CN105780586B - A kind of resistance to white spirit cleans water-based gloss oil - Google Patents
A kind of resistance to white spirit cleans water-based gloss oil Download PDFInfo
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- CN105780586B CN105780586B CN201610209650.6A CN201610209650A CN105780586B CN 105780586 B CN105780586 B CN 105780586B CN 201610209650 A CN201610209650 A CN 201610209650A CN 105780586 B CN105780586 B CN 105780586B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of resistance to white spirit and cleans water-based gloss oil, is made up by mass percentage of following raw material：Anti- white appliances fat liquor 90 95%；Wax assistant 1 5%；Slipping agent（DC‑51）0.1‑0.5%；Coalescents 1 3%；Water cross-linking agent 1 2%；Organic silicon defoamer 0.1 0.3%；Deionized water 0 3%.The water-based gloss oil is environmentally friendly, nontoxic, suitable for the surface coating process of high-grade paper, the paper after coating is had an excellent scrub effect of resistance to white spirit, and gloss is high, anti-hot water, folding, seemingly fill bark effect, greatly improve product packaging class.
Description
Technical field
The present invention relates to water-based gloss oil art, refers in particular to a kind of resistance to white spirit and cleans water-based gloss oil.
Background technology
White spirit scientific name n-hexane, is often called：Machine water, water of wiping one's face, decontaminated water are smeared, is often industrially used as cleaning agent, is
The wide variety of chemical substance of the industries such as hardware, electronics, printing and shoemaking.In printing packaging industry, add after usually there is paper product
Man-hour has stain the problem of glue, the glue on paper product surface can be now cleaned with white spirit, this requires the gloss oil on paper product surface
Coating does not damage after white spirit is cleaned, and reaches the effect of protection printing.
However, traditional anti-white spirit gloss oil is oiliness, though excellent performance, environmental issue protrudes.In recent years, city
Occur many anti-white spirit water-based gloss oils on field, although meeting the needs of market to a certain extent, often go out
The problem of existing various, such as glossiness are not high enough, and either effect resistant to bending is poor or the scrub effect of resistance to white spirit is bad,
Sticked together when either not anti-hot water or printing stack together etc..Therefore, the performance of anti-white spirit water-based gloss oil urgently changes
It is kind.
The content of the invention
In view of this, in view of the existing deficiencies of the prior art, its main purpose is to provide a kind of resistance to white spirit and wiped the present invention
Water-based gloss oil is washed, it not only has the excellent scrub effect of resistance to white spirit, is also equipped with anti-hot water, resistant to bending, bloom, resist blocking and that
Characteristic, suitable for the surface coating process of high-grade paper, bark effect is seemingly filled, greatly improves product specification, and play good guarantor
Shield acts on.
To achieve the above object, the present invention is using following technical scheme：
A kind of resistance to white spirit cleans water-based gloss oil, is made by mass percentage by the mixing of following raw material is scattered：
Anti- white appliances fat liquor 90-95%；
Wax assistant 1-5%；
Slipping agent 0.1-0.5%；
Coalescents 1-3%；
Water cross-linking agent 1-2%；
Organic silicon defoamer 0.1-0.3%；
Deionized water 0-3%；
The mass percent sum of above raw material is 100%.
As a kind of preferred scheme, the anti-white appliances fat liquor is made up of following raw material by mass percentage：
Protecting colloid 40-50%；
Methyl methacrylate 12-16%；
Butyl acrylate 8-10%；
Isooctyl acrylate monomer 8-10%；
Acrylamide 0.5-1%；
Vinyl silicone oil 1-2%；
Neopelex 0.5-1%；
Ammonium persulfate 0.3-0.8%；
TBHP 0.01-0.05%；
Hold white piece of 0.01-0.05% in the month；
Deionized water 10-25%；
The mass percent sum of above raw material is 100%.
As a kind of preferred scheme, the protecting colloid by following raw material, is heated in a kettle by mass percentage
80 DEG C are made for scattered 3 hours：
The hard resins 15% of Joncryl 678；
Indurez SR10 hard resins 15%；
Ammoniacal liquor 8-9%；
Deionized water 60-62%；
Ammonia concn is 25%；
The mass percent sum of above raw material is 100%.
