TW523550B - Steelmaking process using arc furnace to incinerate garbage and recycle flyash - Google Patents

Steelmaking process using arc furnace to incinerate garbage and recycle flyash Download PDF

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TW523550B
TW523550B TW90111315A TW90111315A TW523550B TW 523550 B TW523550 B TW 523550B TW 90111315 A TW90111315 A TW 90111315A TW 90111315 A TW90111315 A TW 90111315A TW 523550 B TW523550 B TW 523550B
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Taiwan
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steel
arc furnace
fly ash
molten steel
steelmaking
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TW90111315A
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Chinese (zh)
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Jung-He Li
Sheng-Tsai Shie
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Jung-He Li
Sheng-Tsai Shie
Tai Chiang Iron And Steel Co L
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

A steelmaking process using an electric arc furnace to incinerate garbage and recycle flying ash uses the characteristic that the flying ash from incineration of garbage contains heavy metals to recycle the flying ash as a portion of the material in steelmaking, and comprises: feeding about 25% to 30% of a steelmaking material into an arc furnace to be melted into a molten steel liquid; adding about 40% to 50% of flying ash from incineration of garbage into the arc furnace to be molten into the steel liquid; covering about 25% to 30% of a steelmaking material on the molten steel liquid; performing a second heating to melt the steel liquid; and performing reduction and oxidation processes to produce a steel blank. Thus, the flying ash can be recycled to avoid environmental contamination.

Description

^3550 、發明說明(1) 曰 修正 , 本發明係有關於一種垃圾焚化飛灰回收再利用之方法 用特別係指—種可有效達到垃圾焚化飛灰之資源回收再利 #以及避免環境污染之環保目的等功效之以電弧爐將垃圾 A化飛灰回收再利用之煉鋼方法。 按’為了解決垃圾量日益增加及垃圾掩埋場地趨於飽 和、尋找不易且有髒亂、污染環境及水源等問題,一種可 將大Ϊ垃级焚化殆盡而大大減少垃圾體積,且較垃圾掩埋 场不佔空間之垃圾焚化爐已逐漸被採用,由於具有乾淨衛 生' 可大量減少垃圾體積、不佔空間等優點,垃圾焚化爐 慑然已成為將來垃圾處理之主要設備之一。且垃圾經由焚 化爐焚化時會產生一種微細粉狀物,一般稱之為垃圾焚化 飛灰’該飛灰會被焚化爐中之靜電集塵器或濾袋集塵器所 收集’然後經過固化處理後掩埋在地底下。然而,由於飛 灰中通常含有大量的重金屬及鹽類等有害物質,埋在地底 下不但易使土壤受到污染,且遇下雨時,該飛灰容易滲入 地下污染水源,並被人們所種植之農作物吸收,導致生產 之農作物容易含有重金屬等有害物質,而間接影響到人體 健康。 是以,本發明之主要目的係在提供一種以電弧爐將垃 圾焚化飛灰回收再利用之煉鋼方法,使達到垃圾焚^飛灰 資源回收再利用並避免環境污染之環保目的等功效者。 於是,本發明以電弧爐將垃圾焚化飛灰回收再利用之 煉鋼方法,係有鑑於垃圾焚化飛灰中含有重金屬成份^ 3550, Description of the invention (1) Amendment, the present invention relates to a method for recycling and incineration of fly ash from waste incineration. In particular, it refers to a kind of resource recovery that can effectively achieve the waste incineration of fly ash # and avoid environmental pollution. For the purpose of environmental protection and other effects, the steelmaking method for recycling and recycling the garbage A fly ash by electric arc furnace. Press' In order to solve the problems of increasing the amount of waste and the landfill sites becoming saturated, difficult to find and dirty, polluting the environment and water sources, etc., one can greatly reduce the volume of waste by incineration of large-scale waste, and it is more than landfill. Garbage incinerators that do not take up space have been gradually adopted. Due to their advantages such as being clean and hygienic, which can reduce the volume of waste and take up no space, garbage incinerators have become one of the main facilities for waste treatment in the future. And when the garbage is incinerated through the incinerator, a fine powder is generated, which is generally called garbage incineration fly ash 'The fly ash will be collected by the electrostatic dust collector or filter bag dust collector in the incinerator' and then solidified. Buried under the ground. However, because fly ash usually contains a large amount of heavy metals and salts and other harmful substances, it is not only easy to contaminate the soil when it is buried under the ground. When it rains, the fly ash easily penetrates into underground polluted water sources and is planted by people. Absorbed by crops, the produced crops are apt to contain harmful substances such as heavy metals, which indirectly affect human health. Therefore, the main object of the present invention is to provide a steel making method for recycling and recycling waste incineration fly ash by an electric arc furnace, so as to achieve the environmental protection purpose of recycling waste ash and fly ash resources and avoiding environmental pollution. Therefore, the present invention uses an electric arc furnace to recover and reuse waste incineration fly ash, in view of the fact that the waste incineration fly ash contains heavy metal components

