TWI249017B - Heat temperature raising system - Google Patents

Heat temperature raising system Download PDF

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Publication number
TWI249017B
TWI249017B TW88113850A TW88113850A TWI249017B TW I249017 B TWI249017 B TW I249017B TW 88113850 A TW88113850 A TW 88113850A TW 88113850 A TW88113850 A TW 88113850A TW I249017 B TWI249017 B TW I249017B
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Taiwan
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heat
medium
temperature
htr
heat transfer
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TW88113850A
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Chinese (zh)
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Sing-Wang Cheng
Hsiang-Jen Cheng
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Hsiang-Jen Cheng
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Abstract

Disclosed is a process and apparatus for transferring heat from a heat source at a first temperature to a heat sink at a second higher temperature in a phase change of a heat transfer fluid. The heat transfer fluid is subjected to a pressure variation which changes the temperature at which the phase change takes place.

Description

1249017 Λ. 曰 修正 低溫熱源僂ϋ,一種熱溫提升之方法及器具,亦即,自 明係有關ΙϊΓΛ溫熱槽之方法及器具。更詳言之,本發 產生第2運教物=:變換運熱物質,而在第2壓力Ρ2下 …物質的蒸氣之方法及器具。 《先行技術》 會改變之2方法係據於物質在作用壓力變化時,其融點 組與加壓琴且★多支導熱及保Μ (亦即,可加壓)導管 化相位之:結。★此等導管内,注入在施壓下可變 變化時,#升媒質(HTR媒質)。當HTR媒質受到壓力 在低溫下吸收及儲存熱量。該HT«f Γ放所Λ之升壓則導致該媒質融點之升高,而使該媒質 ^子之熱量於圍繞之高溫度。如此,HTR媒質則可 據:f υ低溫提昇溫度於高溫。本發明則再使用另一運熱 」貝CM )媒質’以協助並完成自低溫熱源提升溫度於 向溫熱槽之循環。 鹽水之純化過程中可使用融點倒轉一事,則被揭開於 美國專利3, 354, 083號。此種方法則需要大量之高壓及低 壓鹽水及媒質。由於此種操作之困難,該方法則難成功。 因尚需要將大量液體不施加於高壓下,使傳熱物質之融解 潛熱/或蒸發潛熱,可加以傳熱使用之方法及器具。 《本發明概要》 因此’本發明之目的係提供一種自某溫度之?源,傳 發明說明(2)1249017 Λ. 修正 Correction Low-temperature heat source 偻ϋ, a method and apparatus for improving the temperature of the heat, that is, the method and apparatus for the heat-heating tank. More specifically, the present invention produces a second teaching material =: a method and apparatus for converting the heat transfer material and the vapor of the substance under the second pressure Ρ2. The "Advance Technology" will change the method according to the material when the pressure changes, the melting point of the group and the pressure piano and ★ multiple heat conduction and protection (that is, pressurizable) catheterization phase: knot. ★In these pipes, when the injection is changed under pressure, #升媒 (HTR medium). When the HTR medium is under pressure, it absorbs and stores heat at low temperatures. The boost of the HT«f release causes the media to increase in melting point, and the heat of the medium is at a high temperature around it. In this way, HTR media can be based on: f υ low temperature to raise the temperature at high temperatures. In the present invention, another heat transfer "B" CM) medium is used to assist and complete the cycle of raising the temperature from the low temperature heat source to the warm bath. The use of melting point reversal in the purification of brine is disclosed in U.S. Patent No. 3,354,083. This method requires a large amount of high pressure and low pressure brine and medium. This method is difficult to succeed due to the difficulty of such operations. The method and apparatus for heat transfer can be used because a large amount of liquid is not required to be applied to a high pressure to melt the latent heat of the heat transfer material or to evaporate latent heat. SUMMARY OF THE INVENTION Accordingly, the object of the present invention is to provide a temperature from a certain temperature. Source, pass invention description (2)

修正 l249〇17 五 熱於高溫熱槽之方法及器具。 本發明之另一目的係提供藉由傳熱媒 達成傳熱之方法及器具,其令則在相、::變化, 力以交換溫度。 交化下使用可變壓 本發明之再-目# ’則提供減少 之方法及器具。 j雯壓力之液量 不同於上述之先行技術,本發明則 (HTR媒質)保持於導管内。藉由使1{某質:2 f 温釋熱。如此,HTR媒質則可成功地升高敌:=在南 不需要使大量物質經過低屢及高壓之操作’、,;亦。f 可傳熱於第2高溫度。 則自第1 bHL度 在本發明中,高壓區 一 、 升器内(HTR單元),而祇、w’’、疋’並被緊閉於熱溫提 則在低壓由運熱媒質f與兩溫熱槽間之輸熱, 要大量之物質在:壓媒A運f達成。因此,不需 本發明係提供ί;:!;作之間移動。 ,溫(TL)熱源取熱以供熱溫’ 系槽’ 則包括熱溫提升單元f H …、槽HTR系統 媒質),及第丨運熱媒質^单、,及熱溫提升媒質(HTR (HCM-2)。該系統則 ),以及第2運熱媒質Correction l249〇17 Five methods and apparatus for heating in hot water tanks. Another object of the present invention is to provide a method and apparatus for achieving heat transfer by means of a heat transfer medium which is controlled to change the temperature in phase, ::. The use of variable pressure under the cross-linking of the present invention provides a method and apparatus for reduction. The amount of liquid pressure is different from the above-mentioned prior art, and the present invention (HTR medium) is held in the catheter. By using 1{some quality: 2 f to release heat. In this way, the HTR medium can successfully raise the enemy: = In the south, it is not necessary to make a large amount of material pass through low and high pressure operations, and; f can transfer heat to the second high temperature. Then from the first bHL degree in the present invention, the high pressure zone one, the riser (HTR unit), and only, w'', 疋' and is tightly closed to the hot temperature rise at the low pressure by the heat transfer medium f and two The heat transfer between the warm tanks requires a large amount of material: the pressure medium A transport is achieved. Therefore, it is not necessary for the present invention to provide ί;:!; The warm (TL) heat source takes heat to supply the heat temperature 'the trough' includes the hot temperature rise unit f H ..., the trough HTR system medium), and the second heat transfer medium ^, and the hot temperature lifting medium (HTR ( HCM-2). The system is), and the second heating medium

元之中央室(HTR室;Z二2二個成份:亦即,含有HTR單 與HTR室加以分離,貝,】^:!室,以及熱槽室。將熱源室 室加以分離,則有第以^體裝置’而將熱槽室與HTR 該htr單元宜為固定單元,亦即,htr媒質自身並不在Yuan's central room (HTR room; Z 2 2 two components: that is, containing HTR single and HTR room to separate, shell,] ^:! chamber, and hot tank chamber. Separating the heat source chamber, there is The hot trough chamber and the HTR htr unit should be fixed units, that is, the htr medium itself is not in

第5頁 1249017 J^ 88113850 年 月 曰 修正 五、發明說明(3) 一一" 熱源與熱槽之間運熱者。HTR單元係包括導熱及保壓之導 管組及包含於HTR單元中之HTR媒質,以及包含於HTR單元 中之加壓及減壓HTR媒質之加壓器。 加壓器可為,例如,柱塞機構等機械壓縮器,蒸氣 源’或其他壓縮液體源,或實質上可作用液壓於htr媒質 之其他任何裝置。使HTR媒質經受包括在第1壓力及第1溫 度(第1 HTR壓力及第1 HTR溫度)下融解之循環性運作。 而在第2壓力及第2溫度(第2 HTR壓力及第2 HTR溫度)下 加以凝固。第1運熱媒質HCM-1則自熱源受熱而汽化,以形 成HCM-1蒸氣,而其蒸氣則經第1閥體裝置流動,來與HTR 單元相接觸並融解該HTR媒質。由此該HCM-1蒸氣被凝結, 以形成HCM-1凝結體。然後,第2運熱媒質HCM-2被帶來與 HTR媒質相接觸,以在第2HTR壓力及溫度下凝固該HTR,由 此形成第2運熱媒質之蒸氣流(HCM-2蒸氣)。HCM-2蒸器 通過第2閥體而釋熱於熱槽,由此凝結以形成HCM-2媒質凝 結體。該凝結體則被再循環於如上之汽化操作。注意,因 HTR媒質宜含於固定HTR單元内,使得第1及第2 HCM媒質交 換熱源與熱槽之熱量。 本發明之範圍内,再包括使用同一媒質於HCM-1及 HCM-2兩者,在此種變換,形成於低溫凝結運作中所形成 之HCM-1凝結體,可用於高溫汽化運作,而在高溫凝結運 作中所形成之HCM-2凝結體,亦可用於低溫汽化運作。 此種HTR系統可用於冷硬水及空氣調節裝置,以及真 空冷凍法、製冰法、儲冰法、蒸餾冷凍法以及多功能蒸發 法等。Page 5 1249017 J^ 88113850 Year 曰 Amendment V. Invention Description (3) One &one; heat source between heat source and heat sink. The HTR unit includes a heat conducting and holding tube group and an HTR medium contained in the HTR unit, and a pressurizer for pressurizing and depressurizing the HTR medium contained in the HTR unit. The pressurizer can be, for example, a mechanical compressor such as a plunger mechanism, a vapor source' or other source of compressed liquid, or any other device that can substantially act on the htr medium. The HTR medium is subjected to a cyclic operation including melting at the first pressure and the first temperature (the first HTR pressure and the first HTR temperature). The solidification is carried out at the second pressure and the second temperature (the second HTR pressure and the second HTR temperature). The first heat transfer medium HCM-1 is vaporized by heat from the heat source to form HCM-1 vapor, and the vapor flows through the first valve body device to contact the HTR unit and melt the HTR medium. Thereby the HCM-1 vapor is condensed to form an HCM-1 coagulum. Then, the second heat transfer medium HCM-2 is brought into contact with the HTR medium to solidify the HTR at the second HR pressure and temperature, thereby forming a vapor stream (HCM-2 vapor) of the second heat transfer medium. The HCM-2 steamer is released into the hot bath through the second valve body, thereby being condensed to form an HCM-2 medium cement. The condensate is then recycled to the vaporization operation as above. Note that the HTR medium should be contained in the fixed HTR unit so that the first and second HCM media exchange heat with the heat source and the heat sink. Within the scope of the present invention, the use of the same medium in both HCM-1 and HCM-2, in this transformation, forms the HCM-1 condensate formed in the low-temperature condensation operation, which can be used for high-temperature vaporization operation, and The HCM-2 condensate formed during high temperature condensation operation can also be used for low temperature vaporization operation. This HTR system can be used for chilled water and air conditioning equipment, as well as vacuum freezing, ice making, ice storage, distillation and multi-evaporation.

