470774 A7 Έ7 五、發明説明（1 ) 螢明之領域 C請先閲讀背面之注意事項再填寫本頁) 本發明係關於^香科之粒子。更特別地，其係關於香料 粒子，其在加入奇容積密度粒狀清潔㈣，可給予清潔劑 粉末艮好（香味’在凊洗時建立最希望之香味，及在清洗 後給予衣物最希望之餘留香味。 贅明之背景 為了掩飾清潔劑組合物之固有臭味及給多清潔劑與被清 洗之衣物香味，而將香料加入清潔劑組合物，已成爲實 務。然而’在清洗時非常難以建立最希望之香味，及在清 洗後給予衣物最希望之餘留香味。因此，已進行許多努力 以發展滿足這些需求之香料。 近年來，由節省資源之觀點，例如，在清潔劑產物之運 輸及被消費者輸送與儲存之方便性，引起對於濃縮清潔劑 之全球性趨勢。 經濟部中央標準局員工消費合作社印製 比較習知低密度清潔劑（即，通常爲具有約〇3克/立方 公分t容積比重者），高密度粒狀濃縮清潔劑（在此使用之 名詞"高密度"表示具有0.5克/立方公分或更高容積比重 者）含大量之有效成份（例如，界面活性劑等）並且具有高 密度’以降低在單次清洗操作所需之量（重量與體積）（例 如’由40克/30公升降低至25克/30公升）。在此高密度粒 狀濃縮清潔劑以用於習知低密度清潔劑之相同比例加入香 料時’香料成份對清洗水與被清洗衣物之比例随用於單次 清洗操作之清潔劑量之降低而降低。結果，引起在清洗時 僅建立不足香味及在清洗後給予衣物不良殘留香味之問 *· 4 - 不，，悚尺及通用中國國家標準（CNS )以麟（21Q><297公餐） 470774 Α7 Έ7 經濟部中央梯準局員工消費合作社印製 粒 五、發明説明（2 題0 雖然似乎此缺點可僅藉由提高清潔劑中香料成份之含量 而克服，在此情形仍引起另一個問題，粉狀清潔劑之香味 本質變成太濃，因此而令人不悦。 本發明人以前已發現上述問題可藉由使用包含具有指定 蒸氣壓之香料成份之香料组合物而解決，而且此發現揭示 於JP-A-63-101496專利（在此使用之名詞"JP_A)"表示，，未檢 驗公告日本專利申請案"）β然而，此香料組合物包含指定 之香料，其在香料之組合限制自由度。本發明人已進—步 揭示一種方法以將香料包括於如JP_A_M93397專利之ρ产 糊精之含有物化合物中《然而，含有物化合物相當昂貴。 此外，JP-A-57-171910專利已揭示包含親水性物質作爲 主要成份之芳香粒子，而JP-A-5-209189專利已揭示包本： 水性無機載體粒子作爲主要成份之芳香粒子。缺工 "" 么、咐，這此 專利在上述問题之解答均未成功。 — 發明之概要 本發明之目的爲提供香料粒子，其在加入高容積密度护 狀清潔劑時，可給予清潔劑良好之香味，在清洗時建—θ 希望之香味，並且在清洗後給予衣物最希望之殘留香味 在這些情況下，本發明人已進行廣泛之研究以建上 持 清潔劑组合物之香味，清洗浴之香味與衣物中殘留香味' 方法。結果，已成功地發現這些目的可藉由乾燥混人々 指定之陰離子性界面活性劑作爲主要成份之香料粒子與 狀清潔劑組合物而達成，如此完成本發明。 -5- 本紙張尺度適用中國國家標準（CNS ) Α4規格（21〇'〆297公釐） -----II----^-------11·------.#-- (請先聞讀背面之注意事項再填寫本頁} 470774 經濟部中央標準局員工消費合作社印¾ ,A7 B7 五、發明説明（3 ) —-- 因此，本發明提供一種乾燥混合粒狀清潔劑組合物之香 料粒子組合物，其含以下成份⑷、（b) '⑻、（d)與（e): (a) 1至12重量％之香料成分； (b) 40至94重量％之式①代表之陰離子性界面活性劑·· ROS03Na (I) 其中R表示源自具有6至20個碳原子之第一或第二醇之 線形或分支烷基或烯基； (c) 3至30重量％之含結晶水之不溶性固體粒子，其平均 粒度爲20微米或更小； (d) l至10重量％之水溶性聚合物，成份⑻對成份⑷之 重量比例[(b) : (d)]爲5 : 1至50 : 1 ;及 (e) 0.1至1 〇重量％之水。 發明之詳細説明 〈成分（a) > 較佳爲用於本發明之香料成分⑷特別含至少—種選自 包括以下化合物（1)至（9)之化合物： (1) 分子中具有至少一個雙键（_c=c_)之烴·· 例如，I，8-二烯萜、檸檬油精、^卟對室二烯、.苹 烯、β-苹烯等； (2) 遂： 例如，脂族酸，如癸趁、-j--酸、十二酸、甲基壬基乙 趁、十一烯酸等； 菫烯醛，如檸檬醛、羥基香茅醛、香茅醛等； 芳族醛，如苯甲醛、己基桂皮醛、鈐藍醛、向日花香 搭、香草醛、乙基香草醛等；及 -6 - 本紙張尺度適财_家標準（CNS) M規格（2丨GX297錢) (請先閱讀背面之注意事項再填寫本頁) 、τ ---------------- ^ 經濟部中央標準局貝工消費合作社印製 7 7 ο 7 4 A7 B7 __^-—------ 五、發明説明（4) 其他如新铃藍醛、米拉（mylac)醛等； (3) 酯： 例如，甲酸苄酯 '甲酸沈香酯、乙酸香茅酯、乙酸沈香 酯、乙酸異壬酯、乙酸香葉草酯、乙酸蓋埽酯、乙酸異获 酯、6酸三環癸烯酯 '乙酸苄酯、乙酸苯基乙醋，乙酸安 息香烯丙酯、乙酸桂皮酯、乙酸己酯、乙醯基丁香紛、乙 醯基異丁香酚、乙酸雪松酯、o-t-B.C.H.A.等； (4) 内酯： 例如，γ_辛内酯、γ-壬内酯、σ-癸内酯、薰草素等； (5) 酚衍生物： 例如，丁香酚、異丁香酚、瑞香酚等； (6) 分子中具有至少一個雙键（-C=C-)之醇： 例如，檀香腦、尼納醇（ninalol)、香葉草醇、香茅醋、 二羥基月桂油醇等； (7) 分子中具有至少一個雙键（_C=C-)之醚： 例如，橙花醇氧化物、玫瑰油氧化物、沈香醇氧化物 等； (8) 分子中具有至少一個雙键g〇c-)之酮： 例如，紫香酮、甲基紫香酮、二氫大馬酮、黑種草酮 (damascenone)、大納嗣（dynascone)、麥芽嗣等；及 (9) 含氮或硫之有機化合物： 例如，Η卜朵、糞臭素、辛特里（cintronellyl)猜，香葉草腈 等 不用説’可一起使用上列以外之香料化合物 姆尺度適用中國國家標準、釐） ------絮------、11------鵷 (請先閱讀背面之注意事項再填寫本頁) 〈化合物〇；) > 用於本發明之陰離子性界面活性劑爲式（1)表示之化合物 R-OS〇3Na ⑴ 其中R表示源自具有6至2〇個碳原子之第一或第二醇之 線形或分支烷基或烯基； 弋（I)表示之陰離子性界面活性劑可藉已知方法以硫酸醋 化具有6至20個碳原子之第—或第二醇，然後以削狀水 溶液中和之，*如與水之混合物制^在本發明較佳爲， 如此得到之陰離子性界面活性劑與水之混合物含不超過ι〇 重水。在本發明中，較佳爲使用藉喷灑乾燥、在低 壓下之膜乾造等得到之粉末κ針形式之陰離子性界面 活性劑與水之混合物作爲起始物質。 最希k用於本發明之陰離子性界面活性劑爲藉硫酸酯化 具有6至18個碳原子之烷基或烯基之第一醇，而且在中和 後具有5或更低之碘價者。此陰離子性界面活性劑之實例 包括癸基硫酸鈉、月桂硫酸鈉、肉豆蔻硫酸鈉、鯨蠟硫酸 鈉、硬脂硫酸鈉及其混合物。 經濟部中央標準局員工消費合作社印製 在硫酸化之步驟，反應比例通常無法達到1〇〇% ^因 此’仍有未反應之醇。用於本發明之陰離子性界面活性劑 可能被未反應之醇污染，只要其維持藉一般方法得到之比 例（即’基於陰離子性界面活性劑爲約〗0重量％)。 〈成分> 用於本發明之具有結晶水之水不溶性固體粒子具有20微 米或更小’較佳爲0.1至10微米之平均粒度。在平均粒度 ______ _ - 8 - 本紙張尺度適用巾國"^^率（CNS) ( 210X297公瘦）470774 A7 Έ7 V. Description of the invention (1) Field of fluorescent light C Please read the notes on the back before filling out this page) The present invention is about the particles of fragrantaceae. More specifically, it is about perfume particles, which, when added with a bulk cleaning granule with an odd bulk density, can give a detergent powder (scent 'to create the most desirable fragrance when washing, and to give clothing the most desirable after washing Fragrance is left behind. In order to disguise the inherent odor of the detergent composition and to scent multiple detergents and the clothes being washed, it has become a practice to add perfume to the detergent composition. However, 'it is very difficult to establish during cleaning The most desired fragrance, and the most desired residual fragrance given to clothes after washing. Therefore, many efforts have been made to develop fragrances that meet these needs. In recent years, from the perspective of resource conservation, for example, in the transportation of detergent products and The convenience of being transported and stored by consumers has led to a global trend for concentrated detergents. The Central Consumers Bureau of the Ministry of Economic Affairs prints more familiar low-density detergents (ie, usually with a density of about 0.3 g / cm3). t volume specific gravity), high-density granular concentrated detergent (the term used herein " high density " means 0.5g / Those with a cubic centimeter or higher volume content) contain a large amount of active ingredients (eg, surfactants, etc.) and have a high density 'to reduce the amount (weight and volume) required in a single cleaning operation (eg' from 40 g / 30 liters reduced to 25 g / 30 liters). Here the high-density granular concentrated detergent is added at the same ratio as used in conventional low-density detergents. The cleaning dose of a single cleaning operation is reduced. As a result, the problem is that only insufficient fragrance is created during cleaning and bad residual fragrance is given to clothes after cleaning. * · 4-No, Ghost Ruler and Common Chinese National Standard (CNS) Yilin (21Q > < 297 Public Meal) 470774 Α7 Έ7 Printed granules by the Consumer Cooperatives of the Central Government Bureau of the Ministry of Economic Affairs. 