五、發明說^« η 年 料置入— ;b.摻入4 0 全溶入鋼水 ,使覆蓋於 加熱使熔融 等連續鑄造 源回收再利 更詳盡明確 說明如后: 較佳實施例 驟示意圖, 之煉鋼方法 包括有一供 需要用到之 要依序包含 %〜5q% 電弧爐中,使經高溫加熱熔融成鋼水 中;之垃圾焚化飛灰至上述電弧爐内’使完 溶入/ .再加入25%〜3〇%之煉鋼原料於電弧爐中 成鋼水圾义化飛灰之鋼水上層,再經二次高溫 過程]d·將步驟C形成之鋼水經還原、氧化 、製成鋼胚。藉此,達到垃圾焚化飛灰資 用及避免璟户、——九 、兄衣纟兄 >可染之環保目的等功效。 的為期能對本發明之目的、功效以及特徵有 、’、解’兹舉本發明之較佳實施例並配合圖式 請參閱第一圖及第二圖所示,係本發明一 2 $鋼设備的構件方塊示意圖及煉鋼流程及步 /只知例以電孤爐將垃圾焚化飛灰回收再利用 係應用一習知之煉鋼設備1,該煉鋼設備1主要 進行南溫加熱之電弧爐丨丨以及連續鑄造過程中 精煉爐1 2及一連續鑄造機丨3。該煉鋼方法主 下列步驟: a·先將一部分(約25 %〜30%)之煉鋼原料置入上述電弧 爐11中’對電弧爐丨丨加熱至丨6 〇 〇。〇之高溫,使將該 煉鋼原料溶融成鋼水;其中,該煉鋼原料係以廢 鐵、廢鋼等為主要材料。 b·於步驟a·之煉鋼原料融熔成鋼水後,將約40%〜50% 的垃圾焚化飛灰摻入電弧爐丨丨内之鋼水中並與鋼水 調和’使垃圾焚化飛灰能完全溶入鋼水中,此一目 的是為 c.接著,V. Invention ^ «η Yearly Material Placement-; b. Incorporate 40 into the molten steel, so that the continuous casting source covered by heating and melting can be recovered, and the details will be explained in more detail as follows: Schematic diagram, the steelmaking method includes a supply for the need to sequentially contain% ~ 5q% electric arc furnace, melting at high temperature into molten steel; waste incineration fly ash into the above-mentioned electric arc furnace ' .Add 25% ~ 30% of the steelmaking raw materials to the upper layer of molten steel in the electric arc furnace to form molten steel desalination fly ash, and then go through the second high temperature process] d · The molten steel formed in step C is reduced and oxidized. 2. Made of steel embryo. In this way, it can achieve the effects of waste incineration and fly ash, and avoid environmental protection purposes such as households, nine, brothers, and brothers > dyeable. The purpose of this invention is to explain the purpose, efficacy and characteristics of the present invention. The preferred embodiments of the present invention are described below. For the drawings, please refer to the first and second figures. It is a 2 $ steel set of the present invention. Schematic diagram of the component block and steelmaking process and steps / steps. For example, the recycling and reuse of waste incineration fly ash by an electric solitary furnace is a conventional steelmaking equipment 1 which is mainly used for electric arc furnaces heated at south temperature.丨 丨 and refining furnace 12 and a continuous casting machine 丨 3 during continuous casting. The steelmaking method mainly includes the following steps: a. A part (approximately 25% to 30%) of the steelmaking raw material is first placed in the above-mentioned electric arc furnace 11 'and the electric arc furnace is heated to 6600. The high temperature of 〇 causes the steelmaking raw material to be melted into molten steel. Among them, the steelmaking raw material is mainly composed of scrap iron, scrap steel and the like. b. After the steelmaking raw materials in step a · are melted into molten steel, about 40% to 50% of the waste incinerated fly ash is mixed into the molten steel in the electric arc furnace and the molten steel is reconciled with the molten steel to make the waste incinerated fly ash. Can be completely dissolved in molten steel, the purpose of which is c. Then,

