TW491750B - Method and apparatus for electrochemical planarization of a workpiece - Google Patents
Method and apparatus for electrochemical planarization of a workpiece Download PDFInfo
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- TW491750B TW491750B TW90124466A TW90124466A TW491750B TW 491750 B TW491750 B TW 491750B TW 90124466 A TW90124466 A TW 90124466A TW 90124466 A TW90124466 A TW 90124466A TW 491750 B TW491750 B TW 491750B
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- 230000001680 brushing effect Effects 0.000 claims abstract description 42
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- 230000007246 mechanism Effects 0.000 claims abstract description 8
- 238000001465 metallisation Methods 0.000 claims description 7
- 230000002093 peripheral effect Effects 0.000 claims description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 238000005201 scrubbing Methods 0.000 claims description 3
- 238000013459 approach Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract 2
- 235000012431 wafers Nutrition 0.000 description 97
- 229910052751 metal Inorganic materials 0.000 description 30
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- 238000004140 cleaning Methods 0.000 description 28
- 239000004065 semiconductor Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 13
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- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 238000005530 etching Methods 0.000 description 6
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- 239000002002 slurry Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 4
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- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
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- 229910000831 Steel Inorganic materials 0.000 description 1
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
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- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
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- 238000007772 electroless plating Methods 0.000 description 1
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- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 235000012771 pancakes Nutrition 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/04—Lapping machines or devices; Accessories designed for working plane surfaces
- B24B37/046—Lapping machines or devices; Accessories designed for working plane surfaces using electric current
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H5/00—Combined machining
- B23H5/06—Electrochemical machining combined with mechanical working, e.g. grinding or honing
- B23H5/08—Electrolytic grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/04—Lapping machines or devices; Accessories designed for working plane surfaces
- B24B37/07—Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool
- B24B37/08—Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool for double side lapping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D13/00—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
- B24D13/14—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face
- B24D13/145—Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face having a brush-like working surface
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/32115—Planarisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/32115—Planarisation
- H01L21/3212—Planarisation by chemical mechanical polishing [CMP]
- H01L21/32125—Planarisation by chemical mechanical polishing [CMP] by simultaneously passing an electrical current, i.e. electrochemical mechanical polishing, e.g. ECMP
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/288—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
- H01L21/2885—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition using an external electrical current, i.e. electro-deposition
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Weting (AREA)
Abstract
Description
491750 五、發明說明(1) 本發明一般係關於半導體晶圓等工件之拋光或平整系 統,尤指具有金屬化表面的晶圓之電化平整裝置和方法。 背景 積體電路的製造,是從產生高品質半導體晶圓開始。 在晶圓製程中,晶圓要進行多次光罩、刻蝕,以及介質和 導體澱積方法。此外,半導體元件的操作關鍵在於金屬化 ,一般涉及材料,位於晶圓表面的積體電路組件接線和連 接方法及製程。典型上,積體電路的「接線」涉及在平坦 介質(絕緣·體)層蝕刻溝或渠,在溝内充填金屬。491750 V. Description of the invention (1) The present invention generally relates to a polishing or leveling system for workpieces such as semiconductor wafers, especially an electrochemical leveling device and method for wafers having a metallized surface. Background Manufacturing of integrated circuits begins with the production of high-quality semiconductor wafers. During the wafer process, the wafer is subjected to multiple masks, etching, and dielectric and conductor deposition methods. In addition, the key to the operation of semiconductor components is metallization, which generally involves materials, wiring and connection methods and processes of integrated circuit components located on the wafer surface. Typically, the "wiring" of integrated circuits involves etching trenches or trenches in a flat dielectric (insulator, body) layer and filling the trench with metal.
過去,半導體製造所用主要金屬化材料為鋁,因為使 用金會遭遇漏電和黏著問題,用銅則與矽的接觸電阻高。 其他金屬化材料包含Ni、Ta、Ti、W、Ag、Cu/Al、TaN、 TiN、CoWP、NiP和CoP。往昔,半導體業已慢慢移到使用 銅來金屬化,因為鋁顯示在合金和電移上的問題。用銅填 充時,典型上要定著其他材料的障壁層,作溝和渠之襯裡 ,以防銅移動入介質層。障壁金屬可用W、Ti、TiN、Ta、 TaN、各種合金,及其他耐火氮化物,可利用CVD、PJFD, 免電或電解質鍍著法澱積。要達成溝和渠的良好充填,在 製程中要澱積額外金屬,使金屬覆蓋溝和渠上方和外側之 晶圓面積。充填後,典型上即進行平整,除去額外金屬, 至見到介質表面。平整留下充填之溝和渠,得平坦的拋光 表面。In the past, the main metallization material used in semiconductor manufacturing was aluminum, because the use of gold encountered leakage and adhesion problems, and the use of copper has high contact resistance with silicon. Other metallization materials include Ni, Ta, Ti, W, Ag, Cu / Al, TaN, TiN, CoWP, NiP, and CoP. In the past, the semiconductor industry has slowly moved to using copper for metallization, as aluminum has shown problems with alloys and electromigration. When filling with copper, typically a barrier layer of other materials is fixed, which is used to line trenches and canals to prevent copper from moving into the dielectric layer. Barrier metals can be deposited using W, Ti, TiN, Ta, TaN, various alloys, and other refractory nitrides, and can be deposited using CVD, PJFD, electroless or electrolytic plating. To achieve good filling of trenches and trenches, additional metal is deposited during the process so that the metal covers the wafer area above and outside the trenches and trenches. After filling, it is typically flattened to remove extra metal until the surface of the medium is seen. Leveling leaves filled trenches and ditches, resulting in a flat, polished surface.
由於積體電路製造中需要高精密度,一般在半導體晶 圓的至少一側需要極其平坦表面,以確保在晶圓表面所產Due to the high precision required in the fabrication of integrated circuits, generally an extremely flat surface is required on at least one side of the semiconductor wafer, to ensure production on the wafer surface.
