TW415975B - Separate-type hydrogen gas and oxygen gas generator - Google Patents

Separate-type hydrogen gas and oxygen gas generator Download PDF

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Publication number
TW415975B
TW415975B TW086106343A TW86106343A TW415975B TW 415975 B TW415975 B TW 415975B TW 086106343 A TW086106343 A TW 086106343A TW 86106343 A TW86106343 A TW 86106343A TW 415975 B TW415975 B TW 415975B
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Taiwan
Prior art keywords
hydrogen
tank
oxygen
communicating
electrolytic solution
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TW086106343A
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Chinese (zh)
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Satoru Miyata
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Satoru Miyata
Kogawa Takashi
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Hydrogen gas and oxygen gas are generated by electrolysis. An electrolyte supply pipe (71) communicating with an electrolyte supply tank (22), an electrolyte drain pipe (9) communicating with an electrolyte drain tank (5) and an oxygen gas circulation pipe (81) communicating with an oxygen gas tank(4) are connected to an anode (11) provided in an electrolysis bath (1). In the same way, an electrolyte supply pipe (72) communicating with an electrolyte supply tank (21), an electrolyte drain pipe communicating with the electrolyte drain tank and a hydrogen gas circulation pipe (82) communicating with a hydrogen gas tank (3) are connected to a cathode (12) provided in the electrolysis bath (1). As the anode and the cathode are separated from each other by an insulator (10) and a diaphragm (15) which can block the penetration of bubbles of hydrogen gas and oxygen gas generated by both the cathode and the anode, the generated hydrogen gas and oxygen gas can be collected separately.

Description

415975 Α7 Β7 五、發明説明(j) 本發明係有關於一種氫氣及氧氣分離型產生裝置^,藉 由電解以產生氫氣及氧氣,Μ可將所產生之氫氣與氧.氣分 別地收集之。 最近,基於天然資源的減少、大氣污染的嚴電化、二 氧化碳之增加所造成之溫室效應等,對於用以取代習用之 石油或煤炭等所謂化石燃料之替代能源的要求是越來越 高。 氫氣及氧氣係,在工業上被當作焊接用或鍋爐用之氣 體燃料而廣泛地使用之,而最近由於亦可當作化石燃料之 替代能源而受到相當大的重視,故目前已有許多可有效率 地產生氫氣及氧氣之氫氣及氧氣分離型產生裝置的開發 在進行中,且已有各種形態之氫氣及氧氣分離型產生裝置 被揭示出。 上述般之氫氣及氧氣分離型產生裝置之一例可舉本 案申請人在日本特願平8-265416號中所揭示出之技術。 經濟部中央標準局員工消費合作社印製 ----J----"裝--------訂 (請先閱讀背面之注意事項再填寫本頁) 此日本特願平8-265416號之技術爲,介由絕緣墊片 以組合3枚以上的電解板,故與習知技術相較下可擴大電 解板與電解液的接觸面積以提高電解效率,且由於電解板 之枚數爲可變而可容易地調整產生氣體量,又藉由在電解 槽與電解液槽間形成循環路以有效率地冷卻電解過程所 產生之熱,又藉由超音波振動機之配設以洗淨電極板並微 細化電解液之水分子群,故可基於空穴效果以大幅地增加 氣體產生量。 3 本紙張尺度適用中國國家標準(CNS ) Α4規格(2!0Χ297公釐) 經濟部中央標準局貞工消費合作社印製 A7 ___B7 _ 五、發明説明( 如上所述般,本案申請人先前所提出之日本特願平 8-26S416號之技術,與習知之氫氣及氧氣分離型產生裝置 相較下’由於可大幅地增加產生氣體量,因此爲相當優異 的技術;但並無法分離電極扳之陽極所產生之氧氣與陰極 所產生之氫氣而分別地收集之,故存在有僅能在氫氣及氧 氣相混合所構成之氫氧化氣體的狀態下收集產生氣體之 問題。 依本發明的申請專利範圍第1項所述之氫氣及氧氣 分離型產生裝置,具備:藉由電解以產生氫氣及氧氣之電 解槽’用以將電解液供給至該電解槽之電解液供給槽,用 以分別地收集該電解槽所產生之氫氣及氧氣之氫氣槽及 氧氣槽’用以將該電解槽內之電解液排出之電解液排出 槽;其特徵在於:設置於前述電解槽內之陽極具備:用以 連通前述電解液供給槽之電解液供給管,用以連逋前述電 解液排出槽之電解液排出管,及用以連通前述氧氣槽之氧 氣流通管;設置於前述電解槽內之陰極具備:用以連通前 述電解液供給槽之電解液供給管,用以連通前述電解液排 出槽之電解液排出管,及用以連通前述氫氣槽之氫氣流通 管;且’藉由絕緣體及可防止兩電極所產生之氬氣及氧氣 的氣泡通過之隔膜以隔開前述陽極與陰極。 依本發明的申請專利範圍第2項所述之氫氣及氧氣 分離型產生裝置,其爲在申請專利範圖第1項所述之氫氣 及氧氣分離型產生裝置中,自電解槽的一端側向另一端側 ___ _4 本紙張尺度適用中國國家CNS )八4現格(210X297公幻 ----:丨—裝----訂 V 4 # (請先閲讀背面之注意事項再填寫本頁) 經濟部中夬標準局負工消費合作社印製 415975 A7 B7 五、發明説明(1) 將至少2個以上之陽極及陰極呈交錯般設置著。 依本發明的申請專利範圍第3項所述之氫氣及氧氣 分離型產生裝置,其爲在申請專利範園第2項所述之氫氣 及氧氣分離型產生裝置中,電解槽係,藉由連結手段之連 結電極、隔膜、絕綠體、.及設匱於其等兩端之一對支持板 以形成一體化。 依本發明的申請專利範圍第4項所述之氫氣及氧氣 分離型產生裝置,其爲在申請專利範圍第3項所述之氫氣 及氧氣分離型產生裝置中,前述電極及絕緣體係形成環 狀。 依本發明的申請專利範圍第5項所述之氫氣及氧氣 分離型產生裝置,其爲在申請專利範圍第1項所述之氫氣 及氧氣分離型產生裝置中,在前述電解槽中設置超音波振 動器。 【圖式之簡單說明】 圖1係顯示本發明的氫氣及氣氣分離型產生裝置的 全體構成之示意圖。 圖2係顯示本發明的氫氣及氧氣分離型產生裝置的 電解槽構成之示意剖面圖。 圖3係顯示本發明的氫氣及氧氣分離型產生裝置之 電解槽的單位構成之分解斜視圖。 【本發明之實施形態】 以下,基於圖面以說明用以實施本發明之最佳形態。 ϋ. - I -- 1 - I I 1 - I— -- I I - I I -11 !:rJ ,T (請先閲讀背面之注意事項再填寫本頁) 5 本紙掁尺度適用中國國家標準(CNS ) Λ4規格(2丨0X297公釐} 415975 Λ7 Β7 五、發明説明(十) 圖1係顯示本發明的氫氣废氧氣分離型產生裝置的 全體構成之示意圖。