TW559633B - Agents for and methods of processing synthetic fibers - Google Patents

Abstract

An agent containing a polyether compound, a straight-chain polyether modified polyorganosiloxane of a specified kind and a quaternary onium salt of a specified kind at specified ratios are applied at a specified rate to synthetic fibers subjected to a heat treatment such as false twisting.

Description

559633 Intellectual Property Bureau, Ministry of Economic Affairs, B Industrial Cooperative Cooperative, Printing and Printing Co., Ltd. A7 B7 V. Description of the Invention f 1) Detailed Description of the Invention [Technical Field Developed by the Invention] The present invention is a synthetic fiber treatment agent (hereinafter referred to as a treatment agent) Follow the synthetic fiber processing method (hereinafter referred to as the processing method). From the production of synthetic fibers to the processing process, in order to make the synthetic fibers have lubricity and antistatic properties, a treatment agent containing a lubricant and an antistatic agent is attached. However, the synthetic fibers are supplied to a heat treatment process such as a false twist process. It is very important to prevent the pollution of the heater due to the thermal degradation of the treatment agent in the heat treatment process of the relative heat treatment. It is very important to obtain a high-quality false twisted yarn by suppressing the generation of broken feathers or broken yarns. Subject. The present invention relates to a treatment agent and a treatment method that can effectively prevent contamination of heaters. [Preceding technology] In the past, as a treatment agent capable of preventing heater contamination as described above, for example, a mixture of a polyether compound and polyorganosiloxane (Poly-Organosiloxane) and an ionic surfactant was used. Among the related pre-treatment agents, used as a mixed polyorganosiloxane: i) The viscosity of 251c is 30 xio-6 in 2 / sK, and the surface tension of 251C is 28 dyne / cm κ Polydimethylsiloxane or fluoroalkyl-denatured polydimethylsiloxane (Japanese Patent Laid-Open No. 54-46923), 2) Poly 301 with a viscosity of 15 × 10-6 m 2 / sM Dimethylsiloxane (Japanese Patent Application Laid-Open No. 48-5 3093), 3) Phenylpolysiloxane (Japanese Patent Application Laid-open No. Shokai 3) with a viscosity of 10 × 10-0 to 80X10-6 id2 / sM Sho 47_50657) '4) Polyether-denatured polyorganosiloxane (USP 4561987, USP5061384), 5) Sand gas burning unit number 4 to 12 linear polyorganosiloxane (USP5772910)' 6) Sand oxygen This paper size applies to China National Standard (CNS) A4 (210X 297 mm)-4-— II —— ^ --- Feng ------ 1T ------ 0 (Please read the Please fill in this page again for attention) 559633 A7 B7 V. Inventive sharp 4 2) Cyclic polyorganosiloxane (USP5755984) with 4 to 14 alkane units. The heat of the device is about to be increased. In the past, the working period is close to the work process. The heat treatment is processed by the S unit. The front part is not enough, but it is dirty.

The Cheng Cheng of the field is short. The short heat of the V device is short enough. The 30 points that cannot be prevented are not enough to prevent. The dyeing machine is warm and there is a meeting point. Cheng i: The hot hair is broken. this. Because of the wonderful work, the quality of the added product is high enough to make it impossible to prevent. The hot yarn of the stained stain device is broken or the problem is resolved. The former use of the management is used at 30, and the solution used in the temperature test class is CM. Rfu The special heating device of the original process is short and the upper MV is dirty. It ’s enough to stop defenses, but you ca n’t do it together. Cheng Yi, the questioner of the twister, asks the solver 3C. It ’s a special case, but it ’s a special case.

Cheng Zheng's false heat treatment and short-term treatment of OC and physical treatment of ether dyes and polyethers that are physically combined with the agent are heated by the device system. The results are filled with KK, but the law can also be used (please read the precautions on the back before filling in this page). The employee co-operative society of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the facets ne and xa 焼 10 oxygen si silicon. C machine ga has 0Γ The polymer plant 01 will (P and alkane and oxygen, the silicon-forming mechanism has a polymerization agent property activation ether surface polyboundary chain straight away-1 Π Ε heat and heat species for this reason to attach a positive amount 'The definite person refers to the use of a structural agent to make sense. Including this example will be more effective than the actual distribution of the agent.

Due to the fact that the synthetic ether polyether is a series of 0-series fruits, the good properties of the binder are obtained, and the cost of the vinyl issuance is low, the instantaneous process is also X, and the oxygen-forming silicon forming machine of the alkanes has all the polymerizability. The polyether chain on the active surface of the ether is separated from it. E) Show an ox j Ί * i 1 s formula no tga, or y- and 01 1 / p. {This paper is also applicable to Chinese national standards ( CNS M4 specifications (21 () > < 297 mm) 5 559633 A7 B7 V. Description of the invention (4 ·) (Please read the precautions on the back before filling this page) Yes (1) in [Formula 1] When η is 1, there is one linear polyether unit at each end of a linear polysiloxane unit, and the linear polyether unit is connected through a linking group, and the linear polyether is at both ends. For units, (2) When η in [Formula 1] is 2 to 30, two linear polysilicons on KK. Oxane units and two or more linear polyether units are connected through a linking group. It is a straight structure, and the two ends are linear polyether units. The staff of the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperative Cooperative Printing ^ In [Formula 1], the terminal groups R1 Μ and R4 of the linear polyether unit, Residues or hydroxyl groups are removed from compounds containing monovalent active hydrogen having the same or different carbon numbers of 1 to 40. Monovalent active compounds containing 1 to 40 carbon atoms are also included Examples of the hydrogen compound include: (1) methanol, octanol, stearyl alcohol, hexacosanol, isobutanol, 2-ethylhexanol, isohexadecanol, and ishencosanol Aliphatic saturated alcohols having 1 to 40 carbon atoms such as 2-propanol, 12-icosanol, (2) vinyl alcohol, propenyl alcohol, oley 1 alcohol, eicosanol, 2-methyl alcohol Aliphatic unsaturated alcohols having 2 to 40 carbon atoms such as 2-propenyl-1-ol and 15-hexadecen-2-ol, (3) phenol, (4) propylphenol, octylphenol, K alkyl with 1 to 34 carbon atoms such as tridecylphenol, substituted alkylphenol, (5) octanethiol, octadecanethiol, 2-ethylhexanethiol, isododecanethiol, etc. Fatty saturated thiols with 1 to 40 carbon atoms * (6) Fatty saturated carboxylic acids with 1 to 40 carbon atoms such as acetic acid, lauric acid, behenic acid, etc., (7) Oleic acid, erucic acid, Fatty unsaturated carboxylic acids with 2 to 40 carbon atoms, such as oleic acid, 8) Aliphatic alkylamines having 2 to 40 carbon atoms, such as octylamine and diolenylenylamine; (9) Carbon atoms, such as dibutyl ethionylamine and diisooctadecylpropylamine; 40 aliphatic alkanolamines, etc., 7 of which are formed by aliphatic saturated enzymes having 1 to 10 carbon atoms. This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 559633 A 7 B7 5 , Description of invention Γ. (7)