第6頁 491750 五、發明說明(2) 生微電子結構之適當準確性和效能。隨著積體電路尺寸繼 續減小,而積體電路上的微結構密度提高,則精 面的需要更形重要。所以,…工步驟之間,; 將晶圓表面拋光或平整,獲得盡可能最平坦的表面。 化學機械式平整(CMP)為半導體晶圓平整之習用技術 。有關化學機械式平整(CMP)製法和裝置的討論,可參見 例如Arai等人的美國專利4, 8〇5, 348號(1 989年2月發證)、 5,099,614號(1992年7月發證),]^]:151'11(1等人的美國專利 5,329,732號(1994年7月發證),Karl srud的美國專利 5,498, 196號(1996年3月發證),和Karlsrud等人的美國專 利5, 498, 1 9 9號( 1 9 9 6年3月發證)。 、 典型上CMP機包含晶圓載體,構成在晶圓拋光或平整 製程當中,可以持有、轉動、傳送晶圓。在平整操作中, 可與晶圓載體成為一體的施壓元件(例如剛板、軟殼她 等)施壓,使晶圓以所需力量與拋光表面結合。二二二= ,表面典型上以不同轉速轉動,造成拋光表面與晶圓 相對側向運動,並促進均勻平整。 一般而言,拋光表面包括水平拋光墊片,有例如氧化 鈽' 氧化鋁、發煙/沉析氧化矽或其他粒狀磨劑之暴露 面。拋光墊片可由例如技藝上已知和市上有售的各種材 形成。典型拋光墊片有吹塑聚胺酯,諸如美國亞里桑納州 司各特達里市的Rodel產品公司產銷之1(:和Gs系列拋光墊 片。拋光墊片的硬度和密度,視要拋光的材料而定。 若使用正確漿液和製程參變數,cmp有使平整作業很Page 6 491750 V. Description of the invention (2) Appropriate accuracy and efficiency of the microelectronic structure. As the size of integrated circuits continues to decrease and the density of microstructures on integrated circuits increases, the need for precision becomes more important. So, ... between the steps; Polish or flatten the wafer surface to get the flattest surface possible. Chemical mechanical planarization (CMP) is a customary technique for semiconductor wafer planarization. For a discussion of chemical mechanical levelling (CMP) manufacturing methods and devices, see, for example, U.S. Pat. No. 4,805,348 (issued February 1, 989) and 5,099,614 (1992 (Issued in July),] ^]: 151'11 (U.S. Patent No. 5,329,732, issued by 1 et al. (Issued in July 1994), U.S. Patent No. 5,498,196 by Karl srud (issued in March 1996) And US Patent No. 5,498, 199 (issued in March 1996) by Karlsrud et al., CMP machines typically include a wafer carrier, which is formed in a wafer polishing or leveling process, Can hold, rotate, and transfer wafers. In the flattening operation, pressure elements (such as rigid plates, soft shells, etc.) that are integrated with the wafer carrier can be pressed, so that the wafer is combined with the polishing surface with the required force 222 =, the surface typically rotates at different speeds, causing the polishing surface to move laterally relative to the wafer, and promoting uniform flatness. Generally speaking, the polishing surface includes horizontal polishing pads, such as hafnium oxide, alumina, Exposed surface of fumes / sedimented silica or other granular abrasives. Polishing pads can be technically Various types of materials are available on the market in Chiwa. Typical polishing pads are blow molded polyurethanes, such as 1 (: and Gs series polishing pads manufactured and sold by Rodel Products Company, Scottdale, Arizona, USA. The hardness and density of the tablet depends on the material to be polished. If the correct slurry and process parameters are used, cmp can make the leveling operation very
491750 五、發明說明(3) 好的傾向,但作業過的工件會留下應力,以致後來在金屬 層間產生龜裂和短路。此外,半導體逐漸增加使用低k介 質,有成為脆弱材料的傾向。CMP會導致此等脆弱層的剪 割和破裂。CMP也傾向在寬金屬特色的中心造成凹陷,諸 如溝和渠,金屬特色間的氧化物侵蝕,和介質之氧化物損 失。 電化平整是CMP受到矚目的變通方式,因為不會在工 件内產生應力,因而不會減少低k介質元件的完整性到 CMP可能造成的程度。此外,電化平整較不易造成凹陷、 氧化物冲#,和介質層的氧化物損失。 電化平整是基於電氣拋光和電化機製,即兼採電化溶 液和電,從基材除去金屬。第1圖表示已知技藝可得之習 知電刻蝕電池。槽1内裝有液體電解質4,一種塩的水溶液 。二電極(即陽極6和陰極8 )接線到電壓源,諸如電池組1 0 。裝置通電時,陽極6内的金屬原子被電加以離子化,進 入溶液内成為離子。視金屬和塩的化學,陽極6的金屬離 子不是鍍著於陽極8,成沉析物掉落,就是留在溶液内。 用於半導體晶圓上金屬膜之平整時,習知電化平整呈 現的優點是,不能從晶圓選擇性除去金屬。第2圖顯示介 質層12,有溝或渠,上面有金屬障壁層20。金屬層14殿積 在晶圓上的障壁層全面,充填於溝。澱積於障壁層20上後 ,金屬層1 4並非完全平坦,而是具有高地形1 6和低地形1 8 的面積。利用習知電化平整,金屬層是均勻除去,故仍有 高地形和低地形的面積。491750 V. Description of the invention (3) Good tendency, but the work piece will leave stress after work, which will cause cracks and short circuit between the metal layers later. In addition, semiconductors are increasingly using low-k dielectrics, which tends to become fragile materials. CMP can cause cutting and cracking of these fragile layers. CMP also tends to cause depressions in the center of wide metal features, such as trenches and canals, oxide erosion between metal features, and oxide loss in dielectrics. Electrochemical planarization is an attractive workaround for CMP because it does not generate stress in the workpiece and therefore does not reduce the integrity of low-k dielectric components to the extent that CMP may cause. In addition, electrochemical leveling is less likely to cause dents, oxide punches, and oxide loss in the dielectric layer. Electrochemical leveling is based on electropolishing and electrochemical mechanisms, that is, using both electrochemical solutions and electricity to remove metal from the substrate. Figure 1 shows a conventional electro-etched battery available in known art. The tank 1 contains a liquid electrolyte 4, an aqueous solution of tritium. Two electrodes (ie, anode 6 and cathode 8) are wired to a voltage source, such as a battery pack 10. When the device is energized, the metal atoms in the anode 6 are electrically ionized and enter the solution to become ions. Depending on the chemistry of the metal and plutonium, the metal ions of the anode 6 are either plated on the anode 8, falling as a precipitate, or remaining in the solution. When used for the planarization of a metal film on a semiconductor wafer, the conventional electrochemical planarization has the advantage that the metal cannot be selectively removed from the wafer. Figure 2 shows the dielectric layer 12, which has trenches or channels, and a metal barrier layer 20 thereon. The metal layer 14 is a comprehensive barrier layer on the wafer, filling the trench. After being deposited on the barrier layer 20, the metal layer 14 is not completely flat, but has an area of high terrain 16 and low terrain 18. With conventional electrochemical leveling, the metal layer is removed uniformly, so there are still areas of high terrain and low terrain.