圖2係顯示本發明的氫氣及氧氣分離 型產生裝置的電解槽構成之示意剖面圖。 氫氣及氧氣分離型產生裝置係具備:藉由電解以產生 氫氣及氧氣之電解槽1’用以將電解液供給至該電解槽1 之電解液供給槽21、22 ’用以分別地收集該電解槽1所 產生之氫氣及氧氣並進行過濾貯藏之氫氣槽3及氧氣槽 4,用以將該電解槽1內部之電解液排出之電解液排出槽 5 〇 電解液供給槽21、22、氫氣槽3及氧氣槽4係設置 在高於電解槽1之位置,並藉由連結管6以將一電解液供 給槽21連結於氫氣槽3,同時將另一電解液供給槽22連 結於氧氣槽4。 電解槽1中設置複數個呈交錯般之陽極與陰極 12。來自被連結在氧氣槽4的電解液供給槽22之電解液 供給管71係插入陽極11中,來自被連結在氫氣槽3的電 解液供給槽21之電解液供給管72係插入陰極12中。 經濟部中央標準局負工消費合作社印製 <請先閱讀背面之注意事項再填寫本頁) 又本發明中,對於電極的材質並沒有特別的限定,只 要是通常電解用電極所使用之材質皆可,例如可爲石墨、 鎳、鉬、二氧化鉛、鐵、鈷等。 如圖所例示般分別設置陽極Π與陰極12各5個,但 其數目並非以此爲限,設置更多的電極或更少的電極皆 可,但以限定在5〜20左右範圔內較佳。 本紙決尺度適用中國國家標準(CNS ) A4規格(2丨Ox:297公釐) 415975 經濟部中央標率局員工消費合作杜印製 A7 ___ B7 _ 五、發明説明(() 其理由爲,若電極數過少則電解效率會變差,故無法 產生大量的氣體;又電極數過多,則爲了保持電極間隔則 電解槽會變得過大。但當使用上對於電解槽之大小沒有特 別的限定時,則電極數設定成越多越好。 又,在陽極11與陰極12上分別設置氧氣取出口 13、 氫氣取出口 14 ;氧氣取出口 13係介由氧氣流通管81與 電解液供給槽22而連結氧氣槽4 ;氫氣取出口 14係介由 氫氣流通管82與電解液供給槽21而連結氣氣槽3。 電解液排出槽5設置在低於電解槽1之位置,藉由電 解液排出管9以連結設置於電解槽1底部之電解液排出 □。 在陽極11與陰極I2間設置絕緣體10及隔膜15,藉 由絕緣體10以保持陽極11與陰極12間之絕緣,又藉由 隔膜I5以防止兩電極所產生之氫氣及氧氣的氣泡之通 過。 如圖3所示般,電極(陽極11與陰極U)及絕緣體10 分別形成環狀。 且,藉由將形成環狀之隔膜15與絕緣體1〇夾在陽極 11與陰極12間,並藉由2枚支持板14夾住這些陽極11 與陰極12,再藉由連結手段(圖示例爲螺栓π及螺帽16) 之連結,以使得其等一體化而構成電解槽1 ^ 又本發明中,電極(陽極Η與陰極12)及絕緣體10之 形狀並非以環形爲限,例如可形成四角形或六角形等框 I I n I n I 扣衣 I n I !L ~~ 訂 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4规格(210 X 297公釐) 415975 經濟部中央標準肩貝工消費合作社印製 五、發明説明(^) 體。當然,此時隔膜15的形狀亦必須配合變化之。 又,結合手段並非以螺栓及螺帽爲限,只要是可強固 地使得電極、隔膜、絕緣體、支持板形成一體化而防止電 解液的洩漏者皆可,例如使用接著劑等亦可;但基於可隨 意地變更電極的數目,則以使用螺栓及螺帽等可結合分離 之結合手段爲較佳。 絕緣體10係,爲了確保電極間之絕緣並防止電解液 自電解槽1之漏出,故必須具有墊片之效果’故宜使用天 然橡膠、丁二烯-丙烯睛、異丁烯、丙乙烯橡膠、矽橡膠、 聚苯乙烯等彈性絕緣材料,視狀況亦可使用絕緣元件被覆 導電性材料的表面者β 隔膜15係,圖示之例係使用網狀材,但只要可通過 電解液並防止兩電極所產生之氫氣及氧氣的氣泡之通過 皆可,故並非以網狀材爲限。 當採用網狀材時以使用木綿或尼龍等材料爲較佳,有 關網目之大小方面,在不妨礙電解液通過之範圍內越小越 好,一般使用100 # m左右者。 當採用網狀材以外者形成隔膜時,適用者爲玻璃紙、 膠棉膜、脫硝膠棉膜、凝膠玻璃紙膜、假羊皮紙、乙烯醇 膜、細菌纖維素膜、脂肪膜、生體膜、半透膜、西爾弗卜 膜、氰亞鐵酸銅等半透膜。 又,由於藉由在電極的內面側,即電解槽內面側設置 突起或凹凸,可增加電極與電解液之接觸面積以提高電解415975 Α7 Β7 V. Description of the invention (j) The present invention relates to a hydrogen and oxygen separation type generating device ^. By electrolysis to produce hydrogen and oxygen, M can collect the generated hydrogen and oxygen. Gas separately. Recently, based on the reduction of natural resources, the strict electrification of air pollution, and the greenhouse effect caused by the increase of carbon dioxide, the demand for alternative energy sources to replace the so-called fossil fuels such as petroleum or coal is increasing. Hydrogen and oxygen are widely used in the industry as gaseous fuels for welding or boilers. Recently they have received considerable attention because they can also be used as alternative energy sources for fossil fuels. The development of a hydrogen and oxygen separation type generation device that efficiently generates hydrogen and oxygen is underway, and various forms of hydrogen and oxygen separation type generation devices have been revealed. An example of the above-mentioned hydrogen and oxygen separation type generating device is the technology disclosed by the applicant of the present application in Japanese Patent Application No. 8-265416. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ---- J ---- " Packing -------- Order (Please read the precautions on the back before filling this page) The technology of -265416 is that more than three electrolytic plates are combined through an insulating gasket, so compared with the conventional technology, the contact area between the electrolytic plate and the electrolyte can be enlarged to improve the electrolytic efficiency. The number is variable and the amount of generated gas can be easily adjusted, and a circulation path is formed between the electrolytic cell and the electrolytic cell to efficiently cool the heat generated during the electrolytic process, and the ultrasonic vibration machine is equipped with Since the electrode plate is washed and the water molecule group of the electrolytic solution is miniaturized, the amount of gas generated can be greatly increased based on the hole effect. 