8 R

RIX 丨 R

R

B Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs in [Formula 2], X: N or P R6, R7, R8, R9: Simultaneous or different carbon atoms at the same time. Alkyl number 1 to 25, carbon Alkenyl group with 2 to 25 atoms, or Hydroxyalkyl group with 1 to 6 carbon atoms, By ~: From phosphate esters with 1 to 30 carbon atoms, sulfate esters with 1 to 30 carbon atoms, and carbon atoms 1 ~ 30 Sentence (3 ^ If one) acid ester M and carboxylic acid having 1 to 30 carbon atoms selected from the compound selected from the y-valent anion group y of the hydrogen ion: an integer of 1 to 3 is [Formula 2] The iron salt shown, when X in formula (1) is N, is composed of a quaternary ammonium cation group and an anion group in which a part or all of the hydrogen ions are removed from the aforementioned 1 to 3 valence compound. (4) When X in P in (2) [Formula 2] is P, the anion group that removes part or all of the hydrogen ions from the fourth-order radicle cation group and the aforementioned compound of 1 to 3 valence Constructors are included. First, explanation will be given for the fourth-order ammonium salt plus M. The quaternary ammonium cation group constituting the quaternary ammonium salt contains (1) R6 to R9 in [Formula 2] (M is referred to as an organic group in [Formula 2]) and all have 1 to 25 carbon atoms. Alkyl groups (2) Organic groups in [Formula 2] are all alkenyl groups having 2 to 25 carbon atoms, and (3) Organic groups in [Formula 2] are hydroxy groups having 1 to 6 carbon atoms Alkyl groups (4) [2] Some of the organic groups in the formula are alkyl groups having 1 to 25 carbon atoms, and the rest are alkenyl groups having 2 to 25 carbon atoms, (5) [ (Formula 2) Among the organic groups (please read the precautions on the back before filling out this page) The paper size applies to the Chinese National Standard (CNS) Λ4 specification (210, < 2 [; 7 mm) 10 559633 A7 B7 5. The invention is sharp. Part of (8) is an alkyl group having 1 to 25 carbon atoms, and the rest is 1 to 2 carbon atoms (please read the precautions on the back before filling this page) 6 hydroxyalkyl group, (6) A part of the organic group in [Formula 2] is an alkenyl group having 2 to 25 carbon atoms, and a hydroxyalkyl group having 1 to 6 carbon atoms is below, (7) The organic group in [Formula 2] One part of the group is an alkyl group having 1 to 25 carbon atoms, the other part is an alkenyl group having 2 to 25 carbon atoms, and the one below is a hydroxyalkyl group having 1 to 6 carbon atoms. Examples of related fourth-order ammonium cations include (1) tetramethylamine, triethylmethylamine, tripropylethylamine, tributylmethylamine, tetrabutylamine, and the Intellectual Property Office of the Ministry of Economic Affairs. Employee Consumer Cooperative Yinxian triisooctylethylamine, trimethyloctylamine, 2dodecyl2methylamine, 3methyloctadecylamine, etc. The organic groups in [Formula 2] are In the case of an alkyl group having 1 to 25 carbon atoms, (2) dibutenyl diethylamine, dimethyl dioleenyl amine, trimethyl oleenyl amine, and triethyl eicosenyl For amines, etc., in the case where a part of the organic group in [Formula 2] is an alkyl group having 1 to 25 carbon atoms, and the part underneath is an alkenyl group having 2 to 25 carbon atoms, (3) Butylhydroxyethylamine, bis (hydroxyethyl) dipropylamine, tris (hydroxyethyl) octylamine, tris (hydroxypropyl) methylamine, etc., one of the organic groups in [Formula 2] It is preferable that the part is an alkyl group having 1 to 25 carbon atoms, and the lower part is a hydroxyalkyl group having 1 to 6 carbon atoms. The organic groups in M [Formula 2] are all carbon atoms. For alkyl groups of 1 to 12, organic in [Formula 2] In the case of a part of the alkenyl group having 16 to 22 carbon atoms, and the remaining part is an alkyl group having 1 to 12 carbon atoms, and a part of carbon number in [Formula 2] It is particularly preferable when the hydroxyalkyl group is 2 to 4 and the remainder is an alkyl group having 1 to 12 carbon atoms. Examples include tributylmethylamine, tetrabutylamine, trimethylolenylamine, bis (hydroxyethyl) methyloctylamine, and the like. The size of this paper applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm)-11-559633 A7 B7 V. Invented sharp Ming K 9) Anion group constituting 4th level ammonium salt. The compound partially or completely removes the anion group of the hydrogen ion. Examples of related 1 to 3 valence compounds include (1) methyl phosphate, diethyl phosphate, dioctyl phosphate, methyl oleyl phosphate, nonylphenylhydroxyethoxyethane, etc. Phosphates having 1 to 30 carbon atoms such as methyl phosphate, (2) methyl sulfate, ethyl sulfate, dodecyl sulfate, octylphenylhydroxy sulfate (repeated number of ethoxy units) Is 3, hereinafter referred to as η = 3), sulfuric acid esters having 1 to 30 carbon atoms such as ethyl sulfate, (3) butyl sulfonate, dodecyl sulfonate, octadecyl sulfonate Number of carbon atoms, oleyl sulfonate, p-toluene sulfonate, dodecyl phenyl sulfonate, oleyl phenyl sulfonate, naphthyl sulfonate, diisopropyl naphthyl sulfonate, etc. 1 to 30 sulfonic acid esters, (4) acetic acid, hexanoic acid, lauric acid, 2-ethylhexanoic acid, isoctadecanoic acid, oleic acid, erucic acid and other aliphatic monocarboxylic acids having 1 to 30 carbon atoms, Aliphatic dicarboxylic acids having 1 to 30 carbon atoms such as malonic acid, adipic acid, sebacic acid, and pentaenyl succinic acid, benzoic acid, phthalic acid, trimellitic acid, and other carbon atoms 1 to 30 30 aromatic carboxylic acids, lactic acid, castor Fatty hydroxycarboxylic acids having 1 to 30 carbon atoms, such as lysin, 12-hydroxyoctadecanoic acid, and sulfur containing aliphatic carboxylic acids having 1 to 30 carbon atoms, such as thiodipropionic acid, etc., having 1 carbon atom ~ 30 carboxylic acids and so on. Among them, M is an aliphatic phosphoric acid having 1 to 26 carbon atoms, an aliphatic sulfonic acid ester having 1 to 26 carbon atoms, an aliphatic carboxylic acid having 1 to 26 carbon atoms, and the like, and those having 8 to 24 carbon atoms are preferred. Aliphatic sulfonates and aliphatic carboxylic acids having 8 to 24 carbon atoms are particularly preferred. Preferred examples include: dodecyl sulfonate, oleyl sulfonic acid, isoctadecanoic acid, oleic acid, pentaenyl succinic acid, and the like. The present invention does not specifically limit the synthesis of a grade 4 ammonium salt for use in the present invention. The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210, < 297 mm)-12-(Please read the precautions on the back before filling this page) Order the Intellectual Property Bureau of the Ministry of Economy S (Industrial and Consumer Cooperatives Indu 559633 A7 __B7____ V. Description of the invention (10) method, here Examples of K include: (1) a method of reacting a corresponding tertiary amine with a trialkylphosphoric acid ester, (2) a method of reacting a corresponding tertiary amine with a dialkyl sulfuric acid, and (3) the presence of water A method of reacting a corresponding tertiary amine with ethylene oxide to form a tertiary ammonium hydroxide and then reacting a sulfonate '(4) A corresponding tertiary amine and an alkyl halide are reacted to form a tertiary ammonium halide Next, a method for reacting a metal carboxylic acid salt, etc. Next, the fourth-order phosphonium root salt is added with K. The fourth-order phosphonium cation group constituting the fourth-order phosphonium root salt is the same as the case of the fourth-order ammonium cation group. Including: (1) When the organic groups in [Formula 2] are all alkyl groups having 1 to 25 carbon atoms, (2) The organic groups in [Formula 2] are all 2-carbon atoms Intellectual Property Bureau of the Intellectual Property Bureau, M Industrial Consumer Cooperative (please read the precautions on the back before filling out this page) 25 Alkenyl Couplers' (3) When the organic groups in [Formula 2] are all hydroxyalkyl groups having 1 to 6 carbon atoms, (4) Part of the organic groups in [Formula 2] are alkane groups having 1 to 25 carbon atoms When the remainder is a dilute radical having 2 to 25 carbon atoms, the organic radical in (5) [Formula 2] is a sintered radical having 1 to 25 carbon atoms, and the remainder is a carbon atom. In the case of a radical group having a number of 1 to 6, a part of the organic group in (6) [Formula 2] is a benzyl group having 2 to 25 carbon atoms, and the rest is a hydroxyl group having 1 to 6 carbon atoms. In the case of an alkyl group, part of the organic group in (7) [Formula 2] is an alkyl group having 1 to 25 carbon atoms, part is an alkenyl group having 2 to 25 carbon atoms, and the remainder is carbon. Couplers of hydroxyalkyl groups with 1 to 6. As related quaternary phosphonium cations, M (l) tetramethylphosphonium, tributylmethylfluorene, tetrabutylfluorene, methyltrioctyloxyfluorene And dodecyltrimethylsulfonium, etc. [Formula 2] Where the organic groups are all 1 to 25 carbon atoms, (2) trimethyloletenyl, oleylpropenyl, etc. The paper size in [Formula 2] is applicable to Chinese national standards CNS) A4 specification (210X 297 mm) ~ ^ 〇 一 559633 A7 B7 5. Invention Ming 411) Part of the base is an alkyl group with 1 to 25 carbon atoms, and the rest is carbon In the case of an alkenyl group having 2 to 25 atoms, among the organic groups in [Formula 2], such as (3) tributyl (2-hydroxyethyl) fluorene, trioctyl (4-hydroxybutenyl) fluorene, and the like One part is an alkyl group having 1 to 25 carbon atoms, and the other part is a hydroxyalkyl group having 1 to 6 carbon atoms, where the organic groups in M [Formula 2] are all carbon atoms 1 In the case of a ~ 4 alkyl group, it is particularly preferable. Examples include tributylmethylphosphonium, tetrabutylphosphonium, and the like. The anion constituting the fourth-order phosphonium salt is the same as the anion group in the case of the aforementioned ammonium salt. The present invention does not specifically limit the method for synthesizing the fourth-order phosphonium salt for use in the present invention, and examples thereof include: mixing a corresponding organic acid metal salt or ammonium salt with the fourth-order phosphonium salt in a solvent, and washing with water. The derivatized inorganic salt is isolated, or a method such as extraction with an organic solvent such as methanol, isopropanol, or acetone is used. As the polyether compound used in the present invention, for example, a conventional polyether compound can be applied to those disclosed in Japanese Patent Application Laid-Open No. 56-31077 or USP4561987. Similar polyether compounds include polyether monools, polyether glycols, and polyether triols, which are mainly composed of hydroxyethylene units and hydroxypropylene units. Polyether (poly) alcohols such as polyether triols are particularly preferred. The average molecular weight is 700. ~ 20,000 is especially good. The polyether compound includes a mixture of polyether compounds having different molecular weights. However, when a related mixture is used, a mixture of a polyether compound having an average molecular weight of 100 to 3000 and a polyether compound having an average molecular weight of 5000 to 15,000 is used. good. The treatment agent of the present invention, as explained above, is made of polyether compound and straight paper. The Chinese National Standard (CNS) A4 specification (210 × 297 mm) is applied (please read the precautions on the back before filling this page), 1T Φ Intellectual Property Cooperative Cooperative of the Ministry of Economic Affairs, Ministry of Economic Affairs, Industrial Cooperative, Indus 559633 A7 B7 V. Invention Weiming 12) (Please read the precautions on the back before filling this page) Chain