第6頁 1249017 修正 月 曰 -----^^88113850 五、發明說明(4) 《實施例》 二二:圖詳細說明本發明。 固及融解熱溫提升系統(HTR系統),係利用循環性凝 詰操作之」個ΐ ΐ溫提升媒質(HTR媒質),以及汽化及凝 於取自低&amp;或多個運熱媒質(HCM媒質)。HTR系統乃使用 I:熱源並排熱於高溫熱槽。 中,類似數字則矣f統之操作步驟。在該圖及其他圖 熱及保壓導Ϊ=ΓΛ同構造。在該系統,包含於多數導 / . 之HTR媒質’受循環性操作’而經歷·· 驟;a大部分HTR媒質在?膽1及溫度THm下融解之第 將媒質之壓力自PHTR1改變於PHTR2之第2步驟; U驟Ci Ϊ Ϊ Γ分HTR媒質在壓力Ρ_及溫度PHTR2下凝固之第 3步驟〔狀態3〜狀態4〕; &lt;弟 -狀媒質之壓力自Ρ_改變於PHTR1之第4步驟〔狀態4 第1運熱媒質〔HCMM媒質〕係自低溫熱源受埶 第1HCM媒質蒸氣(Hcjj-丨媒質蒸氣),並在第i ^ ^ 於Η則質而凝結。第2運熱媒f〔則驾質〕則由在釋熱| 驟自HTR媒質受熱,以形成阢卜2媒質蒸氣,而 ^庚 下藉由排熱QH於熱槽而凝結。 升阿/皿度 第2圖係熱溫提升單元(HTR單元)之結構圖。其 數導熱及保壓導管2,熱溫提升媒質(HTR媒質)3,頭 以及加壓及減壓HTR媒質之氣缸及活塞。氣缸及活=, 用,當然僅係加壓HTR媒質之一方法例。其它已知之可^ 1249017 案號 88113850 —年 Λ_§ 倐正 五、發明說明(5) 生如同效果之方法當然亦可用 第2 A圖係類似於第2圖之其他熱溫提升單元,除將散 熱片6置於各導管以加強傳熱外。第2B圖係散熱片6之縱向 結構圖,而第2C圖則含有散熱片6之導管2切割圖。 第3 A圖係將波形材料之兩片8加以接合所形成之多數 連結導管7之橫剖面圖。鄰接導管則由側翼9所連結。第3β 圖則類似於第3 A圖之多數導管7之橫剖面圖,其中在各導 管7内設置散熱片1 0以加強傳熱。 第4A圖係將各導管7自鄰接導管所隔離之多數導管或 多數管裝配之橫剖面圖。第4B圖係類似於第4A圖之多數導 管橫剖面圖,其中在各導管内再裝設散熱片丨〇以加強傳 熱。 第5 A圖係具有多數導管丨2之多空隙金屬塊橫剖面 第5B圖係類似於第5 A圖之單元橫剖面圖,其中在各 再設置散熱片1 3。 1 留意,HTR單元之壁(Mw),亦即 ——/ ,,, 等管及頭(參照第2 圖)以及塊(參照第5A圖、第5]5圖)之壁,係影響HTR運 =之主要因素。必須將htr單元(Mw)之壁數量對於htr 、士之比率,保持於低值。在第1途中,HTR單元於第2步驟 1加熱時,該壁(未圖示)則自τ丨被加熱於T2 ,而吸收 二因此一部分HTR媒質凝固以符合能量平衡關係。如 =上凝固之HTR媒質殘餘量則可減少而在步驟3中之釋熱 = &gt;'。再者,在第1圖中,HTR單元於步驟4被冷卻時,…該 則自T2被冷卻於T1,而由此釋放顯熱。如此,一部分μ HTR媒質融解以符合能量平衡關係。因此,融解之htr 1249017 案號 88113850 曰 一修正 五、發明說明(6) 殘餘量變少而在步驟1被吸收之熱量變少。此種問題可稱 為、熱慣性問題&quot;。必須留意,HTR單元之壁數量對於HTR 媒質量愈高,、、熱慣性問題,愈嚴重而HTR之生產愈低, 並HTR單元之效率愈低。 · HTR單元之適當構成物質,則包含鋁、鐵、鋼、黃銅 及其他物質,以及自第1運熱媒質,包含經壁可傳熱自HTR 單元於第2運熱媒質之具有傳熱性質之非金屬物質\ 壁對於HTR媒質之質量比,乃在第4A圖及第4B圖所圖 解之附有多數管裝配之HTR時為最低。由第3A圖及第⑽圖 所圖解之HTR單元連結壁時,壁對於HTR媒質之質量比,則 為較高。第5A圖及第5B圖所圖解之由多空隙塊所製成之、 HTR單元,則壁對於HTR媒質之質量比為最高。 如此,一般不宜使用多空隙塊,因壁對於HTR媒質之 質量比太高而HTR運作之效率為低,而其效率變成太低之 故,作為升溫之T1 一 T2較高時不甚有用。 第6A圖及第6B圖則表示HTR系統,期包括熱溫提升區 〔HTR區(區-1)〕,快速冷卻區16(區-2),及直接接觸 凝結區1 7 (區-3 )。第6 A圖表示供應液體2 1被快速汽化,而 產生運熱媒質V1(HCM_1蒸氣)。然後該HCM-1媒質蒸氣則 通過自動閥1 8 (例如,其格子及轉板由薄膜所製成者), 而與HTR導管之外表面22相接觸,與HTR單元内之HTR媒質 交換熱量,以在THTR1及PHTR2融解HTR媒質。第6B圖則表 示運熱媒質與在PHTR2壓力及THTR2溫度下之HTR單元相接 觸。然後HCM-2媒質蒸氣則通過自動閥19(例如,其格子及 轉版仍由薄膜製成者),而與被導入於區_3接觸於HCM-2蒸Page 6 1249017 Revision Month - -----^^88113850 V. Description of the Invention (4) <<Embodiment>> 22: The figure illustrates the present invention in detail. Solid and melt heat temperature rise system (HTR system), which uses cyclic condensate operation to "enhance temperature" (HTR medium), and vaporize and condense from low &amp; or multiple heat transfer media (HCM) medium). The HTR system uses I: a heat source to heat up the hot water tank. In the case of similar numbers, the operation steps are the same. In this figure and other diagrams, the heat and pressure holding guide = the same structure. In this system, the HTR medium contained in most of the derivatives is subjected to cyclical operations and undergoes a large number of HTR media. The second step of changing the pressure of the medium under the biliary 1 and the temperature THm from PHTR1 to PHTR2; U-Ci Ϊ Ϊ 第 The third step of solidifying the HTR medium under pressure Ρ_ and temperature PHTR2 [state 3~ state 4]; &lt;Digital-like medium pressure self-promotion_Change to PHTR1 step 4 [State 4 The first heat-transfer medium [HCMM medium] is from the low-temperature heat source to receive the first HCM medium vapor (Hcjj-丨 medium vapor) And condensed in the first i ^ ^ Η Η. The second heat transfer medium f (the ride quality) is heated from the HTR medium during the heat release to form the medium vapor, and the heat is condensed by the heat removal QH in the hot bath.升 / / The degree is shown in Figure 2 is the structure of the thermal temperature rise unit (HTR unit). It has several heat-conducting and pressure-maintaining ducts 2, a heat-temperature-enhancing medium (HTR medium) 3, a head and a cylinder and piston for pressurizing and decompressing HTR media. Cylinder and live =, use, of course, only one example of pressurized HTR media. Other known can be ^ 1249017 Case No. 88138850 - Year Λ § 倐 五 五 、, invention description (5) The method of life like effect can of course also use the second A picture is similar to the other thermal temperature rise unit of Figure 2, except for heat dissipation Sheet 6 is placed in each conduit to enhance heat transfer. Fig. 2B is a longitudinal structural view of the heat sink 6, and Fig. 2C is a cutaway view of the catheter 2 containing the heat sink 6. Fig. 3A is a cross-sectional view of a plurality of connecting conduits 7 formed by joining two sheets 8 of corrugated material. Adjacent conduits are joined by side flaps 9. The 3β-Fig. is similar to the cross-sectional view of most of the conduits 7 of Figure 3A, in which fins 10 are placed in each of the tubes 7 to enhance heat transfer. Figure 4A is a cross-sectional view of the assembly of a plurality of conduits or a plurality of tubes from which the conduits 7 are isolated from adjacent conduits. Fig. 4B is a cross-sectional view of a plurality of tubes similar to Fig. 4A, in which heat sinks are further disposed in each of the tubes to enhance heat transfer. Fig. 5A is a cross section of a multi-void metal block having a plurality of ducts 2, and Fig. 5B is a cross-sectional view similar to the unit of Fig. 5A, in which heat sinks 13 are disposed. 1 Note that the wall of the HTR unit (Mw), that is, the wall of the ~/,,, and other tubes (see Figure 2) and the block (see Figure 5A, Figure 5), affects the HTR = the main factor. The number of walls of the htr unit (Mw) must be kept low for the ratio of htr to s. In the first pass, when the HTR unit is heated in the second step 1, the wall (not shown) is heated from T2 to T2, and the second portion of the HTR medium is solidified to conform to the energy balance relationship. For example, the residual amount of HTR medium solidified on the upper side can be reduced and the heat release in step 3 = &gt;'. Further, in Fig. 1, when the HTR unit is cooled in step 4, ... is cooled from T2 to T1, thereby releasing sensible heat. As such, a portion of the μ HTR medium melts to conform to the energy balance relationship. Therefore, the melted htr 1249017 case number 88113850 曰 a correction 5, the invention description (6) The residual amount is reduced and the amount of heat absorbed in step 1 is reduced. This kind of problem can be called, thermal inertia problem. It must be noted that the higher the mass of the HTR unit for the HTR medium, the hotter inertia problem, the lower the HTR production and the lower the efficiency of the HTR unit. · The appropriate constituents of the HTR unit include aluminum, iron, steel, brass and other materials, and from the first heat transfer medium, including the heat transfer properties of the heat transfer medium from the HTR unit to the second heat transfer medium. The mass ratio of the non-metallic substance to the HTR medium is the lowest when the HTR of most tube assemblies is illustrated in Figures 4A and 4B. When the HTR unit is connected to the wall as illustrated in Figs. 3A and (10), the mass ratio of the wall to the HTR medium is higher. The HTR unit made of the multi-void block illustrated in Figures 5A and 5B has the highest mass ratio of the wall to the HTR medium. Thus, it is generally inappropriate to use a multi-void block because the mass ratio of the wall to the HTR medium is too high and the efficiency of the HTR operation is low, and the efficiency becomes too low, which is not very useful as the temperature rise T1 - T2 is high. Figures 6A and 6B show the HTR system, including the hot temperature rise zone [HTR zone (zone-1)], the rapid cooling zone 16 (zone-2), and the direct contact condensation zone 17 (zone-3) . Figure 6A shows that the supply liquid 21 is rapidly vaporized to produce a heat transfer medium V1 (HCM_1 vapor). The HCM-1 medium vapor then passes through an automatic valve 18 (e.g., the grid and the rotating sheet are made of a film), and is in contact with the outer surface 22 of the HTR conduit to exchange heat with the HTR medium in the HTR unit. To melt the HTR medium in THTR1 and PHTR2. Figure 6B shows the heat transfer medium in contact with the HTR unit at PHTR2 pressure and THTR2 temperature. Then the HCM-2 medium vapor is passed through the automatic valve 19 (for example, its lattice and transfer is still made of film), and is introduced into the zone _3 to contact HCM-2 steaming.

1249017 案號 88113850 Λ_Μ Β 修正 五、發明說明(7) 氣之液體24相接觸,以加熱該液體。此種系統則可適用於 產生空氣調節用冷翁水及其他工業用冷卻操作。 第7Α圖及第7Β圖則圖解另一 HTR系統,其包括HTR區15 (區-1),HCM-1蒸氣產生區16(區- 2Α)及熱源區26(區-3Β)。第7Α圖則圖解HCM媒質被帶來與區2Β之熱源交換熱 量,以在區2Α產生HCM-1蒸氣。HCM-1蒸氣被凝結而HTR媒 質則在區1於THTR1及PHTR1被融解。第7Β圖則表示HCM-2作 用於HTR單元之島館外表面23,而被汽化已形成HCM-2蒸氣 V2,而在THTR1及PHTR2下凝固該HTR媒質。然後HCM-2蒸氣 則通過第二閥19而在區3Α被凝結,並藉由釋熱於區-3Β之 熱槽27。 第8Α圖及第8Β圖則圖解使用於真空冷凍操作之jjTR系 統。此種系統則適用於海水淡化、工業溶液濃縮、廢水濃 縮以及水性容易與非水性混合物之結晶化工程。此種系統 則包括HTR區29(區-1),真空冷凍區30(區-2)結晶融解區 34(區-3)及結晶洗滌區33(區-4)。 此種系統之操作步驟,則由海水淡化做為例,加以說 明。在第8Α圖,海水被供於受除氣及換熱操作,而在區一2 被快速汽化,以形成第1低壓水汽,稱為HCM- 1蒸氣V1及冰 結晶35。HCM-1蒸氣之壓力約為3· 5 torr,其為比水之三重 點壓力(4· 58torr)較低。由冰結晶及凝結母液構成濁流 者,被供於結晶洗務區3 3 (區-4 ),而純冰被導入於區一 3。 低壓水蒸氣V1(HCM-1蒸氣)被帶來與在壓力在phtri及溫度 THTR1下之HTR單元相接觸。水蒸氣則被逆昇華以在jjTR單 元之外表面形成回昇華物(冰)36,而HTR媒質則被融解。1249017 Case No. 88113850 Λ_Μ 修正 Correction V. INSTRUCTIONS (7) The gas liquid 24 is in contact with each other to heat the liquid. This system can be used to generate cold water for air conditioning and other industrial cooling operations. Figures 7 and 7 illustrate another HTR system comprising HTR zone 15 (zone-1), HCM-1 vapor generation zone 16 (zone-2) and heat source zone 26 (zone-3Β). Figure 7 illustrates that the HCM medium is brought to exchange heat with the heat source of Zone 2 to produce HCM-1 vapor in Zone 2Α. The HCM-1 vapor is condensed and the HTR medium is melted in zone 1 at THTR1 and PHTR1. Figure 7 shows that HCM-2 is used as the outer surface 23 of the island pavilion of the HTR unit, and vaporized to form HCM-2 vapor V2, and the HTR medium is solidified under THTR1 and PHTR2. Then, the HCM-2 vapor is condensed in the zone 3 through the second valve 19, and is released by the heat sink 27 in the zone -3. Figures 8 and 8 show the jjTR system used for vacuum freezing operations. Such systems are suitable for seawater desalination, industrial solution concentration, wastewater concentration, and crystallization of aqueous and non-aqueous mixtures. Such a system includes HTR zone 29 (zone-1), vacuum free zone 30 (zone-2) crystallization zone 34 (zone-3) and crystallisation wash zone 33 (zone-4). The operational steps of such a system are exemplified by seawater desalination. In Figure 8, the seawater is supplied to the degassing and heat exchange operations, and is rapidly vaporized in Zone 1 to form the first low pressure water vapor, referred to as HCM-1 vapor V1 and ice crystals 35. The pressure of the HCM-1 vapor is about 3.5 Torr, which is lower than the triple point pressure of water (4·58 torr). The turbidity formed by the ice crystals and the condensed mother liquor is supplied to the crystallization washing zone 3 3 (zone-4), and the pure ice is introduced into the zone 1-3. Low pressure steam V1 (HCM-1 vapor) is brought into contact with the HTR unit at pressure phtri and temperature THTR1. The water vapor is sublimated to form a rejuvenation (ice) 36 on the surface of the jjTR unit, and the HTR medium is melted.

