示面板, 其中阻隔層係選自金屬氧化物、金屬、氧化石夕、氮化石夕、 氮氧化石夕及聚合物至少莫中之一。 10、 如申請專利範圍第9項所述之有機電激發光顯示面 板,其中金屬氧化物係選自銦錫氧化物、鋁鋅氧化 物、銦鋅氧化物及锅錫氧化物至少其中之一。 11、 如申請專利範圍第1項所述之有機電激發光顯示面 板,其中基板係選自剛性基板、柔性基板、玻璃基板、 塑膠基板及矽基板至少其中之一。 12、 如申請專利範圍第1項所述之有機電激發光顯示面 板,其中基板之材質係選自聚甲基丙烯甲酯、塑膠、 高分子、玻璃及矽至少其中之一。 19 1270333 13、 如申請專利範圍第1項所述之有機電激發光顯示面 板,其中第一電極及/或第二電極係為導電之金屬氧化 物或導電材質。 14、 如申請專利範園第13項所述之有機電激發光顯示面 板,其中導電之金屬氧化物係選自銦錫氧化物、鋁鋅 氧化物、銦鋅氧化物及鎘錫氧化物至少其中之一。 15、 如申請專利範圍第13項所述之有機電激發光顯示面 板,其中導電材質係選自鋁、鈣、鎂、銦、錫、錳、 銅、銀、金及其合金至少其中之一。 16、 如申請專利範圍第15項所述之有機電激發光顯示面 板,其中含鎮之合金係為鎮銀合金、鎂銦合金、鎂錫 合金、鎂銻合金或鎮碲合金。 17、 如申請專利範圍第6項所述之有機電激發光顯示面 板,其中阻隔層至少其中之一之材質係與第一電極之 材質相同。 18、 如申請專利範圍第1項所述之有機電激發光顯示面 板,其中封裝單元係包含一蓋板與一黏著劑。 20 1270333 19、 如申請專利範圍第1項所述之有機電激發光顯示面 板,其中封裝單元係包含一保護層。 20、 一種有機電激發光顯示面板,包含: 一基板; 至少一有機電激發光元件,係依序包含一光學調變 層、一平坦層、一第一電極、至少一有機官能層與 一第二電極設置於基板上; 至少一阻礙單元,係設置於基板之上;以及 一封裝單元,係覆蓋阻礙單元且連結基板以形成一密 閉空間,有機電激發光元件係位於密閉空間内。 21、 如申請專利範圍第20項所述之有機電激發光顯示面 板’其中阻礙單元係包含聚合物。 22、 如申請專利範圍第21項所述之有機電激發光顯示面 板,其中聚合物係包含壓克力或光阻。 23、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中光學調變層係選自色轉換層、濾光層、光學 多層膜及半鏡面層至少其中之一。 24、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中平坦層係為透明或半透明。 21 1270333 25、 如申請專利範圍第24項所述之有機電激發光顯示面 板,其中平坦層係包含聚合物。 26、 如申請專利範圍第25項所述之有機電激發光顯示面 板,其中聚合物係為壓克力。 27、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中有機電激發光元件更包含: 至少一阻隔層,係設置於平坦層與第一電極之間。 28、 如申請專利範圍第27項所述之有機電激發光顯示面 板,其中阻隔層係包含一第一阻隔層與一第二阻隔 層,第二阻隔層係設置於第一阻隔層之上。 29、 如申請專利範圍第27項所述之有機電激發光顯示面 板,其中阻隔層係為透明或半透明。 30、 如申請專利範圍第29項所述之有機電激發光顯示面 板,其中阻隔層係選自金屬氧化物、金屬、氧化矽、 氮化矽、氮氧化矽及聚合物至少其中之一。 31、 如申請專利範圍第30項所述之有機電激發光顯示面 板,其中金屬氧化物係選自銦錫氧化物、鋁鋅氧化 22 1270333 物、姻辞氧化物及锡錫氧化物至少其中之一。 32、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中基板係選自剛性基板、柔性基板、玻璃基板、 塑膠基板及矽基板至少其中之一。 33、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中基板之材質係選自聚曱基丙烯曱酯、塑膠、 高分子、玻璃及矽至少其中之一。 34、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中第一電極及/或第二電極係為導電之金屬氧化 物或導電材質。 35、 如申請專利範圍第34項所述之有機電激發光顯示面 板,其中導電之金屬氧化物係選自銦錫氧化物、鋁辞 氧化物、銦鋅氧化物及鎘錫氧化物至少其中之一。 36、 如申請專利範圍第34項所述之有機電激發光顯示面 板,其中導電材質係選自鋁、鈣、鎂、銦、錫、錳、 銅、銀、金及其合金至少其中之一。 37、 如申請專利範圍第36項所述之有機電激發光顯示面 板,其中含鎂之合金係為鎂銀合金、鎂銦合金、鎂錫 23 1270333 合金、鎂銻合金或鎂碲合金。 38、 如申請專利範圍第27項所述之有機電激發光顯示面 板,其中阻隔層至少其中之一之材質係與第一電極之 材質相同。 39、 如申請專利範圍第20項所述之有機電激發光顯示面 板’其中封裝單元係包含一蓋板與一黏著劑。 40、 如申請專利範圍第20項所述之有機電激發光顯示面 板,其中封裝單元係包含一保護層。 41、 一種有機電激發光顯示面板,包含: 一基板; 至少一有機電激發光元件,其係依序包含一光學調變 層、一平坦層、一第一電極、至少一有機官能層與 一第二電極設置於基板上;以及 一封裝單元,係連結基板以形成一密閉空間,有機電 激發光元件係位於密閉空間内,且封裝單元之至少 一部分係與平坦層之側邊連結。 42、 如申請專利範圍第41項所述之有機電激發光顯示面 板,其中光學調變層係選自色轉換層、濾光層、光學 多層膜及半鏡面層至少其中之一。 24 1270333 43、 如申請專利範圍第41項所述之有機電激發光顯示面 板,其中平坦層係為透明或半透明。 44、 如申請專利範圍第43項所述之有機電激發光顯示面 板,其中平坦層係包含聚合物。 45、 如申請專利範圍第44項所述之有機電激發光顯示面 板,其中聚合物係為壓克力。 46、 如申請專利範圍第41項所述之有機電激發光顯示面 板,其中有機電激發光元件更包含: 至少一阻隔層,係設置於平坦層與第一電極之間。 47、 如申請專利範圍第46項所述之有機電激發光顯示面 板,其中阻隔層係包含一第一阻隔層與一第二阻隔 層,第二阻隔層係設置於第一阻隔層之上。 48、 如申請專利範圍第46項所述之有機電激發光顯示面 板,其中阻隔層係為透明或半透明。 49、 如申請專利範圍第48項所述之有機電激發光顯示面 板,其中阻隔層係選自金屬氧化物、金屬、氧化矽、 氮化矽、氮氧化矽及聚合物至少其中之一。 25 I270333 50 51 52 53 54 如申請專利範圍第49項所述之有機電激發光顯示面 板’其中金屬氧化物係選自銦錫氧化物、鋁鋅氧化 物、銦鋅氧化物及鎘錫氧化物至少其中之一。 如申請專利範圍第41項所述之有機電激發光顯示面 板’其中基板係選自剛性基板、柔性基板、玻璃基板、 塑膠基板及矽基板至少其中之一。 如申請專利範圍第41項所述之有機電激發光顯示面 板’其中基板之材質係選自聚甲基丙烯甲酯、塑膠、 高分子、玻璃及矽至少其中之一。 如申睛專利範圍第41項所述之有機電激發光顯示面 板,其中第一電極及/或第二電極係為導電之金屬氧化 物或導電材質。 如申請專利範圍第53項所述之有機電激發光顯示面 板,其中導電之金屬氧化物係選自銦錫氧化物、鋁鋅 氧化物、銦鋅氧化物及鎘錫氧化物至少其中之一。 如申請專利範圍第53項所述之有機電激發光顯示面 板’其中導電材質係選自鋁、約、鎂、銦、錫、鐘、 鋼、銀、金及其合金至少其中之一。 55 1270333 56、 如申請專利範圍第55項所述之有機電激發光顯示面 板,其中含鎂之合金係為鎂銀合金、鎂銦合金、鎂錫 合金、鎮銻合金或鎮碲合金。 57、 如申請專利範圍第46項所述之有機電激發光顯示面 板,其中阻隔層至少其中之一之材質係與第一電極之 材質相同。 58、 如申請專利範圍第41項所述之有機電激發光顯示面 板,其中封裝單元係包含一蓋板與一黏著劑。 59、 如申請專利範圍第41項所述之有機電激發光顯示面 板,其中封裝單元係包含一保護層。 271270333 X. Patent Application Range: 1. An organic electroluminescence display panel comprising: a substrate; at least one organic electroluminescent device, comprising an optical modulation layer, a flat layer, a first electrode, The at least one organic functional layer and a second electrode are disposed on the substrate; and a package unit is formed to form a sealed space by the connecting substrate, and the organic electroluminescent device is located in the sealed space. 