As a kind of preferred scheme, the preparation method of the anti-white appliances fat liquor includes following preparation process：
1）By mass parts, protecting colloid is added into reactor, is warming up to 80 DEG C；
2）By mass parts, add deionized water that ammonium persulfate is made to 10% mass concentration, i.e. initiator solution；By methyl
Methyl acrylate, butyl acrylate, Isooctyl acrylate monomer, acrylamide, vinyl silicone oil are mixed to form mix monomer, will mix
Monomer, neopelex and the deionized water scattered 10 minutes at a high speed for accounting for the mass parts of mix monomer 30%, are made pre-emulsification
Liquid；
3）Under the conditions of 80-85 DEG C, by mass parts, 40% initiator solution is first added dropwise, adds within 5 minutes；5% pre- breast is added dropwise again
Change liquid, add within 10 minutes；
4）After 80-85 DEG C of condition is incubated 20 minutes, while remaining initiator solution and pre-emulsion is added dropwise, initiator is molten
Liquid 4 hour adds for 15 minutes, and pre-emulsion adds for 4 hours, drips off follow-up continuation of insurance temperature 1 hour；
5）75 DEG C are cooled to, oxidant TBHP is first added, adds within 10 minutes；Add reducing agent hold in the month it is white
Block, add within 15 minutes；
6）Kept for 75 DEG C react 15 minutes, you can anti-white appliances fat liquor is made in cooling.
As a kind of preferred scheme, the wax assistant is water-borne wax fine dispersion, and wax particle has globular shape, particle diameter point
Cloth is between 0.5 micron to 3 microns.
As a kind of preferred scheme, the model DC-51 of the slipping agent.
As a kind of preferred scheme, the coalescents are a kind of new, environment-friendly type solvent, odorlessness, nonflammable, boiling point
For 191 DEG C.
As a kind of preferred scheme, the water cross-linking agent is the polycarbodiimide aqueous solution, without VOC.
The present invention has clear advantage and beneficial effect compared with prior art, specifically, by above-mentioned technical proposal
Understand：
After such scheme, the gloss oil of the invention prepared, there is the excellent scrub effect of resistance to white spirit, high glaze, prevent
Hot water, folding, resist blocking and that, glazing is packed to expensive goods, greatly improves product specification, and play good protection effect.
Embodiment
The present invention discloses a kind of resistance to white spirit and cleans water-based gloss oil, mixes scattered system by following raw material by mass percentage
Into：
Anti- white appliances fat liquor 90-95%；
Wax assistant 1-5%；
Slipping agent 0.1-0.5%；
Coalescents 1-3%；
Water cross-linking agent 1-2%；
Organic silicon defoamer 0.1-0.3%；
Deionized water 0-3%；
The mass percent sum of above raw material is 100%.
The anti-white appliances fat liquor is made up of following raw material by mass percentage：
Protecting colloid 40-50%；
Methyl methacrylate 12-16%；
Butyl acrylate 8-10%；
Isooctyl acrylate monomer 8-10%；
Acrylamide 0.5-1%；
Vinyl silicone oil 1-2%；
Neopelex 0.5-1%；
Ammonium persulfate 0.3-0.8%；
TBHP 0.01-0.05%；
Hold white piece of 0.01-0.05% in the month；
Deionized water 10-25%；
The mass percent sum of above raw material is 100%.
The protecting colloid by following raw material, is heated to 80 DEG C and is made for scattered 3 hours in a kettle by mass percentage：
The hard resins 15% of Joncryl 678；
Indurez SR10 hard resins 15%；
Ammoniacal liquor 8-9%；
Deionized water 60-62%；
Ammonia concn is 25%；
The mass percent sum of above raw material is 100%.
The preparation method of the anti-white appliances fat liquor includes following preparation process：
1）By mass parts, protecting colloid is added into reactor, is warming up to 80 DEG C；
2）By mass parts, add deionized water that ammonium persulfate is made to 10% mass concentration, i.e. initiator solution；By methyl
Methyl acrylate, butyl acrylate, Isooctyl acrylate monomer, acrylamide, vinyl silicone oil are mixed to form mix monomer, will mix
Monomer, neopelex and the deionized water scattered 10 minutes at a high speed for accounting for the mass parts of mix monomer 30%, are made pre-emulsification
Liquid；
3）Under the conditions of 80-85 DEG C, by mass parts, 40% initiator solution is first added dropwise, adds within 5 minutes；5% pre- breast is added dropwise again
Change liquid, add within 10 minutes；
4）After 80-85 DEG C of condition is incubated 20 minutes, while remaining initiator solution and pre-emulsion is added dropwise, initiator is molten
Liquid 4 hour adds for 15 minutes, and pre-emulsion adds for 4 hours, drips off follow-up continuation of insurance temperature 1 hour；
5）75 DEG C are cooled to, oxidant TBHP is first added, adds within 10 minutes；Add reducing agent hold in the month it is white
Block, add within 15 minutes；
6）Kept for 75 DEG C react 15 minutes, you can anti-white appliances fat liquor is made in cooling.
