TW583193B - Catalytic species based on a rare earth and magnesium, its use in polymerising an olefin or a lactone, and ethylene-co-(meth)acrylic ester diblock copolymers obtained - Google Patents

Catalytic species based on a rare earth and magnesium, its use in polymerising an olefin or a lactone, and ethylene-co-(meth)acrylic ester diblock copolymers obtained Download PDF

Info

Publication number
TW583193B
TW583193B TW091100161A TW91100161A TW583193B TW 583193 B TW583193 B TW 583193B TW 091100161 A TW091100161 A TW 091100161A TW 91100161 A TW91100161 A TW 91100161A TW 583193 B TW583193 B TW 583193B
Authority
TW
Taiwan
Prior art keywords
item
ethylene
catalytic species
patent application
rare earth
Prior art date
Application number
TW091100161A
Other languages
English (en)
Chinese (zh)
Inventor
Jean-Francois Carpentier
Thomas Chenal
Jerome Gromada
Andre Mortreux
Original Assignee
Rhodia Elect & Catalysis
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Elect & Catalysis filed Critical Rhodia Elect & Catalysis
Application granted granted Critical
Publication of TW583193B publication Critical patent/TW583193B/zh

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0211Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212Alkoxylates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/026Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising acrylic acid, methacrylic acid or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/823Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW091100161A 2001-01-09 2002-01-08 Catalytic species based on a rare earth and magnesium, its use in polymerising an olefin or a lactone, and ethylene-co-(meth)acrylic ester diblock copolymers obtained TW583193B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0100214A FR2819199A1 (fr) 2001-01-09 2001-01-09 Espece catatytique a base d'une terre rare et de magnesium, son utilisation dans la polymerisation d'une olefine ou d'une lactone et copolymeres diblocs ethylene-co-esters (meth) acryliques obtenus

Publications (1)

Publication Number Publication Date
TW583193B true TW583193B (en) 2004-04-11

Family

ID=8858617

Family Applications (1)

Application Number Title Priority Date Filing Date
TW091100161A TW583193B (en) 2001-01-09 2002-01-08 Catalytic species based on a rare earth and magnesium, its use in polymerising an olefin or a lactone, and ethylene-co-(meth)acrylic ester diblock copolymers obtained

Country Status (4)

Country Link
AU (1) AU2002228142A1 (fr)
FR (1) FR2819199A1 (fr)
TW (1) TW583193B (fr)
WO (1) WO2002055193A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817659B (zh) * 2015-05-04 2017-04-12 宁波工程学院 降冰片烯类、八氟环戊烯和苯乙烯三元共聚催化剂以及三元共聚方法
FR3123917B1 (fr) * 2021-06-10 2024-04-19 Michelin & Cie Système catalytique pour la polymérisation stéréospécifique de diènes et leur utilisation en procédé de synthèse de polymères diéniques

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8314382D0 (en) * 1983-05-24 1983-06-29 Enoxy Chemicals Ltd Polymerisation of conjugated dienes
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
US5527751A (en) * 1993-06-29 1996-06-18 Maruzen Petrochemical Co., Ltd. Polymerization catalyst and method for producing polyolefin or olefin block copolymer using the same
US5563219A (en) * 1993-07-16 1996-10-08 Mitsui Toatsu Chemicals, Inc. Process for Preparing block copolymer of monoolefin
WO1996019513A1 (fr) * 1994-12-22 1996-06-27 Mitsubishi Rayon Co., Ltd. Copolymere sequence et procede de fabrication
FR2795976B1 (fr) * 1999-07-05 2001-10-05 Rhodia Terres Rares Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures

Also Published As

Publication number Publication date
WO2002055193A3 (fr) 2003-01-03
WO2002055193A2 (fr) 2002-07-18
AU2002228142A1 (en) 2002-07-24
FR2819199A1 (fr) 2002-07-12

Similar Documents

Publication Publication Date Title
Yamago et al. Highly controlled living radical polymerization through dual activation of organobismuthines
EP0265091A1 (fr) Polymérisation de transfert de groupe et initiateurs pour cette polymérisation
Feng et al. Preparation and properties of optically active poly (N-methacryloyl L-leucine methyl ester)
Woodman et al. Heterogenized “ligand-Free” lanthanide catalysts for the homo-and copolymerization of ethylene and 1, 3-butadiene
Ueda et al. Synthesis and homopolymerization kinetics of α-methylene-δ-valerolactone, an exo-methylene cyclic monomer with a nonplanar ring system spanning the radical center
TW583193B (en) Catalytic species based on a rare earth and magnesium, its use in polymerising an olefin or a lactone, and ethylene-co-(meth)acrylic ester diblock copolymers obtained
JPH03263412A (ja) ポリメタクリル酸エステル及びポリアクリル酸エステルの製造方法
JP2854888B2 (ja) モリブデン触媒系を用いる高ビニルポリブタジエンの合成
US5218064A (en) Process for preparing narrow molecular weight distribution syndiotactic polymers or copolymers of unsaturated carboxylic acid esters
JP2013237748A (ja) ビニルエステルとビニルエーテルの共重合体、およびその製造方法
CN109679082B (zh) 利用双核手性胺亚胺镁配合物催化乙交酯聚合的方法
CN109734880B (zh) 利用双核手性胺亚胺镁配合物催化丙交酯聚合的方法
JP4837820B2 (ja) プロピレンオキシドの重合触媒組成物およびプロピレンオキシドの重合体の製造方法
JP5090792B2 (ja) 重合体の製造方法
Kawamura et al. New Iron (II) Complexes for Atom‐Transfer Radical Polymerization: The Ligand Design for Triazacyclononane Results in High Reactivity and Catalyst Performance
JP2003504429A (ja) 希土類元素とマグネシウムを基材とした触媒系、新規なネオジムアルコラート及び不飽和化合物の重合への使用
Gao et al. Heterobimetallic aluminium and zinc complex with N-arylanilido-imine ligand: Synthesis, structure and catalytic property for ring-opening polymerization of ε-caprolactone
Santarella et al. Cationic polymerization of dienes III. Polymerization of 1, 3-pentadiene initiated by ferric chloride in hexane
US20030166804A1 (en) Trivalent organic lanthanoid complex, catalyst for production of (meth) acrylic polymer, and (meth) acrylic polymer
JPH06298869A (ja) ポリ(p−tert−ブトキシスチレン)の製造方法
JPH0693049A (ja) メタクリル系ランダム共重合体およびその製造方法
CN100500717C (zh) 合成降冰片烯与马来酸酐共聚物的方法
Xu et al. Polymerization of n-Hexyl Isocyanate with Rare Earth Catalyst Composed of Nd (P 204) 3/Al (i-Bu) 3
RU2802780C1 (ru) Способ получения низкомолекулярного сополимера этилена и винилацетата (варианты)
JPH11286525A (ja) イソブチレン系ブロック共重合体の製造方法