經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（/ ) 〔發明之背景〕 鼓風口係通常用Μ噴注諸如有機複合物之不同供給原 料，使進入一熔融浴或熔融塩浴。鼓風口典型地係嵌入該 襯裡於該反應器内部的耐火牆内。在一實施例中，一鼓風 口係為經由該耐火牆而延伸至該耐火牆之内表面且與該表 面同在一平面。該鼓風口的開口係經常位在該熔融浴的表 面之下，不是在該反應器牆的底部就是在其側邊。當該供 料被導入該熔融浴，一部份之該供料可被轉折回至該牆。 因此，該被導入該熔融浴之供料受制於一極大量的靜壓力 並形成一供料累積及在該鼓風口開口處之部份分解的供料 〇 由於在該反應器内所遭遇到的高溫，膨脹經常有區別 地發生在該耐火材料和該鼓風口，因而在該鼓風口和該耐 火材料之間導致一空間的形成。而且，典型地該鼓風口並 不達到該耐火材料的溫度，因為該供料未被預熱至該浴的 溫度。因此，供料可自該鼓風口和該耐火襯套之間的反應 器滲至該反器應之外。 預防來自該熔融浴供料之滲出的嗜試包含使用建構成 尺寸公差非常有限的耐火磚。然而，這是非常困難且耗費 時間的。另一選擇是使用一做為噴注供料進入該熔融浴之 埋入式的噴槍。但是，許多噴槍並非很耐用且很快地即被 該熔融浴消耗殆盡。 因此，亟需一用以消除或減小如上所述之問題的設備 -3- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) Λ. 訂 32S246 A7 B7 五、發明説明（>) (請先閱讀背面之注意事項；填寫本頁) 〔本發明之概述〕 本發明係關於一用Μ自動密封一熔融金靨反應器之埋 入式供料入口的設備。 該設備包含一在該埋入式入口且經由一該反應器之耐 火襯套而延伸的鼓風口。一板突出自該鼓風口且嵌入該耐 火襯套，因而供料被導經該鼓風口及滲入該鼓風口及該耐 火襯套之間，並被該板轉向離開自該鼓風口而進入該耐火 襯套以密封該埋人式入口。 在另一實施例中，該設備包含在該埋入式入口且經由 該耐火襯套而延伸的鼓風口。一組裝襯套圍繞該鼓風口及 一部份之鼓耐火襯套且嵌入該耐火襯套，因而供料被等經 該鼓風口及滲入該耐火襯套，並被該組裝襯套轉向而到達 該熔融浴Μ密封該埋入式入口。 經濟部中央標準局員工消費合作社印装 在更一實施例中，該設備包含一在該埋入式入口且經 由該耐火襯套而延伸的鼓風口。一板自該鼓風口而横著突 出且嵌入該耐火襯套，因而供料被導經該鼓風口並滲入該 耐火襯套，且被該板轉向到達該熔融浴以至少部份地密封 該埋入式入口。一組裝襯套圍繞在該鼓風口、該板和該耐 火襯套之部份且嵌入該耐火襯套，因而供料被導經該鼓風 口並滲入該耐火襯套，且更被該組裝襯套轉向到達該熔融 浴Μ密封該埋入式入口。 -4- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐〉 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明（彡） 本發明提供了許多優點。一個優點即是該板择# Μ阻止該供料自該反應器滲出的方法。另一優點即 入空間的供料是被導自該鼓風口而進入具有一溫度高Ml K導致至少該供料之部份分解的耐火襯套。一額外的優15 即是該板相當容易製造且容易被放入該耐火牆内。另一優 點即是累積在該耐火襯套内的液體和氣體會被阻止並被導 回該熔融浴。 〔附圖之簡略說明〕 第一圖：係本發明設備之一實施例在一反應器之熔融 浴内的側剖視圖； 第一A圖：係在第一圖中鼓風口之埋入部份和板的側 剖視圖； 第二匾：係在第一和一A圖中該鼓風口和板之第二實 施例的側剖視圖； 第二圖：係在第一和一A圖中該鼓風口和板之第三實 施例的側剖視圖；Μ及 第四圖：係包含一鼓風口和鼓風口組装襯套之設備的 一個第四實施例之側剖視圖。 〔本發明之詳细敘述〕 本發明特徵和設備之其它细節將參照所附圖示而更特 別地敘述且在申請專利範圍指出。在不同圖示相同標註之 -5- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） (請先閱讀背面之注意事項！填寫本頁)A7 B7 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (/) [Background of the invention] The tuyere is usually sprayed with M to supply different raw materials, such as organic compounds, into a molten bath or molten bath . The tuyeres are typically embedded in the refractory wall lined inside the reactor. In one embodiment, a tuyere extends through the refractory wall to the inner surface of the refractory wall and is in the same plane as the surface. The opening of the tuyere is often located below the surface of the molten bath, either at the bottom of the reactor wall or on its side. When the feed is introduced into the molten bath, a portion of the feed can be turned back to the wall. Therefore, the feed introduced into the molten bath is subjected to an extremely large amount of static pressure and forms a feed that accumulates and partially decomposes at the opening of the tuyere. Due to the encounter in the reactor At high temperatures, expansion often occurs differently between the refractory material and the tuyere, thus resulting in the formation of a space between the tuyere and the refractory material. Moreover, typically the tuyeres do not reach the temperature of the refractory material because the feed is not preheated to the temperature of the bath. Therefore, the feed can penetrate from the reactor between the tuyere and the refractory liner to the outside of the reactor. The habit of preventing exudation from the molten bath feed involves the use of refractory bricks with very limited dimensional tolerances. However, this is very difficult and time-consuming. Another option is to use an embedded spray gun as the injection feed into the molten bath. However, many spray guns are not very durable and are quickly consumed by the molten bath. Therefore, there is an urgent need for a device to eliminate or reduce the above-mentioned