第10頁 1249017 案號 88113850 Λ_Β 曰 修正 五、發明說明(8) 在第8Β圖,HTR單元再受壓力PHTR2及溫度THTR2,以在壓 力約5torr下(比水之三重點還高)產生第2水蒸氣v2(hcM - 2 蒸氣)。第2水蒸氣V 2則被帶來與區3之冰相接觸,由此同 時融解冰而凝結第2水蒸氣V 2做為輸出劉3 9。第2水蒸氣V 2 之凝結務及冰之融解物3 9均變成純化水。 第9A圖及第9B圖所圖解之系統,則類似於第8A圖及第 8 B圖所圖解者,且再此系統中之運作亦相似。在此種系 統’ HCM-2蒸氣則被帶來與區_3中之純結晶間接性相接觸 以交換熱量。融解液體則流出於4 7。 由第1 0 A圖及第1 〇 B凸所圖解之系統,則可適用於水性 容易及菲水性混合物之真空結晶。在此種系統中,所形成 之HCM-2蒸氣則由區-3之冷卻媒質所凝結,而所形成之結 晶則不由HCM-2蒸氣所融解。此種系統特別適用於製造冰 塊,其中被製造於區-2之小冰則被壓縮以形成冰塊。此種 系統亦適用於美國專利4218893號、4433558號、4451273 號及4 5 7 8 0 9 3號所述之蒸餾冷卻操作,而此等專利則全面 性併予本案做參考。 第11 A圖及第11 β圖係圖解多功能蒸發系統,則包括在 主要運作區Z-1之第!多功能蒸發器(z-ia),第2多功能蒸 發器(Z-1B),在Z-2A之第1 HTR單元61及在系統第1末端Z-2B之第2HTR單元62,Z-3A之HTR單元63,在系統第2末端Z -3B之第4HTR單元64等,HTR單元則循環性運作而多功能蒸 發器則略繼績被運作。 第1多功能蒸發器Z-A則包括,例如,串聯之9個蒸發 器69-77(ZE- 1至ZE-9),其中運作壓力則自左端ZE- 1至右Page 10 1249017 Case No. 88138850 Λ _ Β 曰 Amendment 5, Invention Description (8) In Figure 8, the HTR unit is subjected to pressure PHTR2 and temperature THTR2 to produce the second under pressure of about 5 torr (higher than the three points of water). Water vapor v2 (hcM - 2 vapor). The second water vapor V 2 is brought into contact with the ice of the zone 3, whereby the ice is simultaneously melted and the second steam V 2 is condensed as the output Liu 39. Both the condensation of the second steam V 2 and the melt of the ice 3 become purified water. The systems illustrated in Figures 9A and 9B are similar to those illustrated in Figures 8A and 8B, and the operation in this system is similar. In this system, the HCM-2 vapor is brought into contact with the pure crystal indirect in zone _3 to exchange heat. The melted liquid flows out at 47. The system illustrated by Figure 10A and Figure 1B is suitable for vacuum crystallization of aqueous and phenanthrene-based mixtures. In such a system, the HCM-2 vapor formed is condensed by the zone-3 cooling medium and the resulting crystals are not melted by the HCM-2 vapor. Such a system is particularly suitable for making ice cubes in which small ice made in Zone-2 is compressed to form ice cubes. Such a system is also applicable to the distillation cooling operations described in U.S. Patent Nos. 4,218, 893, 4, 433, 558, 4, 527, 273, and 4, 579, 039, the disclosures of which are incorporated herein by reference. The 11A and 11th diagrams illustrate the multi-function evaporation system, which is included in the main operation area Z-1! Multi-function evaporator (z-ia), second multi-function evaporator (Z-1B), first HTR unit 61 in Z-2A and second HTR unit 62 in system first end Z-2B, Z-3A The HTR unit 63 is in the fourth HTR unit 64 of the second end Z-3B of the system, etc., and the HTR unit operates cyclically and the multi-function evaporator is slightly operated. The first multi-function evaporator Z-A includes, for example, nine evaporators 69-77 (ZE-1 to ZE-9) connected in series, wherein the operating pressure is from the left end ZE-1 to the right.

第11頁 j號 88113850 1249017 月 曰 修正 年 五、發明說明(9) 端Z4E-9之方向逐漸減少。第2多功能蒸發器z_iB則包括串 聯之卩個蒸發器”一以^’^至^’^^其中’運作壓力則 自右端ZE’-i向左端ZE’-9之方向逐漸減少。多於哎少於g 功能者也可用,其實際數目則依據運作條件及經濟上之因 素而選擇。 4個HTR單元則各循環性運作而相互作為蒸發器及凝結 器。4個HTR單元則於坐標方式運作。在各端之2個HTRi 1,作用為蒸發器時,其他單元則作用為凝結器。如在第 11A圖所圖解,Z-2A及Z-3B中之HTR單元作用為2個蒸氣產 生器而Z-2B及Z-3A中之HTR單元則作用為2個凝結器。 產生之水蒸氣則被用於供應2個區及ZE,_丨區之水 蒸氣’而開動多功能蒸發運作。離開最後效果區z E _ 9及 ZE’ -9之水蒸氣,則在作用為凝結器之2個jjTR單元中被凝 結。第11B圖則圖解循環另一半之同樣系統,其中ζ_2β&amp; Z-3A中之HTR單元則變成蒸氣發生器,而z_2a及z- 3B中之 HTR單元則變成凝結器。 第12A圖及第12B圖則圖解如同第ha圖及第11B圖所圖 解之多功能蒸發器系統。在此種系統,波形金屬壁9 6,9 7 被用於形成落膜蒸發器89-95及98 - 104。 第1 3圖則圖解自動閥系統,其在不需要任何機械裝置 或電動開關下,可自一室供應蒸氣製另一室。自動閥系統 則由結構支柱用之篩1 〇 5及配附於格子1 〇 7之轉板1 〇 6 (由薄 膜製成)之2室用格子1 〇 7所製成。配附薄膜之袼子則作用 為2室間之分隔器。當一室之壓力比另一室較高時,該薄 膜轉板1 0 6則壓力敏感性之故自動開放,使蒸氣自較高壓Page 11 j No. 88113850 1249017 Month 修正 Revision Year V. Invention Description (9) The direction of the end Z4E-9 is gradually reduced. The second multi-function evaporator z_iB includes one evaporator in series "one to ^'^ to ^'^^ where the operating pressure is gradually reduced from the right end ZE'-i to the left end ZE'-9.哎 Less than g function is also available, the actual number is selected according to operating conditions and economic factors. Four HTR units operate cyclically and act as evaporators and condensers. Four HTR units are in coordinate mode. Operation. When two HTRi 1 at each end acts as an evaporator, the other units act as a condenser. As illustrated in Figure 11A, the HTR units in Z-2A and Z-3B act as two vapors. The HTR unit in the Z-2B and Z-3A acts as two condensers. The water vapor produced is used to supply the water vapor in the two zones and the ZE, _ 丨 zone to activate the multi-function evaporation operation. The water vapor leaving the final effect zones z E _ 9 and ZE' -9 is condensed in the two jjTR units acting as a condenser. Figure 11B illustrates the same system in the other half of the cycle, where ζ_2β&amp; Z-3A The HTR unit in the middle becomes a steam generator, and the HTR unit in z_2a and z-3B becomes a condenser. Figures 12A and 12B illustrate a multi-function evaporator system as illustrated in Figures ha and 11B. In such a system, corrugated metal walls 9 6, 9 7 are used to form a falling film evaporator 89-95 And 98 - 104. Figure 1 3 illustrates an automatic valve system that can supply steam from one chamber to another without the need for any mechanical devices or electric switches. The automatic valve system is used for the screens of structural columns 1 5 and the two compartments of the transfer plate 1 〇6 (made of a film) attached to the lattice 1 〇7 are made of lattice 1 〇 7. The braid attached to the film acts as a separator between the two chambers. When the pressure of one chamber is higher than that of the other chamber, the pressure of the membrane transfer plate is automatically opened, so that the vapor is higher than the pressure.

第12頁 12490 _亲醮 88113850_年月 η 修正_ 五、發明說明(10) 力之第1室流至較低壓力之第2室。當第2室之壓力變成較 高於第1室壓力時,轉板則可自動關閉。 第1 3 Α圖則圖解在通氣孔上面之保持器,配附薄膜轉 板所成之單一閥。 在自然中,熱係自高溫熱源流至低溫熱槽。本發明則 揭開以適當之能量輸入即可完成逆行於自然現象之方法及 器具。理論上對於每單元溫度之昇高所供應之熱提昇量 (HTR媒質之潛熱),輸入於HTR之工作量(施加壓力乘HTR媒 質之容積變化),則反比例於絕對溫度。此種關係可由Page 12 12490 _ Relatives 88113850_Year η Correction _ V. Description of invention (10) The first chamber of force flows to the second chamber of lower pressure. When the pressure in the second chamber becomes higher than the pressure in the first chamber, the flap can be automatically closed. The first 3 Α diagram illustrates the retainer above the vent, with a single valve formed by the membrane transfer. In nature, the heat flows from a high temperature heat source to a low temperature heat sink. The present invention uncovers methods and apparatus for retrograde natural phenomena with appropriate energy input. Theoretically, the amount of heat increase (the latent heat of the HTR medium) supplied for the increase in the temperature per unit, the amount of work input to the HTR (the applied pressure multiplied by the volume change of the HTR medium) is inversely proportional to the absolute temperature. This relationship can be

Clausius-Clapeyron方程式(化學物理雜誌,第25卷第3 號)所導出,而可取{△PV/AH^T} =1/T之形式,以代 表熱溫提升定律。本發明則依據施加之壓力變化時融點可 變之原理。 通用於HTR媒質The Clausius-Clapeyron equation (Journal of Chemical Physics, Vol. 25, No. 3) is derived and can take the form of {ΔPV/AH^T} =1/T to represent the law of thermal temperature rise. The present invention is based on the principle that the melting point is variable depending on the pressure applied. Common to HTR media

