TW523494B - Apparatus for treating the water containing phosphoric acid ions, and method therefor - Google Patents

Apparatus for treating the water containing phosphoric acid ions, and method therefor Download PDF

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Publication number
TW523494B
TW523494B TW088119692A TW88119692A TW523494B TW 523494 B TW523494 B TW 523494B TW 088119692 A TW088119692 A TW 088119692A TW 88119692 A TW88119692 A TW 88119692A TW 523494 B TW523494 B TW 523494B
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TW
Taiwan
Prior art keywords
voltage
ions
power supply
processing device
patent application
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TW088119692A
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Chinese (zh)
Inventor
Keiichi Fujimoto
Masaki Moriizumi
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Sanyo Electric Co
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

The present invention provides an apparatus for treating the water containing phosphoric acid ions, being able to maintain the removability of phosphoric acid and lower the equipment cost, comprising at least a pair of electrode 5 disposed opposite to each other in the water containing phosphoric acid ions in the electrolyte treating tank 4, an electric source 6 for conducting electricity to said electrode 5 and an aeration device 7 for aerating the interior of said treating tank 4, wherein said electric source 6 being a constant voltage source.

Description

523494 A7 B7 五、發明説明(i ) [發明所屬之技術領域] (請先閲讀背面之注意事項再填寫本頁) 本發明為有關一種將家庭廢水或集體住宅之排水等含 有磷酸離子之生活廢水或在熱帶魚水槽循環的水之處理裝 置以及處理方法。 [以往之技術] 自很早以前眾人已知河川或湖泊優養化 (entrophication)的原因之一為磷化合物之存在。在一般家 庭之生活廢水中含有許多該磷化合物,惟該磷化合物為一 種難以淨化處理之物質,致一直到現在尚無有效的處理方 案。 關於填化合物之處理裝置曾經有種種的提案,其中關 於家庭廢水方面則已知有鐵之電解洗提法(參照日本特開 平3-89998號公報、特開平6-254584號公報,C02F 3/12)。 經濟部智慧財產局員工消費合作社印製 該技術係一種將廢水中之鱗酸離子與鐵離子起反應而成為 水不溶性之鹽,例如作成FeP04或Fe(0H)x(P04)y,以使 其凝聚沈殿而除去之技術,而係對於設在電解槽中之鐵製 電極通電,使鐵離子洗提於排水中者。此外,此種採用電 解洗提法之處理裝置,係用在例如,由厭氣槽,好氣槽以 及處理槽所組成而可把該處理水槽之污水經由用以將與碟 酸反應之鐵離子加以洗提之電解裝置循環於厭氣槽所構成 之污水處理裝置等。 [發明欲解決之課題] 依上述電解法之除磷裝置’採用在電極間通以直流電 流,以洗提鐵離子之方法,然而,由於除磷性能係依靠依 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 1 310971 523494 A7523494 A7 B7 V. Description of the invention (i) [Technical field to which the invention belongs] (Please read the precautions on the back before filling out this page) The present invention is a domestic wastewater containing phosphate ions, such as domestic wastewater or drainage of collective housing Or a device and method for treating water circulating in a tropical fish tank. [Past Technology] One of the reasons for the entrophication of rivers or lakes has been known for a long time is the existence of phosphorus compounds. Many domestic phosphorus compounds are contained in domestic household wastewater. However, this phosphorus compound is a substance that is difficult to purify and treat, and there is no effective treatment solution until now. Various proposals have been made on the treatment equipment for filling compounds. Among them, the electrolytic elution method of iron is known for domestic wastewater (see Japanese Patent Application Laid-Open No. 3-89998, Japanese Patent Application Laid-Open No. 6-254584, and C02F 3/12. ). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics This technology is a kind of water-insoluble salt that reacts with phosphonate ions and iron ions in wastewater, such as FeP04 or Fe (0H) x (P04) y to make The technique of agglomerating and removing Shen Dian is to apply electricity to an iron electrode provided in an electrolytic cell to elute iron ions in the drainage. In addition, such a treatment device using an electrolytic stripping method is used in, for example, an anaerobic tank, an aerobic tank, and a processing tank, and the sewage of the processing water tank can be passed through the iron ion used to react with the dish acid. The eluted electrolytic device is circulated in a sewage treatment device constituted by an anaerobic tank. [Problems to be Solved by the Invention] The phosphorus removal device according to the above electrolytic method uses a method in which a direct current is passed between the electrodes to extract iron ions. However, since the phosphorus removal performance depends on the application of Chinese national standards in accordance with the paper scale ( CNS) A4 size (210X297 mm) 1 310971 523494 A7