2. The organic electroluminescent display panel of claim 1, wherein the optical modulation layer is selected from at least one of a color conversion layer, a filter layer, an optical multilayer film, and a semi-mirror layer. 3. The organic electroluminescent display panel of claim 1, wherein the flat layer is transparent or translucent. 4. The organic electroluminescent display panel of claim 3, wherein the flat layer comprises a polymer. 5. The organic electroluminescent display panel of claim 4, wherein the polymer is acrylic. 6. The organic electroluminescent display panel of claim 1, wherein the organic electroluminescent device further comprises: 18 1270333 at least one barrier layer disposed between the planar layer and the first electrode. 7. The organic electroluminescent display panel of claim 6, wherein the barrier layer comprises a first barrier layer and a second barrier layer, and the second barrier layer is disposed on the first barrier layer. 8. The organic electroluminescent display panel of claim 6, wherein the barrier layer is transparent or translucent. 9. The organic electroluminescent display panel of claim 8, wherein the barrier layer is selected from the group consisting of metal oxides, metals, oxidized oxides, cerium nitride, nitrous oxide oxides, and polymers. One. 10. The organic electroluminescent display panel according to claim 9, wherein the metal oxide is at least one selected from the group consisting of indium tin oxide, aluminum zinc oxide, indium zinc oxide, and pot tin oxide. 11. The organic electroluminescent display panel of claim 1, wherein the substrate is selected from at least one of a rigid substrate, a flexible substrate, a glass substrate, a plastic substrate, and a germanium substrate. 12. The organic electroluminescent display panel according to claim 1, wherein the material of the substrate is at least one selected from the group consisting of polymethyl methacrylate, plastic, polymer, glass and enamel. The organic electroluminescent display panel of claim 1, wherein the first electrode and/or the second electrode are electrically conductive metal oxides or conductive materials. 14. The organic electroluminescent display panel of claim 13, wherein the conductive metal oxide is selected from the group consisting of indium tin oxide, aluminum zinc oxide, indium zinc oxide, and cadmium tin oxide. one. 15. The organic electroluminescent display panel according to claim 13, wherein the conductive material is at least one selected from the group consisting of aluminum, calcium, magnesium, indium, tin, manganese, copper, silver, gold and alloys thereof. 16. The organic electroluminescent display panel according to claim 15, wherein the alloy containing the town is a silver alloy, a magnesium indium alloy, a magnesium tin alloy, a magnesium alloy or a strontium alloy. 17. The organic electroluminescent display panel of claim 6, wherein at least one of the barrier layers is made of the same material as the first electrode. 18. The organic electroluminescent display panel of claim 1, wherein the package unit comprises a cover and an adhesive. The organic electroluminescent display panel of claim 1, wherein the encapsulating unit comprises a protective layer. 20 . An organic electroluminescent display panel comprising: a substrate; at least one organic electroluminescent device, comprising an optical modulation layer, a flat layer, a first electrode, at least one organic functional layer and a first The two electrodes are disposed on the substrate; at least one blocking unit is disposed on the substrate; and a packaging unit covers the blocking unit and connects the substrate to form a sealed space, and the organic electroluminescent element is located in the sealed space. 