TW396437B - A method of manufacturing a semiconductor device - Google Patents
A method of manufacturing a semiconductor device Download PDFInfo
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- TW396437B TW396437B TW087118275A TW87118275A TW396437B TW 396437 B TW396437 B TW 396437B TW 087118275 A TW087118275 A TW 087118275A TW 87118275 A TW87118275 A TW 87118275A TW 396437 B TW396437 B TW 396437B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
- H01L28/90—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
- H01L28/92—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by patterning layers, e.g. by etching conductive layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
- H01L28/84—Electrodes with an enlarged surface, e.g. formed by texturisation being a rough surface, e.g. using hemispherical grains
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Abstract
Description
五、發明說明(1) 發明背景 本發明係有關私 .. indri cal 公報第 導體裝置。 柱狀,因此 積,而未增 容量的情形 存電極。 製造方法。 之步驟。選 閘極電極 到4E圖只在 複數個元 .,、 3於—種具圓柱狀電容器(cyl capacltor)之半導體褒置的製造方法。 ' :、、、了牦加5己憶體之電容 5-2 1 8333號提出_錄羽々 +寻不J a開 上述記憶體元件,圓柱狀電容器之半 可藉-介電薄膜增:二之下Ϊ極做成-圓 加電容器所佔據心電極和下電極之接觸面 水m古&隹 的£域’亚且在確保電容器電 下來長:南積集度。今圓4 Z(/1T, 4 ®柱狀之下電極通稱為儲 第4 A到4 E圖!§ + 仏^ .a α顯不—種習知圓柱狀電容器之 參見弟4 Α圖,骑丄每厶从 將评細說明依據一習知製法 矽基底1上形成„閘極氧化層2、一 3、-擴散區4和相似物,以形成—元件。第4a 石夕基底1上顯示一亓杜,h % w + 丁 凡件’但矽基底1實際上具有 仵0 f這些元件和隔離層元件5上依序形成一層間絕緣層6 ::乳化層7。接觸窗14貫通一層間絕緣層“口一氧化層7 κ散區4。在接觸窗丨4之側壁表面上形成一氧化層8以改 =電特性(electrical Chracteristic)。 當接觸窗1 4被填滿時,也在氧化層7形成一既定 (predetermined)厚度之複晶矽層9。在複晶矽層9上堆積 一既定寬度之氧化層30和一複晶矽層丨3。在氧化層3〇和一 矽層1 3之側壁上形成一氧化矽側壁丨。 如第4B圖所示,以氧化層7為蝕刻終土層(etchingV. Description of the invention (1) Background of the invention The present invention relates to the conductor device of the Indri cal bulletin. It is a columnar electrode, so it has a large volume without increasing capacity. Production method. The steps. The selection of the gate electrode to the 4E diagram is only in a plurality of elements. 3, a manufacturing method of a semiconductor arrangement with a cylindrical capacitor (cyl capacltor). ': ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-,-dielectric The lower pole is made up-the contact surface of the core electrode and the lower electrode occupied by the round plus capacitor is in the range of the region and the capacitor is kept long: South accumulation. Jinyuan 4 Z (/ 1T, 4 ® cylindrical lower electrode is commonly referred to as the 4th to 4th E diagrams! § + 仏 ^ .a α is not obvious—see the conventional cylindrical capacitor, see Figure 4A, riding丄 Each from the detailed description, a gate oxide layer 2, a 3, a diffusion region 4 and the like are formed on a silicon substrate 1 according to a conventional manufacturing method to form an element. Section 4a Du Du, h% w + Ding Fan pieces, but the silicon substrate 1 actually has 仵 0 f. These elements and the isolation layer element 5 sequentially form an interlayer insulating layer 6 :: emulsion layer 7. The contact window 14 penetrates the interlayer insulation An oxide layer 7 κ scattered area 4. An oxide layer 8 is formed on the sidewall surface of the contact window 4 to change the electrical characteristics. When the contact window 14 is filled, it is also an oxide layer. 7 forms a polycrystalline silicon layer 9 of a predetermined thickness. An oxide layer 30 and a polycrystalline silicon layer of a predetermined width are stacked on the polycrystalline silicon layer 9. The oxide layer 30 and a silicon layer 1 3 A silicon oxide sidewall is formed on the sidewall. As shown in FIG. 4B, the oxide layer 7 is used as an etching final soil layer.
