TW470773B - Slideway lubricating oil composition - Google Patents

Abstract

A slideway lubricating oil composition uses as base oil at least one oil selected from mineral oil, fat and synthetic oil, and further comprises (A) carboxylic acid and/or ester and (B) phosphoric ester expressed by the formula O=P-(OR1)3 wherein R1 denotes hydrocarbon having from 1 to 24 carbon atoms, or (C) at least one metallic organic acid salt, the metal being selected from alkali metal, alkali earth metal, zinc and lead. This lubricating oil composition is excellent in separability from water-soluble cutting fluid in the case of the mixing thereof into the fluid, as well as in lubricating property and does not adversely affect the performance of water-soluble cutting fluid.

Description

470771 male 33 ^ Dpif.doc / 002

衣 I Λ7 B7 Five '¥ Meng (" The present invention relates to the composition of a kind of lubricating oil (Siideway Lubdcatingou), and in particular to-a kind of very good lubricating properties on the inclined surface, and from water-soluble Cutting lubricant (Water-soloble Cutting Fluid) also has a very good separation. It is often composed of machine tools, such as machine lubricants that may be mixed with inclined surface lubricants. Especially when using water-soluble One of the reasons for the deterioration of water-soluble cutting lubricants (decreasing cutting efficiency, increasing damage, shortening the interval between oil replacements, and increasing the cost of waste liquid treatment) when using cutting lubricants as machine lubricants is to lubricate the inclined surface. Oil is mixed into the lubricant ° and 'for the performance required for the lubricating oil on the inclined surface, when the lubricating oil on the inclined surface is mixed with the lubricant, the separation of the water-soluble cutting lubricant needs to be excellent' and It is necessary to have excellent lubricating properties on the inclined surface. In addition, it is also required that the inclined surface lubricant must not adversely affect the efficiency of the water-soluble cutting lubricant. In the past, it is difficult to obtain additives with generally improved lubricity properties in inclined surface lubricants to obtain inclined surface lubricants with excellent separation and lubricating properties, because these additives tend to make The separation of water-soluble cutting lubricants deteriorates. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page. Therefore, the main purpose of the present invention is to provide a lubricating oil on inclined surfaces When the surface lubricant is mixed into the lubricant, the separation from the water-soluble cutting lubricant is excellent, and the lubricating properties are also excellent, and the composition of the inclined surface lubricant does not adversely affect the water-soluble cutting lubricant. The inventor of the present invention has worked hard to investigate this subject to overcome the above-mentioned problems. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 3360twf.doc / 002 A7 B7 5. Description of the invention (/) (Please First read the precautions on the back and then fill out this page) Question 'I found that the lubricating oil composition with special ingredients has excellent separation from water-soluble cutting lubricants, The lubricating properties on the inclined surface are also excellent to complete the present invention. A first object of the present invention is to provide a lubricating oil composition of the inclined surface as a base oil. At least one oil is selected from the group consisting of mineral oil, grease, and synthetic oil. The composition includes: (A) a carboxylic acid and / or an ester; and (B) a phosphorus-containing ester as shown in the following chemical formula (1) C ^ P-CORl (1) where R1 represents a carbon having 1 to 24 carbon atoms Hydrogen compounds. A second object of the present invention is to provide a sloped lubricating oil composition as a base oil. At least one oil is selected from the group consisting of mineral oil, grease and synthetic oil, and the composition includes: (A) a carboxylic acid and / or an ester; (B) a phosphorus-containing ester, as shown in the following chemical formula (1): 〇 = P- (〇R ′) 3 (1) wherein R1 represents a hydrocarbon having 1 to 24 carbon atoms; and SAMPLE ^ Gongconsumer Co-operative Cooperative Purple (C) at least-metal organic acid salt, the metal is selected from the group consisting of alkali metals, salty metals, zinc and lead. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below, and in conjunction with the attached drawings, it is detailed that this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 470773 3360twf.doc / 002 A7 _________________________________________B7 V. Description of the invention (>) The detailed description is as follows: The diagram is as follows: The first diagram is an explanatory diagram showing the naming of each layer. Verification of the separation of water-soluble cutting lubricants. Examples The present invention will now be described in detail. The inclined surface lubricating oil of the present invention is composed as a base oil 'and at least one oil is selected from the group consisting of mineral oil, grease and synthetic oil. Examples of mineral oils selected as base oils in the present invention include paraffinic or naphthenic mineral oils, which are applied by applying one or more refining methods such as Solvent Deasphalting, Solvent Estraction, Hydro-cracking, Solvent Dewaxing, Contact Dewaxing, Hydro-refining, Sulfuric- Acid Treatment), Clay Treatment and the combination of the above methods, to obtain the fractionation of lubricating oil (Fraction) by distillation of crude oil at normal pressure and reduced pressure (Distillation). The central part of the ministry is accurate and only- " Consumer cooperatives are complicated (please read the precautions on the back before filling this page). Examples of oils and fats include animal fats, lard, soybean oil, rapeseed oil, rice bran oil, coconut Oil, palm oil, palm kernel oil or hydrogenated products or others similar to this. Examples of synthetic oils include poly-olefins (ethylene-propylene copolymers, polybutenes, 1-octene oligomers, 1-decene oligomers, and their hydrogenated products and others similar to this nature), alkanes Base benzene, alkyl naphthalene, monoester (butyl stearate, octyl laurate), diester (di-tridecyl glutarate, adipic acid-_______y ____ This paper size applies to Chinese national standards (cns) M Specifications (2ΐ〇χ297 公) ο 7 4 7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 3360pil'.doc / 002 ^ __________ B7 V. Description of the invention (★) Di-2-ethylhexyl ester, adipic acid Diisodecyl ester, di-tridecyl adipate, di-2-ethylhexylcephacate and others similar to this structure), poly (trimellitic acid salt and others similar to this structure), polyol ester poli. lestei_ (trimethylolpropanecaprilate, trimethylolpropanecaprilate, trimethylolpropanecapriate, acetonitrile nonanoate, trimethylolpropanepelargonate, isopentaerythritol_2_ ethyl hexanoate, isopentaerythritol nonanoate pentaerythritolpelargonate, and other similar structures), polyoxy Alkenyl glycol, polyphenylene ether, the second hospital Diphenyl ethers, phosphates (trimethylphenol phosphates and others similar to this structure), fluorinated compounds (perfluoropolyethers, fluorinated polyolefins and others | members like this structure), silicone oils and others similar to this Nature. The above-mentioned base oils may be used alone or in combination of more than one base oil of the inclined surface lubricating oil of the present invention. When the base oil of the present invention is at 40 ° C, the preferred Kinetic Viscosity range is from 10 to 500 mm2 / s, and the better range is from 15 to 250 mm2 / s, although the dynamic viscosity may be outside these ranges. . Everything of the base oil of the present invention is freely selectable, but usually ranges from 50 to 99.98% by weight based on all compositions. The component (A) of the present invention is a carboxylic acid (A-1) and / or an ester (A-2). When it is possible to use (A-1) carboxylic acid, monocarboxylic acid and polycarboxylic acid, the former has one carboxyl group per molecule and the latter has more than one end group per molecule. Commonly used monocarboxylic acids are fatty acids having 6 to 24 carbon atoms. In addition, linear and dendritic carboxylic acids can be used, and saturated and unsaturated fatty acids can be used. Examples of fatty acids with 6 to 24 carbon atoms, including saturated paper. Applicable to China National Standard (CNS) A4 specifications (210X297 male f) (Please read the precautions on the back before filling this page),-° 470773 3360pif .d〇c / 002 Λ7 ___ ~ ___ Η 7 V. Description of the Invention (f) ~ (Please read the notes on the back before filling out this page) Complete acid and unsaturated carboxylic acid. Among them, saturated carboxylic acids such as linear or dendritic caproic acid, linear or dendritic heptanoic acid, linear or dendritic caprylic acid, linear or dendritic nonanoic acid, linear or dendritic capric acid, linear or dendridecanoic acid, linear or Dendritic acid, linear or dendritic tridecanoic acid, linear or dendritic tetradecanoic acid, linear or dendritic pentadecanoic acid, linear or dendritic hexadecanoic acid, linear or dendritic heptadecanoic acid, linear or dendritic Octadecanoic acid, linear or dendritic decanoic acid, linear or dendritic icosanoic acid, linear or dendritic undecanoic acid, linear or dendritic docosalic acid, linear or dendritic 131 acid, linear Or dendritic acid, and others similar to this structure. Among them, unsaturated carboxylic acids such as linear or dendritic caproic acid, linear or dendritic heptanoic acid, linear or dendritic caprylic acid, linear or dendritic nonanoic acid, linear or dendritic capric acid, linear or dendridecanoic acid, linear or Dendritic acid, linear or dendritic tridecanoic acid, linear or dendritic tetradecanoic acid, linear or dendritic pentadecanoic acid, linear or dendritic hexadecanoic acid, linear or dendritic heptadecanoic acid, linear or dendritic Octadecanoic acid, linear or dendritic decanoic acid, linear or dendritic icosanoic acid, linear or dendritic lauric acid, linear or dendritic lauric acid, linear or dendritic triconic acid, linear or branch It is preferred that the polycarboxylic acid used in the printing of the tetradecanoic acid and other similar similar structures to the consumer cooperation of the Central Bureau of the Ministry of Economic Affairs has 2 to 8 carbon atoms. Examples of the polycarboxylic acid include saturated fatty dicarboxylic acids, unsaturated fatty dicarboxylic acids, and aromatic polycarboxylic acids. Among them, saturated fatty dicarboxylic acids are, for example, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and methylmalonic acid. Acid, ethylmalonic acid, dimethylmalonic acid, methylsuccinic acid, 2,2-dimethylsuccinic acid, 2,3-dimethylsuccinic acid, 2-ethyl-2- Methylsuccinic acid, methylglutaric acid, 3-methylglutaric acid, 3-methyladipate, and others similar to this structure. Unsaturated fat This paper is in accordance with Chinese National Standard (CNS) Α4 size (210 × 297 mm) 470773 3360pif.d〇c / 002 5 Λ7

