TW399106B - Process and plant for electrolytically coating the casting surface of a roll - Google Patents

Process and plant for electrolytically coating the casting surface of a roll Download PDF

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Publication number
TW399106B
TW399106B TW86108694A TW86108694A TW399106B TW 399106 B TW399106 B TW 399106B TW 86108694 A TW86108694 A TW 86108694A TW 86108694 A TW86108694 A TW 86108694A TW 399106 B TW399106 B TW 399106B
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Taiwan
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anode
shields
casting
casting surface
shuttle
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TW86108694A
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Chinese (zh)
Inventor
Herve Lavelaine
Christian Allely
Eric Jolivei
Jean-Claude Catonne
Yann Breviere
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Thyssen Stahl Ag
Usinor Sacilor
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Priority claimed from FR9616255A external-priority patent/FR2750438B1/en
Application filed by Thyssen Stahl Ag, Usinor Sacilor filed Critical Thyssen Stahl Ag
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Publication of TW399106B publication Critical patent/TW399106B/en

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Abstract

The invention relates to a process for electrolytically coating the casting surface of a roll, for the twin-roll or single-roll continuous casting of thin metal strip, with a metal layer, in which process the said casting surface is at least partially immersed in an electrolyte solution, containing a salt of the metal to be deposited, so as to face at least one anode, the said surface is placed at the cathode and a relative movement is created between the said casting surface and the said electrolyte solution, characterized in that insulating masks are interposed between the said anode or anodes and the arrises of the said casting surface, the said insulating masks preventing a concentration of the lines of current on the said arrises and in their vicinity electrolytically coating the casting surface (3) of a roll, for the twin-roll or single-roll continuous casting of thin metal strip, with a metal layer, of the type comprising a tank (1) which contains an electrolyte (2) containing a salt of the metal to be deposited, means (5, 6) for immersing the said casting surface (3) at least partially in the said tank (1) and for creating a relative movement between the said casting surface and the said electrolyte, at least one anode (4, 4') arranged in the tank (1) so as to face the said casting surface (3), and means for raising the said casting surface to a cathode potential, characterized in that the plant includes masks (7, 7'), made of an insulating material, which are interposed between the arrises (12) of the said casting surface (3) and the said anode or anodes (4, 4'), the said masks (7, 7') preventing a concentration of the lines of current on the said arrises (12).

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A7 ___B7_ 五、發明説明(/ ) (請先閲讀背面之注意事項再填寫本頁) 本發明係闥於金屬之連續鑄造。尤其是,本發明係Η 於處理輻子或諸輥子上之外表面,其中後者是構成用於連 續鑄造由諸如期之金羼所製成薄片之模具的移動墅。 用於直接自液態金靨Μ雙輥連鑛_造幾·厚鏞片之機 器,其鋪模包含有一薄造間隙,後者受界定於鐃軸線(其 保持水平狀態)反向旋轉之兩輻的横側面,以及抵壓於該 等輥子端部之兩塊W热側板。這些轎子具有之直徑可高達 1 500«·,而寬度在現今S驗性設備中的為600β至 800·«。然而從長逭看,此S度將必需高達1 300至 1 500·»* Κ期滿足工業設備之生產要求。這些輥子通 常包含有一鋼質芯座*其外周画定一嗣質或銅合金質之套 筒,該套筒藉由在芯座與套筒間或,套筒内部循環水來加Κ 冷卻。 經濟部智慧財產局員工消費合作社印製 怡如用於傳統式連缅鑄造坯錠、坯段或坯板的鑄摸之 表面一般*該套筒接觸液態金屬之表面可鍍覆一金靥層, 所用通常為鎳,其厚度一般高達1至2ra。此鎳層可使套 筒之熱傳導係數調整至最佳值(此值低於若是該金靥直接 接觸鋦時的情況),致使金屬可在瘇切之治金條件下凝固 :凝固過快會造成產品表面之缺陷。此調整可藉由變更鎳 層之厚度K及结構而進行。另一方面,其對銅形成一保護 層,防止其遭受過度之熱應力及機械懕力。此鎳層於輥子 之使用過程中會磨損,而必須周期性地予Μ修復,具體係 局部地或完全地除去殘留之厚度,繼以沈積一新層,但此 -4- 本紙張尺度逍用中國國家標準(C^S ) Α4規格(210Χ297公釐) 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(y) 種修復顧然成本低於整個地更換因磨損而裸露之鋦質套筒 〇 鎳之沈稹最好用下列方法K電解方式進行。新套苘( 一個練已局部或完全除去之套筒)乃係具有中空圔爾髖之 缌通形狀,且由嗣或鋦合金諸如鋦一 (1%)络一(〇♦ 1%)輅合金所製成者,其被安裝在一芯座上,藉此可容 易地在鑲嫌/除嫌工場中自一處理站至另一站地運送。經 歷了各種準備性表面處理(賻光、去油污、酸洗)K提升 練對鋦之附著性之後,該套筒被送至鎳之霣解站。此站包 含有一槽*内有鍍嫌溶液,於其上方芯座可放置呈水平位 置,且被令鐃軸線旋轉。如此套茼之下部便浸入槽中,而 κ諸如約1 〇轉/分之速度旋轉該.芯座/套筒组件可使對 整個套筒之處理得K進行。在K鎳電鍍期間,該套爾構成 陰極•而播極可由一個或多個浸沒在槽中之钛質陽極籃組 成,其中該等陽極藍為薄隔膜所圍封,使得正對套爾之表 面而容置鎳球。倘若亦希望K鎳鍍覆套茼端部之大部(其 於鑄造期間摩擦射磨之側板,因而易於磨損)•則可將其 他隈極籃安置成面朝埴些端部。其他類型之陽極(可溶性 或非可溶性者)亦可使用。 作為一種變形形式,可採取措施使套茼保持靜止而諶 電解質運動通通套筒。因此重要的是於套筒與其電解質之 間產生相對蓮動,以此確保二者交界面之更新。 於鑄件熔鋪期間,級嫌層遭受非常高之愿力,機械應 本紙張尺度適用十國國家梂準(CNS ) Α4規格(210X297公釐) ----^-------^------II 一 . - ί - (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局貝工消費合作社印製 A7 _____B7_ 五、發明説明($ ) 力與热應力均有。常可觀察到,僅寥雾数鑄件熔鏞後,在 接近輥子邊緣處之鍍嫌層中便有裂雄出現。埴些裂雄自套 筒之梭角起波及幾C·寬之區域。彼等可専致缺陷於禱件表 面上之形成,因為其造成後者非均勻之冷卻。鎵之*彼等 會構成弱點,整靨鍍鎳層非常快之蛻變便由此而始。甚至 可能係裂縫之擴展,穿透鍍練層,而可能導致整個套筒之 毀壊。因此這些裂越必然導致立即且永久地停用該轎子並 徹底地重行產生套爾上之鍍層。由於此項作莱耗時長(数 日),是故雙輥鑄鋼法之工業應用需有大量套茼備用,K 期確保《造檄之正常運行。由於套筒所使用之材質K及加 工不易,是乃非常昂貴之元件,故此舉會造成在使用該設 備方面之高成本。 本發明之目的係改菩套筒之金屬鍍暦對熱櫬械應力之 酎受性質,其方法係盡可能減慢甚至防止裂縫於邊嫌匾域 之出現,K便延長套W於其級履兩次修復間之平均使用時 間。 