五、發明說明(2) =?來敍刻梦層9,以氧化層3〇為兹刻終止層來㈣ ,4 C圖所示移除氧化層3 0钱刻以露出矽層9。 =4D圖所示’以側壁…為蝕刻罩幕,蝕 ;底:上有一既定厚度。然後,自石夕層9形成-其頂端開 啟之内凹(recessed)的儲存電極16。 貞鳊開 =4E圖所示,在儲存電極16之表面上形成一介電声 電層18上形成—單元薄板電極(ce 曰 electrode),便完成上述圓柱狀電容器。 知技術上’因為在第4D圖之钱刻石夕層9的步驟中, 二:5 :不易辦別’所以在儲存電極16底部上之矽声的厚 :f不易控制。若底部上之矽層太薄, ;成記憶體操作錯誤(hold err〇r);若石夕層太厚之 乂之儲存電極16的内區域(in j 、 / 容量的減少。 、ner area)會造成電容器之電 發明概述 本發明之一目的為提供一種可輕易 1 導體裳置的製造方法。 I易控制蝕刻深度之半 為達上述目的,本發明提供一種半導 ;,;:於在-半導體基底上形成-=ΐ;:ΐΓ 。。。叆衣造方法包括下列步驟:在上述半 電合 複數層發層,以及用和上述石夕層相異之材料 —終點§己號層(endpoint marker),來將上、十、 口第 部份。蝕刻上述矽層以及第—和第 記;石夕層分成三 °匕琥層,並依照 五、發明說明(3) 被蝕刻物之種類來控制上述矽層之蝕刻深度,以形成上述 儲存電極。 圖式之簡單說明 第1 A至1 Η圖皆為剖面圖,其分別顯示根據本發明之第 一實施例來製造一半導體裝置之步驟。 第2Α至2Β圖皆為剖面圖,其分別顯示根據本發明之第 二實施例來製造一半導體裝置之步驟。 第3圖為一圖表,顯示未摻雜之非晶系石夕層的厚度與 在其上方之形狀不良(erroneous shape)HSG之數目的關 係。 第4A至4E圖皆為剖面圖,其分別顯示製造一傳統半導 體裝置之步驟。 符號說明 1 0 1〜矽基底;1 0 2〜閘氧化層;1 0 3〜閘極電極;1 0 4〜擴 散區;105〜元件隔離層;106〜層間絕緣層;107〜未#雜氧」 化層;1 0 9〜矽層;1 1 0〜終點記號層;1 1 1 ~矽4 ; 1 1 2〜終點 記號層;1 1 3〜矽層;1 1 5〜氧化層;1 1 5 a〜側壁;1 1 6〜儲存 電極;1 1 7〜核;1 1 8 ’介電層;1 1 9〜單元平板電極。 實施例 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂,下文特舉一較佳實施例,並配合所附圖式,作詳 細說明如下。 第1 A至1 Η圖皆為剖面圖,其分別顯示根據本發明之第 一實施例來製造一半導體裝置之步驟。V. Description of the invention (2) = to describe the dream layer 9 and to use the oxide layer 30 as the termination layer to remove the oxide layer 30, as shown in FIG. 4C, to expose the silicon layer 9. As shown in the 4D picture, the sidewall is used as an etching mask, and the bottom is etched with a predetermined thickness. Then, a storage electrode 16 having a recessed opening is formed from the top of the stone layer 9. As shown in FIG. 4E, a dielectric-acoustic layer 18 is formed on the surface of the storage electrode 16—a cell thin plate electrode (ce), and the cylindrical capacitor is completed. Known technically, because in the step of carving the stone layer 9 in FIG. 4D, 2: 5: not easy to do, the thickness of the silicon sound on the bottom of the storage electrode 16: f is not easy to control. If the silicon layer on the bottom is too thin, memory operation error (hold error); if the stone layer is too thick, the inner area of the storage electrode 16 (inj, / capacity reduction, ner area) SUMMARY OF THE INVENTION An object of the present invention is to provide a manufacturing method capable of easily disposing a conductor. I Easy to control half of the etching depth In order to achieve the above-mentioned object, the present invention provides a semiconducting semiconductor ;;: is formed on a -semiconductor substrate-= ΐ;: ΐΓ. . . The method of making clothes includes the following steps: the hair layer is formed in the above-mentioned semi-electrochemical multiple layers, and the material different from the above-mentioned Shi Xi layer-the end point § end point marker (endpoint marker), . The above-mentioned silicon layer and the first and the first are etched; the Shixi layer is divided into three layers, and the etching depth of the above-mentioned silicon layer is controlled according to the description of the invention (3) to be etched to form the above storage electrode. Brief Description of the Drawings The first to the eighth drawings are cross-sectional views each showing a step of manufacturing a semiconductor device according to the first embodiment of the present invention. 2A to 2B are cross-sectional views each showing a step of manufacturing a semiconductor device according to a second embodiment of the present invention. Fig. 3 is a graph showing the relationship between the thickness of the undoped amorphous stone layer and the number of erroneous shapes HSG above it. 4A to 4E are cross-sectional views each showing a step of manufacturing a conventional semiconductor device. DESCRIPTION OF SYMBOLS 1 01 ~ Si substrate; 102 ~ Gate oxide layer; 103 ~ Gate electrode; 104 ~ Diffusion area; 105 ~ Element isolation layer; 106 ~ Interlayer insulation layer; 107 ~ 未 # 杂 氧"Chemical layer; 109 to silicon layer; 1 10 to end point mark layer; 1 1 1 to silicon 4; 1 12 to end point mark layer; 1 1 3 to silicon layer; 1 1 5 to oxide layer; 1 1 5 a ~ sidewall; 1 1 6 ~ storage electrode; 1 1 7 ~ core; 1 1 8 'dielectric layer; 1 1 9 ~ unit plate electrode. Embodiments In order to make the above and other objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below and described in detail with reference to the accompanying drawings. 1A to 1E are cross-sectional views each showing a step of manufacturing a semiconductor device according to the first embodiment of the present invention.