polyether denatured polyorganosiloxane and ionic interface activity It is composed of an agent, and each contains the linear polyether denatured polyorganosiloxane in a proportion of 0.1 to 12% by weight, and further contains the ionic surfactant in an amount of 0.1 to 12% by weight, but M each contains the The linear polyether denatured polyorganosiloxane has a proportion of 0.3 to 5 weight percent, and the ionic surfactant contains a former quaternary 4th grade_salt 0, 3 to 5 weight percent, and is preferably constituted. Printed as a processing agent by the Intellectual Property Bureau of the Ministry of Economic Affairs and the Industrial Cooperative Cooperative, in addition to the polyether compounds, linear polyether denatured polyorganosiloxanes, and ionic surfactants as described above, and designated by M It is preferable to mix | blend a specific ester compound and / or ether ester compound in proportion. The relevant ester compound is not particularly limited as long as it has a total carbon number of 10 to 50. Examples include (1) ethyl laurate, octyl laurate, and isoundecane. Aliphatic monoesters of aliphatic alcohols such as methyl stearate, oleyl erucate, and aliphatic carboxylic acids, (2) 1,4-butyl glycol dicaprylate, dioleyl adipate, Aliphatic alcohols such as methylolethanediisostearate, glycerol laurate, and aliphatic polyvalent esters of aliphatic carboxylic acids, etc., but are aliphatic monovalents having a total carbon number of 15 to 30 Esters are preferred. In addition, as the related ether ester compound, there is no particular limitation as long as the total number of carbon atoms is 10 to 50. Examples include the reaction of the above-mentioned ester compound with an epoxide having 2 to 4 carbon atoms. Among various products, M is preferably an ether ester compound having a total carbon number of 20 to 40 which reacts ethylene oxide with 1 to 10 moles in a monoester of an aliphatic alcohol and an aliphatic carboxylic acid. In the present invention, when an ester compound and / or an ether ester compound of the former compound is used, in the compounding ratio, K becomes 1 to 30 percent of the weight of the child in the treatment agent. This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) — 1 5-559633 A7 B7 V. Description of the invention f 13) (Please read the precautions on the back before filling out this page), preferably the linear polyether denatured poly Organosiloxanes 0.3 to 5 weight percent. In addition, as an ionic surfactant, it contains a grade 4 phosphonium salt of 0.3 to 5 weight percent. It contains ester compounds and / or ether ester compounds 3 to 25 weight percent. The rest It is a polyether compound. In the treatment method of the present invention, it is preferable that the synthetic fiber supplied with the treatment agent of the present invention described in M to 0.1 to 3 weight percent to the heat treatment process be adhered to 0.2 to 1 weight percent. Generally, a treatment agent is attached to a sliver of a synthetic fiber yarn after spinning, and the sliver of the synthetic fiber yarn is supplied to a heat treatment process. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the treatment method of the present invention. As described in Ki :, the treatment agent of the present invention is attached thereto at a fixed ratio to the synthetic fiber, so that the synthetic fiber used in the heat treatment process has Good lubricity, thereby preventing heater contamination of the heat treatment process. Related heat treatment projects include elongation process, yarn twisting process, crimping process, false twisting process, etc. Among them, the treatment agent K and the processing method of the present invention, K will supply the synthetic fiber applicable to the present invention to the false twisting process. The effect is the highest. The false twisting machine used in the false twisting process includes, for example: (1) a heater with a heater temperature of 150 to 2301C and a heater length of 150 to 2 50 cm so that the sliver of synthetic fiber wire contacts the heater board; The contact heater-type false twister that walks upwards. (2) A synthetic weaving yarn sliver M with a heater temperature of 300 to 600 ° C and a heater temperature of 20 to 150 cm is not in contact with Heater-type short-warmer type false twisting machine, etc., especially the treatment agent and treatment method of the present invention are for use with a heater installed at a temperature of 3 50 to 5 50 t: and a heater length of 20 Paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm) -16-559633 A7 B7 V. Description of invention f 14) (Please read the precautions on the back before filling this page) ~ 140 cm short heater, The effect is best when the sliver of synthetic fiber yarn is brought into contact with a false twisting machine which is provided with a yarn path restriction device provided in the heater. The treatment method of the present invention is not particularly limited to a method of attaching the treatment agent of the present invention to synthetic fibers, and related treatment methods include, for example, a roller oil method, a guided oil method using a metering pump, an immersion oil method, and a spray oil method. Conventional methods, such as the oil method, are preferably the roller oil method or the guided oil method using a metering pump. When the treatment agent of the present invention is attached to synthetic fibers, the treatment agent may be used in the form of an aqueous emulsion, an organic solvent solution thereof, or a direct use method, and the use method of the M aqueous emulsion is preferred. In this case, an emulsifier may be appropriately used as required, and it is preferable to prepare a water-based emulsion in a treatment-remembering manner at a ratio of 5 to 30% by weight. When the treatment agent is attached to the synthetic fibers, any other components such as antioxidants, preservatives, and rust inhibitors may be used in combination as long as they are suitable, but the use amount M is preferably as small as possible. The synthesis of the treatment agent M and the treatment method applicable to the invention by the Industrial and Commercial Kettle Co., Ltd. of the Intellectual Property Bureau of the Ministry of Economic Affairs is as follows: (1) polyester whose main constituent is vinyl terephthalate, (2) Polyamides such as nylon 6, nylon 66, (3) Polyacrylics, such as polyacrylonitrile, and (4) Polyolefins, such as polyethylene and polypropylene, of which K is suitable for polyester and polyamide. The effect is higher in the occasion, and the K is particularly suitable for the occasion where the polyester partially stretched yarn, the polyamide partially stretched yarn, or the polyester direct spinning stretch yarn is used. Embodiments of the Invention The embodiments of the treating agent and the treating method of the present invention include the following paper standards that are applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm)-17-559633 Intellectual Property Bureau of the Ministry of Economic Affairs a: Printed by Consumer Cooperatives Α7 Β7 V. Invention Tax < 15) U) to (52) examples. In addition, the contents of the polyether compound, linear polyether denatured polyorganosiloxane, ionic surfactant, ester compound, and ether ester compound used in each embodiment under M are described in detail in the examples described later. . (1) Consists of a polyether compound (P-1), a linear poly-denatured polyorganosiloxane (MS-1), and an ionic surfactant (QS-1), and each contains a polyether compound ( Pl) 96 weight percent, linear polyether denatured polyorganosiloxane (MS-1) 2 weight percent, and ionic surfactant (QS-1) 2 weight percent. The treatment agent is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in such a way that the treatment agent becomes 0.4% by weight with respect to the polyester partly drawn yarn, and this is supplied to a contact heating using a heater temperature of 210 ° (: (2) The treatment agent of (1) above is an aqueous emulsion, and the aqueous emulsion is adhered in such a way that the treatment agent is 0.4% by weight for the polyester partially stretched yarn, And this method is supplied to a false twisting process of a short heater false twister using a heater temperature of 51 OC. (3) Polyether compound (P-1), linear polyether modified polyorganosiloxane (MS-1) and ionic surfactant (QS-1), and each contains 94% by weight of polyether compound (Pl), 2% by weight of linear polyether modified polyorganosiloxane (MS-1) It is composed of the percentage and the weight percentage of the child-like surfactant (QS-1) 4. The treatment agent is made into an aqueous emulsion so that the extension of the treatment agent to the polyester part becomes 0.4% by weight. The aqueous emulsion is adhered and this is supplied to Heater temperature 210 ° (: Method of false twisting process of contact heater type false twister. (4) Make the treatment agent of (3) above into an aqueous emulsion, so as to apply the Chinese national standard for the treatment agent to this paper size ( CNS) Α4 specification (210X297 mm)-18---- ^ ------ ^ equipment ------ order ----- i (Please read the precautions on the back before filling this page) 559633 The employee of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the A7 B7 on the polyester part to extend the yarn to 0.4% by weight to attach the aqueous emulsion, and this was supplied to a short heater using a heater temperature of 510 ° C (5) The method of false twisting of the false twister. (5) Polyether compound (P-1), linear poly-denatured polyorganosiloxane (MS-2), ionic surfactant (QS-2 ), An ester compound (ES-1) M and an ester compound (EE-1), and each contains 82% by weight of a polyether compound (P-1), a linear polyether denatured polyorganosiloxane (MS -2) 3% by weight, 1% by weight of ionic surfactant (QS-2), 4% by weight of ester compound (ES-1), 10% by weight of ether ester compound (EE-1) The treatment agent is an aqueous emulsion, and the aqueous emulsion is adhered in such a manner that the treatment agent is 0.4% by weight with respect to the polyester partly stretched yarn, and this is supplied to the heater temperature. A method of false twisting process of a 210ti contact heater type false twister. (6) The treatment agent of (5) is made into an aqueous emulsion, and the treatment agent is made so that the polyester part stretch yarn is 0.4% by weight. Aqueous emulsion is adhered, and this method is applied to a false twisting process of a short heater false twister using a heater temperature of 510 °. (7) Consists of a polyether compound (P-1), a linear polyether-denatured polyorganosiloxane (PS-1), and a naive surfactant (QS-3), and each contains a polyether compound ( Pl) 95 weight percent, linear polyether denatured polyorganosiloxane (PS-1) 3 weight percent, and ionic surfactant (QS-3) 2 weight percent. The treatment agent is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in a way that the weight of the treatment agent is 0.4% by weight for the polyester partly stretched yarn, and this is supplied to a heater temperature of 210. This paper size applies Chinese national standards ( CNS) Λ4 specification (210 X 297 mm) -1 9-I ^ ^^ Binding L (Please read the notes on the back before filling out this page) 559633 Intellectual Property Bureau of the Ministry of Economic Affairs g (printed by the Industrial and Consumer Cooperatives A7 B7 5 2. Description of the invention The method of false twisting process of a contact heater type false twister in ° C. (8) The treatment agent of the above (7) becomes an aqueous emulsion, and the treatment agent is 0.4% by weight for the polyester partly stretched yarn. This method allows the aqueous emulsion to adhere, and supplies this to a false twist process using a short heater false twister with a heater temperature of 5.1 01C. (9) Polyether compound (P-1), linear type Consisting of polyether modified polyorganosiloxane (PS-2), chickling surfactant (QS-4) M and ether ester compound (ΕΕ-2), and each containing 90 weight of polyether compound (卩 -1) Percent, linear polyether denatured polyorganosiloxane (PS -2) 4% by weight, 1% by weight of ionic surfactant (QS-4), and 5% by weight of ether ester compound (EE-2). The treatment agent is an aqueous emulsion, and The method for making the polyester partly stretched yarn to 0.4% by weight makes the aqueous emulsion adhere, and this is supplied to a false twisting process of a contact heater type false twister using a heater temperature of 2101C. (10) Making the front 逑The treating agent of (9) becomes an aqueous emulsion, and the aqueous emulsion is adhered in such a way that the treating agent is 0.4% by weight with respect to the polyester partly drawn yarn, and this is supplied to a short heating using a heater temperature of 510 ° C U1) Twisting Engineering Method of a False Twisting Machine. U1) Polyether compound (P-1), linear polyether denatured polyorganosiloxane (PS-2) and ionic surfactant (QS-4 ), And each contains 93% by weight of polyether compound (Pl), 4% by weight of linear polyether modified polyorganosiloxane (PS-2), and 3% by weight of ionic surfactant (QS-4) Percentage. The treatment agent is made into an aqueous emulsion, so that the treatment agent is 0.4% by weight for polyester stretch yarn. The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm). 