普通,其被施加於媒質之壓力 此’該媒質則可在低溫及低壓 媒質之融點就增高使其釋放熱 貝,如水,則施加壓力增高時 壓力增高時,融點則減少使冰 而壓力被釋放時在0 °C再凝固, 以媒質在低溫吸熱而在高溫釋 任何媒質均可用為任溫提升媒 含具有熔點在〜3(TC與l0(rc之 =冊中所述者均可作參考併予 有,。c與mt間之共晶:T 增高時,其融點則增高。4 下吸收熱量而施加壓力時, 量而在高溫凝固。β類物 ’融點則降低。施加於冰2 在溫度0 °c下吸熱以融解, 兩類物質均施加壓力變化 熱。因此,融點適當變化4 質。適當之熱溫提升媒質爸 間者,例#,在化學及物楚 t案。ί何結♦混合物應; 種混S物亦可用為HTR媒 1249017 案號 88113850 年Μ 曰 修正 五、發明說明(11) 質。其情形再進一步詳述於後。 在第1圖之系統,含於多數導熱及保壓導管中之HTR媒 質,被施於循環性操作而經(a)在壓力PHTR1及溫度THTR1 下融解大部份HTR媒質之第1步驟〔狀態1 一狀態2〕 ,(b) 改變媒質之壓力自PHTR1至PHTR2之第2步驟〔狀態2 -狀態 3〕 ,(c)在壓力PHTR2及溫度THTR2下凝固大部份媒質之第 3步驟,及(d)改變媒質壓力自PHTR2至PHTR1之第4步驟。 第1運熱媒質〔HCM-1媒質〕自低溫熱源受熱而產生第1 HCM媒質蒸氣,HCM卜媒質蒸氣,則在第1步驟由釋熱qL於 HTR媒質而凝結。第2運熱媒質〔HCM-2媒質〕則在第3步驟 自HTR媒質受熱以形成HCM-2媒質蒸氣,而由排熱QH於昇溫丨 之熱槽而凝結。 再有關第1圖,在狀態1之固體及液體HTR媒質,各由 (mS)HTR&amp; ( mL)HTR所代表;在狀態2之固體及液體HTR媒質, 各由(ms)HTR2及(mL)HTR2所代表;在狀態3之固體及液體HTR媒 質’各由(ms)HTR3及(mL)HTR3所代表;在狀態4之固體及液體 HTR媒質,各由(ms)HTR4及(mL) HTR4所代表。然後,在低 溫熱源Q1所取之熱量則為QL= { (inL)HTR2- (mL)HTR1 } X im,此 中’ lm為HTR媒質之融解潛熱。又,可表示供於高溫熱槽 之熱量負 QH 則為- QH= { (ms)HTR4 — (ms)HTR3 } X lm。當 HTR 單元 改變其溫度自!\似至THTRjf,該HTR單元則釋放顯熱。因 此,一部分HTR媒質融解以滿足能量平衡關係。因此,(mL) htri為較大於(mL)HTR4。此事則可使熱量自低溫熱源較少移 動。同樣,當HTR單元改變其溫度自Τ_至THTR2時,HTR單元 則吸收顯熱。因此,一部分HTR媒質凝固以滿足能量平衡Ordinarily, it is applied to the pressure of the medium. This medium can increase the melting point of the low-temperature and low-pressure medium to release the hot shell. For example, when the pressure is increased when the pressure is increased, the melting point is reduced to make the ice and the pressure When it is released, it will re-coagulate at 0 °C, and the medium absorbs heat at low temperature and releases any medium at high temperature. It can be used as any temperature-enhancing medium containing a melting point of ~3 (TC and l0 (rc== can be used in the book) Reference and presupposition, eutectic between c and mt: When T increases, its melting point increases. 4 When heat is absorbed and pressure is applied, the amount is solidified at high temperature. The β-like substance 'melting point is lowered. Ice 2 absorbs heat at a temperature of 0 °c to melt, and both types of substances exert pressure to change heat. Therefore, the melting point changes appropriately. 4. Appropriate heat temperature raises the medium dad, example #, in the case of chemical and physical Chu何何结♦ Mixture should be; mixed S can also be used as HTR media 1249017 Case No. 88113850 Μ 曰 Amendment 5, invention description (11) quality. The situation is further detailed later. In the system of Figure 1, HTR media contained in most thermal and pressure-maintaining catheters, applied to Cyclic operation through (a) the first step of melting most of the HTR medium under pressure PHTR1 and temperature THTR1 [state 1 state 2], (b) changing the pressure of the medium from PHTR1 to PHTR2 step 2 [state 2 - State 3], (c) the third step of solidifying most of the medium under pressure PHTR2 and temperature THTR2, and (d) the fourth step of changing the medium pressure from PHTR2 to PHTR1. The first heat transfer medium [HCM- 1 medium] The first HCM medium vapor is generated by heating from a low temperature heat source, and the HCM medium vapor is condensed by the heat release qL on the HTR medium in the first step. The second heat transfer medium [HCM-2 medium] is at the third stage. The step is heated from the HTR medium to form the HCM-2 medium vapor, and is condensed by the heat removal QH in the hot water bath. Referring again to Figure 1, the solid and liquid HTR medium in state 1, each (mS)HTR&amp; (mL) represented by HTR; solid and liquid HTR media in state 2, each represented by (ms)HTR2 and (mL)HTR2; solid and liquid HTR media in state 3's (ms)HTR3 and (mL ) represented by HTR3; solid and liquid HTR media in state 4, each represented by (ms)HTR4 and (mL) HTR4. Then, The heat taken by the low temperature heat source Q1 is QL= {(inL)HTR2-(mL)HTR1 } X im, where 'lm is the latent heat of melting of the HTR medium. Also, it can represent the heat negative QH for the high temperature hot tank. Then - QH = { (ms)HTR4 - (ms)HTR3 } X lm. When the HTR unit changes its temperature from !\ to THTRjf, the HTR unit releases sensible heat. Therefore, a portion of the HTR medium melts to satisfy the energy balance relationship. Therefore, (mL) htri is greater than (mL) HTR4. This allows the heat to move less from the low temperature heat source. Similarly, when the HTR unit changes its temperature from Τ_ to THTR2, the HTR unit absorbs sensible heat. Therefore, a part of the HTR medium solidifies to meet the energy balance.

第14頁 1249017 修正Page 14 1249017 Revision

=执:此广,為較大於(心)園。此事則可使施加於 回溫熱槽之熱量為較少。偯赦 ^也加於 --- 案號 88113850 五、發明說明(12) 題,。其可表*當HTR導管專之質詈乂則上為熱慣性問 成愈嚴重,而溫度升高{〜之質τ量增加办:亥熱慣性問題變 變成愈嚴重。 Γ_—Τ_}愈大,熱慣性問題則 该圖亦表示同一物暂- 時’可用做隨而將取= 媒質°此= Executive: This is wide, larger than (heart) garden. This can result in less heat being applied to the warming bath.偯赦 ^ Also added --- Case No. 88113850 V. Inventive Note (12). It can be expressed as * when the quality of the HTR catheter is high, the thermal inertia is more serious, and the temperature rises {~ The mass of the τ increases: the heat inertia problem becomes more serious. The larger the Γ_—Τ_}, the thermal inertia problem, the figure also indicates that the same object temporarily-times can be used to take the medium.

作所形成之:MS 操作。 文HCM 1媒質而使其受低溫蒸發 第2圖則圖解熱溫提升 多數導熱及保壓管2,熱、、四接斗 、…構。其包括 HTR媒質之氣缸及活塞5、、、。值/媒質3,以及加壓及減壓 他類型加壓裝置。 '力裝置也可僅為活塞或其 藉由改變作用於熱溫提升單元之壓力, (HTR媒質)3則在低、;田明勒l + 刀熱,皿棱升媒質 A型物質做為熱溫提升在南溫釋熱°本發明將使用 陶質之潛熱形用=低壓融解而以 媒質之融點升高。在高… 田 壓力增加時,htr 釋放,而htr媒質則再H下/ HTR媒質之潛熱則在高溫被Formed by: MS operation. HCM 1 medium is subject to low temperature evaporation. Fig. 2 illustrates the improvement of hot temperature. Most heat conduction and pressure maintaining tubes 2, heat, four buckets, ... structure. It includes cylinders and pistons 5, H, and HTR media. Value/Media 3, as well as pressurization and decompression. 'The force device can also be only the piston or its pressure acting on the hot temperature lifting unit. (HTR medium) 3 is low, Tian Mingle l + knife heat, and the dish is a type A material. The temperature rises in the south to release heat. The present invention will use the latent heat form of the ceramics = low pressure melting to increase the melting point of the medium. In the high... field pressure increases, htr is released, and htr medium is H again / HTR medium latent heat is at high temperature

則可使HTR媒質完成自 ,此,藉由改變作用壓力HTR 熱溫提升器導管之傳/溫之升高熱溫過程。經過 釋放其潛熱。因此傳媒質愈可快速吸收及 可裝設散熱片以提高HT^R ^ =提2量必須要高。導管内 _ 阿HTR媒質内之傳熱率。第2A圖則圖Then, the HTR medium can be completed, and the heat-temperature process is increased by changing the transmission/temperature of the HTR thermal temperature riser conduit. After releasing its latent heat. Therefore, the quality of the media can be quickly absorbed and the heat sink can be installed to increase the HT^R ^ = 2 must be high. Inside the duct _ A heat transfer rate in the HTR medium. Plan 2A

第15頁 間之HTR導管每單位長户必須快速。由此,每單位時 1249017 案號88113f__-年 月 日 倐正 _ 五、發明說明(13) 解,除在導管裝設縱向散熱片6外,如同第2圖之HTR單 元。第2B圖所示者’則為縱向散熱片之構造。第2C圖則表 示裝設有縱向散熱片於其内之導管一部分切割圖。 熱溫提升器之導管則由傳熱及保壓材料所製成。使用 於構HTR單元之導管構造,則有幾種: 第3 A圖所圖解者為接合波形板8所成之導管組7。鄰接 導管則由側翼9所連結。第3B圖所圖解者,則在導管内裳 設縱向散熱片外,如同第3A圖所示之連結側翼之導管組。 第4A圖則圖解具有實質上均勻壁厚8之導管組7而其導 管為各別分開並鄰接導管之間未有任何連結壁。第4 β圖所 示者則為導管内附有散熱片1〇之如同單元。 第5A圖則圖解未具有實質上均勻厚度導管之多空隙金 屬塊。第5B圖則圖解導管内附有散熱片之如同構造者。 在HTR之高壓運作中,HTR媒質之融點則隨著壓力之增 加而昇高,藉此使HTR媒質在高溫釋熱。同時,hTR導管^ 外壁,將吸收由HTR媒質所釋放之熱量而亦昇高其溫度。 自HTR被釋放壓力後,HTR之壓力會降低,而HTR媒質之融 點則降低,其可使HTR媒質在低溫吸熱,而HTR導管之外壁 則由釋熱降低溫度。HCM媒質自低溫熱源至高溫熱槽之提 高HCM媒質熱溫等級之HTR效率,則賴於由HTR之分批過程 所昇而之HTR潛熱量,減去使用於導管外壁之顯熱量。因 此’由導管外壁所使用之顯熱愈少,HTR之提高熱溫等級 亦有效。如此,使用於構成HTR之顯熱保留較少之材料, 顯熱之損失愈少,而可增加HTR之效率。 因此’上述型之導管,構成HTR之多空隙塊導管宜為The HTR catheter on page 15 must be fast per unit long. Thus, each unit time 1249017 Case No. 88113f__-Year Month Day _ _ V. Invention Description (13) Solution, except that the longitudinal fins 6 are installed in the duct, like the HTR unit of Fig. 2. The figure shown in Fig. 2B is the structure of the longitudinal fin. Figure 2C shows a cut-away view of a portion of the conduit in which the longitudinal fins are mounted. The conduit of the thermal riser is made of heat transfer and pressure retaining material. There are several types of conduit configurations for the HTR unit: Figure 3A illustrates the conduit set 7 formed by joining the corrugated plates 8. Adjacent conduits are joined by side flaps 9. As illustrated in Fig. 3B, the longitudinal fins are disposed outside the catheter, as shown in Fig. 3A. Figure 4A illustrates a catheter set 7 having a substantially uniform wall thickness 8 with separate guide tubes and no associated walls between adjacent conduits. The figure shown in Fig. 4 is a unit in which a heat sink 1 is attached to the catheter. Figure 5A illustrates a multi-voided metal block that does not have a substantially uniform thickness conduit. Figure 5B illustrates the construction of a heat sink in the conduit as a constructor. In the high pressure operation of the HTR, the melting point of the HTR medium increases as the pressure increases, thereby allowing the HTR medium to release heat at a high temperature. At the same time, the outer wall of the hTR conduit will absorb the heat released by the HTR medium and also increase its temperature. After the pressure is released from the HTR, the pressure of the HTR is lowered, and the melting point of the HTR medium is lowered, which allows the HTR medium to absorb heat at a low temperature, while the outer wall of the HTR conduit is cooled by the heat release. The HTR efficiency of the HCM medium from the low temperature heat source to the high temperature heat tank is dependent on the HTR latent heat raised by the HTR batch process, minus the sensible heat used on the outer wall of the conduit. Therefore, the less the sensible heat used by the outer wall of the duct, the higher the heat temperature level of the HTR. Thus, the materials used to form the HTR with less sensible heat retention have less sensible heat loss and can increase the efficiency of the HTR. Therefore, the catheter of the above type, the multi-void block conduit constituting the HTR is preferably

第16頁 1249017 —-_ 案號?Page 16 1249017 —-_ Case number?

