A7 B7_ 五、發明説明（i ) 發明背费 發明範園 此發明係關於一種淸潔堅硬表面的方法，特別是金屬 物體的表面，其經常會受到包括廣泛使用在機械製造上作 爲潤滑油與/或作爲抗生銹的短暫保護物之油或相似的物質 的污染，這種油性物質平常必須實質上全部自金屬表面去 除，以使其在一個塗佈表面上有一致的形態而提供抗生銹 之長期保護。 此處所使用的”鹼性淸潔溶液” 一詞包括所有的水溶 液，其包含（i)至少一個溶解的鹼性構成物，例如鹼性物 質或鹸土族氫氧化物、碳酸鹽、硼酸鹽、磷酸鹽或矽酸鹽 以及（Π)沒有抵銷之酸或是使得所有組成物的pH大於8的 這種酸之一定量，此系列中的硼酸鹽、磷酸鹽及矽酸鹽包 括簡軍與濃縮的兩種形式，例如偏矽酸鹽、焦磷酸鹽、三 聚磷酸鹽以及硼砂和其他類似物，這種鹼性物質與鹼土族 金屬特別包括鈉、磷、鎂、鈣、鋇、及其他類似物，更特 別的是，此項發明關於這些包含氫氧化物作爲惟一或至少 最主要的鹼性組成物之淸潔溶液及製備這些溶液的濃縮 液。 相關抟術之敘述 一般來說，現在被用來作爲金屬表面製備的鹼性淸潔 劑組成物包括一種可能爲一種界面活性劑的單獨化學類型 或是這種化學類型之混合物界面活性劑成份，其包括任何 _；_3__— 本紙張尺度適用中國國家標準（CNS ) A4規格（210><297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 良， 經濟部智慧財產局員工消费合作社印製 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（> ) 或所有陰離子、陽離子、兩性離子及非離子的界面活性劑 之類，（陽離子界面活性劑一般比其他類型較不常使用於金 屬淸潔配方，因爲此等較可能影響後續的過程，及以某種 可能爲副面的方式對金屬表面處理），非離子界面活性劑通 常具有較佳的淸潔力，但卻不容易溶解於髙度濃縮的氫氧 化物水溶液，其就經濟理由上減少運送水的成本爲所需 的：如果一種高度濃縮的液體可以作爲一種強鹼淸潔劑的 濃縮液來補充，包含由該濃縮液而來的鹼性成份之有效的 淸潔溶液可以更經濟地在需要使用之時添加當地的水而配 製。 非離芋表面劑經溶解作用成爲濃縮的鹼性水溶液可以 藉由混合包含磷之陰離子界面活性劑的一些類型來幫助上 是已知的，即使如此，含磷淸潔劑經常爲環境考量上所反 對的，包含安基群的界面活性劑，例如推薦用於作爲強鹼 淸潔劑的一些商業產品之界面活性劑混合物也可能爲環境 上所不欲使用的》 發明說明 發明目槱 此項發明的主要目標在提供一種鹼性、若屬期望之強 鹼的水溶液淸潔組成物與/或一種由其得而來之界面活性劑 之組合物，其淸潔力至少與從前習知技術利用大重含磷與/ 或氮的界面活性劑之組成物所能達到的效果一樣好，但卻 能減少磷與/或氮使用在組成物上的童至最少，其他同時的 _'_4_____ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------------裝-------.--1T------泉/ (請先聞讀背面之注意事項再填寫本頁) A7 B7 五、發明説明（巧） 或另一個目標則在提供具有比以前技術所使用的淸潔劑更 好的淸潔力之水溶液淸潔組成物，其他的目標將於下列敘 述中得知。 說明之槪栝原理 除了在申請專利範圍及操作的例子，或者其他顯示出 表示相反的例子之外，在此敘述中顯示出物質量或反應的 狀況與/或使用之所有數目量，必須藉由文字“大約”的修 改在於敘述此赛明之最廣泛範圍上的修改而使其被了解， 但是，在所陳述之數目的限制之內的實施通常爲較好的， 同時，也經由說明及申請專利範圍，除非相反地陳述表 現：百分ώ、“其中之部份”及重量的比率値；”聚合體”一 詞包括”寡聚合體”、”共聚合體” '”三聚合體”及其他類似 之詞；在與此發明有關連的一個已知目的之合適或較好一 « 個組群或物質的種類之敘述，顯示出任何兩個或兩個以上 的組群或種類之其中部分的混合物爲同等合適或較好的； 以化學名詞對組成物之敘述適用於當組成物加入在此敘述 中所列舉的任何組合，且不需要排除一旦混合之時混合物 的組成物間所產生的化學反應；以離子形式存在的物質之 詳述顯示出足夠反離子的存在，以對於一整體上的組成物 產生電性中和，因此而絕對上較好地列舉出來之任何反離 子是從其他以離子形式存在而淸楚地被列舉出來的組成物 中所選擇出來的，直到可能的程度上；否則，這些反離子 可被自由地選擇出來，除了表現對發明的目標具有負面影 響所須避免的反離子外，；以及”莫耳”一詞與其變化可能 _'__5___ 本紙張尺度適用中國國家標準（CNS > Α4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 泉，· 經濟部智慧財產局員工消費合作社印製 A7 _ B7 五、發明説明（4 ) 適用於離子的、化學上不穩定中性的、或任何其他的化學 種類，不論爲真實或假設的，其會藉由存在的原子之類型 及包含於限定單元中每種原子類型之數目來載明，.同時也 適用於限定明確的中性分子上。 發明摘沭 非離子界面活性劑之特殊類型與陰離子有機物質的一 個特殊類型所組成的混合物已在此被發現，此二者實質上 皆沒有除碳、氫及氧以外的任何化學元素，此混合物可以 在溫和至強鹼的水溶液淸潔組成物中以產生少量可接受的 泡沫來達齒良好的淸潔效力，並且具有足夠的溶解性可使 一包穩定之有超過25 %之全部的鹼性金屬氫氧化物內容物 的液態濃縮液之配方可行。 發明詳沭，包栝鲛籽的窗施例 此項發明的一個較好之實施例，爲一種合適的、經過 水的稀釋後也合適的或者兩種情況下皆合適的水溶液組成 物，以用來淸潔堅硬的表面，特別是鋼鐵與鑛鋅鋼鐵表 面，這種組成物較好地或更好地基本上由水以及 (A) —種溶解的鹼性化成份之量 (B) 一種由分子所組成的組群中逡擇出來有機物質 的已溶解成份之量，其每一個分子包含（i)至少一個羧基 或羧酸鹽部份及（ii)總共至少10個碳原子，以及 (C) 一種非離子界面活性劑之已溶解成份之量，除 _^1_ ---- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) -装· 訂 經濟部智慧財產局員工消費合作社印製 A7 _ B7 五、發明説明（s) (請先閱讀背面之注意事項再填寫本頁) 先前所列舉的任何成份之其中一部份以外，該成份是由每 —個分子包含至少4個- (CH2CH2O)-基團，較好爲相互 連結成一列，所組成的分子中選擇出來的 並且，選擇性地含有下列一種或多種的成份： (D) 任何非先前所列舉成份其中一部份的一種離子 多價螯合劑與/或蟄合劑成份之量， (E) 一種非任何先前所列舉的成份其中一部份的抑 制泡沬劑的成份之量， 對於成份（A)較好的驗性化試劑包括銨、鈉及氫氧化 鉀，其中以後兩者較佳， 這兩者似乎在實質上對促進淸潔的作用是相等的，氫 氧化鈉通常較便宜，但也會與幾乎任何的酸性物質結合而 形成較不可溶之鹽，其酸性物質可能加入此組成物中及/或 對於在共同水溶液中的非電解質較不具耐性，因此，根據 此項發明，至少有一些氫氧化鉀一般較適於極強之濃縮 液，在一個特殊較佳的實施例中，祇有鉀與氫氧化鈉被使 用於成份（A)中。 經濟部智慧財產局員工消费合作社印製 與其他較好的例子無關地，根據此發明的一種濃縮液 組成物，其成份（A)中的溶解的氫氧化物之量可以提供， 以順序表示增加之較佳性，至少全部濃縮液組成物每公斤 中1.0， 2.0， 3.0， 3.5， 3,8， 4.1， 4.4， 4.7或5.0莫 耳的氫氧根離子，當所有可溶之鹼性金屬與鹸土族金靥的 氫氧化物溶解於此組成物中的氫氧根離子之所有化學計量 上之當量被認爲是決定是否達到這些較好値之溶解的氫氧 ____ 7____ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部智慧財產局員工消費合作社印製 ——ο — ο Α7 Β7 五、發明説明（t ) 根離子，除了當已知會與水溶液氫氧根離子快速反應的酸 或其他試劑也加入組成物時之外，在這個例子中，祇有經 過理論性完全的中和或這些加入之試劑所產生的其他快速 反應後之淨殘留的氫氧根離子被認爲是溶解的氫氧根離 子，根據此項發明的有效組成物中，其溶解的氫氧根離子 濃度較好爲先前於此段落中所陳述對濃縮液組成物較好的 濃度之0 . 5到3 . 0 %。 成份（B)較好是由每一分子中包含至少兩個由（i)唆 基及羧酸鹽部份（H)非爲羧基及羧酸鹽部份其中之一的 羰基及羥基部份所組成的組群中所選擇出來的部份，在該 分子之內尚該兩部份分別較好地以至少在該分子中兩個原 子的距離來彼此分開，其中該分子並非是該兩個部份的其 中之一。更好地，由祇包含羧基及羧酸鹽部份之組群中所 選出之至少兩個部份是存在於成份（Β)的每一個分子中， 並且，每一個部份的碳原子是分別地在成份（Β>的一個分 子中由恰好兩個或恰好三個其他原子來分開，就此敘述的 目的上，一般式的一個單一部份： -C-0-C- 被認爲與兩個羧基及羧酸鹽部份相同，這是因爲當此 單一部份在加入一個根據此發明的組成物中之時，會被預 期快速水解爲相同的雙羧酸或鹽。與所有其他較好點無關 地，成份（B)中分子較好地具有所有碳原子之數目以及由 _____a__ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X：297公ϋ I--------裝--.--^--、訂------泉， - . (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（7 ) (i)羧基及羧酸鹽部份（Π)非爲羧基及羧酸鹽部份其中 之一的羰基及羥基部份所組成的組群中所選出的部份之數 目，因此而在所有成份（B)的平均上，所有碳原子之數目 對於由（i)羧基及羧酸鹽部份（ii)非爲羧基及羧酸鹽部 '份其中之一的羰基及羥基部份所組成的組群中所選出的部 份之所有數目的一比率，至少就其逐增之較佳性依序爲 3.0:1.0, 3.5:1.0, 4.0:1.0, 4.5:1.0, 5.0:1.0, 5.5:1.0或5.9:1·0，且分別較好地就其逐增之較佳性依 序爲不超過 20:1.0, 18:1.0, 16:1.0, 14:1.0, 12:1.0, 11.0:1.0, 10.0:1.0, 9,0:1.0, 8.0:1.0, 7.5 :1. 〇/7·0: 1.0或6.5:1.0。最好地，成份（B)是由辛 烷基-與壬烷基-琥珀酸以及其鹽中所選擇出來，其可能以 此形式或上面所提的無水物形式加入組成物中。. 成份（C)較好包括符合至少一種一般式I與II的分子： R1 R2，〇-(-CH-CH2-0)s-R3 ⑴’ 其中R1代表一個氫原子或一個甲基，並且可能在此成 份中因分子之間的差異以及在此成份的一個單一分子內位 置之間的差異而爲相同或不同的；R2代表一個線形、環形 及/或分枝狀、飽和或非飽和之單價脂肪族部份，其中（1) (1.1)爲碳化氫部份，或（1.2)可能在形式上由一個碳 化氫部份衍生而來的，其藉由（1 · 2 . 1 )至少一個鹵素原 __0 __ 本紙張尺度適用中國國家標準（CNS〉A4規格（210X297公釐） I — II------r 裝-----.--訂------'康 (請先閲讀背面之注，意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製. A7 B7 五、發明説明（左） 子來取代至少一個氫原子，以及/或（1·2·2)藉由至少一 個醚氧原子來取代至少一個亞甲基，其亞甲基係由至少三 個碳原子與在式（I)中直接連接在R2的該氧原子分開，以 及（2)具有碳原子與醚氧原子的一個總數，因此而在符合 一般式I的水溶液組成物中，所有分子內的每一個R2部份 上碳原子與醚氧原子總數之平均値，就其逐增的較佳性依 序至少爲 5.0, 6.0， 7,0, 8·0, 9.0， 10.0， 11.0 或 11.8，且分別較好地就其逐增之較佳性依序爲不超過50, 4 0, 3 0，2 5, 2 0, 1 8, 1 6, 1 5.0, 1 4.0, 1 3.5, 1 3.0 或12.5 ; R3代表一個氫原子或一個具有不超過三個碳原 子總數之卓價有機部份；以及s代表一個正整數，但卻不代 表每一個分子具有相同的正整數；以及 R1 R4-(C6H4)-0-(-CH-CHr0)rR3 (Π)ι 其中R1與R3對一般式I上具有相同的意義；R4代表 一個線形' 環形及/或分枝狀、飽和或非飽和之單價脂肪族 部份’其中（1 ) ( 1 . 1 )爲碳化氫部份，或（1 . 