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Description of dicarboxylic acids such as maleic acid, fumaric acid, methacrylic acid, dimethyl maleic acid, methyl fumaric acid Diacids and others similar to this structure. Aromatic polycarboxylic acids are, for example, phthalic acid, terephthalic acid, isophthalic acid, metaphenylene carboxylic acid, and others with similar properties. (A-2) Vinegar is a carboxylic acid-containing alcohol and / or phenol. The formation of (α_ 酉, 米, 苜, Ρ, ΓΓΓ r, i ′ ′) is a monovalent or polyvalent alcohol. For example, for a monovalent alcohol, it is appropriate to use 1 to 1 ”H to suspend 1 to 24 carbon atoms. Fatty alcohols. Taking fatty alcohols with 1 to 24 carbon wires as examples, including methanol, ethanol, linear or dendritic propanol, or dendritic butanol 'linear or dendritic pentanol, linear or dendritic hexanol, Line or = branch 3 heptanol, linear or dendritic octanol, linear or dendritic nonanol, linear shape natural knowledge, linear or dendridecyl alcohol 'linear or dendritic dodecanol, linear alcohol & dendrimer ^ Alcohol, linear or dendritic myristyl alcohol, linear or dendritic fifteen ^ octadecyl or dendritic cetyl alcohol, linear or dendritic heptadecanol, linear or dendritic ^ linear or dendritic nondecyl alcohol, linear or Dendricosyl alcohol, linear or M · τγ ^ ~~ — r ~ undecanol, linear or dendritic eicosandiol, linear or dendritic trichomes, linear or dendritic tetracosanol, and others similar to this Structured. The polyvalent alcohol used is preferably 2 to 10 valence. Taking a polyvalent alcohol having 2 to k as an example, it includes a divalent alcohol, a polyvalent alcohol, and a sugar. Among them, a divalent alcohol such as Ethylene glycol, polypropylene glycol (with 3 to 15 propylene glycol units), U-propylene glycol, 1,2-butanediol, 1,3-butanediol, K-butanol, 2-methyl- 1,2-pentanediol, 2-methyl-1,3-propanediol, I2 pentanol, 1,3-pentanediol, i, 4-pentanol, pentanol, nonanediol, and other similar structures Multivalent alcohols such as stigmatriol, polyglycerol (with narrow 2 to 8 glycerol units, such as dipropylene triol, triglycerol, tetraglycerol (please read the precautions on the back before Fill out this page) Order · This paper size applies Chinese National Standard (CNS) A4 size (210x297gt) 470773 3360 | > il'doc / 002 Printed by the Central Bureau of the Ministry of Economy