3 This paper size applies the Chinese National Standard (CNS) A4 specification (2! 0 × 297 mm) Printed by Zhenong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 ___B7 _ 5. Description of the invention (As mentioned above, the applicant of this case previously proposed Compared with the conventional hydrogen and oxygen separation type generating device, the technology of Japanese Special Debt No. 8-26S416 is a very excellent technology because it can greatly increase the amount of generated gas; however, it cannot separate the anode of the electrode. The generated oxygen is collected separately from the hydrogen generated by the cathode, so there is a problem that the generated gas can be collected only in the state of a hydrogen gas composed of a mixture of hydrogen and oxygen. According to the invention, The hydrogen and oxygen separation type generating device according to item 1, comprising: an electrolytic cell for generating hydrogen and oxygen by electrolysis to supply an electrolytic solution to the electrolytic solution supply tank of the electrolytic cell to collect the electrolysis separately The hydrogen tank and the oxygen tank generated by the hydrogen tank and the oxygen tank are used to discharge the electrolyte in the electrolytic tank; The anode provided in the electrolytic cell is provided with an electrolytic solution supply pipe for connecting the electrolytic solution supply tank, an electrolytic solution discharge pipe for connecting the electrolytic solution discharge tank, and an oxygen circulation pipe for connecting the oxygen tank ; The cathode provided in the electrolytic cell includes: an electrolytic solution supply pipe for communicating with the electrolytic solution supply tank, an electrolytic solution discharge pipe for communicating with the electrolytic solution discharge tank, and a hydrogen circulation pipe for communicating with the hydrogen tank And 'separate the aforementioned anode and cathode by an insulator and a diaphragm that can prevent the bubbles of argon and oxygen generated by the two electrodes from passing through. The hydrogen and oxygen separation type produced according to item 2 of the scope of patent application of the present invention Device, which is the hydrogen and oxygen separation type generating device described in item 1 of the patent application diagram, from one end side to the other end side of the electrolytic cell ___ _4 This paper is applicable to the national CNS of China) 210X297 Public Fantasy ----: 丨 --------- Order V 4 # (Please read the precautions on the back before filling this page) Printed by the China Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 415975 A7 B7 Explanation of the invention (1) At least two anodes and cathodes are arranged in a staggered manner. The hydrogen and oxygen separation type generating device according to item 3 of the scope of patent application of the present invention is the first one in the patent application park. In the hydrogen and oxygen separation type generating device as described in item 2, the electrolytic cell system is connected by connecting means such as an electrode, a diaphragm, a green body, and a pair of support plates provided at one end to form an integration. According to the hydrogen and oxygen separation type generating device described in item 4 of the scope of patent application of the present invention, the electrode and the insulation system form a ring in the hydrogen and oxygen separation type generating device described in item 3 of the scope of patent application. According to the hydrogen and oxygen separation type generating device described in item 5 of the scope of patent application of the present invention, the hydrogen and oxygen separation type generating device described in item 1 of the scope