2 )可能在 形式上由一個碳化氫部份衍生而來的，其藉由（1.2.1) 至少一個鹵素原子來取代至少一個氫原子，以及/或 (1.2.2) 至少一個醚氧原子來取代至少一個亞甲基，或者 (1.2.3) 同時藉由至少一個鹵素原子來取代至少一個氫原 子以及至少一個醚氧原子來取代至少一個亞甲基，以及 (2)具有一個碳原子與醚氧原子的總數，因此而在符合— _____^___ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐〉 -----------^裝—---：—訂------東 . , (請先閲讀背面之注意事項再填寫本頁) A7 B7 五、發明説明（9 ) (請先閱讀背面之注意事項再填寫本頁) 般式II的組成物中所有分子內，在此組成物中的每一個R4 部份之碳原子與醚氧原子總數的平均値，就其逐增之較佳 性依序至少爲 3.0，4.0，5.0，6.0，7.0, 7. 5 或 8.0， 且分別較好地就其逐增之較佳性依序爲不超過20, 18, 16, 15.0, 14.0, 13‘0， 12.0, 11.0， 10.0或9.0; (C6H4)代表一個間位、鄰位或對位次苯基環；並且t代表 一個正整數，但卻不代表每一個分子具有相同的正整數。 符合上面所提一般式I的成份（C)之分子，在此以後可 被共同命名爲成份（C.1)，而相似地，符合上面所提一般 式II的成份（C)之分子，在這裡以後可被共同命名爲成份 (C·2)，成份（C.1)與成份（C·2)兩者其中之一或兩者可 同時但非爲必須地構成所有成份（C ) » 經濟部智慧財產局員工消费合作社印製 更好地，每一個所提的較佳性分別地，各別在每一個 成份（C.1)與成份（C.2)內，對於其特定部份存在於相同 的一般式中：每一個R2與R4爲線形或祇具有一個甲基側 鍵在另外的線形結構上；r3是由氣、甲基、乙基、丙基、 甲醯基及乙醯基部份所組成的組群中所選出；由所有該成 份對於S與R1代表一個氫原子的R1之部份的平均値，成份 (C · 1 )的親水性-親油性平衡値（在此以後簡稱爲“ H L B，’） 因而就其逐增之較佳性依序至少爲5.0，5.5，6.0，6.5, 7.0，7·5，7.9或8.2，且分別較好地就其逐增之較佳性 依序爲不超過 20.0，19.0，18.0，17.0，16.0，15.0, 14_7，14.4, 14.1，13. 9或13. 7;並且由所有成份 (C.2)對於t及R1代表一個氫原子的R1部份之平均値，成 _. _U______ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公瘦) ~ 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（/) 份（C.2)的HLB値因而就其逐增之較佳性依序至少爲8.0, 9.0, 10.0, 11.0, 12.0, 12.3, 12.6, 12.9, 13.2 或13.5，且分別較好地就其逐增之較佳性依序爲不超過 20, 18.0, 17.0, 16.5, 16.0, 15.5, 15.0, 14.5, 14.1， 13.9或13_8= 仍然在較好地、主要地基於經濟上的理由以及分別對 於每一個R2與R4上：在每一個R2或R4部份的醚氧原子上 之所有成份（C.2)的R4或所有成份（C.1)的R2之平均値， 就其逐增之較好性依序爲不超過2.0，1.5，1.0，0.5, 0.3，0.1，0.02或0.002 ;並且，分別地，在每一個R2 或R4部份的鹵素原子之所有成份（C.2)的R4或所有成份 (C. 1 )的R2之平均數目，就其逐增之較佳性依序爲不超過 10， 8， 6, 4， 2.0， 1.5， 1.0， 0.5， 0.3， 0.1， 0.02 或 0 · 0 0 2 ° 與所有其他所陳述對於成份（C.1)的較好性無關地， 就所有成份的平均上來看，每一個分子包含至少一個爲甲 基而非氫的R 1部份。 較好地，根據此發明的一種有效之淸潔組成物，包括 如上述以濃度表示的成份（B)、（C)、（C.1)及（C.2)，因 此分別對於每一個所述的較佳性上：成份（C.1)的濃度就 其逐增之較佳性依序至少爲〇.〇〇1，0.002，0.004, 0.006，0.008或0.010 %，但主要基於經濟的理由上， 就其逐增之較佳性依序爲不超過10，5，4.0，3.〇，2.〇, 1.0, 0.8 0, 0.7 0, 0.6 0, 0.5 0, 0.4 0, 0.3 0, 0.2 0, 本紙張尺度適用中國國家標準（CNS > A4規格（210X297公釐） ----------1^----tr------'線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 A7 _ B7 五、發明説明（|j ) 〇.1〇，0.0 80, 0.060, 0·040 或 0.020%;成份（(3,2) 的濃度就其逐增之較佳性依序至少爲0.002，0.004, 0.008，0.012，0.016或0.020 %，但主要基於經濟的 理由上，就其逐增之較佳性依序爲不超過10，5，4.0, 3.0, 2.0, 1.0, 0.80, 0.70, 0.60, 0.50, 0.40, 0-3 0, 0.20, 0.1 0, 0.0 8 0, 0.06 0, 0.040 或 0.030 % ;成份（C.2)的濃度對於成份（C.1)的濃度（若此 濃度非爲零）之比率，就其逐增之較佳性依序至少爲 0.10:1.0, 0.20:1.0, 0.30:1.0, 0.35:1.0, 0-40:1.0, 0.45:1.0或0.50:1.0，但分別地就其逐增 之較佳性'依序爲不超過50:1.0，40:1.0，30:1.0, 20:1.0, 10:1.0, 9.0:1.0, 8.0:1.0, 7.0:1.0, 6.0:1.0, 5.0 : 1 0，4.0: 1 ·0，3· 0: 1 ·0，2 5 : 1.0 或 2.0:1.0 ;成份（B)的濃度就其逐增之較佳性至少爲0.20, 0.30, 0.40, 0.50, 0.60, 0.70, 0.80, 0.90或0.98 倍相較於較大之（i)成份（C.1)濃度的4倍以及（ii)成 份（C.2)濃度的0.5倍，但是分別主要地基於經濟上的理 由，就其逐增之較佳性依序爲不超過20，15，12，10，8, 7.0，6.5，6.0，5.5, 5.0或4. 5倍相較於所有成份（C) 的濃度。 所觀察到對於成份（C.1)與（C.2)兩者的存在的一個 較好性之主要原因，爲後者在淸潔上較具有效性且較可溶 於強鹸之水溶液中，但有很強的產生泡沫之傾向，.然而前 者本身單獨具有一些淸潔力，並且也不可預期地作爲一種 ______13__ 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） ------------裝--------1T------^ (請先閱讀背面之注意事項再填寫本頁) A7 __B7_ 五、發明説明（、> ) 非常有效的去泡沬劑在一種祇有包括其他成份（A)、（B)以 及（C · 2 )之水溶液組成物上。 對於產生泡沬的抗性在任何淸潔組成物的使用上通常 是有實際上的重要性，因爲過多泡沫之量的產生會使得大 多數的淸潔方法失去效用，一個實驗之測試已發現其與實 際的泡沬抗性一般有很大的關連，實施如下： 一體積爲100毫升的被測試之組成物置於一個具有玻 璃塞且至少250毫升容置的量筒中，此置筒與其內容物藉 由任何合適的方法被帶至於溫度的平衡，通常爲一個可控 制的溫度浴，並且接著當此量筒與玻璃塞在固定位置直立 方向之時/以手將其上下快速強烈搖動連續二十次，在這 搖動完成之後，立刻將此量筒以直立方式置於一個水平的 桌子上並且將玻璃塞移開，當玻璃塞被移開之時即立刻啓 動計時器，泡沫的體積是由量筒上的刻度來測定的，其是 在計時器啓動後的30±1與/或60±1秒時，藉由記錄此童筒 中介於泡沫頂端的刻度與其下的液體組成物頂端的刻度之 不同而得到。 根據此.發明之一個有效的組成物，或根據此發明包含 一個濃縮液組成物2.0 %之一種於水的溶液，較好地爲具 有一個藉由上述測試所測得之泡沬體積，其就逐增之較佳 性依序爲不超過 150, 1 0 0, 75, 60，50，40，30，25, 20, 15, 12, 10, 8 , 7.0, 6.0, 5.0, 4.0, 3.0 或 2.0 毫升》 成份（B)具有相對較小的淸潔力，但似乎作爲一種未 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) .裝·A7 B7_ V. Description of the invention (i) The invention of this invention is a method of cleaning a hard surface, especially the surface of a metal object, which is often subjected to a wide range of applications including lubricants used in machinery manufacturing and / Or as a temporary protection against rust, such as oil or similar substances, this oily substance must usually be substantially completely removed from the metal surface so that it has a consistent morphology on a coated surface to provide long-term resistance to rust. protection. As used herein, the term "alkaline cleaning solution" includes all aqueous solutions that include (i) at least one dissolved alkaline constituent, such as an alkaline substance or a terracotta hydroxide, carbonate, borate, phosphoric acid Quantification of salts or silicates and (Π) one of the acids that does not offset or make the pH of all components greater than 8, the borate, phosphate and silicate in this series include Jian Jun and concentrated Two forms, such as metasilicates, pyrophosphates, tripolyphosphates, and borax and other analogs, this alkaline substance and alkaline earth metals include in particular sodium, phosphorus, magnesium, calcium, barium, and other similar More specifically, this invention relates to these cleaning solutions containing hydroxides as the sole or at least the most basic alkaline composition and the concentrates from which these solutions are prepared. Description of related arts Generally speaking, the alkaline detergent composition currently used as a metal surface preparation includes a single chemical type which may be a surfactant or a mixture of such chemical types. It includes any _; _ 3 __— This