5. Description of the invention (2 Question 0 Although it seems that this disadvantage can only be achieved by increasing the content of perfume ingredients in detergents. However, in order to overcome this situation, another problem is still caused, and the fragrance of the powdered detergent becomes too strong in nature, which is unpleasant. The present inventors have previously discovered that the above problems can be solved by making The fragrance composition containing a fragrance ingredient having a specified vapor pressure was resolved, and the discovery was disclosed in the JP-A-63-101496 patent (the term used herein " JP_A) " indicating that the Japanese patent application was not inspected and published ") β However, this fragrance composition contains a specified fragrance, which restricts the degree of freedom in the combination of fragrances. The present inventors have further disclosed a method for including fragrances in a dextrin-containing substance such as JP_A_M93397 patent Among the compounds, however, the contained compounds are quite expensive. In addition, the JP-A-57-171910 patent has disclosed aromatic particles containing a hydrophilic substance as a main component, and the JP-A-5-209189 patent has disclosed a wrapper: water-based inorganic Carrier particles are aromatic particles whose main component is. Absence of work " " Well, command, these patents failed to answer the above questions. — Summary of the invention The object of the present invention is to provide perfume particles, which can give a good scent to the detergent when a high bulk density protective cleaning agent is added, and to build a θ desired scent when washing, and give clothing the most after washing. Desired residual fragrance Under these circumstances, the present inventors have conducted extensive research to establish a method of holding the fragrance of the detergent composition, the fragrance of the washing bath, and the residual fragrance in the clothes. As a result, it has been successfully found that these objects can be achieved by drying the perfume particle and detergent composition with the mixed anionic surfactant as the main ingredient, thus completing the present invention. -5- This paper size applies to China National Standard (CNS) Α4 specification (21〇'〆297 mm) ----- II ---- ^ ------- 11 · ------ . #-(Please read the notes on the back before filling out this page} 470774 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, A7 B7 V. Description of the Invention (3) --- Therefore, the present invention provides a dry mix Fragrance particle composition of granular detergent composition, which contains the following ingredients ⑷, (b) '⑻, (d), and (e): (a) 1 to 12% by weight of fragrance ingredients; (b) 40 to 94 Anionic surfactants represented by the formula ① by weight: ROS03Na (I) where R represents a linear or branched alkyl or alkenyl group derived from a first or second alcohol having 6 to 20 carbon atoms; (c) 3 to 30% by weight of crystalline water-containing insoluble solid particles, the average particle size of which is 20 microns or less; (d) 1 to 10% by weight of water-soluble polymer, weight ratio of component ⑻ to component [[(b) : (d)] is 5: 1 to 50: 1; and (e) 0.1 to 10% by weight of water. Detailed description of the invention <ingredient (a) > The fragrance ingredient used in the present invention is particularly preferred. Contains at least-selected from the package Compounds of the following compounds (1) to (9): (1) Hydrocarbons having at least one double bond (_c = c_) in the molecule .. For example, I, 8-diene terpenes, lemon olein, peptone (2) Sodium: For example, aliphatic acids, such as decanoic acid, -j--acid, dodecanoic acid, methylnonylethene, undecylenic acid, etc .; Pinenal, such as citral, hydroxycitronellal, citronellal, etc .; aromatic aldehydes, such as benzaldehyde, hexyl cinnamaldehyde, sialaldehyde, sunflower, vanillin, ethyl vanillin, etc .; and- 6-This paper is suitable for financial standards _ Home Standard (CNS) M specifications (2 丨 GX297 money) (Please read the precautions on the back before filling this page), τ -------------- -^ Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 7 7 ο 7 4 A7 B7 __ ^ ----------- 5. Description of the invention (4) Others such as neobell blue aldehyde, mylac Aldehydes, etc .; (3) Ester: For example, benzyl formate, citronella formate, citronella acetate, linal acetate, isononyl acetate, geranyl acetate, capsidyl acetate, isoacyl acetate, 6 acid Tricyclodecenyl 'benzyl acetate, phenyl ethyl acetate, acetic acid Allyl Benzoate, Cinnamate Acetate, Hexyl Acetate, Ethyl Eugenol, Ethyl Isoeugenol, Cedar Acetate, otB.CHA, etc .; (4) Lactones: For example, γ-caprylide, γ -Nononolactone, σ-decanolactone, humulin, etc .; (5) phenol derivatives: for example, eugenol, isoeugenol, eugenol, etc .; (6) at least one double bond in