problems -3- This paper standard is applicable to the Chinese National Standard (CNS) Α4 specification (210 X 297 mm) (please read the precautions on the back before filling in This page) Λ. Order 32S246 A7 B7 5. Description of the invention (>) (Please read the precautions on the back; fill in this page) [Overview of the invention] The present invention is about the automatic sealing of a molten gold with M The device of the embedded feed inlet. The apparatus includes a tuyere extending through the buried inlet and through a refractory liner of the reactor. A plate protrudes from the tuyere and is embedded in the refractory bushing, so the feed is guided through the tuyere and penetrates between the tuyere and the refractory bushing, and is diverted away from the tuyere by the plate to enter the refractory Liner to seal the buried entrance. In another embodiment, the apparatus includes a tuyere at the buried inlet and extending through the refractory bushing. An assembly bushing surrounds the tuyere and a part of the drum refractory bushing and is embedded in the refractory bushing, so the supply is waiting to pass through the tuyere and penetrate into the refractory bushing, and is turned by the assembly bushing to reach the The molten bath M seals the buried inlet. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs In a further embodiment, the device includes a tuyere at the buried entrance and extending through the refractory bushing. A plate protrudes laterally from the tuyere and is embedded in the refractory bushing, so the feed is guided through the tuyere and penetrates into the refractory bushing, and is diverted by the plate to the molten bath to at least partially seal the Entrance. An assembly bushing surrounds the tuyere, the plate and the refractory bushing and is embedded in the refractory bushing, so the feed is guided through the tuyere and penetrates into the refractory bushing, and is further assembled by the assembly bushing Turning to the molten bath M seals the buried inlet. -4- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) Α7 Β7 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (彡) The present invention provides many advantages. One advantage is that The plate selection # Μ prevents the feed from seeping out of the reactor. Another advantage is that the feed into the space is directed from the tuyere and enters with a high temperature Ml K causes at least part of the feed decomposition Refractory bushing. An additional excellent 15 is that the board is relatively easy to manufacture and easy to put into the refractory wall. Another advantage is that the liquid and gas accumulated in the refractory bushing will be blocked and led back The molten bath. [Brief description of the drawings] The first figure: is a side cross-sectional view of a molten bath of a reactor according to an embodiment of the equipment of the present invention; the first figure A: is buried in the tuyere in the first figure Side cross-sectional view of the inlet portion and the plate; Second plaque: side cross-sectional view of the second embodiment of the tuyere and plate in Figures 1 and 1A; Second figure: This is the first and 1A figures Side cross-sectional view of the third embodiment of the tuyere and plate Μ and the fourth figure: It is a side cross-sectional view of a fourth embodiment of a device including a tuyere and tuyere assembling bushing. [Detailed description of the invention] The features of the invention and other details of the device will refer to The drawings are more specifically described and pointed out in the scope of the patent application. The same label in different drawings -5- This paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) (please read the notes on the back first ！ Fill in this page)