五、發明說明(14) 具有較均勻壁厚之導管者,因具有 少每單位導管容積之顯熱損失。用” :J :管可減 多之每單位導管容積之顯材Ϊ 為不且而不適用於HTR中之昇高熱溫之htr。 :其 均勾壁厚之導管,使用於導管壁之材料較少反^由=,較 位導管容積之顯熱,可減少效率之損失。 於母單 ▲ 變換HTR之高壓及低壓,HCM媒質蒸氣之溫度可 . 向;由此HCM媒質蒸氣可凝結叮以,使其潛熱經導管 熱於HTR媒質,並使潛熱液化該jjTR.f。當jjTR2壓力增 加時,HTR媒質之融點會昇高,而htr媒質則在HTR外之^ 溫下傳其潛熱並傳回於HCM媒質。HTR之昇熱容量則賴於^高 壓與低壓間之HTR變換壓力之速度。HTR之高壓與低壓間Z . 變換則賴於HCM媒質傳熱於HTR之比率,或HTR媒質傳回熱 量於HCM媒質之比率。 凝結H C Μ -1蒸氣之傳熱阻力為低,且經過導管之傳熱 阻力亦低。主要傳熱阻力則在經HTR媒質自身之傳熱中。 HCM媒質蒸氣之凝結率為甚快,且經導管壁之傳熱率 亦快’但在金屬管中之HTR媒質之傳熱率則甚慢。因此, 在高壓與低壓間之HTR之變換率,則賴於HTR中媒質之傳熱 率。因此,為提高導管中之HTR媒質之傳熱阻力,則需要 在HTR之導管内裝設散熱片。散熱片有各種,如縱向星形 散熱片及具有孔之縱向星形散熱片。可使用於形成此種傳 熱散熱片之方法及材料有多種。例如,薄金屬片可摺曼於 錯縱形,然後摺疊如第2B圖所示之圓形,使其變成縱向星 形散熱片。熟習此項技藝之人士可自多種已知式樣中選擇V. INSTRUCTIONS (14) A catheter with a relatively uniform wall thickness has a sensible heat loss per unit of conduit volume. Use " :J : The tube can reduce the amount of material per unit of conduit volume Ϊ is not and does not apply to the elevated heat temperature of the HTR htr.: It is the wall thickness of the conduit, the material used in the conduit wall is more Less anti-^ by =, the sensible heat of the volume of the comparative conduit can reduce the loss of efficiency. In the parent single ▲ change the high pressure and low pressure of HTR, the temperature of the HCM medium vapor can be; thus, the HCM medium vapor can be condensed, The latent heat is heated to the HTR medium through the conduit, and the latent heat liquefies the jjTR.f. When the pressure of jjTR2 increases, the melting point of the HTR medium increases, and the htr medium transmits its latent heat at the temperature outside the HTR. Returning to HCM medium. The heat capacity of HTR depends on the speed of HTR conversion pressure between high pressure and low pressure. The conversion between high pressure and low pressure of HTR depends on the ratio of HCM medium heat transfer to HTR, or HTR medium return. The ratio of heat to HCM medium. Condensation HC Μ -1 vapor has low heat transfer resistance and low heat transfer resistance through the conduit. The main heat transfer resistance is in the heat transfer through the HTR medium itself. The rate is fast, and the heat transfer rate through the conduit wall is also fast 'but in the metal The heat transfer rate of the HTR medium in the tube is very slow. Therefore, the conversion rate of HTR between high pressure and low pressure depends on the heat transfer rate of the medium in the HTR. Therefore, in order to improve the heat transfer resistance of the HTR medium in the tube. There is a need to install a heat sink in the HTR conduit. There are various heat sinks, such as a longitudinal star heat sink and a longitudinal star heat sink with holes. There are various methods and materials for forming such a heat transfer fin. For example, a thin metal sheet can be folded into a misaligned shape and then folded into a circular shape as shown in Figure 2B to make it a longitudinal star-shaped heat sink. Those skilled in the art can choose from a variety of known patterns.

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案號 88Π3850 五、發明說明(15) 之。此種散熱片可大大提高HTR中媒質之傳熱率,因星形 散熱片可傳熱於管之星形方向。散熱片之設置可大大減少 HTR之傳熱阻力而增加HTR之壓力變換速度,由此可拗1夕 HTR之升熱容量。 9加 熱溫提升器(HTR)宜為固定裝置,而祇要作用為昇言 器以提高HTR媒質之潛熱溫度。其自身不需要具有自低Z 源傳熱於高溫熱槽之能力。因此,需要i個或2個育埶拔“、、 (HCM媒質)以協助自低溫熱源傳熱於高溫熱槽。在操作溫 度具有適當蒸氣壓之任何化合物均可用為運熱媒質。嚴 與熱源直接相接觸或進行熱交換之區域内Ηα—〗媒 質,則自熱源吸熱以自身蒸發而變成蒸氣。此種 質蒸氣則流向於HTR之區域而在HTR表面凝結。冬 而i 蒸氣在HRE表面凝結時,HTR媒質固體則融解二 R媒質所吸收之熱量則做為HTR媒質之潛埶而| ;融:1 媒,被融解後’施加高壓於圖質,二 =點ΐ:溫。同•’施加之高壓則可導致融解潛 同,皿。然後,HTR媒質釋熱於HCM …、昇至 高溫蒸發。HCM-2媒質進去於高…、 而力媒質則在 氣經直接性或間接性進行敎、:二槽£,&gt;而在此HC^2蒸 明之全過程則包括使HTR單元乂内之而二:熱槽:本發 之分批操作;而使HCM媒質進杆γ :,又到昇高熱溫 熱。HCM媒質則完成自低溫埶=發、凝結、吸收及釋 用。因此,熱溫提升系統皿則…包括傳熱田於高溫熱槽之傳熱功 質,以及1個或2個運熱媒質。…、級提升器,熱溫提昇媒 因由HTR之提升熱溫過程八Case No. 88Π3850 V. Inventive Note (15). Such a heat sink can greatly increase the heat transfer rate of the medium in the HTR, because the star heat sink can transfer heat to the star direction of the tube. The arrangement of the heat sink can greatly reduce the heat transfer resistance of the HTR and increase the pressure conversion speed of the HTR, thereby increasing the heat capacity of the HTR. The 9-plus-heat riser (HTR) should be a fixture as long as it acts as a detector to increase the latent heat temperature of the HTR medium. It does not need to have the ability to transfer heat from a low Z source to a high temperature hot bath. Therefore, it is necessary to use one or two seedlings to extract ", (HCM medium) to assist in the heat transfer from the low temperature heat source to the high temperature heat tank. Any compound having an appropriate vapor pressure at the operating temperature can be used as the heat transfer medium. When the heat source is in direct contact or heat exchange, the Ηα-〗 medium is heated by the heat source to evaporate and become vapor. The mass vapor flows to the HTR region and condenses on the surface of the HTR. Winter i vapor on the HRE surface When coagulation, HTR medium solids melt the heat absorbed by the two R media as the potential of HTR media | | melt: 1 media, after being melted, 'apply high pressure to the picture quality, two = point ΐ: temperature. 'The high pressure applied can lead to the melting potential. Then, the HTR medium releases heat to HCM ... and rises to high temperature evaporation. HCM-2 medium goes in high..., while the force medium is directly or indirectly in gas.敎,: two slots £, &gt; and the entire process of HC^2 steaming includes the HTR unit inside: the hot tank: the batch operation of the hair; and the HCM medium into the rod γ: To raise the heat and heat. HCM medium is completed from low temperature 发 = hair, condensation, Therefore, the heat temperature rise system dish...including the heat transfer function of the heat transfer field in the high temperature heat tank, and one or two heat transfer media...., the grade riser, the heat temperature increase medium is caused by HTR The process of raising the temperature of the heat

第18頁 _______ 係刀批過程,而自每批所昇 1249017 --案號 881〗3«5Π 五、發明說明(16) 年Page 18 _______ is the process of the knife batch, and from each batch of 1249017 - case number 881〗 3 «5 Π V, invention description (16) year

之HTR媒質之潛熱量有限制。如此,當一故程所產生之潛 熱量不夠掩蓋導管外壁之顯熱損失時,可用多組HTR系統 以逐步提高操作至所需溫度。 因有各種不同之熱源,則有不同之操作方法。此種方 法則為如下: 當熱源與HCM媒質無法直接接觸時,可用熱量交換器 以傳熱。例如,空氣調節操作,水用為HCM-1,而室内空 氣作為熱源而產生間接性熱量交換。 當熱源與HCM媒質可直接接觸時,HCM媒質則自低溫熱 源直接吸熱,使HCM-2媒質凝結,而釋熱於高溫熱槽。例、 如,可用非水溶性物質做為HCM物質,以自水行溶液除 熱。 操作之物質可供應HCM媒質而亦可做為熱源。例如, 在水性溶液之快速蒸發,一部分水則變成HCM-1,而剩餘 部分則做為熱源。 ' 發熱化學反應則對於運熱媒質之蒸發產生熱量,以 生HCM媒質蒸氣。 ^ 有多 ,並 在第2圖所示之HTR單元中,熱溫提升單元}則具The potential heat of the HTR medium is limited. Thus, when the latent heat generated by a process is insufficient to mask the sensible heat loss of the outer wall of the conduit, multiple sets of HTR systems can be used to gradually increase the operation to the desired temperature. Because there are different heat sources, there are different methods of operation. This method is as follows: When the heat source is not in direct contact with the HCM medium, a heat exchanger can be used to transfer heat. For example, in an air conditioning operation, water is used as HCM-1, and indoor air is used as a heat source to generate indirect heat exchange. When the heat source is in direct contact with the HCM medium, the HCM medium absorbs heat directly from the low temperature heat source, causing the HCM-2 medium to condense and release the heat in the high temperature heat bath. For example, a water-insoluble substance can be used as the HCM substance to remove heat from the aqueous solution. The substance to be manipulated can be supplied as HCM medium or as a heat source. For example, in the rapid evaporation of an aqueous solution, a portion of the water becomes HCM-1 and the remainder is used as a heat source. The thermochemical reaction generates heat for the evaporation of the heat transfer medium to produce HCM medium vapor. ^ There are many, and in the HTR unit shown in Figure 2, the thermal temperature rise unit}

數導熱保壓導管2 ,而導管2内則填充熱溫提升媒質\ 有頭4及加壓裝置5。 、 LThe number of heat-conducting pressure-retaining ducts 2 is filled, and the inside of the duct 2 is filled with a heat-temperature-enhancing medium, a head 4, and a pressurizing device 5. , L

為了提局傳熱率, 向星形散熱片6如第2A 則可在各傳熱保壓導管2 圖所示。 内裝設縱In order to improve the heat transfer rate, the star heat sink 6 such as the second AA can be shown in each heat transfer pressure maintaining conduit 2. Interior set

第3A圖、第4A圖、及第5A圖所圖解之系絲θΤ ^ 2 . ΛΑ,,. φ , ,, 3Β . , 4Β 圖解取自第2Α之ΑΑ剖面之橫剖面。 圖則The entanglements θ Τ ^ 2 . ΛΑ , , . φ , , , 3Β . , 4Β illustrated in Figures 3A, 4A, and 5A are taken from the cross section of the second Α section. Plans

第19頁 1249017 ^ 修正 案號 881138M 五、發明說明(17) 第3A圖則圖解含有HTR媒質7及附有保壓壁之傳埶 8,及鄰接導管9間之連結壁等之多數連結導管之橫 &amp; 圖。第3B圖則圖解含有11以媒質及附有保壓壁之傳^ 及鄰接導管9間之連結壁,以及裝設於導管内之傳導性 熱片10等之多數連結導管之橫剖面圖。第4A圖則圖解含 HTR媒質7及圍熱各導管之傳熱保壓壁8等之多數管裴配之 橫剖面圖。其中,在鄰接導管間未有連接壁。第4 b圖 圖解含有HTR媒質7及圍繞各管之傳熱保壓壁8且在鄰接管 間未有連結壁,以及管中裝設傳熱散熱片等之多數管裝配 之橫剖面圖。第5A圖則圖解含有HTR媒質12之多數管丨^所 構成之多空隙傳熱塊之橫剖面圖。第5 B圖則圖解含有Η τ尺 媒質12及裝設於導管内之傳熱散熱片之多數導管u所構成 之多空隙傳熱塊之橫剖面圖。Page 19 1249017 ^ Amendment No. 881138M V. INSTRUCTION DESCRIPTION (17) Figure 3A illustrates a plurality of connecting conduits including HTR medium 7 and a crucible 8 with a pressure-retaining wall and a connecting wall between adjacent conduits 9 Horizontal &amp; Fig. 3B is a cross-sectional view showing a plurality of connecting ducts including a medium, a connecting wall with a pressure-retaining wall, and a connecting wall between the adjacent ducts 9, and a conductive heat sheet 10 installed in the duct. Fig. 4A is a cross-sectional view showing a plurality of tubes and the like of the HTR medium 7 and the heat transfer pressure-retaining wall 8 of each of the heat-conducting tubes. There is no connecting wall between adjacent conduits. Fig. 4b is a cross-sectional view showing a majority of the tube assembly including the HTR medium 7 and the heat transfer pressure-retaining wall 8 surrounding each tube and having no connecting wall between adjacent tubes, and a heat transfer fin or the like in the tube. Fig. 5A is a cross-sectional view showing a multi-void heat transfer block composed of a plurality of tubes of the HTR medium 12. Fig. 5B is a cross-sectional view showing a multi-void heat transfer block comprising a plurality of conduits u of a medium 12 and a heat transfer fin mounted in the conduit.

