1240962 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種半導體製程,尤指一種可以抑制缺陷引發的 (defect-induced)瞬間增益擴散(transient enhanced diffusion TED)效 應的半導體製程方法。本發明特別適合應用於具備超淺接面之汲 極/源極延伸區域的電晶體元件的製作過程。 【先前技術】 隨著半導體1C元件推進至次微米或奈米等級以下之微細化尺 寸,積體電路中的M0S電晶體元件須製作成具有超淺接面⑽ra shallow junct㈣之汲極/源極延伸⑽職/办血加咖㈣區域之結 構,以克服元件尺寸縮小所伴隨產生如短通道效應(sh〇rtch雲】 effect)等問題。然而,形成超淺接面之汲極/源極延伸區域的問題 在於其接©城,則MQS電晶體元件的片微越大,如此將導致 兀件操作蚪的飽和電流(saturati〇n cu腦t)不足。這個現象在麗^ 電晶體元件上越顯得嚴重。 般超义接面之汲極/源極延伸區域的製作係以低能量離子佈 ^進入錄底的絲面。在縮小元件尺寸同時,祕,汲極與通 则雜原子/讀必須提高,接面深度減小及摻雜原子濃度分佈 各重^有縣的交化,因此掌握摻雜元素擴散的行為便顯得相 性的与鄕不過石夕曰曰内換雜^素的擴散受到許多製程參數與材質特 、〜曰’例如缺陷引發的瞬間增益擴散(transient enh anced 1240962 diffusion,TED)效應必須設法減小。 因此,目前該技術領域確實需要一種可 =r擴一法,可避免超淺::== 域的摻雜輪廓因擴散而產生改變。 【發明内容】 可以有效抑制前述 本發明之主要目的在提供一種半導體製程, 缺陷引發的瞬間增益擴散效應。 本《明之另-主要目的在提供一種具備超淺接面之沒極/源極 延伸區域的電晶體元件㈣方法,可避免贼接崎極/源極延伸 區域的摻雜輪廓因瞬間增益擴散效應而產生改變。 根據本發明讀佳實關,本發明提供—種具峨接面汲極/ 源極延伸半導體電晶體元件的製作方法,包含有··提供一基底; 於4基底上形成一閘極結構,其包含有兩側壁以及一上表面;於 該閘極結構之側壁上形成偏側壁子;進行第一離子佈植製程,於 該閘極結構兩側之該基底形成第一摻雜區域;於該閘極結構之偏 側壁子上以及其上表面沈積一襯墊層;於該襯墊層上沈積一側壁 子層;進行一應力修正佈植製程,改變該側壁子層之應力狀態由 伸張狀悲(tensile)改變至較為壓縮(compressive)之狀態;以及進行 一乾蝕刻製程,將該側壁子層蝕刻成側壁子。 1240962 為讓本發明之上述目的、特徵、和優點能更明顯易懂,下文特 舉-較佳實施例,並配合所關式,作詳細說明如下。 【實施方式】 明茶閱第1圖至第3圖’其!會示的是根據本發明較佳實施例製· 作具備超雜面线極/源觀輕域18的pMQs電晶體元件⑽. t剖面示意圖。如第!圖所示’在N型基底1〇上以絕緣結構,如 淺溝絕緣(shallow trench —η,STI)結構,定義出主動區域12〇。_ N型基底10如N型石夕基底。在主動區域12〇上形成有多晶石夕問極 結構12。多晶石夕閘極結構12與基底1〇之間有閘極介電層14,例 如二氧化矽等。 在多晶石夕閘極結構12的侧壁上形成有偏侧壁子(〇ffset spaCer)16。偏侧壁子16可以由二氧化矽所構成。在形成偏側壁子 16之後,利用離子佈植製程,在多晶石夕閘極結構I]兩側的基底 修 10内植入P型摻質,例如硼離子,形成超淺接面的p型摻雜區域 18。根據本發明之較佳實施例,p型摻雜區域18的接面深度約為 30埃以内。 隨後’以化學氣相沈積方法或者以爐管,在多晶矽閘極結構12 、 上以及在P型摻雜區域18上沈積二氧化矽襯墊層22。二氧化矽襯 墊層 22 可以是以 BTBAS (bis(tertiarybutylamine)silane)為前驅物 8 1240962 (precursor)與氧氣所產生的二氧化石夕。 接著’於二氧化石夕襯墊層22上沈積氮化石夕侧壁子層24。氮化 矽侧壁子層24 積可以採帛姆餘沈積⑽师㈣,/ (position,CVD)製程。根據本發明之較佳實施例,氮化秒側壁子 層24的厚度約為_至700埃。氮化石夕侧壁子層%此時的^力: 仍為伸張狀態(tensile)。 如第2圖所示,接著對氮化矽側壁子層24進行一應力修正 鲁 (stress modification)佈植製程30,以電性為中性的重摻質,例如鍺 (germanium)或氙(xenon)等,以佈植能量在25至15〇KeV之間劑 量在2E14至5E15at〇ms/Cm2之間的條件下,將原先應力為伸張狀 態(tensile)的氮化石夕側壁子層24改變成較為壓縮(c〇mpressive)之狀 態。根據本發明之較佳實施例,應力修正佈植製程3〇的投射範圍 (projected range,Rp)其值應小於氮化矽側壁子層24的厚度,以厚 度700埃為例,RP較佳介於350至7〇〇埃之間。第4圖係以表列鲁 分別利用鍺以及氤進行佈植製程3〇之較佳化條件。 如第3圖所示,接著進行一乾姓刻製程,將氮化石夕侧壁子層24 名虫刻成在多晶梦閘極結構12側壁上的側壁子34。隨後再進行離子 ' 佈植製程,將P型摻質植入多晶矽閘極結構12兩側的基底1〇内,' 形成PM0S電晶體元件1〇〇的汲極/源極區域48。 9 1240962 第5圖以表列利用錯(Ge)為應力修正佈植製程的接質,在不 同的摻雜條件下所可以改變的氮化石夕側壁子層24應力值以及超淺 接面的P型掺雜區域18的片電阻㈣。如第5圖所示,當錯(Ge) 的佈植能量it _Kev,魅在則atGmsw的條件下,氮僻 . 侧壁子層24應力值由原先的U9E10 dyne/cm2 (tensile)降至 心7E9 dyne/cm2 (compressive),而超淺接面的p型摻雜區域i8的 片電阻(Rs)由4634ohm/sq大幅降低至1787〇hm/sq。 相較於習知技藝,由於本發明以應力修正佈植製程3〇改變氮 · 化石夕侧壁子層24的應力值,使其由原先的伸張狀態㈣此)改變成 較為壓縮(compressive)之狀態,藉此降低矽表面的空隙缺陷 (defect),由此可使植入石夕基底10的硼摻質擴散程度降低,避免超 淺接面汲極/源極延伸區域的摻雜輪廓因瞬間增益擴散效應而產生 改變,因此可以達到降低超淺接面的P型摻雜區域18的片電阻並 且獲得較淺的接面深度。 以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍 所做之均等變化與修飾,皆應屬本發明專利之涵蓋範圍。 【圖式簡單說明】 第1圖至第3圖繪示的是根據本發明較佳實施例製作具備超淺 ' 接面之汲極/源極延伸區域的PMOS電晶體元件的剖面示意圖。 第4圖以表列分別利用鍺以及氙進行佈植製程之較佳化條件。 ⑽962 的摻雜終 =m_Ge則力修蝴·糊《,在不同 的p、斤可以改、交的氮化梦側壁子層應力值以及超淺接面 、型摻雜區域的片電阻(RS)。 