Λ7 B? V. Description of the invention (/)) < Alcohol and those similar to this structure), trimethylalkanes (trimethylalcohol ethane, trimethylalcohol, trimethylalcohol propane and others similar to this) Structure), and the above dimer to octamer, pentyl triol and its dimer to tetramer, I, 2, 4-butyl triol, I, 3, 5. pentyl triol, i, 2,6_hexyltriol, 1,2,3,4, _butyltetraol, hexahexaol, sorbitan anhydride, sorbitol-glycerol condensation, atonitol, arabitol, dimethyl alcohol Benzyl alcohol, hexadecanol, and others similar to this structure. Examples of sugars are xylose, gum aldose, ribose, rhamnose, glucose, fructose, galactose, mannose, herbal tea sugar, cellulose, maltose, isomaltose, sucrose, sucrose, and others similar to this structure. The (A_2) ester may be any of the above-mentioned alcohol derivatives. However, it may be a derivative of a phenolic compound. The phenolic compounds in the present invention have 6 to Π carbon atoms, and include, for example, the special phenol 'cresol (common name cresol) (including all substituted isomers), ethylphenol (including all substituted isomers) ), Dimethyl hydrazone (including all substituted isomers), propyl phenol (including all substituted isomers), ethyl methyl, ^ == isomers), trimethyl acid (including All substituted isomers (including all substituted isomers), amyl group (including all substituted isomers), hexyl group, and others similar to this structure. ) It is like forming the carboxylic acid of the above (A-2), and the same carboxylic acid (A_n as exemplified above) is used as an example. The alcohol used is cis. The purpose is to use the complete ester that is completely esterified with its ammonium group. Although it can retain some esters that are not esterified with hydroxyl groups, it is completely cool (CNS) A4 specification (^ nv « mV ^ mt m ^ — — ^ ϋ v ^ m — ^ ϋ- —flu n ^ n Γ 'N "-mouth (please read the precautions on the back before filling Page} 470773 3360pif.doc / 002 Λ7 Printed by B7 of the Central Bureau of Standards of the Ministry of Economic Affairs on Consumer Consumption V. Invention Description (¾). In this case, only one type of carboxylic acid can be used, and more than one type of carboxylic acid can be used. It is also possible to use carboxylic acids in the same state. Similarly, when using a polycarboxylic acid, such as an acid that forms an (A-2) ester, a complete ester can be used in which all carboxyl groups are esterified. Although at least one carboxyl unesterified can be used Partial esters, but complete esters are preferred. In this case, only one type of alcohol can be used, and more than one type of alcohol can also be used. In the examples of the present invention (A) component can be a compound selected from (A-1) and (A-2), and it can also be a mixture of more than one compound. When (A-1) carboxylic acid is used as (A) component According to all the composition, the maximum weight percentage of (A-1) component is 40%, preferably 20%, more preferably 10%, and most preferably 7%. Amounts greater than 40% by weight are not good because no better results have been found and storage stability Can be deteriorated. In one embodiment of the present invention, (A-2) ester can be used as the base oil. In this case, for (A-2) ester, according to all the composition, the relevant ester exists. The maximum weight percentage is 99.9%, preferably 90%, and more preferably 50%. According to all the compositions, the minimum amount of (A) component is 0.01% by weight, preferably 0.05%, The better is 0.1%, and the best is 0.2%. (A) The presence of less than 0.01% of the component is not good, because the function of lubrication may be deteriorated. This paper size applies the Chinese National Standard (CNS) Λ4 specification ( 210X297 mm) ----- II i II | Bu Yi -------, 1τ (Please read the precautions on the back before filling in this page) 470773 A7 3360pif.doc / 002 V. Description of the invention (Cj) The component (B) of the present invention is a phosphoric ester, as shown in the following formula (1): 〇 = P- (OR 丨) 3 (1) (where R1 represents a hydrocarbon having 1 to 24 carbon atoms) In (1), R1 represents a hydrocarbon having 1 to 24 carbon atoms. Examples of such hydrocarbons include: alkyl, alkenyl, cycloalkyl, alkylcycloalkyl, aromatic hydroxyl, alkylaromatic hydroxyl, and aromatic hydroxyalkyl. Alkyl groups having 1 to 24 carbon atoms, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, second butyl, neobutyl, linear or branched pentyl, Linear or dendritic hexyl, linear or dendritic heptyl, linear or dendritic hemi, linear or dendritic nonyl, linear or dendritic decyl, linear or dendridecyl, linear or dendritic dodecane Base, linear or branched tridecyl, linear or branched tetradecyl, linear or branched pentadecyl, linear or branched ten / alkyl, linear or branched heptadecyl, linear Or branched octadecyl linear or branched undecyl, linear or branched icosyl, linear or branched ten ~ alkyl, linear or branched behenyl, linear or branched 222 Courtyard, linear or dendritic twenty-four courtyards and those similar to this structure; Alkenyl groups with 2 to μ carbon atoms, such as vinyl, linear or dendritic propenyl, linear or dendritic butenyl , Linear or dendritic estryl or dendritic hexyl, linear or dendritic lysyl, linear or dendritic octyl, linear or dendritic nonenyl, linear or dendritic decenyl Linear or dendridecyl, linear or dendritic dodecenyl, linear or dendritic thirteen, linear or dendritic tetradecenyl, linear or dendritic pentaenyl, linear_ this secret ruler Masanori! —-I nm ^^^ 1 I 1- i— n ml I--in 、 一 -SJ (Please read the precautions on the back before filling this page) Λ 部 屮