第6頁 五、發明說明(4) 氧化ϊι:ΑΛ所V選擇性地在-矽基底101上形成-閘 極電;il〇3為罩=乳化層1G2上形成—間極電極1Q3。以間 ^ /、罩幕,在矽基底1 0 1中、閘極電極1 〇 3兩旁之 二ή2成擴散區104。閘氧化層102、間極電極103 ’ 和擴散區104構成—元件。 仕。第1^至1Η圖只顯示一元件’但實際上製造複數個元 711彼此間以一元件隔離層(e 1 ement i solat ion f i lm) 1 05 隔離。 依序在這些元件和元件隔離層丨〇 5上形成一層間絕緣 曰(interUvel insulating film)1〇6 和一未摻雜氧化層 1〇7。接觸窗114穿越層106和1〇7並連通至擴散區1〇4。在 接觸_ 1 1 4内侧上形成一氧化層,以改善電特性。 以稀釋之氰氟酸移除一形成在擴散區丨〇 4在接觸窗丨j 4 底鈿上之一自然(na t i ve )氧化層後,在氧化層丨〇 7上形成 一有既定(predermined)厚度之矽層109.。同時矽層109會 填滿接觸窗11 4。在矽層1 〇 9上依序形成一終點記號層 11 0、一矽層111、一終點記號層丨丨2、和一矽層丨丨3。 當一矽層1 0 9、111和11 3為摻雜磷之非晶系矽所構成 時,可以將一含矽甲烷和磷化氫之氣體放置在52〇〜53〇°c 之間、0.5〜2.0 torr 之成長壓力,及 i.〇e2〇 at〇ms/ccl0 或更高之麟濃度的環境下而形成。石夕層11 3可以是摻雜或 未摻雜的非晶系矽。也可以電漿加強化學氣相沈積法 (Plasma Enhanced-Chemical Vapor Deposition, PE-CVD)形成該非晶系矽。當HSG(半球形顆粒,Page 6 V. Description of the invention (4) Oxide oxide: ΑΛ is selectively formed on the silicon substrate 101-a gate electrode; il03 is formed on the mask = emulsion layer 1G2-an interelectrode electrode 1Q3. With a mask, the diffusion region 104 is formed on both sides of the gate electrode 103 in the silicon substrate 101. The gate oxide layer 102, the inter electrode 103 ', and the diffusion region 104 constitute an element. official. Figures 1 ^ to 1Η show only one element ', but in practice, a plurality of elements 711 are separated from each other by an element isolation layer (e 1 ement i solat ion f i lm) 1 05. An interUvel insulating film 106 and an undoped oxide layer 107 are sequentially formed on these elements and the element isolation layer 05. The contact window 114 passes through the layers 106 and 107 and communicates with the diffusion region 104. An oxide layer is formed on the inner side of the contact 1 1 4 to improve the electrical characteristics. A dilute cyanofluoric acid is used to remove a natural oxide layer formed on the diffusion region, the contact window, and the bottom of the contact window, and a predetermined layer is formed on the oxide layer. ) The thickness of the silicon layer 109. At the same time, the silicon layer 109 will fill the contact window 11 4. An end mark layer 110, a silicon layer 111, an end mark layer 丨 2 and a silicon layer 丨 3 are sequentially formed on the silicon layer 109. When a silicon layer 10, 111, and 11 3 is composed of phosphorus-doped amorphous silicon, a gas containing silicon methane and phosphine can be placed between 52 ° ~ 53 °° C, 0.5 It is formed under a growth pressure of ~ 2.0 torr, and a concentration of i.oe20atoms / ccl0 or higher. The stone layer 111 may be doped or undoped amorphous silicon. The amorphous silicon can also be formed by plasma enhanced chemical vapor deposition (PE-CVD). When HSG (hemispherical particles,
第7頁 1 五、發明說明(5)Page 7 1 V. Description of the invention (5)
Henii - Spherical Grain)未出現在後續步驟時,一 1 〇 9、1 1 1和1 1 3也可採用複晶石夕。 曰 終點記號層11 0和1丨2為約卜2nm厚之氧化矽層或氮化 石^層,其乃在下方‘之矽層^㈣和^!時之程中/加入' 乳或氨而形成s終點記號層丨丨〇和丨丨2之另_赘 軎 止矽層109和111之成長時,加入氧,使得在矽層 之表面上形成一自、然,氧化層(nat i ve 〇xide 。如 此矽層1 Ο 9、1 11和1 1 3可連續地生長。 如第1Β圖所示,對矽層113施以非等向性的乾蝕刻, 使其只留下一既定寬度在接觸窗丨丨4上。此時,隨時監控 在電漿中之被蝕刻物的激發情況,依照終點記號層丨〗2中 内所含之物質的發光強度來決定是否應停止蝕刻: 終點記號層11 2為氧化矽時,便監測氧之發光強度。 也可用質譜儀來分析被姓刻物,取代監視其發光強度之方 法來決定蝕刻終點。 , ^ 如第1C圖所示,在50(TC或更低之溫度,以常靨CVD或 PE-CVD ’在終點記號層112和矽層113上形成一氧化層 一 I 1 5。同時,植入雜質磷或硼,形成一硼磷矽玻璃 (BoroPhosphoSilicate Glass, BPSG)。 如第1 D圖所示,以一非等向性乾蝕刻法回蝕氧化層 II 5,形成在矽層11 3側壁上之側壁11 5 a。 如第1 E圖所示,以側壁11 5a為蝕刻罩幕,蝕刻矽層 11 3、終點記號層11 2和矽層111。在蝕刻矽層丨丨丨之過^ 中,隨時監控在電漿中之被钱刻物的發光情況,依照終點Henii-Spherical Grain) does not appear in the subsequent steps, 109, 1 1 1 and 1 1 3 can also be used polycrystalline. The end mark layers 11 0 and 1 丨 2 are about 2 nm thick silicon oxide layer or nitride ^ layer, which is formed by adding / adding 'milk or ammonia in the silicon layer ^ ㈣ and ^! Below. s end mark layer 丨 丨 〇 and 丨 丨 2 additional _ 軎 to stop the growth of silicon layers 109 and 111, add oxygen, so that a natural, oxide layer (nat i ve 〇xide) is formed on the surface of the silicon layer In this way, the silicon layers 10, 9, 11 and 1 1 3 can be continuously grown. As shown in FIG. 1B, the silicon layer 113 is subjected to anisotropic dry etching so that it only leaves a predetermined width in