【主要元件符號說明】 1〇基底 14 閘極介電層 18 p型摻雜區域 24 氮化矽側壁子層 34 側壁子 100 PMOS電晶體元件 12 多晶石夕閘極結構 16 偏侧壁子 22 二氧化石夕襯塾層 30 應力修正佈植製程 48 汲極/源極區域 120 主動區域1240962 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a semiconductor process, and more particularly to a semiconductor process method capable of suppressing a defect-induced transient enhanced diffusion TED effect. The invention is particularly suitable for the manufacturing process of a transistor element having a drain / source extension region with an ultra-shallow junction. [Previous technology] As semiconductor 1C devices advance to submicron or nanometer-sized miniaturized sizes, M0S transistor devices in integrated circuits must be made with a shallow / junction drain / source extension Unemployment / blood plus coffee area structure to overcome problems such as short channel effect (shortch cloud effect) accompanying the reduction in component size. However, the problem of forming the drain / source extension region of the super shallow junction is that it is connected to the circuit, and the chip of the MQS transistor element is slightly larger, which will cause the saturation current of the element to operate. t) insufficient. This phenomenon becomes more serious on Li transistor devices. The production of the drain / source extension area of the general supersense interface is made by using a low-energy ion cloth to enter the silk surface of the recording bottom. While reducing the size of the element, the secretion, the drain and the general heteroatom / read must be increased, the junction depth is reduced, and the dopant atom concentration distribution is different. There are cross-country crossovers, so mastering the diffusion behavior of dopant elements appears to be consistent However, Shi Xiyue ’s diffusion of internal impurities is affected by many process parameters and material characteristics. For example, transient enh anced 1240962 diffusion (TED) effect caused by defects must be managed to reduce. Therefore, at present, the technical field really needs a method that can be expanded by r, which can avoid the change of the doping profile of the super shallow ::: = domain due to diffusion. [Summary of the Invention] The main objective of the present invention is to effectively suppress the transient gain diffusion effect caused by defects caused by a semiconductor process. The main purpose of this article is to provide a transistor device with an ultra-shallow junction / source extension region, which can avoid the effect of instantaneous gain diffusion on the doping profile of the junction / source extension region. Make a difference. According to the present invention, the present invention provides a method for manufacturing a semiconductor transistor element with an E-junction drain / source extension, including: providing a substrate; and forming a gate structure on 4 substrates. Comprising two side walls and an upper surface; forming side walls on the side walls of the gate structure; performing a first ion implantation process to form a first doped region on the substrate on both sides of the gate structure; A pad layer is deposited on the side wall of the polar structure and on the upper surface thereof; a side wall sub layer is deposited on the pad layer; a stress correction implantation process is performed to change the stress state of the side wall sub layer from a stretched state ( tensile) to a more compressed state; and performing a dry etching process to etch the sidewall sub-layer into a sidewall. 