491750 五、發明說明(4) 然而,在平整中,需要「階段性高度降低」,即選擇 性去除高地形面積的金屬層,接著均勻去除金屬層。階段 高度降低應造成只在溝和渠内留有金屬,形成平坦表面, 如第3圖所示。 由於處理設備之成本高,半導體廠商常偏好使用現有 處理設備,以進行多重功能。習知半導體處理設施中的標 準裝備,包含晶圓清理機,可把處理過的晶圓徹底清理和 淋洗,確保從晶圓除去塵屑。有關現有晶圓清理機的討論 ,可參見例如1 9·94年1 0月25日發證給Onodera的美國專利 ’ 第5, 357, 645號,和2000年1月11日發證給井上等人的美國 _ 專利第6,0 1 2,1 9 3號。需修飾或加裝晶圓清理機,俾進行 電化平整,因而降低設備成本。 籲 因此,亟需有電化平整方法和裝置,完成基材上金屬 層之階段性高度降低,隨即均勻平整金屬層。又需電化平 整技術,可加裝於現有處理設備。 發明概述 本發明上述和其他要旨,凡精於此道之士由本發明參 見附圖就較佳具體例非限制性的下述說明,即可更為明 ~ 白。 . 根據本發明具體例,具有至少一金屬化表面的工件平 整用電化平整裝置,含有第一刷洗表面,構成把緊壓於工 件的金屬化表面。裝置又含有第一驅動器總成,構成促使 工件和第一刷洗表面間之相對運動;以及第一導電元件, 籲 設在鄰接第一刷洗表面。第一電源構成在工件的金屬化表491750 V. Description of the invention (4) However, in leveling, it is necessary to “stagewise decrease”, that is, to selectively remove metal layers with a high terrain area and then uniformly remove the metal layers. The reduction in stage height should result in metal remaining in the trenches and canals to form a flat surface, as shown in Figure 3. Due to the high cost of processing equipment, semiconductor manufacturers often prefer to use existing processing equipment for multiple functions. Standard equipment in conventional semiconductor processing facilities, including wafer cleaners, thoroughly cleans and rinses processed wafers to ensure that dust is removed from the wafers. For a discussion of existing wafer cleaners, see, for example, U.S. Patent No. 5,357,645 issued to Onodera on October 25, 1994, and issued to Inoue on January 11, 2000. Human U.S. Patent No. 6,0 1 2, 1 3. The wafer cleaning machine needs to be modified or installed to perform electrochemical leveling, thereby reducing equipment costs. Therefore, there is an urgent need for an electrochemical leveling method and device to complete the stepwise reduction of the metal layer on the substrate, and then level the metal layer uniformly. It also requires electrochemical leveling technology, which can be added to existing processing equipment. Summary of the Invention The above and other gist of the present invention will be made clearer by those skilled in the art, referring to the accompanying drawings, and referring to the attached drawings for a non-limiting detailed description of the preferred embodiment. According to a specific example of the present invention, an electric leveling device for flattening a workpiece having at least one metallized surface includes a first brushing surface to constitute a metallized surface that is pressed against the workpiece. The device further includes a first driver assembly configured to promote relative movement between the workpiece and the first brushing surface; and a first conductive element is provided adjacent to the first brushing surface. The first power source constitutes a metallized watch on the workpiece
第9頁 491750 五 發明說明(5) ' --_ :ί f丨一 2 ί 70件間遂行電位差。裝置又含有μ 虛 成對第一金屬化表面供應電解ίϊΐ —溶液應 -金:ί 次一具體例,電化平整裝 才文照本發明再一具體例 繞縱軸線轉動。 按照本發明又一具體例 按照本發明又一具體例 按照本發明又一具體例 繞縱轴線轉動。 按照本發明又一具體例 按照本發明又一具體例 按照本發明又一具體例 第一刷洗表面為滾輪 又ί 2表面對面具有第二金屬化表面的工件J t對在第 •‘有ί :刷洗表®,構成緊壓於工件的第:今ΐ。裝置 摩電元件,㉟置鄰接第二刷洗表面化表面 應用,制:構成對第二金屬化表面供應巧二溶液 、照本發明另一具體例,第一刷洗表面以。 構成 第一刷洗表面打孔。 第一刷洗表面具孔隙性。 第一刷洗表面為滾輪,構成 第一刷洗表面打孔。 第一刷洗表面具孔隙性。 工件上金屬化表面之平整方 I二个设%入一具體例,工件上金屬化表面之平整 1;:$元!供=,,構成緊潘於工件金屬化表 二 ,β又置鄰接刷洗表面;把刷洗表面緊壓 於金屬=表面,並造成工件和刷洗表面間之相對運、 ί電液i金屬化表面;以及在工件金屬化表面和導 電兀件間遂仃電位差。 =二士發日月進一步之具體例,具有至少一金屬化表面 的工 弘化平整裝置,包含複數刷洗滾輪,各滾輪具有Page 9 491750 V Description of the invention (5) '--_: ί f 丨 一 2 ί The potential difference between 70 cases. The device also contains μ virtual paired first metallized surfaces to supply electrolysis. The solution should be gold. This is a specific example, and it is electroplated. According to another specific example of the present invention, it is rotated about the longitudinal axis. According to still another specific example of the present invention According to still another specific example of the present invention According to still another specific example of the present invention, it is rotated about the longitudinal axis. According to yet another specific example of the present invention, according to still another specific example of the present invention, according to still another specific example of the present invention, the first brushing surface is a roller and the second surface of the workpiece J t has a second metallized surface. Brushing the watch ® forms the first part pressed tightly against the workpiece: Imamaki. Apparatus The motor element is disposed adjacent to the second brushed surfaced surface. Application, system: It is configured to supply a second solution to the second metalized surface. According to another embodiment of the present invention, the first brushed surface is provided. The first brushing surface is perforated. The first brushed surface is porous. The first brushing surface is a roller, which constitutes the first brushing surface to be perforated. The first brushed surface is porous. The flattening side of the metallized surface on the work piece I set two% into a specific example, the flattening of the metallized surface on the work piece 1 :: $ Yuan! Supply =, constitutes a tight pan on the metallization table of the workpiece, β is placed adjacent to the brushed surface; press the brushed surface tightly against the metal = surface, and cause the relative movement between the workpiece and the brushed surface, and the electro-hydraulic metallized surface And the potential difference between the metallized surface of the workpiece and the conductive element. = A further specific example of Ershifa Sun and Moon, a flattening device with at least one metallized surface, including a plurality of scrubbing rollers, each roller having
五 —發明說明(6) _______ 導電元件和縱軸線,並各 構成使刷洗滾輪繞各縱$ ^ f壓金屬化表面。馬達總成 成在工件金屬化表面和導i ^ ^。裝置又含有供電源’構 應用機制,構成斜今属几^疋件間遂行電位差;以及溶液 圖式簡^供應電解質溶液。 同樣i:月j K參照附圖說明如下,其中同樣符號標示 ΐ ^ ί已知技藝中電刻電池之示意圖; ^圖為具有金屬層的基材之斷面圖; =3圖為具有金屬充填溝的基材之斷面圖; 第4圖為本發明ECMP裝置具體例之示意側視圖; ,5圖為本發明ECP裝置另一具體例之示意側視圖; 第6圖為本發明ECP裝置又一具體例之示意側視圖。 曼骑說明 下述只是具體例,無意對本發明範圍、應用性或構型 作任何限制。而是用來說明實施本發明具體例。所述具體 例就所述元件的功用和配置可作各種變化,不違本發明之 範圍。V. Description of the invention (6) _______ The conductive element and the longitudinal axis, and each of them constitute a brushing roller to press the metallized surface around each longitudinal $ ^ f. The motor assembly is on the metallized surface of the workpiece and guides ^ ^. The device also contains a power supply mechanism and an application mechanism, which constitutes a potential difference between several components; and a solution diagram to supply an electrolyte solution. The same i: month j K is described below with reference to the drawings, where the same symbols indicate ΐ ^ ί Schematic diagram of the electric engraved battery in the known art; ^ The picture is a cross-sectional view of a substrate with a metal layer; = 3 is a metal filling Sectional view of the substrate of the trench; FIG. 4 is a schematic side view of a specific example of the ECMP device of the present invention; FIG. 5 is a schematic side view of another specific example of the ECP device of the present invention; A schematic side view of a specific example. Man riding instructions The following are only specific examples and are not intended to limit the scope, applicability, or configuration of the invention. Instead, it is used to explain specific examples for implementing the present invention. The specific examples can be variously modified in terms of the function and arrangement of the elements without departing from the scope of the present invention.