了讓垃圾焚化飛灰安定化使不致四處飛散。 再加入一部分(約2 5%〜30%)的煉鋼原料於電In order to stabilize the garbage incineration and fly ash, it will not be scattered around. Add another part (about 2 5% to 30%) of steelmaking raw materials to electricity

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^23550 x ---j 號 90111315五、發明說^- 月 曰 呢爐1 1中’使能覆蓋在步驟b之溶入垃圾 的鋼水上層,然後再對電弧爐丨丨二次加熱 之高溫,使電弧爐11中之全部煉鋼原料炼 形成鋼水。 d·最後,將步驟C所形成之鋼水依序送至精 連續鑄造機13,進行還原、氧化等連續g 即可煉製成一鋼胚。且於精煉爐丨2之煉掣 可藉由加入適當母合金之比例,改變所練 胚的純度,例如,若加入電弧爐丨丨之廢鐵 5 0%,垃圾焚化飛灰佔總量50%,且飛^中 量佔2 0 %,使所產出之鋼胚純度僅有6 〇 %, 煉爐1 2中加入一定比例之母合金,使所產 有8 0 %的純度。 此外,於該鋼胚製成後,可再經由直接加工 ’或者再加入其他金屬進行二次加工後製成特殊 成品。 綜合上述,本創作確實具有下列功效: 1 ·達到資源回收再利用之目的 本創作利用垃圾焚化所產生之飛灰 金屬成价之特點,將垃圾焚化飛灰播八 由煉鋼材料所融炫之鋼水内進行煉鋼, 入母合金做成份調整製成鋼胚後,可再 加工或二次加工製成不同用途之碳鋼或 鋼,有效達到垃圾焚化飛灰回收再利用 功效。 ; 焚化飛灰 至 1 6 0 0 °c 融並混合 煉爐1 2及 造程序, 過程中, 製出之鋼 佔總量 之金屬含 則可於精 出鋼胚具 製成碳鋼 合金鋼等 中含有重 電孤爐中 並經由加 經過直接 特殊合金 之目的及^ 23550 x --- j No. 90111315 V. Invention ^-Month of the furnace 1 1 'Enable to cover the upper layer of molten steel dissolved in garbage in step b, and then heat the electric arc furnace 丨 丨 high temperature of secondary heating To make all the steelmaking raw materials in the electric arc furnace 11 into molten steel. d. Finally, the molten steel formed in step C is sequentially sent to the precision continuous casting machine 13 for continuous g such as reduction, oxidation, etc., and then a steel blank can be produced. In addition, the refining switch in the refining furnace 丨 2 can change the purity of the embryos by adding the appropriate proportion of the master alloy. For example, if 50% of the scrap iron is added to the electric arc furnace 丨, the waste incineration fly ash accounts for 50% of the total In addition, the amount of fly ash accounted for 20%, so that the purity of the steel slab produced was only 60%, and a certain proportion of the master alloy was added to the furnace 12 to achieve a purity of 80%. In addition, after the steel billet is made, it can be processed through direct processing 'or added with other metals for secondary processing to make special products. Based on the above, this creation does have the following effects: 1. To achieve the purpose of resource recycling and reuse. This creation uses the characteristics of the fly ash metal produced by waste incineration to spread the waste incineration fly ash into the dazzling of steelmaking materials. After steelmaking in molten steel, the parent alloy is used to adjust the composition to make steel slabs, which can be reprocessed or reprocessed to make carbon steel or steel for different purposes, which effectively achieves the waste incineration fly ash recovery and reuse effect. ; Incineration fly ash to 1 600 ° c melting and mixing furnace 12 and the manufacturing process, in the process, the produced steel accounted for the total metal content can be refined from the steel blank to make carbon steel alloy steel, etc. The purpose of containing special heavy alloys in direct electric furnaces and