(請先閱讀背面之注意事項再填寫本頁) 法拉第定律而流通於電極之總電流量而定,因此要確保除 Μ性能’則須把電流量維持於怪定值。因此,通常,電源 係使用例如第6圖所示,由ac濾波器50、整流·平滑部 51、緩冲(snubber)電路52、開關電路53、次級平滑電路 54、以及電流檢測電路55所構成之開關型悝流電源。 然而’這種開關型之定電流電源比較高價,有設備投 資費增高之虞。 本發明係鑑於如上述之情形,以提供一種能維持磷酸 除去功能下可降低設備投資費之用以處理含有磷酸離子之 水之處理裝置以及處理方法為其目的。 [解決課題之手段] 本發明之用以處理含有磷酸離子之水之處理裝置,包 括有:至少一對電極,係以至少使其一部分浸潰於電解處 理槽内的含有磷酸離子之被處理水中之方式相對著而配 置’該電極之至少一方含有鐵與/或鋁;用以對該電極通 電之電源’以及用以將上述處理槽内部曝氣之曝氣裝置; 經濟部智慧財產局員工消費合作社印製 上述電源係使用疋電壓電源(constant voltage source) 為其特徵。 另外’本發明之用以處理含有磷酸離子之水之處理方 法係種使用含有鐵及/或鋁之至少一對電極以電化學 方式將鐵離子及/或鋁離子從含有磷酸離子之被處理水中 洗提,使磷酸離子與鐵離子及/或鋁離子反應成為不溶性 鹽之形態凝聚沈澱的水之處理方法,而以對上述電極施加 定電壓為其特徵。 2 310971 523494 A7 ______B7五、發明説明(3 ) [發明之實施形態] 以下,根據所附圖面說明本發明之用以4蹄a 離子之水之處理裝置以及處理方法。 ’ [圖示之簡單說明] 第1圖係表示本發明之用以處理含有磷醪離I 處理裝置之一實施形態之說明圖。 第2圖係第1圖之處理裝置之擴大圖。 第3圖係表示定電壓電源之一實施形態之资 第4圖係在第3圖之電源接上電壓轉換教| 峻 制裝置時之電路圖 第5圖係表示本發明之用以處理含有磷 處理裝置之一實施形態之說明圖。 本發明之處理裝置可用於例如合并淨化错 匕 |U 裝置。合并淨化槽’如第1圖所示,由第一厥氣◊廣 處硬 床错 第二厭氣濾床槽B、生物過濾槽等之需氣槽^、 TW Λ Λ 經濟部智慧財產局員工消費合作社印製 D、以及消毒槽Ε所構成,而可把流入前述苐〜 ^ ^ 槽A之廢水經由各槽加以處理後,自消毒槽 氣據床 中處理裝置1係設在將氣泵F所從前述處理水槽〇抽/、 來的水送回至第一厭氣濾床槽A之循環路徑l上。 前述處理裝置1,如第2圖所示,包括有··電解處理 槽4,該電解處理槽4具有被處理水之排水的流入口 2與 流出口 3 ;至少一對電極5,係以使其至少一部分浸潰於 該電解處理槽4内之排水之方式相對著而配置;電源6, 用以對該電極5通電•,以及曝氣裝置7,用以對前述電解 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 3 310971(Please read the precautions on the back before filling this page) Faraday's law depends on the total amount of current flowing through the electrode. Therefore, to ensure the performance in addition to Μ, the current must be maintained at a strange value. Therefore, in general, the power supply system uses, for example, an AC filter 50, a rectifying / smoothing unit 51, a snubber circuit 52, a switching circuit 53, a secondary smoothing circuit 54, and a current detection circuit 55 as shown in FIG. Constituted switch-type current source. However, this type of switch-type constant current power supply is relatively expensive, which may increase the equipment investment fee. In view of the circumstances as described above, the present invention aims to provide a treatment device and a treatment method for treating water containing phosphate ions, which can reduce equipment investment costs while maintaining a phosphoric acid removal function. [Means for solving the problem] The treatment device for treating water containing phosphate ions according to the present invention includes at least a pair of electrodes immersed in at least a part of the treated water containing phosphate ions in an electrolytic treatment tank. Relatively, the method is configured with 'at least one of the electrodes contains iron and / or aluminum; a power source for energizing the electrode' and an aeration device for aerating the inside of the above processing tank; the employees of the Intellectual Property Bureau of the Ministry of Economic Affairs consume Cooperatives printed the above-mentioned power source using a constant voltage source (constant voltage source) as their feature. In addition, the method for treating water containing phosphate ions according to the present invention is to electrochemically remove iron ions and / or aluminum ions from the treated water containing phosphate ions using at least one pair of electrodes containing iron and / or aluminum. A method for eluting and reacting phosphate ions with iron ions and / or aluminum ions to form an insoluble salt, condensing and precipitating water, and characterized by applying a constant voltage to the electrodes. 2 310971 523494 A7 ______B7 V. Description of the Invention (3) [Embodiments of the Invention] The following will describe the device and method for treating water with 4 hoof a ions according to the drawings. [Brief description of the figure] FIG. 1 is an explanatory diagram showing an embodiment of the processing apparatus for processing phosphorus-containing ions I of the present invention. Fig. 2 is an enlarged view of the processing device of Fig. 1. Fig. 3 is a diagram showing an embodiment of a constant-voltage power source. Fig. 4 is a circuit diagram when a voltage converter is connected to the power supply in Fig. 3 | An illustration of one embodiment of the device. The processing device of the present invention can be used, for example, to incorporate a purification unit. Combined purification tanks' As shown in Figure 1, the required air tanks, such as the first hard bed, the second anaerobic filter bed tank B, the biological filter tank, etc. ^, TW Λ Λ employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Consumption cooperatives print D and sterilizing tank E, and can treat the wastewater flowing into 苐 ~ ^ ^ tank A through each tank, and the treatment device 1 in the bed of the gas tank from the sterilizing tank is installed in the air pump F The water pumped from the aforementioned treatment water tank 0 is sent back to the circulation path 1 of the first anaerobic filter bed tank A. The processing device 1 includes, as shown in FIG. 2, an electrolytic treatment tank 4 having an inflow port 2 and an outflow port 3 for drainage of treated water; at least a pair of electrodes 5 At least a part of the drainage is immersed in the electrolytic treatment tank 4 in a relatively opposite manner; the power source 6 is used to energize the electrode 5 and the aeration device 7 is used to apply the above-mentioned electrolytic paper size to the Chinese country Standard (CNS) A4 size (210X297 mm) 3 310971