由第6A圖及第6B圖所圖解之系統,係蒸氣壓提升系 統。其包括蒸氣壓提升區Z-1 15,低壓第1蒸氣發生區z —2 16’及高壓蒸氣凝結區z-3 17,以及自區z-2連結於區Z-1 之閥體18及自區Z-1連結於區Z-3之閥體19。第6A圖則圖解 在區2產生第1蒸氣(HCM -蒸氣)之第1步驟。調整在第1壓力 之HTR媒質壓力(其HTR媒質之融解溫度則低於第1蒸氣之凝 結溫度)’ HCM-1蒸氣則凝結第1蒸氣(HCM-1蒸氣),而在 HTR導管内融解HTR媒質。開動壓力改變裝置,則可控制變 溫’如發生於區2之第1蒸氣(HCM蒸氣)進去於自動閥體18 (由格子及附於格子之薄膜轉板所製),以自第1蒸氣(HCM 蒸氣)傳熱於HTR媒質,由此凝結HCM-蒸氣於固體或液體形 態而融解HTR媒質。The system illustrated by Figures 6A and 6B is a vapor pressure boosting system. The utility model comprises a vapor pressure lifting zone Z-1 15, a low pressure first vapor generating zone z-216' and a high pressure steam condensation zone z-3 17, and a valve body 18 connected from the zone z-2 to the zone Z-1 and Zone Z-1 is coupled to valve body 19 of zone Z-3. Fig. 6A illustrates the first step of generating the first vapor (HCM - vapor) in zone 2. Adjusting the HTR medium pressure at the first pressure (the melting temperature of the HTR medium is lower than the condensation temperature of the first vapor) 'HCM-1 vapor condenses the first vapor (HCM-1 vapor), and melts the HTR in the HTR conduit medium. When the pressure changing device is actuated, the temperature change can be controlled as the first vapor (HCM vapor) occurring in the zone 2 enters the automatic valve body 18 (made of a lattice and a film transfer plate attached to the lattice) from the first vapor ( HCM vapor) transfers heat to the HTR medium, thereby condensing the HCM-vapor in a solid or liquid form to melt the HTR medium.

第20頁 1249017 年月曰_ _案號 88]13R.Rn 五、發明說明(18) 第6B圖則圖解,由開動^仰加壓裝置及施加HTR導管外 之HCM-2液體以施加壓力於媒體,則自HTR媒質傳熱於— 2液體之熱量,凝固HTR媒質而蒸發HCM —2液體,以形成高 壓蒸氣HCM_2蒸氣。經其他自動閥體19 ,自區1流動於區3 之HCM-2蒸氣,則凝結區3内。 第7A圖及第7B圖所圖解之系統,則如同第6A圖及第6β 圖再加2個區者,·則低溫熱源區及高溫熱槽區。第7Α圖及 第7/,則圖解供應於空氣調節或產生冷硬水之系統。其包 括蒸軋壓提升區z-i及第}蒸氣發生區Ζ_1Α及第2蒸氣凝結 區Ζ-3Α及^有低溫熱量交換線圈2U6之低溫熱源區, 以及含有高溫熱量交換線圈27之高溫熱槽區ζ_3β。進入於 區Ζ-1與HTR媒質交換熱量之第1HCM1,則在此内凝結而融、 解HTR媒質。在第7B圖,壓力則被調節於提升HTR之凝固溫 度,而增加液體於傳熱管外。由此,熱量則自HTR媒質被 傳於液體以凝固HTR媒質,並發生第2 HCM-2蒸氣。第2 HCM-2蒸氣進入於z_3A區而空氣則在z-3B區内還流。第2 HCM-2蒸氣與空氣或與ζ_3β區之水交換熱量以凝結而熱 量則由外面空氣或冷卻水被移去。 第8Α圖及第8Β圖所圖解之系統,則如同第6Α圖及第6β 圖^者/在此系統,發生同樣之蒸發及冷凍運作以產生hcm-1蒸氣及運作物質之固體。第8A圖及第8B圖則圖解供應純 水之系統。其包括蒸氣壓提升區Z-1及第丄蒸氣發生區2一2 及第2蒸氣凝結區Z-3以及結晶洗滌區z-4。將運作物質32 供Z-2區内以同時產4HCM1蒸氣及個體。產生於2_2區之 第1HCM1蒸氣,則進入於z-i區與被凝結之htr媒質交換熱Page 20, 1249017, 曰 _ _ Case No. 88] 13R.Rn V. Description of Invention (18) Figure 6B illustrates the application of pressure by actuating the pressurizing device and applying HCM-2 liquid outside the HTR conduit. In the medium, heat is transferred from the HTR medium to the heat of the liquid, and the HTR medium is solidified to evaporate the HCM-2 liquid to form a high-pressure vapor HCM_2 vapor. Through the other automatic valve body 19, the HCM-2 vapor flowing from the zone 1 to the zone 3 is in the condensation zone 3. The systems illustrated in Figures 7A and 7B are like the 6A and 6β maps plus 2 zones, the low temperature heat source zone and the high temperature heat sink zone. Figures 7 and 7/ are diagrams of systems supplied for air conditioning or for producing chilled water. The invention includes a steaming pressure lifting zone zi and a vapor generating zone Ζ_1Α and a second vapor condensing zone Ζ-3Α and a low temperature heat source zone having a low temperature heat exchange coil 2U6, and a high temperature heat sink zone containing the high temperature heat exchange coil 27. Ζ_3β. The first HCM1, which enters the heat exchange between the zone Ζ-1 and the HTR medium, condenses therein to melt and dissolve the HTR medium. In Figure 7B, the pressure is adjusted to raise the solidification temperature of the HTR and to increase the liquid outside the heat transfer tubes. Thereby, heat is transferred from the HTR medium to the liquid to solidify the HTR medium, and the second HCM-2 vapor is generated. The second HCM-2 vapor enters the z_3A zone and the air flows in the z-3B zone. The second HCM-2 vapor exchanges heat with air or water in the ζ3β region to condense and the heat is removed by outside air or cooling water. The system illustrated in Figures 8 and 8 is the same as in Figure 6 and Figure 6 / in this system, the same evaporation and freezing operation occurs to produce hcm-1 vapor and solids of the working substance. Figures 8A and 8B illustrate a system for supplying pure water. It includes a vapor pressure raising zone Z-1 and a second vapor generating zone 2-2 and a second vapor condensation zone Z-3 and a crystallization washing zone z-4. The operating substance 32 is supplied to the Z-2 zone to simultaneously produce 4HCM1 vapor and individual. The first HCM1 vapor generated in zone 2_2 enters the z-i zone and exchanges heat with the condensed htr medium.

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Lmyj l I 案號 88113850 -—-— 五、發明說明(19) 量,以融解該HTR媒質。第8B圖則圖解壓力被調節於提升 HTR媒質勺凝固溫度而將液體施加於傳熱管外。由此,熱 量自HTR媒質傳於運作液體以凝固HTR媒質,而產生第… 2 H C Μ - 2蒸氣。自Z - 4區之被洗務結晶3 3,則被送於z _ 3區使 第2 H C Μ - 2蒸氣凝結,由此融解而產生純水3 g。 第9A圖及第9B圖所圖解之系統,係如同第8A圖及第8β 圖者,而在此系統之運做亦同。在此系統HCM_2蒸氣則被 帶來與3區之純化結晶間接性接觸作交換熱量。 第10A及第10B圖所圖解之系統,則 '適用於水性溶液與 非水性混合物之真空結晶化。在此系統所形成之HCM_2蒸 氣則由3區之冷卻媒質所凝結,而形成之結晶則不被由… H C Μ - 2蒸氣所融解。此種系統特別適用於製造冰塊,由此 在2區被製造之冰小片則可被壓縮以形成冰塊。此種系統 亦甚適用於揭開於美國專利4218893號、4433559號、 4451273號及4578093號之由鄭建炎及鄭興旺所發明之蒸餾 冷凍法。 ^ 第1 1 Α圖及第1 1 Β圖係圖解多功能蒸發系統,其包括在-主要運作區Z-1之第1多功能蒸發器z-ia,第2多功蒸發器 Z-1B,在系統之第]^Z-2A中之第1HTR單元61及Z-2B中之 第2HTR單元62,在系統之第2端Z-3A中之第3HTR單元及在 Z-3B中之第4HTR單元。HTR循環性運作而多功能蒸發器則 略連續地運作。 ° 第1多功能蒸發器z - 1 A則包括,例如,串聯之9個蒸發 器ZE-1 — ZE - 9(69-77),而其運作壓力則自左端ZE-1向右 端ZE-9之方向逐漸減少。第2多功能蒸發器z-iB,則包括Lmyj l I Case No. 88113850 ---- V. Invention Description (19) Quantity to melt the HTR medium. Figure 8B illustrates that the pressure is adjusted to raise the solidification temperature of the HTR media spoon and apply the liquid outside of the heat transfer tubes. Thus, heat is transferred from the HTR medium to the working liquid to solidify the HTR medium to produce the ... 2 H C Μ - 2 vapor. The washed crystals 3 3 from the Z-4 region are sent to the z _ 3 region to condense the second H C Μ - 2 vapor, thereby being melted to produce 3 g of pure water. The systems illustrated in Figures 9A and 9B are similar to those of Figure 8A and Figure 8B, and the operation of this system is the same. In this system, HCM_2 vapor is brought into indirect contact with the purified crystal of Zone 3 for heat exchange. The systems illustrated in Figures 10A and 10B are then suitable for vacuum crystallization of aqueous and non-aqueous mixtures. The HCM_2 vapor formed in this system is condensed by the cooling medium of Zone 3, and the formed crystals are not melted by ... H C Μ - 2 vapor. Such a system is particularly suitable for making ice cubes whereby the ice cubes produced in Zone 2 can be compressed to form ice cubes. Such a system is also suitable for use in the distillation freezing process invented by Zheng Jianyan and Zheng Xingwang, which are disclosed in U.S. Patents 4,218,893, 4,433,559, 4,451,273 and 4,457,093. ^ 1 1 及 and 1 1 系 diagram illustrate a multi-function evaporation system comprising a first multi-function evaporator z-ia, a second multi-function evaporator Z-1B in the main operation zone Z-1, In the first HTR unit 61 and the second HTR unit 62 in the Z^B-2A of the system, the third HTR unit in the second end Z-3A of the system and the fourth HTR unit in the Z-3B . The HTR operates cyclically while the multi-function evaporator operates slightly continuously. ° The first multi-function evaporator z - 1 A includes, for example, 9 evaporators ZE-1 - ZE - 9 (69-77) in series, and its operating pressure is from the left end ZE-1 to the right end ZE-9 The direction is gradually reduced. The second multi-function evaporator z-iB, including