the molecule (-C = C-) alcohols: for example, sandalwood, ninalol, geraniol, lemongrass vinegar, dihydroxylauryl alcohol, etc .; (7) at least one double bond in the molecule (_C = C- ): For example, nerol oxide, rose oil oxide, agarol oxide, etc .; (8) Ketones with at least one double bond in the molecule: goc-): For example, shiverone, methyl violet Ketones, dihydrodamascenone, damascenone, dynascone, maltodon, etc .; and (9) organic compounds containing nitrogen or sulfur: for example, ibudol, skatole, Cintronellyl guessed that geranyl nitrile, etc. needless to say, can be used together with the fragrance compounds other than those listed above. The standard of China is applicable.) ------ Sugar ----- -, 11 ------ 鹓 (Please read the notes on the back before filling this page) <Compound 0;) > The anionic surfactant used in the present invention is the compound R- represented by formula (1) OS〇3Na ⑴ wherein R represents a linear or branched alkyl or alkenyl group derived from a first or second alcohol having 6 to 20 carbon atoms; an anionic surfactant represented by 弋 (I) can be obtained by a known method The first or second alcohol having 6 to 20 carbon atoms is vinegarized with sulfuric acid, and then neutralized with a shaved aqueous solution. * If prepared with a mixture of water ^ It is preferred in the present invention, the anionic interfacial activity thus obtained The mixture of agent and water contains no more than ι0 heavy water. In the present invention, it is preferred to use a mixture of an anionic surfactant in the form of a powder κ needle and water obtained by spray drying, film drying under low pressure, or the like as a starting material. The most preferred anionic surfactant used in the present invention is the first alcohol having an alkyl or alkenyl group having 6 to 18 carbon atoms by sulfuric acid, and having an iodine value of 5 or less after neutralization . Examples of this anionic surfactant include sodium decyl sulfate, sodium lauryl sulfate, sodium myristate, sodium cetyl sulfate, sodium stearate, and mixtures thereof. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs In the sulfurization step, the reaction ratio usually cannot reach 100% ^ Therefore, there is still unreacted alcohol. The anionic surfactant used in the present invention may be contaminated with unreacted alcohol, as long as it maintains the ratio obtained by a general method (i.e., about 0% by weight based on the anionic surfactant). <Ingredients> The water-insoluble solid particles with crystal water used in the present invention have an average particle size of 20 m or less', preferably 0.1 to 10 m. The average particle size ______ _-8-This paper size applies to the country " ^^ 率 (CNS) (210X297 male thin)
發明説明（ 經濟部中央標準局貝工消費合作社印裝 超過20微米時，這些粒子在實際清洗操作中有時被認爲是 不溶物質。作爲水不溶性固體粒子，較佳爲使用下式表示 而且通常稱爲"沸石4A "之結晶鋁矽酸鹽：Description of the invention (When the print of the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs exceeds 20 microns, these particles are sometimes considered as insoluble substances in actual cleaning operations. As water-insoluble solid particles, it is preferably expressed by the following formula and usually A crystalline aluminosilicate called " zeolite 4A ":
Na2〇 · Al2〇3 · nSi〇2 * WH2O 其中N爲1.3至3.0 ;及 w爲絕對正數。 <成份（d)> 用於本發明之水落性聚合物之實例包括聚丙晞酸、聚乙 二醇、丙烯酸/順丁烯二酸共聚物、澱粉、纖維素、聚（乙 ‘希基吡咯哫酮）及其混合物，其各具有3,〇⑽至丨⑽之平 均为子量。最希望用於本發明之水溶性聚合物爲聚丙晞 鉍、聚乙二醇、丙烯酸/順丁烯二酸共聚物、與聚（乙晞基 吡略啶酮）。 本發明香料組合物中之香料成分⑻之含量爲【至12重量 %。在其含量落在此範圍内時，可給予香料粒子組合物足 夠I香味，而且香料粒子組合物具有高流動性.，如此得到 良好之處理特徵。 本發明组合物中陰離子性界面活性劑⑼之含量爲4〇至 94重量％，較佳爲60至94重量％。在其含量落在此範圍内 時，可得到安定之香料粒子組合物。 本發明組合物中具有結晶水之水不溶性固體粒子⑷之 含量爲3至30重量％。在其含量落在此範圍内時，可良好 地支持香料成份，而香料粒子组合物具有高流動性，如此 得到良好之處理特徵。此外，在此範圍内，香料粒子組合 -9- 木紙張尺度適用中國國家標準（CNS ) Α4^Τ7ϊ^ΐ97公釐) ------------驾------t------扃 (請先閲讀背面之注意事項再填寫本頁) ^/0774五 、發明説明（ A7 Ϊ7 物非常溶解並且在清洗步驟中給予希望之香味。 。本發明组合物中水溶性聚合物（d)之含量爲1至1〇重量 /〇在其含量落在此範圍内時，可支持香料成份之強度， 而且防止组合物之不欲之汽化。此外，即使在傲存後亦得 到高香味安定力β 在本發明中，陰離子性界面活性劑（b)對水溶性聚合物 ⑷之重量比例[即，（b):(d)]爲5:1至50:1。在此範内， 可支持香科粒子組合物之強度，而且得到其高流動性。 本發明組合物中水（e)之含量爲01至10重量％。在水含 量落在此範圍内時’香味由於儲存之散逸可減少，並且抑 制香味品質之改變。 在本發明之香料粒子組合物可進—步含已知之染料、顏 料、螢光染料與無機鹽，如芒硝（Na2S〇4 . 1〇H2〇)、亞硫酸 鈉、鈉鹼灰、三聚磷酸鈉與矽酸鈉。較佳爲，鹼金屬碳酸 鹽或驗金屬硬酸鹽之含量不超過5重量％。鹼金屬碳酸鹽 或鹼金屬矽酸鹽之加成有時造成香味之退化。 此外，希望如下所指示將染料或顏料加入本發明之香料 經濟部中央操準局員工消費合作社印製 粒予组合物，以在滲合粒狀清潔劑組合物時改良其外觀。 <染料> C.I.酸性紅 52 (C.I. 45110); 例如，紅色106號。 C.I.酸性藍 9 (C.I. 42090); 例如，藍色1號。 C.I.酸性黃 3 (C.I. 47005); _______- 10- i紙張尺度適用中國國家標牟（CNS) A4規格（2丨ox29i^y 五 、發明説明（8 Λ7 B7 經濟部中央標準局員工消費合作社印製 例如，黃色203號。 <顏料> C.1·顏料綠 7 (C.I. 74260); 例如，Lionol 綠 FB。 C‘L 顏料藍 15 (C.I. 74160); 例如，氰藍BR。 本發明之香料粒子组合物較佳爲具有1〇〇至3 〇〇() μιη， 更佳爲300 1^00 μιη之粒度。在其粒度小於以上指示之下 限時，對於體積之過大表面積造成香料之散逸。另一方 面在粒度超過上限時，粒子之不良溶解度難以使香料順 利釋放。 人本發明之香料粒子组合物乾燥混合粉狀或粒狀清潔劑組 合物。至於清潔劑組合物，可使用包含已知成份者。此清 潔劑组合物其中可事先含香料成份。本發明之香料粒子組 合物以0.1至50重量％之量含於最終之清潔劑組合物。至 於粒狀清潔劑组合物，可適當地使用具有高容積密度之組 合物。在纟發明香料粒子組合物之加成後之最終容積密度 調整至0.6至1.2克/立方公分。 發明之效杲 藉由乾躁混合本發明之香料粒子组合物與粒狀清潔劑組 合物，可給予粒狀清潔劑組合物良好之香味，纟清洗時建 立最希望之香味，及在清洗後給予衣物最希望之餘留香 味。此外，含本發明香料粒子组合物之粒狀清潔劑組合物 即使在儲存後亦具有高香味安定力。 -11- 本紙張尺度適用中國國家標準（CNS ) Α4規格（2l〇x29^y (請先閱讀背面之注意事項再填寫本瓦) -59 470774 A 7 B7 五、發明説明（9 ) 實例 爲了進一步以詳細及非限制之方式描述本發明，給予以 下之實例。 實例（I)與（II)、比較例⑴與（II): (1)香料粒子組合物 藉由使用以下之香料成份（1)與表2所示之成份製備香料 粒子组合物。 I. ί ! I H 1 ί^恭 I n . 、11." (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準扃貝工消費合作社印製 -12- 本紙張尺度適用中國國家標準（CNS_) A4規格（210X29?