本發明之對象係一種對用於雙輥或軍轎連纘鑄埴薄金 靥片之輻子的鐮製表面霄鍍K金屬層之方法•於此法中, 該嫌製表面至少局部地浸沒在一種内含欲沈積之金靥鹽的 電解液中,使成面對至少一個陽極,該表面被放置在陰極 處,且有一相對蓮動產生於該鑄製表面與該霣解液之間, 其特激在於,絕緣護罩插設於該皤極或該等陽極與該鏞製 表面之梭角間,該等絕緣護罩防止霣流媒集中於該等梭角 -6- 本紙張尺度逋用中國國家橾準(CpS ) A4規格(210X297公釐) ----------A------訂------% >- ; ' - -(請先聞讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 _B7_ 五、發明説明(十) 及其附近。 本發明之對象亦係一種對用於雙輥或軍辊連續鏞造薄 金靥片之輥子的禱製表面霣鍍κ金羼層之設備,其所羼之 類型為包含有:一電鍍槽,其容置有内含欲沈積之金靥鹽 的電解霣;用於將該麵製表面至少局部地浸沒在該植内並 用於在該麵製表面與該霣解質之間產生相對運動之機構: 至少一個皤檯,其安置在槽中成面對該鑄製表面;以及用 於提升該鑄製表面至陰極電勢之襯構;特徵在於·該設備 包括有絕緣材質製成之護罩,其插設於該緬製表面之梭角 與該陽極或該等陽極間*該等護罩可防止霣流媒集中於該 等梭角。 較好地,該等護罩具有圼圆形之總體形狀,其曲率 中心相同於所面對之鑛製表面之稜角者*而且具有兩平行 之側面,各面置於該等梭角之延伸處,距後者有相同之距 離〃d" *且二面藉由一轉角形之切口而連接,切口之側 面彼此垂直。 當理解,本發明包括藉由安置絕緣護罩於套茼之附近 而進行金層鍍層之電極沈積。這些護軍(其有一較佳示例 被敘述),乃設計來於套茼之邊緣區域内獲致均勻之霣流 線分佈。此舉可賦予這些區域内之鎪層Μ均勻之厚度* 一 致於所欲之名義厚度。 本發明人業己發現,裂縫出現在套爾邊緣區域之鍍練 層中的快速性與此鍍層於這些區域內之厚度均勻性之間存 本紙張尺度逍用中國國家標準(CNS ) Α4規格(210Χ297公釐) / . ----;--------一水------1Τ . - 广 i · (請先閲讀背面之注意事項再填寫本頁) A7 _B7_ 五、發明説明(f) (請先閲讀背面之注意事項再填寫本頁) 在有相闞性,尤其是顒著梭角處。在無任何特別装置設計 來防止此現象之情況下,鍍嫌層之過厚現象經發現產生在 套茼之梭角中部附近,且顒著這些梭角本身。例如,若箱 層之名義厚度於套筒表面之大部份上為2m,有時會發現 此厚度於顒著梭角處大於7η·。埴些過厚現象當歸咎於電 流媒於該等梭角之中部附近之集中。縱然這些集中現象僅 存在於套筒之非常有限之部位內*但似乎足Μ造成上述裂 越之快速出現。此情事係因為經證實,彼等使得氫得Κ生 成,使正形成中之沈積區中可能產生含氣現象。而且•這 些集中現象使鍍鎳層之晶格结構,進而其硬度及其组嫌於 該等稜角與套商之其餘部份間非均勻。 減少此.一鍍層通厚現象之一種.手段,包括賦予梭角以 幾m之曲率半徑,而非使之成銳利之邊刃。然而,在實際 中,此半徑不得超遇1至2m,否則液態金羼漾進輥子之 端部與射火側板間之可能性便會刺增。 經濟部智慧財產局員工消費合作社印製 另一種習知之手段包括藉由被稱為"據流器β之装置 來偏斜霄流線。瑄些装置為金屬導腥,安置成平行於霣流 媒所穿通之梭角及其附近部位。彼等使有些電流媒朝其偏 斜,而這些電流線在無該等裝置之情況下,原本將集中於 套茼之梭角及其周圜。然而,此方案單獨使用時亦並非令 人滿意。而且,這些據流器之定位及工作參數必須精心測 定,因為若不然,除通厚現象會依然顒著邊緣存在外,有 時會發現癦相反,於一定處之鍍嫌層厚度會小於名義厚度 -8- 本紙張尺度適用中國國家標準(CpS ) Α4規格(210Χ 297公釐) A7 B7 五、發明説明(“) (請先閲t».背面之ji'意事項再填寫本頁) ,表激該等電流媒被過度偏離於相對應之區域。再者,當 電鍍進行時,鎳以並非可忽視之數量沈積在該等擄流器上 。因此便必需回收此鍊,而為沈積之而消耗之電流則表現 為一種純粹之損失。但最重要的是,此嫌之沈横使該據流 器之尺寸變更,而再能K非常規範之方式工作。因此當作 業進行時,據流器之作用變化甚大,使得甚難管理之。實 際上,對於2··之所需鍍層厚度,鍍層於稜角上具2 · 5 之厚度已被認為最佳,惟此值依然太高而不能令人滿意 地解決所提出之問題。因此,對此應用場合•據流器不能 可靠地達成令人滿意之鎳沈積均勻性,特別是對於蓮讀鑄 造輥之鍍暦。 本發明人發現,欲於套筒之梭,角及其中部附近部位獲 致非常均勻之鎳沈積,最可靠之途徑係放置絕緣護罩,最 好係圼規定之结構形態、距梭角短距離者*且發現在這些 條件下,位於套筒邊緣區域之鍍層中過早出現裂縫之現象 可得K消除〇 圖式簡軍說明 經濟部智慧財產局員工消費合作社印製 本發明經閲讀下文說明並參看下列附繭將得以更清楚 地理解: 第一圖K視見端部及I 一 I剖面之圖示性方法,顯示 一種對雙輥式鑄造輥套简進行鍍層之設備,該設備予>乂設 計來霣施依據本發明之方法。 第二圖顯示此同一設備上之I I 一 I I剖面画,解釋 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 B7 五、發明説明(j) 依據本發明之護罩的較佳结構形態。 圖號簡單說明 經濟部智慧財產局員工消費合作社印製 1 電 鍍 槽 2 電 解 質 3 銅 套 4 陽 極 4 〆 陽 極 5 芯 座 6 軸 7 護 罩 7 護 罩 8 活 動 桿 9 轉 角 形 切 P 9 轉 角 形 切 □ 1 0 切 口 之 側 面 1 0 , 切 0 之 側 面 1 1 外 邊 緣 1 1 , 外 邊 緣 1 2 梭 角 1 3 護 罩 之 側 面 1 3 , 護 罩 之 側 面 2 1 垂 直 陽 極 2 1 / 垂 直 陽 極 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A7 B7 五、發明説明(β) 2 1〃 垂直陽極 第一圈K剖視方式顬示一種依據本發明之設備*騸中 剖視平面位於容置有電解液(其主要成份為練H)的霣鍍 播1之周界内,但於放置成作為陰極之铜套3,K及置於 電鍍槽1底都的兩陽極4、4'之前。詷套3,其具有圓 柱形之外形及1 500m之外徑,乃安裝在一芯座5上, 而後者之袖6則於霣鍍作業期間》由圖中未示之機構予K 轉動。至少該鋦套3之下部浸在霣鍍權中。於所示之示例 中,陽極4、4'為可溶性陽極,由充滿練粒子之弧形钛 質陽板籃組成。然而,瑄僅係一種實施例而已,亦可配設 不同數目之隈板以及其他结構形態(例如,一種不溶性陽 極)。陽極4、4'伸展於該剖視.平面之後,其寬度大於 鋦套3。處置成直面嗣套3之邊緣者,為絕緣材質製成之 護罩7、7'(第一圏中僅7可見及),其功能係防止來 自陽極4、4'之電流線直達鐧套之邊緣區域及稜角,K 避其上之鍍鎳層過厚。這些護罩7、7'相對於綢套3之 位置可藉由圖中以活動桿8象徴性地加K顯示之定位櫬構 來調整。 這些護罩7、7'之精確形態示於第二圖中。於所示 之示例中,彼等呈現約為正方形或矩形截面之長體形*且 具有画弧形之總體形狀,其曲率中心相同於所面朝的該銅 套3之梭角者。彼等之上邊緣最接近鋦套之邊掾,並對此 施加作用,這些上邊緣具一轉角形切口9、9',後者之 -11- 本紙張尺度適用中國國家標準(CNS )八4^格(2丨0X297公釐) ----------女各_>1 * - * . (請先閲?#.背面之ji·意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(1 ) 兩側面垂直,且約略等長,例如約為5m。該等護罩7、 7'藉由桿8加Κ安置成使切口 9、9'之外邊緣1 1、 1 1'各放置成相距所面朝的網套3之梭角1 2約有相同 之距離〃 d 〃。當希望沈積鎳成2至3m厚度時,此距離 〃 d "初始約為5ra。另一方面,各護罩7、7’之側面 1 3、1 3'於本發明此一實施例中,必須具有50«之 最小長度。正係在這些條件下護覃7、7'始可充分偏射 霄流媒,使其於钃套邊緣匾域之分佈均勻性最優。 作為任選,可以對護罩7、7'安置成得K於鍍錁層 之厚度增加時渐逐移離鋦套3。此移動可K接埋之步進方 式,或連讀之方式進行。由此可確保有足夠之間隙始终保 留在護罩與鍍層之間,K期讓該莰鎳曆成長。 嫌陽極4、4'及護罩7、7'之精確形態之不同, 對綢套3端部之鍍塗將在其較大抑或較小之表面部份均勻 地進行。為增大此一部份,垂直陽極21、21' 、21 .·,是如充滿練粒子之陽極屋者*可相似於陽極籃4、4 '且面朝鋦套3之端部,誠如已提及之前技中一般放置在 槽1内。 顯然,該等護罩於其结構方面可不同於業已作為範例 而給出者,只要彼等能使欲獲致之鍍層厚度有所欲之均勻 性即可。特別是,彼等可不由正方形、矩形或其他截面之 長形體構成,而係由一板或者一板組件所構成*其中該板 或板組件朗向飼套之面最好具有相同於示例中該畏形體之 -12- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -----------衣-- • ··* (請先閲^背面之&意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 A7 B7 399106 五、發明説明(/to) 结構形態。換言之*此面最好係須包括有兩個平行之邊, 其——應於鋦套梭角之延伸處,距後者有相同之距離"d "且藉由一轉角形切口相連接,其侧面彼此間垂直。 本發明並不排斥這種可行性,K期補充並進一步精化 護罩之作用*亦可持久地或者不接纘地利用據流器,即這 些擄流器加入護罩中或獨立於後者。 當然,本發明可被懕用來將非鎳之金羼沈積於鋦套上 。同理,如此鏟成之輻子不僅可用在供雙輥連銷金鼷薄片 (由期或其他材霣製成)之欐器中,而且可用在供連鑄薄 片且其中有一旋轉轎輕舔金屬液池表面之檐器(軍轘鑄造 )中。而且,其亦可被懕用於後述之情形,即鍍覆實心軸 之鑄製表面*其中該套茼與芯座構.成單一體而為同一工件 。亦可K容易地將之變換成適愿套筒或實心輥完全浸沒於 電解池中之情形。最後,誠如上逑,套简與霣解質間相對 運動之產生可藉由保持套筒靜止,且使電解質於其周圔運 動而為之。此舉可得K達成,特別是套筒全部浸沒在霣解 液中時,以及霣解液之運動係藉由適必定间之噴嘴產生Μ 期於陽極或諸陽極間循環電解液於套筒之周圍。 -13- 本紙張尺度適用中國國家揉準(CNS ) Α4規格(210X297公釐) Ϊ 先 閲 讀· 背 之 注. 意 事 項 再 頁 經濟部智慧財產局員工消費合作社印製A7 ___B7_ 5. Description of the invention (/) (Please read the notes on the back before filling out this page) The invention is based on continuous casting of metal. In particular, the present invention is directed to the processing of the outer and upper surfaces of spokes or rollers, the latter of which is a mobile villa constituting a mold for continuous casting of flakes made of, for example, gold cymbals. A machine for directly making two-roller continuous ore from liquid gold __making several thick slabs, the mold-laying of which includes a thin gap, the latter of which is defined by two spokes rotating in the opposite direction defined by the sacral axis (which maintains a horizontal state). The lateral side, and the two W hot side plates pressed against the ends of the rollers. These cars can have diameters of up to 1 500 «· and widths of 600 β to 800« in today's S-experience equipment. However, from a long perspective, this S degree will have to be as high as 1 300 to 1 500 · »* K period to meet the production requirements of industrial equipment. These rollers usually include a steel core seat * whose outer periphery is drawn with a sleeve made of arsenic or copper alloy. The sleeve is cooled by circulating K between the core seat and the sleeve or the inside of the sleeve. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs on the surface of the traditional Lian-Mian casting billet, billet or slab. The surface of the sleeve that contacts the liquid metal can be plated with a gold layer. Nickel is usually used and its thickness is typically as high as 1 to 2ra. This nickel layer can adjust the thermal conductivity of the sleeve to the optimal value (this value is lower than if the gold 靥 is in direct contact with 鋦), so that the metal can be solidified under the condition of cutting metallization: too fast solidification will cause Defects on the surface of the product. This adjustment can be performed by changing the thickness K and structure of the nickel layer. On the other hand, it forms a protective layer against copper, preventing it from being subjected to excessive thermal stress and mechanical stress. This nickel layer will wear during the use of the roller, and must be repaired periodically, specifically by removing the remaining thickness locally or completely, and then depositing a new layer. Chinese National Standard (C ^ S) A4 specification (210 × 297 mm) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (y) The cost of repairing is lower than the whole replacement due to wear and tear. The precipitation of the high-quality sleeve 0 nickel is preferably performed by the following method K electrolytic method. The new sleeve (a sleeve that has been partially or completely removed) has a hollow shape of a hollow hip, and is made of a rhenium or rhenium alloy such as rhenium (1%) and rhenium (〇 ♦ 1%) rhenium alloy The finished product, which is mounted on a core seat, can be easily transported from one processing station to another station in a mounting / removing factory. After undergoing various preparative surface treatments (calendering, degreasing, pickling) to improve the adhesion to the concrete, the sleeve was sent to a nickel dissolution station. This station pack contains a tank * with plating solution inside, and the core seat above it can be placed in a horizontal position, and the 铙 axis is rotated. In this way, the lower part of the sleeve is immersed in the groove, and κ is rotated at a speed of about 10 rpm, for example. The core seat / sleeve assembly can process the whole sleeve to K. During K-nickel plating, the sheath constitutes the cathode. The emitter can consist of one or more titanium anode baskets immersed in the tank, where the anode blue is enclosed by a thin diaphragm, facing the surface of the sheath. And accommodate nickel balls. If it is also desired that a large portion of the end of the K-nickel-plated sleeve (which rubs against the side plates during casting and is therefore prone to wear) • other pole baskets can be placed facing the ends. Other types of anodes (soluble or insoluble) can also be used. As a variant, measures can be taken to keep the sleeve 茼 still while the electrolyte moves through the sleeve. It is therefore important to create a relative motion between the sleeve and its electrolyte to ensure that the interface between the two is updated. During the casting of the casting, the level of the suspected layer suffered a very high willingness. The machine should comply with the Ten Countries National Standard (CNS) A4 specification (210X297 mm) for this paper size. ---- ^ ------- ^ ------ II I.-ί-(Please read the notes on the back before filling in this page) Printed by A7, Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs _____B7_ 5. Description of Invention ($) Both force and thermal stress Have. It is often observed that after only a few foggy castings have melted, cracks appear in the plating layer near the edge of the roller. Some split males spread from the sleeve angle of the sleeve to a few C · wide areas. They may cause defects to form on the surface of the prayer, because it causes the latter to cool unevenly. Gallium * they can form a weakness, and the very rapid deterioration of the nickel plating layer begins. It may even extend the cracks and penetrate the plating layer, which may lead to the destruction of the entire sleeve. Therefore, these cracks will inevitably lead to the immediate and permanent deactivation of the car and the complete re-production of the coating on the sleeve. Because this operation takes a long time (several days), the industrial application of the twin-roll