第4圖表示本發明電化平整(ECP)裝置100具體例之示 意圖。ECP裝置30 0可採用標準清理裝置,用到「薄餅」式 刷墊。使用薄餅式刷墊的典型清理裝置,載於· 1 9 9 2年9月8 曰發證給G i 1 1的美國專利第5,1 44,7 1 1號,和1 9 9 9年2月1 6 曰發證給Chof fat等人的美國專利第5, 870, 793號,二者内 容均於此列入參玟。此種性能的清理裝置典型上是用來清Fig. 4 is a schematic view showing a specific example of an electrochemical leveling (ECP) device 100 according to the present invention. The ECP device 300 can use standard cleaning devices, using "pancake" brush pads. A typical cleaning device using wafer-type brush pads is contained in U.S. Patent Nos. 5,114,7,11 issued to Gi 11 on September 8, 1982, and 1999 US Patent No. 5,870,793 issued to Chof fat et al. On June 16th, both of which are incorporated herein by reference. This type of cleaning device is typically used for cleaning
491750 五、發明說明(7) 洗化學機械平整後的半導體晶圓,以除去留在晶圓表面的 漿液顆粒。此種平坦薄餅墊片典型上是用黏膠固定在安裝 上,而安裝板則利用螺栓、機器螺釘或其他機械式扣件, 附設於支座。f片是晶圓清理機的一部份,該機轉動安裝 板和墊片,緊罪被清理的半導體晶片之主要平坦表面。 參見第4圖’具有對立金屬化表面4〇1)和40c的晶圓4() ,以複數晶圓支座5 0支持,支座沿周緣側面4 〇 a與晶圓4 〇 接觸。裝置3 0包含二個清理構件。前二清理構件為碟形刷 具60a和60b’ η又在晶圓.40的對立面4〇b和40c,並與晶圓, 的對立面摩擦結合,加以清理。刷具6〇a和60b表面分別靠 近表面40b和40c,具有複數垂直延伸的突塊13〇。各突塊 ’ 呈圓柱形,具有暴露的平坦末端,與其他突塊暴露端實質 上共平面。刷具6 0 a和6 0 b構成繞直立軸線8 0轉動。此外, 刷具60a和60b可在箭頭B、D方向,相對於晶圓40搖動。另 外,刷具60a和6 Ob可相對於晶圓40以擺動方式運動。 第三清理構件為滾輪7〇,與晶圓4〇的周緣側面4〇3摩 擦結合’以清理此邊緣。滾輪7 〇構成繞直立軸線9 〇轉動。 雖然第4圖所示裝置只用一滾輪7〇,須知亦可使用二或以 , 上之滾輪70。另外,裝置30亦可不採用滾輪7〇,有賴刷具 6 0 a和6 0 b從側面4 0 a除去銅屑。 ' 刷具60a和6Ob及滾輪的硬度和密度,是根據要平整的 材料類別選擇。刷具可由聚乙酸乙烯酯(PVA)、聚胺醋, 或可與晶圓40摩擦結合的其他任何適當材料製成,以便對 _ 晶圓40平整,並除去銅屬。刷具6〇a和6〇b應厚到足以防止491750 V. Description of the invention (7) Wash the semiconductor wafer after chemical mechanical planarization to remove the slurry particles left on the wafer surface. This flat wafer gasket is typically fixed to the installation with adhesive, and the mounting plate is attached to the support using bolts, machine screws or other mechanical fasteners. The f-chip is a part of the wafer cleaning machine. The machine rotates the mounting plate and the gasket, which is closely related to the main flat surface of the semiconductor wafer to be cleaned. Referring to Fig. 4 ', the wafer 4 () having opposite metallized surfaces 401) and 40c is supported by a plurality of wafer holders 50, which are in contact with the wafer 4o along the peripheral side 40a. The device 30 contains two cleaning components. The first two cleaning members are dish-shaped brushes 60a and 60b 'η, which are on the opposite sides 40b and 40c of wafer 40, and frictionally combined with the opposite sides of wafer 40 to be cleaned. The surfaces of the brushes 60a and 60b are close to the surfaces 40b and 40c, respectively, and have a plurality of vertically extending protrusions 130. Each protrusion ′ is cylindrical, with exposed flat ends, and is substantially coplanar with the exposed ends of the other protrusions. The brushes 60 a and 60 b constitute a rotation about an upright axis 80. In addition, the brushes 60a and 60b can be shaken with respect to the wafer 40 in the directions of arrows B and D. In addition, the brushes 60a and 6 Ob are movable relative to the wafer 40 in a swinging manner. The third cleaning member is a roller 70, which is bonded to the peripheral side of the wafer 40 by friction of 403 to clean this edge. The roller 70 is configured to rotate around the upright axis 90. Although the device shown in FIG. 4 only uses one roller 70, it should be noted that two or more rollers 70 can also be used. In addition, the device 30 may not use a roller 70, and it is dependent on the brushes 60a and 60b to remove copper shavings from the side 40a. '' The hardness and density of the brushes 60a and 6Ob and the roller are selected according to the type of material to be flattened. The brush may be made of polyvinyl acetate (PVA), polyurethane, or any other suitable material that can be frictionally bonded to the wafer 40 to smooth the wafer 40 and remove copper. Brushes 60a and 60b should be thick enough to prevent