公釐） 470774 A 7 B7 五、發明説明（10 ) <香料成份（i)> 重量％ 經濟部中央標準局員工消費合作社印製 1，8-二婦帖 18.0 辛特里腈 0.5 壬醛 0.2 甲基壬基乙醛 0.1 大納酮 0.1 紫丁香醛 0.1 乙酸己酯 2.0 o-t-B. 0. Η. A. 2.0 苯基乙醇 4.0 己基桂皮醛 10.0 新铃藍酸 10.0 铃藍醒' 10.0 乙酸苄酯 10.0 水揚酸爷酉旨 15.0 沔卜朵 5.0 薰草素 1.0 乙基香草醛 5.0 曱基紫香酮 2.0 向曰花香越· 5.0 總共100.0 現在參考實例（I)敘述香料粒子组合物之製法實例。 375公斤之月桂醯酸鈉（花王公司製造之"Emal 10 與75 -13- 本紙張尺度適用中國國家標隼（CNS ) A4規格（210Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) 470774Na2O.Al2O3.nSi02 * WH2O where N is 1.3 to 3.0; and w is an absolute positive number. < ingredient (d) > Examples of the water-falling polymer used in the present invention include polyacrylic acid, polyethylene glycol, acrylic acid / maleic acid copolymer, starch, cellulose, poly (ethyl'hexyl) Pyrrolidone) and mixtures thereof, each having an average amount of 3,0⑽ to ⑽⑽. The most desirable water-soluble polymers for use in the present invention are polypropylene bismuth, polyethylene glycol, acrylic acid / maleic acid copolymers, and poly (ethylpyrrolidone). The content of the fragrance ingredient ⑻ in the fragrance composition of the present invention is [to 12% by weight. When the content falls within this range, the fragrance particle composition can be given a sufficient I fragrance, and the fragrance particle composition has high fluidity, thus obtaining good processing characteristics. The content of the anionic surfactant ⑼ in the composition of the present invention is 40 to 94% by weight, preferably 60 to 94% by weight. When the content falls within this range, a stable perfume particle composition can be obtained. The content of the water-insoluble solid particles 具有 having crystal water in the composition of the present invention is 3 to 30% by weight. When the content falls within this range, the fragrance ingredients are well supported, and the fragrance particle composition has high fluidity, thus obtaining good processing characteristics. In addition, within this range, the fragrance particle combination-9- wood paper scale is applicable to the Chinese National Standard (CNS) Α4 ^ Τ7ϊ ^ ΐ97mm) ------------ Driving ------ t ------ 扃 (Please read the precautions on the back before filling this page) ^ / 0774 V. Description of the invention (A7 Ϊ7 The substance is very soluble and gives the desired scent in the cleaning step. In the composition of the present invention The content of the water-soluble polymer (d) is 1 to 10 wt./w. When the content falls within this range, it can support the strength of the fragrance ingredients and prevent the unwanted vaporization of the composition. In addition, even in Auronic A high fragrance stability β is also obtained later. In the present invention, the weight ratio [that is, (b) :( d)] of the anionic surfactant (b) to the water-soluble polymer ⑷ is 5: 1 to 50: 1. Within this range, the strength of the Xiangke particle composition can be supported and its high fluidity can be obtained. The content of water (e) in the composition of the present invention is from 01 to 10% by weight. When the water content falls within this range ' Fragrance can be reduced due to storage, and changes in flavor quality can be suppressed. The perfume particle composition of the present invention can further include known dyes Materials, pigments, fluorescent dyes and inorganic salts, such as thenardite (Na2S04.10H2O), sodium sulfite, sodium alkali ash, sodium tripolyphosphate and sodium silicate. Preferably, alkali metal carbonate or metal test The content of stearic acid salt does not exceed 5% by weight. The addition of alkali metal carbonate or alkali metal silicate sometimes causes the deterioration of fragrance. In addition, it is desirable to add dyes or pigments to the central operation of the fragrance economy of the present invention as indicated below. Prospective employees consume cooperatives to print granules to the composition to improve the appearance of the granular detergent composition. ≪ Dye > CI Acid Red 52 (CI 45110); For example, Red No. 106. CI Acid Blue 9 (CI 42090); For example, blue 1. CI acid yellow 3 (CI 47005); _______- 10- i Paper size applies to China National Standards (CNS) A4 specifications (2 丨 ox29i ^ y V. Description of the invention ( 8 Λ7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, for example, Yellow 203. < Pigment > C.1 · Pigment Green 7 (CI 74260); For example, Lionol Green FB. C'L Pigment Blue 15 (CI 74160); for example, Cyan Blue BR. The perfume particle combination of the present invention The material preferably has a particle size of 100 to 300 () μm, more preferably 300 1 ^ 00 μm. When the particle size is less than the lower limit indicated above, the excessive surface area of the volume causes the fragrance to escape. When the particle size exceeds the upper limit, the poor solubility of the particles makes it difficult for the fragrance to be released smoothly. The fragrance particle composition of the present invention is dry-mixed with a powdery or granular detergent composition. As for the detergent composition, those containing known ingredients can be used. The detergent composition may contain perfume ingredients in advance. The perfume particle composition of the