Jih li -t 竹 (\-t 470773 3360pir.doc / 0〇2 Λ7 Wujingjing; Ministry of Central. Central VI if and eliminate η ή i ή ή i description 丨 0 ~~ hexadecenyl, linear or Dendrimeric heptenyl, linear or dendritic octaenyl, linear or dendritic undecenyl, linear or dendritic eicolenyl, linear or dendritic undecenyl, linear or dendritic twentieth Dienyl, linear or dendritic 23-dienyl, linear or dendritic tetradecenyl, and others similar to this structure; cycloalkyl having 5 to 7 carbon atoms, such as cyclopentyl, cyclohexyl, Cyclopeptyl and others similar to this structure; Alkylcycloalkyl with 6 to 11 carbon atoms, such as methylcyclopentyl, dimethylcyclopentyl (including all structural isomers), methyl ethyl Methylpentyl (including all structural isomers), diethylcyclopentyl (including all structural isomers), methylcyclohexyl, dimethylcyclohexyl (including all structural isomers), Methylethylcyclohexyl (including all structural isomers), diethylcyclohexyl (including all structural isomers), methylcycloheptyl, Methylcycloheptyl (including all structural isomers), methylethylcycloheptyl (including all structural isomers), diethyl (including all structural isomers), and others similar to this structure Aromatic hydroxyl groups with 6 to 10 carbon atoms, such as phenyl, naphthyl, and others similar to this structure; Alkyl aromatic hydroxyl groups with 7 to 18 carbon atoms, such as tolyl (including all structural isomers) Materials), xylyl (including all structural isomers), ethylphenyl (including all structural isomers), linear or branched propylphenyl (including all structural isomers), linear Or branched butyl radical (including all structural isomers), linear or branched pentyl radical (including all structural isomers) 'linear or branched hexyl radical (including all structural isomers) Material), linear or branched heptyl phenyl This paper is made of the Ten Countries National Guide (CNS) (Please read the notes on the back before filling out this page) Order 470773 3360pii'doc / 〇〇2 Μ1. ¾ ί / ί IV Λ A7 V. Description of the Invention (丨 I) ~ (including Some structural isomers), linear or branched octylphenyl (including all structural isomers), linear or branched nonylphenyl (including all structural isomers), linear or branched Decylphenyl (including all structural isomers), linear or branched undecylphenyl (including all structural isomers), linear or branched dodecylphenyl (including all Structural isomers) and others similar to this structure; and aromatic hydroxyalkyl groups with 7 to 12 carbon atoms, such as benzyl, phenethyl, phenylpropyl (including all propyl isomers) , Phenylbutyl (including all isomers of butyl), phenpentyl (including all isomers of pentyl), phenhexyl (including all isomers of hexyl), and others similar to this structure. As for the aforementioned functional group R1, phenyl and alkyl aromatic hydroxyl groups having 7 to 18 carbon atoms are preferred, and phenyl and alkyl aromatic hydroxyl groups having 7 to 10 carbon atoms are more preferred because Separability from water-soluble cutting lubricants is very good. Furthermore, R1 may be the same or different from each other within the same molecule. In one embodiment of the present invention, such as the composition (B), a compound selected from the above compounds may be used, or a mixture of more than one compound may be used. Based on all the composition '(B) composition, the maximum weight percentage is 30%, preferably 10%', more preferably 5%, and most preferably 3%. It is not good that the (B) composition appears in excess of 30% by weight 'because no better result is found and the cost may be increased. According to all the compositions, ((B) the composition appears with a minimum weight percentage of 〇01%.) It is preferable that the scale ratio (⑽) Λ4 specification (2 丨 0X297 miscellaneous) II I------I--I 11 Good--I 1--I Τ »(Please read the notes of Back® and fill in this page first) 470773 Λ7 3360pit'.doc / 002 B7 V. Description of the invention (丨 7) 0.05%, better It is 0.1% and the best is 0.2%. (B) The composition appears to be less than 0.01% because the lubricity is deteriorated. In the present invention, in addition to the base oil, when the components (A) and (B) are included, the lubricating oil composition of the inclined surface can obtain excellent lubricating properties, and the separability from the water-soluble cutting lubricant is also very good. In order to increase the separation from water-soluble cutting lubricants, such as component (C), at least one metal organic acid salt should be added, and the metal is selected from alkali metals, alkaline earth metals, zinc and lead. In the above-mentioned (C) component, examples of the alkali metal include sodium, potassium, and the like, and alkaline earth metals include magnesium, calcium, barium, and the like. Further, in the component (C), examples of the organic acid salt include (C-1) sulfonate, (C-2) phenate, (C-3) salicylate, and mixtures thereof. Examples of (C-1) sulfonate include natural sulfonate, basic sulfonate, perbasic carboxylate (super basic) sulfonate, perbasic boric acid (super basic) sulfonate, Or it can be a mixture of the above and other similar properties. Natural sulfonates are obtained by reacting an alkyl aromatic sulfonic acid with an alkali (oxide or hydroxide) of an alkali metal, alkaline earth metal, zinc or lead. The alkyl aromatic sulfonic acid is a sulfonic acid of an alkyl aromatic compound. It is obtained by acidification, wherein the molecular weight of the alkyl aromatic compound is from 100 to 1500, preferably from 200 to 700. Basic sulfonates are obtained by heating natural sulfonates and excessive salts or bases (oxides or hydroxides) of alkali metals, alkaline earth metals, zinc or lead are present in the water. Perbasic carboxylate (super basic) sulfonate is obtained by reacting a natural sulfonate with an alkali (oxide or hydroxide) of an alkali metal, alkaline earth metal, zinc or lead in the presence of carbon dioxide. . Over basic boric acid (except the paper X degree through deduction of the Ten Countries National Standards (CNS) Λ4 specification (2K) X297 public trend) (read the precautions on the back before filling this page) " 衣 _ 3 3360pir. doc / 002 A7 _______________________ —________________ — ____ B7 _ 5. Description of the invention (丨 &) Basic) Sulfonate is a natural sulfonate that reacts with alkali metals, alkaline earth metals, zinc or lead, and compounds with boron Wherein, the boron compound is, for example, boric acid or anhydrous boric acid; or a perbasic carboxylate (super basic) sulfonate can be reacted with a boron compound, wherein the boron compound is, for example, boric acid or anhydrous boric acid . Examples of the above-mentioned alkyl aromatic sulfonic acids