(請先閱讀背面之注意事項再填寫本頁J(Please read the notes on the back before filling in this page J

523494 五、發明説明(4 處理槽4内之排水曝氣。料,上述處理裝η也可 極性反轉裝置以便定期的將上述電極5之極性予以反^ 上述電極5’可由鐵、鐵合金、銘、銘合金或鐵_銘° 合金等之鐵離子及/或鋁離子之發生源製造。另外,上 曝氣裝置7係由設置於電解處理槽4之底中央之多孔質散 氣管10或散氣板、以及用以對該散氣管10送入壓縮=氣 之氣泵11所構成,而上述散氣管1〇與氣泵U係為管 12所連接。 、、玲 本發明以上述電源6為定電壓電源為其特徵。這定電 壓電源,如第3圖所示,例如,可由整流·平滑部13與 疋電壓部14構成之。其中’整流·平滑部13則由變壓器 15a、整流器(二極體電橋)15b及電解電容器15〇構成,而 定電壓部14則可使用由三端子調節器(一元件型定電壓元 件)16a、電容器16b、及電解電容器1^所組成者。為使 上述電極5不致發生腐蝕生成物(aFe〇〇H)之鈍態膜,以 獲得穩定的除攝功能,已知相對於液中磷酸離子濃度之鐵 離子(鋁離子)之洗提濃度之比率(以下稱為莫耳比)是以設 定為1.5倍左右為宜。因此,在本實施形態,若將該莫耳 比設定於較之1·5大一些之值,例如,設定為2 〇的話, 即使電流有些變動,也能獲得穩定的除填功能。 因此,在本實施例,排水係進入電解處理槽4,而電 極5為鐵製之情況下,由該電極5之陽極側洗提之鐵離子 即將與猶酸離子起凝聚反應,生成不溶性之磷酸鐵,然後, 該磷酸鐵即流入第一厭氣濾床槽A,其凝聚物則以第一、 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 310971 (請先閱讀背面之注意事項再填寫本頁) 訂·523494 V. Description of the invention (4 Drainage and aeration in the treatment tank 4. It is also possible that the above-mentioned treatment is equipped with a polarity reversal device so as to periodically reverse the polarity of the above electrode 5. , Ming alloy or iron_ming ° alloy and other iron ions and / or aluminum ion source. In addition, the upper aeration device 7 is a porous air diffusing tube 10 or air diffusing tube installed in the center of the bottom of the electrolytic treatment tank 4. It is composed of a plate and an air pump 11 for feeding compressed air into the diffuser pipe 10, and the diffuser pipe 10 and the air pump U are connected to the pipe 12. The present invention uses the power source 6 as a constant voltage power source. This constant voltage power supply, as shown in FIG. 3, can be composed of, for example, a rectifying / smoothing section 13 and a high-voltage section 14. Among them, the 'rectifying / smoothing section 13 is composed of a transformer 15a, a rectifier (diode power The bridge) 15b and the electrolytic capacitor 15 are configured, and the constant voltage section 14 may be composed of a three-terminal regulator (a one-element constant voltage element) 16a, a capacitor 16b, and an electrolytic capacitor 1 ^. Does not cause corrosion products (a Fe〇〇H) passive film to obtain a stable removal function, the ratio of iron ion (aluminum ion) elution concentration (hereinafter referred to as the molar ratio) to the phosphate ion concentration in the liquid is known It is preferable to set it to about 1.5 times. Therefore, in this embodiment, if the mole ratio is set to a value larger than 1.5, for example, if it is set to 2 0, even if the current changes slightly, stability can be obtained. Therefore, in this embodiment, when the drainage system enters the electrolytic treatment tank 4 and the electrode 5 is made of iron, the iron ions eluted from the anode side of the electrode 5 are about to undergo a condensation reaction with the heptanoic acid ions. The insoluble iron phosphate is formed, and then, the iron phosphate flows into the first anaerobic filter bed tank A, and its agglomerates are in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) 310971 ( (Please read the notes on the back before filling out this page) Order

經濟部智慧財產局員工消費合作社印製 A7Printed by Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs A7