21. The organic electroluminescent display panel as described in claim 20, wherein the hindrance unit comprises a polymer. 22. The organic electroluminescent display panel of claim 21, wherein the polymer comprises acrylic or photoresist. 23. The organic electroluminescent display panel of claim 20, wherein the optical modulation layer is selected from at least one of a color conversion layer, a filter layer, an optical multilayer film, and a semi-specular layer. 24. The organic electroluminescent display panel of claim 20, wherein the flat layer is transparent or translucent. The organic electroluminescent display panel of claim 24, wherein the flat layer comprises a polymer. 26. The organic electroluminescent display panel of claim 25, wherein the polymer is acrylic. The organic electroluminescent display panel of claim 20, wherein the organic electroluminescent device further comprises: at least one barrier layer disposed between the planar layer and the first electrode. The organic electroluminescent display panel of claim 27, wherein the barrier layer comprises a first barrier layer and a second barrier layer, and the second barrier layer is disposed on the first barrier layer. 29. The organic electroluminescent display panel of claim 27, wherein the barrier layer is transparent or translucent. 30. The organic electroluminescent display panel of claim 29, wherein the barrier layer is selected from the group consisting of metal oxides, metals, cerium oxide, cerium nitride, cerium oxynitride, and at least one of polymers. 31. The organic electroluminescent display panel according to claim 30, wherein the metal oxide is selected from the group consisting of indium tin oxide, aluminum zinc oxide 22 1270333, salt oxide and tin tin oxide. One. 32. The organic electroluminescent display panel of claim 20, wherein the substrate is selected from at least one of a rigid substrate, a flexible substrate, a glass substrate, a plastic substrate, and a germanium substrate. 33. The organic electroluminescent display panel according to claim 20, wherein the material of the substrate is at least one selected from the group consisting of polyacrylonitrile, plastic, polymer, glass and enamel. 34. The organic electroluminescent display panel of claim 20, wherein the first electrode and/or the second electrode is a conductive metal oxide or a conductive material. 35. The organic electroluminescent display panel of claim 34, wherein the conductive metal oxide is selected from the group consisting of indium tin oxide, aluminum oxide, indium zinc oxide, and cadmium tin oxide. One. 36. The organic electroluminescent display panel according to claim 34, wherein the conductive material is at least one selected from the group consisting of aluminum, calcium, magnesium, indium, tin, manganese, copper, silver, gold and alloys thereof. 37. The organic electroluminescence display panel according to claim 36, wherein the magnesium-containing alloy is a magnesium-silver alloy, a magnesium-indium alloy, a magnesium-tin 23 1270333 alloy, a magnesium-niobium alloy or a magnesium-niobium alloy. 38. The organic electroluminescent display panel of claim 27, wherein at least one of the barrier layers is made of the same material as the first electrode. 39. The organic electroluminescent display panel as claimed in claim 20, wherein the package unit comprises a cover and an adhesive. 40. The organic electroluminescent display panel of claim 20, wherein the encapsulating unit comprises a protective layer. 