include Petroleum Sulfonic Acid, synthetic sulfonic acids, and others similar to this property. Taking the petroleum sulfonic acid used as an example, the "five acidification" of the alkyl aromatic compound of mineral oil lubricating oil fraction, or "Mahogany Acid", is a by-product made for white oil. Taking synthetic sulfonic acid as an example, a sulfonated alkylbenzene having linear and dendritic alkyl groups is used. The sulfonated alkylbenzene is a secondary product produced from an alkylbenzene plant. Processed detergents, or sulfonated alkylbenzenes, are alkylated with benzene and polyolefins. Sulfonated alkyl naphthalenes, such as sulfonated dinonane naphthalene, are also used. Examples of sulfonating agents used to sulfonate these alkylbenzene compounds include oleum and sulfuric anhydride, although any suitable sulfonating agent can be used. (C-2) Examples of phenates, including neutral phenates, basic phenates, overbased carboxylic acids (super basic), phenates, overbased boric acid (super basic) phenates, or the above Mixtures and others similar to this nature. Neutral phenates react with the alkali (oxide or hydroxide) of an alkali metal, alkaline earth metal, zinc or lead in the presence or absence of sulfur by an alkyl phenol having 1 to 2 alkyl groups, Wherein alkyl has 4 to 20 carbon atoms. The so-called basic phenate, in the presence of water, uses neutral phenate and excessive alkali metals and alkaline earth gold paper. Hongyuan China Standard (CNS) / \ 4 size (21〇χ 297) #) 470773 3360pil.doc / 002 ^ _ — — V. Description of the invention (#) I 11 > clothing n ~~~, 1T (诮 Please read the notes on the back before filling this page) Salt of metal, zinc or lead Or the base (oxide or hydroxide) is obtained by heating. The so-called overbased carboxylic acid (super basic) phenate, in the presence of carbon dioxide, is reacted by a neutral phenate with an alkali (oxide or hydroxide) of an alkali metal, alkaline earth metal, zinc or lead. obtain. So-called overbased boric acid (super basic) phenates are obtained by reacting a neutral phenate with an alkali (oxide or hydroxide) of an alkali metal, alkaline earth metal, zinc or lead, and with a boron-containing compound Among them, boron-containing compounds such as boric acid or anhydrous boric acid, or obtained by reacting a perbasic carboxylic acid (super basic) phenate with a boron-containing compound, among which boron-containing compounds such as boric acid or anhydrous boric acid. (C-3) Examples of salicylate, including neutral salicylate, basic salicylate, perbasic carboxylate (super basic). Salicylate, perbasic boric acid (Super basic) Salicylate or mixtures of the above and others similar to this. Salicylate reacts with an alkali metal, alkaline earth metal, zinc or lead base (oxide or hydroxide) in the presence or absence of sulfur by an alkyl salicylic acid having 1 to 2 alkyl groups Thus, the alkyl group has 4 to 20 carbon atoms. Basic salicylate is obtained in the presence of water by heating a neutral salicylate and excess alkali, alkaline earth metal, zinc or lead salts or alkalis (oxides or hydroxides). Perbasic carboxylate (super basic) salicylate, in the presence of carbon dioxide, by the base or base (oxide or alkali) of a neutral salicylate with an alkali metal, alkaline earth metal, zinc or lead Hydroxide). Perbasic boric acid (superbasic) salicylate, in the presence of carbon dioxide, by a salt or alkali (oxide or hydroxide) of neutral salicylate with an alkali metal, alkaline earth metal, zinc or lead ) And obtained by reaction with boron-containing compounds, such as boron-containing compounds such as boric acid or anhydrous boron, the paper size is applicable to the ten national standard vehicles (CNS) Λ4 specification (21〇ϋ ^ ϋ) ''-'3360pii.doc / 002 部 中 火]! .-Γ; /; fr bamboo 470773 —— A7 —_______ B7 V. Description of the invention (β) acid, or metal-containing salicylic acid by perbasic carboxylic acid (super basic) The salt is obtained by reacting with a boron-containing compound, such as a boric acid or anhydrous boric acid. Regarding the component (c) in the above compounds, organic acid salts of alkaline earth metals are preferable, and all alkaline acid salts of alkaline earth metals having an alkali number of 30 to 500 mg KOH / g are preferable because of their good lubrication. And separation from water-soluble cutting lubricants. According to JIS K 2501 "Petroleum Products and Lubricating Oil-Neutralization test method" in Chapter 7, all references to the number of bases herein refer to the number measured by the perchlorate method. In an embodiment of the present invention, For example, the component (C) may use one selected from those compounds, and a mixture of more than one compound may be used. According to all the composition, the maximum weight percentage of the component (C) is 20%, preferably 10%, more preferably 5%, and most preferably 3%. (C) The presence of more than 20% of the component is not good, because no better results are found, and the cost may increase. According to all Composition, the minimum amount of the (C) component is 0.01% by weight, and is preferably 0.05%, preferably 0.1%, and more preferably 0.2%. The amount of the (C) component is less than 0 · 01% is not good because the separation of the cutting lubricant from the aqueous solution is not expected to be improved. According to the composition of the inclined surface lubricant of the present invention, different kinds of other additives can be mixed, as required, to more Improve it further II--------* m ----—— ·, 1τ (Please read the notes on the back before filling this page) 氺 The paper size is suitable / 1] Chinese National Standard (CMS) Λ4 Specifications (21〇 × 297ϋΓ 470773 3360 |) if.doc / 002 Central Sample II _τ Elimination Λ 印 A7 B7 V. Description of the Invention (仏) Examples of such additives include phenol compounds, antioxidants, antifoams, Pour point inhibitors and viscosity index improving agents. Phenolic compounds such as tertiary butyl p-cresol, bisphenol A, and others similar to this property. Antioxidants such as amines' such as phenyl_α_naphthylamine, N, N , -Bis (2-naphthyl) -p-phenylenediamine and others similar to this property, metal inactivating agents such as benzotriazole, alkylthiazole and others similar to this property. Antifoaming agents such as silicone oil, fluorinated Silicone oil and others similar to this property. Pour point inhibitors such as polymethyl propylene salts and others similar to this property. Viscosity index improving agents such as polymethacrylate salts, polybutene, polyalkylstyrene, and olefin copolymers , Styrene-diene copolymer, styrene-maleic anhydride Polymers and others similar to this nature. When these additives are mixed with the