contact. Window 丨 丨 4. At this time, monitor the excitation of the etched material in the plasma at any time, and decide whether the etching should be stopped or not according to the luminous intensity of the substance contained in the end mark layer 2: End mark layer 11 When 2 is silicon oxide, the luminous intensity of oxygen is monitored. Mass spectrometers can also be used to analyze the inscription of the surname, instead of monitoring its luminous intensity to determine the end point of etching. As shown in Figure 1C, at 50 (TC or At a lower temperature, an oxide layer I 1 5 is formed on the end mark layer 112 and the silicon layer 113 by conventional CVD or PE-CVD. An impurity phosphorus or boron is implanted to form a BoroPhosphoSilicate Glass (BPSG). As shown in FIG. 1D, the oxide layer II 5 is etched back by an anisotropic dry etching method to form a silicon layer 11 3 The side wall 11 5 a on the side wall. As shown in FIG. 1E, the side wall 11 5a is used as an etching mask to etch the silicon layer 11 3, the end mark layer 11 2 and the silicon layer 111. After the silicon layer is etched, the ^, At any time to monitor the luminescence of the money carved in the plasma, according to the end point
五 、發明說明(6) "己號層11 〇中所含之物質之發光強度來決定是否應停止蝕 刻。同時,在側壁1 1 5a外之矽層i n、終點記號層丨丨0,和 石夕層1 0 9也被蝕刻移除。結果,形成一儲存電極i丨6,其中 在底部留下矽層109,使矽層109具有一既定厚度。 當終點記號層1 1 2為氧化石夕時,便監測氧之發光強 度。也可用質譜儀來分析被蝕刻物,取代監視其發光強度 之方法來決定.蝕刻終點。 、 如第1 F圖所示’選擇地移除側壁1 1 5 a。若氧化層1 〇 7 為未摻雜之氧化石夕層及側壁11 5 a為硼填石夕玻璃,則可用氮 氟酸來移除側壁11 5 a。 如第1G圖所示’以稀釋之氫氟酸來移除儲存電極丨】6 上^自然氧化層後’在550〜6 0 0 °c之溫度及imT〇rr或更低 之壓力下,通入矽甲烷氣體以沈積核(nucUi)n7在儲存 電極116之表面上。 ,如第1 H圖所示,當核1 1 7沈積在儲存電極1 1 6之表面上 後,將形成之結構回火(anneal)以形成突出(pr〇jecting) 之HSGsll7a。之後形成一介電層118和—單元平板電極 11 9 ’完成本發明之圓柱狀電容器。 這裡並不-定要成長HSGs。如同f知技術,可以在沒 有HSGs下,在儲存電極上形成介電層和單元平板電極,完 成圓柱狀電谷器。在此例中,石夕層 '不_ θ非a么 ΑΛ- ^ A Τ- Ο T% ^ 尤疋并日日糸石夕。 弟2A至2B圖顯示根據本發明之第二實施例來 導體裝置之步驟。#中與第之同 則 相同部分H實施例中,為了降低電阻或其他==V. Description of the invention (6) " The luminous intensity of the substance contained in the numbered layer 110 is used to determine whether the etching should be stopped. At the same time, the silicon layer i n, the end mark layer 丨 丨 0, and the Shi Xi layer 109 outside the side wall 1 15a are also removed by etching. As a result, a storage electrode i6 is formed, in which a silicon layer 109 is left at the bottom, so that the silicon layer 109 has a predetermined thickness. When the end mark layer 1 12 is oxidized stone, the luminous intensity of oxygen is monitored. Mass spectrometers can also be used to analyze the etched material instead of monitoring its luminous intensity to determine the etching end point. 1. As shown in FIG. 1F ', the side wall 1 1 5 a is selectively removed. If the oxide layer 107 is an undoped oxidized oxide layer and the sidewall 11 5 a is boron-filled glass, the hydrofluoric acid can be used to remove the sidewall 11 5 a. As shown in Figure 1G, 'remove the storage electrode with dilute hydrofluoric acid 丨] 6 after ^ natural oxide layer', at a temperature of 550 ~ 60 0 ° C and a pressure of imTorr or lower, pass Silica gas is introduced to deposit nucUi n7 on the surface of the storage electrode 116. As shown in Fig. 1H, when the core 1 1 7 is deposited on the surface of the storage electrode 1 1 6, the formed structure is annealed to form a protruded HSGsll7a. Then, a dielectric layer 118 and a unit plate electrode 11 9 'are formed to complete the cylindrical capacitor of the present invention. There is no need to grow HSGs here. Like the known technique, a dielectric layer and a cell plate electrode can be formed on the storage electrode without HSGs to complete a cylindrical valley device. In this example, the Shi Xi layer 'not _ θ is not a? ΑΛ- ^ A Τ- Ο T% ^ You Xi and Shi Xi Xi. Figures 2A to 2B show steps of a conductor device according to a second embodiment of the present invention. # 中 同 同 第 The same part in the H embodiment, in order to reduce the resistance or other ==