五、發明説明(5 ) 弟一厭氣遽床槽A及r,,、,ϋ ^ ^ B以及舄氣槽C予以捕捉,即可 從液中把磷除去。 户接著說月本發明之其他實施形態。在本實施形態, 第圖所τ貝ij將上述定電壓部14分成定電壓部…、 b及14c之_部,俾能以分成三階段轉換一定電壓, 並於上述整流•平潛邱1 2也a a 4 13與各疋電壓部i4a、14b及14c 之間連接電壓轉換裝置17。因此,即使電極5間之電阻 因時效變化而有所變化時,只要以該電壓轉換裝置㈣ 換定電壓電源之供應便能維持大致恒定之流通於電極$之 電流。另外,此項電壓變更可於做定期性保養工作時同時 實施’惟若欲以自動方式實施時,較佳的方法,係如第4 圖所示,將用以檢測流通於上述電極5之電流,例如電流 感測斋等之電流檢測裝置18,與可根據該電流檢測裝置18 所檢測之值控制電壓且係由微電腦或比較器等構成之電壓 控制電路等電壓控制裝置19,予以連接,藉此,便能把 供自電流檢測裝置18之檢測結果輸入電壓控制裝置19, 使電壓轉換裝置17自動的運作。 經濟部智慧財產局員工消費合作社印製 本貝施开/愍之處理裝置,如上述,特別可有效地利用 於一般家庭廢水之處理。因此,可單獨使用,但也可搭配 於其他淨化系統,例如,活性污泥法、膜分離法、厭氣, 需氣循環法等以作為家庭用、集體住宅用之綜合廢水淨化 系統。另也可利用於大規模處理系統(屎尿處理場)。 接著說明將本發明之用以處理含有磷酸離子之水之處 _理裝置適用於從上述廢^^外之被處理水施予除磷之水淨 本紙張尺度適用中國國家標準(CNS) -------— 5 310971 523494 五、發明説明(6 (讀先閱讀背面之注意事項再填寫本頁) 化裝置之其他實施形悉。該水淨化裝置係用以除去於水槽 飼養的生物(熱帶魚或其他魚類和貝類、龜或水栖昆蟲等) 之屎尿或剩僻等有機物而淨化水槽之水的裝置。 如第5圖所示,水淨化裝置由水槽50與載置於該水 槽50之上部之過遽器51構成,而該過渡器51具有:位 於下部容器5U與蓋子51b之間以作為過遽部之過渡槽 52、設於該過濾槽52之下游側之處理裝置53、作為脫色 部而設於該處理裝置53之下游側之脫色槽54、作為移送 裝置而具有過濾器55a與抽水管5讣之抽水泵55、以及 作為回送裝置之回流管56。上述處理裝置53係作成與第 2圖及第3圖或第4圖所示之處理裝置i相同構成,1電 極5係裝在電極保持器5a並插入電極固定板心浸潰於 水中。 水係經由形成於上述處理装置53之下㈣流人口 2 而流入電解處理槽4,上述電極5若係由鐵製造,從該電 極5之陽極側洗提出之鑛雜 、 抗出之鐵離子將與磷酸離子起凝聚反應, 形成不溶性之鱗酸鐵。麸饴 經濟部智慧財產局員工消費合作社印製 ^ …、後该磷酸鐵將因曝氣裝置7而 :上來’並經由排出口 3排出於脫色槽54。在本實施形 〜則使用疋電壓電源’把莫耳比設定於稍微高一些,或 在該電源接上電壓轉換裝置’或另再予以檢測電流,便可 維持穩定的除磷性能。 上述過渡槽52,内部裝有用以將魚類和貝類之原尿 ==等有機物以及水中浮遊物加以物理過濾或生物過滤 Η張家標準(烯作為原料之針4 6 310971 經濟部智慧財產局員工消費合作社印製 7 523494 A7 ------B7____ 五、發概明(7 ) " " '一家一'"-- 型片狀不織布(例如,單位重量為400g/m2、厚度為4 〇毫 米 '通氣量為160cc/cm2/sec)予以疊層複數層而成者。水 槽50内之水經由抽水管55b抽上於過濾槽52,接受該過 渡器52a之物理過濾和生物過濾作用,以捕捉及除去水中 浮游物。 上述脫色槽54,用以除去浮游水中而自電解處理槽4 之排出口 3流出之磷酸鐵,係鄰接於電解處理槽4而設, 其内部裝有用以除去該磷酸鐵及實行生物過濾之過濾器 54a。該過濾器54a係把眾多由聚丙烯製造的長度1〇毫米 左右、外桠6毫米左右、内徑3毫米左右之中空圓柱收容 於袋子内而成。 另外’在本實施形態,雖把脫色槽設於電解處理槽下 游侧’惟本發明之水淨化裝置並非限定於此,未具備脫色 槽者也可用。又在本實施例,係就把過瀘、槽(過滤部)配置 於水槽上方之方式加以說明,惟該過濾部也不妨採用由配 置於水槽内而可執行物理過濾及/或生物過濾之過濾器所 構成者。 又本實施例係將之適應於水之淨化裝置,但也可適應 於養殖場或水族館之淨化裝置。 [發明之效果] 如上所說明,依照本發明,使用定電壓電源,把莫耳 比設定於比以往稍微高一些,即能以不會降低除磷性能下 降低整個裝置之成本。結果,可望降低設備費用。 再者’依照本發明,替代把莫耳比設定於比以往稍微 本I張尺度適用中國國家標準(CNS ) M規格(21〇><297公釐) 310971 (請先閱讀背面之注意事項再填寫本頁)V. Description of the invention (5) Brother Yi is anaerobic in bed tanks A and r ,,,, ϋ ^ ^ B, and radon tank C, and the phosphorus can be removed from the liquid. The household goes on to describe other embodiments of the present invention. In this embodiment, the above-mentioned constant voltage section 14 is divided into constant voltage sections…, b, and 14c by τbeij in the figure, and can be converted into three voltages in three stages. A voltage conversion device 17 is also connected between aa 4 13 and each of the high-voltage portions i4a, 14b, and 14c. Therefore, even when the resistance between the electrodes 5 changes due to the aging change, as long as the voltage conversion device ㈣ is used to change the supply of the constant voltage power supply, the current flowing through the electrode $ can be maintained approximately constant. In addition, this voltage change can be implemented at the same time as regular maintenance work. However, if it is to be implemented automatically, the