第22頁 1249017 --襄號 88113850 年月日 修正 五、發明說明(20)^ 两 ' ~&quot; --- 串聯之9個蒸發器ZE,-1向左端ZE,-9之方向逐漸減少。 4個Η T R單元則各循環運作而輪流作為蒸發器及凝結 器。該4個HTR單元運作於坐標方式。在各端之兩個HTR單 疋之1作為蒸發器時,另一單元則作為凝結器。如第1 1 A圖 所示,Z-2A中及Z_3B中之htr單元61、64則當作20個蒸氣 , 發生器時,Z-2B中及Z-3A之HTR單元62、63則當作2個凝妹 器。 、口· 產生之蒸氣流則供於2個ZE-1區及ZE,-1區,由此開動 多功能蒸發運作。離開最後效率器23_9及ZE,_9之蒸氣, 則在2個HTR單元中被凝結,當作凝結器。第丨丨b圖則圖解❶ 循環於另一半之同系統,其中在Z-2B及Z-3A中之HTR單元 則變成蒸氣發生器而Z_2A及Z-3B中之HTR單元則變成凝結 第12A圖及第12B圖係圖解如同第ΠΑ圖及第11B圖所圖 解之多功能蒸發系統。在此種系統,則使用波形金屬壁以 形成落膜蒸發器。此種系統之運作則如同第丨丨A圖及第11 B 圖所解說者。 第13圖係圖解自一室至另一室未具有任何機械裝置或 電開關之自動閥體系統。此種閥體系統則由結構支柱用之 篩105製成’同時具有兩室用之分隔板,與附於分隔板之 L· 轉板106(由薄膜製成)。此種附有薄膜1〇6之分隔板成為兩 室間之分隔器。薄板轉板1 06為壓力敏感性,而一室之壓 — 力為高於另一室時,轉板則自動開放,使蒸氣自高壓第1 _ 室,流於低壓第2室。當第2室之壓力變成高於第1室之壓 力時,其會自動關閉。Page 22 1249017 -- nickname 88113850 Year of the month Amendment 5, invention description (20) ^ two ' ~ &quot; --- 9 evaporators ZE, -1 in the direction of the left end ZE, -9 gradually reduced. The four Η T R units operate in cycles and take turns as evaporators and condensers. The four HTR units operate in a coordinate mode. When one of the two HTRs at each end acts as an evaporator, the other unit acts as a condenser. As shown in Figure 1 A, the htr units 61 and 64 in Z-2A and Z_3B are treated as 20 vapors. In the generator, the HTR units 62 and 63 in Z-2B and Z-3A are treated as 2 condensate devices. The vapor flow generated by the mouth is supplied to two ZE-1 zones and ZE, -1 zones, thereby enabling multi-function evaporation operation. The vapor leaving the final efficiency 23_9 and ZE, _9 is condensed in the two HTR units as a condenser. Figure 丨丨b diagram ❶ Circulates in the same system as the other half, in which the HTR unit in Z-2B and Z-3A becomes a steam generator and the HTR unit in Z_2A and Z-3B becomes condensed. And Fig. 12B is a diagram illustrating a multifunctional evaporation system as illustrated in the first and the eleventh. In such systems, a corrugated metal wall is used to form a falling film evaporator. The operation of such a system is as explained in Figures A and 11B. Figure 13 is an illustration of an automatic valve body system that does not have any mechanical devices or electrical switches from one chamber to another. Such a valve body system is made of a screen 105 for structural struts', and has a partition plate for two chambers, and an L·turn plate 106 (made of a film) attached to the partition plate. This partition plate with the film 1〇6 serves as a separator between the two chambers. The thin plate transfer plate 106 is pressure sensitive, and when the pressure of one chamber is higher than the other, the transfer plate is automatically opened, so that the vapor flows from the high pressure first chamber to the low pressure second chamber. When the pressure in the second chamber becomes higher than the pressure in the first chamber, it automatically closes.

第23頁 1249017 _案號88113850_年月曰 修正_ 五、發明說明(21) 第13A圖則圖解由薄膜106所製成之單一通氣孔,其中 通氣孔之頂面則附有把持具1 0 7。 本發明之構想具有廣泛之用圖範圍,例如空氣調節、 .水純化、蒸餾冷凍、製冰、廢水處理、海水淡化,在周圍 溫度或高溫下之蒸餾,或有機化學純化及分離,以及其他 * 需要自低溫熱源提升熱溫於高溫熱槽之領域。Page 23 1249017 _ Case No. 88138850_年月曰 曰 Amendment _ V. Invention Description (21) Figure 13A illustrates a single vent hole made of film 106, wherein the top surface of the vent hole is attached with a gripper 10 7. The concept of the invention has a wide range of uses, such as air conditioning, water purification, distillation freezing, ice making, wastewater treatment, seawater desalination, distillation at ambient or elevated temperatures, or organic chemical purification and separation, and others* It is necessary to raise the thermal temperature from the low temperature heat source in the field of high temperature heat sinks.

第24頁 1249017 案號 88113850 年月曰 修正 圖式簡單說明 第1圖係本發明HTR系統之一實施例說明圖; 第2圖係本發明HTR單元之一實施例說明圖; 第2A圖係本發明HTR單元之另一實施例說明圖; 第2B圖係本發明縱向散熱片單元之一實施例結構說明 圖; 第2C圖係第2B圖之含有散熱片之HTR單元的一部分切 割圖; 第3A圖係本發多數連結導管單元之一實施例橫剖面 圖; 第3B圖係第3A圖之多數導管單元,再裝赦縱向散熱片 之橫剖面圖; 第4A圖係本發明之多數導管單元之另一實施例橫剖面 圖; 第4B圖係第4A圖之導管單元,再裝設縱向散熱片之橫 剖面圖; 第5 A圖係本發明之多空隙金屬塊單元之一實施例橫剖 面圖; 第5B圖係第5A圖之多空隙金屬塊單元,再裝設縱向散 熱片之橫剖面圖; 第6A圖係本發明之HTR系統與傳熱自第1運熱媒質之一 實施例說明圖; 第6B圖係第6A圖之HTR系統與傳熱於第2運熱媒質之說 明圖; 第7A圖係本發明HTR系統與傳熱自第1運熱媒質之另一 實施例說明圖;Page 24 1249017 Case No. 88113850 Brief Description of the Modifications Fig. 1 is an explanatory diagram of an embodiment of the HTR system of the present invention; Fig. 2 is an explanatory diagram of an embodiment of the HTR unit of the present invention; BRIEF DESCRIPTION OF THE DRAWINGS FIG. 2B is a structural explanatory view of an embodiment of a longitudinal heat sink unit of the present invention; FIG. 2C is a partial cut view of a HTR unit including a heat sink of FIG. 2B; Figure 3 is a cross-sectional view of one embodiment of a plurality of connecting conduit units; Figure 3B is a cross-sectional view of a plurality of conduit units of Figure 3A, reassembled with longitudinal fins; Figure 4A is a plurality of conduit units of the present invention Another embodiment is a cross-sectional view; FIG. 4B is a cross-sectional view of a catheter unit of FIG. 4A, and a longitudinal heat sink; FIG. 5A is a cross-sectional view of one embodiment of the multi-void metal block unit of the present invention; 5B is a cross-sectional view of a multi-void metal block unit of FIG. 5A, and a longitudinal heat sink; FIG. 6A is an explanatory diagram of an embodiment of the HTR system and heat transfer from the first heat transfer medium of the present invention; ; Figure 6B is the HTR system of Figure 6A And heat transfer in the heat transport medium of the second explanatory diagram; FIG. 7A of HTR-based system of the invention and from the other heat transfer medium of the first heat operation explanatory view of the embodiment;

第25頁 1249017 L , 案號88113850_年月 日 修正 囷式簡單說明 第7B圖係第7A圖之HTR系統與傳熱於第2運熱媒質之說 明圖; ' ” 第8Α圖係本發明之適用於真空冷凍之HTR系統與熱 自第1運熱媒質之一實施例說明圖; ”” 第8B圖係第8A圖之HTR系統與傳熱於第2運熱媒質之說 明圖; 第9A圖係適用於真空冷束之本發明HTR系統與 第1運熱媒體之另一實施例說明圖; 、… 第9B圖係第9A圖之HTR系統與傳熱於第二埶 說明圖; 心…姝買急 曰^ 1 0 A圖係適用於水性溶液與非水性混合物之 發明HTR系統與傳熱自P運熱媒質之另一實施例說。明 說明=〇Β圖係第m圖之HTR系統與傳熱於第2運熱媒質之 第11A圖係組合於本發明HTR單元多 運作於豹循環之-實施例說明圖;之多功此蒸發系統並 環之Γ明1Γ係將第⑴圖之多功㈣發“運作於第2循 ^ ^ ^ 'x τίλ&quot; % ^ ^ ^ ^ ^ 形成洛膜蒸發裔並運作於第丨循 之說 第12Β圖係將第12Α圖之多功能茱| w 說 班 明^ 夕功此蒸發器運作於第2循環Page 25 1249017 L , Case No. 88138850_Yearly and Monthly Correction 简单 Simple Explanation Section 7B is an explanatory diagram of the HTR system of Figure 7A and heat transfer to the second heat transfer medium; ' ” Figure 8 is the present invention An illustration of an embodiment of an HTR system and heat from a first heat transfer medium for vacuum freezing; "" Fig. 8B is an explanatory diagram of the HTR system of Fig. 8A and heat transfer to the second heat transfer medium; FIG. 9B is a diagram showing the HTR system of FIG. 9A and the heat transfer in the second 埶; FIG. 9B is a description of another embodiment of the HTR system and the first heat transfer medium of the present invention; Buying an emergency 1 1 0 A diagram is applicable to an aqueous solution and a non-aqueous mixture. Another embodiment of the HTR system and heat transfer from the P heat transport medium. Illustratively = the HTR system of the m-th diagram The 11A image of heat transfer to the second heat transfer medium is combined with the HTR unit of the present invention which is operated in the Leopard cycle - an explanatory diagram of the embodiment; the multi-function evaporation system and the ring system of the first embodiment are as shown in the figure (1) Gong (4) issued "operating in the second cycle ^ ^ ^ 'x τίλ &quot; % ^ ^ ^ ^ ^ formed the Luo film evaporation and operated in the third FIG 12Β based on the first multi-function dogwood FIG 12Α of | W ^ Xi said Class Description This function operates in the second evaporator loop

第26頁 1249017 案號 88113850 年 月 曰 修正 圖式簡單說明 《圖示中元件名稱與符號對照》 1 熱 溫提 升 單 元 2 導 熱 及 保 壓 導管 3 熱 溫提 升 媒 質 5 加 壓 裝 置 6 散 熱片 7 HTR媒質 8 波 形板 9 側 翼 10 散 熱片 11 導 管 12 HTR媒質 15 熱 溫 提 升 區 16 熱 溫發 生 區 17 蒸 氣 凝 結 區 18 閥 體 19 閥 體 21 供 應結 晶 體 23 結 晶 洗 滌 區 26 熱 源區 線 圈 27 熱 槽 線 圈 29 HIR區 30 真 空 冷 凍 區 32 運 作媒 質 33 結 晶 喜 滌 區 34 結 晶溶 解 區 36 昇 華 冰 39 輸 出水 61 第 1HTR 單 元 62 第 2HTR 單 元 63 第 3HTR 單 元 64 第 4HTR 69 〜77 78 86 :蒸發器 89 〜95 '98 104 : 蒸發器 96 ’ .97 :波 形 金 屬 壁 105 : :篩 06 : 薄 膜轉 板 107 : :把 持 具Page 26 1249017 Case No. 88113850 Revision of the monthly 图 简单 简单 “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ “ Medium 8 corrugated board 9 side flap 10 heat sink 11 conduit 12 HTR medium 15 hot temperature rise zone 16 hot temperature generating zone 17 vapor condensation zone 18 valve body 19 valve body 21 supply crystal 23 crystallization washing zone 26 heat source zone coil 27 hot groove coil 29 HIR zone 30 Vacuum freezing zone 32 Operating medium 33 Crystallization zone 34 Crystallization zone 36 liters of ice 39 Output water 61 1HTR unit 62 2HTR unit 63 3HTR unit 64 4HTR 69 ~ 77 78 86 : Evaporator 89 ~ 95 '98 104 : Evaporator 96 ' .97 : Corrugated metal wall 105 : : Screen 06 : Film transfer plate 107 : : Gripper

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Claims (1)