經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（ip ) 標號代表相同的項目。但所應知道者，本發明之特殊實施 例均係W圖解示出而非本發明之極限。本發明之特徵可被 運用在不同的實施例中卻不脫離本發明範圍。除非有特別 指定’所有部份和百分比均依比重示出。 本發明係大致關於具有一耐火襯套用κ在一熔融金屬 S應器中密封一埋入式入口的設備。在一熔融浴中分解廢 棄物I之方法和設備在發給Bach et al的美國專利第4,574, ?14號和第4,602 ,574號中均有所揭示。該等專利文所記述 之方&和設備可摧毀或選擇地與非有機剩餘物共同摧毀多 氛聯笨和其它有機廢棄物。其它用以在一熔融浴分解廢棄 物及用Μ自該廢棄物形成氣體、玻璃狀和熔融金屬產物流 動的設備和方法則揭示於發給N a g e 1 e t a 1的美國專利第5 , 3 0 1 , 6 2 0 號中。 發明之一實施例係描述於第一圖中。其中，系統1 0包 含用K容納一適合於分解一供料之熔融浴的反應器12。適 合之反應器的例子包含Μ習知技術而適當修改之鋼造的容 器，諸如Κ-Β0Ρ，Q-B0P，氩氧除碳熔礦燫（A0D) ，B0F等 。而且，另一涸適合之反應器係揭示於美國第5,301,620號 專利文中。反應器12包含較上部份14和較下部份16。逸氣 出口 18自較上部份14延伸且適合於導引一逸氣複合物出到 反應器12。反應器12具備金靨薄殼17且Κ耐火襯套19為襯 裡。耐火襯套19可為由氧化鋁（Al7 〇3 )、二氧化矽（ S i 0 2 )、二氧化钍（T h 0 2 )、氧化鎂（M g 0)、二氧化锆 -6 ~ 本紙張尺度適用中國國家標準（CNS > A4規格（2丨〇><297公釐〉 (請先閱讀背面之注意事項-ff填寫本頁) 訂· A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ( ) 1 1 ( Zr 0 z ) 或其它諸如陶瓷之適當材料所構成的磚 3該耐火 1 I 襯 套 可以 一 不 能 滲 透 氣體 的 被 覆 物所 覆 蓋 例 如 濺 射 的 氧 1 1 I 化 鋁 〇同 心 開 Ρ 而 到 達入 口 24 〇 覆蓋 氣 體 可 Κ 為 諸 如 氬 或 請 1 1 氖 或丙 烷 之 碳 氫 化 合物 等 鈍 氣 0 閱 讀 背 1 1 底部 攻 螺 絲 嘴 管 44延 伸 白 反 應器 12的 較 低 部 份 16且 係 面 之 1 注 1 適 合 於該 反 應 器 12移 除熔 融 金 鼷 。感 應 線 圈 4 6係 位 於 較 低 意 事 1 項一 部 份 16用 Μ 在 反 應 器 12中 加 埶 熔 融浴 0 為 吾 人 所 知 者 反 4 應 器 12或 可 其 它 諸 如氧 JJMl 燃 料 m Aim 燒器 電 弧 等 適 當 之 方 法 寫 本 頁 水 1 加 埶 /<!>< 0 1 I 熔融 浴 4 8係 形 成 於反 應 器 1 2 之内 〇 熔 融 浴 4 8可 包 含 至 1 1 I 少 一 金屬 或 熔 融 塩 類 。適 當 之 金 靥的 例 子 包 含 Afb 鐵 銅 鎳 1 ·、 鋅 等0 適 當 之 塩 類 包含 氯 化 納 、氛 化 鉀 等 0 熔 融 浴 48也 訂 1 可 包 含一 種 金 屬 Κ 上 。例 如 熔 融浴 4 8可 包 含 諸 如 鐵 和 銖 1 I 之 易 混合 物 金 靨 的 溶 液0 在 —» 實 施例 中 熔 融 浴 4 8可 大 致 1 1 I 以 基 本金 屬 構 成 〇 或 者， 熔 融 浴 48可 大 致 Μ 金 靥 塩 類 構 成 Ί 0 熔 融浴 4 8係 Μ 一 適 當之 金 屬 或 塩而 由 至 少 部 份 充 填 之 反 f 應 器 12構 成 0 在 另 一 霣施 例 中 熔融 浴 4 8係 Κ 不 易 混 合 之 1 I 金 屬 構成 〇 這 些 不 易 混合 的 金 屬 可包 含 諸 如 鐵 的 第 金 靨 1 1 I 50和 諸如 銅 的 第 二 金 屬。 熔 融 浴 4 8係 可 Μ 諸 如 一 未 1>C*I 画 示 之 1 1 感 應 線圈 或 氧 m 料 m 燒器 的 適 合 方法 進 行 加 熱 〇 1 系統 10的 適 當 操 作情 況 包 含 諸如 . 溫 度 足 至 少 部 份 1 I 地 以 分解 方 式 轉 換 含 碳供 料 成 為 基本 碳 或 其 它 基 本 組 成 〇 1 1 1 大 致 上， 適 當 之 溫 度 係在 1300 -7- 至 1700 攝 氏 度 的 範 圍 之 間 0 1 1 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公嫠） A7 B7 325248 五、發明説明（L) 玻璃層54係形成於熔融浴48之上。玻璃層54大致上不 易與熔融浴4 8混合。玻璃層54可較之熔融浴48有較低之熱 導係數。自熔融浴48漏失之輻射熱可因而被大大地降至汞 沒有。 鼓風口 2 G係位於反應器1 2的較下部份1 6且可為一多重 同心鼓風口，尤其是三重同心鼓風口。而一個同心鼓風口 21包含用做在供料入口 24噴注一供料的供料管22。襯裡26 延伸於供料管22和供料源28之間用K導引供料自供料源28 經泉30至供料管22。鼓風口 20之氧化劑管32係在鼓風口入 口 2 4同心地置放在供料管2 2周邊。襯裡3 5延伸於氧化劑源 36和氧化劑管34之間用K導引一適當氧化劑至氧化劑管34 。氧化劑可為氧或空氣Μ能夠氧化一部份之剩餘物使形成 諸如一氧化碳或二氧化碳的分解產物。鼓風口 2{)之覆蓋氣 體管38係在入口 24Κ同心方式置放在氧化劑管32周邊。襯 裡4 0延伸於覆蓋空氣管38和覆蓋空氣源4 2之間用W導引一 適當之覆蓋空氣經由在氧化劑管32和覆蓋氣體管38之間的 玻璃層54而自熔融浴48漏失的輻射熱。 典型地，玻璃層54包含至少一涸金靥氧化物。玻璃層 54可容納一適當複合物用Μ淨化諸如氯或氟等鹵素Μ防止 形成諸如氯化氫之鹵化氫氣體。在一實施例中’玻璃層54 在該糸統10之操作狀況包含一具有一氧化自由能量的金屬 氧化物，該能量係小於自該原子碳至一氧化碳的氧化’例 如氧化鈣（C a 0)。 -8- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公嫠） (請先閱讀背面之注意事項-S填寫本頁) 訂· 經濟部中央標率局員工消費合作社印製 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ( ) 1 1 如第 一 A 圖 所 示 9 一 白 動 密封之埋 入式入 D 包 含鼓 風 1 1 I □ 20和板 54 其 位 於 在 耐 火 襯 套19内之 覆蓋氣 體 管 38周 邊 1 1 I 〇 板 54具 有 一 一 大 致 與 鼓 風 Ρ 2 0之外半 徑相同 之 内 半徑 0 請 1 1 閱 I 板 54的一 個 外 邊 緣 延 伸 至 在 耐 火襯套19内之區 域 56内部 〇 讀 背 1 1 區 域 5 6係 處 在 情 況 足 Μ 分 解 出 現於其內 之該供 料 之 一 S 質 Λ 之 注 1 I 的 部 份。 意 事 1 項一 空間 58在 耐 火 襯 套 1 9和 鼓 風口 20之 間自該 耐 火 襯套 19 4 寫 之 内 表面 而 延 伸 至 板 54 〇 空 間 58在該反 應器之 操 作 溫度 下 本 頁 1 可 在 該耐 火 材 料 19和 鼓 風 □ 2 0之該熱膨 脹内形 成 一 差別 的 1 1 結 果 〇 1 I 板54 i 該 鼓 風 0 20之 該 外 圓周而延 伸入該 耐 火 襯套 19 1 1 訂 1 0 在 一買 施 例 中 環 狀 板 具 有 一半徑約 8公分和厚度約0 .1 公 分 。