steel casting method requires a large number of backups, and the period K ensures the normal operation of the production. Since the material K used for the sleeve is not easy to process and is a very expensive component, this will cause high costs in using the equipment. The purpose of the present invention is to modify the endurance properties of the metal plating of the sleeve to the thermal mechanical stress. The method is to slow down or even prevent the appearance of cracks in the plaque area as much as possible. Average time between repairs. The object of the present invention is a method of plating a K metal layer on a sickle surface of a double-roller or a spoke of a thin cymbal of a limousine cast iron. In this method, the suspect surface is immersed at least partially. In an electrolytic solution containing gold osmium salt to be deposited, facing the at least one anode, the surface is placed at the cathode, and a relative motion is generated between the casting surface and the dissolution solution, Its special feature is that the insulation cover is inserted between the pole or the anode and the shuttle angle of the surface, and the insulation shield prevents the flow medium from being concentrated on the shuttle angle. China National Standard (CpS) A4 Specification (210X297mm) ---------- A ------ Order ------% >-; '--(Please listen first (Please read the notes on the back and fill in this page) A7 _B7_ printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention (ten) and its vicinity. The object of the present invention is also a device for plating a kappa gold layer on a prayer surface of a roller for continuously forming a thin gold reed roll for a double roll or a military roll. The type thereof includes: a plating tank, It contains an electrolytic tincture containing gold tincture salt to be deposited; a mechanism for immersing the surface at least partially in the plant and for generating a relative movement between the surface and the disintegration substance : At least one stirrup, which is placed in the tank so as to face the casting surface; and a lining for lifting the casting surface to the cathode potential; characterized in that the device includes a shield made of an insulating material, which The shields interposed between the Burmese surface and the anode or the anodes * The shields can prevent the flow media from concentrating on the shuttle angles. Preferably, the shields have the general shape of a round shape, the center of curvature is the same as the corners of the mineral surface facing them *, and they have two parallel sides, each side being placed at the extension of the shuttle angle , The same distance from the latter 〃d " * and the two sides are connected by a corner cut, the sides of the cut are perpendicular to each other. It will be understood that the present invention includes electrode deposition of a gold layer by placing an insulating shield near the jacket. These garrisons (with a good example described) are designed to achieve a uniform streamline distribution in the edge area of the nest. This will give the 锼 layers M uniform thicknesses in these areas * to the desired nominal thickness. The inventors have discovered that the rapidity of cracks in the plating layer in the edge area of Tall and the uniformity of the thickness of the coating in these areas are maintained in accordance with the Chinese National Standard (CNS) A4 specification ( 210 × 297 mm) /. ----; -------- Yishui ----- 1T.-Guang i · (Please read the precautions on the back before filling this page) A7 _B7_ V. Description of the Invention (f) (Please read the precautions on the back before filling out this page) There is similarity, especially at the corner of the shuttle. In the absence of any special device design to prevent this phenomenon, the phenomenon of excessive thickness of the plating layer was found to occur near the middle of the shuttle corners of the sleeves, and to hold these shuttle corners themselves. For example, if the nominal thickness of the box layer is 2m over a large part of the sleeve surface, it may sometimes be found that the thickness is greater than 7η · at the shuttle angle. Some of these over-thickness phenomena can be attributed to the concentration of current media near the middle of these shuttle angles. Even though these concentration phenomena exist only in very limited parts of the sleeve *, it seems that the above-mentioned cracks occur rapidly enough. This is because it has been confirmed that they have generated hydrogen from K, which may cause gas-containing phenomena in the forming sedimentary area. And • these concentration phenomena make the lattice structure of the nickel plating layer, and hence its hardness and its group, suspect that the edges and corners are non-uniform with the rest of the suitor. One way to reduce this phenomenon of through-thickness of the plating layer is to give the shuttle angle a radius of curvature of several meters instead of making it a sharp edge. However, in practice, this radius must not exceed 1 to 2 m, otherwise the possibility of liquid gold splashing between the end of the roller and the firing side plate will increase. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Another conventional method involves skewing the streamline by means of a device called " data collector β. These devices are metal-guided, and are arranged parallel to the shuttle angle and its vicinity through which the flow medium passes. They skewed some of the current medium towards them, and without these devices, these current lines would have concentrated on the shuttle angle of the sleeve and its surroundings. However, this solution is not satisfactory when used alone. Moreover, the positioning and operating parameters of these current collectors must be carefully measured, because otherwise, in addition to the phenomenon of through-thickness, the edge will still exist, sometimes it will be found that the opposite, the thickness of the plating layer in a certain place will be less than the nominal thickness -8- This paper size applies to Chinese National Standard (CpS) A4 specification (210 × 297 mm) A7 B7 V. Description of invention (") (Please read the" I "on the back of t» before filling out this page), table These current media are excessively deviated from the corresponding areas. Furthermore, when electroplating is performed, nickel is deposited on the current collectors in a non-negligible amount. Therefore, it is necessary to recover this chain, and it is for the sake of sedimentation. The current consumed is a pure loss. But the most important thing is that this disastrous change changes the size of the data collector, and then it can work in a very standardized way. Therefore, when the work is in progress, the data collector The effect varies greatly, which makes it difficult to manage. In fact, for the required coating thickness of 2 ··, the coating has a thickness of 2 · 5 on the edges and corners has been considered the best, but this value is still too high to make it Satisfactory resolution Therefore, for this application, the streamer cannot reliably achieve satisfactory nickel deposition uniformity, especially for the tinplate of lotus reading casting rolls. The inventors have discovered that the A very uniform nickel deposit was obtained in the middle and near the middle. The most reliable way is to place an insulation shield, preferably the specified structure shape, a short distance from the shuttle angle * and found that under these conditions, it is located in the edge area of the sleeve The phenomenon of premature cracks in the coating can be eliminated by K. Schematic illustration of the army printed by the consumer property cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The present invention will be more clearly understood by reading the following description and referring to the following cocoons: K is a diagrammatic method for seeing the ends and the I-I section, showing an apparatus for coating a double-roller casting roll sleeve, which is designed to carry out the method according to the invention. Show this II-II cross-section drawing on the same device, explaining that the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (j) According to the invention The preferred structure of the shield. The drawing number is a simple illustration of the printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 1 Electroplating tank 2 Electrolyte 3 Copper sleeve 4 Anode 4 〆Anode 5 Core holder 6 Shaft 7 Guard 7 Guard 8 Movable rod 9 Corner cut P 9 Corner cut □ 1 0 Side of cut 1 0, Side of cut 1 1 Outer edge 1 1, Outer edge 1 2 Shuttle angle 1 3 Side of shield 1 3, Side of shield 2 1 Vertical Anode 2 1 / vertical anode (please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (β) 2 1〃 Vertical anode The first circle K section view shows a device according to the present invention. * The cross-section plane is located within the perimeter of 霣 plating 1 which contains the electrolyte (the main component of which is H), but it is placed as The copper sleeves 3, K of the cathode are placed before the two anodes 4, 4 'at the bottom of the plating tank 1. The sleeve 3, which has a cylindrical outer shape and an outer diameter of 1,500 m, is mounted on a core seat 5, and the sleeve 6 of the latter is rotated by a mechanism not shown in the figure during K plating operation. At least the lower part of the holster 3 is immersed in a holm plating right. In the example shown, the anodes 4, 4 'are soluble anodes and consist of an arc-shaped titanium anode basket filled with particles. However, rhenium is only one embodiment, and different numbers of rhenium plates and other structural forms (for example, an insoluble anode) can also be provided. The anodes 4, 4 'extend beyond this cross-section. After the plane, their width is larger than the sleeve 3. Those treated as straight edges of the holster 3 are shields 7, 7 'made of insulating material (only 7 is visible in the first holster), and