of patent application is provided in the electrolytic cell. Ultrasonic vibrator. [Brief Description of the Drawings] Fig. 1 is a schematic diagram showing the overall configuration of a hydrogen and gas-separation generating device of the present invention. Fig. 2 is a schematic cross-sectional view showing the configuration of an electrolytic cell of a hydrogen and oxygen separation type generating device of the present invention. Fig. 3 is an exploded perspective view showing a unit configuration of an electrolytic cell of the hydrogen and oxygen separation type generating device of the present invention. [Embodiment of the present invention] Hereinafter, the best mode for implementing the present invention will be described based on the drawings. ϋ.-I-1-II 1-I--II-II -11!: rJ, T (Please read the notes on the back before filling this page) 5 The paper's dimensions are applicable to the Chinese National Standard (CNS) Λ4 Specifications (2 丨 0X297mm) 415975 Λ7 B7 V. Description of the invention (ten) Figure 1 is a schematic diagram showing the overall structure of the hydrogen waste oxygen separation type generating device of the present invention. Figure 2 is a diagram showing the hydrogen and oxygen separation type of the present invention A schematic sectional view of the configuration of the electrolytic cell of the generating device. The hydrogen and oxygen separation type generating device is provided with an electrolytic cell 1 ′ for generating hydrogen and oxygen by electrolysis to supply an electrolytic solution to the electrolytic solution supply tank of the electrolytic cell 1. 21, 22 'Hydrogen tank 3 and oxygen tank 4 for collecting hydrogen and oxygen generated by the electrolytic cell 1 and filtering and storing them, and an electrolytic solution drain tank 5 for discharging the electrolyte in the electrolytic cell 1 〇Electrolyte supply tanks 21 and 22, hydrogen tank 3, and oxygen tank 4 are installed at positions higher than the electrolytic tank 1, and an electrolyte supply tank 21 is connected to the hydrogen tank 3 through a connecting pipe 6, while another An electrolyte supply tank 22 is connected to the oxygen tank 4. A plurality of staggered anodes and cathodes 12 are provided in the electrolytic cell 1. The electrolytic solution supply pipe 71 from the electrolytic solution supply tank 22 connected to the oxygen tank 4 is inserted into the anode 11, and from the hydrogen tank 3 connected The electrolytic solution supply tube 72 of the electrolytic solution supply tank 21 is inserted into the cathode 12. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economics < Please read the precautions on the back before filling this page) Also in the present invention, for the electrode There is no particular limitation on the material of the material, as long as it is a material commonly used for electrolysis electrodes, and examples thereof include graphite, nickel, molybdenum, lead dioxide, iron, and cobalt. As shown in the figure, 5 anodes and 12 cathodes are respectively provided, but the number is not limited to this. More or less electrodes may be provided, but it is limited to a range of about 5 to 20. good. This paper applies the Chinese National Standard (CNS) A4 specification (2 丨 Ox: 297 mm) 415975 Employee consumption cooperation of the Central Standards Bureau of the Ministry of Economic Affairs, printed A7 ___ B7 _ V. Description of the invention (() The reason is that if If the number of electrodes is too small, the electrolysis efficiency will be deteriorated, so a large amount of gas cannot be generated. If the number of electrodes is too large, the electrolytic cell will become too large in order to maintain the electrode interval. However, when the size of the electrolytic cell is not particularly limited in use, The number of electrodes is set to be as large