板 54 附 火 襯 套 19的 表 面21起大 約10公 分 〇 在另 一 1 | 實 施 例中 板 5 4係 呈 波 浪 狀 0 在反應器 12的操 作 狀 況下 9 1 I 在 該 板的 外 邊 緣 的 溫 度 係 大 約 在80 0至1 1 0 〇攝氐溫度的範圍 Ί 內 0 在被 熔 融 浴 加 熱 之 外 板 54可被Κ 其它諸 如 經 過該 板 Γ 所 傳 導之 電 流 的 阻 抗 加 熱 0 環 狀板係被 考慮成 很 薄 ，K 致 1 I ( ( Kr/Lr) / (Kf/Lf) ) / (L f / 5 f)的比 值 大 約比 1大 1 I 0 Kr 和Kf分 別 表 示 該 耐 火 襯 套 和環狀板 的熱傳 導 係 數。 Lr 1 I 表 示 自耐 火 表 面 2 1 至 板 5 4的 距 離。Lf表 示自覆 蓋 氣 «an trtfr： 趙営 38 1 至 板 54之 外 邊 緣 5 5的 距 離 0 δ f表示板54的厚度c 1 I 板5 4係 >λ 能 夠 抵 抗 在 反 應 器12之該 操作溫 度 下 該熔 融 1 I 浴 46和供 料 的 溫 度 和 情 況 〇 在 一簧施例 中，板 5 4係 以選 白 1 1 I - 9- 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印裝 Α7 Β7 五、發明説明（8) 由不锈鋼、鈦、鎢、钽和锆所構成之組裡的一個金屬所製 成。並且，一陶瓷也可被使用。板54係K在板54和防止該 供料自其通過的鼓風口 20之間形成密封53的方式而附著於 鼓風口 20。例如，板54可被焊至鼓風口 20。熱電偶62可被 置於板54上的點Μ監測環狀板54的溫度。 鼓風口 24和板54可Μ成為鼓風口組裝69。鼓風口組裝 6 9可被Μ鼓風口組裝襯套7 fl或圍繞鼓風口組裝6 9的”罐” 形成一耐火磚。鼓風口組裝襯套7 0可被以一金臛、陶瓷或 電漿被覆物構成。一適合的材料包含熔點高於該熔融浴之 操作的情況且能抵抗化學反應。這種材料包含鎢、氧化锆 和濺射的锆。在一實施例中，鼓風口組裝襯套7 〇係Μ 一金 靨或電漿被覆物形成Μ防止氣體經該鼓風口組裝69的側邊 而外出。該電漿被覆物係習知以電漿噴耪法所運用的材料 0 諸如氣態、液態或固態之供料係自供料源28經襯裡26 至反應器2Q内之供料管22而被導入熔融浴48。供料在入口 2 4進到熔融浴48。氧或另一氧化劑係自氧化劑源3 5經襯裡 34而被導至氧化劑管38。一諸如碳化氫或純氣之適當覆蓋 氣體係自覆蓋氣體源4 2經襯裡40而被導到覆蓋氣體管38。 當供料被導入熔融浴48時，一部份之該供料被形成於 鼓風口開口 24的累積及向著耐火襯套19和鄰接至耐火襯套 13之空間58之熔融浴48的靜壓所轉向。該供料沿該鼓風口 20的外側以朝著反應器12之外部的方向64而行動。板54使 -10- 本紙張尺度適用中國國家標準^奶^私見格^⑽29·^*) (請先閱讀背面之注意事項月填寫本頁) 訂-· A7 B7 經濟部中央標準局員工消費合作杜印製 五、發明説明 ( 1 ) 1 1 至 少 一 部 份 白 熔 融 浴 48逸 出 之 供 料 Μ 延 伸 鼓 風 口 20之 長 度 1 I 之 軸 的 横 切 方 向 而 偏 轉 0 該 供 料 可 被 導 入 具 有 可 分 解 該 供 1 1 I 料 使 成 為 諸 如 碳 氧 化 物 氣 體 之 狀 況 的 區 域 56 〇 在 反 懕 器 12 請 先 1 I 更 閲 I 阻 塞 將 逸 出 之 供 料 和 分 解 產 物 之 剰 餘 的 操 作 期 間 該 分 it 背 1 1 解 的 產 物 可 留 在 耐 火 襯 套 内 因 而 白 動 密 封 該 埋 入 式 人 Ρ 面 之 1 注 1 0 一 部 份 之 該 分 解 產 物 可 經 耐 火 襯 套 19而 到 達 熔 融 浴 48 〇 意 事 1 項一 V I 在 第 二 圖 中 顯 示 本 發 明 之 一 第 二 實 施 例 0 錐 形 板 6 6被 Μ ά. 放 置 在 鼓 風 □ 20周 邊 〇 外 邊 緣 68延 伸 向 熔 融 浴 48以 横 向 於 % 本 頁 1 該 鼓 風 □ 之 軸 而 導 引 逸 出 之 供 料 使 到 達 熔 融 浴 4 8 0 該 供 料 '—^ 1 I 可 被 導 入 具 有 能 夠 分 解 該 供 料 成 為 分 解 產 物 之 狀 況 的 區 域 1 1 1 56 0 這 些 產 物 可 停 留 在 該 耐 火 襯 料 内 阻 止 更 將 逸 出 之 供 1 料 和 分 解 產 物 〇 在 另 一 霣 施 例 中 該 板 垂 直 地 白 該 鼓 風 口 訂 1 延 伸 並 成 圓 錐 形 地 朝 向 該 熔 融 浴 〇 1 I 在 第 三 圖 中 顯 示 本 發 明 之 一 第 二 實 施 例 0 一 序 列 之 板 1 1 1 可 被 使 用 〇 例 如 第 二 板 90被 放 置 在 鼓 風 口 20周 邊 〇 第 二 * 1 板 9 0偏 轉 至 少 一 額 外 部 份 白 熔 融 浴 48逸 出 的 供 料 〇 第 二 板 Γ 90可 平 行 於 板 54 C 在 一 實 施 例 中 第 二 板 90具 有 __- 較 板 54 1 I 為 大 的 直 徑 〇 較 佳 地 板 5 4的 放 置 使 板 54上 的 溫 度 高 於 該 1 1 I 供 料 的 分 解 溫 度 且 第 二 板 90Κ 高 於 該 分 解 產 物 的 汽 化 溫 1 度 而 放 置 0 在 另 實 施 例 中 諸 如 三 重 板 的 多 重 板 被 使 用 1’ 著 0 而 且 該 等 板 可 不 同 材 料 構 成 9 諸 如 其 中 板 金 1 I 屬 構 成 ， 而 一 第 二 板 Μ 陶 瓷 構 成 〇 再 者 > 每 —. 板 可 以 個 別 1 1 地 K 適 當 加 紈 法 加 熱 〇 1 1 — 11 — 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） a? B7 五、發明説明（β ) 在第四圖中顯示本發明之一第四實施例。鼓風口組裝 69具有一無板的鼓風口組裝襯套鼓風口組裝襯套7〇容 許分解之氣體產物和液體被容納於鼓風口組裝70並被導入 在部位92内的熔融浴。鼓風口組裝襯套70可被以類似於連 接板54至鼓風口 20之密封53的方法而連接至鼓風口 20。 熟悉本技藝之人士將認知或能夠使用僅僅慣常之實驗 而確知本文中記載之發明特定實施例的許多相同部份。如 此之相同部份將包含在Μ下之申請專利的範圍之内。 (請先閲讀背面之注意事項名填寫本頁) 經濟部中央標準局員工消費合作社印製 -12- 本紙張尺度適用中國_國家標準（CNS ) Α4規格（2]〇Χ：297公釐）A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. The description of the invention (ip) symbol represents the same item. However, it should be understood that the specific embodiments of the present invention are shown diagrammatically rather than the limits of the present invention. The features of the invention can be used in different embodiments without departing from the scope of the invention. Unless otherwise specified, all parts and percentages are shown in proportion. The present invention relates generally to equipment having a refractory bushing κ to seal an embedded inlet in a molten metal S-reactor. The method and apparatus for decomposing waste I in a molten bath are disclosed in U.S. Patent Nos. 4,574, 14 and 4,602,574 issued to Bach et al. The methods and equipment described in these patent documents