paper size applies to Chinese National Standard (CNS) A4 specifications (210 > < 297 mm) (Please read the notes on the back before filling this page) Well-Ordered, Staff of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperative, printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperative, A7 B7 V. Description of Invention (>) or all anionic, cationic, zwitterionic and nonionic surfactants, etc. Types are less commonly used in metal cleaning formulas because these are more likely to affect subsequent processes and to treat metal surfaces in a way that may be a secondary surface). Nonionic surfactants usually have better cleaning power. , But it is not easy to dissolve in concentrated aqueous hydroxide solution, which is necessary for economic reasons to reduce the cost of transporting water : If a highly concentrated liquid can be supplemented as a concentrated solution of a strong alkaline detergent, an effective cleaning solution containing alkaline ingredients from the concentrated solution can be more economically added when needed. With water. Non-ionized taro surfactants become concentrated alkaline aqueous solutions through dissolution, which can be helped by mixing some types of anionic surfactants containing phosphorus. Even so, phosphorus-containing detergents are often environmentally considered. Contrary to this, surfactants containing angemine groups, such as surfactant mixtures recommended for some commercial products as strong base detergents, may also be environmentally undesirable. [Explanation of the invention] This invention The main goal is to provide an alkaline, if desired, strong alkaline aqueous solution cleaning composition and / or a surfactant-derived composition that has a cleaning power at least as great as previously known techniques. The composition of the surfactant containing heavy phosphorus and / or nitrogen can achieve the same effect, but it can reduce the use of phosphorus and / or nitrogen in the composition to the minimum, and other _'_ 4_____ This paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) ------------ installation -------.-- 1T ------ Quan / (Please first listen (Read the notes on the back and fill out this page) A7 B7 V. Invention (Qiao) or another object is to provide Qing than previously used in detergent technology better cleaning power of Qing Qing aqueous cleaning composition, other objects will be described in the following classification known. Except for the example of the scope and operation of the patent application, or other examples showing the opposite, the description of the quality or reaction status and / or all the quantities used in this description must be obtained by The modification of the word "about" is to describe the widest scope of this seming to make it known, but it is usually better to implement it within the stated number of limitations.At the same time, it is also explained and patented. Scope, unless stated otherwise: Percentage, "part of it" and weight ratio 値; the term "polymer" includes "oligomers", "copolymers", "" tripolymers "and other similar Word; a description of a group or substance suitable or better for a known purpose in connection with this invention, showing a mixture of any two or more groups or species Are equally suitable or better; the description of the composition in chemical terms applies when the composition is added to any combination listed in this description, and does not need to be excluded once mixed The chemical reaction between the constituents of the mixture at that time; the detailed description of the substances in the form of ions shows the existence of sufficient counter ions to electrically neutralize the composition as a whole, so it is absolutely better Any counter-ions enumerated are selected from other compositions that are meticulously enumerated in the form of ions, to the extent possible; otherwise, these counter-ions can be freely selected, except for performance The counter ion that must be avoided that has a negative impact on the object of the invention, and the word "Mole" and its possible changes _'__ 5___ This paper size applies to Chinese national standards (CNS > Α4 size (210X 297 mm)) (Please Please read the notes on the back before filling this page) Dingquan, · Printed by A7 _ B7, Consumer Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (4) Applicable to ionic, chemically unstable neutral, or any Other chemical species, whether real or hypothetical, will depend on the type of atom present and the number of each atom type contained in the defined unit It is stated that, at the same time, it is also applicable to clearly defined neutral molecules. A mixture of a special type of nonionic surfactant and a special type of anionic organic substance has been found here, and the two are essentially There are no chemical elements other than carbon, hydrogen and oxygen. This mixture can produce a small amount of acceptable foam in a mild to strong alkaline aqueous cleaning composition to achieve good cleaning performance and has sufficient dissolution. It can make a package of stable liquid concentrate with more than 25% of the total content of alkaline metal hydroxides feasible. Details of the invention, the example of the window containing the seeds, a better one of this invention The embodiment is a suitable aqueous