第12頁 491750 五、發明說明(8) 晶圓40與導電構件12〇&和12〇1)(詳後)直接接觸。此外,因 為習用刷具一般不導電,刷具60a和6〇b宜均勻打孔成且有 許多洞孔160,容許晶圓40的表面4〇b和40c與導電構件 12 0 a = 1 2 0 b間導電。另外,刷具6 〇 a和6 〇 b可具有孔隙性, 以便容許晶圓40的表面40b和40c與導電構件12〇&和12〇b間 晶圓40可利用晶圓支座50保持在靜止位置,或把晶圓 ^座50構成繞其直立軸線轉動,故在刷具6〇a和6〇b繞其軸 線8 0轉動時,晶圓4 〇同時繞軸線丨〇 〇轉動。另外,裝置3 〇 了 f 40的擺動而非轉動,把晶圓4〇平整。利用擺動把 曰曰,拋光之例,詳見1 996年9月1〇日發證給Briev〇gei等人 之美國專利5, 5 54, 064號,於此列入參玫。 化平整,裝置30亦包含導電構件i2〇w〇i2〇b 的曰曰曰圓40上下。,電構件i2〇a 可由鋼等金屬’或任何適當導電材料製。 構=120a和120b分別與晶圓40的金屬化表面 行1 ί ί ί LT150對晶圓40的表面40b和4〇c供應正電 ^對導電構件12〇a和120b供應負電荷,遂行電位差。 雖然弟4圖的具體例顯示二電壓源,但須知 差 ma和120b與晶圓40間可遂行電位差的任W 何數量均可用。 』為夭孜術之任 電解質平整溶液可利用管道i丨〇施加。另外,須知 解質平整溶液亦可經刷具6〇a和6〇b供應,、 圖上未示)和洞孔160’或利用任何適當分配以:置(電Page 12 491750 V. Description of the invention (8) The wafer 40 is in direct contact with the conductive members 12 & In addition, since the conventional brushes are generally non-conductive, the brushes 60a and 60b should be uniformly perforated with many holes 160, allowing the surfaces 40b and 40c of the wafer 40 and conductive members 12 0 a = 1 2 0 Conduction between b. In addition, the brushes 60a and 60b may have porosity so as to allow the surfaces 40b and 40c of the wafer 40 and the conductive members 120 and 120b to be held between the wafers 40 using the wafer holder 50. The rest position, or the wafer holder 50 is configured to rotate around its upright axis, so when the brushes 60a and 60b rotate around their axis 80, the wafer 400 rotates around the axis at the same time. In addition, the device 30 oscillates f 40 instead of rotating, and flattens the wafer 40. An example of polishing using a swing handle is described in U.S. Patent No. 5,5,54,064 issued to Brievogei et al. On September 10, 1996 for details. Leveling, the device 30 also includes the upper and lower circles 40 of the conductive member i20woi20b. The electrical component i20a may be made of a metal such as steel or any suitable conductive material. Structure = 120a and 120b and the metallized surface of the wafer 40, respectively. 1 LT LT150 supplies positive electricity to the surfaces 40b and 40c of the wafer 40 ^ supplies negative charges to the conductive members 12a and 120b, and then performs a potential difference. Although the concrete example of Figure 4 shows the two voltage sources, it should be noted that any number of possible potential differences between the difference ma and 120b and the wafer 40 can be used. The electrolyte leveling solution can be applied using a pipe i. In addition, it should be noted that the leveling solution can also be supplied through the brushes 60a and 60b (not shown in the figure) and the holes 160 'or using any appropriate distribution to:
第13頁 胃/50 I、I明說明(9) 等貝=整溶液可含有磷酸銨 '磷酸、硫酸銅、鈐酸、鉻酸 材料和/或添加劑,亦可為該材料和習用CMP漿液之組 S物〇 於 裝置30在操作時,刷具60a和6 Ob分別以所需力量緊壓 ^表面4 0 b和4 0 c,同時分別繞其直立軸線轉動。刷具6 〇 & 口6〇13最好以大約〇51^1或以下之壓力緊壓於表面4〇13和 〇 c ’雖則可促進平整之任何適當壓力均可用。晶圓支座 胃〇亦可繞其直立軸線轉動,使晶圓4 〇繞軸線1 〇 〇轉動。在 ,電構件120a和12 Ob與晶圓40的金屬化表面40b和40c間遂 行電位差時,即從晶圓40的表面40a、40b、40c釋出金屬 離子,以致金屬從晶圓脫鍍。Page 13 Stomach / 50 I, I state (9) The shellfish solution can contain ammonium phosphate 'phosphoric acid, copper sulfate, osmic acid, chromic acid materials and / or additives, and can also be used for this material and conventional CMP slurry. In group S, when the device 30 is in operation, the brushes 60a and 6 Ob are pressed against the surfaces 40b and 40c with the required force, respectively, while rotating around their upright axes respectively. The brush 6 0 & port 6 0 13 is preferably pressed against the surface 4 0 13 and 0 c ′ at a pressure of about 0 51 ^ 1 or less, although any suitable pressure that can promote flattening can be used. Wafer holder Stomach 〇 can also rotate around its upright axis, so that the wafer 400 can rotate around the axis 100. When the electrical component 120a and 12 Ob and the metallized surface 40b and 40c of the wafer 40 have a potential difference, metal ions are released from the surfaces 40a, 40b, and 40c of the wafer 40, so that the metal is deplated from the wafer.
平整完成後’從金屬化表面遺留的金屬和剩餘的暴露 障壁層2 0,如第2圖所示,可利用標準蝕刻法,諸如濕刻 '蒸刻、喷刻、電漿刻,或化學機械式平整除去,因為晶 圓表面已剛好經本發明實質上平整過。蝕刻方法和化學之 k擇’視障壁層化學而定。 雖然在上述具體例中,晶圓4 0兩側4 0 b和4 0 c的金屬化 表面被實質上除去,但須知裝置3 0可經修飾,使電化平整 只對晶圓之一表面進行。例如,晶圓4 0可利用習用轉動平 枱支持在側面40c,即可選擇性在側面40b進行電化平整。After leveling is completed, the metal left from the metallized surface and the remaining exposed barrier layer 20, as shown in Figure 2, can be etched using standard etching methods such as wet etching, steam etching, plasma etching, or chemical mechanical The flat surface is removed because the wafer surface has just been substantially flattened by the present invention. The choice of etching method and chemistry depends on the chemistry of the barrier layer. Although in the above specific example, the metallized surfaces of 40 b and 40 c on both sides of the wafer 40 are substantially removed, it should be noted that the device 30 may be modified so that the electrochemical planarization is performed on only one surface of the wafer. For example, the wafer 40 can be supported on the side surface 40c by a conventional rotating platform, and can be electrified and flattened on the side surface 40b selectively.