523550 五、發明說明 顏 90111315 (4) 達到避免環境污 續前所述, 飛灰資源回收做 鋼胚的一部分, 綜合 垃圾焚化 鋼原料中 並且避 境的情況 綜上 用之煉鋼 為煉鋼原 環境遭受 再利用之 未見有雷 利要件, 唯, 凡應用 化,理應 及價值 環境及 上述,飛灰内 進行煉 免該等 發生。 所述, 方法, 料5不 垃圾焚 功效增 同或近 爰依專 以上所 本發明 包含在 ,而不會 水源污染 本發明利 含重金屬 鋼,不但 垃圾焚化 本發明以 利用垃圾 但具有資 化飛灰之 進,是以 似之物品 利法之規 述者,僅 說明書及 本發明之 染之環保目 由於本創作 為一部分煉 使垃圾焚化 被隨意棄置 專問題’有 用垃圾焚化 之特點,將 將垃圾焚化 飛灰被埋置 丑— 日 __修正 的 將垃圾焚化 鋼材料並成 飛灰有再利 或掩埋於地 效達到環保 爐焚化垃圾 垃圾焚化飛 飛灰重新回 於地底下造 所產生之 為所煉製 用之去處 下而造成 之目的。 所產生之 灰摻入煉 收再利用 成污染環 電弧爐將垃圾焚化飛灰回收再利 焚化爐所產生之垃圾焚化飛灰做 源回收再利用之優點,且能避免 污染’確實具有環保及資源回收 ,本發明誠為一進步之設計,又 揭露於市,誠已符合新穎性的專 定提出申請。 係本發明之較佳實施例而已,故 申請專利範圍所為之等效結構變 專利範圍内。 523550523550 V. Description of the invention Yan 90111315 (4) As mentioned before, to avoid environmental pollution, as described above, fly ash resources are recycled as part of the steel embryo, comprehensive waste incineration of steel raw materials and avoidance of the environment. There are no Rayleigh requirements for the environment to be reused. However, where applied, the environmental value and the environment should be rectified and exempted. In the method, material 5 does not increase the efficiency of waste incineration, or it can be used in accordance with the above invention. The invention is included in the invention without water pollution. The invention uses heavy metal steel. Ashinjin is a narrator of similar articles, only the description and the environmental protection of the invention are part of the creation. As a part of this creation, garbage incineration is randomly disposed of. The problem of "useful garbage incineration" will dispose of garbage. Incineration fly ash is buried ugly — Japan's __ revised amendment to the incineration of waste steel materials into fly ash is beneficial or buried in the ground to achieve environmental protection furnace incineration waste garbage incineration fly ash is returned to the ground The purpose of the refinement where it is made. The generated ash is blended with refining and reused into a polluting ring electric arc furnace. The waste incineration fly ash is recovered and reused. The incineration fly ash produced by the incinerator has the advantages of recycling and reuse, and it can avoid pollution. It does have environmental protection and resources. Recycling, the present invention is sincerely a progressive design, and also disclosed in the city, since the application has been made in accordance with the novelty. It is only the preferred embodiment of the present invention, so the equivalent structure within the scope of the patent application is within the scope of the patent. 523550