its function is to prevent the current lines from the anodes 4, 4' from reaching the holster. Edge area and edges, K to avoid the nickel plating on it is too thick. The positions of these shrouds 7, 7 'relative to the silk cover 3 can be adjusted by the positioning structure in which the moving rod 8 is shown in FIG. The exact form of these shields 7, 7 'is shown in the second figure. In the example shown, they present an elongated shape of approximately a square or rectangular cross section * and an overall shape with a curved shape, the center of curvature of which is the same as the shuttle angle of the copper sleeve 3 facing. Their upper edges are closest to the edge of the sleeve and exert an effect on them. These upper edges have a corner cutout 9, 9 ', the latter of which is -11-. This paper standard applies to China National Standard (CNS) 8 4 ^ Grid (2 丨 0X297mm) ---------- females_ > 1 *-*. (Please read the ji · Issue on the back of ## before filling this page) Order the wisdom of the Ministry of Economy A7 B7 printed by the Consumer Cooperative of the Property Bureau V. Description of the invention (1) Both sides are vertical and approximately the same length, for example, about 5m. The shields 7, 7 'are arranged by the rod 8 plus K so that the outer edges 1 1, 1 1' of the cutouts 9, 9 'are each placed at about the same shuttle angle 1 2 from the facing net cover 3 The distance 〃 d 〃. When it is desired to deposit nickel to a thickness of 2 to 3 m, this distance 〃 d " is initially about 5ra. On the other hand, the sides 1 3, 1 3 'of each shield 7, 7' must have a minimum length of 50 «in this embodiment of the present invention. It is precisely that under these conditions, the protection of Qin 7, 7 'can fully polarize the Xiaoliu media, making it the best distribution uniformity in the plaque field on the edge of the sack. As an option, the shields 7 and 7 'can be arranged such that K gradually moves away from the jacket 3 as the thickness of the plating layer increases. This movement can be performed in a step-by-step manner or by continuous reading. This ensures that there is sufficient clearance to remain between the shield and the coating at all times, and the K phase allows the rhenium nickel calendar to grow. It is suspected that the precise shapes of the anodes 4, 4 'and the shields 7, 7' are different. The plating on the ends of the silk cover 3 will be performed uniformly on the larger or smaller surface portions. In order to increase this part, the vertical anodes 21, 21 ', 21 ... are like the anode house filled with training particles *, which can be similar to the end of the anode basket 4, 4' and facing the sleeve 3, as It has been mentioned in the prior art that it is generally placed in the slot 1. Obviously, these shields may differ in their structure from those given as an example, as long as they can achieve the desired uniformity of the thickness of the coating to be achieved. In particular, they may not be composed of square, rectangular or other sections of elongated bodies, but may be composed of a plate or a plate assembly. * The surface of the plate or plate assembly facing the feeding jacket preferably has the same as that in the example. -12- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) ----------- clothing-• · * (please read ^ & on the back first) Please fill in this page for the matters needing attention) Print the A7 B7 399106 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (/ to) Structure. In other words * this surface should preferably include two parallel sides, which should be at the extension of the shuttle sleeve angle, the same distance from the latter " d " and connected by a corner cut, Its sides are perpendicular to each other. The present invention does not exclude this feasibility. The K-phase supplements and further refines the effect of the shroud. * It is also possible to use the data flow device permanently or indirectly, that is, these flow devices are added to the cover or are independent of the latter. Of course, the present invention can be used to deposit non-nickel gold rhenium onto a holster. In the same way, the shovel formed in this way can be used not only in the double-roller continuous pin gold slabs (made from period or other materials), but also in the slabs for continuous casting and one of the rotating cars gently licks the metal. In the eaves on the surface of the liquid pool (army casting). Moreover, it can also be used in the case described below, that is, the cast surface of a solid shaft is plated * in which the sleeve and the core seat are formed into a single body and the same workpiece. It can also be easily transformed into a situation where a suitable sleeve or solid roller is completely immersed in the electrolytic cell. Finally, as above, the relative movement between the nesting and the decomposing mass can be produced by keeping the sleeve stationary and the electrolyte moving around its periphery. This can be achieved by K, especially when the sleeve is completely immersed in the hydrolysis solution, and the movement of the hydrolysis solution is generated by the nozzles in a certain interval to circulate the electrolyte between the anodes and the anodes around. -13- This paper size is applicable to China National Standard (CNS) Α4 size (210X297mm)