本發明ECP裝置之優點是,同時電化蝕刻和機械清洗 晶圓,先從高地形面積除去金屬化表面,隨即均勻蝕刻和 平整。本發明電化蝕刻方面可在低壓得高除去率,減少凹 陷和氧化物冲蝕。又一優點是,由於標準洗濯裝置可加裝The advantage of the ECP device of the present invention is that the wafer is electrochemically etched and mechanically cleaned at the same time, the metallized surface is removed from the high terrain area first, and then uniformly etched and leveled. The electrochemical etching of the present invention can achieve a high removal rate at low pressure, and reduce pitting and oxide erosion. Another advantage is that the standard washing unit can be retrofitted
第14頁 491750 五、發明說明(10) 來進行ECP,故不需購買專用ECP機,因而減少額外的設備 成本。 參見第5圖,本發明ECP裝置的變通具體例2〇〇,可用 刷具滾輪把兩面具有金屬化表面的晶圓平整。有關栋闲、、食 輪的清理裝置之討論,可參見^㈣年丨丨月?曰發有證關給使用滚Page 14 491750 V. Description of the invention (10) To perform ECP, there is no need to purchase a dedicated ECP machine, thus reducing additional equipment costs. Referring to FIG. 5, a modified specific example 200 of the ECP device of the present invention can use a brush roller to flatten a wafer having metallized surfaces on both sides. For discussions on the cleaning devices of the building idlers and eaters, please refer to ^ ㈣ 年 丨 丨 月? Issued a license to use the roll
Shurtliff的美國專利第5, 9 75, 094號,其内容於此列入參 玫。 具有對立金屬化表面2 1 0 b和2 1 0 c的晶圓2 1 0,利用沿 周緣側面210a與晶圓210接觸的複數晶圓支座220支持。裝 置2 0 0含有三個清理構件。前二清理構件為刷具滾輪2 4 〇 a 和2 4 0 b,設置鄰接晶圓2 1 0的金屬化表面2 1 〇 b和2 1 〇 c,並 可與晶圓2 1 0兩側摩擦結合,加以清理。刷具滾輪2 4 〇 a和 2 401)宜實質上圓柱形,構成繞個別縱軸線25〇&和25〇1)轉動 ,並平移運動跨越晶圓210表面。刷具滾輪240a和240b可 由I乙fee乙烤S曰(PVA)、聚胺醋或任何適當材料製成。此 外,刷具滾輪2 4 0 a和2 4 0 b宜均勻打孔成具有複數洞孔3 2 〇 ,容許晶圓210的表面210b和210c與導電構件260a和260b 間導電’詳後。另外’刷具滚輪2 4 0 a和2 4 0 b可具有孔隙性 ,以便讓晶圓210的表面21 Ob和210c與導電構件2 6 0a和 2 6 Ob間導電。第三清理構件為滾輪270,可與晶圓21〇的周 緣側面2 1 0 a摩擦結合,以清理此邊緣。滾輪2 7 〇構成繞直 立軸線2 8 0轉動。雖然第5圖所示裝置只用一滾輪2 7 〇,但 亦可用二或以上的滾輪270。另外,裝置2 00可不採用滾^輪 2 7 0,而依賴刷具滾輪240a和240b從側面21〇a除去銅屬。Shurtliff U.S. Patent No. 5,9 75,094, the contents of which are incorporated herein by reference. The wafer 2 1 0 having opposite metallized surfaces 2 1 0 b and 2 1 0 c is supported by a plurality of wafer holders 220 in contact with the wafer 210 along the peripheral side surface 210 a. The device 200 contains three cleaning components. The first two cleaning members are brush rollers 2 4 0a and 2 4 0 b, and metallized surfaces 2 1 0b and 2 1 0c adjacent to the wafer 2 10 are provided, and can be rubbed with both sides of the wafer 2 10 Combine and clean it up. The brush rollers 2 400a and 2401) should be substantially cylindrical, constituting rotations about the respective longitudinal axes 25 ° and 2601), and a translational movement across the surface of the wafer 210. The brush rollers 240a and 240b may be made of PVA, PVA, polyurethane, or any suitable material. In addition, the brush rollers 2 40 a and 2 0 0b should be uniformly perforated to have a plurality of holes 3 2 0, allowing the surfaces 210b and 210c of the wafer 210 to conduct electricity between the conductive members 260a and 260b. In addition, the brush rollers 2 4 0 a and 2 4 0 b may have porosity so as to allow conduction between the surfaces 21 Ob and 210c of the wafer 210 and the conductive members 2 6 0a and 2 6 Ob. The third cleaning member is a roller 270, which can be frictionally combined with the peripheral side 21a of the wafer 21 to clean this edge. The roller 270 is configured to rotate about the upright axis 280. Although the device shown in FIG. 5 uses only one roller 270, two or more rollers 270 may be used. In addition, the device 200 may not use the roller 270, but relies on the brush rollers 240a and 240b to remove copper from the side 21a.
第15頁 五、發明說明(11) 晶圓210可利用晶圓支座22 0保持在靜止位置, ^ 20構成繞其直立軸線轉動,在刷具滾輪24〇&和在 ,、軸線2 5 0a和2 50b轉動時,使晶圓繞軸線29〇轉動。 為進行電化平整,各刷具滾輪24〇&和24〇b含有導電構 件,分別為導電構件26 0a和260b。導電構件2 6 0a和260b分 別位在刷具滾輪24〇a和240b内,延伸於刷具滾輪24〇a和 240b之大約全長。利用電壓源3〇〇和31〇對晶圓表面以“和 210〇施以正電荷,對導電構件26〇&和26〇1)施以負電荷,而 在導電構件260a和260b與晶圓2.10的金屬化表面21〇b和 2 1 0 c之間’遂行電位差。雖然第5圖所示具體例具有二電 壓源’但在導電構件2 6 0a和2 6 0b與晶圓210間遂行電位差 所用任何習知技術之任何數量均可採用。含有電解質溶液 或與習用CMP漿液組合的電解質溶液之電解質平整溶液, 均可透過刷具滾輪2 4 0 a和2 4 0 b和洞孔3 2 0,或利用任何適 “刀配7〇件供應。 裝置2 00在操作時,刷具滾輪240a和240b分別緊壓於 表面2 1 0 b和2 1 0 c,同時繞其個別縱軸線轉動。晶圓支座 2 2 0亦可繞其直立軸線轉動,使晶圓2丨〇繞軸線2 9 〇轉動。 電解質平整溶液供應至晶圓210的二表面210b和210c。在 導電構件260 a和260b與晶圓的金屬化表面210b和210c間遂 行電位差時,金屬離子即從晶圓2 1 〇的側面2 1 0 a、2 1 0 b、 210c釋出’以致金屬化表面從晶圓脫鍍。 雖然第5圖所示本發明具體例,是採用位於晶圓2 1 0對 立表面2 1 0 b和2 1 0 c的二刷具滾輪,同時對該表面加以電化Page 15 V. Description of the invention (11) The wafer 210 can be held in a static position by using the wafer support 22 0, and ^ 20 constitutes rotation about its upright axis, the brush roller 24 0 &, the axis 2 5 When 0a and 2 50b are rotated, the wafer is rotated around the axis 290. For galvanic smoothing, each brush roller 24o & 24b contains a conductive member, which is a conductive member 260a and 260b, respectively. The conductive members 26a and 260b are located in the brush rollers 24a and 240b, respectively, and extend approximately the entire length of the brush rollers 24a and 240b. A voltage source of 300 and 31 was used to apply a positive charge to the surface of the wafer with "and 2100", and a negative charge was applied to the conductive members 26 and 261), while the conductive members 260a and 260b and the wafer 2.10 metallized surface 21ob and 2 1 0 c 'successive potential difference. Although the specific example shown in Figure 5 has two voltage sources', the conductive potential difference between the conductive members 2 6 0a and 2 6 0b and the wafer 210 Any number of conventional techniques can be used. The electrolyte leveling solution containing the electrolyte solution or the electrolyte solution combined with the conventional CMP slurry can pass through the brush rollers 2 4 0 a and 2 4 0 b and the holes 3 2 0 , Or use any suitable "knife with 70 pieces of supply. When the device 200 is in operation, the brush rollers 240a and 240b are pressed against the surfaces 2 1 0 b and 2 1 0 c, respectively, while rotating around their respective longitudinal axes. The wafer support 220 can also be rotated around its upright axis, so that the wafer 2 is rotated around the axis 290. The electrolyte leveling solution is supplied to both surfaces 210b and 210c of the wafer 210. When a potential difference is established between the conductive members 260 a and 260 b and the metallized surfaces 210 b and 210 c of the wafer, metal ions are released from the sides 2 1 0 a, 2 1 0 b, 210c of the wafer 2 ′, resulting in metallization. The surface is stripped from the wafer. Although a specific example of the present invention is shown in FIG. 5, two brush rollers located on the opposite surfaces 2 1 0 b and 2 1 0 c of the wafer are used, and the surface is electrified at the same time.