Claims (1)

523550523550 案號90111315_年 月 六、 申請專利範圍 利用之煉鋼方法 •一種以電弧爐將垃圾焚化飛灰回收再利 ’係依序包含有下列步驟: 棟鋼設備之電 ‘ a·預先將約25%〜30%之煉鋼原料放入〆% 弧爐中,使經高溫加熱熔融成鋼水; b·將約4 0%〜50%之垃圾焚化飛灰摻入步驟a之鋼水中並 與鋼水調和,使完全溶入鋼水中; c ·再將約2 5 %〜3 0 %之煉鋼原料放入該電弧爐中’使覆 蓋於步驟b之溶入垃圾焚化飛灰的鋼水上層’並經 二次高溫加熱使炫融成鋼水; • d.將步驟c之鋼水經還原、氧化等連續鑄造程序煉製 成一鋼胚。 依申請專利範圍第1項所述以電弧爐將垃圾焚化飛灰 回收再利用之煉鋼方法,其中,步驟a及步驟c中之高 溫加熱溫度約為1 6 0 0 °C。 依申請專利範圍第1項所述以電弧爐將垃圾焚化飛灰 回收再利用之煉鋼方法,其中,於步驟d中可藉由加 入適當母合金之比例,調整所媸制山 曰 4Case No. 90111315_Sixth of the year of the patent application, a steel-making method using a patent scope • An electric arc furnace to recycle waste incineration fly ash for re-use and benefit 'system contains the following steps in sequence: a. % ~ 30% of the steelmaking raw materials are placed in a 〆% arc furnace, which is melted into molten steel by high temperature heating; b. About 40% ~ 50% of garbage incineration fly ash is mixed into the molten steel in step a and mixed with steel Water is blended to completely dissolve in the molten steel; c. Put about 25% to 30% of the steelmaking raw material into the electric arc furnace 'make the upper layer of molten steel dissolved in the waste incineration fly ash covered in step b' The molten steel is melted into molten steel through secondary high-temperature heating; d. The molten steel in step c is made into a steel billet by continuous casting procedures such as reduction and oxidation. According to item 1 of the scope of the patent application, a steelmaking method for recycling incinerated fly ash by an electric arc furnace, wherein the high-temperature heating temperature in step a and step c is about 160 ° C. According to the steelmaking method for recycling incineration fly ash by electric arc furnace as described in item 1 of the scope of the patent application, in step d, the proportion of the appropriate master alloy can be adjusted to adjust the sintered mountain. J正Μ琛製出之鋼胚的绌声。 依申請專利範圍第1項所述以雷沉隨收 又 回收再利用之煉鋼方法,i中,本_」 人化化灰 ^ r 步驟d所制尘a λ 可經由再加入其他成分金屬燎制# χ成之鋼胚 等不同鋼材。 Λ荷殊合金鋼J is the snoring of the steel embryo made by M Chen. According to the steelmaking method of recovering and reusing as described in item 1 of the scope of the patent application, i., This _ "humanized ash ^ r dust produced in step d a λ can be added by adding other constituent metals 燎## χ 成 之 子 embryo and other different steels. ΛHosh alloy steel
TW90111315A 2001-05-11 2001-05-11 Steelmaking process using arc furnace to incinerate garbage and recycle flyash TW523550B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI660048B (en) * 2018-03-26 2019-05-21 郭風坤 Treatment method for incineration recycling of stainless steel materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI660048B (en) * 2018-03-26 2019-05-21 郭風坤 Treatment method for incineration recycling of stainless steel materials

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