present invention is contained in the final detergent composition in an amount of 0.1 to 50% by weight. As for the granular detergent composition, a composition having a high bulk density can be suitably used. The final bulk density after the addition of the perfume particle composition of the invention is adjusted to 0.6 to 1.2 g / cm3. Effect of the invention: By mixing the perfume particle composition and the granular detergent composition of the present invention dryly, the granular detergent composition can be given a good fragrance, and the most desirable fragrance is established during cleaning, and is given after cleaning The most hopeful fragrance of clothes. In addition, the granular detergent composition containing the fragrance particle composition of the present invention has high fragrance stability even after storage. -11- The size of this paper applies Chinese National Standard (CNS) A4 specification (2l0x29 ^ y (please read the precautions on the back before filling in this tile) -59 470774 A 7 B7 V. Description of the invention (9) The present invention is described in a detailed and non-limiting manner, and the following examples are given: Examples (I) and (II), Comparative Examples ⑴ and (II): (1) Perfume particle composition by using the following perfume ingredients (1) Prepare the perfume particle composition with the ingredients shown in Table 2. I. ί! IH 1 ί ^ I n., 11. " (Please read the precautions on the back before filling this page) Central Standard of the Ministry of Economic Affairs Printed by Consumer Cooperatives -12- This paper size applies Chinese National Standard (CNS_) A4 specification (210X29? Mm) 470774 A 7 B7 V. Description of the invention (10) < Spice ingredients (i) > Weight% Central Ministry of Economic Affairs Printed by the Bureau of Consumers of the Standards Bureau 1,8-Di-Women 18.0 Cintrinitrile 0.5 Nonanal 0.2 Methyl Nonylacetaldehyde 0.1 Dananone 0.1 Syringal 0.1 Hexyl Acetate 2.0 otB. 0. A. 2.0 Phenylethanol 4.0 Hexyl cinnamaldehyde 10.0 Neobelling acid 10.0 10.0 Benzyl acetate 10.0 Salicylic acid 15.0 Phosphoric acid 5.0 Evanillin 1.0 Ethyl vanillin 5.0 Acetyl violet ketone 2.0 Xianghua Xiangyue · 5.0 Total 100.0 Now referring to Example (I), the perfume particle composition will be described An example of the production method. 375 kg of sodium lauryl sulfate (" Emal 10 and 75 -13 made by Kao Corporation) This paper size applies to China National Standard (CNS) A4 (210 × 297 mm) (please read the note on the back first) (Fill in this page again) 470774
經濟部中央標準局員工消費合作社印製 公斤之沸石4A進料至Tokuju R-型帶混合器R-1300型（總容 量：2.000公升，進料容量：13〇〇公升，以下稱爲"混合器 11)。在20 rpm混合30分鐘後，25公斤之香料成份⑴倒入混 合器中。混合15分鐘後，1〇公斤之聚乙二醇（平均分予 量：6,000 )與15公斤之水，其已混合在一起並且在60 °C溶 化，倒入混合器中繼而混合另外15分鐘。如此得到之粉末 藉擠製器（順向擠製器，網度：1.0毫米）擠製及以修整機 (冨士粉末公司製造之"FL_2〇〇型"，網度：側面3 〇毫米， 底邵4_0毫米）修整而粒化，此外，這些粒子通過5〇〇 篩 並且取殘留於篩上的作爲樣品。 以相同之方法製備實例（Η)及比較例⑴與（π)之组合物， 但是”其他成份"與成份（b)同時進料至混合器中。 (2)粉狀合成清潔劑a 爲了評估表2所示之本發明產物，以以下之方法製備粉 狀清潔劑组合物（粉狀合成清潔劑A )。粉狀合成清潔劑之 組合物示於表1。 藉由使用1.0公斤之沸石、4.0公斤之LAS、0.3公斤之 AE、0.5公斤之AA-MA共聚物（丙烯酸/順丁烯二酸共聚 物）、0.15公斤之羧基甲基纖維素、〇·〗公斤之fa、1_0公斤 之妙酸鈉JIS 2號、0.5公斤之鈉絵·灰與0.05公斤之螢光染 料，得到水性漿料（固體含量：60%)。其次，噴灑乾燥而 且如此得到之粒子進料至Loedige混合器中（Matsuzaka Giken 製造）。此外，加入1·〇公斤之沸石4A、0.5公斤之鈉鹼 灰' 0.1公斤之酶與其餘使用之芒硝（Na2S04 . 10Η20)。在 ____ - 14 - · 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） " I.丨.]1_!----裝------訂------立 (請先閎讀背面之注意事項再填寫本頁} 470774 A7 B7 經濟部令央標準局負工消費合作社印製 五、發明説明（12 ) 混合下將0.2公斤加熱至7〇。(：之AE逐漸倒入、f & a 成*中 而粒化。進一步加入〇·25公斤之沸石4A後，進〜、 繼 延行粒化並且 排除未通過1410微米篩之粒子。如此得到高密度粒狀清潔 劑組合物（平均粒度：450微米，容積密度：750克/公 升）。 表1 成份（重量％、 粉妝会成清潔劑A LAS 40.0 FA 1.0 AE 5.0 沸石4A 22.5 矽酸鈉JIS 2號 10.0 鈉驗灰 10.0 AA-MA共聚物 5.0 螢光染料 0.5 酶 1.0 羧基甲基纖維素 1.5 芒硝（Na，S04.1〇Η?0) 其餘 總共（％) 100.0 *1LAS ··線形烷基(C12)苯磺酸之Na鹽。 *2FA :牛油脂肪酸Na鹽。 *3 AE :聚氧化乙烯第一十二醚（HLB=13.1) *4AA-MA共聚物：SokalanCP5 (BASF 製造） -15- 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ί 1.! J----裝------訂------一旅 (請先閲讀背面之注意事項再填寫本頁) 470774 A7 ΊΒ7 五、發明説明（13 ) *5勞光染料：4,4'-雙- (2-硫苯乙晞基）聯苯鹽。 *6 酶：API-21H (Showa Denko 公司製造）、Lipolase 100T (Novo Nordisc公司製造）、Celluzyme 0.1T (Novo —Nordisc公 司製造）、Termamyl 60T (Novo Nordisc 公司製造）以 2 : 1 : 1 : 1之混合物。 *7罗至基甲基纖維素：Shikoku化學公司製造之KMC-II。 *8芒硝：以調整全部成份至1〇〇%之量使用。 (3) 含香料粒子之粉狀清潔劑 在以上（2)得到之粉狀合成清潔劑a加入5重量％之以上 (1)得到之香料粒子組合物，因而給予含香料粒子之粉狀 清潔劑。 (4) 性能之評估 關於以上得到之含香料粒子之粉狀清潔劑，由對香味具 有高敏感性之小组評估在儲存之前與之後之香味變化。使 用尚儲存前之粉狀清潔劑及在4〇 °C儲存30天後者，對粒子 之強度與喜好及在以下條件下實行之清洗操作時之香味強 度進行評估。結果示於表2。 經 中 A 榇 準 h Ά 工 消 費 a h 衽 印 (請先閱讀背面之注意事項再填寫本頁) <清洗操作之條件> 在雙盆型洗衣機中引入1_5公斤之衣物與3〇公升之水。 然後加入25克含香料粒子之粉狀清潔劑之樣品（在儲存之 前或之後）。攪拌15分鐘後’衣物整批浸濕2次繼而評估。 爲了比較，香料以給予如各實例之相同香料组合物之方 式噴灑於粉狀清潔劑（不含香料粒子）上。對於如此得到之 各粉狀清潔劑，製備在40 °C儲存30天之前或之後之樣品。 氏張尺度適用中關家標準（CNS )八4聽_ ( 21Qx297M ) 470774 經濟部中央標準局員工消費合作社印製 A7 ______ B7 _ 五、發明説明（14)^ 一 — ^ 藉由使用這些比較例，在以上指定之條件下實行清洗操 作，以提供香科變化之標準。 <清洗時香味之評估> 1 :在以上條件下攪拌1分鐘後之清洗水之香味強度。 ii :在以上條件下攪拌15分鐘後之清洗水之香味強 度。 111 :在以上條件下攪拌15分鐘，清洗及脱水後之衣物 之香味強度。 上述各步驟⑴至㈣之香味強度比較比較性樣品，並且 依照以下之標準評估。 4:遠比比較性強之香味。 3 :比比較性強之香味。 2 :稍微比比較性強之香味。 1 :可與比較比擬之香味強度。 <粉末香咮之評估> 1 :稍微比比較性強之香味。 0 :可與比較性比擬之香味強度。 1 ·稍微比比較性弱之香味。 A ··比比較性較佳之香味。 B :可與比較性比擬之香味。 C ·未比比較性較佳之香味。 