composition of the inclined surface lubricating oil of the present invention, it is possible to use only each additive, or it is also possible to use more than one combination of additives. Each known additive The amount of the additive can be freely selected, and according to all the composition, the use of all these known additives should always be at a maximum of 15%. Example A typical embodiment of the present invention will be described in detail below. However, the present invention It is not limited to the substances, strips or process parameters proposed in these examples. (Examples 1 to 9) The composition of the inclined surface lubricating oil of the present invention is shown in Table 1 (Examples 1 to 6) and Table 2 (Examples 7 to 9). For these components, 'I n--i I --- I ----, 1T (Please read the notes on the back before filling this page) 氺 China National Standards for Paper Scale (CNS) Λ4 Specification ( 2 丨 0X297 mm) 470773 3360pif.doc / 002 A7 B7 V. Description of the Invention (q) ~~~~ The following methods are used to evaluate the positioning performance of the machine tool and the separation from the water-soluble cutting lubricant. The results are shown in Table 1 (Examples 1 to 6) and Table 2 (Examples 7 to 9). (Comparative Example) For comparison, the compositions prepared for the slant surface lubricant composition are shown in Table 3 (Comparative Examples 1 to 4) and Table 4 (Comparative Examples 5 to 7). For these components', the positioning performance of the machine tool and the separability from the water-soluble cutting lubricant were estimated by the same method as in Examples 1 to 9. The results are shown in Tables 3 (Comparative Examples 1 to 4) and Table 4 (Comparative Examples 5 to 7). By the way, the ingredients used in the examples and comparative examples are as follows: base oil base oil 1: high solvent refined alkane mineral oil (68.0mm2 / s (@ 40 ° 〇) base 2: mixed oil in poly α-ene The composition ratio of the hydrocarbons (average molecular weight is 650) to trimethylpropyl trilaurate (68.0mm2 / s (@ 40 ° C)) is 65:35 ° (A) What is the composition of the composition? ^ 部 屮 荣 " ^ ^ 、. ^^^ 炎 么 ^:. &Quot; 卬, $ .i · ϊ nn I-I-nl ^ i ..J ^ ·. ^ Ϋ -I ...... II -1 ^ 1 1 ^ 1 to 0, (Please read the precautions of Back® '.' Before filling this page) A1: Oleic acid A2: Glycerol-glycerol trioleate (B) Ingredient B1: Trimethyl phosphate 0 Di-P- ( OC6H4CH3) 3 B2: Diphenyltoluene phosphate ------------ ^ ---- _________20_______________ Zhangzhou Shizhou China National Standard ((: ^) Λ4 Specification (210X297 mm) 470773 A7 3360pif. doc / 002 V. Explanation of the invention ((?) 0 = P- (0C6H4CH3) (0C6H5) 2 B3: Diphenyl phosphate xylene 0 = P- [OC6H3 (CH3) 2] (OC6H5) 2 (C) component C1 : Calcium Carboxylate Containing Calcium Perbasic Calcium (Perbasic Calcium Salt of Petroleum Sulfonic Acid The average molecular weight is 45. The number of all bases (perchlorate method) is 160mg K OH / g, calcium content is 6.6% by weight) C2: Calcium borate containing calcium perbasic salicylate (perbasic calcium salt of alkyl salicylic acid has a 0C-olefin mixture derived from 12 to 20 carbons Alkyl group, the number of bases (perchlorate method) is 170mg KOH / g, brocade content is 6.8% by weight) C3: calcium carboxylate containing calcium perbasic benzene salt (perbasic calcium of alkylphenols) The salt has an alkyl group derived from a mixture of α-olefins of 9 to 18 carbons, and the number of bases (perchlorate method) is 125 mg KOH / g, and the calcium content is 5.7% by weight) C4: Contains perbasic formula Calcium carboxylate of calcium salicylate (perbasic calcium salt of alkyl salicylic acid with alkyl groups derived from a mixture of α-olefins of 12 to 20 carbons, all base numbers (perchlorate method) are 160 mg KOH / g, calcium content is 6.2% by weight) (Positioning efficiency of machine tools) Place the circular test device on the mechanical table. When setting on the XY plane ^ Shi YiΊ (Read the precautions on the back before filling this page ) This paper size applies to China National Standards (CNS) Λ4 size (210X 297 mm) 470773 3360pif.doc / 002 A7 B7 Scaling rate X; II Digestion Penny 5. Description of the invention (good movement of the circle 'measure the circle under the following test conditions (μηι based on "smaller circle, higher positioning efficiency" to make a judgment . Test conditions Circular test device: CMD (Mechanical center obtained from MakiFuraisu company: UB-75-11 (obtained from Nissei Urawa company) Measuring plane: χ_γ plane_ Radius of movement: 200mm Supply speed: 300mm / min Measuring point Number: 1258 points / 360 degrees (separability from water-soluble cutting lubricant) Put 30ml of sample oil and 70ml of water-soluble cutting lubricant into a 100ml measuring cylinder, stopper with a stopper, and then shake the cylinder one Minutes 'After a given period' observe the state of separation. The water-soluble cutting lubricants are as follows: Emulsion type cutting lubricant: JIS K 2241 "Cutting lubricant, type W1, Νο · 1, etc. , The dilution ratio is 10 times the dissolution type cutting lubricant: JIS Κ 2241 "Cutting lubricant ,,, W2 type, No.l, etc., the dilution ratio is 30 times. Chuan Zhen will mention, the judgment of the separation state is as follows: Status cell (21GX297 ^ T ^ -— ^ 1 11-· -1 I m 1 I ^------\,. 今 -0 (Please read the precautions on the back before writing the page on this page) 470773 3360pif. doc / 002 A7 B7 V. Description of the invention (2c〇 The first picture is drawn The different separation layers shown in the measurement column are maintained for a period of time after shaking. Name each separation layer according to Figure 1, and measure the volume (ml) of each layer. From Table 1 to Table 2, the inclined surface according to the present invention The lubricant composition (Examples 1 to 6) was found to have better results in terms of positioning performance, lubricating properties, and separation from water-soluble cutting lubricants when the lubricating oil on the inclined surface was mixed with fluid. Conversely, from Table 3 To Table 4, the compositions of the inclined surface lubricants of Comparative Examples 1 to 7 were found to have poor results in terms of positioning performance, lubricating properties, and water-soluble cutting lubricants. According to the composition of the inclined surface lubricants of the present invention, When the above substances are mixed into a fluid, the separation from the water-soluble cutting lubricant is excellent, and the lubricating properties are also excellent. The lubricating oil composition of this inclined surface does not adversely affect the water-soluble cutting lubricant. (诮(Read the precautionary note before filling out this page)