better method is to detect the current flowing through the electrode 5 as shown in Figure 4. For example, a current detection device 18 such as a current sensing device, and a voltage control device 19 such as a voltage control circuit that can control a voltage based on the value detected by the current detection device 18 and is composed of a microcomputer or a comparator, etc. Therefore, the detection result supplied from the current detection device 18 can be input to the voltage control device 19, so that the voltage conversion device 17 can automatically operate. The processing equipment printed by Benbesch / Bei, printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, can be effectively used for general household wastewater treatment as described above. Therefore, it can be used alone, but it can also be used with other purification systems, such as activated sludge method, membrane separation method, anaerobic, and gas-recycling method as comprehensive wastewater purification systems for domestic and collective housing. It can also be used in large-scale treatment systems (stool treatment plants). Next, the place where the present invention is used to treat water containing phosphate ions is described. The device is suitable for applying phosphorus-removed water from the treated water other than the waste ^^ above. The paper size applies Chinese National Standards (CNS)- -----— 5 310971 523494 V. Description of the invention (6 (Read the precautions on the back before filling this page) Other implementation descriptions of the chemical device. The water purification device is used to remove organisms raised in the water tank ( Tropical fish or other fish and shellfish, turtles, aquatic insects, etc.) The device for purifying the water in the water tank, as shown in Fig. 5, the water purification device is composed of the water tank 50 and the water tank 50. The upper part 51 is constituted, and the transition part 51 has a transition groove 52 located between the lower container 5U and the lid 51b as a transition part, a processing device 53 provided on the downstream side of the filter groove 52, and decoloring A decoloring tank 54 provided downstream of the processing device 53, a suction pump 55 having a filter 55a and a suction pipe 5 讣 as a transfer device, and a return pipe 56 as a return device. The processing device 53 is made up of Figures 2 and 3 Or, the processing device i shown in FIG. 4 has the same structure, and the 1 electrode 5 is installed in the electrode holder 5a and inserted into the electrode fixing plate and immersed in water. The water system flows through the population 2 formed below the processing device 53. Flow into the electrolytic treatment tank 4, if the electrode 5 is made of iron, iron ions and refractory iron ions washed out from the anode side of the electrode 5 will react with phosphate ions to form insoluble iron scaly acid. Bran Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ ... Later, the