solution composition which is also suitable after dilution with water or in both cases for cleaning hard surfaces, especially steel and zinc-steel steel surfaces. This composition Better or better consisting essentially of water and (A) the amount of a dissolved alkaline component (B) a dissolved organic substance selected from a group of molecules The amount of dissolved ingredients, each molecule of which contains (i) at least one carboxyl or carboxylate moiety and (ii) a total of at least 10 carbon atoms, and (C) the amount of dissolved ingredients of a nonionic surfactant, Except _ ^ 1_ ---- This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) Print A7 _ B7 V. Description of the invention (s) (Please read the notes on the back before filling this page) Except for one of the previously listed ingredients, this ingredient is composed of at least 4 molecules per molecule -(CH2CH2O)-groups, preferably connected to each other in a row, selected from the group consisting of molecules and optionally containing one or more of the following components: (D) any of the components not previously listed The amount of an ion sequestering and / or chelating agent component, (E) an amount of a suds suppressing component that is not a part of any of the previously listed ingredients, a better test for ingredient (A) Gendering agents include ammonium, sodium Potassium hydroxide, the latter two of which are better, the two seem to have substantially the same effect on promoting cleanliness. Sodium hydroxide is usually cheaper, but it also combines with almost any acidic substance to form a more insoluble. Salt, whose acidic substance may be added to the composition and / or less resistant to non-electrolytes in a common aqueous solution. Therefore, according to the invention, at least some potassium hydroxide is generally more suitable for extremely concentrated concentrates, In a particularly preferred embodiment, only potassium and sodium hydroxide are used in component (A). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, regardless of other good examples, a concentrated liquid composition according to this invention, the amount of dissolved hydroxide in its component (A) can be provided, and the increase is expressed in order. Preferably, at least 1.0, 2.0, 3.0, 3.5, 3, 8, 4.1, 4.4, 4.7 or 5.0 moles of hydroxide ions per kilogram of the entire concentrated liquid composition, when all soluble alkaline metals and All stoichiometric equivalents of hydroxide ions of the 鹸 Tu group gold hydroxide dissolved in this composition are considered to determine whether to reach these better 溶解 dissolved hydroxides __ 7____ This paper standard applies to China National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-ο-ο Α7 Β7 V. Description of the invention (t) Root ions, except when known to react with hydroxide ions in aqueous solution In addition to the reaction acid or other reagents added to the composition, in this example, only the net residual after theoretically complete neutralization or other rapid reactions generated by these added reagents The remaining hydroxide ions are considered to be dissolved hydroxide ions. In the effective composition according to the present invention, the dissolved hydroxide ion concentration is preferably the concentration of the concentrated liquid composition previously stated in this paragraph. A better concentration is 0.5 to 3.0%. Ingredient (B) is preferably composed of at least two carbonyl and hydroxyl moieties consisting of (i) a fluorenyl group and a carboxylate moiety (H) which is not one of a carboxyl group and a carboxylate moiety in each molecule. The selected part of the group, the two parts are separated from each other by the distance of at least two atoms in the molecule, and the molecule is not the two parts. Serving one of them. More preferably, at least two moieties selected from the group consisting of only a carboxyl group and a carboxylate moiety are present in each molecule of the component (B), and the carbon atoms of each moiety are separately Earth is separated by exactly two or exactly three other atoms in one molecule of the component (B>). For the purposes of this description, a single part of the general formula: -C-0-C- The carboxyl and carboxylate portions are the same because when this single portion is added to a composition according to the invention, it is expected to rapidly hydrolyze to the same dicarboxylic acid or salt. As with all other good points Irrespective, the molecule in component (B) has the number of all carbon atoms and is _____a__ This paper size applies the Chinese National Standard (CNS) A4 specification (210X: 297) I -------- installation --.-- ^-、 Order ------ Quan,-. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description ( 7) (i) carboxyl and carboxylate moiety (Π) carbonyl and hydroxyl which are not one of the carboxyl and carboxylate moiety The number of selected moieties in the group of moieties. Therefore, on the average of all ingredients (B), the number of all carbon atoms is not equal to (i) carboxyl and carboxylate moieties (ii). A ratio of the total number of selected moieties in the group consisting of the carbonyl and hydroxy moieties of one of the carboxyl and carboxylate moieties is at least 3.0: 1.0 in order of increasing preference. , 3.5: 1.0, 4.0: 1.0, 4.5: 1.0, 5.0: 1.0, 5.5: 1.0, or 5.9: 1.0, respectively, and it is better that their progressiveness is not more than 20: 1.0, 18 in order : 1.0, 16: 1.0, 14: 1.0, 12: 1.0, 11.0: 1.0, 10.0: 1.0, 9,0: 1.0, 8.0: 1.0, 7.5: 1. 