I sample / 0 .T consumption fr ^ f 卬 f This paper is suitable for Λ medium 闼 national standard (CNS) Λ4 specification (210X 297 mm) 470773 printed by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs

V. Description of the invention (d) 9ύ · 9- 24 9 ^ §ι [6.96] Iffis [ΓΙΤ161 I Tan «t7locia > B3Is

Oooopop'c! Do9 £ rn [ςοι ιν

[Sdl IOQ [soΙα Α.6 0 -OS -0310-os -0 £ 0 Ο-69-1-οε_οΟ _89, (n-6s_iΟ -89-ε -63 ο _ΟΔοοε-ο (A \ .lwlul〇_, i) 0 ^ .0 .0 .02 os-τοε-ο os-l _0r? loz, —ol < N_or? (NOS -ε -οε-ε OS -ο -οε_ο

[000] IV

[601 S ΓΟΙ Ο -69-τοε-ο 0-69-ι-οΓΠ-ι Ο -69-Ι-0ε- (Ν Ο -69-cn_6s Ο _89—inch—8 (ν-inch 0-OS-OS (Λ \ .— 3ιο—2) 69-0-(ν-6 < ν-0 69-0- < ν-6 (ν-1 89_0 _γο—6 (ν_ (ν 009-0 -23 Α9Ι0 —9 _ Bu (ν-90Α_0, 0 -οε—0 inch Luo [inch · inch6] Iss

ΟΊΙ IV ΓΟΙ Ο -69-CN-63 Ο-69- (ν-6 < ν—ι Ο -69cn-6 (n- (n Ο -89-2 (N-ε Ο -bu 9-9 -Z. Sο, 0s .02 (彡 —a—u—o—fe 69-0-τοεό 69 -Ο-«N-6S 009 · 0 _ inch-8CN-1 L9S—LZ-Z inch 9-οο, 9 (ν4ΟΑ _0 -ο-οε · ο (Please read the notes on the back before filling this page) 丽 3 ίδι

Is

[Εο6] ι Thinking S ο · ιη] (Νν

0.1] IS Ι.ΟΙ 0—69-2-63—0 o-oo9rA-6CN_I Ο -Δ9 -7SZ-< Ν Ο -99 -00-93, inch 0-inch 9-11_ £ 2 0-οζ. οοε -ο (Α \ —Η—υ—〇-ΡΗ) 69ό- < Ν-6 < Ν_ 0090-7¾. ^ 89 —04—83 | Inch: A9 —ο 丨 9 ή-9 S9 -Ο -6 -93-00OA -o -o, οε _0 〔6 · ε6〕 z thinking «

OIJ IV [inch.0] ia bu.01 (Λ \ -Η—υιο-ΡΗ) Ο-69- (ν-6 (ν-ι 0-89-76311 Ο -Α9-ιη-00 (Ν— (Ν Ο -99 -Δή-inch 〇, S9, 6 -9CN, /, 〇ΟΑ -0-οεο 69-0-l-oe—l 69_0-Ι-0ε-Ι 69, 0 ', οε — (Ν 69 -Ο -(N-6CN-inch89,04Ι8Z —90bu-ο -ο-οε —ο 'install --------, inch order --------- # _ 1 【ι · > -η6] think for a while

[90] IV

〔Sdl IS

SOI οόζ.-(Ν-6 (ν, 0 0,69-(ν-6 (ν-0 989 _ε _63—ΐ 0_Δ9 -S ώζ—ζ Ο-inch 9-01-93 οο /,-οοεο (Λ \ —3—υ—0_ΡΗ) 69-0—2-62 69—ο- (ν-63-1 009 —ο —ε -6S 009 —ο4—8 (Ν_ε Α9 -Ο, 9 -SΟ 卜 —οο- οε-ο (V) < R chain

(S < R1S U) < R chain

. / 0 _ «IIII (Sri) e inch (N β9 (βε βι (q) soflsM 1« 0000 ^ (I and imll (q) inch ζ β9 (ee βι (eso 鹚 SM IK Opinion f " Paper size applies to Chinese National Standard (CNS) Al specifications (2) 0 X 297 mm 470773

IE A7 B7 Hao: ¾ V. Description of the invention 9a 9, inch < n / 6 / I ooIN: a > tnHr # l} KHJ # ι} »^:« ^ ψ.ane001 SOFOO 城 赃 _lao〇 0POP.G! D09ee_ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy (Nm Example 9 Base oil 1 [93.8] Γ ^ Ί ί— ^ 1_1 < 1-1 P, r—η CQ 1 l CO pi Cj oo On (FOCEW) 0- 30- 0-70- 0 4-29- 3-68- 0 2-29- 2-69- 0 1- 30- 1-69-0 0-30- 0-70- 0 0- 30- 0-70- 0 0- 30- 0- 0-70 4-28- 5- 0-67 2-29- 3- 0-68 1- 29- 2- 0-69 1-30- 1-0 -69 Ό-30- 0- 0-70 Example 8 Base oil 1 [94.7] Α1 [0.6] 1-1 in p, s ρρ Cj On (FOCEW) 0- 30- 0-70- 0 3-28-4 -68-0 2-29- 2-69- 0 1- 30- 1-69-0 1-30- 1-69- 0 0-30- 0-70- 0 0- 30- 0- 0-70 3 -29- 3- 0-68 1- 29- 2- 0-69 0-30- 1- 0-69 0-30- 0- 0-70 0-30- 0- 0-70 Example 7 Base oil 1 [ 95.8] 1-1 pi < B1 [0.5] C2 [0.4] (N ON j (FOCEW) 0- 30- 0-70- 0 3-29- 2-69- 0 2-30- 1-69-0 1- 30- 1-69-0 0-30- 0-70- 0 0-30- 0-70- 0 0- 30- 0- 0-70 4-28- 4- 0-68 2-30- 1 -0-69 1- 30- 1-0-69 0-30- 0- 0-70 0-30- 0- 0-70 Base oil component (A) component (B) component (c) positioning performance measurement (μιη) Water-soluble cutting fluid separability test (ml) Emulsion type cutting fluid before shaking 0.5 (h) 1 (h) 3⑻ 6 (h) 24 (h) Soluble cutting fluid before shaking 0.5 (h) ) 1⑻ 3 (h) 6 (h) 24 (h) Composition weight nnn an nnnn flu I US `` nnnn -n J1 · AB ^ i 1 0¾ ^ -δέ, ν; (Please read the precautions on the back before filling in this Page) This paper size is in accordance with Chinese National Standard (CNS) A < 1 specifications (210 X 297 mm) 470773 A7 B7 f Dong; Γ Supplement i 5. Description of invention. Κί 1:, ;; inch 〇-) / 6 / | 〇〇2: stamped on 031 制 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ίίlip? Llis a so Is splash Φ5 soopop.y! Q.09 £ ro 1 Comparative Example 4 Base Oil 1 [94.2 > So 〇i CN CQ 1 18.2 (FOCEW) 0-30- 0- 70- 0 10-19-28-52-0 8-21-15-63-0 2- 24 -11-64-0 3- 25- 9- 65- 0 3-25- 8-66-0 0-30- 0-0-70 18-0-0- 98-0 13- 1 -0-68- 30 9- 3-0-54-62 5-10-25- 0-65 0-25- 9-0-66 Comparative Example 3 Base oil 1 [93.6] 1 1 pu 28.3 1 (FOCEW) 0-30- 0 -70- 0 20- 0- 99- 0- 0 16- 0- 68-31-0 13-0- 48-50-0 8- 0- 36-61-0 0- 0- 30-60-0 0 -30- 0- 0-70 15- 0- 0-99-0 12- 2- 0-72-25 9- 4- 0-68-30 6- 9-27- 0-64 5-10-25- 0-65 丨 Comparative Example 2 Base oil 1 [92.1] r ^ —ι Τ—Η l—J 1 < < 1 1 10.5 j __1 (FOCEW) 0-30- 0-70- 0 30- 0- 95 -0-0 20- 0- 98-0-0 14-0-98-0-0 10- 2- 47-50-0 8- 5- 40-54-0 0-30- 0- 0-70 30 -0- 0-97-0 23- 0-0-98 -0 18-3-0-73-24 0- 5-0-59-36 0- 8-0-47-45 Comparative Example 1 Base oil 1 [94.6] r, _1 vq 〇 Τ-Η < 1 1 10.3 1 (FOCEW) 0-30- 0-70- 0 30- 0- 95- 0- 0 25- 0-97-0-0 20- 0-97- 0-0 15-0- 98- 0-0 10- 0- 98- 0-0 I 1 0-30-0-0 -70 '27-0- 0- 96- 0 21-0-0- 97- 70 18- 0- 0-98-70 12- 0- 0- 99-70 8-0-3-75-22 base oil component (A) 1 1 component (B) component (c) positioning performance test (μιη) Water-soluble cutting fluid separation test (ml) 0.5 (h) 1 (h) 3 (h) 6 (h) 24 (h) after shaking ) 1 (h) 3⑻ 6 (h) 24 (h) Composition weight% i / c / This paper size is applicable to China National Standard (CNS) A <〗 Specifications (210 X 297 mm) ------- ---- ^ -------- 9 Order --------- ^ (Please read the notes on the back before filling this page) 470773