Described wax assistant is a kind of water-borne wax fine dispersion, should from the MD-2100 of German Keimadditec companies
The particle of type wax fine dispersion has globular shape, and for particle diameter distribution between 0.5 micron to 3 microns, delustring degree is low, anti-stick
Even and rub resistance is good.According to the smaller wax emulsion of particle diameter, though not delustring, resistance to blocking is poor；It is bigger according to particle diameter
Wax liquor, although resistance to blocking is excellent, delustring degree is too strong.Therefore, by series of contrast, present invention employs
Comprehensive optimal wax fine dispersion MD-2100.
A kind of described coalescents are a kind of new, environment-friendly type solvent, from Luo Diya（Rhodia）Augeo
SL191.The auxiliary agent derives from renewable resource, odorlessness, nonflammable, and boiling point is 191 DEG C.With alcohol ether esters coalescents phase
Than Augeo SL191 toxicity is lower, to human health and more environment-friendly.
A kind of described water cross-linking agent is the polycarbodiimide crosslinkers aqueous solution, from Dutch Si Teer（Stahl）
XL-702, without VOC, be crosslinked with carboxyl reaction, the performance such as the water-fast of system, chemically-resistant, wear-resisting can be effectively improved.
The model DC-51 of the slipping agent.
Described vinyl silicone oil is the small molecule silicone oil containing vinyl, from the C-168 of Foshan Hunter chemical industry, Neng Gouxian
Write the pliability after the water resistance and film forming of raising system.
With multiple embodiments, the invention will be further described below：
Embodiment 1：
The preparation of protecting colloid：
By mass percentage by following raw material, it is 30% to be heated to 80 DEG C in a kettle and solid content is made within scattered 3 hours
The protecting colloid aqueous solution：
The hard resins 15% of Joncryl 678；
Indurez SR10 hard resins 15%；
Ammoniacal liquor（Concentration 25%） 8-9%；
Deionized water 60-62%；
The mass percent sum of above raw material is 100%.
Embodiment 2：
The preparation of anti-white appliances fat liquor
The present embodiment provides a kind of anti-white appliances fat liquor, with protecting colloid, monomer, emulsifying agent, initiator and deionized water
For raw material, it is prepared through pre-emulsification, seed reaction, polymerisation.Specifically include：
Raw-material weight part
Protecting colloid 400
Methyl methacrylate（MMA） 150
Butyl acrylate（BA） 90
Isooctyl acrylate monomer（2-EHA） 90
Acrylamide（AM） 10
Vinyl silicone oil C-168 20
Neopelex (SDBS) 7.2
Ammonium persulfate (APS) 3.6
TBHP 0.2
Hold white piece 0.2 in the month
Deionized water 228.8
Sum 1000
The preparation method of above-mentioned anti-white appliances fat liquor, is carried out in the steps below：
1）Protecting colloid aqueous solution 400kg and 58kg deionized water is added into reactor, is warming up to 80 DEG C.
2）Add 32.4kg deionized waters that 3.6kg ammonium persulfates are made into initiator solution；By mix monomer（150kgMMA、
90kgBA, 90kg2-EHA, 10kgAM, 20kg vinyl silicone oil C-168）, 7.2kg emulsifying agents SDBS and account for 108kg deionized waters
At a high speed（800-1000r/min）It is scattered 10 minutes, pre-emulsion is made.
3）Under the conditions of 80-85 DEG C, 14.4kg initiator solution is first added dropwise, adds within 5 minutes；24kg pre- breast is added dropwise again
Change liquid, add within 10 minutes.
4）After 80-85 DEG C of condition is incubated 20 minutes, while remaining initiator solution is added dropwise（Add within 15 minutes 4 hours, use
5kg deionized water rinsing head tanks）And pre-emulsion（Add within 4 hours, with 10kg deionized water rinsing head tanks）, drip off follow-up
Continuation of insurance temperature 1 hour.