iron phosphate will be 'up' by the aeration device 7 and discharged to the decoloring tank 54 through the discharge port 3. In this embodiment, a“ voltage power supply ”is used to The Mohr ratio is set to be slightly higher, or a voltage conversion device is connected to the power supply, or the current is detected to maintain stable phosphorus removal performance. The transition tank 52 is provided with a raw material for fish and shellfish. Urine == organic matter and floating matter in water should be physically or biologically filtered. Zhangjia Standard (needle of olefin as raw material 4 6 310971 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 7 523494 A7 ------ B7____ 5 Found (7) " " 'One Family One' "-Laminated sheet-like non-woven fabrics (for example, a unit weight of 400g / m2, a thickness of 40 mm 'and a ventilation volume of 160cc / cm2 / sec) are laminated A plurality of layers are formed. The water in the water tank 50 is pumped to the filter tank 52 through the suction pipe 55b, and receives the physical filtering and biological filtering functions of the transition device 52a to capture and remove floating matter in the water. The decoloring tank 54 is used for The iron phosphate flowing out of the outlet 3 of the electrolytic treatment tank 4 after removing the floating water is provided adjacent to the electrolytic treatment tank 4, and a filter 54a for removing the iron phosphate and performing biological filtration is installed inside. The filter 54a is made up of a plurality of hollow cylinders made of polypropylene, each having a length of about 10 mm, an outer diameter of about 6 mm, and an inner diameter of about 3 mm. In addition, in the present embodiment, although the decoloring tank is provided on the lower side of the electrolytic treatment tank, the water purification device of the present invention is not limited to this, and a person without a decoloring tank may be used. Also in this embodiment, the method of arranging the filter and the trough (the filtering part) above the water tank will be described, but the filtering part may also be a filter that can perform physical filtration and / or biological filtration by being disposed in the water trough. Device. Also, this embodiment is adapted to a water purification device, but it can also be applied to a farm or aquarium purification device. [Effects of the Invention] As described above, according to the present invention, a constant voltage power supply is used, and the molar ratio is set to be slightly higher than in the past, that is, the cost of the entire device can be reduced without reducing the phosphorus removal performance. As a result, it is expected to reduce equipment costs. Furthermore, according to the present invention, instead of setting the Morse ratio slightly higher than in the past, the Chinese standard (CNS) M specification (21〇 > < 297 mm) is applicable. 310971 (Please read the notes on the back first (Fill in this page again)