as possible. Also, an oxygen outlet 13 and a hydrogen outlet 14 are provided on the anode 11 and the cathode 12, respectively; the oxygen outlet 13 is connected to the electrolyte supply tank 22 through an oxygen circulation pipe 81 The oxygen tank 4; the hydrogen take-out port 14 is connected to the gas tank 3 through the hydrogen circulation pipe 82 and the electrolyte supply tank 21. The electrolyte discharge tank 5 is disposed at a position lower than the electrolytic tank 1, and through the electrolyte discharge pipe 9 The electrolyte solution discharged at the bottom of the electrolytic cell 1 is connected. An insulator 10 and a separator 15 are provided between the anode 11 and the cathode I2. The insulator 10 is used to maintain the insulation between the anode 11 and the cathode 12, and the separator I5 is used to The passage of bubbles of hydrogen and oxygen generated by the two electrodes is prevented. As shown in FIG. 3, the electrodes (anode 11 and cathode U) and the insulator 10 are respectively formed into a ring shape. Further, the ring-shaped diaphragm 15 and the insulator are formed. 10 is sandwiched between the anode 11 and the cathode 12, and the anode 11 and the cathode 12 are sandwiched by two supporting plates 14, and then connected by a connecting means (the example of the bolt is π and the nut 16) so that These are integrated to form the electrolytic cell 1 ^ In the present invention, the shapes of the electrodes (anode Η and cathode 12) and the insulator 10 are not limited to a ring shape, and for example, a quadrilateral or hexagonal frame II n I n I can be formed. I n I! L ~~ Order (please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 415975 Central Standard Shoulder Worker Consumer Cooperative of the Ministry of Economic Affairs 5. The description of the invention (^) is printed. Of course, the shape of the diaphragm 15 must also be changed at this time. In addition, the coupling means is not limited to bolts and nuts, as long as the electrodes, the diaphragm, the insulator, Support board is integrated to prevent electricity Anyone who leaks the solution can be used, such as adhesives. However, based on the number of electrodes that can be changed arbitrarily, it is better to use bolts and nuts that can be combined and separated. Insulator 10 series, in order to ensure The insulation between the electrodes and the leakage of the electrolyte from the electrolytic cell 1 must be the effect of a gasket. 'It is therefore appropriate to use natural rubber, butadiene-acrylic, isobutylene, propylene rubber, silicone rubber, polystyrene and other elasticity. Insulating materials, depending on the situation, can also use insulating elements to cover the surface of conductive materials. Β diaphragm 15 series, the example shown in the figure uses a mesh material, but as long as it can pass through the electrolyte and prevent the hydrogen and oxygen bubbles generated by the two electrodes It can pass through, so it is not limited to the net material. When using a mesh material, it is better to use materials such as cotton or nylon. As for the size of the mesh, the smaller the range that does not prevent the electrolyte from passing, the better, generally about 100 #m. When a membrane other than a mesh material is used to form the separator, the cellophane film, rubber cotton film, denitrified cotton film, gel cellophane film, fake parchment paper, vinyl alcohol film, bacterial cellulose film, fat film, biofilm, Semi-permeable membranes, such as semi-permeable membranes, silver film, copper ferrocyanate, etc. In addition, by providing protrusions or irregularities on the inner surface side of the electrode, that is, on the inner surface side of the electrolytic cell, the contact area between the electrode and the electrolyte can be increased to improve the electrolysis.