5）75 DEG C are cooled to, first adds 0.2kg oxidants TBHP and the mixed liquor of 5.4kg deionized waters,
Add within 10 minutes；The mixed liquor that 0.2kg reducing agents hold white piece and 10kg deionized waters in the month is added, is added within 15 minutes.
6）Kept for 75 DEG C react 15 minutes, you can solid content about 48%, pH value 8.0-9.0, viscosity 90-110s/ is made in cooling
（30 DEG C, apply 4# cups）Anti- white appliances fat liquor.
Embodiment 3：
（One）Resistance to white spirit cleans water-based gloss oil A
Anti- white appliances fat liquor 92%
Wax assistant MD-2100 2%；
Slipping agent DC-51 0.3%；
Coalescents SL191 2%；
Water cross-linking agent XL-702 1%；
Organic silicon defoamer 0.1%；
Deionized water 2.6%；
The mass percent sum of above raw material is 100%.
（Two）Preparation method：Under normal temperature, anti-white appliances fat liquor is first added, dispersing speed is adjusted to 600-800r/min,
MD-2100, DC-51, SL191, XL-702, organic silicon defoamer are sequentially added, after stirring 15 minutes, is adjusted with deionized water
Viscosity, it is 35-50s/ to produce viscosity（Painting 4# cups, 30 DEG C）The water-based gloss oil of resistance to white spirit A.
Embodiment 4：
（One）Resistance to white spirit cleans water-based gloss oil B
Anti- white appliances fat liquor 91%；
Wax assistant MD-2100 2%；
Slipping agent DC-51 0.3%；
Coalescents SL191 2%；
Water cross-linking agent XL-702 2%；
Organic silicon defoamer 0.1%；
Deionized water 2.6%；
The mass percent sum of above raw material is 100%.
（Two）Preparation method is identical with implementation column 3, therefore does not repeat.
Embodiment 5：
（One）Resistance to white spirit cleans water-based gloss oil C
Anti- white appliances fat liquor 91%；
Wax assistant MD-2100 2%；
Slipping agent DC-51 0.3%；
Coalescents SL191 2.5%；
Water cross-linking agent XL-702 1.5%；
Organic silicon defoamer 0.1%；
Deionized water 2.6%；
The mass percent sum of above raw material is 100%.
（Two）Preparation method is identical with implementation column 3, therefore does not repeat.
The water-based gloss oil of resistance to white spirit produced by the present invention is obtained, with No. 12 bars of RDS on having had the coating paper of tusche
Scrape one layer of gloss oil, be placed in 80 DEG C of baking ovens and dry 30 minutes, then room temperature place 2 hours after gloss, anti-hot water, resistance to is carried out to it
Folding, the test of resistance to white spirit, resist blocking and that.
Test result is expressed as below：
Note：The coating paper glossiness for having gone up tusche only has 7 ° or so.
Test condition：
Gloss：Use vancometer（Crevice projection angle is 60 °）Test, survey 3 times and average；
Anti- hot water：90 DEG C of hot water are dropped in into coating surface, whether observation coating, which whitens, after 5 minutes washmarking.Do not whiten nothing
Washmarking then illustrates that anti-hot water is excellent, and not whitening has washmarking then to illustrate that anti-hot water is good, and whiting has washmarking then to illustrate that anti-hot water is poor；
Folding：After sample doubling will be scraped, observe behind fold position repeatedly doubling 10 times and whether burst at folding line, then said without quick-fried trace
Bright bending resistance is strong；There is quick-fried trace then to illustrate that bending resistance is poor.
Resistance to white spirit：With cotton swab in white spirit（N-hexane）In fully absorb, then rapidly in dry sample table
Face wipes 30 times back and forth, and whether observation cotton swab has color, and whether coating surface leaves a trace.
Resist blocking and that：By the coated face-to-face doubling of sample, analyzer is carried on the back using Specac is viscous, at 0.2 ton, 40 DEG C
Under conditions of test 30 minutes, take out sample observation whether adhesion.