〇 / 7 · 0: 1.0 or 6.5: 1.0. Most Well, ingredient (B) is selected from octyl- and nonyl-succinic acid and its salts, and it may be added to the composition in this form or in the form of the anhydrous mentioned above. Ingredient (C ) Preferably include molecules that conform to at least one of the general formulae I and II: R1 R2, 0-(-CH-CH2-0) s-R3 ⑴ 'where R1 represents a hydrogen atom or a methyl group, and may be in this component Due to the differences between the molecules and a single The differences between the positions within the sub-groups are the same or different; R2 represents a linear, ring-shaped and / or branched, saturated or unsaturated monovalent aliphatic moiety, of which (1) (1.1) is a hydrocarbon moiety , Or (1.2) may be derived in form from a hydrocarbon moiety, which is based on (1 · 2. .1) at least one halogen source __0 __ This paper size applies Chinese national standards (CNS> A4 specifications ( 210X297 mm) I — II ------ r equipment -----.-- order ------ 'Kang (please read the note on the back first, please fill in this page before filling in this page) Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau. A7 B7 V. Description of the invention (left) to replace at least one hydrogen atom, and / or (1 · 2 · 2) to replace at least one methylene group with at least one ether oxygen atom, Its methylene system is separated by at least three carbon atoms from the oxygen atom directly connected to R2 in formula (I), and (2) has a total number of carbon atoms and ether oxygen atoms, and thus conforms to the general formula I In the aqueous solution composition, the average of the total number of carbon atoms and ether oxygen atoms in each R2 part of all molecules is The order of preference is at least 5.0, 6.0, 7,0, 8 · 0, 9.0, 10.0, 11.0, or 11.8, and the order of increasing preference is preferably not more than 50, 4 0, respectively. , 3 0, 2 5, 2 0, 1 8, 1 6, 1 5.0, 1 4.0, 1 3.5, 1 3.0 or 12.5; R3 represents a hydrogen atom or a valence organic unit having a total number of not more than three carbon atoms And s represents a positive integer, but does not mean that each molecule has the same positive integer; and R1 R4- (C6H4) -0-(-CH-CHr0) rR3 (Π) ι, where R1 and R3 are general formulas I have the same meaning; R4 represents a linear 'ring and / or branched, saturated or unsaturated monovalent aliphatic moiety' (where (1) (1.1) is a hydrocarbon moiety, or (1. 2) May be formally derived from a hydrocarbon moiety, which replaces at least one hydrogen atom by (1.2.1) at least one halogen atom, and / or (1.2.2) at least one ether oxygen atom Replace at least one methylene group, or (1.2.3) simultaneously replace at least one methylene group with at least one halogen atom and at least one ether oxygen atom , And (2) has a total number of carbon atoms and ether oxygen atoms, and therefore meets — _____ ^ ___ This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm> --------- -^ 装 ——---: — Order ------ East., (Please read the notes on the back before filling this page) A7 B7 V. Description of the invention (9) (Please read the notes on the back first (Fill in this page again.) In all the molecules of the composition of general formula II, the average of the total number of carbon atoms and ether oxygen atoms of each R4 moiety in the composition is at least in order of their increasing preference. It is 3.0, 4.0, 5.0, 6.0, 7.0, 7. 5 or 8.0, and it is better not to sequentially increase the gradual betterness of 20, 18, 16, 15.0, 14.0, 13'0, 12.0 , 11.0, 10.0 or 9.0; (C6H4) represents a meta-, ortho- or para-phenylene ring; and t represents a positive integer, but does not mean that each molecule has the same positive integer. Molecules that compose the component (C) of the general formula I mentioned above can be collectively named components (C.1) hereafter, and similarly, molecules that compose the component (C) of the general formula II mentioned above, Hereafter they can be collectively named ingredients (C · 2). One or both of the ingredients (C.1) and (C · 2) can form all ingredients (C) at the same time but not necessarily »Economy The Intellectual Property Bureau's Consumer Cooperatives printed better. Each of the mentioned advantages is separately in each component (C.1) and component (C.2). In the same general formula: each of R2 and R4 is linear or has only one methyl side bond on another linear structure; r3 is composed of gas, methyl, ethyl, propyl, methylamyl and ethylamyl Selected from the group consisting of parts; the mean 値 of all the constituents for the part of R1 where S and R1 represent a hydrogen atom, and the hydrophilic-lipophilic balance of the constituent (C · 1) 値 (after this Abbreviated as "HLB, ') Therefore, it is at least 5.0, 5.5, 6.0, 6.5, 7.0, 7.5, 7.9 or 8. 2, and it is better in terms of its increasing preference in order not to exceed 20.0, 19.0, 18.0, 17.0, 16.0, 15.0, 14_7, 14.4, 14.1, 13. 9 or 13. 