---------^------ΐτ (請先閲讀背面之注意事項再填寫本頁J 本紙張尺度適用中國國家榡準(CNS ) Α4规格(210X297公釐) 415975 A7 B7 五、發明説明(κ ) 效率,故可適當地實施之。 又,較佳之狀態爲,在電解槽1之外面設置超音波振 動器18 β 對於超音波振動器18的種類並沒有特殊的限定,只 要輸出爲100〜1000W/h,可產生頻率數20~60kH左右之 音波者皆可。 藉由將超音波振動器18設置在電解槽1的外面,可 微細化電解液中之水分子群以提高電解速度。此乃基於, 經微細化之水分子群會構成可在電解槽內活潑地移動之 分子群,故會增加其接觸電極表面之頻率而提高了電解速 度。 又由於超音波振動器18具有可除去附著在電極表面 之污物的作用,故藉此亦可提高電解速度。 以下說明本發明的氫氣及氧氣分離型產生裝置之作 用。 將電壓施加至陽極11與陰極12,則電解槽1內之電 解液會產生電解,以分別在陽極11表面產生氧氣、陰極 12表面產生氫氣。 在電解槽內,由於在陽極11與陰極12間藉由可防止 氫氣及氧氣的氣泡逋過之隔膜15以隔開,故所產生之氫 氣及氧氣不致互相混合,因此氧氣可由氧氣取出口 13通 過氧氣流通管81收集在氧氣槽4中,氫氣可由氫氣取出 口 14通過氫氣流通管82收集在氫氣槽3中。 9_ I紙張適用中國國家標华(CNS > Α4現格(210X297公釐) 11 I, I -^-1 J "訂 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印焚 415975 Α7 Β7 五、發明説明(t) .基於上述作用’電解槽1內所產生之氫氣及氧氣不致 混合而可分別被收集在氫氣槽3及氧氣槽4中,故相當方 便地可單獨的作爲氫氣或氧氣使用之,或以所需之混合比 例相混合’因此其使用用途變得相當廣,且可防止基於混 合氣體的產生所導致之危險· 以下’說明本發明的氫氣及氧氣分離型產生裝置之實 施例。 依本發明的氫氣及氧氣分離型產生裝置製造1號 機、2號機' 3號機等3種裝置,分別測定其氫氣產生量、 消耗電力、產生氣體壓力、消費水量;並使用依本案發明 人先前所提出之日本特願平8-265416號之所製造出之3 種氫氣產生裝置作爲比較例,同時進行相同的測定石 (请先閱讀背面之注意事項再填寫本買) 裝. 經濟部中央標準局員工消費合作社印製 比較例 實施例 1號機 2號機 3號機 1號機 2號機 3號機 外觀 W 250 470 522 250 450 500 大小 Η 230 740 945 220 700 900 L 440 715 867 420 700 800 本體重量(Kg) 25 120 346 23 80 180 使用電壓(V) 220 220 3B0 100 200 200 產生量(L/h) 200 1200 2000 400 1200 2000 消耗電力 0.66 5.5 6.6 0.4 1.2 2.0 (kwh) 壓力(kg/cm2) 1.0 0.7 1.0 3.0 3.0 3.0 本紙張·尺度適用中國國家標準(CNS ) A4規格(210'乂297公釐) 415975 A7 B7 五、發明説明(了) 消費水量(L/h) 0.1 0.65 I 1.0 0.2 0.6 1.0 由上述之結果可知,依本發明之氫氣及氧氣分離型產 生裝置,在與習知裝置得出相同的氣體產生量之場合,僅 須使用較小型且較輕量的裝置即可,且使用較少的消耗電 力即可達成。 因此,依本發明之氫氣及氧氣分離型產生裝置,不僅 可將氫氣及氧氣分離開來收集之,且其氣體產生效率也比 習知之裝來得優異。 如上所述般,依本發明之氬氣及氧氣分離型產生裝 置,不僅可作爲銲接用或鍋鑪用之工業用氣體燃料產生裝 置,且所產生之氫氣及氧氣亦可作爲廚餘垃圾等燃燒用燃 料使用之,也就是說其所產生之氫氣及氧氣之用途變得相 當廣泛。 ---------^ ! (請先閲讀背面之注意事項再填寫本頁) 經濟.部中夬標準局員工消費合作社印製 本紙悵尺度適用中国國家標準(CNS ) Λ4規格(210X297公釐)--------- ^ ------ ΐτ (Please read the notes on the back before filling in this page. J This paper size applies to China National Standard (CNS) Α4 size (210X297 mm) 415975 A7 B7 V. Description of the invention (κ) efficiency, so it can be implemented appropriately. Also, it is preferable to set the ultrasonic vibrator 18 outside the electrolytic cell 1 β There is no particular limitation on the type of the ultrasonic vibrator 18 As long as the output is 100 ~ 1000W / h, it can generate sound waves with a frequency of about 20 ~ 60kH. By setting the ultrasonic vibrator 18 outside the electrolytic cell 1, the water molecule group in the electrolytic solution can be miniaturized This is to increase the electrolysis speed. This is based on the fact that the micronized water molecular group will constitute a molecular group that can move actively in the electrolytic cell, so it will increase the frequency of its contact with the electrode surface and increase the electrolysis speed. The device 18 has the function of removing the dirt adhering to the surface of the electrode, so that the electrolysis speed can also be improved. The function of the hydrogen and oxygen separation type generating device of the present invention will be described below. Applying a voltage to the anode 11 and the cathode 12, Electrolytic cell 1 The electrolyte inside will generate electrolysis to generate oxygen on the surface of anode 11 and hydrogen on the surface of cathode 12. In the electrolytic cell, the diaphragm 15 prevents the bubbles of hydrogen and oxygen from passing between the anode 11 and the cathode 12. It is separated, so the generated hydrogen and oxygen are not mixed with each other. Therefore, oxygen can be collected in the oxygen tank 4 through the oxygen take-out port 13 through the oxygen circulation pipe 81, and hydrogen can be collected in the hydrogen tank 3 through the hydrogen take-out port 14 through the hydrogen circulation pipe 82. Medium. 