第9頁 五、發明說明(7) 質’梦層109 —.二111和丄11為摻—雜之..非晶表矽。另外,如第 2 A圖所示’未摻雜之矽層1 2 0和1 2 1分別形成在終點記號層 1 1 0和1 1 2與矽層1 1 1之界面上。 , 石夕層109之厚度為15〇·、矽層hi之厚度為49〇nm,以 及石夕層11 3之厚度為4 3 0 n m。.未摻雜之非晶系矽層1 2 〇和1 2 1 之尽度皆為3〇nm。 一若在一氧化層上直接形成一濃摻雜之非晶系矽層,則 在尚溫製程中,例如生長層、形成HSG核,以及HSG回火等 製程’非晶系矽會從氧化層之界面上開始結晶化。更明確 地說,第2A圖中,摻雜之察晶系矽層1〇9、丨丨i和:〗13可能 會結晶化。當HSG要長在儲存電極之表面上時,.矽層之結 曰曰化若達到儲存電極之表面,會阻止Hsg之生長。. 因為如C ’特別需避免在儲存電極丨丨6中佔有最大面 積之石夕層1 1 1被結晶化。 - 本發明之發明者發現,矽層丨丨i义結晶化可藉由i 點記號層110和112與矽層Uli界面上,分別形成未摻ς 之矽層1 2 0和1 2 1來避免。 所以,雖然接觸氧化層107和115之矽層1〇9和113 晶化成如第2Β圖所示之複晶矽122 ’矽層Π1仍被未摻雜= 矽層1 2 0和1 2 1包夾住而耒結晶化。, ’ '之 _雖然終點記號層11 〇仍留在儲#電極11 6中,但其尸挣 薄如卜2 nm。薄的終點記號層丨丨〇可令電子如穿n—流^^ (tunnel current)般通過其中,所以並不會產生寄生 器(paraSltlC capacitor)。終點記號層層11〇孓厚度為各Page 9 V. Description of the invention (7) The qualitative ‘dream layer 109—II 111 and 丄 11 are doped-doped .. amorphous silicon. In addition, as shown in FIG. 2A, the 'undoped silicon layers 1220 and 1221 are formed on the interfaces of the end mark layers 1 10 and 1 12 and the silicon layer 1 11 respectively. The thickness of the stone evening layer 109 is 150 °, the thickness of the silicon layer hi is 49 nm, and the thickness of the stone evening layer 11 13 is 4 30 nm. The extent of the undoped amorphous silicon layers 1 2 0 and 1 2 1 is 30 nm. Once a heavily doped amorphous silicon layer is formed directly on an oxide layer, in the still-temperature process, such as the growth layer, the formation of HSG cores, and HSG tempering and other processes, the amorphous silicon layer will be removed from the oxide layer. Crystallization begins at the interface. More specifically, in Fig. 2A, the doped crystalline silicon layers 109, 丨 i, and 13 may be crystallized. When the HSG is to grow on the surface of the storage electrode, if the silicon layer reaches the surface of the storage electrode, it will prevent the growth of Hsg. Because, for example, C ′, it is particularly necessary to avoid the crystalline layer 1 1 1 which occupies the largest area in the storage electrode 丨 6. -The inventors of the present invention have discovered that the silicon layer can be avoided by forming undoped silicon layers 1 2 0 and 1 2 1 on the interface of the i-dot mark layers 110 and 112 and the silicon layer Uli, respectively. . Therefore, although the silicon layers 109 and 113 contacting the oxide layers 107 and 115 are crystallized into the polycrystalline silicon 122 ′ shown in FIG. 2B, the silicon layer Π1 is still undoped = silicon layers 1 2 0 and 1 2 1 Clamped and the osmium crystallized. Although the end mark layer 110 remains in the storage #electrode 116, its body is as thin as 2 nm. The thin end mark layer allows electrons to pass through it like a n-current (tunnel current), so no paraSltlC capacitor is generated. The thickness of the end mark layer is 10mm.
五、發明說明(8) lnm或更大,所以可當作可靠的蝕刻終點記號。 將說明如何決定夫松雜夕非s & β 弋木4雜之弈日日糸矽層1 2 0和1 2 1的厚 度。 弟3圖將祝明未摻雜之非晶系石夕層 形狀不良之HSG之數目的關係。如第3圖所顏豆 摻雜之非晶系矽層的含Ρ濃产而定,芒 ’、視/、下方之 層m和⑴料“ 之HSG的發生。 厂1乂避免开y狀不良 將詳細說明依據本發明之實施例。實 LP-CVD形成矽層1〇9和113 ;實施例4 1 pE-CVD沈積產生。 中之矽層113則以 〈實施例1 > 各層之材料和厚度如下所述: 矽層U 3 : b雜之非晶系石夕層(4 3 〇 n m) 終點記號層1 1 2 : 氧化矽層(1〜2nm) 未換雜之非晶系矽層1 2 1 : 未推雜之非晶系石夕層121(30nm) 矽層111 : 4雜之非晶系石夕層(4 9 Ο n m ) 未捧雜之非晶系矽層120 : 未推雜之非晶系矽層121(30ηπ〇 終點記號層層1 1 〇 :5. Description of the invention (8) lnm or larger, so it can be used as a reliable etching endpoint mark. It will be explained how to determine the thickness of the Fusong Zaxifei s & β Tochigi 4 Misaki ri sundial silicon layer 1 2 0 and 1 2 1. Figure 3 shows the relationship between the number of HSGs with poor shape in the undoped amorphous stone layer. As shown in Fig. 3, depending on the concentration of P-containing amorphous silicon-doped amorphous silicon layers, HSG's, depending on the layer below, and the material "HSG" will occur. The embodiment according to the present invention will be described in detail. The actual LP-CVD is used to form the silicon layers 109 and 113; the embodiment 4 is produced by pE-CVD deposition. The silicon layer 113 is formed by the material of each of the embodiments and The thickness is as follows: Silicon layer U 3: b-amorphous amorphous silicon layer (4 30 nm) end mark layer 1 1 2: silicon oxide layer (1 to 2 nm) non-amorphous amorphous silicon layer 1 2 1: Undoped amorphous lithium layer 121 (30nm) Silicon layer 111: 4 doped amorphous lithium layer (49 nm) Undoped amorphous crystalline silicon layer 120: Undoped Amorphous silicon layer 121 (30ηπ〇 end mark layer 1 1 〇:
第11頁 五、發明說明(9) 氣化石夕層(1〜2nm) 矽層1 0 9 : 捧雜之非晶糸石夕層(15〇nm) 偵測發光強度之方法如下所述。方法(1 ) ~ ( 3 )其中之 一都可用來偵測終點記號層i ^ 〇和1 1 2。 (1 )偵測氧之發光強度。當強度增強時便可.視為蝕刻 終點。債測之光波長為437、497、502、533、544、6 0 5 616、646、70 0、725,和 mnm。 (2 )偵測二氧化矽之發光強度。當強度增強時便可視 為蝕刻終點。偵測之光波長為241、234和249_。 p之3ΐ未ί雜層和摻雜層中p濃度之差異。®此偵》 ^ ^又。§強度增強時便可視為蝕刻终里έ。偵測t 先波長為214和253nm。 、一占價利之 以下敘述使用質譜儀夕八#古、土 . 之—都可用來炊Μ I儀刀析方法。方法(1)〜(4)其中 丨』用求、冬點記號層層! j 〇和丨j 2。 (1 )以質量愈令丨’ 1 β丨丨七,卜 視為蝕刻終點。 "、測氧原子,當強度增強時便可 時便可:見為。J’點6°:來偵測二氧化矽原子’當強度增 點。 ’'子虽強度增強時便可視為蝕刻終 (4)利用未摻雜爲$ 以質量數"59"來袖^c s和推雜層中SiP濃度之差里。因 果偵測SiP原子。杏 又心產,、因丑Page 11 V. Description of the invention (9) Gasification stone layer (1 ~ 2nm) Silicon layer 1 0 9: Amorphous vermiculite layer (150nm) is used to detect the luminous intensity as follows. One of the methods (1) to (3) can be used to detect the end mark layers i ^ 0 and 1 12. (1) Detect the luminous intensity of oxygen. When the intensity increases, it can be regarded as the end point of etching. The wavelengths of the light measured by the debt are 437, 497, 502, 533, 544, 60 5 616, 646, 70 0, 725, and mnm. (2) Detecting the luminous intensity of silicon dioxide. When the intensity increases, it can be regarded as the end point of etching. The detected light wavelengths are 241, 234, and 249_. The difference between the p concentration in the 3rd p-doped layer and the doped layer. ® This detective ^ ^ again. § When the strength is increased, it can be regarded as the end of etching. The detection wavelength is 214 and 253nm. 1. The best price and advantage The following description uses the mass spectrometer Xiba # ancient, soil. The — all can be used to cook the M I instrument analysis method. Methods (1) ~ (4) Among them, 丨 』use layers of winter and winter marks! j 〇 and 丨 j 2. (1) The more the quality becomes, the more the 1 ', the more the β is, and the later is regarded as the end point of the etching. " 、 Measure the oxygen atom, when the intensity is enhanced, it is only necessary: see it. J 'point 6 °: to detect the silicon dioxide atom' as the intensity increases. Although the strength is enhanced, it can be regarded as the end of the etching. (4) The difference between the SiP concentration in the dopant layer and the dopant layer is calculated by using the undoped amount of "59" as the mass number. Causal detection of SiP atoms. Xing was born again,
田強度增強時便可視為蝕 五、發明說明(IQ) 刻終點。 〈貫施例2 > 各層之材料和厚度如下所述: 矽層11 3 : 摻雜之非晶系矽層(430nm) 終點記號層層丨丨2 : 氧化石夕層(1〜2nm) 未摻雜之非晶系矽層1 2 1 : 未摻雜之非晶系矽層1 2 1 ( 3 0 nm ) 矽層111 : 摻雜之非晶系矽層㈠9 〇nm) 未摻雜之非晶系矽層1 2 0 : 未摻雜之非晶系矽層121 (30nm) 終點記號層層1 1 〇 : 氧化矽層(l~2nm) 碎層1 0 9 : 摻雜之非晶系石夕層(1 5 〇 n m ) 偵測發光強度之方法如下所述。方法(1 )〜(3 )其中之 一都可用來終點記號層丨丨〇和丨丨2。 (1 )偵測氧之發光強度。當強度增強時便可視為蝕刻 終點。偵測之光波長為4 3 7、4 9 7、5 0 2、5 3 3、5 4 4、6 0 5、 616、646、700、725,*777nm。 (2 )偵測二氧化矽之發光強度。當強度增強時便可視 為餘刻終點。偵測之光波長為241、234和249nm。Field strength can be regarded as eclipse. 5. End of Invention (IQ) engraving. <Example 2> The material and thickness of each layer are as follows: Silicon layer 11 3: Doped amorphous silicon layer (430 nm) End mark layer 丨 2: Oxide oxide layer (1 to 2 nm) Doped amorphous silicon layer 1 2 1: undoped amorphous silicon layer 1 2 1 (30 nm) silicon layer 111: doped amorphous silicon layer (90 nm) undoped non Crystalline silicon layer 1 2 0: Undoped amorphous silicon layer 121 (30nm) End mark layer 1 1 〇: Silicon oxide layer (1-2nm) Fragment layer 1 0 9: Doped amorphous system stone The method for detecting the luminous intensity by the evening layer (150 nm) is as follows. One of the methods (1) to (3) can be used for the end mark layer 丨 丨 〇 and 丨 丨 2. (1) Detect the luminous intensity of oxygen. When the intensity increases, it can be regarded as the end point of etching. The detected light wavelength is 4 3 7, 4, 9 7, 5 0 2, 5 3 3, 5 4 4, 6 0 5, 616, 646, 700, 725, * 777nm. (2) Detecting the luminous intensity of silicon dioxide. When the intensity increases, it can be regarded as the end point of rest. The detected light wavelengths are 241, 234, and 249 nm.