第16頁 491750 五、發明說明(12) 平整,惟須知本發明亦可採用唯一滾輪刷具,對晶圓之一 表面加以平整。另外,在晶圓之一表面可有複數 ,對該表面加以平整。 第6圖表示本發明又一具體例,為具有至少一金屬化 表面的晶圓之電化平整,構成清理站4〇〇。清理站4〇〇可設 在處理或清理半導體晶圓(或其他工件)之較大型機哭内, 如1 9 9 9年9月14日發證給Peters〇n等人的美國專利w 5, 9 5 0, 32 7號所載,其全部内容於此列入參玫。清理站4〇〇 宜包括容器,例如淨洗箱,容納複數對刷具滾輪。清理站 40 0包括底板412、頂板414、側板410、後板(圖上未示)和 前板(圖上未示)。因此,諸板包括自容箱,需要更換一或 以上刷具滾輪時,使用手柄42〇即可快速而容易除去和更 換。 清理站400包括複數對刷具滚輪,構成驅動晶圓,通 過淨洗箱,同時把通過其間的晶圓頂部和/或底部平坦表 面同時電化平整。如第6圖所示,清理站4〇〇宜 口 416,構成把晶圓接受入容器有-圓 2驅動滚輪(詳後)即「抓住」晶圓,向前饋送ΛΛ 滾輪。 4 清理站4 0 〇可有任何备吾μ 見,第6圖只顯示成對滾輪,雖然為方便起 中,淨洗箱包含第、一對刷且\輪之清理站。在圖示具體例 •篦-對、、衰輪 ^ α ^ ” /袞輪,包括個別滾輪430和432 ,弟一 W /农輪,包括h刷呈、、呑 四對滚輪,包括Ιϊίί輪if 434和下刷具滾輪440;第 刷八滚輪442和下刷具滚輪444;第五對Page 16 491750 V. Description of the invention (12) Leveling, but it must be understood that the present invention can also use a single roller brush to level one surface of the wafer. In addition, there may be a plurality of on one surface of the wafer, and the surface is flattened. FIG. 6 shows still another specific example of the present invention, which is for electrochemically planarizing a wafer having at least one metallized surface, and constitutes a cleaning station 400. The cleaning station 400 can be set in a larger machine that processes or cleans semiconductor wafers (or other workpieces), such as US Patent w 5, issued to Peterson et al. On September 14, 1999. The full contents of 9 5 0, 32 7 are included here. The cleaning station 400 should include a container, such as a cleaning tank, containing a plurality of pairs of brush rollers. The cleaning station 400 includes a bottom plate 412, a top plate 414, a side plate 410, a rear plate (not shown in the figure), and a front plate (not shown in the figure). Therefore, the plates include a self-contained box, and when one or more brush rollers need to be replaced, the handle 42 can be quickly and easily removed and replaced. The cleaning station 400 includes a plurality of pairs of brush rollers, which constitute a driving wafer, and pass through the cleaning box, while simultaneously flattening the flat surface of the top and / or bottom of the wafer passing therethrough. As shown in Fig. 6, the cleaning station 400 is 416, which constitutes a wafer-receiving-in-a-round 2 driving roller (detailed later), that is, "grasping" the wafer and feeding the ΛΛ roller forward. 4 Cleaning station 4 0 〇 There can be any preparations. Figure 6 only shows the pair of rollers, although for convenience, the cleaning box contains the cleaning station for the first and the second brushes and wheels. Specific examples in the illustration • 篦 -pair, 、 衰 α ^ ”/ 衮 wheels, including individual rollers 430 and 432, Di Yi W / agricultural wheels, including h brush show, 呑 four pairs of rollers, including Ιϊίί wheel if 434 and lower brush roller 440; eighth brush roller 442 and lower brush roller 444; fifth pair
491750 五、發明說明(13) _ 滾輪’包括上刷具滾輪446和下刷具滾輪44 終端滾輪,包括上刷具滾輪45〇和下刷’ 第六對 4⑽,成晶圓從遠左方進入,隨即被逼經站輪^52。/理站 置(取近滾輪450和452)離站。 您右方位 m ^ η奇數對滾輪(即第一對滾輪430, 432、第-粗 438,440、第五對滾輪446,448),宜且 第二對滾輪 ,各對驅動滾輪以驅動速度s〗操 /、 動滾輪的功能 432, 438, 440, 446, 448即以驅動速卢 ^,刷具滾輪430, 輪,即滾輪432,436,440,444“81^=2。底部刷具滾 如圖所示。此外,各偶數刷,安鉍2j嗔時鐘方向轉動, 442, 450 ’亦順時鐘方向刷^滾輪的頂部刷具滾輪434, 部滾輪430, 438, 446,宜反睡接取後’各奇數對滾輪的頂 各偶數對滾輪(例如第二、$向轉動。 理速度S2操作。各奇數對滾一'曰弟四、第六對)宜構成以處 未示)驅動,使晶圓以基本上取好以第一驅動馬達(圖上 4〇〇。各偶數對滾輪最好被,句速率被驅動通過清理站 以此方式,操作者可藉設定邀一達以處理速度S 2驅動。 ’控制驅動速度S1,亦可^ 第一馬達關聯之第一控制器 制器,單獨控制處理速度s"2呆第二馬達關聯之第二控 S1和S2,可在清理站4〇〇^内 =操作者動態構成個別速度 雖然上述滾輪速度如第 =上適應性。 内可以實際上採用任何數 圖所示,須知在本發明脈絡 向之任意組合。例如,可以p 1以及滾輪速度和滾輪方 速度,選擇速度和方向 二^一、三或甚至更多的滾輪 的各種排列叙合,以達成所需用途491750 V. Description of the invention (13) _ Roller 'including upper brush roller 446 and lower brush roller 44 terminal roller, including upper brush roller 45 and lower brush' 6th pair 4⑽, wafers enter from far left , Then was forced to pass the station round ^ 52. / Manage the station (take rollers 450 and 452) to leave the station. Your right bearing m ^ η odd number of rollers (that is, the first pair of rollers 430, 432, the first-thickness 438,440, and the fifth pair of rollers 446,448), and the second pair of rollers, each pair of driving rollers at the driving speed s〗 The function of the moving roller 432, 438, 440, 446, 448 is the driving speed ^, the brush roller 430, the wheel, that is, the roller 432,436,440,444 "81 ^ = 2. The bottom brush roller is shown in the figure. In addition, each even brush , Bismuth 2j 转动 clockwise rotation, 442, 450 'also brush clockwise ^ roller top brush roller 434, roller 430, 438, 446, it should be reversed to pick up' each odd number of the top of the roller even number The rollers (for example, the second and the $ directions are rotated. The operation speed is S2. The odd pairs of rollers (the fourth and sixth pairs) should be formed (not shown)), so that the wafer is basically taken first and the first Drive motor (400 on the picture. Each even-numbered pair of wheels is best driven and the sentence rate is driven through the cleaning station. In this way, the operator can set the drive to drive at the processing speed S2. 'Control the drive speed S1, also ^ The first controller associated with the first motor can control the processing speed independently. The second controls S1 and S2 associated with the two motors can be set up individually within the cleaning station 4 00 ^ = operator dynamics although the above-mentioned wheel speed is as described above. The actual number can be used as shown in any figure. Any combination of directions in the context of the present invention. For example, you can select various arrangements of the speed and direction of two, one, three, or even more rollers to achieve the desired use.
