406093 a? _______B7 五、發明説明（1 ) 發明背景: 有機矽氧烷化合物，具低表面張力、潤滑、柔軟、濕 潤、及離型等特性，因此常被應用於其他高分子樹脂的表 面性質改質，改質的方式，有時添加，有時共聚合，有時 接枝，而達成表面改質的目的。 亞克力乳液具有許多用途，廣泛使用於塗料樹脂，接 著，油墨及纖維的後處理劑。亞克力乳液使用於織物背膠 方面，其功能爲不織布剪裁時，不會脫紗。背膠材有許多 種（1)油性亞克力樹脂(2)水性亞克力樹脂，即一般所謂亞克 力乳液，（3)熱熔膠(4)不織布直接以低融點的纖維製成。 塗佈方法（1)全面塗佈，不織布經浸漬槽，壓乾，乾燥。 此種過程常造成含浸樹脂過量，降低不織布的手感。另方 面，織維間的空隙塞滿樹脂，造成不透氣，雖然達成背膠 材的功能，但亦造成品貫下降，與樹脂材料的損耗，（2)泡 沬塗佈方法，也就是所謂點狀塗佈，此種方法，不僅能達 成背膠材之功能，不會造成手感下降與不透氣的缺點，而 且區域性的點狀分散，也節省耗材。 經濟部中央標準局員工消費合作社印製 I---.--(1--裝-------.訂 (請先閱讀背面之注意事項再填寫本頁) 通常點狀塗佈背膠都使用亞克力乳液，在塗佈加工 時，必須先機械方式，強力攪拌，打成泡沬狀態，爲維持 均一細緻的泡沬與一定高度的泡高，即所謂穩定度，必須 加入一種穩泡劑，這種穩泡劑絕大部分爲矽油或改質的矽 油，此種穩泡劑，雖然能維持泡沬高度一定時間，但無泡 沬再現性，亦即泡沬隨時間流逝，再重新強力攪拌起泡， 也無法恢復所需加工的泡沬高度，意即變成有抑泡現象。 406093 經濟部中央標準局員工消費合作社印製 五、發明説明（2) 同時新塡加之矽油，殘存於背膠材中，造成接著力下降。 爲解決上述外加穩泡劑缺點，本發明利用習知矽化物 接枝亞克力乳液的技術，以特定組成之矽化物接枝亞克力 乳液，經適當各種添加劑的調製，完成本發明“具自控泡亞 克力乳液組成”。 發明目的: 本發明的目的係提供一種有關具自控泡能力的亞克力 乳液組成，該組成乳液經外加機械式強力攪拌發泡，不會 產生凝集現象，所形成之乳液泡沬呈均勻細緻狀態，且能 維持一時間的泡沬高度，並有再現能力，意即泡沬消失或 泡高下降後，再重新強力攪拌發泡，亦能獲得原來的結果。 該組成亞克力乳液係一種矽化物接枝的亞克力乳液經 適當的塡加劑、增粘劑、凝集劑、濕潤劑等成份的調配而 成，可應用於非織物的泡沬背膠材。 發明詳細說明: 一般亞克力乳液，經特定攪拌葉或蝶式攪拌盤以 500〜io,oo〇rpm，高速攪拌10秒〜10分鐘乳液會呈現出比原 乳液高上幾倍的高度，以及不同泡沬的綿密程度，乳膠經 攪拌起泡過程，視其機械安定性的不同，某些乳膠會立即 凝聚膠化而不堪使用，而一般乳膠起泡後，隨時間的流逝， 會逐漸破泡/消泡而復原，同時泡沬通常大小不一，在含有 砂聚合物(如Silicone oil)添加的場合，泡沬大小較均一，但 由於Silicone oil的存在下，經常影響乳膠的性能，如接著 力。 4 本紙張尺度適用中國國家標¥ ( CNS ) Α4規格（210Χ297公釐） -------.—---1.--.裝-- I · (請先閲讀背面之注意事項再填寫本頁)406093 a? _______B7 V. Description of the invention (1) Background of the invention: Organic siloxane compounds have low surface tension, lubricity, softness, wetting, and release characteristics, so they are often used to modify the surface properties of other polymer resins. Quality, modification methods, sometimes added, sometimes copolymerized, sometimes grafted to achieve the purpose of surface modification. Acrylic emulsions have many uses and are widely used in coating resins, adhesives, inks and fiber post-treatment agents. Acrylic emulsion is used for fabric backing. Its function is not to take off yarn when cutting non-woven fabric. There are many types of adhesive materials (1) oily acrylic resins, (2) water-based acrylic resins, generally known as acrylic emulsions, (3) hot-melt adhesives, and (4) non-woven fabrics made directly from low-melting-point fibers. Coating method (1) Comprehensive coating, the non-woven fabric is passed through a dipping tank, pressed to dry, and dried. This process often results in an excessive amount of impregnated resin and reduces the feel of the non-woven fabric. On the other hand, the gap between the weaving dimensions is filled with resin, which causes airtightness. Although it achieves the function of the backing material, it also results in a drop in product quality and loss of resin materials. (2) Foam coating method, also known as dot This method can not only achieve the function of the backing material, but also not cause the disadvantages of reduced hand feel and airtightness. It can also be dispersed in a dot pattern and save consumables. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs I ---.-- (1--install -------.) (Please read the precautions on the back before filling this page) Usually dot-coated back All glues use acrylic emulsions. During the coating process, they must be stirred mechanically and foamed. In order to maintain a uniform and fine foam and a certain height of foam, the so-called stability, a stable foam must be added. Most of this foam stabilizer is silicone oil or modified silicone oil. Although this foam stabilizer can maintain the foaming height for a certain period of time, it has no foaming reproducibility, that is, foaming over time, and then re- Strong stirring and foaming can not restore the foaming height required for processing, which means that it has foam suppression phenomenon. 406093 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (2) At the same time, new silicone oil and silicone oil remain in In the adhesive material, the adhesive force is reduced. In order to solve the above-mentioned disadvantages of the added foam stabilizer, the present invention uses the conventional silicide grafted acrylic emulsion technology to graft the acrylic emulsion with a silicide of a specific composition, and is adjusted by appropriate various additives. Complete the present invention "Composition of self-controlling foam acrylic emulsion". Purpose of the invention: The purpose of the present invention is to provide a composition of acrylic emulsion with self-controlling foaming ability. The composition emulsion is foamed by mechanical stirring with strong mechanical force. The formed emulsion foam is uniform and delicate, and can maintain the foam height for a period of time, and has the ability to reproduce, which means that after the foam disappears or the foam height decreases, the foam can be stirred and foamed again to obtain the original results. The composition acrylic emulsion is a silicide-grafted acrylic emulsion prepared by blending appropriate additives, tackifiers, coagulants, humectants and other ingredients, which can be applied to non-woven foam backing materials. Detailed description: General acrylic emulsion, through a special stirring blade or butterfly stirring plate at 500 ~ io, oo〇rpm, high speed stirring for 10 seconds ~ 10 minutes, the emulsion will show several times higher than the original emulsion, and different foams Depending on the mechanical stability of the latex, the latex will foam immediately after being stirred. After foaming, the foam will gradually break / defoab and recover with the passage of time. At the same time, the foams are usually of different sizes. When sand polymers (such as Silicone oil) are added, the foams are more uniform in size. In the presence of oil, it often affects the properties of latex, such as adhesion. 4 This paper size applies to the Chinese national standard ¥ (CNS) A4 specification (210 × 297 mm) -------.---- 1 .-- .Installation-I · (Please read the precautions on the back before filling this page)