can destroy or selectively destroy non-organic residues together with the atmosphere and other organic waste. Other equipment and methods for decomposing waste in a molten bath and using M to form gas, glass and molten metal product flows from the waste are disclosed in U.S. Patent No. 5, 3 0 1 issued to N age 1 eta 1 , 6 2 0. An embodiment of the invention is described in the first figure. Among them, the system 10 includes a reactor 12 in which K contains a molten bath suitable for decomposing a feed. Examples of suitable reactors include steel-made containers suitably modified by conventional techniques, such as K-BOP, Q-BOP, argon-oxygen decarburized molten ore (AOD), BOF, etc. Moreover, another suitable reactor is disclosed in U.S. Patent No. 5,301,620. The reactor 12 includes an upper part 14 and a lower part 16. The outgassing outlet 18 extends from the upper portion 14 and is suitable for guiding an outgassing compound out to the reactor 12. The reactor 12 is provided with a thin shell 17 of gold and a refractory bush 19 as a lining. The refractory bushing 19 can be made of alumina (Al7 〇3), silicon dioxide (S i 0 2), thorium dioxide (T h 0 2), magnesium oxide (M g 0), zirconium dioxide-6 The paper standard is applicable to the Chinese National Standard (CNS & A4 specifications (2 丨 〇 > < 297mm> (please read the notes on the back -ff to fill out this page) Order · A7 B7 Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Print 5. Description of the invention () 1 1 (Zr 0 z) or other suitable materials such as ceramic bricks 3 The refractory 1 I liner can be covered by a gas-impermeable coating such as sputtered oxygen 1 1 I Aluminum oxide 〇Concentric opening and reaching the inlet 24 〇The covering gas can be a passive gas such as argon or please 1 1 Neon or propane hydrocarbon 0 Reading back 1 1 The bottom tapping the screw nozzle tube 44 extends the white reactor 12 The lower part 16 and the surface 1 are suitable for the removal of molten gold in the reactor 12. The induction coil 4 6 is located in the lower part 1 Item part 16 Use M to add a molten bath to the reactor 12. As far as I know, the reactor 12 or other suitable methods such as oxygen JJMl fuel m Aim burner arc etc. / <! > < 0 1 I molten bath 4 8 is formed in the reactor 1 2. The molten bath 4 8 may contain up to 1 1 I less than one metal or molten metal. Examples of suitable gold oxides include Afb Iron, copper, nickel, zinc, etc. 0 Suitable species include sodium chloride, potassium oxychloride, etc. 0 Melting bath 48 can also be ordered 1 can contain a metal K. For example, the molten bath 4 8 can contain materials such as iron and baht 1 I The solution of the mixture of gold and thorium 0. In the embodiment, the molten bath 4 8 may be approximately 1 1 I composed of basic metals. Alternatively, the molten bath 48 may be approximately Μ gold and hydride like Ί 0. The molten bath 4 8 is a suitable metal. Or it is composed of at least partially filled reactor 12 0 in another Rainstorm Example molten bath 48 based Κ not easily mixed with the 1 I metal constituting the square of these is not miscible metal may be coated on the gold dimple containing such as iron 1 1 I 50 and as the second metal copper metal. The melting bath 4 8 can be heated by a suitable method such as an induction coil or an oxygen m material m burner such as an end 1> C * I. The proper operation of the system 10 includes conditions such as. The temperature is at least partially 1 I convert the carbon-containing feedstock into basic carbon or other basic components by decomposition method. 