第18頁 491750Page 18 491750
五、發明說明(14) 之最適效益。 各偶數對刷具滾輪434, 436, 442, 444, 450, 452,分別 含有導電構件454, 456, 458, 460, 46 2, 464。導電構件454, $ 5 6」=8,4 6 0,4 6 2,4 6 4位於其内,延伸於個別刷具滾輪之 幾乎全長。刷具滾輪434, 436, 442, 444, 45〇, 452可由聚乙 酸乙烯酯(PV A )、聚胺酯或任何其他適當材料製成。此外 垂刷具滾輪最好是均勻打孔,使導電構件和晶圓間可以導 ,二另=,此等刷具滚輪亦可具孔隙性,使導電構件和晶 0可以導電。5. Description of invention (14). Each even-numbered pair of brush rollers 434, 436, 442, 444, 450, 452 contains conductive members 454, 456, 458, 460, 46 2, 464, respectively. The conductive member 454, $ 5 6 ″ = 8, 4 6 0, 4 6 2, 4 6 4 is located in it, and extends over almost the entire length of the individual brush roller. The brush rollers 434, 436, 442, 444, 45, 452 may be made of polyvinyl acetate (PV A), polyurethane, or any other suitable material. In addition, the vertical brush rollers are preferably uniformly perforated, so that the conductive member and the wafer can be guided. Secondly, these brush rollers can also have porosity, so that the conductive member and the crystal can be conductive.
# ^ 了Ϊ板4 1 4還可包含一或以上流體進口(圖上未示),構 配至清理站40 0内側的分開部位或整體。頂板 理二ί t總官(圖上未示),配置成把流體輸送至清 平敕位置。例如,頂板414可包括輸送電解1 ί m: ί:總管,輸送習用漿液的第二岐管,和輸3 ^ =的第二總管。各單獨總管構成與其他總管不通 ϊ二f 2,一 ΐ以上流體進口可聯結在一起,使單〆流$ i:η ,:以上。總管可構成把流體分佈至相鄰刷^ -曰圓 :S之間。此項配置容許流體在通過清理站1 ϊ = ^。4理站400亦可包含流體出口(圖上未示),在平 -^ ^ ψ η π ^ 電解貝/谷液可經此通過。可視需要, 體出口收回的電解質溶液再循環、丟棄或按需要處# ^ ΪΪ 4 1 4 may also contain one or more fluid inlets (not shown in the figure), configured to separate parts or the whole inside the cleaning station 400. The top panel governor (not shown in the figure) is configured to deliver fluid to the Qingping site. For example, the top plate 414 may include an electrolysis 1 lm: ί: a main pipe, a second manifold for conveying conventional slurry, and a second main pipe for conveying 3 ^ =. Each of the individual headers is not connected to other headers. Two f 2, one or more fluid inlets can be connected together to make a single stream $ i: η,: or more. The manifold can be configured to distribute fluid between adjacent brushes ^-said circle: S. This configuration allows fluid to pass through the cleaning station 1 ϊ = ^. The 4 station 400 may also include a fluid outlet (not shown in the figure), and the electrolysis shell / valley fluid can pass through in the flat-^ ^ ψ η π ^. Recycling, discarding or disposing of the electrolyte solution withdrawn from the body outlet as needed
第19頁 491750 五、發明說明(15) 分佈至滾輪,在刷具滾輪的導電構件和晶圓間遂行電位差 。晶圓被刷具滾輪434, 436, 442,444, 450, 454推動時,金 屬離子即從金屬化表面釋出,以致金屬化表面脫鍍。晶圓 與刷具滾輪接觸時,進一步被刷具滾輪以及平整溶液内的 任何磨粒之研磨作用所平整。結果,金屬化表面的高地形 面積即被除去,然後進行均勻蝕刻和平整。 雖然本發明已參照附圖說明如上,惟須知本發明不限 於此。上述組件以及使用本發明裝置所述步驟可有各種修 飾和配置,不違本發明在所附申請專利範圍内規定之精神 和範圍。Page 19 491750 V. Description of the invention (15) Distributed to the roller, the potential difference is established between the conductive member of the brush roller and the wafer. When the wafer is pushed by the brush rollers 434, 436, 442, 444, 450, 454, metal ions are released from the metallized surface, and the metallized surface is deplated. When the wafer is in contact with the brush roller, it is further smoothed by the abrasive action of the brush roller and any abrasive particles in the leveling solution. As a result, the high terrain area of the metallized surface is removed, and then uniformly etched and leveled. Although the present invention has been described above with reference to the accompanying drawings, it should be understood that the present invention is not limited thereto. The above-mentioned components and the steps described using the device of the present invention may have various modifications and configurations without departing from the spirit and scope of the present invention within the scope of the appended patent application.
第20頁 491750 圖式簡單說明 第1圖為已知技藝中電刻電池之示意圖; 第2圖為具有金屬層的基材之斷面圖; 第3圖為具有金屬充填溝的基材之斷面圖; 第4圖為本發明ECMP裝置具體例之示意側視圖; 第5圖為本發明ECP裝置另一具體例之示意側視圖 第6圖為本發明ECP裝置又一具體例之示意側視圖Page 491750 Brief description of the drawings. Figure 1 is a schematic diagram of an electric engraved battery in a known technology. Figure 2 is a sectional view of a substrate with a metal layer. Figure 3 is a fragment of a substrate with a metal filling groove. Figure 4 is a schematic side view of a specific example of an ECMP device of the present invention; Figure 5 is a schematic side view of another specific example of an ECP device of the present invention; Figure 6 is a schematic side view of another specific example of an ECP device of the present invention
第21頁Page 21
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US4140598A (en) * | 1976-06-03 | 1979-02-20 | Hitachi Shipbuilding & Engineering Co., Ltd. | Mirror finishing |
WO1998028101A1 (en) * | 1996-12-20 | 1998-07-02 | Unique Technology International Private Limited | Texturing and electro-deburring of magnetic disk substrate |
JPH10321572A (en) * | 1997-05-15 | 1998-12-04 | Toshiba Corp | Both-surface cleaning apparatus for semiconductor wafer and polishing method for semiconductor wafer |
JPH1158205A (en) * | 1997-08-25 | 1999-03-02 | Unique Technol Internatl Pte Ltd | Electrolytic polishing as well as polishing texture processing device and manufacture thereof and electrolytic polishing as well as polishing texture tapeused thereto |
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2001
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