Γ紙張尺度適 —— - i „ .I壤------、τ-------·"· i%4閑讀背面之注意事項再填寫本頁) 470774 經濟部中央標準局員工消費合作社印製 A7 ________B7 五、發明説明（U) 表2 實例(X) 實例(π) 比較例(Ώ ί速例0) 香料粒子組合物 成份(a) 香料成份(i) 5%香料成分(i) 8%香料成份(丨）5%香料成分(0 8% 成份(b) 月挂硫酸鈉75%月桂硫酸鈉64%月桂硫酸鈉30%月桂硫酸鈉20% 成份(c) 沸石4An 15% 沸石 4A” 20% 沸石 4A*1 50% 成份⑹ 聚乙二醇*2 2%丙烯酸/順丁晞二聚(乙烯基吡咯啶丙烯酸/順丁烯二 成份(e) 水 酸共聚物” 3%酮10%酸共聚物*3 15% 3% 水 2.9% 水 5% 水 2〇% 其他 月桂醇 2% 碳酸鈉 37% 著色劑A45 0.1% (請先閱讀背面之注意事項再填寫本頁) -18- 本紙張尺度適财關家( eNS ) ( 210X297公笼~7 470774 A7 B7 五、發明説明（l6) 經濟部中央標準局員工消費合作社印象 表 2(ϋΊ 清洗時香味 儲存前1 實例(I) IBS) 比較例ω 比較例(I 評估(i) 1 1 1 1 評估(ii) 3 3 1 1 評估(iii) 儲存後： 3 3 1 1 評估(i) 3 3 2 1 評估(ii) 4 4 2 1 評估(iii) 粉末香味 4 4 2 1 儲存前 -1Λ _1，A -1，Α -Ι,Α 儲存後 〇,A 〇，A 1，Β -i，c (註） Η沸石：平均粒度=4 μιη *2聚乙二醇：平均分子量=6〇〇〇。 *3丙缔酸/順丁埽二酸共聚物：s— cj>5 (basf製造）。 *4聚（乙烯基吡咯啶酮）：平均分子量=3〇〇〇〇。 *5著色劑A : Lmol綠FB [ C.I,顏料綠7號，（c丄74260)]。 實例ijj.D與J1Y1、比較例: 藉由使用實例（I)製備之香料成份（i)，以如實例（I)之 同方法製備表4所示之香料粒子組合物。然後5重量％之j 組合物加入藉以下方法製備之粉狀合成清潔劑B以給予< ____ -19- ( CNS ) ( 210X297^ ) -------------絜-------、1Ί------J. (請先閱讀背面之注意事項再填寫本頁) 470774 Α7 Β7 經濟部中央標準局貝工消費合作社印製 五、發明説明（Π) 香料粒子之粉狀清潔劑，其然後以如實例⑴之相同方法評 估。結果示於表4。 <粉狀合成清潔劑B > 爲了評估表4所示之本發明產物，以以下之方法製備粉 狀清潔劑組合物（粉狀合成清潔劑A)。粉狀合成清潔劑b 之組合物示於表3。 藉由使用1.5公斤之三聚磷酸鈉、4〇公斤之laS、〇 3公 斤之AE、0· 1公斤之AA-MA共聚物（丙烯酸/順丁缔二酸共 聚物）、0.05公斤之羧基甲基纖維素、〇丨公斤之fa、ί ο公 斤之矽酸鈉JIS 2號、0.2公斤之鈉鹼灰與0 〇5公斤之螢光染 料，得到水性漿料（固體含量：50%)。其次，喷灑乾燥而 且如此得到之粒子進料至Loe(jige混合器中（Matsuzaka Giken 製造）。此外，加人1.0公斤之沸石4A、〇 5公斤之鈉鹼 灰、〇.1公斤之酶與其餘使用之芒硝（Na2S〇4 ·10 h2〇)。在 混合下將0 _ 2公斤加熱至7 〇 ΐ之AE逐漸倒入這些成份中繼 而粒化。進一步加入〇.25公斤之沸石4八後，進行粒化並且 排除未通過1410微米篩之粒子。如此得到高密度粒狀清潔 劑紅合物（平均粒度：400微米，容積密度7〇〇克/公升）。 這些成份各用於實例（I)相同。 _ -20- 本纸張尺度適用中國國家椁準（CNS ) Α4規格（210 X 297公釐） -----I ----— 裝------1Τ------J (請先閱讀背面之注意事項再填寫本頁) 470774 A7 F7 經濟部中央標準局員工消費合作社印製 發明説明（I8) 成份（重量％) 表3 粉狀合成清潔 LAS 40.0 FA 1.0 AE 5.0 滞石4A ' 12.5 三聚攝酸鈉 15.0 矽酸鈉JIS 2號 10.0 納驗灰 7.0 AA-MA共聚物 1.0 螢光染料 0.5 酶 1.0 羧基甲基纖維素 1.5 芒硝（Na2S04 · 10H20) 其餘 總共（％) 100.0 •21- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 470774 A7 E7 經濟部中央標準局員工消費合作社印製 五、發明説明（l9 ) 表4 實例(ΠΏ 實例(IV) 比較例(ΠΟ 比較例(IV) 香料粒子組合物 成份(a) 香料成份(i) .5%香料成分(i) 8%香料成份(i) 5%香料成分(i) 8% 成份(b) 月桂硫酸鈉75%月桂硫酸鈉64%月桂硫酸鈉30%月桂硫酸釣20% 成份(C) 沸石4A*·1 15% 沸石4A*1 20%沸石4An 50% 成份(d) 丙烯酸/順丁烯二聚(乙烯基吡咯啶聚丙烯酸~ 丙烯酸/順丁烯二 酸共聚物η 2% 酮)*3 3% 10% 酸共聚物^ 15% 成份(e) 水 2.9% 水 5% 水 22% 其他 水 3%月桂醇 2% 三聚磷酸鈉35% 著色劑B” 0.1% (請先閱讀背面之注意事項再填寫本頁} ( CNS V ( 210X297^t ) 470774 A7 B7 五、發明説明（20 )表4(續）The Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed kilograms of zeolite 4A to feed Tokuju R-type with mixer R-1300 (total capacity: 2.000 liters, feed capacity: 13,000 liters, hereinafter referred to as " mixing器 11). After mixing for 30 minutes at 20 rpm, 25 kg of perfume ingredients were poured into the mixer. After 15 minutes of mixing, 10 kg of polyethylene glycol (average portion dose: 6,000) and 15 kg of water, which have been mixed together and dissolved at 60 ° C, are poured into a mixer and mixed for another 15 minutes. The powder obtained in this way was extruded by an extruder (forward extruder, mesh size: 1.0 mm) and extruded with a trimmer ("FL_2〇〇 型" manufactured by 冨 士 粉 公司), mesh size: 30 mm on the side, The bottom is 4_0 millimeters) trimmed and granulated. In addition, these particles passed through a 500 sieve and a sample remaining on the sieve was taken. The compositions of Examples (i) and Comparative examples (i) and (π) were prepared in the same way, but "other ingredients" were simultaneously fed into the mixer with ingredient (b). (2) Powdery synthetic detergent a The product of the present invention shown in Table 2 was evaluated, and a powdered detergent composition (powdered synthetic detergent A) was prepared by the following method. The composition of the powdered synthetic detergent is shown in Table 1. By using 1.0 kg of zeolite , 4.0 kg of LAS, 0.3 kg of AE, 0.5 kg of AA-MA copolymer (acrylic acid / maleic acid copolymer), 0.15 kg of carboxymethyl cellulose, 0.00 kg of fa, 1_0 kg of Sodium Miao Sodium JIS No. 2, 0.5 kg of sodium hafnium · ash and 0.05 kg of fluorescent dye to obtain an aqueous slurry (solid content: 60%). Next, spray-dried and the particles thus obtained were fed into a Loedige mixer (Manufactured by Matsuzaka Giken). In addition, 1.0 kg of zeolite 4A, 0.5 kg of sodium alkali ash '0.1 kg of enzyme and other thenardite (Na2S04. 10Η20) are used. ____-14-· This paper size applies China National Standard (CNS) Α4 specification (210X297 mm " I. 丨.] 1 _! ---- install ------ order ------ stand (please read the precautions on the back before filling out this page) 470774 A7 B7 Order of the Ministry of Economic Affairs Printed by the Bureau of Work and Consumer Cooperatives V. Description of the Invention (12) 0.2 kg is heated to 70 under mixing. (: AE is gradually poured, f & a into * and granulated. Further add 0.25 kg of After 4A of zeolite, granulation was continued, and particles that did not pass through the 1410 micron sieve were excluded. Thus, a high-density granular detergent composition (average particle size: 450 micrometers, bulk density: 750 g / liter) was obtained. Ingredients (% by weight, powder make-up cleaner A LAS 40.0 FA 1.0 AE 5.0 Zeolite 4A 22.5 Sodium silicate JIS 2 No. 10.0 Sodium ash test 10.0 AA-MA copolymer 5.0 Fluorescent dye 0.5 Enzyme 1.0 Carboxymethyl cellulose 1.5 Glauber's salt (Na, S04.1〇Η? 0) The rest total (%) 100.0 * 1LAS ·· Na salt of linear alkyl (C12) benzenesulfonic acid. * 2FA: Tallow fatty acid Na salt. * 3 AE: Polyoxidation Ethylene dodecyl ether (HLB = 13.1) * 4AA-MA copolymer: SokalanCP5 (manufactured by BASF) -15- This paper size applies to Chinese National Standard (CNS) A4 Specifications (210X297 mm) ί 1.! J ---- install ------ order ------ a trip (please read the notes on the back before filling this page) 470774 A7 ΊΒ7 V. Invention Explanation (13) * 5 Laoguang dye: 4,4'-bis- (2-thiophenethylfluorenyl) biphenyl salt. * 6 Enzymes: API-21H (manufactured by Showa Denko), Lipolase 100T (manufactured by Novo Nordisc), Celluzyme 0.1T (manufactured by Novo—Nordisc), Ternamyl 60T (manufactured by Novo Nordisc), 2: 1: 1: 1 Of a mixture. * 7 Rotyl methyl cellulose: KMC-II manufactured by Shikoku Chemical Co., Ltd. * 8 Glauber's salt: Use it to adjust all ingredients to 100%. (3) Powdery detergent containing perfume particles To the powdery synthetic detergent a obtained in the above (2), 5% by weight or more of the perfume particle composition obtained in (1) is added, so the powdery detergent containing the perfume particles is given. . (4) Evaluation of performance Regarding the powdery detergent containing the fragrance particles obtained above, the panel having a high sensitivity to flavor was evaluated for flavor changes before and after storage. The powdered detergent before storage and the latter stored at 40 ° C for 30 days were used to evaluate the strength and preference of the particles and the scent strength during cleaning operations performed under the following conditions. The results are shown in Table 2. The standard A h quasi h 消费 industrial consumption ah seal (please read the precautions on the back before filling out this page) < conditions for cleaning operation > Introduce 1 to 5 kg of clothes and 30 liters of water in the double basin type washing machine . Then add a 25 g sample of powdered detergent with perfume particles (before or after storage). After 15 minutes of agitation, the entire batch of the laundry was soaked twice and evaluated. For comparison, the perfume was sprayed on the powdered detergent (without perfume particles) in the same manner as the same perfume composition as in each example. For each of the powdered detergents thus obtained, samples were prepared before or after storage at 40 ° C for 30 days. The Zhang scale is applicable to the Zhongguanjia Standard (CNS) 8-4 _ (21Qx297M) 470774 Printed by the Consumer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ______ B7 _ V. Description of the Invention (14) ^ I-^ By using these comparative examples , Under the conditions specified above, the cleaning operation is performed to provide standards for the change of incense. < Evaluation of fragrance during washing > 1: The fragrance strength of the washing water after stirring for 1 minute under the above conditions. ii: The fragrance intensity of the washing water after stirring for 15 minutes under the above conditions. 111: Stir under the above conditions for 15 minutes. The aroma intensity of the clothes after washing and dehydration. The aroma intensity of each step ⑴ to ㈣ was compared with a comparative sample and evaluated according to the following criteria. 4: Far stronger fragrance than comparison. 3: Stronger fragrance than comparison. 2: Slightly stronger than comparative flavor. 1: Comparable fragrance intensity. < Evaluation of powdered citron > 1: Slightly stronger than comparative flavor. 0: Comparable fragrance intensity. 1. Slightly weaker fragrance than comparison. A ·· A better fragrance than comparison. B: Scent comparable to comparison. C. No better fragrance than comparison. Γ The paper scale is appropriate --- i „.I soil ------, τ ------- " · i% 4 Notes on the back of idle reading, please fill out this page) 470774 Central Standard of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau A7 ________B7 V. Description of the invention (U) Table 2 Examples (X) Examples (π) Comparative Examples (Ώ 例 0) Fragrance particle composition ingredients (a) Fragrance ingredients (i) 5% perfume Ingredient (i) 8% perfume ingredient (丨) 5% perfume ingredient (0 8% ingredient (b) sodium lauryl sulfate 75% sodium lauryl sulfate 64% sodium lauryl sulfate 30% sodium lauryl sulfate 20% ingredient (c) zeolite 4An 15% zeolite 4A "20% zeolite 4A * 1 50% composition⑹ polyethylene glycol * 2 2% acrylic acid / cis butane dimerization (vinyl pyrrolidine acrylic acid / cis butene two components (e) hydroacid copolymer" 3% ketone 10% acid copolymer * 3 15% 3% water 2.9% water 5% water 20% other lauryl alcohol 2% sodium carbonate 37% colorant A45 0.1% (Please read the precautions on the back before filling this page ) -18- This paper is scaled to fit the family (eNS) (210X297 male cage ~ 7 470774 A7 B7) V. Description of the invention (16) Impression Form 2 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (I) IBS) Comparative Example ω Comparative Example (I Evaluation (i) 1 1 1 1 Evaluation (ii) 3 3 1 1 Evaluation (iii) After storage: 3 3 1 1 Evaluation (i) 3 3 2 1 Evaluation (ii) 4 4 2 1 Evaluation (iii) Powder flavor 4 4 2 1 Before storage -1Λ_1, A -1, Α-1, Α After storage 〇, A 〇, A 1, B -i, c (Note) Smellite: average particle size = 4 μιη * 2 Polyethylene glycol: average molecular weight = 600. * 3 Acrylic acid / maleic acid copolymer: s-cj> 5 (manufactured