9_ I paper is applicable to China National Standards (CNS > Α4 now (210X297 mm) 11 I, I-^-1 J " Order (Please read the notes on the back before filling this page) Central Ministry of Economic Affairs Standards Bureau employee consumer cooperatives burned 415975 A7 B7 V. Description of the invention (t). Based on the above-mentioned effect, the hydrogen and oxygen generated in the electrolytic cell 1 can be collected in the hydrogen tank 3 and the oxygen tank 4 without mixing. It is quite convenient to use it alone as hydrogen or oxygen, or to mix it in the required mixing ratio ', so its use has become quite wide, and it can prevent the Dangers · The following describes an embodiment of the hydrogen and oxygen separation type generating device of the present invention. According to the hydrogen and oxygen separation type generating device of the present invention, three types of devices such as No. 1 and No. 2 machines are manufactured and measured separately. Its hydrogen generation amount, power consumption, gas pressure generation, and water consumption amount; and three types of hydrogen generation devices manufactured according to Japanese Patent Application No. 8-265416 previously proposed by the inventor of the present case were used as comparative examples, and the same were performed simultaneously. Measurement stone (please read the precautions on the back before filling in this purchase). Packed. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Appearance W 250 470 522 250 450 500 Size Η 230 740 945 220 700 900 L 440 715 867 420 700 800 Body weight (Kg) 25 120 346 23 80 180 Operating voltage (V) 220 220 3B0 100 200 200 Production (L / h) 200 1200 2000 400 1200 2000 Power consumption 0.66 5.5 6.6 0.4 1.2 2.0 (kwh) Pressure (kg / cm2) 1.0 0.7 1.0 3.0 3.0 3.0 This paper · size applies Chinese National Standard (CNS) A4 specification (210 '乂297 mm) 415975 A7 B7 V. Description of the invention (consumed) Water consumption (L / h) 0.1 0.65 I 1.0 0.2 0.6 1.0 According to the above results, according to the hydrogen and oxygen separation type generating device of the present invention, When the device obtains the same amount of gas, it is only necessary to use a smaller and lighter device and use less power consumption. Therefore, according to the hydrogen and oxygen separation type generating device of the present invention, not only the hydrogen and oxygen can be separated and collected, but also the gas generation efficiency is better than that of the conventional device. As described above, the argon and oxygen separation type generating device according to the present invention can be used not only as an industrial gas fuel generating device for welding or boilers, but also the generated hydrogen and oxygen can be used for cooking waste and other waste. The use of fuel, that is, the use of hydrogen and oxygen produced by it has become quite extensive. --------- ^! (Please read the notes on the back before filling out this page) Economy. Ministry of Standards, Bureau of Standards, Bureau of Consumers' Cooperatives, printed this paper, the standard is applicable to Chinese National Standard (CNS) Λ4 specification (210X297 Mm)

Claims (1)

ABCD ! 公告’身' Μ 7T、+讀鼻利耗圍 1.一種氫氣及氧氣分離型產生裝置,具備:藉由電解 以產生氫氣及氧氣之電解槽1,用以將電解液供給至該電 解槽之電解液供給槽21、22,用以分別地收集該電解槽 所產生之氫氣及氧氣之氫氣槽3及氧氣槽4,用以將該電 解槽內之電解液排出之電解液排出槽5 ;其特徵在於: 設置於前述電解槽內之陽極Π具備:用以連通前述 電解液供給槽22之電解液供給管71,用以連通前述電解 液排出槽之電解液排出管9,及用以連通前述氧氣槽之氧 氣流通管81 ;設置於前述電解槽內之陰極12具備:用以 連通前述電解液供給槽21之電解液供給管72,用以連通 前述電解液排出槽之電解液排出管,及用以連通前述氫氣 槽之氫氣流通管82 ;且,藉由絕綠體10及可防止兩電極 所產生之氫氣及氧氣的氣泡通過之隔膜15以隔開前述陽 極與陰極。 2如申請專利範圍第1項所述之氫氣及氧氣分離型產 生裝置,其中,自電解槽的一端側向另一端側將至少2個 以上之陽極及陰極呈交錯般設置著。 3. 如申請專利範圍第2項所述之氫氣及氧氣分離型產 生裝置,其中,電解槽係,藉由連結手段16、17之連結 電極、隔膜、絕緣體、及設置於其等兩端之一對支持板14 以形成一體化。 4. 如申請專利範圍第3項所述之氬氣及氧氣分離型產 生裝置,其中,前述電極及絕緣體係形成環狀。 ----------. — ^------'1τ------Λ * t . (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本纸張尺度適用中國國家標隼{ CNS ) Α4規格(210Χ297公釐) 415975 AS BS C8 D8 申請專利範園 5.如申請專利範圍第1項所述之氫氣及氧氣分離型產 生裝置,其中,在前述電解槽中設置超音波振動器W。 