Claims (1)

Α8 Β8 G8 D8 399106 申請專利範圍 88- ιΠ> 1 · 一種電鍍轘子之_造表面的方法,其用於雙輥或 單輥之薄金屬片的埋績薄造,輥子的表面霄鍍以金屬層, 於此方法中,該鏞製表面至少局部地浸沒在一種內含欲沈 積之金靥邇的電解液中,使成面對至少一個陽極,該表面 被放置在陰極處,且有一相對運動產生於該薄製表面與該 電解液之間,其特徵在於,絕緣護罩插設於該陽極或該等 陽檯與該鐲製表面之稜角間,該等絕緣護罩防止霣流媒集 中於該等梭角及其附近。 2 ·如申請專利範圍第1項之方法,其中,該等護罩 可於金靨鍍層之厚度增加之際逐漸移離該等稜角。 3 · —種電鍍輥子之鐘造表面(3)的設備*其用於 雙輥或單輥之薄金羼片的連續鑄_,輥子的表面(3)霣 鍍Κ金靥層*類型為包含有:一霣鍍檑(1),其容置有 內含欲沈積之金羼鹽的霣解質(2 ):用於將該鑄製表面 經濟部智慧財產局員工消費合作社印製 ----------士4 — ► - I -請先閱讀背面4注意事項再填寫本頁) 、1T X (3)至少局部地浸沒在該槽(1)內並用於在該鑄製表面 (3)與該霣解質(2)之間產生相對運動之機構(5、 6);至少一偁陽極(4、4'),其安置在榴(1)中 成面對該鏞製表面(3) ; Κ及用於提升該鑄製表面至陰 極霣勢之棰構;特激在於,該設備包括有由絕緣材質製成 之護罩(7、7'),其插設於該鋪製表面(3)之梭角 (12)與該陽極或該等陽槿(4、4')間,該等護罩 (7、7')可防止霣流線集中於該等梭角(12) 〇 4 ·如申請專利範圃第3項之設備,其中*該等護罩 -1- 本紙張尺度逋用中國國家橾準(CNS ) Α4规格(210X297公釐) Α8 Β8 G8 D8 399106 申請專利範圍 88- ιΠ> 1 · 一種電鍍轘子之_造表面的方法,其用於雙輥或 單輥之薄金屬片的埋績薄造,輥子的表面霄鍍以金屬層, 於此方法中,該鏞製表面至少局部地浸沒在一種內含欲沈 積之金靥邇的電解液中,使成面對至少一個陽極,該表面 被放置在陰極處,且有一相對運動產生於該薄製表面與該 電解液之間,其特徵在於,絕緣護罩插設於該陽極或該等 陽檯與該鐲製表面之稜角間,該等絕緣護罩防止霣流媒集 中於該等梭角及其附近。 2 ·如申請專利範圍第1項之方法,其中,該等護罩 可於金靨鍍層之厚度增加之際逐漸移離該等稜角。 3 · —種電鍍輥子之鐘造表面(3)的設備*其用於 雙輥或單輥之薄金羼片的連續鑄_,輥子的表面(3)霣 鍍Κ金靥層*類型為包含有:一霣鍍檑(1),其容置有 內含欲沈積之金羼鹽的霣解質(2 ):用於將該鑄製表面 經濟部智慧財產局員工消費合作社印製 ----------士4 — ► - I -請先閱讀背面4注意事項再填寫本頁) 、1T X (3)至少局部地浸沒在該槽(1)內並用於在該鑄製表面 (3)與該霣解質(2)之間產生相對運動之機構(5、 6);至少一偁陽極(4、4'),其安置在榴(1)中 成面對該鏞製表面(3) ; Κ及用於提升該鑄製表面至陰 極霣勢之棰構;特激在於,該設備包括有由絕緣材質製成 之護罩(7、7'),其插設於該鋪製表面(3)之梭角 (12)與該陽極或該等陽槿(4、4')間,該等護罩 (7、7')可防止霣流線集中於該等梭角(12) 〇 4 ·如申請專利範圃第3項之設備,其中*該等護罩 -1- 本紙張尺度逋用中國國家橾準(CNS ) Α4规格(210X297公釐) A8 399106 ?I ___ D8 六、申請專利範圍 ,,(請先閲讀背面之)ϊ^項再填寫本頁) (7、7')具有呈圇弧形之鐮體形狀,其曲率中心相同 於所面對之鑄製表面(3)之梭角者,而且具有兩平行之 側面(13、13'),各面放置於該等梭角(12)之 延伸處,距後者有相同之距離〃 d〃 ,且二面藉由一轉角 形之切口 (9、9')而連接,切口之倜面(1〇、1〇 ')彼此互相垂直。 5 ♦如申諸專利範國第4項之設備,其中,該等護罩 (7、7 ')由長形體组成。 6 ♦如申請專利範園第4項之設備,其中,該等護罩 (7 ^ 7 f )由板或板之姐件组成。 7 ·如申請專利範圃第3項之設備,其中,其包含有 用於在該金羼鍍層埔厚之際將該萼護罩(7、7')逐禰 移離該等梭角(12)之櫬構(8)。 8 ·如申諝專利範圃第3至第7項中任一項之設備, 其中*其亦包括有各安置成面對該績製表面(3 )之一端 部之陽極(21、21^)。 經濟部智慧財產局員工消費合作社印製 9 *如申請專利範圍第3至第7項中任一項之設備, 其中*其亦包括有據流器。 1 0,如申請專利範困第9項之設偁,其中,該擄流 器被納入於該護罩(7、7')中。 1 1 ♦如申謫專利範画第3至第7項中任一項之設備 ,其中,該用於在該鑭製表面(3)與該電解質(2)間 產生相對蓮動之櫬構為用於旋轉該鑄製表面(3)之镅構 -2 - 本&張尺度逋用中國國家梂準(CNS ) A4规格(210X297公釐) 399106 ll D8六、申請專利範圍 備間該 設 } 環 之 2 循 項 ί > 1 質 3 任解 { 中電面 項該表 7 與造 第 } 鏞 至 3 該 3 {著 第面键 圍表於 範製用 利鏞為。 專該構構 請在機機 申 於之之 如用動 } . 該運 2 2 * 對 ί 1 中相質 其生解 , 產電 (請先閲讀背面之ji意Ϋ項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度逋用中國國家標準(CNS > Μ規格(210Χ297公釐)Α8 Β8 G8 D8 399106 Application patent scope 88- ιΠ > 1 · A method for forming the surface of electroplated rafters, which is used for the thin production of thin metal sheets of double rolls or single rolls, and the surface of the rolls is plated with metal In this method, the stamped surface is at least partially immersed in an electrolyte containing gold tincture to be deposited so as to face at least one anode, the surface is placed at the cathode, and there is a relative movement Generated between the thin surface and the electrolyte, characterized in that an insulating shield is interposed between the anode or the balcony and the corner of the bracelet surface, and the insulating shields prevent the flow medium from being concentrated on These shuttle corners and their vicinity. 2. The method according to item 1 of the scope of patent application, wherein the shields can be gradually moved away from the corners as the thickness of the gold-plated coating increases. 3 · —A kind of equipment for plating the surface (3) of electroplated rollers * It is used for continuous casting of thin gold slabs of double rolls or single rolls. There is: a tinplate (1), which contains the disintegrating substance containing the gold tincture salt to be deposited (2): used for printing on the cast surface of the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs --- ------- Shi 4 — ►-I-Please read the precautions on the back 4 before filling this page), 1T X (3) at least partially immersed in the groove (1) and used for the casting surface (3) a mechanism (5, 6) that generates relative motion with the disintegration substance (2); at least one anode (4, 4 '), which is placed in the grit (1) so as to face the casting surface (3); K and a structure for lifting the casting surface to the cathode potential; particularly exciting is that the device includes a shield (7, 7 ') made of insulating material, which is inserted in the shop Between the shuttle angle (12) of the control surface (3) and the anode or the hibiscus (4, 4 '), the shields (7, 7') can prevent the streamline from focusing on the shuttle angle (12) ) 〇4 · If the equipment of the patent application No. 3, * of these shields -1- This paper uses China National Standards (CNS) A4 size (210X297 mm) Α8 Β8 G8 D8 399106 Application patent scope 88- ιΠ > 1 · A method for making surface of electroplated rafters, which is used for The thin metal sheet of the double roll or single roll is thinly built, and the surface of the roll is plated with a metal layer. In this method, the prepared surface is at least partially immersed in an electrolyte containing gold tincture to be deposited. In order to face at least one anode, the surface is placed at the cathode, and a relative motion is generated between the thin surface and the electrolyte, characterized in that an insulating shield is inserted between the anode or the like Between the balcony and the edges and corners of the bracelet surface, the insulating shields prevent the flow media from concentrating on the shuttle corners and their vicinity. 