:1T 「多一此 . I補无氕〜” A 7 —* ' B7 五、發明説明（3) 為克服上述泡沫的不均一及不穩定性，本發明直接將特 足及定量的有機矽化合物接枝於特定組成之亞克力乳液，並 經適當的填加物調配，製成具自控泡能力的亞克力乳液組成 物。 習知藉有機矽化合物接枝亞克力乳液達成改質目的的 有：USP 4,987，180, USP 4,985,155係有關纖維柔軟與彈性改 質；，日本特許平3-227312係有關安定性及常溫架橋；日本特 許平3-227313係有關溶液聚合無機材粘合劑；EP0,350,240係 有關硬化塗料及油漆；日本特許昭63_227670，USP 3,575,910 ’ USP 3,294, 725係有關潤滑性離型性、潑水性塗 料等。 本發明使用之有機矽化合物接枝亞克力乳液，其中有機 石夕化合物為含乙烯端基或丙婦端基之矽氧烷化合物，如 S710(Dow Coming)，接枝量0.1 〜3.〇wt%，以0_5〜1.5wt0/〇為 適當’接枝之亞克力乳液，固含量為40〜5〇wt%，乳化粒徑 為120〜180nm，玻璃轉移溫度Tg為-HTC〜1(TC，為適當特定 組成的乳液樹脂。有機梦化合物含量約佔亞克力乳液固含量 的0.5〜5.0wt% 〇 經濟部中央標準局員工消費合作社印製 (請先聞讀背面之注項再填寫本頁) 使用之填充劑爲無機填充劑，如磁_鈣或二菌北功。本 發明使用的碳酸鈣有三種粒徑：NS-400，NS-1000，及SS-30， 填加方式有：(】)碳酸弼預先處理成糊狀，再加入乳液中混合， (2)碳酸鈣直接加入乳液混合。前者，將碳酸鈣用攪拌機或球 磨機預先磨成40〜60wt%糊狀物，竣酸鈣粒徑以NS-1000爲 適當，若使用55wt%糊狀物，其使用量爲40〜6〇phr (per hundred msin)，（40〜60phr是指有機矽化合物接枝亞克力乳 液與填充劑混合重量比例爲100 : 40〜60。）而以50phr爲適當。 - 5-(修正頁） 本紙張尺度逋用中國國家標準（CNS ) M規格（2丨〇><297公釐） 4060 ⑽五、發明説明（4 ) A7 B7 修正補无 經濟部中央標準局員工消費合作社印製 増粘劑可使用聚乙稀醇(PVA)或織維n中继錐素可 A輕丙基纖維素、射基纖維素、醋酸曱基纖維素、或酷酸 丁基纖維素。具ϋ的市售^例子為：Bp_5__絲、Bp_2〇 及BP-24E(長春聚乙埽醇PVA)，幾丙基纖維素⑼％)，結 果顯πΗΡ{3優於BP-5、BP-20，以及BP-24E的穩泡效果，且 不會造成碳酸鈣沈澱的現象。增粘劑使用量為1〜6phr，而 以3〜4phr為適當。 凝集劑I為氨电或胺類化合物，Hi的氤十，或含 2個碳至6個碳之絲馆液。若仙3_。錢水，使用量為 0.8phr〜1.6phr，而以1.2〜i.4phr為適當。 濕潤劑可使組成乳液增加被塗佈物的濕潤性，本發明使 用之濕潤劑314聚鍵醇類，j·艚砧例子^聚乙二醇(peg)， 其为子量可為200〜1000，而以分子量400〜600為適當，其 使用量為4〜12phr ’而以6〜8phr為適當。 爲讓本發明之上述和其他目的、特徵、和優點能更明顯 易懂，下文特舉一些較佳實施例，並配合所附表格，作詳細 説明如下： 《實施例1》矽化合物接枝亞秀.力菌,液(丨)之劁借 本發明矽化合物接枝亞克力乳液聚合製備裝置，如一般 亞克力樹脂乳液合成裝置，包括：授拌機（日製DC_rt型）、 四口型反應槽4L、pyrex玻璃裝置、加熱包、溫控器、熱感 應器(Sensor)、冷卻管、氮氣。反應成份依a、b、c、D、£ 分別先配製’再依反應時間逐次加入反應槽中。本反應採氧 化還原方法，反應時間約共320分鐘，每隔約30分鐘逐 (请先聞讀背面之注項再填寫本頁) 丁 一 6—(修正頁): 1T "More than one. I fill without 氕 ~" A 7 — * 'B7 V. Description of the invention (3) In order to overcome the unevenness and instability of the above-mentioned foam, the present invention directly applies a specific and quantitative organosilicon compound It is grafted on acrylic emulsion with specific composition and formulated with appropriate additives to make acrylic emulsion composition with self-controlling foaming ability. Acrylic emulsions grafted with organosilicon compounds have been used to achieve the purpose of modification: USP 4,987,180, USP 4,985,155 are related to the softness and elasticity of fibers; Japan Patent Hei 3-227312 is related to stability and normal temperature bridges; Japan is licensed Hei 3-227313 is related to solution polymerized inorganic material adhesives; EP0,350,240 is related to hardened coatings and paints; Japanese Patent No. 63_227670, USP 3,575,910 'USP 3,294,725 is related to lubricity and release, water-repellent coatings, etc. The organosilicon compound grafted acrylic emulsion used in the present invention, wherein the organosilicon compound is a siloxane compound containing an ethylene end group or a propyl end group, such as S710 (Dow Coming), and the graft amount is 0.1 to 3.0% by weight. 