1249017 -——案號88113850 一修正 θ 六、中請專利範圍 1 ·使用一種熱溫提升媒質來 傳入熱槽之方法,其包括如下步驟昇…概,並使熱從熱源 (a)在第一運熱媒質蔘齑 — 直接或間接接觸熱源並從至::第-運熱媒質經 化變為第-運熱媒質的蒸氣、:、^生J ?第:運f媒質汽 的溫度係高於熱溫提昇媒質(遽質)的融點’、媒質的蒸氣 個乂 , ί 一運熱媒質的蒸_其汽化潛熱,經過第-該埶熟,胤棱昇至中的熱溫提昇裝置; ::j:裝置疋由一個或多個導管内加有熱溫提昇媒 ^接於一個可控制管内熱溫提昇媒質之融點 态所形成的裝置; ^ /c)由於第一運熱媒質係將從熱源取得的熱轉為本身 番潛熱,並進入熱溫提昇室,第一運熱媒質在熱溫提昇裝 =的表面冷卻並將潛熱傳入熱溫提昇裝置内的熱溫提昇媒 貝使其融解,且將熱變為熱溫提昇媒質的融解潛熱,而 於熱溫提昇媒質中; (d) 熱溫提昇媒質經加壓,使其融點提昇到與壓力相 對,溫度’此時熱溫提昇媒質會將融解潛熱傳到導管,並 ^管外的運熱媒質蒸發而產生第二運熱媒質的蒸氣、而熱 因此從熱溫提昇媒質傳給第二運熱媒質,成為二埶 媒質的汽化潛熱; …、 (e) 第二運熱媒質蒸氣帶著其汽化潛熱,經過第二個 :向閥體到達第二運熱媒質冷卻室,I第二運熱媒質的蒸 、直接或間接將其潛熱傳給熱槽,如此完成了將熱從熱源1249017 - - Case No. 88138850 A modified θ VI, the scope of the patent 1 · A method of using a hot temperature to enhance the medium to the heat sink, which includes the following steps, and heat from the heat source (a) A heat medium is used to directly or indirectly contact the heat source and from: to: the first heat transfer medium is transformed into the first heat transfer medium vapor, :, ^ 生 生 ? ?: transport f medium steam temperature is high In the hot temperature to enhance the melting point of the medium (enamel), the vapor of the medium, the steam of the heat medium, the latent heat of vaporization, after the first - the hot temperature rise device that is raised to the middle; ::j: means: a device formed by one or more conduits with a thermal temperature enhancement medium attached to a melting point of a thermally adjustable medium in a controllable tube; ^ /c) due to the first heat transport medium The heat obtained from the heat source is converted into its own latent heat, and enters the hot temperature lifting chamber. The first heat transport medium is cooled on the surface of the hot temperature lifting device and the latent heat is introduced into the hot temperature lifting device. It melts and turns the heat into the latent heat of the heat-enhancing medium, while the heat is raised. (d) The heat temperature raising medium is pressurized to raise the melting point to be opposite to the pressure, and the temperature 'the hot temperature raising medium will transfer the latent heat of fusion to the conduit, and the heat transfer medium outside the tube evaporates. The vapor of the second heat transport medium is generated, and the heat is transferred from the hot temperature raising medium to the second heat transport medium to become the latent heat of vaporization of the second medium; (e) the second heat transfer medium vapor carries the latent heat of vaporization, After the second one: reaching the second heat transfer medium cooling chamber to the valve body, the steam of the second heat transport medium directly or indirectly transfers the latent heat to the heat tank, thus completing the heat from the heat source 第28頁 1249017 案號 88113850 曰 修正 六、申請專利範圍 傳到熱槽的方法 專利範圍第1項所述之方法,所述一個或多 裝置之金屬導管内乃加裝散熱片來加快管内 2. 如申請 個的熱溫提昇 的傳熱速度者。 3. 如申請專利範圍第1項或第2項所述之方法,其中第 一運熱媒質的蒸氣帶著汽化潛熱,經過第一個單向閥體並 在熱溫提昇裝置之導管之表面冷卻,且至少將導管内部份 的熱溫提昇媒質融解。 4 ·如申請專利範圍第1項或第2項所述之方法,其中在 管内的熱溫提昇媒質經加壓後會至少部份固化,並釋出潛 熱,其潛熱將使第二運熱媒質汽化,這些汽化的第二運熱 媒質蒸氣會經過第二個單向閥體到達第二運熱媒質冷卻 室,第二運熱媒質蒸氣直接或間接將其潛熱傳給熱槽並自 行冷卻。 5. 如申請專利範圍第1項或第2項所述之方法,其中熱 溫提昇器之管的表面對運熱媒質而言,既是冷卻器也是蒸 發器,當熱溫提昇器在低壓時,管的表面是第一運熱媒質 冷卻的冷卻器,然而當熱溫提昇器在高壓時,管的表面是 第二運熱媒質蒸發的蒸發器。 6. 如申請專利範圍第1項或第2項所述之方法,其中熱 從熱源傳到熱槽是經由運熱媒質帶著熱源的熱到熱溫提昇 器並從熱溫提昇器到達熱槽,在熱溫提昇器内的熱溫提昇 媒質是固定在導管内,且不流動至熱源或熱槽,熱溫提昇 器本身也是固定的,且不移動至熱源或熱槽。Page 28 1249017 Case No. 88138850 曰 Amendment VII. Method of Transmitting Patent Scope to Hot Tray Patent Method No. 1, the metal conduit of the one or more devices is equipped with a heat sink to accelerate the inside of the tube. For example, if you apply for a heat transfer rate that increases the heat temperature. 3. The method of claim 1 or 2, wherein the vapor of the first heat transfer medium carries the latent heat of vaporization, passes through the first one-way valve body and is cooled on the surface of the conduit of the hot temperature riser And at least melt the thermal temperature enhancing medium inside the conduit. 4. The method of claim 1 or 2, wherein the heat-increasing medium in the tube is at least partially cured after being pressurized, and releasing latent heat, the latent heat of which will cause the second heat-transporting medium Vaporization, the vaporized second heat transfer medium vapor passes through the second one-way valve body to the second heat transfer medium cooling chamber, and the second heat transfer medium vapor directly or indirectly transmits the latent heat to the heat tank and cools by itself. 5. The method of claim 1 or 2, wherein the surface of the tube of the hot riser is both a cooler and an evaporator for the heat transfer medium, and when the hot riser is at a low pressure, The surface of the tube is the first heat transfer medium cooled cooler, however, when the hot temperature riser is at a high pressure, the surface of the tube is the evaporator of the second heat transfer medium evaporation. 6. The method of claim 1 or 2, wherein the heat is transferred from the heat source to the heat sink via a heat transfer medium with a heat source to the heat riser and from the hot riser to the heat sink. The hot temperature raising medium in the hot temperature riser is fixed in the duct and does not flow to the heat source or the hot tank, and the hot temperature riser itself is fixed and does not move to the heat source or the hot tank. 第29頁 1249017 案號 88113850 年 曰 修正 六、申請專利範圍 7. 如申請專利範圍第1項或第2項所述之方法,其中單 向閥體是設在於第一運熱媒質蒸氣生產室與熱溫提昇室之 間,及設在熱溫提昇室與第二運熱媒質冷卻室之間,而此 閥體是由鐵網做間隔及支架,並用薄膜做為閥門。 8. 如申請專利範圍第2項所述之方法,其中為了增加 熱溫提昇裝置的效能、傳熱片可裝置於管内,來縮短管内 熱溫提昇媒質之傳熱距離,進而增加管内的熱傳速度。Page 29 1249017 Case No. 88113850 曰 Amendment VI. Patent Application No. 7. The method of claim 1 or 2, wherein the one-way valve body is located in the first heat transfer medium steam production room and Between the thermal temperature riser chambers and between the hot temperature riser chamber and the second heat transfer medium cooling chamber, the valve body is made of iron mesh spacers and brackets, and the film is used as a valve. 8. The method according to claim 2, wherein in order to increase the efficiency of the hot-temperature lifting device, the heat transfer sheet can be installed in the tube to shorten the heat transfer distance of the heat-increasing medium in the tube, thereby increasing the heat transfer in the tube. speed. 9. 如申請專利範圍第1項或第2項所述之方法,其中當 用一個步驟的熱溫提昇裝置還無法達到所需之溫度時,可 用多數的熱溫裝置以多層次來達到所要求的熱溫。 1 0.如申請專利範圍第1項或第2項所述之方法,其中 第一運熱媒質以間接取熱的方式從空氣取熱,並產生第一 運熱媒質蒸氣者。 11.如申請專利範圍第1項或第2項所述之方法,其係 用水當作是熱源,並讓水流入第一運熱媒質蒸氣生產室, 水會在此室極速蒸發,產生第一運熱媒質的蒸氣並同時使 水流冷卻者。9. The method of claim 1 or 2, wherein when a step of the temperature riser fails to reach the desired temperature, the majority of the heats can be used to achieve the desired level at multiple levels. The heat temperature. The method of claim 1 or 2, wherein the first heat transfer medium extracts heat from the air in an indirect heat extraction manner and generates the first heat transfer medium vapor. 11. The method of claim 1 or 2, which uses water as a heat source and allows water to flow into the first heat transfer medium vapor production chamber, where water will evaporate at a rapid rate to produce a first The heat of the medium is transported while the water is cooled. 1 2.如申請專利範圍第1項或第2項所述之方法,其係 用水間接從空氣取熱,使水的溫度提高,並使水的顯熱增 加,並將這些高顯熱的水在第一運熱媒質蒸氣生產室内極 速蒸發且產生第一運熱媒質蒸氣者。 1 3.如申請專利範圍第1項或第2項所述之方法,其中 第一運熱媒質蒸氣的製造是至少將部份的第一運熱媒質蒸 發,其蒸發之方法是將第一運熱媒質同時蒸發與固化,使1 2. The method of claim 1 or 2, wherein the method uses water indirectly to extract heat from the air, raises the temperature of the water, and increases the sensible heat of the water, and increases the sensible heat of the water. In the first heat transfer medium steam production chamber, the first heat transfer medium vapor is generated. 1. The method of claim 1 or 2, wherein the first heat transfer medium vapor is produced by evaporating at least a portion of the first heat transfer medium, and the evaporation method is the first transport The heat medium evaporates and solidifies at the same time 第30頁 1249017 案號 88113850 曰 修正 六、申請專利範圍 其產生大量的媒質的固體, 1 4.如申請專利範圍第1 該運作係使用於空氣調節蒸 水處理、脫鹽、在常溫或高 純化及分離、或需要自低溫 作者。 1 5.如申請專利範圍第1 中,該運作係使用此反向熱 熱槽,藉此使其傳熱的速度 1 6.如申請專利範圍第1 裝置於第一運熱媒質蒸氣生 溫提昇室與第二運熱媒質冷 1 7.如申請專利範圍第1 係包括多數閥門,使蒸氣流 1 8.如申請專利範圍第1 中閥體是由至少一個分隔器 蒸氣通過。 及第一運熱媒質蒸氣。 項或第2項所述之方法,其中 餾冷凍、製冰、海水純化、廢 溫下之蒸餾操作、有機化合物 熱源提昇溫度於高溫熱槽之操 項或第2項所述之方法,其 傳方式由低溫熱源傳熱至高溫 較一般增加者。 項所述之方法,其中熱溫提昇 產室與熱溫提昇室之間及在熱 卻室之間設有單向閥體者。 6項所述之方法,其中該閥體 通於單一方向者。 6項或第1 7項所述之方法,其 由鐵絲網做支架,並用薄膜使 &lt;1Page 30 1249017 Case No. 88113850 曰 Amendment VII. Applying for a patent range It produces a large amount of solids in the medium, 1 4. If the scope of application is No. 1 This operation is used for air conditioning steam treatment, desalting, at room temperature or high purification and Separated, or required from cryogenic authors. 1 5. In the first application of the patent scope, the operation uses the reverse heat-heating tank, thereby making the heat transfer rate of the gas-heating medium of the first heat-transfer medium. The chamber is cooled with the second heat transfer medium. 1. 7. As claimed in the patent scope, the first system includes a plurality of valves for vapor flow. 1. The valve body of the first aspect of the patent application is passed by at least one separator vapor. And the first heat transfer medium vapor. The method of item 2, wherein the distillation, ice making, seawater purification, distillation operation at waste temperature, organic compound heat source raising temperature in a high temperature heat tank or the method described in item 2, The mode of transmission is from heat transfer from a low temperature heat source to a higher temperature than the general increase. The method of the invention, wherein the heat temperature is raised between the production chamber and the hot temperature rise chamber and the one-way valve body is provided between the heat chambers. The method of item 6, wherein the valve body is in a single direction. The method of item 6 or item 17, which is made of a wire mesh as a support and is made of a film &lt;1 第31頁Page 31
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