1240962 In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, the following describes the preferred embodiment in combination with related formulas in detail as follows. [Embodiment] Mingcha read Figure 1 to Figure 3 'its! Will be shown in accordance with the preferred embodiment of the present invention to make · pMQs transistor with super-heteroline line pole / source view light domain 18 ⑽. Schematic t section. As the first! As shown in the figure, the active region 12 is defined by an insulating structure on the N-type substrate 10, such as a shallow trench insulation (STI) structure. _ The N-type substrate 10 is an N-type Shixi substrate. A polycrystalline stone interrogation structure 12 is formed on the active region 120. There is a gate dielectric layer 14 between the polycrystalline silicon gate structure 12 and the substrate 10, such as silicon dioxide. A sidewall spacer 16 is formed on the sidewall of the polycrystalline stone gate structure 12. The side wall 16 may be made of silicon dioxide. After the partial sidewalls 16 are formed, P-type dopants, such as boron ions, are implanted into the substrate 10 on both sides of the polycrystalline stone gate structure I] using an ion implantation process to form a p-type super shallow junction. Doped region 18. According to a preferred embodiment of the present invention, the junction depth of the p-type doped region 18 is within about 30 angstroms. Subsequently, a silicon dioxide liner layer 22 is deposited on the polycrystalline silicon gate structure 12 and on the P-type doped region 18 by a chemical vapor deposition method or a furnace tube. The silicon dioxide lining cushion layer 22 may be a bismuth dioxide produced by using BTBAS (bis (tertiarybutylamine) silane) as a precursor 8 1240962 (precursor) and oxygen. Next, a nitride stone sidewall sub-layer 24 is deposited on the stone dioxide gasket layer 22. The silicon nitride sidewall sub-layers can be deposited by a deposition method (position, CVD). According to a preferred embodiment of the present invention, the thickness of the nitrided second sidewall sub-layer 24 is about ˜700 Å. Nitrile stone side wall sublayer% force at this time: still in a stretched state (tensile). As shown in FIG. 2, a stress modification implantation process 30 is performed on the silicon nitride sidewall sub-layer 24, and a heavy neutral dopant such as germanium or xenon ), Etc., under the condition that the implantation energy is between 25 and 150 KeV and the dose is between 2E14 and 5E15 at 0 ms / Cm2, the nitrided nitride sidewall sub-layer 24 originally changed to a tensile state is changed to Compressed. According to a preferred embodiment of the present invention, the projected range (Rp) of the stress correction implantation process 30 should be smaller than the thickness of the silicon nitride sidewall sub-layer 24. Taking the thickness of 700 angstroms as an example, RP is preferably between Between 350 and 700 Angstroms. Figure 4 