7; and by all ingredients (C.2) For t and R1 representing the average 値 of the R1 part of a hydrogen atom, it becomes _. _U______ This paper size applies to China National Standard (CNS) A4 specification (210X297 male thin) ~ Consumption by the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative prints A7 B7 5. The HLB of the invention description (/) (C.2) is therefore at least 8.0, 9.0, 10.0, 11.0, 12.0, 12.3, 12.6, 12.9. 13.2 or 13.5, and in order of preference, they are preferably not more than 20, 18.0, 17.0, 16.5, 16.0, 15.5, 15.0, 14.5, 14.1, 13.9 or 13_8 = still better, Mainly for economic reasons and for each R2 and R4: R4 of all components (C.2) or R2 of all components (C.1) on the ether oxygen atom of each R2 or R4 moiety The average 値, in terms of its progressive increase, is no more than 2.0, 1.5, 1.0, 0.5, 0.3, 0.1, 0.02, or 0.002; and, in each R2 or R4 part, respectively The average number of R4 of all components (C.2) or R2 of all components (C.1) of the halogen atom is preferably not more than 10, 8, 6, 4, 2.0 in order of increasing. 1.5, 1.0, 0.5, 0.3, 0.1, 0.02 or 0 · 0 0 2 ° Regardless of all the other stated goodness of ingredients (C.1), on the average of all ingredients, each molecule contains at least One R 1 moiety is methyl rather than hydrogen. Preferably, an effective cleaning composition according to the present invention includes the components (B), (C), (C.1), and (C.2) expressed in terms of concentration as described above. In terms of the above-mentioned preference: the concentration of the component (C.1) is at least 0.001, 0.002, 0.004, 0.006, 0.008, or 0.010% in order of its increasing preference, but mainly for economic reasons In terms of its increasing preference, it is not more than 10, 5, 4.0, 3.0, 2.0, 1.0, 0.8 0, 0.7 0, 0.6 0, 0.5 0, 0.4 0, 0.3 0, 0.2. 0, This paper size applies to Chinese national standards (CNS > A4 size (210X297 mm) ---------- 1 ^ ---- tr ------ 'line (please read the back first Please note this page before filling in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _ B7 V. Description of invention (| j) 〇.1〇, 0.0 80, 0.060, 0 · 040 or 0.020%; ingredients ((3 , The concentration of 2) is at least 0.002, 0.004, 0.008, 0.012, 0.016, or 0.020% in order, but it is mainly based on economic reasons. More than 10, 5, 4.0, 3.0, 2.0, 1.0, 0.80, 0.70, 0.60, 0. 50, 0.40, 0-3 0, 0.20, 0.1 0, 0.0 8 0, 0.06 0, 0.040 or 0.030%; the concentration of the component (C.2) to the concentration of the component (C.1) (if this concentration is not zero) ), In order of their increasing preference, they are at least 0.10: 1.0, 0.20: 1.0, 0.30: 1.0, 0.35: 1.0, 0-40: 1.0, 0.45: 1.0 or 0.50: 1.0, but respectively The progressively better 'sequence is not more than 50: 1.0, 40: 1.0, 30: 1.0, 20: 1.0, 10: 1.0, 9.0: 1.0, 8.0: 1.0, 7.0: 1.0, 6.0: 1.0, 5.0 : 1 0, 4.0: 1 · 0, 3 · 0: 1 · 0, 2 5: 1.0 or 2.0: 1.0; the better the concentration of component (B) is at least 0.20, 0.30, 0.40, 0.50 , 0.60, 0.70, 0.80, 0.90, or 0.98 times compared to 4 times the concentration of the larger (i) component (C.1) and 0.5 times the concentration of (ii) component (C.2), but mainly based on For economic reasons, the order of increase is preferably no more than 20, 15, 12, 10, 8, 7.0, 6.5, 6.0, 5.5, 5.0 or 4.5 times compared to all ingredients (C) concentration. One of the main reasons observed for the goodness of the presence of both components (C.1) and (C.2) is that the latter is more effective in cleaning and is more soluble in strong aqueous solutions of thorium, However, there is a strong tendency to produce foam. However, the former itself has some cleaning power, and it is also unpredictable as a ______13__ This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)- ----------- Installation -------- 1T ------ ^ (Please read the notes on the back before filling this page) A7 __B7_ V. Description of the invention (&>) Very effective defoaming tincture on an aqueous solution composition containing only the other ingredients (A), (B) and (C · 2). The resistance to foaming is generally of practical importance in the use of any cleaning composition, because the generation of excessive foam will make most cleaning methods ineffective. An experimental test has found that It is generally related to the actual foam resistance, and is implemented as follows: A 100 ml volume of the composition to be tested is placed in a graduated cylinder with a glass stopper and at least 250 ml. The cylinder and its contents are borrowed. It is brought to the equilibrium of temperature by any suitable method, usually a controllable temperature bath, and then when the graduated cylinder and the glass stopper are in a fixed position upright direction / shake it up and down strongly by hand for twenty consecutive times, Immediately after this shaking, place the graduated cylinder on a horizontal table in an upright manner and remove the glass stopper. When the glass stopper is removed, start the timer immediately. The volume of foam is determined by the scale on the graduated cylinder. It is determined by recording the scale between the top of the foam and the liquid group below it at 30 ± 1 and / or 60 ± 1 seconds after the timer starts. It is obtained by the difference of the scale on the top of the object. According to this, an effective composition of the invention, or a solution containing 2.0% of a concentrated liquid composition in water according to the invention, preferably has a bubble volume measured by the above test, which is The order of increasing preference is not more than 150, 1 0 0, 75, 60, 50, 40, 30, 25, 20, 15, 12, 10, 8, 7.0, 6.0, 5.0, 4.0, 3.0 or 2.0. Ingredients (B) have relatively small cleaning power, but it seems to be a Chinese paper standard (CNS) A4 specification (210X297 mm). .Fitting