0 ~ 5 ~ 1.5wt0 / 〇 as appropriate 'grafted acrylic emulsion, solid content is 40 ~ 50wt%, emulsified particle size is 120 ~ 180nm, glass transition temperature Tg is -HTC ~ 1 (TC, as appropriate specific Emulsion resin consisting of organic dream compounds, which accounts for about 0.5 to 5.0% by weight of the solid content of acrylic emulsions. 〇 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page). It is an inorganic filler, such as Magnetic Calcium or Erfang Beigong. The calcium carbonate used in the present invention has three particle sizes: NS-400, NS-1000, and SS-30. The adding methods are: ()) Process into a paste and mix with the emulsion. (2) Calcium carbonate is directly added to the emulsion and mixed. In the former, the calcium carbonate is pre-milled into a 40-60 wt% paste with a blender or a ball mill. To be appropriate, if 55wt% paste is used, the amount used is 40 ~ 60 phr ( per hundred msin), (40 ~ 60phr refers to the mixing weight ratio of organosilicon compound-grafted acrylic emulsion and filler is 100: 40 ~ 60.) and 50phr is appropriate.-5- (correction page) This paper is not applicable China National Standard (CNS) M Specification (2 丨 〇 < 297 mm) 4060 ⑽5. Description of the invention (4) A7 B7 amendments to supplement the printing of adhesives printed by employees' cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Ethyl alcohol (PVA) or weaving n-cone may be light propyl cellulose, radiocellulose, ethyl acetate, or butyl cellulose. Examples of commercially available products include: Bp_5__silk, Bp_2〇 and BP-24E (vinca polyacetate PVA), isopropyl cellulose ⑼%), the results showed that πΗP {3 is better than BP-5, BP-20, and stable foam of BP-24E Effect without causing precipitation of calcium carbonate. The amount of the thickener used is 1 to 6 phr, and 3 to 4 phr is appropriate. The agglutinating agent I is an ammonium or amine compound, Hi 氤 氤, or silk solution containing 2 to 6 carbons. Roxian 3_. Money water, the amount used is 0.8phr ~ 1.6phr, and 1.2 ~ i.4phr is appropriate. The wetting agent can make the composition emulsion to increase the wettability of the coated object. The wetting agent 314 used in the present invention is a poly-bond alcohol, j. Anvil example ^ polyethylene glycol (peg), which can be 200 ~ 1000 in sub-quantity. However, a molecular weight of 400 to 600 is appropriate, and its use amount is 4 to 12 phr ', and 6 to 8 phr is appropriate. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, some preferred embodiments are given below, and the accompanying table will be described in detail as follows: "Example 1" Silicon compound grafted Xiu.li bacteria, liquid (丨) of the invention by the invention of silicon compound grafted acrylic emulsion polymerization preparation device, such as general acrylic resin emulsion synthesis device, including: blender (DC_rt type), four-port reaction tank 4L , Pyrex glass device, heating bag, thermostat, heat sensor (Sensor), cooling pipe, nitrogen. The reaction components are first prepared according to a, b, c, D, and £, and then added to the reaction tank one by one according to the reaction time. This reaction uses an oxidation reduction method. The reaction time is about 320 minutes, and every 30 minutes (please read the note on the back before filling this page) Ding 6— (correction page)
修正 福充 406093 A? ---------B7 五'發明説明（5) 次加入，溫度控制在45°c〜50。(：内，攪拌速度160〜280rpm。 表(1)為A、B、C、D、E先行配製液，Λ為預乳化物配製液， Β為pH調整劑，C、D、Ε為起始劑。全部含量約2427克’固 含量1092克(45%) ’ S-710為有機石夕化合物l〇.3g，約佔固含量 之。合成步驟如矣(7)所示。 《實施例2〜4》硬化合物接枝亞克力乳液(2-4)之锄_ 合成配方及合成步驟如實施例1 ’唯其中s_71〇用量由 1〇.38改成5.：^、30_9§、51.56’其用量比例分別約為〇.5〇/0、3〇/0、 5%(固含量比）。 if裨例^^_8》具自控泡能力之亞克力乳液組成物匍偌 上述實施例1-4所得之有機矽化合物接枝亞克力乳液(μ4) 各取lOOphr，分別加入增粘劑(HPC10%) 3.6phr、填充劑(預 先處理球磨碳酸鈣55%)53phr，凝集劑(氨水3〇%)i.4phr，濕 潤劑(聚乙二酵)6phr後，以特定攪拌葉強力糌棘估夕。 授掉條件為4500rpniX2分鐘。其結果如表(3、。 《比較例1》 合成配方及合成步驟如實施例1 ’唯其中S-710用量為〇(不 加）’所得之亞克力乳液並依實施例^^之步驟分別加入增 粘劑、填充劑、凝集劑及濕潤劑，以特定攪拌葉強力攪拌使 之均勻。攪拌條件為4500rpmX2分鐘。其結果如表(3)所示。 -7-(修正頁) ( CNS ) A4«^ ('il〇X297i：i 5 ' I. .1 - - - HI - - τ- --. I ---: ----I I ----I F · . - (請先閲讀背面之注意事項再填寫本頁) 經濟部中央梯率局員工消費合作杜印製 406093 A7 B7Amend Fuchong 406093 A? --------- B7 Five 'invention description (5) Add, temperature controlled at 45 ° c ~ 50. (Inside, the stirring speed is 160 ~ 280 rpm. Table (1) is A, B, C, D, E first preparation solution, Λ is pre-emulsion preparation solution, Β is pH adjuster, C, D, E are starting The total content of about 2427 grams 'solid content 1092 grams (45%)' S-710 is 10.3 g of organic stone compound, accounting for about the solid content. The synthetic steps are shown in (7). << Example 2 ~ 4 "锄 of hard compound grafted acrylic emulsion (2-4) _ The synthetic formula and synthetic steps are as in Example 1 except that the amount of s_71〇 was changed from 10.38 to 5.:^, 30_9§, 51.56 'which The dosage ratios are about 0.50 / 0, 30/0, and 5% (solid content ratio) respectively. If exemplified ^^ _ 8 "Acrylic emulsion composition with self-controlling foaming ability 所得 Obtained from the above Examples 1-4 The organosilicon compound-grafted acrylic emulsion (μ4) each took 100 phr, and added a thickener (HPC10%) 3.6 phr, a filler (pre-treated ball-milled calcium carbonate 55%), 53 phr, an aggregating agent (aqueous ammonia 30%) i. After 4 phr, wetting agent (polyethylene glycol) 6 phr, it is estimated that the strength of the specific stirrer leaves is strong. The conditions of the teaching are 4500 rpniX for 2 minutes. The results are shown in Table (3. Comparative Example 1) Example 1 'Acrylic emulsion obtained by using S-710 in an amount of 0 (no addition)' and adding the thickener, filler, aggregating agent and wetting agent according to the steps of Example ^^, and vigorously stirred with a specific stirring leaf Make it uniform. The stirring conditions are 4500 rpm × 2 minutes. The results are shown in Table (3). -7- (Correction page) (CNS) A4 «^ ('il〇X297i: i 5' I.. 1---HI --τ--. I ---: ---- II ---- IF ·.