41. An organic electroluminescent display panel, comprising: a substrate; at least one organic electroluminescent device, comprising an optical modulation layer, a flat layer, a first electrode, at least one organic functional layer and one in sequence The second electrode is disposed on the substrate; and a package unit is configured to connect the substrate to form a sealed space, the organic electroluminescent device is located in the sealed space, and at least a portion of the package unit is coupled to the side of the flat layer. 42. The organic electroluminescent display panel of claim 41, wherein the optical modulation layer is selected from at least one of a color conversion layer, a filter layer, an optical multilayer film, and a semi-specular layer. The organic electroluminescent display panel of claim 41, wherein the flat layer is transparent or translucent. 44. The organic electroluminescent display panel of claim 43, wherein the planar layer comprises a polymer. 45. The organic electroluminescent display panel according to claim 44, wherein the polymer is acrylic. 46. The organic electroluminescent display panel of claim 41, wherein the organic electroluminescent device further comprises: at least one barrier layer disposed between the planar layer and the first electrode. 47. The organic electroluminescent display panel of claim 46, wherein the barrier layer comprises a first barrier layer and a second barrier layer, and the second barrier layer is disposed on the first barrier layer. 48. The organic electroluminescent display panel of claim 46, wherein the barrier layer is transparent or translucent. 49. The organic electroluminescent display panel of claim 48, wherein the barrier layer is selected from the group consisting of metal oxides, metals, cerium oxide, cerium nitride, cerium oxynitride, and at least one of polymers. 25 I270333 50 51 52 53 54 The organic electroluminescent display panel of claim 49, wherein the metal oxide is selected from the group consisting of indium tin oxide, aluminum zinc oxide, indium zinc oxide, and cadmium tin oxide. At least one of them. The organic electroluminescent display panel as described in claim 41, wherein the substrate is selected from at least one of a rigid substrate, a flexible substrate, a glass substrate, a plastic substrate, and a germanium substrate. The organic electroluminescent display panel as described in claim 41, wherein the material of the substrate is at least one selected from the group consisting of polymethyl methacrylate, plastic, polymer, glass and enamel. The organic electroluminescence display panel as described in claim 41, wherein the first electrode and/or the second electrode is a conductive metal oxide or a conductive material. The organic electroluminescent display panel of claim 53, wherein the electrically conductive metal oxide is selected from at least one of indium tin oxide, aluminum zinc oxide, indium zinc oxide, and cadmium tin oxide. The organic electroluminescent display panel as described in claim 53 wherein the conductive material is at least one selected from the group consisting of aluminum, about, magnesium, indium, tin, bell, steel, silver, gold, and alloys thereof. 55 1270333 56. The organic electroluminescent display panel according to claim 55, wherein the magnesium-containing alloy is a magnesium-silver alloy, a magnesium-indium alloy, a magnesium-tin alloy, a ballast alloy or a ballast alloy. 57. The organic electroluminescence display panel according to claim 46, wherein at least one of the barrier layers is made of the same material as the first electrode. 58. The organic electroluminescent display panel of claim 41, wherein the package unit comprises a cover and an adhesive. 59. The organic electroluminescent display panel of claim 41, wherein the encapsulating unit comprises a protective layer. 27
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