、1T 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（θ) 可預期的有效之可使成份（C)溶解化於強鹼水溶液中之趨 水劑。 對於可選擇的成份（D)之合適的離子多價螯合劑包括 山黎糖、甘露糖、葡糖酸、檸檬酸、庚葡糖酸、乙二銨四 醋酸（EDTA)、晴三醋酸（NTA)以及其他具水溶性包含至 少兩個羧基、羧酸鹽與/或羥基部份之有機化合物，最後者 爲不包括羧基部份其中之一的羥基，其由至少兩個，更好 的是恰巧兩個或三個，其他非爲羧基、羧酸鹽或羥基部份 的原子在此分子內彼此分開，同時也包括先前在此段落中 所有引述爲酸的化合物之鹽，特別是鉀鹽與鈉鹽。葡糖 酸、庚葡#酸、EDTA、NTA、山梨糖與/或甘露糖爲較 好的，根據此發明在一個濃縮組成物中之離子多價螯合劑 的濃度較好地就其逐增之較佳性依序至少爲0.1，0.3, 0.5，1.0，1.5，2.0，2.5，2 _9，3_1 或 3.3 %，並且分 別主要地基於經濟之理由，就其逐增之較佳性依序爲不超 過20， 15， 10， 8.0， 7.0， 6.0， 5.0， 4.5， 4.1， 3.9 或 3 · 7 % ° 根據此發明之淸潔的實施可以藉由以任何方法將欲被 淸潔之弄髒的堅硬表面送至與根據本發明的一種液態之有 效淸潔組成物接觸一段足夠的時間，以將至少部份在堅硬 表面的污物轉移至液態之有效淸潔組成物中，然後自與液 態之有效淸潔組成物的接觸中將表面移開而使其被淸潔， 並且，選擇性地但非通常地，以水沖洗已淸潔的表面以除 去任何附著的淸潔組成物》較好地，在一個被淸潔的表面 _；_15___ 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（叫） 與一種根據本此發明之組成物接觸的期間，根據此發明之 組成物的溫度就其逐增之較佳性依序至少爲30，35，40, 45，50, 55或60°C，且主要基於經濟的理由上，較好地 就其逐增之較佳性依序爲不超過90，85，80，75，70或 65。C 〇相較於其他接觸這些表面之方法，以一種有效淸潔 組成物噴灑於欲被淸潔表面上一般爲較好的，因爲噴灑衝 擊的機械作用有助於將污物快速轉移至液態淸潔劑中。 較好地，爲了防止環境污染以及其他多種的理由，根 據此發明之組成物較好爲包含，分別地對於每一個較好如 下所述的最小成份，就其逐增之較佳性依序爲不超過5.0, 3.0， 1.0, 0.5, 0.2, 0.10, 0.05， 0.02, 0.01， 0.005, 0.002, 0.001, 0.0005, 0.0002, 0.0001, 0.00005, 0.00002或0.00001百分比在於任何的： 磷、氮以及任何物質中其（i)非爲上述必須或可選擇的成 份之一的其中部份，以及（ii)在美國法律規範之下當作 “揮發性有機化合物”。 此發明之進一步的瞭解可藉由下列實例與比較例來得 到，這些例子在於欲說明此發明而非限制此發明。 賨例與比較例 顯示於下列表1與表2中之液態組成物被製備出來，大 部份但並非所有組成物是根據此發明而來，以及由其中一 些而來之有效組成物被製備與使用，如在此表的註解中所 敘述者，除#10以外的所有的組成物爲視覺上淸晰的且沒 ib 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) ”裝· 訂 經濟部智慧財產局員工消费合作社印製_ A7 7 Β 經濟部智慧財產局員工消費合作社印製. 五、發明説明（) 有相分離之目視證據顯示出來。 表1 成份 成份的百分比在組成物編號中： 1 2 3 4 5 6 於粒50%氫氧化納 9.6 9.6 9.6 9.6 9.6 9.6 於拉45%氫氧化鉀 24.0 24.0 24.0 24.0 24.0 24.0 麵麵C粉末） 3.5 3.5 3.5 3.5 3.5 3.5 壬基號《酐 1.0 2.0 3.0 3.0 2.0 2.0 TRITON™ X-405 1.0 1.0 « _ 1.0 TRITON™ X-100 • _ 0.5 0.5 0.5 TERGITOL™ 15-S-3 - - 3.0 2.5 1.5 - 表1之註解 在此表中對於每一個組成物未淸晰被顯示出來之平衡 爲水。 TRITON™ X - 4 0 5 係由 Van Waters and Rogers商業上所供應的，並且藉由其供給者而被敘述爲 一種酒精之被改良聚乙氧基配位鹽，而造成一個具有一個 HLB値爲13.6的非離子界面活性劑；TRITONTM X-100係由Van Waters and Rogers商業上所供應的，並 且藉由其供給者而被敘述爲一個壬苯之聚乙氧基配位鹽， 而造成一個具有一HLB値爲13.5的非離子界面活性劑； 以及 TERGITOLTM15_S-3 係由 Van Waters and Rogers商業上所供應的，並且藉由其供給者而被敘述爲 — Cii-15第二醇的聚乙氧基配位鹽，而造成一個具有一 H LB値爲8. 3的非離子界面活性劑。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） ------------------^裝-----^—訂------線 (請先閱讀背面之注意事項再填寫本頁) 17 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（4) 表2 成份 祕的百分比在 5$^物號碼： 7 8 9 10 11 12 13 14 於水之50%氫氧化納 . 5.0 於粒45%氫氧化鉀 40.0 40.0 40.0 50.0 40.0 40.0 65.0 70.0 壬基號班酸酐 20.0 12.0 12.0 12.0 12.0 2.0 2.0 2.0 TRITON™ X-100 L0 1.0 12.0 4,0 1.0 1.0 ANTAROX™ LF-224 3.0 3.0 3.0 _ 0.50 0.50 泡粒體横毫 升，經過： 30秒 5 2 7 Π.ΙΏ. 230 130 30 2 60秒 1 2 6 run. 230 130 30 2 無水突面百分比 0 70 100 η·πκ 100 100 100 100 表2之註解. 在此表中對於每一個組成物未被淸晰顯示出來之平衡 爲水** 泡沫之體積係藉由主要本文中所述之測試方法在於水 濃縮液之2 . 0 %溶液中於4 9 ° C之下而測量出來的》 “ n . m . ”表示“未測量”（因爲組成物非爲一個單獨相） 水突面百分比（％ Water-Break)値係由一個有經驗 的測率者經目視而測量出來，即標準化之弄髒的金屬測試 控制板之沒有被水突面所覆蓋表面的區域百分比，換言 之，一個附著之水層被分割爲目視上明顯的厚與薄的區 域，在不需額外的機械攪動，浸泡於一個有效之組成物中 10分鐘接著以水完全淸洗後，其組成物是藉由溶解相同的 濃縮液於水中以得到於此有效之組成物2.0 %濃縮液之水 溶液而製成，並且在浸泡期間被保持於60°c之下β _ _ ---------1-T 裝--，---- -I-訂------辣 (請先閱讀背面之注意事項再填寫本頁) 適 度 尺 張 紙 準 標 家 * 公 7 29， 1T Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (θ) A predictable effective water-soluble agent that can dissolve the component (C) in a strong alkaline aqueous solution. Suitable ionic sequestrants for optional ingredient (D) include selenic acid, mannose, gluconic acid, citric acid, heptonic acid, ethylene diammonium tetraacetic acid (EDTA), sunny triacetic acid (NTA ) And other organic compounds which are water-soluble and contain at least two carboxyl groups, carboxylates and / or hydroxyl moieties. The last one is a hydroxyl group that does not include one of the carboxyl moieties. Two or three, other atoms which are not carboxyl, carboxylate or hydroxyl moieties are separated from each other in this molecule, and also include all the salts of compounds previously cited as acids in this paragraph, especially potassium and sodium salt. Gluconic acid, heptogluconic acid, EDTA, NTA, sorbose and / or mannose are preferred, and the concentration of the ion sequestrant in a concentrated composition according to the present invention is preferably increased gradually. The order of preference is at least 0.1, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5, 2 _9, 3_1 or 3.3%, and based on economic reasons, respectively, the order of increasing preference is not More than 20, 15, 10, 8.0, 7.0, 6.0, 5.0, 4.5, 4.1, 3.9, or 3 · 7% ° The implementation of the cleanliness according to this invention can be achieved by any method that hardens the soil to be cleaned by cleanliness The surface is brought into contact with a liquid effective cleaning composition according to the present invention for a sufficient period of time to transfer at least part of the dirt on the hard surface to the liquid effective cleaning composition, and then self-effective with the liquid The surface is removed from contact with the cleaning composition to make it clean, and, optionally, but not usually, the cleaned surface is rinsed with water to remove any attached cleaning composition. On a cleaned surface _; _15___ This paper