V. Description of the invention 90. 9 ~ Μ% s / 6 / i (N: a > [nHI «}, -3; :: —») ^ = 5 一 驾 ^ 子 銮 〇〇1360?: 8 ____ 800ρορ.ο! Ιο-09ε £ _ Comparative Example 7 printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 7 Base oil 1 [93.6] 1 1 1 '' " 1 〇ι 1 I 1 〇〇〇 | ΓΟ U 〇 ^ 0 1 1 (FOCEW) 0-30- 0-70- 0 12-18-23-58-0 10-20-17-62-0 9-23-12-64-0 5-25- 7- 67- 0 3-27-5-68-0 0-30- 0- 0-70 13-1-0-98-0 9- 4- 0-40-55 6- 9-26- 0-65 0- 17-17-0-66 0-27-6-0-67 Comparative Example 6 Base oil 1 [95.3] 1 Γ—Ί 5 P, οι U inch ^ 6 Τ—Η (FOCEW) 0- 30-0-70 -0 10-18-23-58-0 8-20-18-61-0 5-25-12-63-0 3-26- 8 -66-0 1- 27- 6-67-0 Ο CN ^ 00 Bu Cun m heart 1 1 1 I 1 1 ο ζί ο cp Ο Ο FREE ^ Ρ! Μ ^ ^ (1 t 1 I ι 〇rH 〇〇ro. 、 一 (ΝCN (Ν 1 1 1 1 1 I 〇 00. Inches m (N Comparative Example 5 Base oil ί [93.9] 1 ST 〇1_1 5 1 1 ρ V '< U VO un 1 < (FOCEW) 0-30- 0-70-0 14-19- 19-61-0 12-25-11-63- 0 18-26- 6 -66- 0 10-27- 5-67-0 4-28-4-68-0 Ο. Ον Inches 〇Ο ーΌ \ 〇1 1 1 1 1 I Ο Ον Ο Ο Ο Ο ώ 2 ^ i ^ ι, Γν ι ι ι 1 1 1 1 1 I Ο Ο inch (N — 〇 base oil component (Α) component (B) component (C) positioning performance test (μιη) 1 fie Xue Mcnso 艺 #i 诿 到 龆 耶 锲 起 嫠 s δ Name keyΐί! Μ! | Ϊ́ϊ 溶 Soluble cutting fluids are shaken before shaking 0.5〇ι) 1 (h) 3 (h) 6 (h) 24 (h) Composition weight (please read the note on the back of the phonetic note before filling out this page) The size of this paper is applicable to the Chinese National Standard (CNS) A < 1 specification (210 X 297mm f)

Claims (1)

470773 No. 8 ^) 9 # 丨 8 No. 8 Chinese Defective Fan Yuan Correction Book dc / 008 A8 B8 C8 D8 Revision + · > .. ”f 'tv» _ _ ·. * Ι · ι_ II · ΐί'βίΐΒ &)) 1/9/24 It consists of a straight chrome HI supplement 1. A kind of lubricating oil for inclined surfaces, including 1 base oil, which is composed of at least one of mineral oil, grease and synthetic oil: (A-1) Carboxylic acids and / or (A-2) esters; and (B) phosphorus-containing esters, as shown in the following chemical formula (1): 0 = P- (0R 丨): (1) where R1 represents 1 to 24 carbons Atomic hydrocarbons, the weight percentage of the component (A-1) is between 0.01 and 40, the weight percentage of the component (A-2) is between 0.01 and 1, and (B) The weight percentage of the ingredients is between 0.01 and 30. ---------------- (Please read the precautions on the back before filling out this page) I Printed clothing by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The composition includes a base oil consisting of at least one of mineral oil, grease, and synthetic oil: (A-1) carboxylic acid and / or (A-2) ester; and (B) phosphorus Esters, as shown in the following chemical formula (1): 0 = P- (0R ') 3 (1) where R1 represents a hydrocarbon having 1 to 24 carbon atoms; and (C) at least one metal organic acid salt, which The metal is selected from alkali metals, salty metals, zinc and lead; wherein the weight percentage of (A-1) component is between 0.01 and 40, and the weight percentage of (A-2) component is between 0.01 and 1 In between, the weight percentage of the (B) component is between 0.01 and 30, and the weight percentage of the (C) component is between 0.01 and 20. 28 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)