1 1 1 Generally, the appropriate temperature is between 1300 -7- and 1700 degrees Celsius. 0 1 1 1 1 1 Applicable to China National Standard (CNS) A4 specification (210X297 gong) A7 B7 325248 V. Description of invention (L) The glass layer 54 is formed on the molten bath 48. The glass layer 54 is not easily mixed with the molten bath 48. The glass layer 54 may have a lower thermal conductivity than the molten bath 48. The radiant heat lost from the molten bath 48 can thus be greatly reduced to mercury. The tuyere 2 G is located in the lower part 16 of the reactor 12 and can be a multiple concentric tuyere, especially a triple concentric tuyere. And a concentric tuyere 21 includes a supply pipe 22 for injecting a supply at the supply inlet 24. The liner 26 extends between the supply pipe 22 and the supply source 28 to guide the supply from the supply source 28 through the spring 30 to the supply pipe 22 with K. The oxidant pipe 32 of the tuyere 20 is placed concentrically around the feed pipe 22 at the tuyere inlet 24. The liner 35 extends between the oxidant source 36 and the oxidant tube 34 to direct a suitable oxidant to the oxidant tube 34 with K. The oxidant may be oxygen or air M capable of oxidizing a portion of the residue to form decomposition products such as carbon monoxide or carbon dioxide. The covering gas tube 38 of the tuyere 2 {) is placed concentrically around the oxidant tube 32 at the inlet 24K. The lining 40 extends between the covering air tube 38 and the covering air source 42 to guide a suitable covering air to the radiant heat lost from the melting bath 48 via the glass layer 54 between the oxidant tube 32 and the covering gas tube 38 . Typically, the glass layer 54 contains at least one gold oxide oxide. The glass layer 54 can contain an appropriate compound to purify halogen M such as chlorine or fluorine with M to prevent the formation of hydrogen halide gas such as hydrogen chloride. In one embodiment, the operating state of the glass layer 54 in the system 10 includes a metal oxide with free energy of oxidization, which is less than the oxidation from the atomic carbon to carbon monoxide 'such as calcium oxide (Ca 0) . -8- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297). (Please read the precautions on the back-S to fill out this page) Order · A7 B7 Economy Printed by the Employee Consumer Cooperative of the Central Standard Rating Bureau of the Ministry of Economic Affairs Printed by the Ministry of Standards and Standards Bureau employee consumer cooperative. V. Description of invention () 1 1 As shown in the first figure A 9 A white dynamic seal of the embedded type D Including the blast 1 1 I □ 20 and the plate 54 which is located in the fire-resistant The liner 19 covers the periphery of the gas tube 38. The plate 54 has an inner radius that is approximately the same as the outer radius of the blower Ρ20. The outer edge of the plate 54 extends to the refractory liner. Inside the area 56 in the sleeve 19, the read back 1 1 area 5 6 is in the condition that the decomposition occurs in the note 1 I of one of the feeds S quality Λ in which the decomposition occurs. Idea 1 Item 1 A space 58 extends from the inner surface of the refractory bushing 19 4 to the plate 54 between the refractory bushing 19 and the tuyere 20. The space 58 at the operating temperature of the reactor A difference is formed within the thermal expansion of the refractory material 19 and the blast □ 2 0 1 1 result 〇1 I plate 54 i The outer circumference of the blast 0 20 extends into the refractory bushing 19 1 1 Set 1 0 In one embodiment, the annular plate has a radius of about 8 cm and a thickness of about 0.1 cm. The surface 54 of the plate 54 with the fire liner 19 starts from about 10 cm. In another 1 | the plate 5 4 in the example is wavy. 0 The operating conditions of the reactor 12 9 1 I The temperature at the outer edge of the plate It is approximately in the range of 80 to 1 1 0 ° C. The temperature in the range Ί 0 is outside the heated by the molten bath. The plate 54 can be heated by the impedance of other currents such as the current conducted through the plate. 