size applies National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling out this page) Order A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (called) and a basis During the contact of the composition of the present invention, the temperature of the composition according to the present invention is preferably at least 30, 35, 40, 45, 50, 55, or 60 ° C in order of increasing temperature, and is mainly based on economics. For reasons, it is better to sequentially increase it to no more than 90, 85, 80, 75, 70, or 65. C. Compared with other methods of contacting these surfaces, it is generally better to spray an effective cleaning composition on the surface to be cleaned, because the mechanical effect of spray impact helps to quickly transfer the dirt to the liquid. Detergent. Preferably, in order to prevent environmental pollution and many other reasons, the composition according to the present invention preferably contains, and for each of the smallest components that are preferably described below, the increasing order of the ingredients is sequentially as follows: Not more than 5.0, 3.0, 1.0, 0.5, 0.2, 0.10, 0.05, 0.02, 0.01, 0.005, 0.002, 0.001, 0.0005, 0.0002, 0.0001, 0.00005, 0.00002, or 0.00001. Percentages are in any of the following: phosphorus, nitrogen, and any substance (I) are not part of one of the above required or optional ingredients, and (ii) are considered "volatile organic compounds" under US law. Further understanding of this invention can be obtained from the following examples and comparative examples, which are intended to illustrate this invention and not to limit it. Examples and Comparative Examples The liquid compositions shown in Tables 1 and 2 below were prepared. Most, but not all, of the compositions were prepared according to this invention, and effective compositions derived from some of them were prepared. Use, as described in the notes of this table, all components except # 10 are visually clear and not ib This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please Please read the notes on the back before filling this page) ”Binding · Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs _ A7 7 Β Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Visual evidence shows. Table 1 The percentage of ingredients in the composition number: 1 2 3 4 5 6 50% sodium hydroxide 9.6 9.6 9.6 9.6 9.6 9.6 45% potassium hydroxide 24.0 24.0 24.0 24.0 24.0 24.0 noodles Face C powder) 3.5 3.5 3.5 3.5 3.5 3.5 3.5 Nonyl Anhydride 1.0 2.0 3.0 3.0 2.0 2.0 TRITON ™ X-405 1.0 1.0 «_ 1.0 TRITON ™ X-100 • _ 0.5 0.5 0.5 TERGITOL ™ 15-S-3-- 3.0 2.5 1.5-table The note of 1 in this table is not clearly shown for each composition as the balance is water. TRITON ™ X-4 0 5 is commercially supplied by Van Waters and Rogers and is used by its suppliers Described as a modified polyethoxy complex salt of alcohol, resulting in a nonionic surfactant with an HLB 値 of 13.6; TRITONTM X-100 is commercially available from Van Waters and Rogers, and by Its supplier was described as a polyethoxyl complex salt of nonylbenzene, resulting in a nonionic surfactant with an HLB 値 of 13.5; and TERGITOLTM15_S-3 was commercially supplied by Van Waters and Rogers And, by its supplier, it is described as a —polyethoxy complex salt of a Cii-15 second alcohol, resulting in a non-ionic surfactant with an H LB 値 of 8.3. This paper applies China National Standard (CNS) Α4 specification (210X 297 mm) ------------------ ^ installation ----- ^-order ------ line ( (Please read the notes on the back before filling out this page.) 17 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4. Description of the invention (4) Table 2 The percentage of ingredients is 5 $ ^ Item number: 7 8 9 10 11 12 13 14 50% sodium hydroxide in water. 5.0 45% potassium hydroxide in grains 40.0 40.0 40.0 50.0 40.0 40.0 65.0 70.0 Nonylhaobanic anhydride 20.0 12.0 12.0 12.0 12.0 2.0 2.0 2.0 TRITON ™ X-100 L0 1.0 12.0 4,0 1.0 1.0 ANTAROX ™ LF-224 3.0 3.0 3.0 _ 0.50 0.50 Transverse vesicles in milliliters, after: 30 seconds 5 2 7 Π.ΙΏ. 230 130 30 2 60 seconds 1 2 6 run. 230 130 30 2 Percentage of anhydrous surface 0 70 100 η · πκ 100 100 100 100 Note to Table 2 for each component in this table The balance shown clearly is water ** The volume of the foam is measured by using the test method described in this article mainly in a 2.0% solution of water concentrate below 49 ° C. "" N . m. ”means“ not measured ”(because the composition is not a separate phase). The percentage of water burst surface (% Water-Break) is measured by visual inspection by an experienced rater, that is, standardized soiling. 100% of the area of the metal test control panel that is not covered by the water projection surface Than, in other words, an attached layer of water is divided into visually distinct thick and thin areas. After no additional mechanical agitation is required, it is immersed in an effective composition for 10 minutes and then completely rinsed with water. The product is made by dissolving the same concentrated solution in water to obtain a 2.0% concentrated aqueous solution of the effective composition, and it is kept below 60 ° c during the soaking period. Β _ _ ------ --- 1-T Pack-, ---- -I-Order ------ Spicy (Please read the precautions on the back before filling in this page) Moderate rule paper standard mark * Public 7 29