裝-- (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐)ABCD! Announcement 'body' Μ 7T, + reading nose consumption consumption 1. A hydrogen and oxygen separation type generation device, equipped with: an electrolysis cell 1 that generates hydrogen and oxygen by electrolysis to supply electrolyte to the electrolysis The electrolyte supply tanks 21 and 22 of the tank are used to collect the hydrogen and oxygen generated by the electrolytic tank, respectively, the hydrogen tank 3 and the oxygen tank 4, and the electrolyte discharge tank 5 for discharging the electrolyte in the electrolytic tank. It is characterized in that the anode provided in the electrolytic cell is provided with an electrolytic solution supply pipe 71 for communicating with the aforementioned electrolytic solution supply tank 22, an electrolytic solution discharge pipe 9 for communicating with the aforementioned electrolytic solution discharge tank, and An oxygen circulation pipe 81 communicating with the aforementioned oxygen tank; a cathode 12 provided in the electrolytic tank is provided with an electrolytic solution supply pipe 72 for communicating with the aforementioned electrolytic solution supply tank 21 and an electrolytic solution discharge duct for communicating with the aforementioned electrolytic solution discharge tank And a hydrogen flow pipe 82 for communicating with the foregoing hydrogen tank; and, the anode and the cathode are separated by a green insulator 10 and a diaphragm 15 that can prevent the bubbles of hydrogen and oxygen generated by the two electrodes from passing through. 2 The hydrogen and oxygen separation type generating device according to item 1 of the scope of the patent application, wherein at least two anodes and cathodes are arranged in a staggered manner from one end side to the other end side of the electrolytic cell. 3. The hydrogen and oxygen separation type generating device as described in item 2 of the scope of the patent application, wherein the electrolytic cell is connected to the electrode, the diaphragm, the insulator, and one of the two ends by the connecting means 16,17. The supporting plate 14 is integrated. 4. The argon and oxygen separation type production device according to item 3 of the scope of patent application, wherein the electrodes and the insulation system form a ring. ----------. — ^ ------ '1τ ------ Λ * t. (Please read the notes on the back before filling out this page) Staff of Central Bureau of Standards, Ministry of Economic Affairs The paper size printed by the consumer cooperative is applicable to the Chinese national standard {CNS) A4 specification (210 × 297 mm) 415975 AS BS C8 D8 Patent application park 5. The hydrogen and oxygen separation type production as described in item 1 of the scope of patent application An apparatus in which an ultrasonic vibrator W is provided in the aforementioned electrolytic cell. Packing-(Please read the notes on the back before filling this page) Printed by the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs This paper size is applicable to China National Standard (CNS) Α4 size (210 X 297 mm)
TW086106343A 1997-05-12 1997-05-13 Separate-type hydrogen gas and oxygen gas generator TW415975B (en)

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AUPR883901A0 (en) 2001-11-13 2001-12-06 Casey, Alan Patrick Method and means for hydrogen and oxygen generation
JP2004137528A (en) * 2002-10-16 2004-05-13 Naoki Nomura Device for generating gas by electrolysis
JP4695426B2 (en) * 2005-04-01 2011-06-08 三井化学株式会社 Electrolytic tank for producing nitrogen trifluoride gas and method for producing nitrogen trifluoride gas
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JP2977738B2 (en) * 1995-04-28 1999-11-15 神鋼パンテツク株式会社 Hydrogen / oxygen generator

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CN102328972B (en) * 2011-10-27 2012-11-07 大连理工大学 Device and method for treating waste water and preparing hydrogen simultaneously
CN103774170A (en) * 2012-10-23 2014-05-07 黄金宏 Oxyhydrogen circulating delivery conduit of oxyhydrogen manufacturing machine

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