2. The method according to item 1 of the scope of patent application, wherein the shields can be gradually moved away from the corners as the thickness of the gold-plated coating increases. 3 · —A kind of equipment for plating the surface (3) of electroplated rollers * It is used for continuous casting of thin gold slabs of double rolls or single rolls. There is: a tinplate (1), which contains the disintegrating substance containing the gold tincture salt to be deposited (2): used for printing on the cast surface of the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs --- ------- Shi 4 — ►-I-Please read the precautions on the back 4 before filling this page), 1T X (3) at least partially immersed in the groove (1) and used for the casting surface (3) a mechanism (5, 6) that generates relative motion with the disintegration substance (2); at least one anode (4, 4 '), which is placed in the grit (1) so as to face the casting surface (3); K and a structure for lifting the casting surface to the cathode potential; particularly exciting is that the device includes a shield (7, 7 ') made of insulating material, which is inserted in the shop Between the shuttle angle (12) of the control surface (3) and the anode or the hibiscus (4, 4 '), the shields (7, 7') can prevent the streamline from focusing on the shuttle angle (12) ) 〇4 · If the equipment of the patent application No. 3, * of these shields -1- This paper uses China National Standards (CNS) A4 size (210X297 mm) A8 399106? I ___ D8 6. Scope of patent application, (please read the first one on the back), and then fill in this page) (7, 7 ') has a sickle shape with a sigmoid arc shape, the center of curvature is the same as the shuttle angle of the casting surface (3) facing, and has two parallel sides (13, 13'), each The planes are placed at the extensions of these shuttle angles (12), the same distance from the latter 〃d〃, and the two sides are connected by a corner-shaped cut (9, 9 '), and the cut plane (1〇 , 10 ′) are perpendicular to each other. 5 ♦ If the equipment is applied to item 4 of the patent, the shields (7, 7 ') are composed of elongated bodies. 6 ♦ If you apply for the equipment of patent park No. 4, in which the shields (7 ^ 7 f) are composed of boards or board sisters. 7 · The equipment according to item 3 of the patent application, which includes the device for removing the hood (7, 7 ') from the shuttle angle (12) one by one when the gold lining is thick. The structure of (8). 8 · The equipment of any one of items 3 to 7 of the Shen Fan Patent Garden, which * also includes anodes (21, 21 ^) each arranged to face one end of the performance surface (3) . Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 9 * If the equipment in any of the scope of patent applications No. 3 to No. 7 is applied, * it also includes a data flow device. 10, as set forth in item 9 of the patent application, wherein the flow generator is incorporated in the shield (7, 7 '). 1 1 ♦ The device of any one of items 3 to 7 of the Shen Fan Patent Painting, wherein the structure for generating a relative lotus motion between the lanthanum surface (3) and the electrolyte (2) is Structure for rotating the casting surface (3)-2-The & Zhang scale uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 399106 ll D8 Circumstance 2 > 1 qualitative and 3 arbitrary solutions {CLP surface item of the table 7 and the first part} 镛 to 3 The 3 {the surface key surrounding the table is used in the standard system for profit. This structure should be used in the application of the machine}. The transport 2 2 * The quality of the 1 medium, the production of electricity (please read the meaning of the item on the back before filling this page) Ministry of Economic Affairs The paper size printed by the Intellectual Property Bureau employee consumer cooperative uses the Chinese national standard (CNS > M specification (210 × 297 mm)
TW86108694A 1996-12-31 1997-06-21 Process and plant for electrolytically coating the casting surface of a roll TW399106B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9616255A FR2750438B1 (en) 1996-06-27 1996-12-31 METHOD AND INSTALLATION FOR ELECTROLYTIC COATING WITH A METAL LAYER OF THE SURFACE OF A CYLINDER FOR CONTINUOUS CASTING OF THIN METAL STRIPS

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