20-(Please read the back first Please pay attention to this page and fill in this page again.) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, M & D, 559633 A7 B7 < 18) The method of making the aqueous emulsion adhere, and supplying this to a false twisting process of a contact heater type false twister using a heater temperature of> 210 °. " (12) The treatment agent of the former (Π) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in a manner of 0.4% by weight to the polyester partly stretched yarn, and this is used for heating The method of fake grabbing of the short heater false twister with a temperature of 5101C. (13) Consists of a polyether compound (P-1), a linear polyether-denatured polyorganosiloxane (PS-3), and an ionic surfactant (QS-5), and each contains a polyether compound ( P_1) 96 weight percent, 2 weight percent of straight polyether modified polyorganosiloxane (PS-3), and 2 weight percent of ionic surfactant (QS-5). The treatment agent was made into an aqueous emulsion, and the treatment agent was attached to the polyester partly stretched yarn so that the weight of the treatment agent was 0.4% by weight, and this was supplied to a contact heater type dummy with a heater temperature of 210 ° C. Twisting machine false twist method. (14) The treatment agent of the above (13) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion with a weight percentage of 0, 4 for the polyester part of the drawn yarn, and this is supplied to a heater temperature of 510. False twisting method of short heater false twister at ° C. (15) Consists of a polyether compound (P-1), a linear polyether denatured polyorganosiloxane (PS-4), and an ionic surfactant (FN-1), and each contains a polyether compound ( Pl) 93 weight percent, 5 weight percent of linear polyether denatured polyorganosiloxane (PS-4), and 2 weight percent of ionic surfactant (P N-1). The treatment agent is made into an aqueous emulsion, so that the treatment agent for the polyester part is extended to 0.4% by weight. This paper applies the Chinese National Standard (CNS) A4 specification (210 乂 297 mm)-21-1IL- -^ --------- IT ----- J (please first read the notes on the back before filling out this page) 559633 A7 ____B7 V. Description of the invention f 19) The proportion of the water makes the water The emulsion is adhered, and this is supplied to a false twisting process of a contact heater false twister using a heater temperature of 21 ο υ. U6) The treatment agent of the above (15) is made into an aqueous emulsion, and the aqueous emulsion is adhered so that the treatment agent is 0.4% by weight of the polyester partly drawn yarn, and this is supplied to a heater with a temperature of 510 ° C. Method for false twisting process of short heater type false twister. (17) Consists of a polyether compound (P-1), a linear polyether-denatured polyorganosiloxane (PS-5), and an ionic surfactant (PA-1), and each contains a polyether compound ( P_1) 93 weight percent, 5 weight percent of straight polyether modified polyorganosiloxane (PS-5), and 2 weight percent of heterogeneous surfactant (PA-1). The treatment agent was made into an aqueous emulsion, and the treatment agent was attached to the polyester partly stretched yarn so as to be 0.4% by weight, and this was supplied to a contact heater with a heater temperature of 210 ° C. The method of false twisting process of the false false twisting machine. (18) The treatment agent of the above (17) is made into an aqueous emulsion, and the water-based emulsion is adhered so that the treatment agent is 0.4% by weight of the polyester partly drawn yarn, and this is supplied to a heater temperature of 510 ° C. The method of false twisting of the short heater type false twister. (19) Consists of a polyether compound (P-2), a linear polyether-denatured polyorganosiloxane (PS-4), and an ionic surfactant (QS-4), and each contains a polyether compound ( P-2) 98.5 weight percent, 0.5 weight percent of linear polyether denatured polyorganosiloxane (PS-4), and 1 weight percent of ionic surfactant (QS-4). The treatment agent is made into an aqueous emulsion, so that the treatment agent is 0.8 weight for the polyester part stretch yarn. The paper size applies the Chinese National Standard (CNS) Λ4 specification (210, < 297 mm) Please read and read the notes on the back before you read J% \ Ma. This page y orders the printed goods of the 8th Intellectual Property Cooperative Cooperative of the Ministry of Economic Affairs 22 printed goods of the 16th Intellectual Property Cooperative Cooperative of the Ministry of Economic Affairs 559633 A7 B7 V. Invention 20) The method of attaching the aqueous emulsion as a percentage, and supplying this to the false twisting process of a contact heater false twister using a heater temperature of 210 ° C. (20) The treatment agent of the above (19) is made into an aqueous emulsion, and K makes the aqueous emulsion adhere to the treatment agent to 0.8% by weight for the polyester partly stretched yarn, and supplies this to a heater temperature of 510. False twisting method of short heater false twister at ° C. (21) Consists of a polyether compound (P-1), a linear polyether-denatured polyorganosiloxane (TS-1), and an ionic surfactant (QS-1), and each contains a polyether compound ( P-1) 93 weight percent, 5 weight percent of linear polyether denatured polyorganosiloxane (TS-1), and 2 weight percent of ionic surfactant (QS-1). The treatment agent was made into an aqueous emulsion, and the treatment agent was made to adhere to the aqueous emulsion in such a way that the weight of the treatment agent was 0.4% by weight for the polyester partly drawn yarn, and this was supplied to a contact heater type false twister using a heater temperature of 2101C The method of false twist works. (2 2) The treatment agent of the above (2 1) is made into an aqueous emulsion, and the treatment agent is attached to the aqueous emulsion in a manner of 0.4% by weight with respect to the polyester partly stretched yarn, and this is supplied to a heater. Method for false twisting process of short heater false twister with temperature of 510 ° C. (23) Consists of a polyether compound (P-2), a linear polyether denatured polyorganosiloxane (TS-2), and an ionic surfactant (QS-2), and each contains a polyether compound ( P-2) 93 weight percent, linear polyether modified polyorganosiloxane (1 $ -2) 2 weight percent, and ionic surfactant (QS-2) 5 weight percent. The treatment agent is made into an aqueous emulsion to make the treatment agent extend to the polyester part to a weight of 0.4. The paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm)-23-I --- 1- ---- • Equipment ------ Order ------ i (Please read the precautions on the back before filling in this page) 559633 Α7 Β7 Intellectual Property Co., Ltd. S Industrial Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Rui Ming f 21) The method of making the aqueous emulsion adhere as a percentage, and supplying this to a false twist process of a contact heater false twister using a heater temperature of 210 t :. (24) The treatment agent of the above (23) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in a manner of 0.4% by weight with respect to the polyester partly stretched yarn, and this is supplied to a heater temperature of 510. False twisting method of short heater false twister at ° C. (25) Consists of a polyether compound (P-2), a linear polyether denatured polyorganosiloxane (TS-3), and an ionic surfactant (QS-3), and each contains a polyether compound ( P-2) 96 weight percent, linear polyether denatured polyorganosiloxane (TS-3) 2 weight percent, and ionic surfactant (QS-3) 2 weight percent. The treatment agent was made into an aqueous emulsion, and the treatment agent was allowed to adhere to the polyester partly stretched yarn to 0.4% by weight, and this was supplied to a contact heater type false twister using a heater temperature of 2101C. The method of false twist works. (26) The treatment agent of the above (25) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion so that the polyester part stretch yarn becomes 0.4% by weight, and this is supplied to a heater temperature of 510. False twisting method of short heater false twister at ° C. (27) Consists of polyether compound (P-1), linear polyether denatured polyorganosiloxane (MS-3), ionic surfactant (QS-4), and ester compound (ES-1) It also contains 90% by weight of polyether compound (Pl), 1% by weight of linear polyether modified polyorganosiloxane (MS-3), 7% by weight of ionic surfactant (QS-4), and ester compound. (ES-1) Consists of 2 weight percent. To make this treatment agent an aqueous emulsion, make M apply the Chinese National Standard (CNS) Λ4 · Specifications (210X 297 mm) to this paper size — ~ 2 4-(Please read the precautions on the back before filling this page) Ϊ · 、 1Τ Φ 559633 A7 B7 __ V. Invention A Ming (° 22) Formula for polyester partially stretched yarn '%% ^^ This aqueous emulsion is attached, and this is supplied to the heater using 21010 Method for false twisting process of contact heater type false twister. (28) The treatment of the aforementioned U7) _ becomes an aqueous emulsion, and the aqueous emulsion is adhered in such a manner that the treatment agent is 0.3% by weight for the polyester partly stretched yarn, and this is supplied to Method for false twisting process of short heater type false twister. (29) Consists of polyether compound (P-1), linear polyether denatured polyorganosiloxane (MS-4), heterogeneous surfactant (QS-5), and each contains a polyether compound (Pl) 89% by weight, 1% by weight of linear polyether denatured polyorganosiloxane (MS-4), and 10% by weight of ionic surfactant (QS-5). The treatment agent was made into an aqueous emulsion, and the treatment agent was attached to the polyester partly stretched yarn so that the weight of the treatment agent was 0.3% by weight, and this was supplied to a contact heater type dummy using a heater temperature of 210 ° C. Twisting machine false twist method. (30) The treatment agent of the former (29) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in a manner of 0.3% by weight with respect to the polyester partly stretched yarn, and this is supplied to the heater temperature. 