523494 A7 B7 五、發明説明(8 ) 高一些之方法,而把電壓轉換裝置連接於定電壓電源的 話,即使於因時效變化致電極間之電阻有變化時,也可藉 由改變電壓使電流變化減少,而獲得穩定的除磷性能。 [圖面之簡單說明] 第1圖係表示本發明之用以處理含有磷酸離子之水之 處理裝置之一實施形態說明圖。 第2圖係第1圖之處理裝置擴大圖。 第3圖係表示定電壓電源之一實施例之電路圖。 第4圖係把電壓轉換裝置與電壓控制裝置連接於第3 圖之電源時之電路圖。 第5圖係表示本發明之用以處理含有磷酸離子之水之 處理裝置之一實施形態說明圖。 第6圖係表示以往之定電流電源之一例子之電路圖。 [符號之說明] (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 1 處理裝置 2 流入口 3 流出口 4 電解處理槽 5 電極 6 電源 7 曝氣裝置 10 散氣管 11 氣泵 12 管子 13 整流·平滑部 17 電壓轉換裝置 18 電流檢測裝置 19 電壓控制裝置523494 A7 B7 V. Description of the invention (8) A higher method, and if the voltage conversion device is connected to a constant voltage power supply, the current can be changed by changing the voltage even when the resistance between the electrodes changes due to time-dependent changes. Reduce, while obtaining stable phosphorus removal performance. [Brief description of the drawing] Fig. 1 is an explanatory diagram showing an embodiment of a treatment apparatus for treating water containing phosphate ions according to the present invention. Fig. 2 is an enlarged view of the processing device of Fig. 1; Fig. 3 is a circuit diagram showing an embodiment of a constant voltage power supply. Fig. 4 is a circuit diagram when a voltage conversion device and a voltage control device are connected to the power supply of Fig. 3. Fig. 5 is an explanatory view showing an embodiment of a treatment apparatus for treating water containing phosphate ions according to the present invention. Fig. 6 is a circuit diagram showing an example of a conventional constant current power supply. [Explanation of symbols] (Please read the precautions on the back before filling this page) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperatives 1 Processing device 2 Inlet 3 Outlet 4 Electrolytic treatment tank 5 Electrode 6 Power supply 7 Aeration device 10 Air diffuser 11 Air pump 12 Pipe 13 Rectifier / smoothing unit 17 Voltage conversion device 18 Current detection device 19 Voltage control device