0 The ring-shaped plate system is considered It is very thin, and the ratio of K to 1 I ((Kr / Lr) / (Kf / Lf)) / (L f / 5 f) is approximately greater than 1 1 I 0 Kr and Kf represent the refractory bushing and ring Thermal conductivity of the board. Lr 1 I represents the distance from the refractory surface 21 to the panel 54. Lf represents self-covering gas «an trtfr: distance from Zhao 38 1 to the edge 5 5 outside the plate 54 0 δ f represents the thickness of the plate 54 c 1 I plate 5 4 series > λ can resist this operation in the reactor 12 The temperature and condition of the melting 1 I bath 46 and the feed material at the temperature. In the spring example, the plate 54 is selected with white 1 1 I-9- 1 1 1 The paper size is applicable to the Chinese National Standard (CNS) A4 Specifications (210X297mm) Printed by the Consumer Standardization Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Α7 Β7 V. Description of invention (8) Made of one metal in the group consisting of stainless steel, titanium, tungsten, tantalum and zirconium. Also, a ceramic can be used. The plate 54 is attached to the tuyere 20 in such a manner that a seal 53 is formed between the plate 54 and the tuyere 20 through which the feed material passes. For example, the plate 54 may be welded to the tuyere 20. Thermocouple 62 may be placed at point M on plate 54 to monitor the temperature of ring plate 54. The tuyere 24 and the plate 54 can be a tuyere assembly 69. Blast port assembly 6 9 can be formed into a refractory brick by the M blower port assembly bushing 7 fl or a 6 9 "can" assembled around the blow port. The tuyere assembly bush 70 can be constructed of a gold coat, ceramic or plasma coating. A suitable material contains the case where the melting point is higher than the operation of the molten bath and can resist chemical reactions. This material includes tungsten, zirconia, and sputtered zirconium. In one embodiment, the tuyere assembly bushing 70 is a M-gold or plasma coating to form M to prevent gas from going out through the sides of the tuyere assembly 69. The plasma coating is a material that is conventionally used by the plasma spray method. A feed such as a gas, liquid, or solid is introduced from the feed source 28 through the lining 26 to the feed pipe 22 in the reactor 2Q to be melted. Bath 48. The feed enters the molten bath 48 at the inlet 24. Oxygen or another oxidant is led from the oxidant source 35 through the liner 34 to the oxidant tube 38. A suitable covering gas system, such as hydrocarbon or pure gas, is led from the covering gas source 42 through the lining 40 to the covering gas tube 38. When the feed material is introduced into the molten bath 48, a portion of the feed material is accumulated by the blast opening 24 and the static pressure of the molten bath 48 toward the refractory bush 19 and the space 58 adjacent to the refractory bush 13 Turn around. The feed material moves along the outside of the tuyere 20 in a direction 64 toward the outside of the reactor 12. Board 54 enables-10- This paper scale is applicable to the Chinese national standard ^ Milk ^ Private