510t: The method of false twisting of the short heater false twister. (31) Consists of a polyether compound (P-1), a linear polyether-denatured polyorganosiloxane (PS-6), and an ionic surfactant (qs-1), and each contains a polyether compound ( P-1) 91 weight percent, linear polyether denatured polyorganosiloxane (PS-6) 6 weight percent, and ionic surfactant (QS-1) 3 weight percent. To make this treatment agent an aqueous emulsion, the paper size applies the Chinese national standard (〇 乂 5) / \ 4 size (2 丨 0 / ^ 7mm) -25-(Please read the precautions on the back before filling this page ) | ------ Order ------ Printed by S Industry Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ Printed by the Consumer Cooperative Society of the Intellectual Property Bureau of the Ministry of Economic Affairs 559633 A7 B7 V. Description of Invention f 23) The processing agent is a polyester partly drawn yarn of 0.3% by weight so that the aqueous emulsion is adhered, and this is supplied to a false twisting process of a contact heater type false twister using a heater temperature of 210 ° C. (32) The treatment agent of the former (31) was made into an aqueous emulsion, and the aqueous emulsion was adhered in such a manner that the polyester part stretch yarn was 0.3% by weight for the treatment, and this was supplied to a heater with a temperature of 5101C. Method for false twisting process of short heater type false twister. (33) Consists of polyether compound (P-1), linear polyether denatured polyorganosiloxane (PS-7), and ionic surfactant (FN-1), and each contains a polyether compound ( Pl) 88% by weight, 9% by weight of linear polyether denatured polyorganosiloxane (PS-7), and 3% by weight of ionic surfactant (PN-1). The treatment agent was made into an aqueous emulsion, and the treatment agent was made to adhere to the aqueous emulsion in such a way that the weight of the treatment agent and the polyester partly drawn yarn was 0.3% by weight, and this was supplied to a contact heater type using a heater temperature of 2 1 (TC Method of false twisting process of false twisting machine. (34) The treatment agent of (33) is an aqueous emulsion, and the aqueous emulsion is adhered in such a manner that the treatment agent is 0.3% by weight for the polyester partly stretched yarn. This method is applied to a false twist process of a short heater false twister using a heater temperature of 510C. (35) The treatment agent of (5) is made into an aqueous emulsion, and the treatment agent is extended to the nylon yarn portion. The method of making the aqueous emulsion adhere to the yarn in a weight percentage of 0.50, and supplying this to a false twisting process of a contact heater false twister using a heater temperature of 2101C. (36) Making the above (5) The treatment agent becomes an aqueous emulsion, and K makes the paper size of the treatment agent applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm)-26-I 丨 ^ ------ ^ 装 ------ Order ------ ί (Please read the notes on the back before filling Page) Cooperate with employees of the Intellectual Property Bureau of the Ministry of Economic Affairs to print 559633 A7 B7 V. Invent sharp sharp f 24) Make the water-based emulsion adhere to the nylon yarn part extension yarn to 0.50% by weight, and supply this for heating The method of false twisting of a short heater false twister with a temperature of 460 C. (37) The treatment agent of the above (7) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion so that the treatment agent is 0.55 weight percent of the nylon yarn partially drawn yarn, and this is supplied to a contact using a heater temperature of 2101C. Method of false twist process of heater type false twister. (38) The treatment agent of the above (7) is made into an aqueous emulsion, and the aqueous emulsion is adhered so that the treatment agent is 0.55 weight percent with respect to the nylon yarn partially stretched yarn, and this is supplied to a heater temperature of 460 or other Method for false twisting process of short heater type false twister. (39) The treatment agent of the above (9) is made into an aqueous emulsion, and the treatment agent is attached to the nylon yarn partly stretched yarn at a weight percentage of 0.45%, and this is supplied to a heater temperature of 210TC Method of false twisting process of contact heater type false twister. (40) The treatment agent of the above (9) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in such a way that the treatment agent is 0.45 weight percent of the nylon yarn partially drawn yarn, and this is supplied to a heater temperature of 46 0 10 The method of false twisting of the short heater type false twister. (41) The treatment agent of (19) is made into an aqueous emulsion, and the aqueous emulsion is adhered in such a way that the extension of the treatment agent to the nylon yarn portion is 0.65 weight percent, and this is supplied to the use heater temperature 2]. υ The method of false twisting of a heater-type false twister. (42) The treatment agent of the aforementioned (19) is made into an aqueous emulsion so that the paper size of the treatment agent applies the Chinese National Standard (CNS) A4 specification (210; < 297 mm) 1 2Ί-——L --- r --------- IT ----- (Please read the notes on the back before filling this page) 559633 Intellectual Property Bureau, Ministry of Economic Affairs S. Consumer Cooperatives Co., Ltd. Printing Fan A7 B7 V. Description of the Invention The water-based emulsion was attached in such a way that the nylon yarn partially stretched yarn became 0.65 weight percent, and this was supplied to a short heater false twister using a heater temperature of 46 Ot False twist engineering method. (43) The treatment agent of the above (21) is made into an aqueous emulsion, and the treatment agent is made to adhere to the aqueous emulsion in such a manner that the treatment agent is 0.55 weight percent of the nylon yarn partially drawn yarn, and this is supplied to a heater temperature of 21 ° Method of false twisting process of contact heater type abdominal twister. (44) The treatment agent of the aforementioned (21) is made into an aqueous emulsion, and the treatment agent is made to attach to the aqueous emulsion in a manner of 0.55% by weight with respect to the nylon yarn partially drawn yarn, and this is supplied to a heater temperature of 460. 1C method of false twisting of short heater false twister. (45) The treatment agent of the former (5) is made into an aqueous emulsion, and the treatment agent is made to attach to the aqueous emulsion in a manner of 0.35% by weight to the polyester direct spinning extension yarn, and this is used for heating. The method of false twisting process of a contact heater false twister with a temperature of 2101C. (46) The treatment agent of the above (5) is made into an aqueous emulsion, and the aqueous emulsion is adhered in such a way that the treatment agent is 0.35 weight percent of the polyester direct-spun stretch yarn, and this is supplied to a heater temperature of 51010. The method of false twisting of the short heater type false twister. (47) The treatment agent of the above (9) is made into an aqueous emulsion, and the water-based emulsion is adhered so that the treatment agent is 0.35% by weight with respect to the polyester direct-spun stretch yarn, and this is supplied to a heater for use. Method for false twisting process of a contact heater false twister at a temperature of 21 °. (48) Make the treatment agent of (9) above into an aqueous emulsion, so as to make the treatment agent-2 8-(Please read the precautions on the back before filling this page). ) A4 size (210X 297 mm) 559633 Α7 Β7 V. Description of the invention (please read the precautions on the back before filling this page) For the direct spinning polyester extension yarn to be 0.35 weight percent to make the aqueous emulsion adhere This method is used for the false twist process of a short heater false twister using a heater temperature of 510 t :. (49) The treatment agent of the former () 5) is an aqueous emulsion, and the aqueous emulsion is adhered so that the treatment agent is 0.35 weight percent of the polyester direct-spun stretch yarn, and this is supplied to a heater. Method of false twisting process of contact heater false twister with temperature of 2101C. (50) The treatment agent of the above (15) is made into an aqueous emulsion, and K is made to attach the aqueous emulsion so that the treatment agent is 0.35 weight percent of the polyester direct-spun stretch yarn, and this is supplied to a heater temperature of 5101C. The method of false twisting of the short heater type false twister. (51) The treatment agent of the above (23) is made into an aqueous emulsion, and the treatment agent is attached to the polyester direct-spun stretch yarn to 0.35 weight percent, and this is supplied to Method for false twisting process of contact heater type false twister. Yinxian (52), Consumer Cooperative of Employees and Intellectual Property Bureau of the Ministry of Economic Affairs, made the treatment agent of (23) above into an aqueous emulsion, so that the treatment agent and the polyester direct-spun stretch yarn became 0.35 weight percent. This method was applied to a false twist process of a short heater false twister using a heater temperature of 51 ° C. In M, the structure and effect of the present invention will be described more specifically by giving examples and comparative examples, but the present invention is not limited thereto. In the following examples and comparative examples, "part" refers to the heavy child part, and "" "refers to the weight percentage. Examples The paper size applies the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) -29- 559633 A7 B7 V. Description of the invention Test classification (treatment agent preparation) • Preparation of treatment agent mixed polyether compound ( Pl) 96 parts, 2 linear polyether denatured polyorganosiloxanes (MS-1) and 2 ionic surfactants (QS-1) to prepare a treatment agent (Example 1). Other processing agents were prepared in the same manner as this processing agent (Example 1), and these processing agents are arranged in Tables 1 and 2. -^ ------ ^^ Installation ------ Order ----- (Please read the notes on the back before filling out this page) Intellectual Property Bureau of the Ministry of Economy S (Printed by Industrial and Consumer Cooperatives) Paper size applies Chinese National Standard (CNS) Α4 size (210X 297 mm) — 3001559633 A7 B7 V. Description of the invention < 2S) 袅 1 Processing agent printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs: Composition of polyether linear polyether denatured ionic interface Other compound classification compounds Polyorganosiloxane active agent type used amount used amount used Quantity Type Usage Example 1 P-1 96 MS-1 2 QS-1 2 2 P-1 94 MS-2 2 QS-1 4 3 P-1 82 MS-2 3 QS-2 1 ES -1 4 EE -1 10 4 P-1 95 PS-1 3 QS-3 2 5 P-1 90 PS-2 4 QS-4 1 EE-2 5 6 P-1 93 PS-2 4 QS-4 3 7 P-1 96 PS-3 2 QS-5 2 8 P-1 93 PS-4 5 FM-1 2 9 P-1 93 PS-5 5 PA -1 2 10 P-2 98.5 PS-2 0.5 QS-4 1 11 P -1 93 TS -1 5 QS-1 2 12 P-2 93 TS-2 2 QS-2 5 13 P-2 96 TS-3 2 QS-3 2 14 P-1 90 MS-3 1 QS-4 7 ES-1 2 15 BU 1 89 MS-4 1 QS-5 10 16 P-1 91 PS-6 6 QS -1 3 17 P-1 88 PS-7 9 FN-1 3 18 P-3 96 MS -1 3 QS-1 1 19 P-4 86 PS -1 2 QS-6 2 EE -1 10 (Please read the precautions on the back before filling out this page) Binding, binding, and thread size The paper size applies to Chinese national standards (CNS ) A4 size (2 丨 OX 297 male ) A 31- 559633 A7 B7 Ministry of Economic Affairs Intellectual Property Office g (f consumer cooperatives printed work