-(Please read the precautions on the back before filling out this page) Printed by the Consumer Affairs Cooperation of the Central Slope Bureau of the Ministry of Economic Affairs 406093 A7 B7
五、發明説明（6 ) 表(1)矽化合物接枝亞克力乳液之合成配方 成份編號 組成份 添加量(g) 固成份(g) A (預乳化物） DS-4(10%) 153.3 15.33 NP-6 17.5 17.5 NP-9 17.5 17.5 去離子水 518 — 硫醇 1.6 1.6 I-Acid 10.3 10.3 2-HEMA 31 31 MMA 6.2 6.2 AN 103 103 BA 103 103 EA 770 770 S-710 10.3 10.3 B 醋酸(10%) 7 — 去離子水 2.87 — C AP 2.52 2.52 去離子水 70 — D t-BHP 1.0 1.0 去離子水 70 — E SFS 2.66 2.66 去離子水 245 — Total 2,427 1,092 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 DS-4 :十二基笨績酸納(dodecylbenzene sulfonic acid;中曰合成公司) NP_6 :含6個E0之界面活性劑(中日合成公司） NP-9 :含9個E0之界面活性劑（中日合成公司） 1- acid :衣康酸(itaconic acid) 2- HEMA :曱基丙稀酸-2-經基乙8l(2-hydroxyethyl methacrylate) MMA : 2-曱基丙烯酸甲 g旨(methyl methacrylate) AN :丙烯騰(acrylonitrile) BA :丙烤酸丁醋(butyl acrylate) EA :丙晞乙醋(ethyl acrylate) S-710 :含丙稀端基之碎氧坑化合物(D〇wComing公司） AP :過硫酸銨(ammonium persulfate) t-BHP :三級過氧丁醇(t-butyl hydroperoxide) SFS :甲酸硫醯納(sodium formaldehyde sulfate) —8 —(修正頁) 本紙張尺度適用中國國家梂準（CNS ) A4規格（210X297公釐） 406093 A7 B7V. Description of the invention (6) Table (1) Synthetic formula of silicon compound grafted acrylic emulsion Composition number Composition amount (g) Solid content (g) A (pre-emulsified product) DS-4 (10%) 153.3 15.33 NP -6 17.5 17.5 NP-9 17.5 17.5 Deionized water 518 — Mercaptan 1.6 1.6 I-Acid 10.3 10.3 2-HEMA 31 31 MMA 6.2 6.2 AN 103 103 BA 103 103 EA 770 770 S-710 10.3 10.3 B Acetic acid (10% ) 7 — Deionized water 2.87 — C AP 2.52 2.52 Deionized water 70 — D t-BHP 1.0 1.0 Deionized water 70 — E SFS 2.66 2.66 Deionized water 245 — Total 2,427 1,092 (Please read the precautions on the back before filling (This page) Consumption cooperation by employees of the Central Bureau of Standards of the Ministry of Economic Affairs Du-print DS-4: dodecylbenzene sulfonic acid (Zhongyue Synthetic) NP_6: Surfactant containing 6 E0 (China-Japan Synthetic) ) NP-9: 9 E0-containing surfactants (Chung Nippon Synthetic Corporation) 1- acid: itaconic acid 2-HEMA: fluorenyl acrylic acid 2-mercaptoethyl 8l (2-hydroxyethyl methacrylate) MMA: 2-methyl methacrylate AN: acrylonitrile BA: Baked acid butyl acrylate EA: ethyl acrylate S-710: Acrylic end group-containing broken oxygen pit compound (DowComing) AP: ammonium persulfate t-BHP : T-butyl hydroperoxide SFS: sodium formaldehyde sulfate —8 — (correction page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) 406093 A7 B7