view grid ^ ⑽29 · ^ *) (please read the precautions on the back first to fill out this page) Order- · A7 B7 Employee consumption cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Du Yinzhi V. Description of the invention (1) 1 1 At least a part of the feed material escaping from the white molten bath 48 extends the length of the tuyere 20 1 the transverse direction of the axis of the I is deflected 0 the feed material can be introduced with It can decompose the supply 1 1 I material into a region such as a carbon oxide gas 56. At the reactor 12, please read 1 I first. I block the excess of the supply and decomposition products that will escape. The product of the split 1 1 solution can be left in the refractory bushing, so that the buried human P surface 1 is white sealed. Note 1 0 A part of the decomposition products can reach the molten bath 48 through the refractory bushing 19. Idea 1 item one VI in the second A second embodiment of the present invention is shown in Fig. 0. The conical plate 6 is placed by 6 Μά. Placed on the periphery of the blast 20. The outer edge 68 extends toward the molten bath 48 to be transverse to the% page 1 of the axis of the blast Guide the escaping supply to reach the molten bath 4 8 0 The supply '— ^ 1 I can be introduced into an area with conditions that can decompose the supply into decomposition products 1 1 1 56 0 These products can stay in the refractory In the lining, the feed and decomposition products are prevented from escaping. In another embodiment, the plate extends vertically to the tuyere and extends conically toward the molten bath. A second embodiment of the invention is shown in FIG. 0 A sequence of plates 1 1 1 can be used. For example, a second plate 90 is placed around the blast port 20. A second * 1 plate 90 is deflected by at least an additional portion of white melt Feed material escaping from bath 48. Second plate Γ 90 can be flat In an embodiment of the plate 54 C, the second plate 90 has a diameter larger than that of the plate 54 1 I. Preferably, the placement of the floor 54 makes the temperature on the plate 54 higher than the decomposition of the 1 1 I feed. Temperature and the second plate 90K is 1 degree higher than the vaporization temperature of the decomposition product and placed 0. In another embodiment, multiple plates such as triple plates are used 1 ′ to 0 and the plates can be made of different materials 9 such as plate gold 1 I It belongs to a composition, and a second plate M ceramic composition 〇 No. > Each-. The plate can be individually 1 1 K to add appropriate heating method 〇1 1 — 11 — 1 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) a? B7 V. Description of the invention (β) In the fourth figure, a fourth embodiment of the invention is shown. Blower assembly 69 has a plateless blower assembly bushing Blower assembly bushing 70. Allowable decomposed gas products and liquids are contained in the blower assembly 70 and introduced into the molten bath in the portion 92. The tuyere assembly bushing 70 may be connected to the tuyere 20 in a similar manner to the seal 53 connecting the plate 54 to the tuyere 20. Those familiar with the art will recognize or be able to use only routine experimentation to ascertain many of the same parts of the specific embodiments of the invention described herein. The same part will be included in the scope of patent application under Μ. (Please read the note name on the back to fill in this page) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs -12- This paper scale is applicable to China_National Standard (CNS) Α4 Specification (2) 〇Χ: 297mm)