第13頁 五、發明說明(11) (3 )利用未摻雜層和摻雜層中P濃度之差異。因此藉偵 測P之發光強度來探測阻絕層1 1 2,當強度增強時便可視為 蝕刻終點。因此藉偵測P之發光強度來探測阻絕層1 1 0,當 強度增強時便可視為蝕刻終點。偵測之光波長為2 1 4,和 2 5 3 nm ° 以下敘述使用質譜儀之分析方法。 (1 )以質量數"1 6"來偵測氧原子,當強度增強時便可 視為蝕刻終點。 (2 )以質量數’’ 6 0 "來偵測二氧化矽原子,當強度增強 時便可視為蝕刻終點。 (3)利用未摻雜層和摻雜層中P濃度之差異。因此以質 量數” 3 1''偵測P原子來探測阻絕層1 1 2。當強度增強時便可 視為钱刻終點。 (4 )利用未摻雜層和摻雜層中S i P濃度之差異。因此以 質量數"59"偵測SiP原子來探測阻絕層1 1 0。當強度增強時 便可視為蝕刻終點。 〈實施例3 > 各層之材料和厚度如下所述: 矽層11 3 : 換雜之非晶糸砍層(430nm) 終點記號層11 2 : 氧化石夕層(1〜2nm) 未摻雜之非晶系矽層1 2 1 : 未摻雜之非晶系矽層121 (30nm)Page 13 V. Description of the invention (11) (3) The difference between the P concentration in the undoped layer and the doped layer is used. Therefore, by detecting the luminous intensity of P to detect the barrier layer 1 12, when the intensity is enhanced, it can be regarded as the end point of the etching. Therefore, by detecting the luminous intensity of P to detect the barrier layer 110, when the intensity is enhanced, it can be regarded as the end point of the etching. The detected light wavelengths are 2 1 4 and 2 5 3 nm. The analysis method using a mass spectrometer is described below. (1) Detecting the oxygen atom by the mass number "1 6", when the intensity is enhanced, it can be regarded as the end point of the etching. (2) Detecting the silicon dioxide atom with the mass number '' 60 ", when the strength is enhanced, it can be regarded as the end point of the etching. (3) The difference between the P concentration in the undoped layer and the doped layer is used. Therefore, the mass layer "3 1" is used to detect the P atom to detect the barrier layer 1 1 2. When the strength is increased, it can be regarded as the end point of the money engraving. (4) The concentration of Si P in the undoped layer and the doped layer is used. The difference. Therefore, the mass layer " 59 " detects SiP atoms to detect the barrier layer 1 1 0. When the strength is enhanced, it can be regarded as the end point of the etching. <Example 3> The materials and thickness of each layer are as follows: Silicon layer 11 3: Doped amorphous amorphous silicon layer (430nm) End mark layer 11 2: Oxide oxide layer (1 ~ 2nm) undoped amorphous silicon layer 1 2 1: undoped amorphous silicon layer 121 (30nm)
第14頁Page 14
石夕層11 1 : 換雜之非晶糸石夕層(4 9 0 n m) 未摻雜之非晶系矽層1 2 Ο : 未摻雜之非晶系矽層121 (30nm) 終點記號層層11 〇 : 氧化石夕層(l~2nm) 矽層1 0 9 : 摻雜之非晶系石夕層(1 5 〇 n m) 偵測發光強度之方法如下所述。 ^ (1 )偵測S 1 Ν之發光強度。當強度增強時便可視為蝕刻 、、、2。偵測之光波長為 4 41、4 〇 5、4 0 9、41 3、4 2 0,和 424nm 。 C2)關於終點記號層112之探測,以偵測⑶之發光 ^來進行,當強度增強時便可視為蝕刻終點。 長為 387、418、647、7〇9、和78一。 偵=2 裎中之光阻提供的。 N T之^疋在製 以下敛述使用質譜儀之分析方法。 ::;s氮广當強度增強時便可視為蝕刻終點。 ⑶利用j子,當強度增強時便可視為钱刻終點。 U )利用未摻雜層和摻雜層中s i P濃度之羔显 m 列::S1P原子來探測阻絕層110,當強度增強時便二、g此以 刻終點。 * ¥便可硯為餘 、、則P it) t1用未摻雜層和摻雜層中P濃度之差里m W原子來探測I絕層112,當強度增強時:此以偵 ____一視為蝕刻終Shi Xi layer 11 1: Non-doped amorphous vermiculite layer (490 nm) Undoped amorphous silicon layer 1 2 0: Undoped amorphous silicon layer 121 (30 nm) End mark layer Layer 11 〇: Oxide oxide layer (1-2nm) Silicon layer 109: Doped amorphous stone layer (150nm) The method for detecting luminous intensity is as follows. ^ (1) Detect the luminous intensity of S 1 Ν. When the strength is increased, it can be regarded as etching. The detected light wavelengths are 4 41, 4 05, 4 0 9, 41 3, 4 2 0, and 424 nm. C2) The detection of the end mark layer 112 is performed by detecting the light emission ^ of the CD. When the intensity is enhanced, it can be regarded as the end of the etching. Lengths are 387, 418, 647, 709, and 78. Detect = 2 Photoresistance provided by 裎. The following describes the analytical method using a mass spectrometer. ::; s Nitrogen can be regarded as the end of the etch when the strength is increased. (3) Using j, when the intensity is increased, it can be regarded as the end point of money. U) The m column :: S1P atom in the undoped layer and the doped layer is used to detect the barrier layer 110, and when the strength is increased, the end point is g. * ¥ can be used as the remainder, then P it) t1 uses the m W atoms in the difference between the P concentration in the undoped layer and the doped layer to detect the I insulation layer 112. When the strength is increased: this is used to detect ____ Etched
第15頁 五、發明說明(13) 點。 〈貫施例4 > 各層之材料和厚度如下所述: 矽層1 1 3 : 電漿-CVD之摻雜之非晶系矽層(43〇nm) 終點記號層11 2 : 自然氧化石夕層(native oxide film)(l〜2nm) 未摻雜之非晶系石夕層1 21 : 未摻雜之非晶系矽層(3〇nm) 矽層1 1 1 :P.15 5. Description of the invention (13) point. <Example 4> The material and thickness of each layer are as follows: Silicon layer 1 1 3: Plasma-CVD doped amorphous silicon layer (43 nm) End mark layer 11 2: Natural oxide stone Layer (native oxide film) (l ~ 2nm) undoped amorphous silicon layer 1 21: undoped amorphous silicon layer (30nm) silicon layer 1 1 1:
換雜之非晶系矽層(4 9 0 nm) 未摻雜之非晶系矽層丨2 〇 : 未接雜之非晶系矽層121 (30nm) 終點記號層1 1 〇 : 氧化矽層(1〜2_) 矽層1 0 9 : 払雜之非晶系矽層(丨5 〇 ) $測發光強度之方法如下所述。 故叫(1 I偵測氧之發光強度。當強度增強時便可視為蝕刻 、、、;點。偵測夕土、丄 只』之先波長為437、497、502、533、544、605、 616 、646 、70〇 (2) 偵 和 777nm。 ^ ^ 、測二氧化矽之發光強度。當強度增強時便可視 為蝕刻終點。找、, g ^ (3) 利 價測之光波長為241、234和249rim ° 1用未摻雜層和摻雜層中P濃度之差異。因此藉福Doped amorphous silicon layer (490 nm) Undoped amorphous silicon layer 丨 2 〇: Undoped amorphous silicon layer 121 (30nm) End mark layer 1 1 〇: Silicon oxide layer (1 ~ 2_) Silicon layer 1 0 9: Doped amorphous silicon layer (丨 5 〇) The method for measuring the luminous intensity is as follows. Therefore, it is called (1 I to detect the luminous intensity of oxygen. When the intensity is increased, it can be regarded as an etch, ..., dot. The first wavelength of the detection of evening soil, crickets is 437, 497, 502, 533, 544, 605, 616, 646, 70 (2) detection and 777nm. ^ ^, Measure the luminous intensity of silicon dioxide. When the intensity is increased, it can be regarded as the end point of the etching. Find,, g ^ (3) The light wavelength measured by the price is 241 , 234, and 249rim ° 1 use the difference in P concentration between the undoped layer and the doped layer.