shows the optimal conditions for the implantation process 30 using germanium and thallium, respectively, in the form of tablelu. As shown in FIG. 3, a dry last engraving process is then performed to engraving 24 worms on the side walls of the nitrided stone side wall into side walls 34 on the side wall of the polycrystalline gate structure 12. Subsequently, an ion implantation process is performed, and a P-type dopant is implanted into the substrate 10 on both sides of the polycrystalline silicon gate structure 12 to form a drain / source region 48 of the PMOS transistor element 100. 9 1240962 Fig. 5 shows the table in Table 5 using stress (Ge) as the stress to modify the bonding process of the implantation process. Under different doping conditions, the stress value of the nitrided nitride sublayer 24 and the P of the super shallow junction can be changed. The sheet resistance of the type doped region 18 is chirped. As shown in Figure 5, when the implantation energy of it (Ge) is it_Kev, the charm is at Gmsw, and the nitrogen is isolated. The stress value of the side wall sublayer 24 is reduced from the original U9E10 dyne / cm2 (tensile) to the heart. 7E9 dyne / cm2 (compressive), and the sheet resistance (Rs) of the p-type doped region i8 of the super shallow junction was greatly reduced from 4634ohm / sq to 1787hm / sq. Compared with the conventional technique, the present invention changes the stress value of the nitrogen · fossil evening wall sublayer 24 by the stress correction process 30, so that it changes from the original stretched state to a more compressed one. State, thereby reducing void defects on the silicon surface, thereby reducing the degree of diffusion of boron dopants implanted into the substrate 10, and avoiding the doping profile of the drain / source extension region of the super shallow junction due to transient The gain diffusion effect causes a change, so that it is possible to reduce the sheet resistance of the P-type doped region 18 of the super shallow junction and obtain a shallower junction depth. The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the scope of patent application of the present invention shall fall within the scope of the patent of the present invention. [Brief description of the drawings] FIGS. 1 to 3 are schematic cross-sectional diagrams of manufacturing a PMOS transistor device having a drain / source extension region with an ultra shallow junction according to a preferred embodiment of the present invention. Figure 4 lists the optimized conditions for the implantation process using germanium and xenon, respectively. The doping end of ⑽962 = m_Ge Zelixiu. "The stress value of the nitrided nitride sidewall sublayer can be changed at different p, jin, and the sheet resistance (RS) of the super shallow junction and type doped regions. . [Description of main component symbols] 10 base 14 gate dielectric layer 18 p-type doped region 24 silicon nitride sidewall sublayer 34 sidewall 100 PMOS transistor 12 polycrystalline silicon gate structure 16 partial sidewall 22 Stone dioxide lining 30 Stress correction process 48 Drain / source region 120 Active region