V. Description of the invention G2S Table 2 Composition of the treatment agent Polyether linear polyether denatured ionic interface Other compounds classification compound Polyorganosiloxane active agent type used amount used amount used amount used amount used amount Example 1 P-1 95.95 MS-2 0.05 QS -1 4 2 P-1 95,95 PS-2 4 QS -1 0.05 3 P-1 81 MS-2 15 QS -1 4 4 P-1 81 PS-2 4 QS-1 15 5 P-1 93 QS -1 2 ci " One 1 5 6 P-1 93 QS-2 2 cr_2 5 7 P-1 90 QS-3 5 cr ~ 3 5 8 P-1 95 QS-4 2 cr-3 3 9 P-1 92 QS-5 3 cr-4 5 10 P-2 98 QS-5 2 11 P-2 94 QS-1 2 cr -1 4 12 P-2 93 QS-2 3 cr-2 4 13 P-2 92 FN-1 5 cr-3 3 14 P-2 94 PA -1 2 cr ~ 4 4 15 PS-2 50 QS-4 50 16 P-3 95.95 MS-3 0.05 QS -1 4 Please first_ Read the precautions on the back before loading

The paper size of the III-line book applies to the Chinese National Standard (CNS) A4 (210X 297 mm) 32 559633 A7 B7 V. Description of the invention [30] In Tables 1 and 2, Usage: Weight percentage (please read the back Please fill in this page again.) Polyether compound (P-1): ratio of hydroxyethylene unit / hydroxypropylene unit = 80/20 (mole ratio). Block-added methoxypolyalkenyl ethylene with an average molecular weight of 2000. A mixture of 70 glycol ethers with a ratio of hydroxyethylene units / hydroxypropylene units = 20/80 (molar ratio) to a polyether compound (P- 2): The ratio of hydroxyethylene units / hydroxypropylene units = 80/20 (molar ratio), 50 pieces of dodecyloxypolyalkenyl glycol ether with an average molecular weight of 2000, and hydroxyethylene units / The ratio of hydroxypropene units = 40/60 (mole ratio) is randomly added to 40 parts of butoxy polyalkenyl glycol ether having an average molecular weight of 2 500, and hydroxyethylene units / hydroxypropylene units = 40/60 (mo Ear ratio) ratio of random added poly (ethylene) ethylene with an average molecular weight of 11,000 Polyether compound (P-3) with a mixture of 10 ethers: a ratio of hydroxyethylene units / hydroxypropylene units = 50/50 (mole ratio) randomly added octyloxypolyalkenyl glycol ether having an average molecular weight of 1,000 Polyether compound (P-4) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs: the ratio of hydroxyethylene units / hydroxypropylene units = 25/75 (mole ratio) randomly added methoxypolyene with an average molecular weight of 12,000 Glycol ether linear polyether denatured polyorganosiloxane (MS-1) ~ (MS-4), (PS-1) ~ (PS-7): Both are straight The contents of the chain-type polyether-denatured polyorganosiloxane are summarized in Table 3 below. In addition, the symbols in Table 3 are equivalent to those used in [Formula 1], B represents a block attachment, and R represents a random attached paper. The paper size is applicable to the Chinese National Standard (CNS) Λ4-specification (210X297 mm) _ 33 _ 559633 A7 B7 V. Invention Description G 31) Plus (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs This paper applies Chinese National Standard (CNS) A4 specifications (2 丨 0 : < 297 mm) 34 559633