五、發明説明（7) 經濟部中央標準局員工消費合作社印製 表(2)矽化合物接枝亞克力之合成步驟 時間(分） 步驟 加料順序 0 0 開機，B成份入反應槽，攪拌 N2 Sweep 15 1 (A)100g 加入 (C，D)各3.8g (E)12.8g 160 rpm 45 2 (A)100g (C，D)各4.5g (E)15g 160 rpm 75 3 (A)150g (C，D)各5.7g (E)19.2g 160 rpm 105 4 (A)200g (C，D)各7.6g (E)25.6g 180 rpm 135 5 (A)200g (C，D)各7.6g (E)25.6g 200 rpm 165 6 (A)200g (C，D)各7.6g (E)25.6g 220 rpm 195 7 (A)250g (C，D)各9.5g (E)32g 240 rpm 225 8 (A)250g (C, D)各9.5g (E)32g 260 rpm 255 9 (A)250g (C，D)各9、5g (E)32g 280 rpm 285 10 餘(C, D, E)加入 280 rpm 一 9 —(修正頁） 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 83. 3.10,000 ---L——.----裝------lir-ll·---線 (請先聞讀背面之注意事項再填寫本頁) 406093 A7 _________ ___B7 五、發明説明（7) 表(3)發泡結果評估 矽化合物接枝 亞克力乳液來源 ------ 實施例1 Γ _ 實施例2 實施例3 實施例4 比較例1 S-710在原亞克力 乳液含量 1% 0.5% 3% 5% 0% 起泡倍率 3.5 細緻均一 3.5 細敏均一 卜3.5 細敏均一 3.85 細敏均一 3 略粗不均 泡沫均質性 3hrs後消泡率 未消泡 未消泡 未消泡 未消泡 全部 lOhrs後消泡率_ 7% 30% 11% 100% 全部 lOhrs碳酸鈣沈澱 些微 — 些微 1/10 全部 中等 一- — 雖然本發_-錄佳實關揭露如上，並非用以 限定本發明’任何Μ此賴者，在錢離本發明之精神和 犯圍内’當可作些狀更祕_，目此本發明之保護 當視後附之申請專利範圍所界定者為準。 10 -(修正頁)V. Description of the invention (7) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (2) Synthesis time of silicon compound grafted with acrylic acid Step time (minutes) Step feeding sequence 0 0 Start, B component into reaction tank, stir N2 Sweep 15 1 (A) 100g (C, D) each 3.8g (E) 12.8g 160 rpm 45 2 (A) 100g (C, D) each 4.5g (E) 15g 160 rpm 75 3 (A) 150g (C, D) each 5.7g (E) 19.2g 160 rpm 105 4 (A) 200g (C, D) each 7.6g (E) 25.6g 180 rpm 135 5 (A) 200g (C, D) each 7.6g (E) 25.6g 200 rpm 165 6 (A) 200g (C, D) 7.6g each (E) 25.6g 220 rpm 195 7 (A) 250g (C, D) 9.5g each (E) 32g 240 rpm 225 8 (A) 250g (C, D) each 9.5g (E) 32g 260 rpm 255 9 (A) 250g (C, D) each 9, 5g (E) 32g 280 rpm 285 10 more (C, D, E) add 280 rpm a 9 — (Correction page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 83. 3.10,000 --- L ——.---- installation ------ lir-ll · --- line (please read the notes on the back before filling this page) 406093 A7 _________ ___B7 V. Description of the invention (7) Table (3) Evaluation of foaming results Silicone grafted acrylic emulsion source --- Implement 1 Γ _ Example 2 Example 3 Example 4 Comparative Example 1 S-710 in the original acrylic emulsion content 1% 0.5% 3% 5% 0% Foaming ratio 3.5 Fine uniform 3.5 Fine uniformity 3.5 Fine uniform 3.85 Fine Uniform 3 Slightly coarse, uneven foam, homogeneity, defoaming rate after 3hrs, no defoaming, no defoaming, no defoaming, no defoaming. All defoaming rates after 10hrs _ 7% 30% 11% 100% all 10hrs calcium carbonate precipitates slightly-slightly 1 / 10 All Medium One-Although the disclosure of Lu Jia Shiguan is disclosed above, it is not intended to limit the present invention to "any person who depends on it, within the spirit and guilty of the present invention" should make some changes. Therefore, the protection of the present invention shall be determined by the scope of the attached patent application. 10-(correction page)