by basf). * 4 Poly (vinylpyrrolidone) : Average molecular weight = 3000. * 5 Colorant A: Lmol Green FB [CI, Pigment Green No. 7, (c 丄 74260)]. Examples ijj.D and J1Y1, Comparative Example: By using the example (I ) The prepared perfume ingredient (i), and the perfume particle composition shown in Table 4 was prepared in the same manner as in Example (I). Then 5% by weight of the j composition was added to the powdery synthetic detergent B prepared by the following method to Giving < ____ -19- (CNS) (210X297 ^) ------------- 絜 -------, 1Ί ------ J. (Please read the back first Note for re-filling this page) 470774 Α7 Β7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Π) A powdered detergent of perfume particles, which is then evaluated in the same way as in Example VII. The results are shown in Table 4. < Powdered synthetic detergent B > In order to evaluate the products of the present invention shown in Table 4, a powdered detergent composition (powdered synthetic detergent A) was prepared by the following method. The composition of the powdery synthetic detergent b is shown in Table 3. By using 1.5 kg of sodium tripolyphosphate, 40 kg of laS, 03 kg of AE, 0.1 kg of AA-MA copolymer (acrylic acid / maleic acid copolymer), and 0.05 kg of carboxymethyl Base cellulose, 0 kg of fa, ο kg of sodium silicate JIS No. 2, 0.2 kg of sodium alkali ash, and 0.05 kg of fluorescent dye to obtain an aqueous slurry (solid content: 50%). Next, spray-dried and the thus-obtained particles were fed into a Loe (jige mixer (manufactured by Matsuzaka Giken). In addition, 1.0 kg of zeolite 4A, 0.05 kg of sodium alkali ash, 0.1 kg of enzyme and The other mirabilite (Na2S〇4 · 10 h2〇) is used. Under mixing, AE that has been heated from 0 to 2 kg to 70 deg. P is gradually poured into these ingredients for relaying and granulation. Further, 0.25 kg of zeolite is added after 48 days. Granulation was performed and particles that did not pass through a 1410 micron sieve were excluded. Thus, a high-density granular detergent red compound (average particle size: 400 micrometers, bulk density of 700 g / liter) was obtained. Each of these ingredients was used in the example (I ) The same. _ -20- This paper size applies to China National Standard (CNS) Α4 size (210 X 297 mm) ----- I ------ installed ------ 1T --- --- J (Please read the notes on the back before filling this page) 470774 A7 F7 Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (I8) Composition (wt%) Table 3 Powdery synthetic cleaning LAS 40.0 FA 1.0 AE 5.0 Chorite 4A '12.5 Sodium Trimerate Sodium 15.0 Sodium Silicate JIS No. 2 10.0 Nano Test 7 .0 AA-MA copolymer 1.0 Fluorescent dye 0.5 Enzyme 1.0 Carboxymethyl cellulose 1.5 Glauber's salt (Na2S04 · 10H20) The rest total (%) 100.0 • 21- (Please read the precautions on the back before filling this page) This paper Standards are applicable to China National Standard (CNS) A4 specifications (210X297 mm) 470774 A7 E7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (l9) Table 4 Examples (ΠΏ Example (IV) Comparative Example (ΠΟ Comparative Example (IV) Fragrance particle composition ingredients (a) Fragrance ingredients (i). 5% perfume ingredients (i) 8% perfume ingredients (i) 5% perfume ingredients (i) 8% ingredients (b) sodium lauryl sulfate 75% laurel Sodium sulphate 64% Sodium laurate 30% Sodium laurate sulfate 20% Ingredients (C) Zeolite 4A * · 1 15% Zeolite 4A * 1 20% Zeolite 4An 50% Ingredients (d) Acrylic acid / cis-butene dimerization (vinyl pyrrole) Polyacrylic acid ~ acrylic acid / maleic acid copolymer η 2% ketone) * 3 3% 10% acid copolymer ^ 15% Ingredients (e) Water 2.9% Water 5% Water 22% Other water 3% Lauryl alcohol 2 % Sodium tripolyphosphate 35% Colorant B ”0.1% (Please read the precautions on the back before filling this page} (CNS V (210X297 ^ t) 4707 74 A7 B7 V. Description of the invention (20) Table 4 (continued)
清洗時香味 儲存前： 實例(I) 實例(H) 比較例(I) 比較例〇Ι) 評估(i) 1 1 1 1 評估⑻ 3 3 1 1 評估Ciii) 儲存後·· 3 3 1 1 評估① 3 3 2 1 評估(ii) 4 4 2 1 評估(iii) 粉末香味 4 4 2 1 儲存前 -1Λ -1Λ Ι,Α -Ι,Α 儲存後 Ο,Α Ο,Α -1，Β -1，C (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製 (註） *1沸石：平均粒度=4微米 *2丙烯酸/順丁晞二酸共聚物：Sokalan CP5 ( BASF製造）。 *3聚（乙烯基p比咯淀酮）：平均分子量=30,000。 *4聚丙烯酸：平均分子量二13,000。 *5著色劑B :紅色106號[C.I.酸性紅52 (C.I. 45110)]。 -23- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐〉Before scent storage during washing: Example (I) Example (H) Comparative example (I) Comparative example 〇) Evaluation (i) 1 1 1 1 Evaluation ⑻ 3 3 1 1 Evaluation Ciii) After storage ... 3 3 1 1 Evaluation ① 3 3 2 1 Evaluation (ii) 4 4 2 1 Evaluation (iii) Powder flavor 4 4 2 1 Before storage -1Λ -1Λ Ι, Α-Ι, Α After storage 〇, Α Ο, Α -1, Β -1 , C (Please read the notes on the back before filling out this page) Printed by the Consumers Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (Note) * 1 Zeolite: average particle size = 4 microns * 2 acrylic acid / maleic acid copolymer: Sokalan CP5 (manufactured by BASF). * 3 Poly (vinyl p-pyrrolidone): average molecular weight = 30,000. * 4 Polyacrylic acid: average molecular weight is 23,000. * 5 Colorant B: Red No. 106 [C.I. Acid Red 52 (C.I. 45110)]. -23- This paper size is applicable to China National Standard (CNS) A4 (210X297 mm)