第16頁 1Page 16 1
測P之發光強度來探 蝕刻終點。藉偵測p之='、、巴層112,當強度增強時便可視為 增強時便可視為姓刻二光強探測阻絕層110 ’當強度 以下敘述使用皙二:债測之光波長為214和25 3nm。 ⑴以質量ΑΛ:分析方法。 視為蝕刻終點。 來偵測氧原子,當強度增強時便可 (2 )以質量齡,,β n" + 睥#可谰么為數 來偵測二氧化秒原子’當強度增強 日守便T視為钱刻終點。 旦勃:H用f摻雜層和摻雜層中p濃度之差異。因此以質Measure the luminous intensity of P to probe the end point of etching. By detecting p = ', and the layer 112, when the intensity is enhanced, it can be regarded as an enhancement. It can be regarded as the last name of the light intensity detection blocking layer 110'. When the intensity is described below, the light wavelength of the test is 214. And 25 3nm. ⑴ Mass Λ: Analysis method. Considered as the end of etching. To detect the oxygen atom, when the intensity is increased, (2) the mass age, β n " + 谰 # can be counted as the number to detect the second atomic atom. 'When the intensity is enhanced, the day will be regarded as the end of the money. . Denbo: The difference between the p concentration in the f-doped layer and the doped layer for H. Therefore with quality
=么為;tr丨故肩P原子來探測阻絕層1 1 2。當強度增強時便可 視為银刻終點。 折旦(4 利用未摻雜層和摻雜層中S ip濃度之差異。因此以 貝里數5 9偵測s i p原子來探測阻絕層丨丨〇。當強度增強時 便可視為蝕刻終點。 a在貫施例4中’因未摻雜之非晶系矽層是以電漿乂” 來成長,所以可以採用比Lp_CVD較低之成長溫度,形成作 犧牲石夕層用之石夕層113時,熱履歷““】。hysteresis) 會減少,並且儲存電極丨丨6之結晶化不易發生。 實施例1〜4之蝕刻條件如下所示。 蝕刻儀器 平行平板型反應性離子蝕刻儀器(parallel plate reactive ion etching apparatus) 壓力:100 mTorr 電極間距離(inter-electrode gap) :80 mm= Mody; tr 丨 Therefore, shoulder P atoms to detect the barrier layer 1 1 2. When the intensity increases, it can be regarded as the end point of silver engraving. Zindan (4 uses the difference between the S ip concentration in the undoped layer and the doped layer. Therefore, the barrier layer is detected by detecting the Sip atom with a Bailey number of 5 9. When the strength is increased, it can be regarded as the end of the etching. A In Example 4, "because the undoped amorphous silicon layer is grown by plasma", it is possible to use a lower growth temperature than Lp_CVD to form the stone layer 113 for the sacrificial stone layer. The thermal history "". Hysteresis) will be reduced, and crystallization of the storage electrode 丨 6 will not occur easily. The etching conditions of Examples 1 to 4 are as follows. Etching equipment Parallel plate reactive ion etching equipment (parallel plate reactive ion etching apparatus) pressure: 100 mTorr inter-electrode gap: 80 mm
第17頁 五、發明說明(15) C 12 : 1 5 0 seem HBr -450 seem 〇2 : 5 seem 頂端電力(top-side power) :5〇0 ψ 底部電力(b〇tt〇m-side p〇wer) :3〇〇 wPage 17 V. Description of the invention (15) C 12: 1 5 0 seem HBr -450 seem 〇 2: 5 seem top-side power: 5〇0 ψ bottom power (b〇tt〇m-side p 〇wer): 3〇〇 w
如上所述,根據本發明,因 G 號層是位於儲存電極内,仏 ^ 才 〜點5己 ^ π 所以準確地控制蝕刻深唐。 在加工儲存電極( · ,,,,^ pr〇Cessing the storage e e c r o e)日守,因為終點記^ ^ ^ ^ ^ 並”要額外的移除步驟。 夕層纟起移除,所以 藉由在矽層的二部分内形成 避免結晶化被二芦石々厣勺十―斗办雜之非日曰糸矽層,可 不良之HSG。 丁 y層防止產生形妝As described above, according to the present invention, since the G-number layer is located in the storage electrode, 仏 ^ ~ 5 points ^ π, so the etching is accurately controlled. When processing the storage electrode (· ,,,, ^ pr0Cessing the storage eecroe), the end point is recorded ^ ^ ^ ^ ^ and "extra removal steps are required. The layer is removed from the surface, so by using silicon The two parts of the layer are formed to avoid crystallization. The silicon layer that is mixed with the non-Japanese iron can be harmful to the HSG. The D layer prevents the formation of makeup.
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US6440869B1 (en) * | 2000-06-26 | 2002-08-27 | Vanguard International Semiconductor Corporation | Method of forming the capacitor with HSG in DRAM |
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US7713813B2 (en) * | 2005-08-31 | 2010-05-11 | Micron Technology, Inc. | Methods of forming capacitors |
JP5524453B2 (en) * | 2008-05-15 | 2014-06-18 | Sumco Techxiv株式会社 | Silicon wafer etching method and etching apparatus |
JP2011066164A (en) * | 2009-09-16 | 2011-03-31 | Tokyo Electron Ltd | Mask pattern forming method, and semiconductor device manufacturing method |
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