本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 310971This paper size applies to China National Standard (CNS) A4 (210X297 mm) 310971

Claims (1)

523494 ^六、申請專利範圍 1. 一種用以處理含有磷酸離子之水之處理裝置,係包括 有:至少-對電極,係以至少使其一部分浸潰於電解 處理槽内的含有磷酸離子之被處理水中之方式相對著 而配置’該-對電極之至少一方為含有鐵及/或銘用 以對該電極通電之電源;以及用以曝氣上述處理槽之 曝氣裝置;其特徵為上述電源係使用定電壓電源。 2. 如申請專利範圍第i項之處理裝置,其中上述定電壓 電源由整流•平滑電路與定電壓電路構成。 頁 3. 如申請專利範圍第2項之處理裝置,其中上述定電壓 電路由三端子調節器與電容器構成。 4. 如申請專利範圍第i、2、或3項之處理裝置,其中具 備用以把供自上述定電壓電源之電壓轉換成複數種電 壓之電壓轉換裝置。 4 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 5·如申請專利範圍第4項之處理裝置,其中具備用以檢 測流通於上述電極的電流之電流檢測裝置,以及用以 根據由該電流檢測裝置所檢測之值而控制電壓之電壓 控制裝置,而予以轉換供自上述定電壓電源之電壓者。 6. —種用以處理含有磷酸離子之水之處理方法,係使用 含有鐵及/或鋁之至少一對電極以電化學方式將鐵離子 及/或鋁離子從含有磷酸離子之被處理水中洗提,使磷 酸離子以與鐵離子及/或鋁離子反應成為不溶性鹽之形 態而凝聚沈澱之處理方法,其特徵為對上述電極施加 定電壓者。 7·如申請專利範圍第6項之處理裝置,其中將上述定電 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公爱) 9 310971 523494 A8 B8 C8 D8 「、申請專利範圍 壓轉換為複數種之一定電壓者。 8 ·如申請專利範圍第7項之處理裝置,其中加以檢測流 通於上述電極之電流而轉換供自上述定電壓電源之電 壓者。 --------訂--------- (請先閱讀背面之注意事項^填寫本頁) 寫太 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 10 310971523494 ^ VI. Patent application scope 1. A treatment device for treating water containing phosphate ions, comprising: at least-a counter electrode, at least a part of which is immersed in an electrolytic treatment tank containing phosphate ions The method of treating water is relatively arranged, and at least one of the -counter electrodes is a power source containing iron and / or an inscription for energizing the electrode; and an aeration device for aerating the treatment tank; characterized in that Use a constant voltage power supply. 2. The processing device of item i in the scope of patent application, wherein the above-mentioned constant-voltage power supply is composed of a rectification / smoothing circuit and a constant-voltage circuit. Page 3. The processing device according to item 2 of the patent application range, wherein the constant voltage circuit is composed of a three-terminal regulator and a capacitor. 4. If there is a processing device in the scope of application for item i, 2, or 3, there is a voltage conversion device reserved to convert the voltage supplied from the above-mentioned constant-voltage power supply into a plurality of voltages. 4 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. If the processing device of the scope of patent application No. 4 is provided, it includes a current detection device for detecting the current flowing through the electrodes, and a device for detecting the current flowing through the current detection device. The voltage control device that controls the voltage by the detected value is converted to the voltage supplied from the above-mentioned constant voltage power supply. 6. —A treatment method for treating water containing phosphate ions, wherein at least one pair of electrodes containing iron and / or aluminum is used to electrochemically wash iron ions and / or aluminum ions from the treated water containing phosphate ions The treatment method for causing phosphate ions to condense and precipitate in the form of reacting with iron ions and / or aluminum ions into an insoluble salt is characterized in that a constant voltage is applied to the electrode. 7 · If the processing device of the scope of patent application No. 6 is adopted, the above-mentioned fixed electricity paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 public love) 9 310971 523494 A8 B8 C8 D8 " Those who convert to a plurality of certain voltages. 8 · For example, the processing device in the scope of patent application No. 7, which detects the current flowing through the electrodes and converts the voltage supplied from the constant voltage power supply. ------- -Order --------- (Please read the precautions on the back ^ Fill this page first) Write the paper printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employee Consumer Cooperatives. This paper is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 10 310 971
TW088119692A 1998-12-16 1999-11-11 Apparatus for treating the water containing phosphoric acid ions, and method therefor TW523494B (en)

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JP10357864A JP2000176456A (en) 1998-12-16 1998-12-16 Treatment device and method for phosphate ion- containing water

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JP4520053B2 (en) * 2001-01-23 2010-08-04 三洋電機株式会社 Sewage treatment equipment
JP4548955B2 (en) * 2001-03-14 2010-09-22 三洋電機株式会社 Electrolyzer for sewage treatment equipment
JP4548958B2 (en) * 2001-03-19 2010-09-22 三洋電機株式会社 Electrolytic treatment tank for sewage treatment equipment
JP3536092B2 (en) * 2001-06-11 2004-06-07 群馬大学長 Method for removing phosphorus from water to be treated using electric field
CN1872714B (en) * 2005-05-30 2010-11-03 韩群 Technique in use for engineering of water treatment by using liquid electrode to generate aluminium ion
CN102976453A (en) * 2012-12-20 2013-03-20 山东国辰环境科技有限公司 Electrolytic dephosphorization equipment
CN103601270A (en) * 2013-11-22 2014-02-26 苏州优德通力电气有限公司 Electrolysis phosphorus removal device capable of reducing anode passivation
CN103613170A (en) * 2013-11-22 2014-03-05 苏州优德通力电气有限公司 Double-aluminum-electrode electrolytic phosphorous removing device and using method thereof
KR101699233B1 (en) * 2015-03-31 2017-01-24 (주)미라클인 Power supply circuit forelectrolysis apparatus and, forelectrolysis apparatus comprising the same
KR102014323B1 (en) 2017-07-06 2019-08-26 주식회사 브리슨 Rice Polisher
CN110330081A (en) * 2019-08-01 2019-10-15 广东维清环境工程有限公司 A kind of new multipolar aluminium cell phosphorus removing method
CN111362372A (en) * 2020-04-16 2020-07-03 王招 Synchronous nitrogen and phosphorus removal system of electrochemistry

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JP3691165B2 (en) * 1996-08-08 2005-08-31 三洋電機株式会社 Sewage treatment equipment

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