AB V. Description of the invention (32) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Table 3 Classification of brackets R1 A1 0 P Additional R2 Siloxane unit R3 0A2 q Additional η R4 Form R5 in \ Form MS-1 Octyloxyethoxy 10 B trimethylmethyl 5 trimethyl vinyl 10 B 1 lauryl phenylene (p > cy MS-2 octyloxyethoxy / 35 B trimethylmethyl 10 trimethylhydroxy Vinyl 35 B 1 octyloxypropoxyalkylene / hydroxypropenyl = 10/10 = 10/10 MS-3 phenoxyethoxy / 20 B trimethylmethyl 17 trimethylhydroxy vinyl 20 B 1 Propylphenoxyloxy / hydroxypropenyloxy = 10/10 = 10/10 MS-4 oleylethoxy / 20 R trimethylmethyl / 25 trimethylhydroxyvinyl 20 R 1 oleyl Propoxyl r-trifluorol / hydroxypropenyl = 15/5 propyl: ¾ = 15/5 PS -1 butoxyethoxy / 60 B tetramethylmethyl 10 'tetramethylhydroxyethylene 60 B 2 butoxypropoxyl fluorenyl / hydroxypropenyl = 30/30 = 30/30 PS-2 allylethoxy / 60 R trimethylol 10 trimethylhydroxyvinyl 60 R 2 allyloxyoxypropoxyalkylene plug, / hydroxypropenyl group = 15 / 45 = 15/45 PS-3 buteneethoxy / 100 R tetramethylmethyl 10 tetramethylhydroxyvinyl 100 R 7 buteneoxyoxypropoxyalkylene / hydroxypropenyl = 80 / 20 = 80/20 PS-4 allylethoxy / 150 B trimethylol 50 trimethylhydroxyvinyl 150 B 15 allyloxyoxypropoxyalkylene / hydroxypropenyl = 125/25 = 125 / 25 PS-5 Allyl ethoxy / 180 B trimethylmethyl 180 trimethyl f-based vinyl 180 B 30 oxypropoxyalkylene / hydroxypropenyl = 80/100 = 80/100 PS-6 Dibutylethoxy / 20 B tetramethylmethyl / 15 tetramethylhydroxyvinyl 20 B 2 Dibutylaminopropoxyphenylphenylene / hydroxypropenylethanolamine = 10/10 = 10/5 = 10 / 10-based PS-7 octylfluorenylethoxy / 20 B tetramethylmethyl 30 tetramethylhydroxyethyl Alkenyl 20 B 4 octylthiopropoxyalkylene / hydroxypropenyl group = 10/10 = 10/10 (Please read the precautions on the back before filling this page) This paper size applies to China Standard (CNS) A4 specifications (210X 297 mm)-35-559633 A7 B7 V. Description of the invention f 33) Ionic surfactants (QS-1) ~ (QS-5): All are [Math. 2] The contents of the grade 4 sulfonium salt shown are summarized in Table 4 below. The symbols in Table 4 correspond to the symbols in [Formula 2]. Ionic Surfactant (FN-1): Sodium Isooctadecanoate Ionic Surfactant (PA-1): Decyl Polyethoxy (η = 4) Ethyl Phosphate Dibutyl Ethanol Ammonium Salt (Please read the precautions on the back before filling out this page) • Binding-Order ▼ Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Printed by the Consumer Consumption Cooperatives of 36. This paper size applies to the Chinese National Standard (CNS) Λ4 specification (21ϋ × 297 mm) 559633 A7 B7 V. Description of the invention C 3 $ Table 4 Types of compounds R6 R7 R8 R9 Compounds forming B QS -1 QS-2 QS-3 QS-4 QS-5 QS-6 butylmethylhydroxyethylbutylbutylbutylbutylmethyl Hydroxyethyl butyl butyl butyl methyl methyl butyl butyl butyl methyl octyl oleyl methyl butyl oleyl oleate dodecanesulfonate pentadecenosuccinate tridecanoate sulfonate Octyl Phenylethoxylate Ethyl Sulfate (Please read the notes on the back before filling out this page) Printed by Intellectual Property Co., Ltd. of the Ministry of Economy, Intellectual Property Co., Ltd.% This paper size applies to China National Standard (CNS) Α4 size (210 × 297 mm) 37 559633 Employees of the Bureau of Intellectual Property, Ministry of Economic Affairs赀 Cooperative cooperative printing A7 B7 V. Description of the invention G 3¾ Ester compound (ES-1): Octyl dodecyl ether ester compound (EE-1): Octyloxy polyethoxy ester (ethoxy unit number 2 5 , K is expressed as n = 5) the ester ether ester compound (EE-2) with dodecanoic acid: octyloxy polyalkoxy ester (polyalkoxy ester is K ethoxy unit 5 pseudo and propoxy Units of 3 randomly connected) ester compounds with dodecanoic acid (cr-1): linear polydimethylsiloxane compounds with average molecular weight 3000 (cr-2): 2 methyl • phenylsiloxanes Units are linear polyorganosiloxane compounds (cr_3) linked to 20 dimethylsiloxane units: 140 dimethylsiloxane units and 8 siloxane units with polyether denaturing groups Random M siloxanes are linearly-linked polyether-denatured polyorganosiloxanes. Polyether denatured groups are side-chain type polyether-denatured silicones composed of 80 hydroxyethylene units and 20 hydroxypropylene units. Oxane compound (cr-4): a dimethylsiloxane unit and a siloxane unit having a polyether denaturing group are randomly combined by a siloxane to form a linear polyether modified polyorganic Oxane, polyether modified polyorganosiloxane with an average molecular weight of 8600, polyether modified group content of 92% by weight, and polyether deformed group consisting of 15 hydroxyethylene units and 15 hydroxypropylene units randomly connected Polyether-modified organosiloxane test group 2 based on pendant type (treatment agent adhesion K for polyester yarn partially drawn yarn and its evaluation) • Treatment agent for polyester yarn partially drawn yarn adhered to test category 1 Adding water to the treatment agent, to adjust the concentration of the treatment agent 38. One paper size applies the Chinese National Standard (CNS) Λ4 specification (210 乂 297 mm) (Please read the precautions on the back before filling this page) 559633 Bureau of Intellectual Property of the Ministry of Economic Affairs (printed by the Industrial and Consumer Cooperation A7 B7__V. Description of the invention < 36) 15% water-based emulsion • Polyethylene terephthalate with an inherent viscosity of 0.64 and a titanium oxide content of 0.2% After the tablets are dried by the conventional method, they are spun at 295 ° C using an extruder, discharged from the discharge port, and cooled and solidified. The walking sliver K-roller oiling method adheres the aqueous emulsion without mechanical extension. K per minute 33 It was taken up at a speed of 00 meters to obtain a rolled cake of 10 kg of partially stretched yarn of 150 denier (72 deniers) with the amount of treatment agent attached to the sliver as described in Table 5 or Table 6. • False twist processing by a contact heater type false twister and its evaluation Using the yarn cake obtained in the above manner, false twist processing was performed according to the false twist processing conditions of the contact heater type false twister described below to evaluate the heater's performance. Pollution. The results are shown in Tables 5 and 6. According to the false twist processing conditions of the contact heater type false twister: using a contact heater type false twister (SDS1200B manufactured by Arnest Scrug and Sons (Transliteration)), M processing speed = 800ro / min, extension ratio = 1.522, application Twisting method = 3-axis disc external friction method (1 entry guide disc, 1 exit guide disc, 7 rigid polyurethane discs), twisting side heater = length 2.5m surface temperature 212 ° C ， Untwisting side heater = None, target twist number = 3300T / m, work continuously for 25 days for false twist processing. Assessment of heater contamination: After 25 days of continuous rotation of the ore lotus under the conditions above K, the heater tar on the yarn path on the surface of the heater on the twisting side was brushed under the brush, and the taken slag was given to K Weighing. Results are measured for 10 spindles. * The average weight per milligram of spindles (mg) is expressed as °. • False twist processing by a short heater type false twister and its evaluation. __ This paper size applies Chinese national standards. (CNS) A4 size (210X 297mm) -_ (Please read the precautions on the back before filling out this page) -Installation_ Order ▼ 线 559633 Α7 Β7 V. Description of the invention (37) The yarn cake obtained by the above method, False twist processing was performed according to the false twist processing conditions of the short heater type false twister described below, and contamination of the heater was evaluated. The results are shown in Tables 5 and 6. According to the false twist processing conditions of the short heater type false twister: Using a short heater type false twister (No33J Mach Clinper manufactured by Murata Machinery Co., Ltd.), M processing speed = 900m / min, extension ratio = 1.522, twisting Method = Nip belt friction method, twisting side heater = length (population section = 30 cm, exit section = 70 cm) surface temperature is 480 1C at the entrance, 410 ° C at the exit, and untwisted heater = none , False twist processing is performed for 33 consecutive days under the condition of the target twist number = 3300T / in. Evaluation of heater contamination: After continuous continuous rotation for 3 to 3 days under the above conditions of K, brush K is used to set up a ceramic yarn path on the twisting side heater to limit the mud-like deposits on the surface of the guide wheel. And weighed. The display is the same as in the case of a contact heater type false twister. (f Please read the notes on the back before filling in this page) Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 40% This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (21 ϋ X 2 () 7 mm) 559633 A7 B7 V. Description of the invention f 38) Table 5 Evaluation of the percentage of treatment agent adhesion ratio used for the classification of the treatment agent used by the Intellectual Property Bureau of the Ministry of Economic Affairs and the Employees' Cooperatives in India and China ⑴ Contact heater (in g) Short heater (mg) S Application Example 20 Example 1 0.4 98 23 Example 21 Example 2 0. 4 84 18 Example 22 Example 3 0. 4 79 15 Example 23 Example 4 0.4 79 16 Example 24 Example 5 0 * 4 60 6 Example 25 Example 6 0.4 75 10 Example 26 Example 7 4 82 17 Example 27 Example 8 0 · 4 140 35 S Example 28 Example 9 0.4 155 38 Example 29 Example 10 0.8 8 85 18 Example 30 Example 11 0. 4 205 65 Example 31 Example 12 0. 4 210 60 Example 32 Example 1 3 0.4 220 70 Example 33 Example 1 4 0. 3 160 28 Example 34 Example 15 0. 3 155 30 Example 35 Example 16 0. 3 150 26 Example 36 Example 1 7 0.3 17 0 45 Example 3 7 Example 1 8 0.3 95 24 Example 38 Example 19 0.3 68 13 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling (This page) > Installation, 11 41 559633 A7 B7 V. Description of the invention (39) Table 6 Proportion of treatment agent used by classification 之 Evaluation of heater pollution Contact heater (rag) Short heater (mg) Comparative example 1 7 Comparative Example 1 0,4 540 190 Comparative Example 1 8 Comparative Example 2 0.4 .510 180 Comparative Example 1 9 Comparative Example 3 0,4 500 205 Comparative Example 20 Comparative 洌 4 0.4 555 185 Comparative Example 2 1 Comparative Example 5 0.4 1150 420 Comparative Example 2 2 Comparative Example 6 0.4 1030 395 Comparative Example 2 3 Comparative Example 7 0. 4 670 310 Comparative Example 2 4 Comparative Example 8 0, 4 705 340 Comparative Example 2 5 Comparative Example 9 0 * 4 580 305 Comparative Example 2 6 Comparative example 1 0 0, 4 1500 180 Comparative example 27 Comparative example 11 0. 4 1200 445 Comparative example 2 8 η, mountains --- ^ ------ install ------ order- --- • Line (Please read the notes on the back before filling out this page) Printed on the paper standard of China Industrial Standards printed by S Industrial Consumers Cooperative of Intellectual Property Bureau of Ministry of Economic Affairs (CNS) Size 8 (210 X 297 mm) 42 559633 A7 B7 V. Description of the invention (40) In Table 5M and Table 6 Adhesion ratio: The amount of the treatment agent attached to the partially stretched polyester yarn ((Please Read the precautions on the back before filling in this page)%) This: Linear polydimethylsiloxane with a viscosity of 3〇1〇20 > < 10-61〇2 /? Chain polyether modified organosiloxane (MS-1) / potassium stearate = 96/2/2 (weight ratio) treatment agent consisting of: multiple yarn breaks, continuous operation cannot be performed under the same test classification 3 (treatment agent attachment M for nylon yarn part extension yarn and its evaluation) • treatment agent for nylon yarn part extension yarn is attached to the treatment agent printed by test classification 1 plus water, printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs , Prepare an aqueous emulsion with a treatment agent concentration of 10%. The nylon 6,6 small pieces with a relative viscosity of sulfuric acid Ur) 2.4 and a titanium oxide content of 0.1% were dried by a conventional method, spun at 29 0 1C using an extruder, discharged from a discharge port, and cooled and solidified. The strip M is guided to the oil method to adhere the aqueous emulsion, and it is wound up at a speed of 4,000 meters per minute without mechanical extension, to obtain a denier of 70 deniers as described in Table 7. denier) 2 4 silk partly stretched 8 kg roll cake. • According to the false twist processing conditions of the contact heater-type false grab machine: The yarn cake obtained above is used to perform false twist processing in the same conditions as described in Test Category 2 except for the conditions under K. Heater contamination was evaluated in the same way as Category 2. The results are shown in Table 7. False twist processing conditions by a contact heater type false twister: This paper size applies the Chinese National Standard (CNS) A4 (210X 297 mm) _ 43-559633 A7 B7 V. Description of the invention (41) Extension magnification = 1.220 Twisting method = external friction method of 3-axis disc (1 entry guide disc, 1 exit guide disc, 5 ceramic discs), and the target twist number is 3000T / m. • False twisting by a short heater type false twister; E and its evaluation. The yarn cake obtained from the upper reel is used to perform false twist processing in the same conditions as described in Test Category 2 except for the conditions under M. The heater contamination was evaluated by the same method as described in Test Category 2. The results are shown in Table 7. According to the false twist processing conditions of the short heater false grab machine: processing speed = 1000m / min, elongation ratio = 1.220, surface temperature is 475T at the entrance: 380C at the exit, and the target twist number is 3000T / βι. Please read and read the notes before ordering # 1 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employees' Cooperatives This paper is printed in accordance with the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) 44 559633 A7 B7 Wisdom of the Ministry of Economic Affairs Printed by the Employees ’Cooperative of the Property Bureau V. Description of the invention (-42) Table 7: Proportion of treatment agent used by category (%) Assessment of heater pollution Contact heater (mg) Short heater (mg) Example 39 Example 3 0.50 85 25 Example 4 0 Example 4 0. 55 87 28 Example 41 Example 5 0.45 75 19 Example 42 Example 10 0.65 88 30 Example 43 Example 11 0 · 55 228 70 Comparative Example 2 9 Comparative Example 1 0 0.55 1450 200 Comparative Example 3 0 Comparative Example 11 0.55 1230 390 Comparative Example 3 1 Comparative Example 1 2 0. 55 1080 405 Comparative Example 3 2 Comparative Example 1 3 0 .55 760 305 Comparative Example 3 3 Comparative Example 1 4 0 .55 595 300 Comparative example 3 4 Comparative example 1 0.5 0.55 Comparative example 3 5 Comparative example 1 6 0. 55 1280 250 (Please read the notes on the back before filling out this page) This paper size applies Chinese National Standard (CNS) A4 Specifications (210X 297 mm) 45 559633 A7 B7 5 3. Description of the invention "3) Test category 4 (adhesion of processing agent for polyester yarn direct spinning and extending yarn and evaluation thereof) • Treatment agent for direct spinning of polyester yarn extending and attaching to processing agent obtained in test category 1. Water was added to prepare an aqueous emulsion with a treatment agent concentration of 10%. The polyester yarn walking sliver K was guided to the oil method to attach the aqueous emulsion, and the first godet roller rotated at a speed of 3000m / min was pulled and the Mechanically stretched between the second godet rollers and wound up at a speed of 5000 m / min to obtain 5 kg of 75 denier direct-spun stretch yarns with a 0.35% attachment amount to the sliver treatment agent Gauze. • False twist processing by contact heater false twister and high temperature short heater false twister and its evaluation. The yarn cake obtained using the above method, except for the overfeed rate of 3%, false twist processing speed. Except for 650m / dm, other conditions were the same as those of Test Category 2 for false twist processing, except that K was evaluated in the same way as Test Category 2 for heater contamination. The results are shown in Table 8. (Please read the note on the back first Please fill in this page for matters) The Intellectual Property Cooperative of the Intellectual Property Bureau Employee Cooperative 46 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 559633 A7 B7 8 Assessing the pollution of the treatment agent heaters used by classification Contact heaters (in g) Short heaters (in g) Example 44: Example 3 75 18 Example 45 Example 5 60 15 Example 46 Example 8 125 33 Example 47 Example 12 225 58 Comparative example 36 Comparative example 5 880 440 Comparative example 37 Comparative example 7 665 380 Comparative example 38 Comparative example 9 585 340 (Please read the precautions on the back before filling this page) Binding and binding paper Standards are applicable to China National Standard (CNS) 8-4 specifications (210X 297 mm) 47 559633 A7 B7 V. Description of the invention < 45) The effect of the invention is very obvious, the treatment agent and treatment method of the invention described on κ * For the synthetic fiber treatment process, even the false twist process accompanied by the excessive heat treatment process, it has the effect of preventing heater pollution sufficiently. Please read first-Read the memorandum of the memorandum before ordering φί Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) Α4 specification (210X 297 mm) 48