Coating it can be seen from test result after the coated printing of the water-based gloss oil of resistance to white spirit produced by the present invention has
Gloss is high, anti-hot water is strong, bending resistance is rolled well, resistance to white spirit cleans the characteristics such as excellent and resist blocking and that, and surface is smooth, seemingly fills bark effect,
Substantially increase the class of printing packaging.
The above described is only a preferred embodiment of the present invention, be not intended to limit the scope of the present invention,
Therefore any subtle modifications, equivalent variations and modifications that every technical spirit according to the present invention is made to above example, still
Belong in the range of technical solution of the present invention.
Claims (7)
1. a kind of resistance to white spirit cleans water-based gloss oil, it is characterised in that：It is made by mass percentage by the mixing of following raw material is scattered：
Anti- white appliances fat liquor 90-95%；
Wax assistant 1-5%；
Slipping agent 0.1-0.5%；
Coalescents 1-3%；
Water cross-linking agent 1-2%；
Organic silicon defoamer 0.1-0.3%；
Deionized water 0-3%；
The mass percent sum of above raw material is 100%；
The anti-white appliances fat liquor is made up of following raw material by mass percentage：
Protecting colloid 40-50%；
Methyl methacrylate 12-16%；
Butyl acrylate 8-10%；
Isooctyl acrylate monomer 8-10%；
Acrylamide 0.5-1%；
Vinyl silicone oil 1-2%；
Neopelex 0.5-1%；
Ammonium persulfate 0.3-0.8%；
TBHP 0.01-0.05%；
Sodium formaldehyde sulfoxylate 0.01-0.05%；
Deionized water 10-25%；
The mass percent sum of above raw material is 100%.
2. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The protecting colloid presses matter
Percentage is measured by following raw material, 80 DEG C is heated in a kettle and is made for scattered 3 hours：
The hard resins 15% of Joncryl 678；
Indurez SR10 hard resins 15%；
Ammoniacal liquor 8-9%；
Deionized water 60-62%；
Ammonia concn is 25%；
The mass percent sum of above raw material is 100%.
3. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The anti-white appliances fat liquor
Preparation method include following preparation process：
1）By mass parts, protecting colloid is added into reactor, is warming up to 80 DEG C；
2）By mass parts, add deionized water that ammonium persulfate is made to 10% mass concentration, i.e. initiator solution；By metering system
Sour methyl esters, butyl acrylate, Isooctyl acrylate monomer, acrylamide, vinyl silicone oil are mixed to form mix monomer, and mixing is single
Body, neopelex and the deionized water scattered 10 minutes at a high speed for accounting for the mass parts of mix monomer 30%, are made pre-emulsification
Liquid；
3）Under the conditions of 80-85 DEG C, by mass parts, 40% initiator solution is first added dropwise, adds within 5 minutes；5% pre-emulsification is added dropwise again
Liquid, add within 10 minutes；
4）After 80-85 DEG C of condition is incubated 20 minutes, while remaining initiator solution and pre-emulsion, initiator solution 4 is added dropwise
Hour adds for 15 minutes, and pre-emulsion adds for 4 hours, drips off follow-up continuation of insurance temperature 1 hour；
5）75 DEG C are cooled to, oxidant TBHP is first added, adds within 10 minutes；Add reducing agent sodium formaldehyde sulfoxylate, 15
Minute adds；
6）Kept for 75 DEG C react 15 minutes, you can anti-white appliances fat liquor is made in cooling.
4. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The wax assistant is water-based
Wax fine dispersion, wax particle have globular shape, and particle diameter distribution is between 0.5 micron to 3 microns.
5. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The model of the slipping agent
For DC-51.
6. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The coalescents are one
Kind of environment-friendly type solvent, odorlessness, nonflammable, boiling point is 191 DEG C.
7. a kind of resistance to white spirit according to claim 1 cleans water-based gloss oil, it is characterised in that：The water cross-linking agent is
The polycarbodiimide aqueous solution, without VOC.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676036A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based matte touch gloss oil and preparation method thereof |
| CN102911559A (en) * | 2012-11-22 | 2013-02-06 | 南京瑞固聚合物有限公司 | Anti-after tack acrylic latex for water-based ink |
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- 2016-04-06 CN CN201610209650.6A patent/CN105780586B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676036A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based matte touch gloss oil and preparation method thereof |
| CN102911559A (en) * | 2012-11-22 | 2013-02-06 | 南京瑞固聚合物有限公司 | Anti-after tack acrylic latex for water-based ink |
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