Claims (1)

559633 AS B3 C8 D8 Amendment and replacement 7. 7. Kana 92. 7. 1 Replacement [8. VII. Patent application scope 1 · A synthetic fiber treatment agent, consisting of a polyether compound and the following formula [1] Chain type polyether modified polyorganosiloxane (poly-organosiloxane) and the following grade 4 onium salt (formium salt); [formula 1] factory CH3 CH3 · R2 (SiO) m- SiR3 (OA2) q R5 CH; n. 一 --- ^ —'-------- install --- (Please read the precautions on the back before filling this page) Employee Cooperatives of Intellectual Property Bureau, Ministry of Economic Affairs India? π It is characterized by containing in the synthetic fiber treatment agent separately, the linear polyether denatured polyorganosiloxane is 0.1 to 1 2 weight percent ratio, and the 4th grade salt is 0 · 1 to 1 2 weight percentage ratio; (in [Formula 1], R1, R4: alkoxy group with 1 to 10 carbon atoms or alkenyloxy group with 2 to 10 carbon atoms R2, R3: number of carbon atoms 3 or 4 alkylene R5: methyl A1, A2: alkylene with 2 carbon atoms and / or alkylene with 3 carbon atoms p, q: an integer of 20 to 150 m: an integer of 5 to 20 η: an integer from 1 to 9); [Formula 2] D. Shi Yi ° --Line-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1 559633 Αδ Β8 C8 D8 VI. Application Scope of patent: Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives. R7 -X-] R8 (In [Formula 2], X: N or p R, R, R, R9: The same or different number of carbon atoms 1 ~ Alkyl group of 25, alkynyl group of 2 to 25 slave atoms, or hydroxyalkyl group of 1 to 6 carbon atoms, B • Phosphate from 1 to 3 of slave atoms, 1 to 3 carbon atoms ThioS The y-valent anion group y from which the hydrogen ion is removed from the compound selected from the maple (5111 丨 01 ^) acid ester with a daily anti-atomic number of 1 to 30 and the m acid with a carbon number of 1 to 30: an integer of 1 to 3). 2. The synthetic fiber treating agent as described in the first item of the patent application, wherein the 4th grade green salt 'wherein "B of the formula 2" is an aliphatic acid acid vinegar having 1 to 2 carbon atoms and 1 to 6 carbon atoms An y-valent anion group from which hydrogen ions are removed from compounds selected from aliphatic sulfonate (su 1 f ο ne) acid esters and aliphatic carboxylic acids having 1 to 2 6 carbon atoms. The synthetic fiber treatment agent according to item 1, wherein the polyether compound is mainly composed of hydroxyethylene units and hydroxypropylene units, and the average molecular weight is 700 to 20,000. 4 · The synthetic fiber treatment agent according to item 2 of the patent application scope, wherein Polyether compounds are based on hydroxyethylene units and hydroxypropylene units. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). 2 1 --------·! I Order -! I!-* 5 ^ (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs π 559633 AS B8 C8 D8 6. The scope of patent application and the average molecular weight is 7 0 0 ~ 2 0 0 0 0. 5 · Synthesis such as the third item in the scope of patent application A vitamin treatment agent, which further contains an ester compound and / or an ether ester compound having a total carbon number of 10 to 50 in a proportion of 1 to 30 weight percent. 6. The synthetic fiber treatment agent according to item 4 of the scope of patent application It further contains an ester compound and / or an ether ester compound having a total carbon number of 10 to 50 in a proportion of 1 to 30 weight percent. 7. A synthetic fiber processing method, characterized in that the scope of patent application The synthetic fiber treating agent according to item 1 is attached to the synthetic fiber for heat treatment process so that the proportion of the synthetic fiber becomes 0.1 to 3% by weight. 8 · —A synthetic fiber processing method, characterized in that: : The synthetic fiber treatment agent described in the scope of the patent application, item 3, is attached to it in such a manner that the ratio of synthetic fibers for heat treatment process becomes 0.1 to 3 weight percent. 9 · A synthetic fiber treatment 1〜3 重量 ％ The method is characterized in that: the synthetic fiber treatment agent described in the fourth item of the scope of the patent application, for the ratio of synthetic fibers for heat treatment engineering to 0. 1 ~ 3 weight percent 1 0-A synthetic fiber treatment method, characterized in that the ratio of the synthetic fiber treatment agent described in item 5 of the patent application range to 0 for the synthetic fiber used in the heat treatment process is 0 1 ~ 3 weight percent is attached to it. 1 1 · A synthetic fiber processing method, characterized in that the scope of patent application of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ^ --- T ------------------- Order --------- (Please read the notes on the back before filling this page) 3 Ministry of Economy 1 ～ 3 重量 ％ The consumer property cooperative of the Intellectual Property Bureau printed "M 559633 A8 B8 C8 D8 VI. The synthetic fiber treatment agent described in the scope of the patent application No. 6 in order to the ratio of synthetic fibers for heat treatment projects to 0. 1 ~ 3 weight percent Way attached to it. 1 2. The synthetic fiber treatment method according to item 7 of the scope of patent application, wherein the heat treatment process is a false twist process. 1 3 · The synthetic fiber treatment method according to item 8 of the scope of patent application, wherein the heat treatment process is a false twist process. 14 · The synthetic fiber treatment method according to item 9 of the scope of patent application, wherein the heat treatment process is a false twist process. 15 · The synthetic fiber treatment method according to item 10 of the patent application scope, wherein the heat treatment process is a false twist process. 1 6. The synthetic fiber treatment method according to item 11 of the scope of patent application, wherein the heat treatment process is a false twist process. 17 • The synthetic fiber processing method according to item 13 of the scope of patent application, wherein the false twisting process is a process using a short heater with a heater temperature of 300 to 600 ° C. 1 8 · Synthetic fiber treatment method as described in item 14 of the scope of patent application, in which the false twisting process is a process using a short heater with a heater temperature of 300 ~ 600 ° C ° 1 9 The synthetic fiber processing method according to claim 15 of the patent scope, wherein the false twist process is a process using a short heater with a heater temperature of 300 to 600 ° C. 2 0. The synthetic fiber treatment method according to item 16 of the scope of patent application, in which the false twisting process uses a short heater with a heater temperature of 300 to 600 ° C. The paper dimensions are applicable to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) I 4ϋ n i.— n ϋ «ϋ nnn I« ϋ I— n ϋ nn-OJI nn III n I (Please read the notes on the back before filling out this page) 4 559633 AS B8 C8 D8 VI. Projects for the application of patents (short heater) (please read the precautions on the back before filling this page) Printed on paper scales of the China National Standards (CNS) A4 Specification (210 X 297 mm) 5